GEWATA GENERAL SECONDARY SCHOOL

2017 E.C / 2025 G.C CHEMISTRY WORKSHEET FOR

GRADE 11 AND 12TH

DIRECTION I : CHOOSE THE CORRECT ANSWER FROM THE FOLLOWING ALTERNATIVES

1. Which one of the following compounds contains both ionic, covalent and dative
bond? A. CH3Cl B.NH4Cl C. NH3BF3 D. Al2Cl6
3
2. All of these molecular shapes can be explained by sp d hybridization of
electrons on the central atom EXCEPT
A. T-shape B. See-saw C. Trigonal planar D. Trigonal bipyramidal
3. From the following AFn molecules, which one has the smallest bond angle?
A. BF3 B. CF4 C. NF3 D. OF2
4. The hybridization of carbon atoms in C2H2, C2H4 and C2H6. respectively are:
2 3 2 3 3 2
A. sp , sp and sp B. sp3, sp2 and sp C. sp, sp and sp D. sp , sp and sp
5. The C-to-C bond in ethanal molecule (CH3CHO) is connected by the overlap
of____&____ hybrid orbitals. A. sp3, sp 2 B. sp, sp C. p, sp D. sp 3, sp
6. Which one of the following molecules has a dipole moment (is polar)?
A. CCl4 B. PF5 C. NCl3 D. SO3
7. According to Molecular orbital theory (MOT) theory, which species has the
shortest bond length? A. O22- B. O2+ C. O2 D. O2-
8. A (pi) bond is the result of the:
A. Sidewise overlap of two parallel p orbitals C. Overlap of two s orbitals.
B. Overlap of two p orbitals along their axes. D. Overlap of an s and a p orbital
9. The following table shows substance of comparable molecular mass with their
dominant intermolecular forces.
Substance Dominant intermolecular force
A Hydrogen bonding
B London-dispersion force
C Dipole –dipole force
Which of the following is FALSE about the substances?
A. “B” has the weakest intermolecular force attraction
B. “C” has the highest boiling point than “A”
C. “A” has the strongest intermolecular force attraction
D. “C” has the strongest intermolecular than “B”
10.If a molecule has Trigonal bipyramidal electron pair arrangement and T –shape
molecular geometry, how many non-bonding pair of electrons is present in the
valence shell of the central atom? A. 1 B. 2 C. 3 D. 0
11.Which reaction involves a change in the hybridization state of the underlined atom?
A. 2SO2 + O2 → 2SO3 C. H2O + H+ → H3O+
B. BF3 + F- → BF4- D. NH3 + H+ → NH4+
12.In ___________ bond, two atoms share valence electrons (outer-shell electrons),
which are attracted to the positively charged cores of both atoms, thus linking
them. A. Covalent B. Metallic C. Ionic D. Dative
13.A __________ is a bond formed when both electrons of the bond are donated
by one atom: A. Donor-Acceptor B. Coordinate covalent C. Dative D. None
14.A neutral molecule having the general formula AB3 has two unshared pair of
electrons on A. What is the hybridization of A? A. sp B. sp2 C. sp3 D. sp3d
15.Which of the following is the ground-state electron configuration of a C3- ion?
A. 1s22s22p4 B. [He]2s1 C. [He] 2s22p6 D. 1s22s22p5 E. 1s22s22p63s1
16.Which of the following molecules contains only double bonds? If none do, so
state. A. NCCN B. CO2 C. C2H4 D. O3 E. N2
17.Point out Incorrect about symbol of an atomic ion with its electron configurations:
