THERMOCHEMISTRY (Physical Chemistry)

EXERCISE: I
DPP-01
(Enthalpy Change)

1. The enthalpy change in a reaction does not depend upon

(A) the state of reactants and products.
(B) the nature of the reactants and products.
(C) different intermediate steps in the reaction.
(D) initial and final enthalpy of the system.

2. The word standard in molar enthalpy change implies

(A) temperature 298 K and pressure 1 atm.
(B) any temperature and pressure 1 atm.
(C) any temperature and pressure 1 bar.
(D) any temperature and pressure.

3. Which of the following statement is correct regarding enthalpy of reaction -

(A) It does not depend on physical state of reactant or products
(B) It always increases with increase in temperature
(C) It is equal to ratio of activation energy of forward reaction to activation energy of backward
reaction.
(D) It does not depend on presence of catalyst

4. Which is not the standard state (or reference state) of an element

(A) H2 O(l) (B) I2 (s) (C) Hg(l) (D) D2 (g)

5. Which of the following equations represents a reaction that provides the heat of formation of
CH3Cl?
(A) C(graphite) + HCl(g) + H2(g) → CH3Cl(g)
(B) C(graphite) + 3/2 H2(g) + → Cl2(g) → CH3Cl(g)
(C) C(graphite) + 3H(g) + Cl(g) → CH3Cl(g)
(D) CH4(g) + Cl2(g) → CH3Cl(g) + HCl(g)

1
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

6. Which reaction represents enthalpy of formation of product

(A)4 Al(s) + 3O2 (g) → 2Al2 O3 (s)
(B)H2 (g) + Br2 (g) → 2HBr(g)
(C)P4 (white) + 5O2 (g) → P4 O10 (s)
(D) S8 (rhombic) + 8O2 (g) → 8 SO2 (g)

7. Use the given standard enthalpies of formation to determine the heat of reaction of the following
reaction:
TiCl4(g) + 2 H2O(g) → TiO2(g) + 4 HCl(g)
H°f TiCl4(g) = –763.2 kJ/mole H°f TiO2(g) = –944.7 kJ/mole
H°f H2O(g) = –241.8 kJ/mole H°f HCl(g) = –92.3 kJ/mole
(A) –278.1 kJ (B) +369.2 kJ (C) +67.1 kJ (D) –67.1 kJ

8. Using the following information calculate the heat of formation of CH4.

CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) ; rH° = – 890.4 kJ
H°f CO2(g) = – 393.5 kJ/mole H°f H2O(l) = – 285.9 kJ/mole
(A) – 98.6 kJ (B) – 65.5 kJ (C) – 74.9 kJ (D) – 43.5 kJ

9. The standard enthalpy of formation of ammonia gas is -


Given : N2H4(g) + H2(g) ⎯→ 2NH3 (g) ; H r = – 40kJ /mol

Hf [N2H4(g)] = – 120kJ /mol

(A) –60 kJ (B) –180 kJ (C) 40 kJ (D) –80 kJ

10. Determine f Ho (NO, g) at 25°C. Using the following information

f Ho (CO2, g) = –393.5 KJ/mol

2NO(g) + O2 (g) → 2NO2 (g);  r Ho = –114.0 KJ / mol

2CO(g) + O2 (g) → 2CO2 (g); f Ho = –566.0 KJ / mol

4CO(g) + 2NO2 → C +  (g) ;  r Ho = −1198.4 kJ / mol

2
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

11. On the basis of the following thermochemical data :

H2O() → H+(aq) + OH–(aq) ; H = 57.32 kJ/mol
1
H2(g) + O2(g) → H2O () ; H = –286.20 kJ/mol
2

 Hf [H+(aq)] = 0
o

Find the value of enthalpy of formation of OH– (aq) ion at 25°C is :-

(A) +228.88 kJ/mol (B) –343.52 kJ/mol
(C) –22.88 kJ/mol (D) –228.88 kJ/mol

12. Enthalpy of formation of C2H6(g) at 300K is –20 kcal/mol then U for formation of C2H6(g) will
be (R = 2 cal/mol-K)
(A) –24.4 kcal/ mol (B) –21.2 kcal/ mol
(C) –18.8 kcal/ mol (D) –1180 kcal/ mol

13. From the following data at 25°C, Calculate the standard enthalpy of formation of FeO(s) and of
Fe2O3(s).
Reaction rH° (kJ/mole)
(A) Fe2O3(s) + 3C(graphite) → 2Fe (s) + 3CO(g) 492
(B) FeO (s) + C(graphite) → Fe(s) + CO(g) 155
(C) C(graphite) + O2(g) → CO2(g) –393
(D) CO(g) +1/2 O2(g) → CO2(g) –282

14. Given that

1
P4(s) + 3Cl2(g) → 2PCl3(l); H = –600 kJ/mol
2
PCl3(l) + Cl2(g) → PCl5(s); H = –200 kJ/mol

3
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-02
(Enthalpy of Combustion)
15. ΔHr of which reaction equals to the Hcomb. of reactant at room temperature
(A) 4Al(s) + 3O2 (g) ⟶ 2Al2 O3 (s)
(B) CH4 (g) + 2O2 (g) → CO2 (g) + 2H2 O(g)
3
(C) S (rhombic) + 2 O2 (g) ⟶ SO3 (g)
9 5 1
(D) CH3 NH2 (g) + 4 O2 (g) → CO2 (g) + 2 H2 O(ℓ) + 2 N2 (g)

16. Select incorrect option

(A) ΔHcomb. [diamond] < 0 (B) ΔHcomb. [CO2 ( g)] = 0.
(C) ΔHcomb. [graphite] = 0 (D) Hcomb. [O2 (g)] = 0

17. If the enthalpy of combustion of benzene(l), carbon (s) & hydrogen (g) are Q1, Q2 & Q3
respectively. What will be enthalpy of formation of Benzene –
(A) Q1 + 6Q2 + Q3 (B) 6Q2 + Q1 + 3Q3
(C) 6Q2 – 3Q3 – Q1 (D) 6Q2 + 3Q3 – Q1

18. The heats of formation of CO2(g) and H2O(l) are –394 kJ/mole and –285.8 kJ/mole respectively

& HCombustion [C3H8(g)] = –2221.6 kJ. Then calculate the heat of formation of C3H8(g).

(A) 212.2 kJ (B) – 143.3 kJ (C) 185.4 kJ (D) – 103.6 kJ

19. What amount of heat energy (kJ) is released in the combustion of 12.0 g of C3H4?
(Atomic weights: C = 12, H = 1, O = 16).
C3H4(g) + 4O2(g) → 3CO2(g) + 2H2O(l)
H° = –1939.1 kJ
(A) 725 (B) 504 (C) 783 (D) 581.73

20. Enthalpy of formation of P4O10(s) is -

(A) HC (P4,solid,red) (B) – HC (P4,solid,red)
(C) HC (P4,solid,white) (D) –HC (P4,solid,white)

21. Calculate heat released (in kJ) when 2 moles of gaseous methane undergo combustion in a rigid
vessel of volume 50 litres causing a change in pressure from 10 bar to 2 bar.
[Given : Hf (H2O ) = –280 kJ/mole, Hf (CO2) = –390 kJ/mole
Hf (CH4) = 70 kJ/mole]
4
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Calorimetry
22. When 0.2 g of butanol was burnt in a suitable apparatus, the heat evolved was sufficient to raise
the temperature of 200 g of water by 5K. The heat of combustion of butanol in kcal/mole will be-
(Specific heat of water : 1cal/gm-K)
(A) 0.37 (B) 37 (C) 307 *(D) 370

23. When 1.0 g of solid oxalic acid (H2C2O4) is burned in a bomb calorimeter whose heat capacity is
8.75 kJ/K, the temperature increases by 0.312 K. The enthalpy of combustion of oxalic acid at
27ºC is :

24. 0.16 g of methane was subjected to combustion at 27ºC in a bomb Calorimeter.

The temperature of Calorimeter system (including water) was found to rise by 0.5ºC at constant
volume. Calculate the heat of combustion of methane at
(i) constant volume (U) (ii) constant pressure (H)
The thermal capacity of Calorimeter system is 17.7 kJ K–1. (R = 8.313 mol–1 K–1)

5
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-03
(Bond Enthalpy)
25. Select the incorrect option
(A) ΔHr = ΣH (Product) − ΣH (Reactant)
(B) ΔHr = ∑ΔHf (Product) −∑ΔHf (Reactant)
(C) ΔHr = ∑ΔHcomb (Product) −∑ΔHcomb (Reactant)
(D) ΔHr = ∑ΔHBE (Gaseous Reactant) −∑ΔHBE (Gaseous Product)

26. Select correct option

(A) Enthalpy of formation is always negative
(B)Enthalpy of combustion is always negative
(C) Bond enthalpy can be positive & negative.
(D) Energy is released when bond is broken.

27. The enthalpy change at 298K for decomposition is given in following steps-
Step-1: H2O(g) → H(g) + OH(g)H = 498kJ/mol–1
Step-2: OH(g) → H(g) + O(g)H = 428kJ/mol–1
Then value of mean bond enthalpy of O–H bond will be -
(A) 498 kJ/mol (B) 463kJ/mol (C) 428 kJ/mol (D) 70 kJ/mol

28. The reaction CH4(g) + Cl2(g) ⎯→ CH3Cl(g) + HCl(g) has H = –25 kcal.
Bond Bond Enthalpy kcal
C–Cl 84
H–Cl 103
C–H X
Cl–Cl Y
x:y=9:5
From the given data, what is the bond enthalpy of Cl—Cl bond
(A) 70 kcal (B) 80 kcal (C) 67.75 kcal (D) 57.75 kcal

29. The bond dissociation energy of gaseous H2, Cl2 and HCl are 104, 58 and 103 kcal mol–1
respectively. The enthalpy of formation for HCl gas will be :-
(A) –44.0 kcal (B) –22.0 kcal (C) 22.0 kcal (D) 44.0 kcal

6
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

30. The enthalpy change for the following reaction is 513kJ. Calculate the average Cl – F bond energy.
ClF3(g) → Cl(g) + 3 F(g)
(A) 1542 kJ (B) 88 kJ (C) 171 kJ (D) 514 kJ

31. If x1, x2 and x3 are enthalpies of H–H, O=O and O–H bonds respectively, and x4 is the enthalpy of
vaporisation of water, estimate the standard enthalpy of combustion of H2(g)
x2 x2
(A) x1 + − 2x 3 + x4 (B) x1 + − 2x 3 − x4
2 2
x2 x2
(C) x1 + − x 3 + x4 (D) 2x 3 − x1 − − x4
2 2

32. If bond enthalpy of C–C and C = C are 348 kJ /mole and 615 kJ/mole respectively then calculate
enthalpy change (in kJ/mole) which occurs during the isomerisation of cyclopropane (g) into
propene (g)
(A) 19 (B) 81 (C) 1 (D) 20

33. For the reaction

N2H4(g) → N2H2(g) + H2(g) ;  Heaction = 109 kJ/ mol

0

N–N = 163 kJ/mol

N–H = 391 kJ/mol
H–H = 436 kJ/mol
Then the bond dissociation energy of N = N is
(A) 500 kJ/mol (B) 436 kJ/mol (C) 600 kJ/mol (D) 400 kJ/mol

34. Find the enthalpy of S–S bond from the following data.
(i) C2H5 – S – C2H5 (g) fH° = – 150 kJ/mol
(ii) C2H5 – S – S – C2H5 (g) fH° = – 200 kJ/mol
(iii) S (g) fH° = 225 kJ/mol

35. What will be C–H bond enthalpy if

CH4(g) + 2O2(g) → CO2(g) + 2H2O(l); H = –890 kJ
CO2(g) → C(graphite) + O2(g) ; H = 393 kJ
2H2O(l) → 2H2(g) + O2(g) ; H = 571 kJ
2H2(g) → 4H(g) ; H = 871 kJ
C(graphite) → C(g) ; H = 716 kJ
(A) 1663.39 kJ/mol (B) 415.25 kJ/mol (C) 917.3 kJ/mol (D) 215.5 kJ/mol
7
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

36. Boron exists in different allotropic forms. All allotropic form contains icosahedral units
(icosahedral is a regular shape with 12 corners & 20 faces) with boron atoms at all 12 corners
and all bonds are equivalent.

Calculate H (in kJ) per mole of boron atoms forming gaseous icosahedral
if HBE (B –B)= 200 kJ/mol.
(A) 1000 (B) 600 (C) 500 (D) 250

8
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-04
(Enthalpy of Atomisation)
37. The standard heat of formation of carbon atom in gaseous state in kJ/mol is -
Hº (atomisation of CO gas) = 1072 kJ/mol
Hº (formation of 'O' gas) = 247 kJ/mol
Hº (formation of CO gas) = –114 kJ/mol
(A) 400 (B) 311 (C) 600 (D) 711

38. What is heat of atomisation of P4O6(s)

Given heat of sublimation of P4O6 is x kJ/mol & P–O bond energy is y kJ/mol.
(A) x + 6y (B) x + y (C) x + 8y (D) x + 12y

39. Select the correct reaction representing ΔH atomisation

(A) H2 O(ℓ) → H2 (g) + 1/2O2 (g)

(B) H2 O(ℓ) → H + (aq) + OH − (aq)

(C) H2 O(ℓ) → 2H(g) + O(g)

(D) 2H2 O(ℓ) → 2H2 (g) + O2 (g)

40. Find relationship between ionisation enthalpy and ionisation energy

(A) ionisation enthalpy = – ionisation energy
(B) ionisation enthalpy = ionisation energy
5
(C) ionisation enthalpy = ionisation energy + RT
2
5
(D) ionisation enthalpy = lonisation energy − 2 RT

41. Find relationship between electron gain enthalpy and electron affinity.
(A) ΔHeg = − Election affinity (EA)
(B) ΔHeg = Electren affinity (EA)
5
(C) ΔHeg = – Electron affinity − 2 RT
5
(D) ΔHeg = Electon affinity + RT
2

9
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

42. Select the correct no. of statements

(A) Lattice enthalpy is always positive.
(B) Ionisation enthalpy of an atom in always positive
(C) Electron gain enthalpy of an atom is always negative
(D) Enthalpy of atomisation is always positive.

43. Calculate the enthalpy change for the reaction XeF4 ⎯→ Xe+ + F– + F2 + F.
The average Xe–F bond enthalpy is 34 kcal/mol, first ionisation enthalpy of Xe is 279 kcal/mol,
electron affinity of F is 85 kcal/mol & bond dissociation enthalpy of F2 is 38 kcal/mol.

44. Calculate the electron gain enthalpy of fluorine atom using the following data. Make Born –
Haber's cycle. All the values are in kJ mol–1 at 25º C . Hdiss (F2) = 160, fH (NaF(s)) = –571, I.E.
[Na(g)] = 494, Hvap [Na(s)] = 101, Lattice enthalpy of NaF(s) = 894.

45. The Born–Haber cycle for formation of rubidium chloride (RbCl) is given below
(the enthalpies are in k Cal mol–1)

Find the value of X.

46. Fe3 O4 a mixed oxide of iron consists of only Fe+2 &Fe+3 ions, with the ratio of Fe+2 : Fe+3 = 1: 2
in the mixed oxide. From the data given below,
Enthalpy of formation, ΔHf (Fe3 O4 ) = −1092 kJ/mol.
Enthalpy of sublimation, ΔHsub (Fe) = 390 kJ/mol.
B.D.E of O2 = 490 kJ/mol.
I. E1 of Fe = 760 kJ/mol.
I. E2 of Fe = 1560 kJ/mol.
I. E3 of Fe = 2960 kJ/mol.10
I. E1 of O2− = −844 kJ/mol.
I. E2 of O2− = 142 kJ/mol.
Find Lattice Enthalpy of Fe3 O4 in kJ/mol.

10
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-05
(Other types of Enthalpies of reaction)
47. Find enthalpy of hydration of Na2 SO4 (s).
Given: LE[Na2 SO4 ( s)] = 1250kJ/mol
LE(Na2 SO4 ⋅ 10H2 O(s)] = 1328 kJ/mol
(A) −78kJ/mol (B) 78 kJ/mol (C) 2578 kJ/mol (D)−2578 kJ/mol

48. 4g NH4NO3 were dissolved in 100 g water in bomb calorimeter with heat capacity of calorimeter
system 150JK–1. The temperature dropped by 1.5 K. Enthalpy of solution of NH4NO3 is :
(A) 450 kJ mol–1 (B) – 450 kJ mol–1 (C) 4.5 kJ mol–1 (D) –4.5 kJ mol–1

49. The lattice enthalpy of solid NaCl is 772 kJmol–1 and enthalpy of solution is 2 kJmol–1. If the
hydration enthalpy of Na+(g) & Cl–(g) ions are in the ratio of 3:2.5, what is the enthalpy of
hydration of chloride ion?
(A) –140 kJmol–1 (B) –350 kJmol–1 (C) –351.81 kJmol–1 (D) None

50. The enthalpy of solution of anhydrous CuSO4(s) is –16 kcal and that of CuSO4.5H2O is 3 kcal.
Calculate the enthalpy of hydration of CuSO4(s).

51. By using the following data draw an appropriate enthalpy cycle & calculate the enthalpy change
of hydration of (i) the chloride ion ; (ii) the iodide ion.
Comment on the difference in their values.
Enthalpy of solution of NaCl(s) = –2 kJ/mol.
Enthalpy of solution of NaI(s) = +2 kJ/mol.
enthalpy of hydration of Na+(g) = –390 kJ/mol.
lattice enthalpy of NaCl = 772 kJ/mol.
lattice enthalpy of NaI = 699 kJ/mol.

52. Enthalpy of dilution of 4M HCl to 2M HCl is –2.5 kJ/mol. Find enthalpy change when 500 ml of
HCl is diluted from 4M to 2M
(A) –2.5 kJ/mol (B) –5 kJ/mol (C) –10 kJ/mol (D) –1.25 kJ/mol

53. If the enthalpy of formation of HCl(g) and Cl–(aq) are –90 kJ/mole and –170 kJ/mol, find the
enthalpy of solution of hydrogen chloride gas.

