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Classification of

The document contains a series of questions related to the classification of elements and periodicity in properties, covering topics such as atomic number, electronic configuration, ionization energy, and metallic character. It includes multiple-choice questions that test knowledge on the periodic table and the behavior of different groups of elements. The questions address various concepts in chemistry, including electronegativity, ionic sizes, and electron gain enthalpy.

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0% found this document useful (0 votes)
28 views10 pages

Classification of

The document contains a series of questions related to the classification of elements and periodicity in properties, covering topics such as atomic number, electronic configuration, ionization energy, and metallic character. It includes multiple-choice questions that test knowledge on the periodic table and the behavior of different groups of elements. The questions address various concepts in chemistry, including electronegativity, ionic sizes, and electron gain enthalpy.

Uploaded by

Jude Rao
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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CLASSIFICATION OF 8.

If the atomic number of an element is 33, it


will be placed in the periodic table in the
ELEMENTS AND (a) First group
(b) Third group
PERIODICITY IN (c) Fifth group
PROPERTIES (d) Seventh group.
9. In the periodic table from left to right in a
period, the atomic volume
1. Pauling’s electronegativity values for (a) Decreases
elements are useful in predicting (b) Increases
(a) Polarity of the molecules (c) Remains same
(b) Position in the E.M.F. series (d) First decrease then increases
(c) Coordination numbers 10. Which electronic configuration of an element
(d) Dipole moments. has abnormally high difference between second
2. The electronic configuration of four elements and third ionization energy?
are given below. Which elements does not (a) Is2, 2 s2, 2 p6, 3 s-1
belong to the same family as others? (b) Is2, 2 s2, 2 p6, 3 s13 p1
(a) [Xe]4f14 5d10 1s2 (c) Is2, 2 s2, 2 p6, 3 s23 p2
(b) [kr]4d10 5s2 (d) Is2, 2 s2, 2 p6, 3 s2
(c) [Ne]3s23p5 11. One of the characteristic properties of non
(d) [Ar]3d10 4s2 metals is that they
3. In the periodic table, with the increase in (a) Are reducing agents
atomic number, the metallic character of an (b) Form basic oxides
element (c) Form cations by electron gain
(a) Decreases in a period and increases in a (d) Are electronegative
group 12.The electronic configuration of an element is 1s2
(b) Increases in a period and decreases in a 2s22p6 3s2 3p3. What is the atomic number of the
group element , which is just below the above element in
(c) Increases both in a period and the group the periodic table ?
(d) Decreases in a period and the group. (a) 33
4. Elements of which of the following groups will (b) 34
form anions most readily? (c) 36
(a) Oxygen family (d) 49
(b) Nitrogen family 13. The element, with atomic number 118, will
(c) Halogens be
(d) Alkali metals (a) alkali
5. Which of the following sets has strongest (b) noble gas
tendency to form anions? (c) lanthanide
(a) Ga, In, Tl (d) transition element
(b) Na, Mg, Al 14. Which one of the following ions will be the
(c) N, O, F smallest in size?
(d) V, Cr, Mn (a) Na+
6. One would expect proton to have very large (b) Mg2+
(a) Charge (c) F2
(b) Ionization potential (d) O2+
(c) Hydration energy 15. Which of the following does not represent
(d) Radius. the correct order of the properties indicated
7. Na++ , Mg2+ , Al3+ and Si4+ are isoelectronic. The (a) Ni2+> Cr2+> Fe2+> Mn2+( size)
order of their ionic size is (b) Sc > Ti > Cr > Mn- (Density)
(a) Na+> Mg2+< Al3+< Si4+ (c) Mn2+ > Ni2+< Co2+<Fe2+unpaired electron)
(b) Na+< Mg2+> Al3+> Si4+ (d) Fe2+> Co2+> Ni2+> Cu2+( unpaired electron)
(c) Na+> Mg2+> Al3+> Si4+ 16. The first ionization potentials (eV) of Be and
(d) Na+< Mg2+> Al3+< Si4+ B respectively are
(a) 8.29, 9.32 (d) directly proportional to square of effective
(b) 9.32, 9.32 nuclear charge
(c) 8.29, 8.29 24. Which one of the following oxides is
(d) 9.32, 8.29 expected to exhibit paramagnetic behaviour?
17. Of the given electronic configurations for (a) CO2
the elements, which electronic configuration (b) SiO2
indicates that there will be abnormally high (c) SO2
difference in the second and third ionization (d) ClO2
energy for the element? 25. Which one of the following arrangements
(a) 1s22 s-22 p63 s2 represents the correct order of electron gain
(b) 1s22 s22 p63 s1 enthalpy (with negative sign) of the given
(c) 1s22 s22 p63 s33 p1 atomic species?
(d) 1s22 s22 p63 s23 p1 (a) S< O< Cl < F
18. Correct order of first IP among following (b) Cl < F< S< O
elements Be, B, C, N, Ois (c) F< Cl < O< S
(a) B< Be < C< O< N (d) O< S< F< Cl
(b) B< Be < C< N< O 26. Identify the correct order of the size of the
(c) Be < B< C< N< O following:
(d) Be < B< C< O< N (a) Ca2+< K+< Ar < Cl-< S2-
19. Which of the following order is wrong? (b) Ar < Ca2+< K+< Cl-< S2-
(a) NH3 < PH3 < AsH3 – Acidic (c) Ca2+< Ar < K+< Cl-< S2-
(b) Li < Be < B< C– First IP (d) Ca2+< K+< Ar < S2-< Cl-
(c) Al2O3 < MgO< Na2O< K2O– Basic 27. Which of the following electronic
(d) Li+< Na+< K+< Cs+– Ionic radius configuration an atom has the lowest ionisation
20. An atom has electronic configuration 1s22s2 enthalpy?
2p63s23 p63 d34 s2, you will place it in which (a) 1s22 s2sp3
group? (b) 1s22 s22 p53 s1
(a) Fifth (c) 1s22 s22 p6
(b) Fifteenth (d) 1s22 s22 p5
(c) Second 28. Which one of the following ionic species has
(d) Third the greatest proton affinity to form stable
21. Which of the following statements is true? compound?
−¿¿
(a) Silicon exhibits 4 coordination number in its (a) NH 2
compound (b) F-
(b) Bond energy of F2 is less than Cl2 (c) I-
(c) Mn(III) oxidation state is more stable than (d) HS-
Mn(II) in aqueous state 29. The stability of + 1 oxidation state increases
(d) Elements of 15th group shows only +3 and in the sequence:
+5 oxidation states (a) Tl < In < Ga < Al
22. Among K, Ca, Fe and Zn the element which (b) In < Tl < Ga < Al
can form more than one binary compound with (c) Ga < In < Al < Tl
chlorine is (d) Al < Ga < In < Tl
(a) Fe 30. Amongst the elements with following
(b) Zn electronic configurations, which one of them
(c) K may have the highest ionization energy?
(d) Ca (a) Ne [3s23p2 ]
23. Ionic radii are (b) Ar [3d104s24p3]
(a) inversely proportional to effective nuclear
(c) Ne [3s23p1]
charge
(d) Ne [3s23p2]
(b) inversely proportional to square of effective
nuclear charge 31. The correct order of the decreasing ionic
(c) directly proportional to effective nuclear radii among the following isoelectronic species
charge are:
(a) Ca2+ > K+ > S2-- > Cl-1
(b) Cl- > S2- > Ca2+ > K+ 38. The correct order of hydration energy of
(c) S2- > Cl- >K+ > Ca2+ alkali is
(d) K+ > Ca2+ > Cl- > S2- (a) Li+ > Na+ > K+ > Rb+
32. Which of the following represents the (b) Rb+ > K+ > Na+ > Li+
(c) Na+ > K+ > Li+ > Rb+
correct order of increasing electron gain
(d) K+ > Rb+ > Na+ > Li+
enthalpy with negative sign for the elements O,
S, Fand Cl? 39. Which one of the following
(a) CI< F< O< S arrangements does not give the correct
(b) O< S< F< CI picture of the trends indicated against it ?
(c) F< S< O< CI (i) F2 > Cl2 > Br2 > I2 : Oxidizing power
(d) S< O< CI< F (ii) F2 > Cl2 > Br2 > I2 : Electron gain
33. Among the elements Ca, Mg, Pand Cl, the enthalpy
order of increasing atomic radii is: (iii) F2 > Cl2 > Br2 > I2 : Bond dissociation
(a) Ca < Mg < P< Cl energy
(b) Mg < Ca < Cl < P (iv) F2 > Cl2 > Br2 > I2 : Electronegativity.
(c) Cl < P< Mg < Ca (a) (ii) and (iv)
(b) (i) and (iii)
(d) P< Cl < Ca < Mg
(c) (ii) and (iii)
34. What is the value of electron gain enthalpy
(d) (ii), (iii) and (iv)
of Na+ if IE1 of Na = 5.1 eV?
(a) –5.1 eV 40. Which of the following statement is
(b) –10.2 eV correct about ionization potential?
(c) +2.55 eV (a) It is independent of atomic radii
(d) +10.2 eV (b) It remains constant with change in
35. Identify the wrong statement in the atomic radii
following: (c) It increases with an increase in atomic
(a) Amongst isoelectronic species, smaller the radii
positive charge on the cation, smaller is the ionic (d) It decreases with an increase in atomic
radii
radius.
(b) Amongst isoelectronic species, greater the
41. The ionic radii of isoelectronic species
negative charge on the anion, larger is the ionic are found to be 171 pm, 136 pm & 140 pm
radius. respectively. The isoelectronic species are
(c) Atomic radius of the elements increases as _____
one moves down the first group of the periodic (a) N3– , O2– , F–
table. (b) F– , O2– , N3–
(d) Atomic radius of the elements decreases as (c) O2– , N3– , F–
one moves across from left to right in the 2nd (d) N3– , F– , O2-
period of the periodic table.
36. Which one of the following arrangements 42. In the periodic table, with the increase
represents the correct order of least negative to in atomic number, the metallic character of
an element
most negative electron gain enthalpy for C, Ca,
(a) decreases in a period and increases in a
Al, Fand O? group
(a) Ca < Al < C< O< F (b) increases in a period and decreases in a
(b) Al < Ca < O< C< F group
(c) Al < O< C< Ca < F (c) increases both in a period and the
(d) C< F< O< Al < Ca group
37. The atomic number of elements M, N, & (d) decreases in a period and the group.
P are x, x–1, x–3. If P is a halogen atom
then the type of bond between N & P is 43. The first 2nd and 3rd ionization
(a) Covalent enthalpies of gallium are 579 KJ mol –1 ,1979
(b) Ionic KJ mol–1 & 2962 KJ mol–1 even though the
(c) Coordinate iii I.P is highest Ga3+ is the most stable
(d) Metallic because
(a) The energy loss is maximum resulting (d) F
greater stability
(b) The size of Ga3+ is smallest 51. The electronic configuration of an
(c) Ga3+ is most reactive element is 1s2 2s2 2p6 3s2 3p3. the atomic
(d) It attains a stable configuration number of the element which is just below
the above element in the periodic table is?
44. Among the elements Ca, Mg, P and Cl, (a) 33
the order of increasing atomic radii is (b) 34
(a) P < Cl < Ca < Mg (c) 36
(b) Mg < Ca < Cl < P (d)49
(c) Cl < P < Mg < Ca
(d) Ca < Mg < P < Cl 52. The ionisation potential of N > O
because
45. Properties of Li are similar to Mg (a) Ionisation potential increases with
because decrease in size
(a) The size of Li & Mg are different (b) N posses stable half filled p–orbital
(b) The size by charge ratio is similar (c) The screening effect in N > O
(c) The charges are same (d) O is more electropositive than N
(d) Both are reactive
53. One of the characteristic properties of
46. One of the characteristic properties of nonmetals is that they
nonmetals is that they (a) are reducing agents
(a) are reducing agents (b) form basic oxides
(b) form basic oxides (c) form cations by electron gain
(c) form cations by electron gain (d) are electronegative
(d) are electronegative.
54. The element Z = 114 has been
47. The correct decreasing order of first discovered recently. It will belong to which
ionization enthalpies of five elements of the of the following family/group and electronic
second period is configuration?
(a) Be > B > C > N > F (a) Carbon family, [Rn] 5f14 6d10 7s2 7p2
(b) N > F > C > B > Be (b) oxygen family, [Rn] 5f14 6d10 7s2 7p4
(c) F > N > C > Be > B (c) Nitrogen family, [Rn] 5f14 6d10 7s2 7p6
(d) N > F > B > C > Be (d) Halogen family, [Rn] 5f14 6d10 7s2 7p5

48. In the periodic table from left to right in 55. The element with atomic number 117
a period, the atomic volume has not been discovered yet. In which
(a) decreases family would you place this element if
(b) increases discovered ?
(c) remains same (a) Alkali metals
(d) first decrease then increases (b) Alkali earth metals
(c) Halogens
49. Four elements A, B, C & D. D is non (d) Noble gases
reactive gas. C is a highly reactive gas, B is
a solid & forms oxide, A is high reactive 56. Which one of the following is the correct
solid & used to prepare Lasagne’s solution. order of the size of iodine species?
Choose the correct sequence of possible (a) I > I- > I+
atomic no. of elements (b) I > I+ > I-
(a) 12, 18, 9, 11 (c) I+ > I- > I
(b) 11, 36, 9, 20 (d) I- > I > l+
(c) 20, 36, 11, 9
(d) 9, 18, 11, 20 57. The correct order of atomic radii in
group 13 elements is
50. Which of the following elements has the (1) B < Al < In < Ga < Tl
maximum electron affinity? (2) B < Al < Ga < In < Tl
(a) I (3) B < Ga < Al < In < Tl
(b) Br (4) B < Ga < Al < Tl < In
(c) Cl
58. For the second period elements the
correct increasing order of first ionisation
enthalpy is:
(1) Li < Be < B < C < N < O < F < Ne
(2) Li < B < Be < C < O < N < F < Ne
(3) Li < B < Be < C < N < O < F < Ne
(4) Li < Be < B < C < O < N < F < Ne

