Classification of
Classification of
48. In the periodic table from left to right in 55. The element with atomic number 117
a period, the atomic volume has not been discovered yet. In which
(a) decreases family would you place this element if
(b) increases discovered ?
(c) remains same (a) Alkali metals
(d) first decrease then increases (b) Alkali earth metals
(c) Halogens
49. Four elements A, B, C & D. D is non (d) Noble gases
reactive gas. C is a highly reactive gas, B is
a solid & forms oxide, A is high reactive 56. Which one of the following is the correct
solid & used to prepare Lasagne’s solution. order of the size of iodine species?
Choose the correct sequence of possible (a) I > I- > I+
atomic no. of elements (b) I > I+ > I-
(a) 12, 18, 9, 11 (c) I+ > I- > I
(b) 11, 36, 9, 20 (d) I- > I > l+
(c) 20, 36, 11, 9
(d) 9, 18, 11, 20 57. The correct order of atomic radii in
group 13 elements is
50. Which of the following elements has the (1) B < Al < In < Ga < Tl
maximum electron affinity? (2) B < Al < Ga < In < Tl
(a) I (3) B < Ga < Al < In < Tl
(b) Br (4) B < Ga < Al < Tl < In
(c) Cl
58. For the second period elements the
correct increasing order of first ionisation
enthalpy is:
(1) Li < Be < B < C < N < O < F < Ne
(2) Li < B < Be < C < O < N < F < Ne
(3) Li < B < Be < C < N < O < F < Ne
(4) Li < Be < B < C < O < N < F < Ne
36.
30.
Ans: (a)
Ans: (d)
E.A=F>O>Al>Ca
The elements having half-filled and fully filled
orbitals in electronic configuration has more Electron affinity increases across period from left to
ionisation energy than the value observed in right due to decrease in size , more Zeffective
trends. causes more attraction of electrons incoming.
Here, in [Ne] 3s23p3, 'p' orbital is half-filled.
37.
Outermost electronic configuration 3s23p3. (b) ionic
31. 38.
Ans: (c) (a) Hydration enthalpy depends upon ionic
In iso-electronic species, if a positive charge is more potential (charge / size). As ionic potential
then they will have a very less ionic radius. Because increases hydration enthalpy increases.
here protons are more than electrons and protons
attract electrons to come close to the nucleus. But 39.
in anionic iso-electronic species, electrons are more (c) from the given options we find option (a) is
than protons. Protons which are in less number correct. The oxidising power of halogens follow the
can't attract all the electrons to come closer. So, order F2 > Cl2 > Br2 > I2 . Option (b) is incorrect
because it in not the correct order of electron gain
ionic radius increases in the case of anionic species,
enthalpy of halogens. The correct order is Cl2 > F2 >
if negative charge increases. Therefore the correct
Br2 > I2 . The low value of F2 than Cl2 is due to its
order is small size. Option (c) is incorrect. The correct order
S−2>Cl−>K+>Ca+2 of bond dissociation energies of halogens is Cl2 >
Br2 > F2 > I2 . Option (d) is correct. It is the correct
32. order of electronegativity values of halogens. Thus
Ans: (b) option (b) and (c) are incorrect.
The electron gain enthalpy (EA) of elements
increases along a period towards right. Also it 40.
decreases down the group. However the EA of Cl is (d) The ionisation potential decreases with increase
higher than that of F and EA of S is higher than that in atomic radii.
of O as F and O are very small in size. Thus the
correct order of EA is 41.
(d) N3– , F– , O2-
O<S<F<Cl
42. High ionization energies
(a) Metallic character decreases in a period and High electronegativities
increases in a group. Poor thermal conductors
Poor electrical conductors
43. Brittle solids—not malleable or
(d) It attains a stable configuration Little or no metallic luster
Gain electrons easily
44. Dull, not metallic-shiny, although they may
(c) The atomic radii decrease on moving from left be colorful
to right in a period, thus order of sizes for Cl, P and Lower melting points and boiling point than
Mg is Cl < P < Mg. Down the group size increases. the metals
Thus overall order is : Cl < P < Mg < Ca.
54. (a) Z=114 belong to Group 14, carbon family
45. Electronic configuration = [Rn] 5f14 6d10 7s2 7p2
(b) Properties of Li are similar to Mg because The
size by charge ratio is similar 55.(C) Halogens
49.(c) 20, 36, 11, 9 58 (2) ‘Be’ and ‘N’ have comparatively more stable
valence sub-shell than ‘B’ and ‘O’. Correct order of
50.(c)The reason for this is probably due to small first ionisation enthalpy is: Li < B < Be < C < O < N <
size of fluorine atom, electron density is high. As F < Ne
such, because of interelectronic repulsion, affinity
of F to accept electrons is less than that of Cl 59 (2)
51.(a)The element which present just below this Atomic Name IUPAC
element will have outermost electronic number official
configuration as 4s2 4p3 , so its full electronic name
configuration is 1s2, 2s2 2p6, 3s23p6 , 4s2, 3d10 ,4p 3 101 Unnilunium Mendelevium
and hence, its atomic number is 33. 103 Unniltrium Lawrencium
106 Unnilhexium Seaborgium
52.(a) The ionisation potential of N > O because N
111 Unununnium Roentgenium
posses stable half filled p–orbital
60 (1)
53.(d) following are characteristic properties of
nonmetals are as below: