®

PHYSICAL
CHEMISTRY
JEE (MAIN+ADVANCED)
ENTHUSIAST COURSE

EXERCISE
Thermochemistry
English Medium
 ALLEN
® Thermochemistry

EXERCISE # S-I
Miscellaneous
Q.1 Lime is made commercially by decomposition of limestone, CaCO3. What is the change in internal
energy (in kJ) when 1.00 mole of solid CaCO3(V = 34 ml) absorbs 180 kJ of heat and decomposes at
certain temperature against a pressure of 1.0 bar to give solid CaO.(Volume = 16 ml) and
CO2(g)(V = 20 L). [Give your answer as nearest integer] TC0023
Q.2 For the gaseous reaction:

3A + 2B ¾¾
® 4C ; DH = –300 Cal/mol
If 5 moles of A are mixed with 4 moles of B at 300K, the magnitude of work (in cal) involved
in reaction is. TC0025
Q.3. When the following reaction was carried out in a bomb calorimeter, DU is found to be

®
–742.7 kJ/mol of NH2CN(s) at 300 K.
3
NH2CN(s) + O (g) ¾® N2(g) + CO2(g) + H2O(l)
2 2
Calculate DH300K (in kJ/mole) for the reaction. (R = 8 J/mole-K). TC0093
Q.4. For the reaction : 2A (g) + 3B (g) ¾® 4C (g) + D (l) ; DH = –20 KJ/mole
Find the heat gained (in kJ) when 0.4 mole of A reacts with excess of B in a closed rigid container. The
temperature is constant at 300 K. [R=8.3 J/K mole]
TC0094
Q.5 Ethyl chloride (C2H5Cl), is prepared by reaction of ethylene with hydrogen chloride :
C2H4(g) + HCl(g) ¾® C2H5Cl(g) DH = – 72.3 kJ/mol
What is the value of DU (in kJ), if 70 g of ethylene and 73 g of HCl are allowed to react at 300 K ?
TC0004
Q.6 Determine the amount of heat (in kcal) lost to surroundings at constant volume when 0.5 mol of N2 &
1.5 mol of H2 reacted according to equation at 300 K.
N2(g) + 3H2(g) ® 2NH3(g) ; DrH300 = – 380 kcal/mol
(Given : R = 2 cal / mol-K) TC0003
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Q.7 The enthalpy change for the reaction of 50 ml of ethylene with 50.0 ml of H2 at 1.5 bar pressure is
DH = – 0.31 KJ. Find DU (in kJ) for this process ? TC0001
Enthalpy of formation and combustion
Q.8 Find standard enthalpy of formation of ammonia gas in kJ/mol -
Given : N2H4(g) + H2(g) ¾¾
® 2NH3 (g) ; D r H 0 = -40kJ / mol

DH °f [N 2 H 4 (g)] = -120kJ / mol

TC0095
Q.9 The enthalpy change for the reaction C3H8(g) + H2(g) ¾® C2H6(g) + CH4(g) at 25º C is
- 55.7 kJ/mol. Calculate the enthalpy of combustion of C2H6(g) (in kJ/mole). The enthalpy of
combustion of H2, C3H8 & CH4 are -285.7, – 2220 & -890.0 kJ/mol respectively.
TC0096

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Q.10 Calculate standard enthalpy of formation of carbon-di-sulphide (l) (in kJ/mole). Given the standard
enthalpy of combustion of carbon (s) , sulphur (s) & carbon-di-sulphide (l) are : - 393, - 293 and
- 1108 kJ mol -1 respectively.
TC0097
Q.11 At 300 K, the standard enthalpies of formation of C 6H5COOH(s), CO2 (g) & H2O (l) are
– 408, – 393 & –286 kJ mol –1 respectively . Calculate the heat of combustion (in kJ/mole) of
benzoic acid at : (i) constant pressure (ii) constant volume. TC0008
Q.12 When 2 moles of C2H6(g) are completely burnt, 3120 kJ of heat is liberated . Calculate the enthalpy of
formation (in kJ/mol) of C2H6(g) . Given DfH for CO2(g) & H2O (l) are - 395 & - 286 kJ respectively.
TC0006
Q.13 From the following data at 25°C, Calculate the standard enthalpy of formation of FeO(s) and of Fe2O3(s).
Reaction D r H o (kJ/mole)

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(1) Fe2O3(s) + 3C(graphite) ® 2Fe (s) + 3CO(g) 492
(2) FeO (s) + C(graphite) ® Fe(s) + CO(g) 155
(3) C(graphite) + O2(g) ® CO2(g) –393
(4) CO(g) +1/2 O2(g) ® CO2(g) –282 TC0007
Relationship between DH & DU
Q.14 Determine DH for the following reaction at 500K and constant pressure :
CO(g) + H2O (g) ® CO2 (g) + H2 (g)
use the following data :
Substance Cp(J/mol K) Df H(300K) (kJ/mol)
CO (g) 29 –110
H2O (g) 33 –241
CO2 (g) 37 –393
H2 (g) 29 0 TC0005
Q.15. 0.16 g of methane was subjected to combustion at 27º C in a bomb Calorimeter . The temperature of
Calorimeter system (including water) was found to rise by 0.5º C . Calculate the heat of combustion of
methane at [Heat capacity of carlorimeter & its contents = 17.7 kJ/mole] node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

(i) constant volume (ii) constant pressure. [Give your answer as nearest integer]
TC0098
Q.16. One gm sample of NH4NO3 (s) is decomposed in a bomb calorimeter (constant volume). The temperature
of the calorimeter system falls by 6K. If the heat capacity of system is 1.25 kJ/K, what is the molar enthalpy
of decomposition of NH4NO3(s) (in kJ/mole) at 300 K.
[R = 8.3 JK-1 mol-1]. NH4NO3(s) ® N2O(g) + 2H2O(l).
TC0099
Q.17 0.821 l sample of a mixture of CH4(g) & O2(g) measured at 27º C & 760 torr was allowed to react at
constant pressure in a calorimeter which together with its contents had a heat capacity of 1200 Cal/K.
The complete combustion of methane to CO 2 & H 2 O caused a temperature rise,
in the calorimeter, of 0.25 K. What was the mole percent of CH4 in the original mixture?
DHºcomb (CH4) = - 200 kcal mol-1 . TC0010
-1
The thermal capacity of Calorimeter system is 17.7 kJ K . (R = 8.313 mol K ) -1 -1

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Bond Enthalpy
Q.18 For the reaction : N2H4(g) ® N2H2 (g) + H2(g) ; DrH° = 109 kJ /mol
Calculate the bond enthalpy of N = N.
Given : B.E. (N – N ) = 163 kJ/mol, B.E. (N–H) = 391 kJ/mol, B.E. (H–H) = 436 kJ/mol
TC0100
Q.19 Using bond enthalpy data, calculate enthalpy of formation of gaseous isoprene .
5 C(s) + 4 H2(g) ¾® H2C = C — C = CH2(g)
| |
CH 3 H
Given : C–H = 98.8 kcal/mol ; H - H = 104 kcal/mol ; C–C = 83 kcal/mol ; C = C = 147 kcal/mol &
C(s) ® C(g) = 171 kcal/mol.
TC0101

®
Q.20 Compute the enthalpy of formation of liquid methyl alcohol in kJ mol-1, using the following data. Enthalpy
of vaporisation of liquid CH3OH = 38 kJ/ mol .
Enthalpy of formation of gaseous atoms from the elements in their standard states are
H ® 218 kJ / mol ; C® 715 kJ / mol ; O ® 249 kJ / mol.
Bond Enthalpies
C - H ® 415 kJ / mol ; C - O ® 356 kJ / mol ; O - H ® 463 kJ / mol TC0011
Q.21 The polymerisation of ethylene to linear polyethylene is represented by the reaction
n CH2 = CH2(g) ® (–CH2 -CH2)n (g)
where n has a large integral value . Given that the average enthalpies of bond dissociation for C=C &
C-C at 298 K are + 590 & + 331 kJ mol-1 respectively. Calculate the enthalpy of polymerisation
per mole of ethylene (in kJ) at 298 K . TC0013
Q.22 White phosphorus is a tetra-atomic solid P4 (s) at room temperature.
P

P P
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P
Find average (P –P) bond enthalpy in kJ/mol.
Given : DHsublimation of P4 (s) = 59 kJ/mol
DHatomisation of P4 (s) = 1265 kJ/mol TC0014
Q.23 Calculate the magnitude of resonance enthalpy (in kJ/mole) of CO2(g) from following data
º
DH combustion [C(graphite) ] = – 390 kJ/mol
º
DH atomisation [C(graphite) ] = 715 kJ/mol

DHºB.E.[O = O] = 500 kJ/mol

DHºB.E.[C = O] = 800 kJ/mol TC0017

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Q.24 Calculate enthalpy of combustion of propane [C3H8 (g)] in kJ/mol at 298 K.

Given : B.E. (O = O) = 498 kJ/mole ; B.E. (C = O) = 804 kJ/mole
B.E. (C–H) = 410 kJ/mole ; B.E. (O–H) = 464 kJ/mole
B.E. (C–C) = 345 kJ/mole ; Resonance energy of CO2 (g) = – 143 kJ/mole
DHvaporization (H2O, l) = 41 kJ/mole TC0015
Q.25 Use the following data to answer the questions below :

H2
Ni ; DH = –28.6 Kcal mol–1 ;

excess H2
Ni
; DH = –116.2 Kcal mol–1

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Calculate the resonance energy of anthracene, TC0016

Other types of Enthalpy of reaction

Q.26 Calculate the electron gain enthalpy of fluorine atom (in kJ/mole) using the following data .
(All the values are in kJ mol-1 at 25º C). DHdiss (F2) = 160, DfH (NaF(s)) = - 571, I.E. [Na(g)] = 494,
DHsub [Na(s)] = 101 , Lattice enthalpy of NaF(s) = 894.
TC0102
Q.27 The enthalpy of solution of anhydrous CuSO4 is –16 kcal/mol and that of CuSO4.5H2O is 3 kcal/mol
Calculate the enthalpy of hydration of CuSO4 (in kcal/mol)
TC0103
Q.28 If the enthalpy of formation of HCl (g) and Cl– (aq) are –90 kJ/mole and – 170 kJ/mol, find the enthalpy
of solution of hydrogen chloride gas (in kJ/mol). TC0021
Q.29 Calculate the enthalpy of ionisation of weak acid H2A(H2A®2H++A2–) in Kcal/ mol, if enthalpies of
neutralisation of HCl and H2A by a strong base are –14 Kcal/eq and –11 Kcal/eq respectively.
TC0104 node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

Q.30 Enthalpy of neutralization of H3PO3 acid is -106.68 kJ/mol using NaOH. If enthalpy of neutralization
of HCl by NaOH is –55.84 kJ/mol. Calculate DHionization of H3PO3 into its ions (in kJ/mol)
TC0105
Q.31 Two solutions initially at 25°C were mixed in an adiabatic constant pressure calorimeter. One contains
400 ml of 0.2 M weak monoprotic acid solution. The other contain 100 ml of 0.80 M NaOH. After
mixing temperature increased to 26.2 °C. How much heat is evolved in the neutralization of 1 mole of
acid (in kJ) ? Assume density of solution 1.0 g/cm3, and specific heat of solution 4.2 J/g-K. Neglect heat
capacity of the calorimeter. TC0106

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EXERCISE # S-II
Q.1 The enthalpy of formation of C2H5OH(l) is - 66 k Cal/mol . The enthalpy of combustion of
CH3-O-CH3 is - 348 k Cal/mol . Given that the enthalpies of formation of CO2(g) and H2O(l) are
- 94 k Cal/mol & - 68 kcal/mol respectively, calculate DH (in kcal/mole) for the isomerisation of
ethanol to methoxymethane. All data are at 25º C. TC0026
Q.2 Calculate the mass of mercury (in grams) which can be liberated from HgO at 27º C by the treatment
of excess HgO with 9 kJ of heat at (a) constant pressure, (b) constant volume
Given : DHfº (HgO, s) = - 90 kJ mol-1 & Molar mass of (Hg) = 200 g mol-1 . TC0027
Q.3 A stoichiometric mixture of ferric oxide & Al is used as solid rocket fuel . Calculate the fuel
value ((in kcal/gram) & fuel value (in kcal/cc) of the mix . Enthalpy of formation & densities
are :

®
DHfº (Al2O3) = - 399 k Cal/mole ; DHfº (Fe2O3) = - 199 kcal / mole,
density of Fe2O3 = 5.2 g/cc ; density of Al = 2.7 g/cc. TC0028
Q.4 Calculate the enthalpy change for the reaction (in kcal/mole) : XeF4 ¾® Xe+ + F- + F2 + F.
The average Xe-F bond enthalpy is 34 kcal/mol, first I.E. of Xe is 279 kcal/mol, electron affinity of
F is 85 kcal/mol & bond dissociation enthalpy of F2 is 38 kcal/mol. TC0029
Q.5 Calculate the bond enthalpy of the O–H bond in water (in kJ/mole) at 298K using the data/information
given below :-
(A) Df H0[H(g)] = 218 kJ/mol
(B) Df H0[O(g)] = 249.2 kJ/mol
(C) Df H0[H2O(g)] = –241.8 kJ/mol
The bond enthalpy of the O–H bond in water is defined as one-half of the enthalpy change for the
reaction H2O(g) ® 2H(g) + O(g).
Also, determine the DU of the O–H bond in water at 298K (in kJ/mole) . Assume ideal gas behaviour.
Given : (8.314 × 0.298 = 2.5) TC0091
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Q.6 (i) From the following data :

Enthalpy of formation of C2H6 = – 83 kJ/mol
Enthalpy of sublimation of graphite = 719 kJ/mol
Enthalpy of bond dissociation of H2 = 435 kJ/mol
C–H bond enthalpy = 414 kJ/mol
Calculate the bond enthalpy of C – C (in kJ/mole)
(ii) By using data of above question calculate bond enthalpy of CºN (in kJ/mole) if enthalpy of
formation of CH3CN = 87 kJ/mol and enthalpy of bond dissociation of nitrogen = 945 kJ/mol
TC0092

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Q.7 Calculate the enthalpy change (in kcal/mole) when infinitely dilute solution of CaCl2 and Na2CO3 are
mixed DfH° for Ca2+(aq), CO32– (aq) and CaCO3 (s) are – 129, – 161, – 288 kcal mol–1 respectively.
TC0030
Q.8 The enthalpy of formation of ethane(g), ethylene(g) and benzene(g) from the gaseous atoms are
–2840, –2275 and –5530 kJmol–1 respectively. Calculate the magnitude of resonance energy of
benzene (in kJ/mole) . The bond enthalpy of C–H bond is given as equal to + 410 kJ/mol.
TC0031
Q.9 Calculate the enthalpy of combustion of methyl alcohol (l) (in kJ/mole) at 298 K from the following
data
Bond C-H C-O O-H O=O C=O
Bond Enthalpy(kJ mol-1) 414 351.5 464.5 494 711

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Resonance energy of CO2 = - 143 kJ mol-1
Latent heat of vaporisation of methyl alcohol = 35.5 kJ mol-1.
Latent heat of vaporisation of water = 40.6 kJ mol-1. TC0032
Q.10 The bond enthalpies of C–C, C=C & CºC bonds are 348, 610 & 835 kJ/mol respectively at 298K
& 1 bar. What is of the enthalpy change of polymerisation at 298K & 1 bar per mole of 2-butyne
(in kJ/mole) ?
nCH3–C º C–CH3(g) ® (–CH2–CH=CH–CH2–)n (g)
[‘n’ is a large integral value] TC0033

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EXERCISE # O-I
Relationship of DH & DU
Q.1 For a reaction, 2X(s) + 2Y(s) ® 2C(l) + D(g)
The qp at 27°C is – 28 Kcal mol–1, the qV is ----------- Kcal mol–1
(A) – 27.4 (B) + 27.4 (C) – 28.6 (D) 28.6 TC0034
Q.2. On the basis of the following thermochemical data :
H2O(l) ® H+(aq) + OH–(aq) ; DH = 57.32 kJ

1
H2(g) + O2(g) ® H2O (l) ; DH = –286.20 kJ
2

The value of enthalpy of formation of OH– ion at 25°C is :- [AIEEE-2009]

®
(A) +228.88 kJ (B) –343.52 kJ (C) –22.88 kJ (D) –228.88 kJ
TC0107
Q.3 For which reaction will DH = DU ?
(A) H2(g) + Br2(g) ® 2 HBr(g) (B) C(s) + 2 H2O(g) ® 2H2(g) + CO2(g)
(C) PCl5(g) ® PCl3(g) + Cl2(g) (D) 2CO(g) + O2(g) ® 2 CO2(g)
TC0108
Q.4 A mixture of 2 moles of carbon monoxide and one mole of oxygen in a closed vessel is ignited to get carbon
dioxide. If D H is the enthalpy change and DU is the change in internal energy, then :-
(A) D H > D U (B) D H < D U (C) D H = D U (D) Not definite
TC0109
Q.5 What amount of heat energy (kJ) is released in the combustion of 12.0 g of C3H4 at 1atm constant pressure.
C3H4(g) + 4 O2(g) ® 3 CO2(g) + 2 H2O(l) ; DHo = –1939 kJ
(A) 696.3 (B) 1939 (C) 6463.3 (D) 581.7 TC0040
Q.6 NH3(g) + 3Cl2(g) ® NCl3(g) + 3HCl (g); DH1
N2(g) + 3H2(g) ® 2NH3(g); DH2
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H2(g) + Cl2(g) ® 2HCl (g) ; DH3

The enthalpy of formation of NCl3 (g) in the terms of DH1, DH2 and DH3 is
DH 2 3 DH 2 3
(A) DHf = – DH1 + - DH3 (B) DHf = DH1 + - DH3
2 2 2 2
DH 2
3
(C) DHf = DH1 – -
DH3 (D) DHf = DH1 + DH2 – DH3 TC0041
2 2
Q.7 Consider the reaction at 300 K
H2(g) + Cl2(g) ¾® 2HCl(g) DH = –185kJ/mol
Calculate DU if 3 mole of H2 completely react with 3 mole of Cl2 to form HCl.
(A) 0 (B) –185 kJ (C) 555 kJ (D) – 555 kJ
TC0035
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Q.8 Ethanol can undergoes decomposition to form two sets of products

; 45 kJ
C2H5OH (g) ¾®
; 63 kJ
if the molar ratio of C2H4 to CH3CHO is 8 : 1 in a set of product gases, then the enthalpy involved
in the decomposition of 1 mole of ethanol is
(A) 423 kJ (B) 47 kJ (C) 61 kJ (D) 549 kJ TC0050
Q.9 Given the correct order of initials T (true) or F (false) for following statements.
(i) For the reaction CaCO3 (Calcite) ® CaCO3 (aragonite) ; DH= – 1127.75 kJ/mol,
then Calcite form is more stable at standard conditions.