11
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

54. 200 ml of 0.2M NaOH solution is prepared then it is diluted to 0.1M. Find the magnitude of total
change in enthalpy (in Joule)
Given : Hsolution (0.2M) = –15 kJ/mol
Hdilution (0.2M to 0.1M) = –3 kJ/mol
Fill your answer as sum of digits till you get the single digit answer.

55. Select the correct no. of statements.

(A) Enthalpy of solution of an Ionic compound is mostly positive
(B) Enthalpy of hydration of an ionic compound is mostly negative
(C) Enthalpy of dilution is always negative
(D) Enthalpy of solution is constant for a given substance in a given solvent.

56. When 1 mol Cl–(g) are added to 1 lit H2 O(ℓ), x kJ heat is evolved. Select correct option
(A) Heat evolved will be x kJ if 2 moles are dissolved in 2 lit H2 O(ℓ)
(B) Heat evolved all will be 2x kJ if 1 mol is dissolved in 2 lit. H2 O(ℓ),
(C) Heat evolved will be 2x kJ if 2 mols are dissolved in 1 lit H2 O(ℓ)
(D) Heal evolved will be 10x kJ if 10 moles are dissolved in 10 lit H2 O(ℓ)

12
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-06
(Resonance Enthalpy)
57. What is the enthalpy change for the isomerization reaction?

CH2=CH–CH2–CH=CH–CH=CH2(A) ⎯⎯⎯ → CH2=CH–CH=CH–CH=CH–CH3 (B)

2 NaNH


Magnitude of resonance energies of A and B are 50 and 70 kJ/mol, respectively.

Enthalpies of formation of A and B are –2275.2 and – 2839.2 kJ/mol, respectively.
(a) –584 kJ (b) –564 kJ
(c) –544 kJ (d) –20 kJ

58. Enthalpy change for Cyclohexa-1,3-diene to Cyclohexa-1,4-diene is 75 kJ/mol. Find magnitude of

resonance energy of Cyclohexa-1,3-diene.

59. In which of the following heat liberated is maximum

CO2 and ⎯→ Resonance hybrid

O = C = O and ⎯→ Resonating structure

(A) (g) + O2 (g) ⎯→ CO2 (g) + H2O (l)

(B) (g) + O2 (g) ⎯→ O = C = O (g) + H2O (l)

(C) (g) + O2 (g) ⎯→ CO2 (g) + H2O (l)

(D) (g) + O2 (g) ⎯→ O = C = O (g) + H2O (g)

60. Consider the following isomerization process.

CH2=CH–CH2–CH=CH2(g) → CH2=CH-CH=CH-CH3(g)
No of correct statements are
(A) The process is exothermic.
(B) Enthalpy change of reaction = Resonance enthalpy of product.
(C) The magnitude of enthalpy of combustion of product is less than that of reactant.
(D) The magnitude of enthalpy of hydrogenation of product is greater than that of reactant.

13
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

61. Calculate resonance enthalpy of CO2(g) from following data

H0combustion [C(graphite)] = – 390 kJ/mol

H0atomisation [C(graphite)] = 715 kJ/mol

H0B.E. [O = O] = 500 kJ/mol

H0B.E. [C = O] = 675 kJ/mol

62. If enthalpy change for hydrogenation of ethylene is –132 kJ/mole and enthalpy of formation 1,3-
butadiene (g) and butane (g) are 115 kJ and –140 kJ/mole respectively then calculate resonance
energy of 1,3-budadiene (in kJ).
(A) –9 kJ (B) –18 kJ (C) –4 kJ (D) –10 kJ

63. Use the following data to answer the questions below :

H = –28.6 Kcal mol–1 ;

H = –116.2 Kcal mol–1

Calculate the resonance energy of anthracene,

64. Find Resonance energy of Benzene in kJ/mol using following information

Hf[C6H6(g)] = 80 kJ/mol
Hatomization [graphite] = 700 kJ/mol
Bond H—H C—H C—C C=C
Bond enthalpy (kJ/mol) 440 400 350 600

14
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-07
(Enthalpy of Neutralization)
65. Magnitude of enthalpy of neutralization is minimum for :
(A) HCN + KOH (B) HCl + KOH (C) HCl + NH4OH (D)HCN+ NH4OH

66. 100 ml 0.2 M NaOH is mixed with 100 ml 0.4 M HCl solution. Determine energy released during
the reaction.
Given : H+(aq) + OH–(aq) ⎯⎯→ H2O(l) ; H = –57.5 kJ mol–1
(A) 1150 J (B) 1150 KJ (C) 2300 J (D) 2300 KJ

67. Enthalpy of neutralization of NaOH with H2SO4 is –57.3 kJ eq–1 and ethanoic acid –55.2 kJ eq–1.
which of the following is the best explanation of this difference -
(A) Ethanoic acid is a weak acid and thus requires less NaOH for neutralization
(B) Ethanoic acid is only partly ionised, neutralization is therefore incomplete
(C) Ethanoic acid is monobasic while H2SO4 is dibasic
(D) Some heat is used to ionize ethanoic acid completely

68. Enthalpy of neutralization of H2C2O4 acid is –109 kJ/mol using NaOH. If enthalpy of
neutralization of HCl by NaOH is –57 kJ/mol. Calculate Hionization of H2C2O4 into its ions
(A) 52 kJ/mol (B) 5 kJ/mol (C) 2.5 kJ/mol (D) 10 kJ/mol

69. The enthalpies of neutralization of NaOH & NH4OH by HCl are –13680 Cal and –12270 Cal
respectively. What would be the enthalpy change if one gram equivalent of NaOH is added to one
gram equivalent of NH4Cl in solution ? Assume that NH4OH and NaCl are quantitatively obtained.

70. H+ + OH– ⎯→ H2O ; Hº = –57 kJ/mol

Hionisation
0
[HCN] = 45 kJ/mol

If 200 ml, 1/10 M Ba(OH)2 solution is mixed with 500 ml , 1/10M HCN, then find out the heat
evolved.

71. When 100 ml 0.2 M KOH is mixed with 100 ml 0.2M HCl in a rigid adiabatic container,
temperature of solution increase by t1°C while when 300 ml 0.1M KOH is mixed with 300 ml 0.1M
HCl then increase in temperature is t2°C then which one is correct. (Assuming density as well as
specific heat of all final solutions are same)
(A) t1 = t2 (B) t1 > t2 (C) t1 < t2 (D) can’t compare

15
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

72. Two solutions initially at 25°C were mixed in an adiabatic constant pressure Calorimeter. One
contains 400 ml of 0.2 M weak monoprotic acid solution. The other contain 100 ml of 0.80 M
NaOH. After mixing temperature increased to 26.2 °C. How much heat is evolved in the
neutralization of 1 mole of acid?
Given: density of solution 1.0 g/cm3, and specific heat of solution 4.2 J/g-K.
Neglect heat capacity of the Calorimeter.

73. Which of the following enthalpy may be positive or negative both ?

(A) Enthalpy of atomisation (B) Enthalpy of combustion
(C) Enthalpy of solution (D) Enthalpy of hydration

74. Calculate the enthalpy change when infinitely dilute solution of CaCl2 and Na2CO3 are mixed fH°
for Ca2+(aq), CO32– (aq) and CaCO3 (s) are – 129, – 161, – 288 kcal mol–1 respectively.

16
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-08
(Free Energy Change)
75. Calcium oxide (CaO) prepared by reaction
CaCO3 (s) → CaO (s) + CO2 (g)
Calculate free energy change for the reaction (rGº) in kJ/mole at 300 K
Given: fHº (CaO,s) = – 635 kJ/mole ;
fHº (CO2,g) = –394 kJ/ mole
fHº (CaCO3,s) = – 1207 kJ/mole
Sº(CO2,g) = 214 J/K-mole;
Sº (CaO,s) = 40 J/K-mole
Sº(CaCO3,s) = 94 J/K-mole ; all given data at 300 K

76. Find G(J/mol) for the reaction at 300 kPa & 27ºC when all gases are in stoichiometric ratio of
moles.
N2O4(g) → 2NO2(g) [ln2 = 0.7]

Given :  G f (N2O4 ) = 100kJ / mol

 G f (NO2 ) = 50kJ / mol

R = 8 J / mol-K
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

77. Calculate rG(in kJ/mol) for reaction at 300 K

N2(g) + O2(g) ⎯→2NO(g)
the partial pressure of N2, O2 & NO are 10–4 bar, 10–2 bar and 10–5 bar respectively when mixed
together at 300 K.
Given : 2.303 RT = 5750 J/mol
 f H300
0
(NO, g) =90.5 kJ/mol;
0
S300 (N2, g) = 190 J/K – mol
0
S300 (NO, g) = 210 J/K–mol ;
0
S300 (O2, g) = 205 J/K–mol