59. Identify the incorrect match.


Name IUPAC Official Name
(a) Unnilunium (i) Mendelevium
(b) Unniltrium (ii) Lawrencium
(c) Unnilhexium (iii) Seaborgium
(d) Unununnium (iv) Darmstadtium
(1) (c), (iii)
(2) (d), (iv)
(3) (a), (i)
(4) (b), (ii)

60. From the following pairs of ions which


one is not an iso-electronic pair?
(1) Fe2+ , Mn2+
(2) O2- , F-
(3) Na+ , Mg2+
(4) Mn2+ , Fe3+
Solutions : With increase in the atomic number, the
1.
nuclear charge increases but the number of
Ans: (a) shells in the atoms of all the elements in a given
Pauling's electronegativity values are useful in period remains the same. The attraction
determination of polarity of the bond in molecules. between the nucleus and the valence electrons
If electronegativity difference is zero, then the increases. This decreases the atomic radius.
molecule is non-polar otherwise it is polar.
xA−xB=0.028√ Δ E Thus, in a given period, the alkali metals have
xAandxB are electronegativities of the atoms largest atomic volume, on moving from left to
A and B respectively. While, right in a period, the atomic volume decreases
ΔE = actual bond energy −√ E A −A × E B−B and halogens have smallest atomic volume in a
2. given period. The atomic volume of noble gases
Ans: (c) [Ne]3s23p5 is comparatively larger as they have large van
3. der Waals radii due to completed valence shell,
Ans: (a) decreases in a period and increases in a
with all electrons paired which causes greater
group.
repulsion.
1. As the tendency to lose electrons increases,
the metallic character increases from top to
10.
bottom in a group. This enhances the Ans: (d) When the element having
electropositive and metallic properties. 1s2,2s22p6,3s2 configuration, loss two electrons,
2. From left to right, the metallic character then it acquire the electronic configuration of noble
decreases. This is due to the fact that the gas (Ne), so to remove third electron a large
ionization energy increases over time. This amount of energy is required and hence, its second
reduces the electropositive and metallic and third ionisation energy have large difference.
properties. 11.
Ans: (a)
4. Are electronegative
Ans: (c) 12.
As halogens have seven electrons (ns2np5) in the Ans: (a) The atomic number of the above element
valence shell, they have a strong tendency to is 2+2+6+2+3=15. The atomic number of the
acquire the nearest inert gas configuration by element below the given element is 15+18=33.
gaining an electron from the metallic atom and 13.
form halide ions easily. Ans: (b) Electronic configuration of element with
5. atomic number 118 will be [Rn]5f146d10 7s27p6 .
Ans: (c) N, O and F are highly electronegative non since its electronic configuration in the outer most
metals and will have the strongest tendency to form orbit (ns2np6) resemble with that of inert or noble
anions by gaining electrons from metal atoms. gases, therefore it will be noble gas element.
6. 14.
Ans: (c) Ans: (b)Na+,Mg2+,O2−andF− all are isoelectronic but
Hydration energy Mg2+ have 12 protons in his nucleus, so the
7. attraction force on last shell is maximum and hence
Ans: (c) it have smallest size.
Na+> Mg2+> Al3+> Si4+
8. 15.
Ans: (c) Ans: (B)
Element with Z = 33 ) The correct order of the density is Sc<Ti<Cr<Mn.
(1s2 2s2p6 3s2p6d104s2p3) lies in fifth (or 15th group) Hence, option B is correct. On moving from left to
9. right, the density increases as the atomic mass
increases and the atomic size decreases
Ans: (d) In the periodic table from left to right
in a period the atomic volume first decreases
16.
then increases. Ans: (d) First ionisation potential of Be is greater
than boron due to following configuration
4Be =1s2 , 2s2 2 2
5B = 1s , 2s 2p
1 2
n a0 1
Order of attraction of electron towards nucleus 2s rn= or rn 
Z z
>2p , so more amount of energy is required to when n = principal quantum number
