CLASS :- XIIth CHEMISTRY BY :- VIBHA MAM (8375810029)

An Expert of Conceptual & Magical Chemistry

(DO/DIE QUESTIONS)
DPP – 1 (Chapter – Some Basic Concepts of Chemistry)
Q.1. Based on Laws of chemical combination Q.2. A mole is defined as
which of the following statement is correct a) The amount of substance containing the same
a) In compound A, 1.00g nitrogen combines with number of chemical units as the number of atoms in
0.57g oxygen. In compound B, 2.00g nitrogen exactly 12g of C12
combines with 2.24g oxygen. In compound C, 3.00g b) The amount of substance containing Avogadro
nitrogen combines with 5.11g oxygen. These results number of chemical units
obey Law of multiple proportion c) The unit for expressing amount of a substance
b) In the reaction Hydrogen(g) + Oxygen(g) → water d) The gas that occupies 22.4 L at NTP
vapour, the ratio of volumes is 2 : 1 : 2. This Q.3. One mole of atoms of oxygen represents
illustrates Avagadro’s law a) 6.02 2 1023 Molecules of SO3
c) Two samples of lead oxide were separately b) 32g of oxygen
reduced to metallic lead by heating in a current of c) 22.4L of CO at STP
hydrogen. The weight of lead from one oxide was d) 8g of Ca(OH)2
half the weight of lead obtained from the other Q.4. The mixture containing the same number of
oxide. The data illustrates Law of definite molecules as that 14g of CO is
proportions a) 14g of Nitrogen + 16g of Oxygen
d) A sample of pure carbon dioxide, irrespective of b) 18g of Glucose + 6g of Urea
its source contains 27.27% carbon and 72.73% c) 53g of Na2CO3 + 2g of H2
oxygen. The data support law of conservation of d) 85.5g of Sucrose + 180g of C60
mass
CLASS :- XIIth CHEMISTRY BY :- VIBHA MAM (8375810029)
Q.5. Which of the following samples contain 0.1 a) 1 mole of N2O2 and 1 mole of N2O4
mole glucose b) 1 millimole of HCl and 0.5 millimole of H2SO4
a) 9 gms of glucose c) 11.2 cc of nitrogen (at STP) and 0.015 g of nitric
b) 100 ml of 2 M glucose solution oxide
c) 6.023 × 1022 molecules glucose in 100 ml water d) 22.4 litres of nitrous oxide (at STP) and 22.4 litres
d) 500 ml of 10% W/V glucose solution of nitric oxide (at STP)
Q.6. Which of the following statement is correct Q.11. In the reaction Hydrogen (g)+Oxygen(g)
a) 0.66g of a compound gave 112ml of nitrogen gives water vapour, the ratio of volumes is 2 : 1
measured at STP in the Dumas method. The :2.
percentage of Nitrogen in the compound is 21.2 This illustrates the law of
b) A compound contains 90% C and 10% H. The a) conservation of mass
empirical formula of the compound is C15H30 b) combining weights
c) 60g of a compound on analysis gave C=24g, c) combining volumes
H=14g and O=32g. Its empirical formula is CH2O d) all the above
d) The empirical formula of a compound is C2H2O. Q.12. Which of the following reactants is not
Its molecular weight is 120. The molecular formula correct according to the law of conservation of
of the compound is C4H8O5 mass?
Q.7. 6.023 × 1022 atoms of Hydrogen can not a) 2 Mg(s) + O2(g) →2 MgO(s)
form b) C3H8(g) + O2(g) →CO2(g) + H2O(g)
a) 0.05 moles of H2 molecules c) P4(s) + 5O2(g) →P4O10(s)
b) 0.1 gms of Hydrogen atoms d) CH4(g) + 2O2(g) →CO2(g) + 2H2O(g)
c) 0.1 ‘gram-molecules’ of Hydrogen Q.13. Which of the following combinations
d) 0.1 ‘gram-atoms’ of Hydrogen illustrate the law of Multiple proportion?
Q.8. Match Amount of product formed with a) PH3, P4O6, P4O10
appropriate reaction b) CH4, CO2, H2O
Column I Column II c) NaCl, NaBr, NaI
(Reaction) (Product formed) d) N2O, N2O3, NO2
A N2 + 3H2 → 2NH3 P 4.16 × 10 mol Q.14.