(A) 150.5 kJ/mol

(B) 173.5 kJ/mol
(C) 196 kJ/mol

17
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

(D) None of these

78. PCl5(g) ⎯→PCl3(g) + Cl2(g)
G°f [PCl5(g)] = – 74 kcal /mol G°f [PCl3(g)] = – 60 kcal /mol
then calculate value of equilibrium constant for dissociation of PCl5(g) at 727ºC temperature ?
(ln2 = 0.7)
(A) 210 (B) 2–10 (C) 2–20 (D) 2+20

79. Calculate partial pressure of HCl (g) in bar at TK above the sample of NH 4Cl(s) as result of its
decomposition.
Given data:

 G f [NH4Cl (s)] = – 100 kJ mol–1

 G f [NH3 (g) ] = – 17 kJ mol–1

 G f [HCl (g) ] = – 97 kJ mol–1

Use: RT = 10000 J mole–1 & e0.7 = 2

80 From the given table answer the following questions:

CO(g) CO2(g) H2O(g) H2(g)

(fH°)298 (kcal/mole) –26 –94 –57 0

(fG°)298 (kcal/mole) –32 –94 –54 0

S°298 (Cal/K/mole) 47 51 ? 31

Reaction : H2O(g) + CO(g) ⎯→ H2(g) + CO2(g)


(i) Calculate rH298

(ii) Calculate rG 298

(iii) Calculate rS298

(iv) Calculate  r U298

(v) Calculate S298 [H2O(g)]

Temperature should be 300 K

18
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

81. Ethanol can undergo decomposition to form two sets of products

1
C2H4(g) + H2O (g) H° = 45.54 kJ
C2H5OH (g) ⎯→ 2
CH3CHO(g) + H2 (g) H° = 68.91 kJ

if the molar ratio of C2H4 to CH3CHO is 8 : 1 in a set of product gases, then the enthalpy involved
in the decomposition of 1 mole of ethanol is
(A) 65.98 kJ (B) 48.137 kJ (C) 48.46 kJ (D) 57.22 kJ

82. Reactions involving gold have been of particular interest to a chemist . Consider the following
reactions,
Au(OH)3 + 4 HCl ⎯→ HAuCl4 + 3 H2O, H = 28 kcal
Au(OH)3 + 4 HBr ⎯→ HAuBr4 + 3 H2O , H = –36.8 kcal
In an experiment there was an absorption of 0.44 kcal when one mole of HAuBr4 was mixed with
4 moles of HCl . What is the percentage conversion of HAuBr4 into HAuCl4 ?
(A) 0.5 % (B) 0.6 % (C) 5 % (D) 50 %

83. For the allotropic change represented by the equation C (graphite) → C (diamond), H= 1.9 kJ.
If 6 g of diamond and 6 g of graphite are separately burnt to yield CO2, the enthalpy liberated in
first case is
(A) less than in the second case by 1.9 kJ
(B) more than in the second case by 11.4 kJ
(C) more than in the second case by 0.95 kJ
(D) less than in the second case by 11.4 kJ

84. From the following data of H of the following reactions

C(s) + 1/2O2(g) ⎯→ CO(g) ; H = –110 kJ
and C(s) + H2O(g) ⎯→ CO(g) + H2(g) ; H = 130 kJ
The mole ratio of O2 & steam being passed over coke at 1273 K, so that temperature remains
constant is :
(A) 0.6 : 1 (B) 1.67 : 1 (C) 0.3 : 1 (D) 0.4 : 1

19
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

EXERCISE: II
Single Correct Questions
1. Hydrazine, a component of rocket fuel, undergoes combustion to yield N2 and H2O.
N2H4(l) + O2 (g) ⎯→ N2 (g) + 2H2O (l)
What is the enthalpy change of combustion of N2H4 (kJ/mole)
Given Reaction H/kJ
2NH3 (g) + 3N2O (g) ⎯→ 4N2(g) + 3H2O (l) – 1011 kJ
N2O (g) + 3H2 (g) ⎯→ N2H4 (l) + H2O (l) – 317 kJ
4NH3 (g) + O2 (g) ⎯→ 2N2H4 (l) + 2H2O (l) – 286 kJ
1
H2 (g) + O2 (g) ⎯→ H2O (l) – 285 kJ
2
(A) – 620.5 (B) – 622.75 (C) 1167.5 (D) + 622.75

2. 2NO2(g) → N2O4(g)
U°f [N2O4(g)] = 2kcal/ mole
and U°reaction = –16 kcal /mol then calculate H°formation of NO2 at 727ºC
(A) 9 kcal /mol (B) 4.5 kcal /mol (C) 8 kcal /mol (D) 10 kcal /mol

3. Molar enthalpy of combustion of C2H2(g) , Cgraphite and H2(g) are –1300, –394 and –286 kJ/mole
respectively than calculate Bond enthalpy of CC bond in kJ/mole.
Given : Hsub(Cgraphite) = 715 kJ/mole
HBE(H – H) = 436 kJ/mole
HBE(C – H) = 413 kJ/mole
(A) 415 (B) 610 (C) 1215 (D) 814

4. In a constant pressure calorimeter 224 ml of 0.1M KOH (aq.) solution is reacted with 50 ml of
0.1M H2SO4 (aq.) solution then increase in temperature of solution will be (assume heat capacity
of calorimeter is negligible) -
Given : Specific heat of solution = 1 cal/gm–K
Density of solution = 1 gm/ml
(A) 0.5 K (B) 1K (C) 2K (D) None

20
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Multiple Choice Questions

5. Which of the following do(es) not represent H formation of the product.
1 1
(A) H2(g) + H2O(l) ⎯→ H+(aq) + e– (B) O3(g) ⎯→ O2(g)
2 2
(C) NH+4 + Cl–(g) ⎯→ NH4Cl(s) (D) P4(black) + 5O2 (g) ⎯→ P4O10(s)

6. Pick out the incorrect statement(s) among the following.

(A) He(g) > 0 at 298 K (B) Sof H2O(g) > 0 at 298 K

(C) S° of H2 gas > 0 at 298 K (D) G of H2(g) > 0 at 298 K

7. Select the correct option -

(A) Hf(H(g)) is equal to Hatomisation of H2(g)
(B) HBE(H–H) is equal to Hf of H(g)
(C) HBE(H–H) is equal to Hatomisation of H2(g)
(D) Hcombustion [H2(g)] is equal to Hf [H2O(l)] at 300K

8. Select the correct option(s) :

(A) Entropies of ion in aqueous form may be positive or negative
(B) Entropies of H+ (aq) is assumed to be zero
(C) Entropies of ions in aqueous solution are relative to H+(aq)
(D) ∆Hf of ions in aqueous solution are relative to H+(aq)

9. For the change -

R → P ; H = –ve
If above reaction increases the disorder of system, then -
(A) Hf(P) > Hf (R) (B) HC(P) > HC (R)
(C) Gf(P) > Gf (R) (D) Sf(P) > Sf (R)

10. Select the correct statement for the neutralisation of strong acid & strong base in a solution :
(A) S = –ve (B) H = –ve (C) G = –ve (D) U = –ve

11. For MX2(s) lattice enthalpy is 800kJ mol–1 and enthalpy of solution is 50 kJ mol–1. If hydration
energies of M2+ and X– ions are in the ratio 3 : 1, then correct options are :

21
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

(A) Hydration energy of M2+ is 300 kJ/mol

(B) Hydration energy of M2+ is 450 kJ/mol
(C) Hydration energy of X– is 300 kJ/mol
(D) Hydration energy of X– is 150 kJ/mol

12. Which of the following mixture of strong acid & strong base will give same temperature change
for solution (Assume density & specific heat same for all solutions)-
(A) 50 ml 0.1 M HCl + 50 ml 0.1 M NaOH
(B) 30 ml 0.1 M HCl + 30 ml 0.1 M NaOH
(C) 25 ml 0.1 M H2SO4 + 50 ml 0.1 M KOH
(D) 50 ml 0.1 M H2SO4 + 50 ml 0.1 M NaOH

13. 100ml 0.5 NH2 SO4 (strong acid) is neutralised with 200ml0.2MNH4 OH in a constant pressure
Calorimeter which results in temperature rise of 1.4∘ C. If heat capacity of Calorimeter content is
1.5 kJ/ ∘ C. Which statement is/are correct
Given :
HCl + NaOH ⟶ NaCl + H2 O + 57 kJ
CH3 COOH + NH4 OH ⟶ CH3 COONH4 + H2 O + 48.1 kJ
(A) Enthalpy of neutralisation of HClv/sNH4 OH is −52.5 kJ/mol
(B) Enthalpy of dissociation (ionization) of NH4 OH is 4.5 kJ/mol
(C) Enthalpy of dissociation of CH3 COOH is 4.6 kJ/mol
(D) ΔH for 2H2 O(l) ⟶ 2H + (aq.) +2OH − (aq.) is 114 kJ

22
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Passage Based Question

Paragraph for Q.7 to Q.8
Chemist seemingly insatiable need to measure heat has led to a broad spectrum of measurement
methods. A special calorimeter is the ice calorimeter, in which the heat released in an exothermic
reaction is trapped in an ice -water mixture at 273K, causing ice to melt which result in
contraction of volume. A student employs this method to determine the heat of combustion of
acetic acid. He finds that when a sample of acetic acid weighing 0.60 g is burnt in excess oxygen
in an ice calorimeter at constant volume and 273K, according to the reaction,
CH3COOH (l) + 2O2(g) ⎯⎯→ 2CO2(g) + 2H2O (l)
the volume of ice and water surrounding the sample decreased by 1.82 ml.
Reaction tube Ice-water volume
measurement