®
(ii) For the reaction,
(a) C(diamond) + 2H2 (g) ® CH4(g) ; DH1
(b) C(g) + 4H(g) ® CH4(g) ; DH2
then more heat is evolved in reaction (b)
(iii) DfH° (I2,g) = DsubH [I2, s] at 25°C
(iv) For the exothermic reaction 2Ag(s) + 1/2 O2(g) ® 2Ag2O(s) at 298 K. DH < DU
(A) FTTT (B) TTFT (C) TFTF (D) TTTT TC0047
Q.10 Use the given standard enthalpies of formation to determine the enthalpy of reaction of the following
reaction : TiCl4(g) + 2 H2O(g) ®TiO2(g) + 4 HCl(g)
o o
DH f TiCl4(g) = –763.2 kJ/mole DH f TiO2(g) = –944.7 kJ/mole
o o
DH f H2O(g) = –241.8 kJ/mole DH f HCl(g) = –92.3 kJ/mole
(A) – 278.1 kJ (B) + 369.2 kJ (C) + 67.1 kJ (D) – 67.1kJ
TC0110
Q.11. For which species DHformation ¹ 0
(A) H+(aq.) (B) Br2(g) (C) I2(s) (D) C(graphite)
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TC0111
Q.12. Which of the following equations represents a reaction that provides the enthalpy of formation of
CH3Cl(g) ?
(A) C(s) + HCl(g) + H2(g) ® CH3Cl(g) (B) C(s) + 3/2 H2(g) + 1/2 Cl2(g) ® CH3Cl(g)
(C) C(s) + 3 H(g) + Cl(g) ® CH3Cl(g) (D) CH4(g) + Cl2(g) ® CH3Cl(g) + HCl(g)
TC0112
Q.13 The heats of formation of CO2(g) and H2O(l) are –394 kJ/mole and –285.8 kJ/mole respectively Using
the data for the following combustion reaction, calculate the heat of formation of C2H2(g).
2 C2H2(g) + 5 O2(g) ® 4 CO2(g) + 2 H2O(l) ; DHo = – 2601 kJ
(A) – 238.6 kJ/mole (B) 253.2 kJ/mole (C) 238.7 kJ/mole (D) 226.7 kJ/mole
TC0113

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Q.14 The heats of formation of CO2(g) and H2O(l) are –394 kJ/mole and –285.8 kJ/mole respectively &
DHºCombustion [C3H8(g)] = –2221.6 kJ. Then the heat of formation of C3H8(g) is -
(A) 212.2 kJ/mole (B) – 143.3 kJ/mole (C) 185.4 kJ/mole (D) – 103.6 kJ/mole
TC0114
Enthalpy of formation and combustion
Q15. The enthalpies of combustion of carbon and carbon monoxide are –393.5 and –283 kJ mol–1 respectively.
The enthalpy of formation of carbon monoxide per mole :- [AIEEE-2004]
(A) 110.5 kJ (B) 676.5 kJ (C) –676.5 kJ (D) –110.5 kJ
TC0115
Q.16 Study the following thermochemical equations :
A ® B ; DH = + 100 kcal
B ® C ; DH = – 80 kcal
The correct order of enthalpies of formation of A, B and C is -

®
(A) A < B < C (B) A < C < B (C) C < A < B (D) B < C < A
TC0036
Q.17 N2(g) + 2O2(g) ® 2NO2 DH = + x kJ
2NO(g) + O2(g) ® 2NO2(g) DH = + y kJ
The enthalpy of formation of NO is
1 1
(A) (2x – 2y) kJ/mol (B) (x – y) kJ/mol (C) (y – x) kJ/mol (D) (x –y) kJ/mol
2 2
TC0037
Bond enthalpy
Q.18 The enthalpy change for the following reaction is 513 kJ. Calculate the average Cl – F bond energy.
ClF3(g) ® Cl(g) + 3 F(g)
(A) 1542 kJ/mole (B) 88 kJ/mole (C) 171 kJ/mole (D) 514 kJ/mole
TC0116
Q.19 If enthalpy change for hydrogenation of ethylene is –132 kJ/mole and enthalpy of formation
1,3-butadiene (g) and butane (g) are 115 kJ and –140 kJ/mole respectively then calculate resonance
energy of 1,3-budadiene (in kJ).
(A) 9 (B) 18 (C) 4 (D) 10 TC0046
Q.20 The bond dissociation energy of gaseous H2, Cl2 and HCl are 104, 58 and 103 kcal mol –1
respectively. The enthalpy of formation for HCl gas will be :-
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(A) –44.0 kcal/mol (B) –22.0 kcal/mol (C) 22.0 kcal/mol (D) 44.0 kcal/mol
TC0042
Q.21 The reaction CH4(g) + Cl2(g) ¾® CH3Cl(g) + HCl(g) has DH = –25 kcal.
Bond
Bond Enthalpy
kCal
eC—Cl 84
eH—Cl 103
eC—H x
eCl—Cl y
x:y=9:5

From the given data, what is the bond enthalpy of Cl—Cl bond
(A) 70 kcal/mol (B) 80 kcal/mol (C) 67.75 kcal/mol (D) 57.86 kcal/mol
TC0043
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Q.22. The standard enthalphy of formation of NH3 is –46.0 kJ mol–1. If the enthalpy of formation of H2
from its atoms is –436 kJ mol–1 and that of N2 is –712kJ mol–1, the average bond enthalpy of
N–H bond in NH3 is :-
(A) –1102 kJ mol–1 (B) –964 kJ mol–1 (C) + 352 kJ mol–1 (D) +1056 kJ mol–1
TC0117
Q.23 If x1, x2 and x3 are enthalpies of H–H, O=O and O–H bonds respectively, and x4 is the enthalpy of
vaporisation of water, estimate the standard enthalpy of combustion of hydrogen
x2 x2 x2 x2
(A) x1+ –2x3+x4 (B) x1+ –2x3–x4 (C) x1+ –x3+x4 (D) 2x3–x1– –x4
2 2 2 2
TC0044
Q.24. If the bond dissociation energies of XY, X2 and Y2 (all gaseous diatomic molecules) are in the ratio of

®
1 : 1 : 0.5 and DfH for the formation of XY is –200 kJ mol–1. The bond dissociation energy of X2 will be