remove the electron with 2s- orbital in comparison Z – effective nuclear change.
to 2p orbital.
17.
24.
Ans: (a)
Ans: (d)
Mg = 1s22s22p63s2
After removing of 2 electron, the magnesium
acquired noble gas configuration hence removing of
3rd electron will require large amount of energy
18.
Ans: (a)
Be – 1s22s2 , B – 1s22s22p1 ,. C – 1s2s22p2 ; N – 1 25.
s22s22p3 ; O – 1s22s22p4 . IP increases along the Ans: (b)
period . But IP of Be > B. Further IP of O<N because In chlorine and fluorine. Cl has high electron gain
atom with fully or partly filled are most stable and enthalpy because the small size of F and there is
hence have high ionisation energy. very high electronic repulsion among the electrons
19. of fluorine. This makes incoming of another
Ans: (b) This is because of inter – electronic electron not very favourable.
repulsions between lone pairs.
In sulphur and oxygen, sulphur has high electron
gain enthalpy than oxygen because of larger size
and lower electron density.
So, O<S<F<Cl
The Cl has a most negative electron gain enthalpy
20. and O has a least negative electron gain enthalpy.
Ans: (a) The outermost shell and one shell prior to By considering the negative sign, the more negative
it in d subshell, has total 5 electron so it will be value will be small and less negative value will be
placed in fifth group in transition element or 'd' large.
block of periodic table. Thus, the correct order will be Cl<F<S<O
21.
Ans: (b) The bond strength of F-F is high owing to 26.
the small size. .Therefore the halogen- Ans: (a)
halogen bond becomes weaker. Fluorine is an
A cation has always the lesser ionic size than a
exception due to its extremely small size. The F-F
metal atom due to loss of electrons and an
bond length is so short that the lone pairs of
anion has always the greater size than metal
electrons on the fluorine atoms repel each other
atom due to gain of electrons. So, the correct
and weakens the F-F bond.
order of size is as
The order of Bond energy is is, Cl2>Br2>F2>I2
Ca2+<K+<Ar<Cl−<S2−
22.
Ans: (a) A binary compound is that compound
27.
which is formed by two different elements. Metals
Ans: (b)
or elements which shows variable oxidation states
The alkali metals have a very high tendency to lose
can form more than one binary compound. In the
electron as their uni positive cation has the inert
given elements only Fe shows +2 and +3 oxidation
gas configuration.
states. So, it can form two binary compounds with
chlorine as FeCl2andFeCl3.
Thus, their IE value is very low. Among given
23.
options, 1s22s22p63s1 is a alkali metal
Ans: (a)
Ionic radii are inversely proportional to effective
28.
nuclear charge.
Ans: (a)
Ionic radii in the nth orbit is given as
Proton affinity decreases across a period, from left
to right, and down a group, from top to bottom. 33.
Thus, nitrogen family has the highest proton Ans: (c)
affinity, followed by oxygen family, followed by The atomic radii decreases on moving from left to
halogens. Also, the ionic species with the greatest right in a period, thus order of sizes
proton affinity forms the strongest base or the for Cl,P and Mg is Cl<P<Mg. Down the group size
weakest acid. Of all the acids that these ionic increases. Thus overall order is : Cl<P<Mg<Ca..
species will form (HI, H2S, NH3 and HF), NH3 is the
weakest acid. 34.
Ans: (a)
29. IE1 of Na=− Electron gain enthalpy of Na+ ion =
Ans: (d) − 5.1eV.
The stability of +1 oxidation state
among Al, Ga, In and Tl increases in the sequence. 35.
Al<Ga<In<Tl. Ans: (a)
This is due to inert pair effect due to which, on Among the isoelectronic species, smaller the
moving down the group, the stability positive charge on the cation, higher the ionic
of +3 oxidation state decreases while the stability radius because the effective nuclear charge
of +1 oxidation state increases. increases as the positive charge increases.