0.1 mol 0.1 mol List – I List – II
B H2 + 2C → C2H2 Q 4.16 × 10 mol (Molecules) (Empirical
1g 1g Formula)
C C + O2 → CO2 R 6.25 × 10 mol A Glucose [C6H12O6] 1 BNH2
0.5g (22.4 L at NTP) B Oxalic acid [H2C2O4] 2 CH2O
D 2H2 + O2 → 2H2O S 6.67 × 10 mol C Inorganic Benzene 3 CH
1g 1g [B3N3H6]
a) A-S, B-P, C-Q, D-R b) A-R, B-P, C-Q, D-S D Oxygenated water 4 CHO2
c) A-P, B-Q, C-S, D-R d) A-S, B-R, C-Q, D-P [H2O2]
Q.9. Nitrogen forms five stable oxides with 5 HO
oxygen of the formula, N2O, NO, N2O3, N2O4, N2O5. The correct match is
The formation of these oxides explains fully the A B C D A B C D
a) Law of definite proportions a) 3 5 2 4 b) 2 4 1 5
b) Law of partial pressures c) 1 3 2 4 d) 4 2 1 3
c) Law of multiple proportions Q.15. The empirical formula of acetic acid
d) Law of reciprocal proportions. (CH3COOH) is the same as that of
Q.10. Which of the following pairs contains a) Sucrose (C12H22O11) b)
equal number of atoms? Glucose(C0H12O6)
CLASS :- XIIth CHEMISTRY BY :- VIBHA MAM (8375810029)
c) Oxalic acid (H2C2O4) d) Formic acid c) 2 moles d) 6.023 × 1024
(HCHO) Q.23. A gaseous mixture contains (in grams) CO2
Q.16. A molecule is found to contain 47.35% C, and O2 in the ration 11 : 8. Therefore the ratio of
10.60% H and 42.05% O. What is the empirical the number of CO2 and O2
formula? a) 1 : 2 b) 1 : 1
a) C2H6O b) C3H8O2 c) 2 : 1 d) 11 : 8
c) C4H8O3 d) C4H8O3 Q.24. Arrange the following in order of
Q.17. An organic compound is found to contain C increasing mass
= 54.5%, O=36.4% and H = 9.1% by mass. Its (i) 3.0115 × 1023 molecules of white phosphorus
empirical formula is (ii) 10 moles of H2 gas
a) CH2O b) CHO2 (iii) 1 g molecule of anhydrous Na2CO3
c) C2H4O d) C3H4O (iv) 33.6 L of CO2 gas at STP
Q.18. a) ii < i < iv < iii b) iii < iv < i < ii
List I List II c) i < ii < iv < iii d) i < iv < iii < ii
(Wt. of the gas) (Volume at S.T.P.) Q.25. 1.5 mol of O2 combines with Mg to form
A 3 grams of ethane 1 11.2 lit oxide MgO. The mass of Mg (at. mass 24) that has
B 7 grams of Nitrogen 2 2.24 lit combined is
C 3.35 grams of 3 5.6 lit
a) 72 g b) 36 g
chlorine
c) 48 g d) 24 g
D 8.8 grams of CO2 4 4.48 lit
5 1.12 lit Q.26. How much sulphur is to be burnt to
Answer is produce 0.224 lit of SO2 at NTP?
a) A-2, B-4, C-3, D-5 b) A-2, B-1, C-5, D-4 a) 0.03g b) 0.32g
c) A-2, B-3, C-5, D-4 d) A-4, B-2, C-5, D-1 c) 3.2 g d) 32g
Q.19. One mole of CO2 contains Q.27. When 22.4 litres of H2(g) is mixed with
a) 3 gram atoms of CO2 11.2 litres of Cl2(g) each at S.T.P. the moles of HCl
b) 18 × 1023 CO2 molecules (g) formed is equal to
c) 6 × 1023 O atoms a) 1 mol of HCl(g) b) 2 mol of HCl(g)
d) 6 × 1023 C atoms c) 0.5 mol of HCl(g) d) 1.5 mol of HCl(g)
Q.20. The pair of gases containing the same Q.28. Liquid benzene (C6H6) burns in oxygen
number of molecules is according to the equation
a) 22g of CO2 and 14g of N2 2C6H6(l) + 15O2 (g) → 12CO2 (g) + 6H2O(g)
b) 8g of O2 and 22g of CO2 How many litres of O2 at STP are needed to
c) 28 g of N2 and 22 g of CO2 complete the combustion of 39 g of liquid
d) 32g of O2 and 32g of N2 benzene?