(A) 200 kJ mol–1 (B) 100 kJ mol–1 (C) 800 kJ mol–1 (D) 300 kJ mol–1
TC0118
Q.25 If bond enthalpy of C–C and C = C are 348 kJ /mole and 615 kJ/mole respectively then calculate enthalpy
change (in kJ/mole) which occurs during the isomerisation of cyclopropane (g) into propene(g)
(A) –267 (B) 81 (C) –81 (D) 267 TC0045
Q.26 The enthalpy changes for the following processes are listed below :
Cl2(g) = 2Cl(g), 242.3 kJ mol–1
I2(g) = 2I(g), 151.0 kJ mol–1
ICl(g) = I(g) + Cl(g), 211.3 kJ mol–1
I2(s) = I2(g), 62.76 kJ mol–1
Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard enthalpy of formation
for ICl(g) is :-
(A) –16.8 kJ mol–1 (B) +16.8 kJ mol–1 (C) +244.8 kJ mol–1 (D) –14.6 kJ mol–1
node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65
TC0119
Q.27 DH 0f of water is – 285.8 kJ mol–1. If enthalpy of neutralisation of monoacid strong base and mono basic
strong acid is –57.3 kJ mol–1, DH 0f of OH– ion will be
(A) – 228.5 kJ mol–1 (B) 228.5 kJ mol–1 (C) 114.25 kJ mol–1 (D) –114.25 kJ mol–1
TC0049
Q.28 Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below:
1
Cl (g) ¾¾ ® Cl(g) ¾¾ ® Cl–(g) ¾¾ ® Cl–(aq)
2 2
1
The energy involved in the conversion of Cl2(g) to Cl–(aq)
2
(Using the data Ddiss HΘCl = 240 kJ mol–1, Deg HΘCl = –349 kJ mol–1, Dhyd HΘCl = –381 kJ mol–1) will be :-
2
-

(A) –610 kJ mol–1 (B) –850 kJ mol–1 (C) +120 kJ mol–1 (D) +152 kJ mol–1
TC0120
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Q.29 The lattice enthalpy of solid NaCl is 772 kJmol–1 and enthalpy of solution is 2 kJmol–1. If the hydration
enthalpy of Na+ & Cl– ions are in the ratio of 3:2.5, what is the enthalpy of hydration of chloride ion?
(A) –140 kJmol–1 (B) –350 kJmol–1 (C) –351.81 kJmol–1 (D) –420 kJ/mol
TC0121
Q.30 The enthalpy changes of the following reactions at 27°C are
1
Na(s) + Cl2 (g) ¾® NaCl (s) DrH = –411 kJ/mol
2
H2(g) + S (s) + 2O2 (g) ¾® H2SO4 (l) DrH = –811 kJ/mol
2Na(s) + S(s) + 2O2 (g) ¾® Na2SO4 (s) DrH = –1382 kJ/mol
1 1
H2(g) + Cl2(g) ¾® HCl (g) DrH = –92 kJ/mol;
2 2
from these data, the heat change of reaction at constant volume ( in kJ/mol) at 27°C for the process

®
2NaCl (s) + H2SO4 (l) ¾® Na2SO4 (s) + 2HCl (g) is (R = 8.3 J/K-mol)
(A) 67 (B) 62.02 (C) 71.98 (D) 64.51 TC0051
Q.31 Reactions involving gold have been of particular interest to a chemist . Consider the following reactions,
Au(OH)3 + 4 HCl ¾® HAuCl4 + 3 H2O , DH = - 28 kcal
Au(OH)3 + 4 HBr ¾®HAuBr4 + 3 H2O , DH = - 36.8 kcal
In an experiment there was an absorption of 0.44 kcal when one mole of HAuBr4 was mixed with
4 moles of HCl . What is the percentage conversion of HAuBr4 into HAuCl4 ?
(A) 0.5 % (B) 0.6 % (C) 5 % (D) 50 % TC0052
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EXERCISE # O-II
Single Correct :
Q.1 What is the ratio of the enthalpy yield on combustion of hydrogen atoms to steam to the yield on
combustion of an equal mass of hydrogen molecules to steam?
1
Given : H2(g) + O (g) ® H2O(g) ; DH = – 242 kJ
2 2
B.E. (H – H) = 436 kJ
(A) 0.80 : 1 (B) 1 : 0.80 (C) 1.80 : 1 (D) 2.80 : 1 TC0053
Q.2 For the allotropic change represented by the equation C (graphite) ¾® C (diamond), DH = 1.9 kJ.
If 6 g of diamond and 6 g of graphite are separately burnt to yield CO2, the heat liberated in first case is
(A) less than in the second case by 1.9 kJ (B) more than in the second case by 11.4 kJ

®
(C) more than in the second case by 0.95 kJ (D) less than in the second case by 11.4 kJ
TC0054
Q.3 (i) Cis-2 - butene ® trans - 2 - butene, DH1
(ii) Cis - 2- butene ® 1 - butene, DH2
(iii) Enthalpy of combustion of 1-butene, DH = -649.8 kcal/mol
(iv) 9DH1 + 5 D H2 = 0
(v) Enthalpy of combustion of trans 2 - butene, DH = -647.0 kcal/mol.
The value of DH1 & DH2 in Kcal/mole are
(A) -1.0 , 1.8 (B) 1.8, –1.0 (C) –5, 9 (D) –2, 3.6 TC0055
Q.4 Hydrazine, a component of rocket fuel, undergoes combustion to yield N2 and H2O.
N2H4 (l) + O2 (g) ¾® N2 (g) + 2H2O (l)
What is the enthalpy change of combustion of N2H4 (kJ/mole)
Given Reaction DH/kJ
2NH3 (g) + 3N2O (g) ¾® 4N2 (g) + 3H2O (l) – 1011 kJ
N2O (g) + 3H2 (g) ¾® N2H4 (l) + H2O (l) – 317 kJ node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

4NH3 (g) + O2 (g) ¾® 2N2H4 (l) + 2H2O (l) – 286 kJ

1
H2 (g) + O2 (g) ¾® H2O (l) – 285 kJ
2
(A) – 620.5 (B) – 622.75 (C) 1167.5 (D) + 622.75 TC0056
Q.5 The enthalpy change for the reaction,
CH3CHO (g) ® CH4(g) + CO(g) at 300 K is – 17.0 kJ/mol
Calculate the temperature at which DrH for the reaction will be zero.
[Given : Cp,m (CH4,g ) = 38 J/K mol ; Cp,m (CO, g) = 31 J/K mol & Cp,m (CH3CHO,g) = 52 J/K mol]
(A) 1300°C (B) 1027°C
(C) 700°C (D) 754ºC TC0057

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More than one may correct
Q.6 Select the correct option -
(A) DHf(H(g)) is equal to DHatomisation of H2(g)
(B) DHBE(H–H) is equal to DHf of H(g)
(C) DHBE(H–H) is equal to DHatomisation of H2(g)
(D) DHcombustion [H2(g)] is equal to DHf [H2O(l)] at 300K TC0058
Q.7 Which of the following statement is (are) correct ?
(A) for any reaction DrHº = åDf H0 product – å DfH0reactant