A. Ca+; 1s22s22p63s23p6 B. Sc3+; 1s22s22p63s23p64s1 C. Co2+; 1s22s22p63s23p63d8
D. Ga3+; 1s2 2s22p63s23p63d104s2 E. Rb+; 1s22s22p63s23p63d104s24p6
18.An ion M2+ has the configuration [Ar]3d2, and an atom has the configuration [Ar]4s2.
2+ 2+ 2+ 2+
Identify the ion & an atom. A. Fe & Fe B. Zn & Zn C. Ti & Ti D. Ca &Ca
19.According to the VSEPR model, the bond angle in PH3 is
A. 1200 B. 109.50 C. 900 D. a little less than 1200 E. a little less than 109.50
20.Which of the following molecular geometries does the XeF5+ cation exhibit?
A. Tetradral B. T-shaped C. Octahedral D. Square pyramidal E. Trigonal bipyramidal
21.One is a polar molecule A. CO2 B. H2S C. CH4 D. SF6 E. BeF2
22.What is the bond order of NO? A. B. 1 C. D. 3 E.
23.Which of the following molecules would be expected to have zero dipole moment on the
basis of their geometry? A. CS2 B. TeF2 C. SeCl4 D. XeF4
24.Points out series of diatomic molecules are arranged in order of increasing order
of bond length.
A. F2 > Cl2 > ICl > BrCl > I2
B. F2 > BrCl > Cl2 > ICl > I2
C. F2 < Cl2 < BrCl < ICl < I2
D. BrCl < F2 < Cl2 < I2 < ICl
25.Which of the following molecules would be expected to have a dipole moment of zero
because of symmetry? A. SeF2 B. BeI2 C. TeF6 D. TeF4
26.The concept that electron pairs located in the valence shell of an atom bonded
to other atoms tend to stay as far apart as possible so as to minimize repulsions
between them is incorporated in the:
A. Heisenberg uncertainty principle C. Molecular orbital theory
B. Valence shell electron pair repulsion theory D. Valence bond theory
27.Only one molecule has a linear geometry. Identify it:
A. Water B. Ammonia C. Methane D. Tri iodide ion
28.If the geometry is T-shape, then how many lone pairs are there on the central
atom? A. 1 B. 2 C. 4 D. 3
29.Dimethyl ether (CH3-O-CH3) boils at -240 its isomer ethanol CH3CH2OH boils
at 78.30. Why?
A. Dimethyl ether is more volatile than ethyl alcohol
B. Hydrogen bonding exists in ethyl alcohol but not in dimethyl ether
C. Ethanol is polar while dimethyl ether is not polar
D. Density of dimethyl ether is smaller than ethyl alcohol
30.Point out species DOES NOT resonate. A.NO2 B. CO32- C.SO3 D. NO3- E. BF3
31.Identify a molecule that is not paramagnetic A. NO B. O2- C.CO+ D. O2 E.O22-
32.Of the following molecule,one can’t exist A. NO+ B.CN- C.H2+ D.Ne2 E. He2+
33. How many pi (π) bond are there in butenyne? A. 2 B. 0 C.1 D. 3
34.Identify the molecule having 2σ & 2π bonds. A.C2H2 B. CO C. HCN D. N2O4
35.Using the following data, what is the lattice energy potassium fluoride (KF)?
Enthalpy of sublimation (ΔHSub) 90kJ/mol
Enthalpy of dissociation (ΔHDis) 160 kJ/mol
Enthalpy of ionization energy (ΔHIE) 419 kJ/mol
Enthalpy of electron affinity(ΔHEA) -328 kJ/mol
0
Enthalpy of formation (ΔHf ) -547kJ/mol
Lattice energy (U) = ?
A. -888 kJ/mol B.888 kJ/mol C. -808 kJ/mol D. 808 kJ/mol
36.Point out series of compounds that arranged in order of increasing order of ionic
character.
A. NaI > NaBr > NaCl > NaF
B. NaF < NaCl < NaBr < NaI
C. NaI < NaBr < NaCl < NaF
D. NaF > NaCl > NaBr > NaI
A. Sulfur D. Phosphorus