Ice-water mixture

Ice calorimeter

[Given : specific volume of ice = 1.091 ml/gm, specific volume of H2O (l) = 1ml/gm,
Hfusion of ice = 340 J/gm, R = 8J/mol/K]
14. What is internal energy change of combustion for methanol -
(A) –680 kJ/mole (B) –6.8 kJ/mole (C) –567 kJ/mole (D) –5.67 kJ/mole

15. Find Hf of CH3COOH (l) at 273K

given : Hf (CO2(g)) = –390 kJ/mol , Hf (H2O(l)) = –280 kJ/mol
(A) –5.47 kJ/mol (B) –6.6 kJ/mol (C) –660 kJ/mol (D) –547 kJ/mol

23
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Match the column:

16. Column–I Column–II

(A) C(graphite) + O2(g) → CO2(g) (P) H0formation

(B) C(graphite) ⎯→ C(gas) (Q) H0combustion

(C) CH3COOH(aq) + OH– (aq) ⎯→ CH3COO– (aq) + H2O(l) (R) H0atomization

(D) CH4(g) ⎯→ C(g) + 4H(g) (S) H0neutralization

17. List-I List-II

(P) O2(g) (A) fHº = +ve fSº = +ve

(Q) O3(g) (B) fHº = –ve fSº = –ve

(R) Br2(g) (C) fHº = +ve fSº = –ve

(S) H2(l) (D) fHº = 0 fSº = 0

Code :

P Q R S

(A) 4 3 1 2

(B) 2 4 1 3

(C) 3 4 1 2

(D) 2 3 1 4

24
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

18. Column I contains some chemical reactions and Column II contains some AH values (in kJ). Match
the correct AH in Column II for the chemical reaction in Column I with the help of the following
thermochemical equations given.
H+(aq) + OH–(aq) → H2O(l); H = –57.3 kJ
HSolution of HA(g) = –70.7 kJ/mol
HSolution of BOH(g) = 20 kJ/mol
HIionization of HA = 15 kJ/mol and BOH is a strong base.
Column-I Column-II
(Chemical reactions) (H values in kJ)
(A) HA(aq) + BOH(aq) → BA(aq) + H2O (P) –42.3
(B) HA(g) + BOH(g)→ BA (aq) + H2O (Q) –93
(C) HA(g) → H+(aq) + A–(aq) (R) –55.7

(D) B+(aq) + OH–(aq) → BOH(aq) (S) 0

(A) 1-P,2-Q,3-S,4-R (B) 1-P,2-R,3-Q,4-S

(C) 1-S,2-Q,3-R,4-P (D)1-P,2-Q,3-R,4-S
Assertion and Reason
19. Statement- 1 : Absolute entropy of an ion in aqueous solution at 298 K may be negative.
Statement -2 : Absolute entropy at 298 K of any substance can never be negative.
(A) Statement-1 is true, statement- 2 is true and statement- 2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false
(D) Statement-1 is false, statement-2 is true.

20. In the following questions, two statements are given:

One labelled as Assertion A and the other as Reason R. Examine the two statements carefully and mark
the correct choice (A), (B), (C) and (D) according to the instructions given below

Assertion A : f Ho400 is zero for O2(g).

o
Reason R :  f H 298 is zero for O(g).

(A) if both A and R are correct and R is correct explanation of A

(B) If both A and R are correct but R is not the explanation of A
(C) If A is correct but R is wrong
(D) If A is wrong but R is correct

25
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

21. In the following question, two statements are given: One labelled as Assertion A and the other as
Reason R. Examine the two statements carefully and mark the correct choice (A), (B), (C) and (D)
according to the instructions given below
Assertion A :  Hf of sulphur (rhombic) at 25°C is zero

Reason R :  Hf of all elements in their standard state is zero.

(A) If both A and R are correct and R is correct explanation of A

(B) If both A and R are correct but R is not the explanation of A
(C) If A is correct but R is wrong
(D) If A is wrong but R is correct

Numerical Value:
22. The enthalpy of formation of C2H5OH(l) is –66 k Cal/mol. The enthalpy of combustion of CH3–O–
CH3 is –348 k Cal/mol. Given that the enthalpies of formation of CO2(g) and H2O(l) are –94 k
Cal/mol & –68 k Cal/mol respectively, calculate H for the isomerisation of ethanol to
methoxymethane. All data are at 25º C.

23. Calculate the bond enthalpy of the O–H bond in water at 298K using the information given below :-
(A) fH0[H(g)] = 218 kJ/mol
(B) fH0[O(g)] = 249.2 kJ/mol
(C) fH0[H2O(g)] = –241.8 kJ/mol
Also, determine the U of the O–H bond in water at 298K. Assume ideal gas behaviour.

24. The polymerisation of ethylene to linear polyethylene is represented by the reaction

n CH2 = CH2 → (–CH2 – CH2)n
where n has a large integral value. Given that the average enthalpies of bond dissociation for C=C
& C–C at 298 K are + 590 & + 331 kJ mol–1 respectively. Calculate the enthalpy of polymerisation
per mole of ethylene at 298 K.

25. Find the Bond enthalpy (in kJ/mol) of one "three centre two electron bond" in
B2H6 {B–H–B → 2B(g) + H(g) + H(g)} from the given data.
H0f [BH3 (g)] = 100 kJ/mole H0f [B2H6 (g)] = 36 kJ/mole
Hatm2[B(s)] = 565 kJ/mole Hatm[H2(g)] = 436 kJ/mole

26
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

26. Calculate magnitude of enthalpy of combustion of benzene () at 1 atm & 298 K from the
following data :

Bond C–H C–C C=C C=0 O–H O=O

Bond enthalpy (kJ/mole) 400 350 600 700 450 500

Hvap. [C6H6()] = 30 kJ / mole

Hvap. [H2O()] = 40 kJ / mole
Resonance energy of benzene = –150 kJ / mole
Resonance energy of CO2 = –140 kJ / mole
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

27
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

EXERCISE # (JEE-MAIN)
1. If at 298 K the bond energies of C–H, C–C, C=C and H–H bonds are respectively 414, 347, 615
and 435 kJ mol–1, the value of enthalpy change for the reaction : [AIEEE-2003]
H2C = CH2(g) + H2(g) ⎯→ H3C–CH3(g) at 298 K
will be :-
(A) +125 kJ (B) –125 kJ (C) +250 kj (D)–250 kJ

2. The enthalpies of combustion of carbon and carbon monoxide are –393.5 and –283 kJ mol–1
respectively. The enthalpy of formation of carbon monoxide per mole :- [AIEEE-2004]
(A) 110.5 kJ (B) 676.5 kJ (C) –676.5 kJ (D) –110.5 kJ

3. If the bond dissociation energies of XY, X2 and Y2 (all diatomic molecules) are in the ratio of
1 : 1 : 0.5 and fH for the formation of XY is –200 kJ mol–1. The bond dissociation energy of X2
will be :- [AIEEE-2005]
(A) 200 kJ mol–1 (B) 100 kJ mol–1 (C) 800 kJ mol–1 (D) 300 kJ mol–1

4. The enthalpy changes for the following processes are listed below : [AIEEE-2006]
Cl2(g) ⎯→ 2Cl(g), 242.3 kJ mol–1
I2(g) ⎯→ 2I(g) 151.0 kJ mol–1
ICl(g) ⎯→ I(g) + Cl(g), 211.3 kJ mol–1
I2(s) ⎯→ I2(g), 62.76 kJ mol–1
Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard
enthalpy of formation for ICl(g) is :-
(A) –16.8 kJ mol–1 (B) +16.8 kJ mol–1 (C) +244.8 kJ mol–1 (D) –14.6 kJ mol–1

5. The standard enthalpy of formation (fH°) at 298K for methane, CH4(g), is –74.8 kJ mol–1.
The additional information required to determine the average energy for C–H bond formation
would be:- [AIEEE-2006]
(A) Latent heat of vapourization of methane
(B) The first four ionization energies of carbon and electron gain enthalpy of hydrogen
(C) The dissociation energy of hydrogen molecule H2
(D) The dissociation energy of H2 and enthalpy of sublimation of carbon

28
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

6. Oxidising power of chlorine in aqueous solution can be determined by the parameters

indicated below:
1
1 diss H eg H  hyd H
Cl2 (g) ⎯⎯⎯⎯
2
→ Cl(g) ⎯⎯⎯ → Cl− (g) ⎯⎯⎯ → Cl− (aq) [AIEEE-2008]
2
1
The energy involved in the conversion of Cl2(g) to Cl– (aq)
2
(using the data diss H Cl2 = 240 kJ mol–1, eg HCl = –349 kJ mol–1, hyd HCl– =
–381 kJ mol–1) will be:-
(A) –610 kJ mol–1 (B) –850 kJ mol–1 (C) +120 kJ mol–1 (D) +152 kJ mol–1