(B) DH°f of CO2(g) is same as the DH°comb. of carbon graphite

(C) All exothermic gaseous reactions, å (B.E.)reactants > å (B.E.)products

®
(D) for a reaction N2(g) + O2(g) ¾® 2NO(g), the heat at constant pressure and the heat at constant volume
at a given temperature are same TC0059
Q.8 Which of the following do(es) not represent DH0 formation of the product.
2
(A) H2(g) + I2(s) ¾® 2HI(g) (B) O3(g) ¾® O2(g)
3
(C) NH +4 (g) + Cl–(g) ¾® NH4Cl(s) (D) P4(black) + 5O2 (g) ¾® P4O10(s)

(E) Reaction representing DHcombustion of C (graphite). TC0060

Q.9 From the following data at 25°C
Reaction DrH° kJ/mol
1 1
H (g) + O2(g) ¾® OH (g) 42
2 2 2
1
H2(g) + O2(g) ¾® H2O(g) –242
2
H2(g) ¾® 2H(g) 436
O2(g) ¾® 2O(g) 495
Which of the following statement(s) is/are correct:
node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

(A) DrH° for the reaction H2O (g) ¾® 2H(g) + O(g) is 925.5 kJ/mol
(B) DrH° for the reaction OH(g) ¾® H(g) + O(g) is 502 kJ/mol
(C) Enthalpy of formation of H(g) is –218 kJ/mol
(D) Enthalpy of formation of OH(g) is 42 kJ/mol TC0061
Match the column :
Q.10 Column-I Column-II
(A) C(graphite) + O2(g) ® CO2(g) (P) DH0formation
(B) C(graphite) ® C(gas) (Q) DH0combustion
(C) CH3COOH(aq) + OH– (aq) ® CH3COO–(aq) + H2O(l) (R) DH0atomization
(D) CH4(g) ® C(g) + 4H(g) (S) DH0neutralization
TC0062
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MATCH LIST :
Q.11 Match the enthalpy change (DH) mentioned in list-II for 16 gm O2 with the various reaction in
list-I.
List-I List-II (DH in kJ)
(P) 2C2H2 + 5O2(g) ¾® 4CO2(g) + 2H2O(l), DH– 2601 kJ (A) –285.8
(Q) H2(g) + 1/2O2(g) ¾® H2O(g), DH= – 285.8 kJ (B) –196.75
(R) 3FeO(s) + 1/2O2(g) ¾® Fe3O4(s), DH = –302.4 kJ (C) –260.1
(S) Cgraphite + O2(g) ¾® CO2(g), DH = –393.5 kJ (D) –302.4 TC0063
Code :
P Q R S

®
(A) 4 1 3 2
(B) 3 1 4 2
(C) 3 4 1 2
(D) 2 3 1 4
Paragraph for Q.12 & Q.13
Bond dissociation enthalpy of the first H–S bond in hydrogen sulphide is 376 kJ/mole. The enthalpies of
formation of H2S(g) and S(g) are –20.0 and 277.0 kJ/mole respectively. The enthalpy of formation of gaseous
hydrogen atom is 218 kJ/mole. Using above information, answer following questions :
Q.12 The enthalpy of formation of free radical HS is
(A) 138 kJ/mole (B) –138 kJ/mole (C) –10 kJ/mole (D) 357 kJ/mole
TC0064
Q.13 The bond dissociation enthalpy of the free radical HS is
(A) 138 kJ/mole (B) 276 kJ/mole (C) 357 kJ/mole (D) 376 kJ/mole
TC0064
Paragraph for Q.14 & Q.15 node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

Amount of heat evolved during complete combustion of liquid benzene can be calculated from the
following data.
(i) 18 gm of graphite on complete combustion evolve 591 kJ heat

(ii) DH f (H 2O, l) = – 286 kJ/mol

º

(iii) The heat of formation of liquid benzene is 50 kJ /mole

Q.14 Heat of formation of CO2(g) from following data is-
(A) –286 kJ/mole (B) –590 kJ/mole (C) –394 kJ/mole (D) –3268 kJ/mole
TC0065
Q.15 Find heat evolved from combustion of 78 gm benzene
(A) 3272 kJ (B) 6345 kJ (C) 4536 kJ (D) 5364 kJ TC0065
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Table Type Question :
Column-I Column-II Column-III

(Reactions) (Characteristics) (Characteristics)

(I) C(s) + O2(g) ® CO2(g) (i) DH = +ve (P) DH > DE
1
(II) SO3(g) ® SO2(g) + O (g) (ii) Dng = +ve (Q) | DH | > |DE|
2 2
(III) 2CO(g) + O2(g) ® 2CO2(g) (iii) Dng = –ve (R) DH < DE
1
(IV) C(s) + O (g) ® CO(g) (iv) DH = –ve (S) | DH | < | DE |
2 2
Q.16 Which of the following is only correct match ?
(A) I , i , P (B) II , ii , Q (C) III , iii , S (D) IV , iv , R

®
TC0066
Q.17 Which of the following is only incorrect match ?
(A) II , i , P (B) III , iv , R (C) IV , iii , S (D) II , ii , Q
TC0066
Q.18 Which of the following is only correct match ?
(A) I , ii , Q (B) II , iii , Q (C) III , iv , S (D) IV , ii , P
TC0066
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EXERCISE # J-MAIN
1. Consider the reaction : [AIEEE-2011]
4NO2(g) + O2(g) ® 2N2O5(g), DrH = –111kJ.
If N2O5(s) is formed instead of N2O5(g) in the above reaction, the DrH value will be :-
(given, DH of sublimation for N2O5 is 54 kJ mol–1)
(1) –165 kJ (2) +54 kJ (3) +219 kJ (4) –219 kJ TC0067
2. The value of enthalpy change (DH) for the reaction
C2H5OH(l) + 3O2(g) ® 2CO2(g) + 3H2O(l)
at 27°C is –1366.5 kJ mol–1. The value of internal energy change for the above reaction at this
temperature will be :- [AIEEE-2011]
(1) –1371.5 kJ (2) –1369.0 kJ (3) –1364.0 kJ (4) –1361.5 kJ TC0068

®
3. The enthalpy of neutralisation of NH4OH with HCl is –51.46 kJ mol and the enthalpy of neutralisation
–1

of NaOH with HCl is –55.90 kJ mol–1. The enthalpy of ionisation of NH4OH is:
[JEE-MAINS (online) 2012]
(1) +107.36 kJ mol –1 (2) –4.44 kJ mol–1 (3) –107.36 kJ mol (4) +4.44 kJ mol–1
–1