37. The element X below could

¨
·X· B. Iodine
C. Aluminum
E. Silicon

¨
 38.How many bonding pairs and lone pairs, respectively does the tri-iodide ion
(I3-) have? A.3,6 B. 2,18 C. 2,9 D. 4,6
39.The reason, why at room temperature, Cl2 is a gas, Br2 is a liquid, and I2 is a
solid? A. Dipole-dipole force B. Hydrogen bonding
C. London dispersion force D. Ionic bonding
40.Which of the following are isoelectronic with the potassium ion, K+?
−
A. Al B. Cl C. Kr D. Cl+ E. Ca+
41.Carbon and chlorine form a series of compounds: CH3Cl, CH2Cl2, CHCl3, CCl4. Which of these will
be polar?
A. CCl4 only
B. CH3Cl and CHCl3 only
C. CH3Cl, CH2Cl2 and CHCl3 only
D. CH3Cl, CH2Cl2, CHCl3 and CCl4

DIRECTION II: MATCH THE FOLLOWING ITEMS UNDER COLUMN “A” WITH ITEMS UNDER COLUMN “B”
“A” “B”
1. Hetroatomic molecules A. They have Seesaw geometry
2. Homoatomic molecules B. Formed when electrons are distributed unequally.
3. Hybridization C. CO2, SO2, H2O, HCl, …etc
4. CH4 D. Bond order equals to three
5. SF6 E. KCl, CsCl, NaCl,…etc
6. BF3 F. Side to side overlap
7. PCl5 G. Diamond, SiC, Graphite
8. Molecular Crystals H. H2, O2, Cl2, F2, …etc
9. Ionic Crystals I. Intermixing of atomic orbitals to form new orbitals
10. Covalent network solid J. Aspirin, Sugar, Dry CO2, …etc
11. Pi (π) bond K. Head to head overlap
12. Triple bond L. sp3 hybridization
13. Polar bond M. sp3d2 hybridization
− −
14. SiF4, IF4 , ICl4 N. sp2 hybridization
15. Sigma (σ) bond O. sp3d hybridization

DIRECTION II: GIVE APPROPRIATE ANSWER(S) FOR THE FOLLOWING

QUESTIONS ACCORDINGLY
1. Determine number of set of electrons and predict electron-pair geometry
(arrangement) on each the central atom for the following
a. SbF5
b. ICl3
c. XeF2
 d. CH3OH
e. Cl2O
f. ICl2−
g. CH3−CH2−CH=CH−C≡C−CH3
2. Determine number of unshared electron on central atom (if any) for the following
molecules, and state their geometry O
a. PCl3 c. O2 e. XeF4 ║
b. N2 d. H2O2 f. CH3− C−OH
3. Classify the following molecules as Paramagnetic or Diamagnetic, Stable or
Unstable [Hint: Use molecular (orbital) electron configuration]
a. N2 d. C22- g. O2+
b. NO- e. HeH+ h. BN
+ 2+
c. CN f. O2 i. C2+
4. Write some non-polar electron-pair molecules with polar bond [Hint: Dipole
moment]
5. Describe the hybrid orbitals used by each central atom in the following
molecules: a. N≡C−C≡N b. CH2=C=CH2 c. CH3OH d. HNO3 d.IF5
+
6. The oxygen–oxygen bond in O2 is 112 pm and in O2 is 121 pm. Explain why
the bond length in O2 is shorter than in O2. Would you expect the bond length in
−
O2 to be longer or shorter than that in O2? Why?
7. The nitrogen–nitrogen bond distance in N2 is 109pm. On the basis of bond
orders, would you expect the bond distance in N2+ to be less than or greater than
−
109pm? Answer the same question for N2 .
8. Write their electron configuration and state whether they fulfill octet or not
a. Sn and Sn2+ b. Ni2+ and Ni3+ c. Cu+ and Cu2+ d. Ga and Ga3+
9. Write the d/c b/n Non-crystalline (Amorphous) solids and Crystalline solids
give some examples for each of them.
10. List four major difference between sigma (σ) and pi (π) bonds.
11. Which one is stronger: sigma (σ) bond or pi (π) bond? Why?
12.The enthalpy change for each of the following reactions was calculated using
bond energies. The bond energies of X−O, Y−O,& Z−O are all equal.
X−X + O=O → X−O−O−X; ΔH = −275 kJ
Y−Y + O=O →Y−O−O−Y; ΔH = +275 kJ
Z−Z + O=O →Z−O−O−Z; ΔH = −100 kJ
a. Rank the bonds X−X, Y−Y, and Z−Z from strongest to weakest.
 b. Compare the energies required to completely dissociate each of the
products to atoms.
c. If O2 molecules were O−O instead of O=O, how would this change ΔH
for each reaction?
13.Given the dipole moment of the molecules
Molecules Dipole moment (D)
HF 1.92
NH3 1.47
HI 0.44
H2S 0.95
HCl 1.08
HBr 0.82
NF3 0.23
Arrange them in increasing order of:
a. Bond length b. Bond Strength c. Polarity
14.What kinds of intermolecular forces (London, dipole–dipole, hydrogen
bonding) would you expect in the following substances?
a. CHCl3 b. H2O c. F2 d. HBr e. CH3NH2
15.Determine the of pi (π) and sigma (σ) bonds in the following molecules
a. HCOOH c. H2SO4 e. SO2

b. O d. 1,3,5-hexatriene
║
C
OH
O
║
C
O CH3