7. In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
3
CH3OH(l) + O2(g) ⎯→ CO2(g) + 2H2O(l)
2
At 298 K standard Gibb's energies of formation for CH3OH(l), H2O(l) and CO2(g) are –166.2,
–237.2 and –394.4 kJ mol–1 respectively. If standard enthalpy of combustion of methanol is
–726 kJ mol–1, efficiency of the fuel cell will be [AIEEE-2009]
(A) 90% (B) 97% (C) 80% (D) 87%

8. +
On the basis of the following thermochemical data : G0fH(aq) (
=0 )
H2O(l) → H+(aq) + OH– (aq) ; H = 57.32 kJ
1
H2(g) + O2(g) → H2O (l) ; H = –286.20 kJ
2
The value of enthalpy of formation of OH– ion at 25°C is :- [AIEEE-2009]
(A) +228.88 kJ (B) –343.52 kJ (C) –22.88 kJ (D) –228.88 kJ

9. The standard enthalpy of formation of NH3 is –46.0 kJ mol–1. If the enthalpy of formation of H2
from its atoms is –436 kJ mol–1 and that of N2 is –712kJ mol–1, the average bond enthalpy of N–
H bond in NH3 is :- [AIEEE-2010]
(A) –1102 kJ mol–1 (B) –964 kJ mol–1 (C) + 352 kJ mol–1 (D) +1056 kJ mol–1
10. Consider the reaction : [AIEEE-2011]
4NO2(g) + O2(g) → 2N2O5(g), rH = –111kJ.
If N2O5(s) is formed instead of N2O5(g) in the above reaction, the rH value will be :-
(given, H of sublimation for N2O5 is 54 kJ mol–1)
(A) –165 kJ (B) +54 kJ (C) +219 kJ (D) –219 kJ

29
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

11. The enthalpy of neutralisation of NH4OH with HCl is –51.46 kJ mol–1 and the enthalpy of
neutralisation of NaOH with HCl is –55.90 kJ mol–1. The enthalpy of ionisation of NH4OH is:
[JEE-MAINS (online) 2012]
(A) +107.36 kJ mol–1 (B) –4.44 kJ mol–1 (C) –107.36 kJ mol–1 (D) +4.44 kJ mol–1

12. Given [JEE-MAINS (Online) 2013]

Reaction Energy Change (in kJ)
Li(s) ⎯→Li(g) 161
Li(g) ⎯→Li+(g) 520
1
F2(g) ⎯→ F(g) 77
2
F(g) + e– ⎯→ F– (g) (Electron gain enthalpy)
Li+(g) + F–(g) ⎯→ LiF(s) –1047
1
Li(s) + F2(g) ⎯→ Li F(s) –617
2
Based on data provided, the value of electron gain enthalpy of fluorine would be :
(A) –300 kJ mol–1 (B) –328 kJ mol–1 (C) –350 kJ mol–1 (D) –228 kJ mol–1

13. Given : [JEE-MAINS (online) 2013]

1
(a) H2 (g) + O2 (g) → H2O (l) ; Hº298K = –285.9 kJ mol–1
2
1
(b) H2(g) + O2 (g) → H2O (g) ; Hº298K = – 241.8 kJ mol–1
2
The molar enthalpy of vapourisation of water will be :-
(A) 241. 8 kJ mol–1 (B) 527.7 kJ mol–1 (C) 44.1 kJ mol–1 (D) 22.0 kJ mol–1

14. The standard enthalpy of formation (fHº298) for methane, CH4 is– 74.9 kJ mol–1.
In order to calculate the average energy given out in the formation of a C–H bond from this it is
necessary to know which one of the following? [JEE-MAINS(online) 2014]
(A) the dissociation energy of the hydrogen molecule, H2.
(B) the dissociation energy of H2 and enthalpy of sublimation of carbon (graphite).
(C) the first four ionisation energies of carbon and electron affinity of hydrogen.
(D) the first four ionisation energies of carbon.

30
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

15. For complete combustion of ethanol, C2H5OH(l) + 3O2(g) → 2CO2(g) + 3H2O(l), the amount of
heat produced as measured in bomb calorimeter, is 1364.47 kJ mol–1 at 25ºC.
Assuming ideality the Enthalpy of combustion, cH, for the raction will be :-
(R = 8.314 kJ mol–1) [JEE-MAINS 2014]
(A) –1460.50 kj mol–1 (B) – 1350.50 kJ mol–1
(C) – 1366.95 kJ mol–1 (D) – 1361.95 kJ mol–1

16. The heat of atomisation of methane and ethane are 360 kJ/mol and 620 kJ/mol, respectively.
The longest wavelength of light capable of breaking the C–C bond is :
(Avogadro number = 6.02 × 1023, h = 6.62 × 10–34 J s) [JEE-MAINS (Online) 2015]
(A) 2.48 × 103 nm (B) 1.49 × 103 nm (C) 2.49 × 104 nm (D) 2.48 × 104 nm

17. The heats of combustion of carbon and carbon monoxide are –393.5 and –283.5 kJ mol–1,
respectively. The heat of formation (in kJ) of carbon monoxide per mole is :
[JEE-MAINS 2016]
(A) 676.5 (B) – 676.5 (C) –110.5 (D) 110.5

18. Given
C(graphite) + O2 (g) → CO2 (g) ; rH° = – 393.5 kJ mol–1
1
H2(g) + O2(g) → H2O (l) ; rH° = – 285.8 kJ mol–1
2
CO2 (g) + 2H2O (l) → CH4 (g) + 2O2 (g) ; rH° = + 890.3 kJ mol–1
Based on the above thermochemical equations, the value of rH° at 298 K for the reaction
C(graphite) + 2H2(g) → CH4 (g) will be: [JEE-MAINS 2017]
(A) +74.8 kJ mol–1 (B) +144.0 kJ mol–1 (C) –74.8 kJ mol–1 (D) –144.0 kJ mol–1
19. The combustion of benzene (l) gives CO2(g) and H2O (l). Given that heat of combustion of
benzene at constant volume is – 3263.9 kJ mol–1 at 25º C ; heat of combustion (in kJ mol–1)
of benzene at constant pressure will be : (R = 8.314 JK–1 mol–1) [JEE-MAINS 2018]
(A) – 3267.6 (B) 4152 . 6 (C) –452. 6 (D) 3260

31
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

20. Given:
(i) C (graphite) +O2 ( g) → CO2 ( g); ΔrH ∘ = xkJmol−1
1
(ii) C (graphite) + 2 O2 ( g) → CO2 ( g); ΔrH ∘ = ykJ mol
1
(iii) CO(g) + 2 O2 ( g) → CO2 ( g); ΔrH ∘ = zkJmol−1

Based on the above thermochemical equations, find out which one of the following algebraic
relationships is correct ? [JEE-MAINS 2019 (Jan.)]
(A) x = y–z (B) y = 2z–x (C) z = x + y (D) x = y + z
21. Enthalpy of sublimation of iodine is 24 cal g–1 at 200ºC. If specific heat of I2(s) and I2(vap) are
0.055 and 0.031 cal g–1 K–1 respectively, then enthalpy of sublimation of iodine at 250ºC in cal
g–1 is: [JEE-MAINS 2019 (Apr.)]
(A) 2.85 (B) 22.8 (C) 11.4 (D) 5.7
22. The internal energy change (in J ) when 90 g of water undergoes complete evaporation at
100∘ C is (Given : ΔHvap for water at 373 K = 41 kJ/mol, 𝑅 = 8.314JK −1 mol−1 )
[JEE-MAINS 2020]
23. Lattice enthalpy and enthalpy of solution of NaCl are 788kJmol−1 and 4kJmolJm−1, respectively.
The hydration enthalpy of NaCl is [JEE-MAINS 2020]
(A) 784kJmol−1 (B) −780kJmol−1 (C) 780kJmol−1 (D) −784 kJ mol−1
24. According to the following diagram, 𝐴 reduces BO2 when the temperature is :
[JEE-MAINS 2020]

(A) > 1400∘ C (B) < 1400∘ C

(C) > 1200∘ C but < 1400∘ C (D) < 1200∘ C

25. The first and second ionisation enthalpies of a metal are 496 and 4560 kJ mol−1 , respectively.
How many moles of HCl and H2 SO4 , respectively, will be needed to react completely with 1
mole of the metal hydroxide? [JEE-MAINS 2020]
(A) 1 and 0.5 (B) 2 and 0.5 (C) 1 and 2 (D) 1 and 1

32
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

26. For the reaction

C2H6 → C2H4 + H2
the reaction enthalpy rH = ______ kJ mol–1.
(Round off to the Nearest Integer).
[Given : Bond enthalpies in kJ mol–1 : C–C : 347, C=C : 611; C–H : 414, H–H : 436]

[JEE Main, March 2021]

27. The Born-Haber cycle for KCl is evaluated with the following data:

[JEE Main, August 2021]

 f H– for KCl = – 436.7 kJ mol–1 ;

 sub H–for K = 89.2 kJ mol–1;

 ionization H– for K = 419.0 kJ mol–1;

 electron gain H– for Cl(g) = – 348.6 kJ mol–1;

 bond H– for Cl2 = 243.0 kJ mol–1;

The magnitude of lattice enthalpy of KCl in kJ mol–1 is _______ (Nearest integer)

28. At 25C and 1 atm pressure, the enthalpy of combustion of benzene (A) and acetylene (g) are –
3268 kJ mol–1 and –1300 kJ mol–1, respectively. The change in enthalpy for the reaction 3
C2H2(g) → C6H6(l), is [JEE Main, June 2022]

(A) + 324 kJ mol–1 (B) +632 kJ mol–1

(C) – 632 kJ mol–1 (D) – 732 kJ mol–1

29. 2.4 g coal is burnt in a bomb calorimeter in excess of oxygen at 298 K and 1 atm pressure.
The temperature of the calorimeter rises from 298 K to 300 K. The enthalpy change during the
combustion of coal is – x kJ mol–1. The value of x is ___________. (Nearest integer)

(Given : Heat capacity of bomb calorimeter 20.0 kJ K–1. Assume coal to be pure carbon)

[JEE Main, July 2022]

33
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

30. While performing a thermodynamics experiment, a student made the following observations,
HCl + NaOH → NaCl+ H2O H = –57.3 kJ mol–1

CH3COOH + NaOH → CH3COONa + H2O H = –55.3 kJ mol–1.