36.
30.
Ans: (a)
Ans: (d)
E.A=F>O>Al>Ca
The elements having half-filled and fully filled
orbitals in electronic configuration has more Electron affinity increases across period from left to
ionisation energy than the value observed in right due to decrease in size , more Zeffective
trends. causes more attraction of electrons incoming.
Here, in [Ne] 3s23p3, 'p' orbital is half-filled.
37.
Outermost electronic configuration 3s23p3. (b) ionic

31. 38.
Ans: (c) (a) Hydration enthalpy depends upon ionic
In iso-electronic species, if a positive charge is more potential (charge / size). As ionic potential
then they will have a very less ionic radius. Because increases hydration enthalpy increases.
here protons are more than electrons and protons
attract electrons to come close to the nucleus. But 39.
in anionic iso-electronic species, electrons are more (c) from the given options we find option (a) is
than protons. Protons which are in less number correct. The oxidising power of halogens follow the
can't attract all the electrons to come closer. So, order F2 > Cl2 > Br2 > I2 . Option (b) is incorrect
because it in not the correct order of electron gain
ionic radius increases in the case of anionic species,
enthalpy of halogens. The correct order is Cl2 > F2 >
if negative charge increases. Therefore the correct
Br2 > I2 . The low value of F2 than Cl2 is due to its
order is small size. Option (c) is incorrect. The correct order
S−2>Cl−>K+>Ca+2 of bond dissociation energies of halogens is Cl2 >
Br2 > F2 > I2 . Option (d) is correct. It is the correct
32. order of electronegativity values of halogens. Thus
Ans: (b) option (b) and (c) are incorrect.
The electron gain enthalpy (EA) of elements
increases along a period towards right. Also it 40.
decreases down the group. However the EA of Cl is (d) The ionisation potential decreases with increase
higher than that of F and EA of S is higher than that in atomic radii.
of O as F and O are very small in size. Thus the
correct order of EA is 41.
(d) N3– , F– , O2-
O<S<F<Cl
42.  High ionization energies
(a) Metallic character decreases in a period and  High electronegativities
increases in a group.  Poor thermal conductors
 Poor electrical conductors
43.  Brittle solids—not malleable or
(d) It attains a stable configuration  Little or no metallic luster
 Gain electrons easily
44.  Dull, not metallic-shiny, although they may
(c) The atomic radii decrease on moving from left be colorful
to right in a period, thus order of sizes for Cl, P and  Lower melting points and boiling point than
Mg is Cl < P < Mg. Down the group size increases. the metals
Thus overall order is : Cl < P < Mg < Ca.
54. (a) Z=114 belong to Group 14, carbon family
45. Electronic configuration = [Rn] 5f14 6d10 7s2 7p2
(b) Properties of Li are similar to Mg because The
size by charge ratio is similar 55.(C) Halogens

46. 56.(a) Anions are always larger as compared


(d) are electronegative. to the corresponding parent atom as the
effective nuclear force of attraction decreases
47.
(c)In general, as we move from left to right in a
per electron, while on losing an electron
period, the ionization enthalpy increases with (cation formation), size shrinks as effective
increasing atomic numbers. But the ionization nuclear charge increases per electron.
enthalpy of B is lower than that of Be. This is
because the electronic configuration of
(1s2 2s2 2p1) is less stable than that of Be (1s2 2s2 )
(1s2 2s2) which has completely filled orbitals. As a
result, the 2p-electron of B is not strongly attracted 57 (3)
by the nucleus as the 2s-electron of Be. Thus, the Elements Atmoic radii
increasing order of first ionization enthalpies of (pm)
elements is. F>N>C>Be>B B 85
Ga 135
48. (d) Atomic volume is the volume occupied by
Al 143
one gram of an element. Within a period from left to
right, atomic volume first decreases and then In 167
increases. Tl 170

49.(c) 20, 36, 11, 9 58 (2) ‘Be’ and ‘N’ have comparatively more stable
valence sub-shell than ‘B’ and ‘O’. Correct order of
50.(c)The reason for this is probably due to small first ionisation enthalpy is: Li < B < Be < C < O < N <
size of fluorine atom, electron density is high. As F < Ne
such, because of interelectronic repulsion, affinity
of F to accept electrons is less than that of Cl 59 (2)

51.(a)The element which present just below this Atomic Name IUPAC
element will have outermost electronic number official
configuration as 4s2 4p3 , so its full electronic name
configuration is 1s2, 2s2 2p6, 3s23p6 , 4s2, 3d10 ,4p 3 101 Unnilunium Mendelevium
and hence, its atomic number is 33. 103 Unniltrium Lawrencium
106 Unnilhexium Seaborgium
52.(a) The ionisation potential of N > O because N
111 Unununnium Roentgenium
posses stable half filled p–orbital
60 (1)
53.(d) following are characteristic properties of
nonmetals are as below:

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