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Xii - Chem - Work Sheet - 19.05.2025

The document is a worksheet for Class XII Chemistry at Arise International School of Excellence, focusing on colligative properties of solutions. It includes questions on various aspects of colligative properties, van’t Hoff factor, and related concepts. The worksheet consists of multiple sections including direct questions, one-word answers, multiple choice questions, and assertion-reason type questions.

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11 views2 pages

Xii - Chem - Work Sheet - 19.05.2025

The document is a worksheet for Class XII Chemistry at Arise International School of Excellence, focusing on colligative properties of solutions. It includes questions on various aspects of colligative properties, van’t Hoff factor, and related concepts. The worksheet consists of multiple sections including direct questions, one-word answers, multiple choice questions, and assertion-reason type questions.

Uploaded by

mohammedashad848
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ARISE INTERNATIONAL SCHOOL OF EXCELLENCE (CBSE)

KURANGU CHAVADI, PERUMAL MALAI ADIVARAM, SALEM.


CLASS : XII WORK SHEET SUBJECT: CHEMISTRY

I. READ THE FOLLOWING PASSAGE AND ANSWER THE QUESTIONS: (5X1=5M)


Colligative properties of a solution depend upon the number of moles of the solute dissolved and do not
depend upon the nature of the solute. However, they are applicable only to dilute solutions in which the
solutes do not undergo any association or dissociation. For solutes undergoing such changes, van’t Hoff
introduced a factor, called van;t Hoff factor(i). This has helped not only to explain the abnormal molecular
masses of such solutes in the solution but has also helped to calculate the degree of association or
dissociation
1. Name the colligative property in which universal gas constant is involved?
2. What is the value of van’t Hoff factor when the given electrolyte undergoes tetramerisation?
3. Why boiling point of water is increased on addition of sodium chloride into it?
4. What do you mean by isotonic solutions?
5. What is the value of I for Al2(SO4)3(very dilute)?

II. ONE - WORD ANSWERS: (5X1=5M)


6. Liquid ‘Y’ has higher vapour pressure than liquid ’ X’ .
Which of them will have higher boiling point.
7. Liquids A and B on mixing produce a warm solution.
Which type of deviation from Raoult’s law is shown?
8. Under what condition Van’t Hoff factor is less than 1?
9. Two liquids X and Y boil at 380 K and 400K respectively, which of them is more volatile?
10. Out of molarity(M) and molality(m), which is temperature dependent?

III. (MULTIPLE CHOICE QUESTION)MCQ: (5X1=5M)


11. The unit of ebulioscopic constant is.
(i) K kg /mol or K (molality)–1 (ii) mol kg/ K or K–1 (molality)
(iii) kg mol–1 K–1 or K–1(molality)–1 (iv) K mol kg–1 or K (molality)
12. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because.
(i) it gains water due to osmosis. (ii) it loses water due to reverseosmosis.
(iii) it gains water due to reverse osmosis. (iv) it loses water due to osmosis.
13. The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are .
(i) 2, 2 and 2 (ii) 2, 2 and 3 (iii) 1, 1 and 2 (iv) 1, 1 and 1
14. The value of Henry’s constant KH is .
(i) greater for gases with higher solubility. (ii) greater for gases with lower solubility.
(iii) constant for all gases. (iv) not related to the solubility of gases.
15. We have three aqueous solutions of NaCl labeled as ‘A’, ‘B’ and ‘C’ with concentrations
0.1M, 0.01M and 0.001M, respectively. The value of van’t Hoff factor for these solutions will
be in the order .
(i) iA < iB < iC (ii) iA > iB > Ic (iii) iA = iB = iC (iv) iA < iB > ic
IV. ASSERTION -REASON TYPE: (5X1=5M)
A statement of assertion is followed by a statement of reason. Mark the correct choice from the options
given below:
(a) Both assertion and reason are true and reason is the correct explanation of assertion.
(b) Both assertion and reason are true but reason is not the correct explanation of assertion.
(c) Assertion is true but reason is false.
(d) Both assertion and reason are false.
16. Assertion : In an ideal solution, ∆mix H is zero.
Reason : In an ideal solution, A - B interactions are lower than A-A and B-B interactions.
17. Assertion : Osmosis does not take place in two isotonic solutions separated by semi- permeable membrane.
Reason : Isotonic solutions have same osmotic pressure.
18. Assertion : Lowering of vapour pressure is not dependent on the number of species present in the solution.
Reason : Lowering of vapour pressure and relative lowering of vapour pressure are colligative properties.
19. Assertion : 1 M solution of KCl has greater osmotic pressure than 1 M solution of glucose at same
temperature.
Reason : In solution KCl dissociates to produce more number of particles.
20.Assertion : Two liquids nitric acid and water form a maximum boiling azeotrope when mixed
in the ratio of 68% and 32% respectively
Reason : Interaction between nitric acid and water are stronger than nitric acid - nitric acid
interactions and water - water interactions.

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