The enthalpy of ionization of CH3COOH as calculated by the student is________ kJ mol–1.

(Nearest integer) [JEE Main, July 2022]

31. When 600 mL of 0.2 M HNO3 is mixed with 400 mL of 0.1M NaOH solution in a flask, the rise in
temperature of the flask is _________ × 10–2 0C.

(Enthalpy of neuralization = 57 kJ mol–1 and specific heat of water = 4.2 JK–1 g–1)

(Neglect heat capacity of flask) [JEE Main, July 2022]

1
32. The enthalpy change for the conversion of Cl2 (g) to Cl– (aq) is (-) _______ kJ mol–1
2
(Nearest integer) Given : dis H oCl2( g ) = −240 kJmol–1, [JEE Main, Jan. 2023]

dis H oCl2( g ) = −350 kJmol–1,

dis HoCl− = −380 kJmol–1,

(g)

33. Enthalpies of formation of CCl4(g) , H2O(g) , CO2(g) and HCl(g) are –105, –242, –394 and –92 kJ
mol–1 respectively. The magnitude of enthalpy of the reaction given below is ______ kJ mol–1
(nearest integer) CCl4(g) + 2H2O(g) → CO2(g) + 4HCl(g) [JEE Main, Jan. 2023]

34. At 25°C, the enthalpy of the following processes are given: [JEE Main, Jan. 2023]
H2(g) + O2(g) → 2OH(g) H° = 78 kJ mol–1
1
H2(g) + O2(g) → H2O(g) H° = –242 kJ mol–1
2
H2(g) → 2H(g) H° = 436 kJ mol–1
1
O2(g) → O(g) H° = 249 kJ mol–1
2
What would be the value of X for the following reaction? _____ (Nearest integer)
H2O(g) → H(g) + OH(g) H0 = X kJ mol–1

34
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

EXERCISE # (JEE-ADVANCE)

1. Estimate the average S–F bond enthalpy in SF6. The H°f values of SF6 (g), S(g), and F (g) are –
1100 , 275 and 80 kJ/mol respectively. [JEE 1999]

2. Which of the following is not an endothermic reaction? [JEE 1999]

(A) Combustion of methane
(B) Decomposition of water
(C) Dehydrogenation of ethene to acetylene
(D) Conversion of graphite to diamond

3. Diborane is a potential rocket fuel which undergoes combustion according to the reaction,
B2H6(g) + 3O2(g) ⎯→ B2O3(s) + 3H2O(g)
From the following data, calculate the enthalpy change for the combustion of diborane :
[JEE 2000]
3
2B(s) + O2(g) ⎯→ B2O3(s) ; H = –1273 kJ
2
1
H2(g) + O2(g) ⎯→ H2O(l) ; H = –286 kJ
2
H2O(l) ⎯→ H2O(g) ; H = 44 kJ
2B(s) + 3H2(g) ⎯→ B2H6(g) ; H = 36 kJ

4. H°f for CO2(g), CO(g) and H2O(g) are – 393.5, –110.5 and –241.8 kJ mo–l respectively.
The standard enthalpy change (in kJ) for the reaction [JEE 2000]
CO2(g) + H2(g) ⎯→ CO(g) + H2O (g) is
(A) 524.1 (B) 41.2 (C) –262.5 (D) – 41.2

5. Which of the following reactions defines H°f ?

(A) C(diamond) + O2(g) ⎯→ CO2(g) (B) 1/2 H2(g) + 1/2 F2(g) ⎯→ HF(g)
(C) N2(g) + 3H2(g) ⎯→ 2NH3 (D) CO(g) + 1/2O2(g) ⎯→ CO2(g) [JEE 2003]

35
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

6. In a constant volume calorimeter, 3.5 g of a gas with molecular weight 28 was burnt in excess
oxygen at 298.0 K. The temperature of the calorimeter was found to increase from 298.0 K to
298.45 K due to the combustion process. Given that the heat capacity of the calorimeter is
2.5 kJ K–1, the numerical value for the enthalpy of combustion of the gas in kJ mol–1 is
[JEE 2009]
7. Using the data provided, calculate the multiple bond energy (kJ mol–1) of a C  C bond in
C2H2. That energy is (take the bond energy of a C–H bond as 350 kJ mol–1.) [JEE 2012]
2 C(s) + H2(g) ⎯→ C2H2(g) H = 225 kJ mol–1
2 C(s) ⎯→ 2C(g) H = 1410 kJ mol–1
2 C(s) ⎯→ 2C(g) H = 1410 kJ mol–1
H2 (g) ⎯→ 2H(g) H = 330 kJ mol–1
(A) 1165 (B) 837 (C) 865 (D) 815
8. The standard enthalpies of formation of CO2(g), H2O(l) and glucose(s) at 25ºC are
–400 kJ/mol, –300 kJ/mol and –1300 kJ/mol, respectively. The standard enthalpy of
combustion per gram of glucose at 25ºC is [JEE (Advance)2013]
(A) +2900 kJ (B) – 2900 kJ (C) –16.11 kJ (D) + 16.11 kJ
9. Choose the reaction(s) from the following options, for which the standard enthalpy of reaction
is equal to the standard enthalpy of formation. [JEE (Advance)2019]
(A) 2H2 (g) + O2(g) → 2H2O(l) (B) 2C(g) + 3H2(g) → C2H6(g)
1 3
(C) S8(s) + O2(g) → SO2(g) (D) O2(g) → O3(g)
8 2
10. Tin is obtained from cassiterite by reduction with coke. Use the data given below to determine
the minimum temperature (in K) at which the reduction of cassiterite by coke would take place.
At 298 K: Δf H 0 (SnO2 (s)) = −581.0 kJ mol−1 , Δf H 0 (CO2 (g)) = −394.0 kJ mol−1 ,
S 0 (SnO2 (s)) = 56.0 J K −1 mol−1 , S 0 (Sn(s)) = 52.0 J K −1 mol−1 ,
S 0 (C(s)) = 6.0 J K −1 mol−1 , S 0 (CO2 ( g)) = 210.0 J K −1 mol−1 .
Assume that the enthalpies and the entropies are temperature independent.
[JEE (Advance)2020]
11. 2 mol of Hg(g) is combusted in a fixed volume bomb calorimeter with excess of O2 at 298 K and
1 atm into HgO (s). During the reaction, temperature increases from 298.0 K to 312.8 K. If heat
capacity of the bomb calorimeter and enthalpy of formation of Hg(g) are 20.00 kJ K −1 and
61.32 kJ mol−1 at 298 K, respectively, the the calculated standard molar enthalpy of formation
of HgO(s) at 298 K is XkJ mol−1 . The value of |X| is _________ . [JEE (Advance)2022]
[Given: Gas constant R = 8.3 J K −1 mol−1 ]

36
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

ANSWER KEY
DPP-01

1. C 2. C 3. D 4. A 5. B

6. C 7. D 8. C 9. D

10. 90.2 KJ/mol 11. D 12. C

13. –266 kJ/mol and –825 kJ/mol 14. 5

DPP-02

15. D 16. C 17. D

18. D 19. D 20. C 21. -2000

22. A 23. D 24. (i) – 885 kJ/mol (ii) – 889.95 kJ/mol

DPP-03

25. C 26. B 27. B 28. D 29. B

30. C 31. B 32. B 33. D

34. 275 kJ/mol 35. B 36. C

DPP-04

37. D 38. D 39. C 40. C 41. C

42. C 43. 292 kcal/mol 44. –392 kJ mol–1

45. – 90.75 kcal mol–1 46. 18930

DPP-05

47. A 48. C 49. B 50. –19 kcal/mole

51. (i) –384 kJ mol–1 (ii) –307 kJ mol–1 52. B

53. – 80 kJ/mole

54. 9 55. D 56. D

37
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

DPP-06

57. D 58. 75 59. C 60. 1

61. -255 kJ/mol 62. A 63. 84 64. −190

DPP-07

65. D 66. A 67. D 68. B 69. −1410 Cal

70. 480 J 71. B 72. –31.5 kJ/mole 73. C

74. 2 kcal

DPP-08

75. 130 kJ/mole 76. 3360 77. 150.5 kJ/mol

78. B 79. 2

80. (i) – 11 kcal/mole; (ii) – 8 kcal/mole, (iii) – 10.067 Cal / K mole,

(iv) –11 kcal/mole, (v) + 45.067Cal/ K mole

81. B 82. C 83. C 84. A

EXERCISE-II
Single Choice Question
1. (A) 2. (C) 3. (D) 4. (A)