TC0069
4. Given [JEE-MAINS (online) 2013]
Reaction Energy Change (in kJ)
Li(s) ¾® Li(g) 161
Li(g) ¾® Li+(g) 520
1
F (g) ¾® F(g) 77
2 2
F(g) + e– ¾® F–(g) (Electron gain enthalpy)
Li+(g) + F–(g) ¾® LiF(s) –1047
1
Li(s) + F (g) ¾® Li F(s) –617
2 2
Based on data provided, the value of electron gain enthalpy of fluorine would be :
(1) –300 kJ mol–1 (2) –328 kJ mol–1 (3) –350 kJ mol–1 (4) –228 kJ mol–1 TC0070
node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65
5. Given : [JEE-MAINS (online) 2013]
(1) H2 (g) + 1 2 O2 (g) ® H2O (l); DHº298K = –285.9 kJ mol–1

(2) H2(g) + 1 2 O2 (g) ® H2O (g) ; DHº298K = – 241.8 kJ mol–1

The molar enthalpy of vapourisation of water will be :-
(1) 241. 8 kJ mol–1 (2) 527.7 kJ mol–1 (3) 44.1 kJ mol–1 (4) 22.0 kJ mol–1 TC0071
6. The standard enthalpy of formation (DfHº298) for methane, CH4 is– 74.9 kJ mol–1. In order to calculate
the average energy given out in the formation of a C–H bond from this it is necessary to know which
one of the following? [JEE-MAINS(online) 2014]
(1) the dissociation energy of the hydrogen molecule, H2.
(2) the dissociation energy of H2 and enthalpy of sublimation of carbon (graphite).
(3) the first four ionisation energies of carbon and electron affinity of hydrogen.
(4) the first four ionisation energies of carbon. TC0072

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7. For complete combustion of ethanol, C2H5OH(l) + 3O2(g) ® 2CO2(g) + 3H2O(l), the amount of heat
produced as measured in bomb calorimeter, is 1364.47 kJ mol–1 at 25ºC. Assuming ideality the Enthalpy
of combustion, DcH, for the reaction will be :- [JEE-MAINS(offline)2014]
(R = 8.314 J mol–1)
(1) –1460.50 kJ mol–1
(2) – 1350.50 kJ mol–1
(3) – 1366.95 kJ mol–1
(4) – 1361.95 kJ mol–1 TC0073
8. The heats of combustion of carbon and carbon monoxide are – 395.5 and – 285.5 kJ mol–1, respectively.
The heat of formation (in kJ) of carbon monoxide per mole is :-

®
[JEE-MAINS(offline)2016]
(1) – 110.5 (2) 110.5 (3) 676.5 (4) – 676.5 TC0074
9. The enthalpy change on freezing of 1 mol of water at 5°C to ice at –5°C is :
(Given DfusH = 6 kJ mol–1 at 0°C, CP(H2O, l) = 75.3 J mol–1 K–1, CP(H2O, s) = 36.8 J mol–1 K–1)
[JEE-MAINS(online)2017]
(1) 6.56 kJ mol–1 (2) 5.81 kJ mol–1 (3) 6.00 kJ mol–1 (4) 5.44 kJ mol–1 TC0075
10. Given [JEE-MAINS(offline)2017]
C(grahite) + O2(g) ® CO2(g) ; DrH° = –393.5 kJ mol–1

1
H 2 (g) + O 2 (g) ® H 2O(l); D H° = –285.8 kJ mol–1
2 r

CO2(g) + 2H2O(l) ® CH4(g) + 2O2(g) ; DrH° = +890.3 kJ mol–1

Based on the above thermochemical equations, the value of DrH° at 298 K for the reaction
C(grahite) + 2H2(g) ® CH4(g) will be :-
node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

(1) +74.8 kJ mol–1

(2) +144.0 kJ mol–1
(3) –74.8 kJ mol–1
(4) –144.0 kJ mol–1 TC0076
11. The combustion of benzene (l) gives CO 2(g) and H 2O(l). Given that heat of combustion
of benzene at constant volume is –3263.9 kJ mol–1 at 25° C ; heat of combustion (in kJ mol–1)
of benzene at constant pressure will be - [JEE-MAINS(offline)2018]
(R = 8.314 JK–1 mol–1 )
(1) –452.46 (2) 3260 (3) –3267.6 (4) 4152.6 TC0077

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12. Given [JEE-MAINS(online)2018]

(i) 2Fe2O3(s) ® 4Fe(s) + 3O2(g) ; DrG° = +1487.0 kJ mol–1
(ii) 2CO(g) + O2(g) ® 2CO2(g) ; DrG° = –514.4 kJ mol–1
Free energy change, DrG° for the reaction
2Fe2O3(s) + 6CO(g) ® 4Fe(s) + 6CO2(g)
will be :-
(1) –112.4 kJ mol–1 (2) –56.2 kJ mol–1
(3) 168.2 kJ mol–1 (4) 208.0 kJ mol–1 TC0078
13. Given : [JEE-MAINS(online)2019]
(i) C(graphite) + O2(g) ® CO2(g) ; DrH° = x kJ mol–1
1
(ii) C(graphite)+ O2(g) ® CO(g) ; DrH° = y kJ mol–1

®
2
1
(iii) CO(g) + O2(g) ® CO2(g) ; DrH° = z kJ mol–1
2
Based on the above thermochemical equations, find out which one of the following algebraic relationships
is correct ?
(1) z = x + y (2) x = y – z (3) x = y + z (4) y = 2z – x TC0079
14. The difference between DH and DU (DH–DU), when the combustion of one mole of heptane (1) is carried
out at a temperature T, is equal to: [JEE-MAINS-(ONLINE)-2019]
(1) 3RT (2) –3RT (3) –4RT (4) 4RT TC0080
15. Enthalpy of sublimation of iodine is 24 cal g–1 at 200°C. If specific heat of I2(s) and I2(vap) are 0.055
and 0.031 cal g–1K–1 respectively, then enthalpy of sublimation of iodine at 250°C in cal g–1 is :
[JEE-MAINS(online)2019]
(1) 2.85 (2) 11.4 (3) 5.7 (4) 22.8 TC0081
16. The standard heat of formation ( D f H 298
0
) of ethane in (kJ/mol), if the heat of combustion of ethane, hydrogen
and graphite are –1560, –393.5 and –286 kJ/mol, respectively is _______ node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