Q.21. Maximum number of atoms are present in 1.10 (Mol wt of O2 = 32, C6H6 = 78)
a) 11.2 lit. of SO2 at STP a) 74 L b) 11.2 L
b) 22.4 lit. of Helium at STP c) 22.4 L d) 84 L
c) 2.0 gms. of hydrogen Q.29. Match the column I with column II and
d) 11.2 litres of methane at STP mark the appropriate choice.
Q.22. 4.4 g of CO2 and 2.24 litre of H2 at STP are Column I Column II
mixed in a container. The total number of A Mass of H2 produced i 3.01 × 10
when 0.5 mole of zinc molecules
molecules present in the container will be
reacts with excess of HCl
a) 6.023 × 1023 b) 1.2046 ×
1023
CLASS :- XIIth CHEMISTRY BY :- VIBHA MAM (8375810029)
B Mass of all atoms of a ii 6.23 × 10 a) 6.0 × 1023 b) 1.3 × 1023
compound with formula molecules c) 3.8 × 1022 d) 6.0 × 1021
C70H22 Q.38. Which of the following has maximum
C Number of molecules in iii 1.43 × 10 g mass?
35.5 g of Cl2
a) 0.1 g atom of C
D Number of molecules in iv 1 g
64 g of SO2 b) 0.1 mole of NH3
a) A-ii, B-i, C-iv, D-iii b) A-i, B-ii, C-iii, D-iv c) 6.02 × 1022 molecule of H2 gas
c) A-iv, B-iii, C-i, D-ii d) A-iv, B-iii, C-ii, D-i d) 1120 ml of CO2 at 1 atm, 273 K
Q.30. The number of oxygen atoms present in 1 Q.39. The number of gram molecules of oxygen
mole of H2C2O4·2H2O in 6.02 × 1024 CO molecules is
a) 6 × 1023 b) 6.023 × 1034 a) 10 g molecules b) 5 g molecules
c) 7.22 × 1023 d) 36.13 × 1023 c) 1 g molecules d) 0.5 g molecules
Q.31. A mixture having 2g of hydrogen and 32g Q.40. In the reaction,
of oxygen occupies how much volume at NTP ? 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l)
a) 44.8 L b) 22.4 L when 1 mole of ammonia and 1 mole of O2 are
c) 11.2 L d) 67.2 L made to react to completion
Q.32. An organic compound contains C = 40%, H a) All the oxygen will be consumed
= 13.33% and N = 46.67%. Its empirical formula b) 1.0 mole of NO will be produced
is c) 1.0 mole of H2O is produced
a) C2H2N b) C3H7N d) All the ammonia will be consumed
c) CH4N d) CHN
Q.33. How much oxygen is required for complete
combustion of 560 g of ethene ?
a) 6.4 kg b) 1.92 kg
c) 2.8 kg d) 9.6 kg
Q.34. Calcium carbonate decomposes on heating
to give calcium oxide and carbon dioxide. How
much volume of CO2 will be obtained by thermal
decomposition of 50 g of CaCO3 ?
a) 1 L b) 11.2 L
c) 44 L d) 22.4 L
Q.35. The largest number of molecules is in
a) 36 g of water
b) 28 g of carbon monoxide
c) 46 g of ethyl alcohol
d) 54 g of nitrogen pentoxide
Q.36. Volume at STP of 0.44 gm of CO2 is the same
as that of :
a) 0.02 gm of hydrogen gas
b) 0.085 gm of ammonia gas
c) 320mg of sulphur dioxide gas
d) none of these
Q.37. How many H atoms are in 3.42 g of
C12H22O11?