[JEE-MAINS(online)2020]
TC0082
17. If enthalpy of atomisation for Br2(1) is x kJ/mol and bond enthalpy for Br2 is y kJ/mol, the relation between
them : [JEE-MAINS(online)2020]
(1) is x = y (2) is x < y
(3) does not exist (4) is x > y TC0083
18. If the standard molar enthalpy change for combustion of graphite powder is -2.48 × 102 kJ mol-1, the amount
of heat generated on combustion of 1 g of graphite powder is _______ kJ. (Nearest integer)
[JEE-MAINS(online)2021]
TC0122

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19. At 298 K, the enthalpy of fusion of a solid (X) is 2.8 kJ mol-1 and the enthalpy of vaporisation of the liquid
(X) is 98.2 kJ mol-1. The enthalpy of sublimation of the substance (X) in kJ mol-1 is ________ .
(in nearest integer) [JEE-MAINS(online)2021]
TC0123
20. For water at 100°C and 1 bar,
DvapH - DvapU = ________ × 102 J mol–1. [JEE-MAINS(online)2021]
(Round off to the Nearest Integer)
[Use : R = 8.31 J mol–1 K–1]
[Assume volume of H2O(l) is much smaller than volume of H2O(g). Assume H2O(g) treated as an ideal gas]
TC0124

®
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EXERCISE # J-ADVANCE

Q.1 Using the data provided, calculate the multiple bond energy (kJ mol–1) of a C º C bond in C2H2. That
energy is (take the bond energy of a C–H bond as 350 kJ mol–1.) [JEE 2012]

2 C(s) + H2(g) ¾® C2H2(g) DH = 225 kJ mol–1

2 C(s) ¾® 2C(g) DH = 1410 kJ mol–1

H2(g) ¾® 2H(g) DH = 330 kJ mol–1

(A) 1165 (B) 837 (C) 865 (D) 815 TC0087

®
Q.2 The standard enthalpies of formation of CO2(g), H2O(l) and glucose(s) at 25ºC are –400 kJ/mol,
–300 kJ/mol & –1300 kJ/mol, respectively. The standard enthalpy of combustion per gram of glucose at
25ºC is - [JEE 2013]

(A) + 2900 kJ (B) – 2900 kJ (C) –16.11 kJ (D) + 16.11 kJ TC0088

Paragraph For Questions 3 and 4

When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant
pressure, a temperature increase of 5.7 ºC was measured for the beaker and its contents.
(Expt-1). Because the enthalpy of neutralisation of a strong acid with a strong base is a constant
(–57.0 kJmol–1), this experiment could be used to measure the calorimeter constant. In a second experiment
(Expt-2), 100 mL of 2.0 M acetic acid (K a = 2.0 × 10 –5 ) was mixed with 100 mL of
1.0M NaOH (under identical conditions to (Expt-1)) where a temperature rise of 5.6 ºC was measured.

(Consider heat capacity of all solutions as 4.2 Jg–1K–1 and density of all solutions as 1.0 g mL–1)
[JEE 2015]
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Q.3 Enthalpy of dissociation (in kJ mol–1) of acetic acid obtained from the Expt-2 is

(A) 1.0 (B) 10.0 (C) 24.5 (D) 51.4 TC0089

Q.4 The pH of the solution after Expt-2

(A) 2.8 (B) 4.7 (C) 5.0 (D) 7.0 TC0089

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Q.5 Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is equal
to the standard enthalpy of formation. [JEE 2019]

3
(A) O 2 (g) ® O3 (g)
2

1
(B) S8 (s) + O 2 (g) ® SO 2 (g)
8

(C) 2H2(g) + O2(g) ® 2H2O(l)

(D) 2C(g) + 3H2(g) ® C2H6(g) TC0090

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®

ANSWER KEY
EXERCISE # S-I

Q.1 178.00 kJ Q.2 1000.00 cal

Q.3 –741.50 kJ/mole Q.4 –3.50 kJ

Q.5 – 139.60 Q.6 189.40 kcal

Q.7 –0.30 kJ Q.8 –80.00

Q.9 –1560.00 Q.10 129.00 kJ

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Q.11 –3201, – 3199.75 kJ/mole Q.12 - 88.00 kJ mol–1

Q.13 –266.00 kJ/mol & –825 kJ/mole Q.14 –41.20 kJ

Q.15 (i) –885 kJ/mol (ii) – 890 kJ/mole Q.16 (602.49 kJ/mole)

Q.17 4.50 % Q.18 400.00 kJ/mole

Q.19 20.60 kcal/mole Q.20 – 266 kJ/mole

Q.21 –72 kJ/mole Q.22 201.00 kJ

Q.23 5.00 kJ/mole Q.24 –2669.00 kJ/mole

Q.25 –84.00 kJ/mole Q.26 –352.00 kJ/mole

Q.27 –19.00 kJ/mole Q.28 –80.00 kJ/mole

Q.29 6.00 kJ/mole Q.30 5.00 kJ/mole node06\B0BC-BD\Kota\JEE(Advanced)\Enthuse\Chem\Module\4-TD-01-TC-TD-02 & I.Eq.-(PC)\Eng\2-Thermochemistry\02_Ex.p65

Q.31 31.50 kJ/mole

EXERCISE # S-II

Q.1 22 kcal mol-1

Q.2 (a) 20 g (b) 20.28 g

Q.3 0.93 or 0.94 kcal g-1, 3.94 kcal cm-3

Q.4 292 kcal/mol

Q.5 E(O–H) = 463.5 kJ/mol DU = 461 kJ/mol

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Q.6 (i) 342 kJ/mol–1 ; (ii) 892 kJ/mol–1

Q.7 2 kcal

Q.8 25 kJ/mol

Q.9 – 669.7 kJ mol-1

Q.10 –123 kJ/mol

EXERCISE # O-I

Que. 1 2 3 4 5 6 7 8 9 10

®
Ans. C D A B D B D B A D
Que. 11 12 13 14 15 16 17 18 19 20
Ans. B B D D D B D C A B
Que. 21 22 23 24 25 26 27 28 29 30
Ans. D C B C B B A A B B
Que. 31
Ans. C

EXERCISE # O-II

Que. 1 2 3 4 5 6 7 8 9
Ans. D C A A B C,D A,B,D A,B,C,D A,D
Que. 10 11 12 13 14 15 16
Ans. A-P,Q B-P,R C-S D-R B A C C A B
Que. 17 18
Ans. C D
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EXERCISE # J-MAIN

Que. 1 2 3 4 5 6 7 8 9 10
Ans. 4 3 4 2 3 2 3 1 1 3
Que. 11 12 13 14 15 16 17 18 19 20
Ans. 3 2 3 3 4 -192.50 4 21 101 31

EXERCISE # J-ADVANCED

Que. 1 2 3 4 5
Ans. D C A B A,B

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