Multiple Choice Question

5. (ABCD) 6. (ABD) 7. (CD) 8. (ABCD)
9. (BD) 10. (ABCD) 11. (BD) 12. (ABD)
13. (ABD)
14. (A) 15. (C)
16. A → P, Q; B → P, R; C → S; D→R
17. (A) 18. (D)
Assertion and Reason
19.(C)
20.(C)
21.(C)

38
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Numerical Value:
22. 22 kcal mol–1 23. H (O–H) = 463.5 kJ/mol U = 461 kJ/mol
24. –72kJ mol–1 25. 455 kJ/mole
26. 2880 kJ
OMR ANS. (9)

JEE MAIN

1. (B) 2. (D) 3. (C) 4. (B) 5. (D) 6. (A)

7. (B) 8. (D) 9. (C) 10. (D) 11. (D) 12. (B)

13. (C) 14. (B) 15. (C) 16. (B) 17. (C) 18. (C)

19. (A) 20. (D) 21. (B) 22. (189494) 23. (D)

24. (A) 25. (A) 26. (128) 27. (718) 28. (C) 29. (200)

30. (B) 31. (54) 32. (610) 33. (173) 34. (499)
JEE ADVANCED

1. (309.16kJ/mol) 2. (A) 3. (–2035kJ mol–1) 4. (B)

5. (B) 6. (9) 7. (D) 8. (C) 9. (C,D)

10. (935) 11. (90.39)

39
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

SOLUTION
EXERCISE-I
DPP-01
(Enthalpy Change)
1. Enthalpy is a state function
2. For standard state, the pressure should be 1 bar, but temperature, any specified temperature.
3 1
5. C(graphite) + H2(g) + Cl2(g) ⎯→ CH3Cl(g)
2 2
7. rH = –944.7 – 4 × 92.3 + 763.2 + 2 × 241.8 = –67.1 kJ
8. –890.4 = –393.5 – 2 × 285.9 – Hf + CH4(g)
Hf CH4(g) = –74.9 kJ
9. –40 = 2Hf NH3 – Hf N2H4(g)
–40 = 2 Hf NH3(g) + 120
2Hf NH3(g) = –160  Hf NH3(g) = –80 kJ

10 2CO(g) + O2 (g) → 2CO2 (g);  r Ho = –566.0 KJ / mol

NO2 (g) + NO(g) → 1/ 2O2 (g); f Ho = –114.2 KJ / mol

2CO2 (g) + 1/ 2N2 → 2CO(g) + NO2 (g); r Ho = 1198.4 kJ / mol

_______________________________________
1 1
N2 (g) + O2 (g) → NO(g); f Ho (NO, g) = 90.2 KJ / mol
2 2
12. 2C(s) + 3H2(g) → C2H6(g) ;
H = U + ng RT
2
– 20 = U – 2 × × 300
1000
U = – 20 + 1.2 = – 18.8 kcal / mol
13. From reaction (D)
1
CO (g) + O2(g) ⎯→ CO2(g)
2
H = –282 kJ
–282 = Hf CO2 (g) – Hf CO (g)
From reaction (C)
Hf CO2 (g) = –393 kJ
–282 = –393 – Hf CO (g)
Hf CO (g) = –393 + 282= –111 kJ/mol

40
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Form reaction (B)

155 = Hf CO (g) – Hf FeO (s)
Hf FeO(s) = –111 –155= –266 kJ/mol
492 = –3 × 111 – Hf Fe2O3(s)
Hf Fe2O3(s) = –333 – 492= –825 kJ
1 5
14. P4 (s) + Cl2 (g) → PCl5(s) ...(1)
4 2

1
P4 (s) + 3Cl2 → 2PCl3(s) ...(2)
4
1
PCl3(l) + Cl2(g) → PCl5(s) ...(3)
4
On applying thermodynamic operation (1)
1
= (3) + (1)
2
1
= –200 + (– 600)
2
= – 500 kJ
= – 5 × 102 kJ
DPP -02
(Enthalpy of Combustion)
17. 6C (graphite) + 3H2(g) → C6H6 H = ?
15
C6H6 + O2 → 6CO2 + 3H2O Q1
2
C + O2 → CO2 Q2
1
H2 + O2 → H2O Q3
2
H = 6Q2 + 3Q3 – Q1
18. C3H8(g) + SO2(g) ⎯→ 3CO2(g) + 4 H2O(l)
–2221.6 = – 3 × 394 – 4 × 285.8 – Hf C3H8(g)
Hf C3H8(g) = 103.6 kJ
1939.1
19. H = − 12 = –1939.1 × 0.3 kJ= –581.73 kJ
40
Calorimetry

41
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

1
23. H2C2O4(s) + O2(g) → H2O() + 2CO2(g);
2
ng = 3/2
0.312  8.75
Uc = – × 90 = –245.7 kJ / mol
1
3 8.314  300
H = U + ngRT = – 245.7 +  = –241.96 kJ / mol
2 1000
24. q = 0.5 × 17.7 kJ
−0.5 17.7
U = 16 = – 885 kJ mol–1
0.16
CH4(g) + 2O2(g) ⎯→ CO2(g) + 2H2O(l)
2  8.314  300
H = –885 – = –889.95 kJ/mol
1000
DPP -03
(Bond Enthalpy)
27. Form step-1 rH = O–H
Form step-2 rH = O–H
2O–H = 498 + 428
O–H = 463 kJ/mol
28. CH4(g) + Cl2(g) ⎯→ CH3Cl(g) + HCl(g)
rH = 4 × C–H + Cl–Cl – 3 × C–H – 3 × C–H – C–Cl – H–Cl
–25 = x + y – 84 – 103
x 9
x + y = 162 and =
y 5
2.8 y = 162 x = 1.8 y
Cl–Cl = y = 57.75
1 1
29. H2(g) + Cl2(g) ⎯→ HCl(g)
2 2
1 1
rH = × 104 + × 58 – 103= –22.0 Kcal
2 2
30. ClF3(g) ⎯→ Cl(g) + 3F(g)
rH = 3 Cl–F = 513 kJ
Cl–F = 171 kJ

42
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

H2(g) + O2(g) H2O(l)

–x4
H2O (g)

31.
x2
rH2 = x1 + – 2x3
2
x2
rH1 = x1 + – 2x3 – x4
2

(g) ⎯→ CH3–CH=CH2
32.
rH = 3 C–C – C–C – C=C
= 2 C–C – C=C = 2 × 348 – 615= + 81 kJ/mol
33. 109 = (N–N + 4N–H) – (N=N + 2N–H) – H–H
109 = N–N – N=N + 2N–H – H–H
109 = 163 – N=N + 2 × 391 – 436
N=N = 54 + 782 – 436
N=N = 836 – 436 = 400 kJ
34. C2H5 – S – S – C2H5(g) ⎯→ C2H5 – S – C2H5(g) + S(g)
rH = –150 + 225 + 200 = +275 kJ/mol
rH = S–S = +275 kJ/mol
35. CH4(g) + 2O2(g) ⎯→ CO2(g) + 2H2O() ;
H = –890 kJ
CO2(g) ⎯→ C(graphite) + O2(g) ;
H = 393 kJ
2H2O() ⎯→ 2H2(g) + O2(g) ;
H = 571 kJ
2H2(g) ⎯→ 4H(g) ; H = 871 kJ
C(graphite) ⎯→ C(g) ; H = 716 kJ
CH4(g) ⎯→ 4H(g) + C(g) ; H = 166
1661
50 C–H = = 415.25
4
DPP -04

43
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

(Enthalpy of Atomisation)
37. CO (g) → C (g) + O (g).
1072 = fHº(C,g) + 247 – (–144)
fHº(C, g) = 711
P O P

O O O O

x 12y
P O P (S) P4O6(g) 4P(g) + 6O(g)
38.
43. XeF4 (g) ⎯→ Xe+ (g) + F– (g) + F2(g) + F(g)
rH = 4 × Xe – F + I.E. Xe(g) – Heg [F(g)] – F – F
= 4 × 34 + 279 – 85 – 38 = + 292 Kcal / mol

Na(s) + F2(g) NaF(s)

101 80

Na(g) F(g)
–894

+494 egH

Na+(g) + F–(g)
44.
–571 = 101 + 494 + 80 + Heg F(g) – 894
Heg F(g) = –392 kJ/mol
45. –105 = 20.5 + 28.75 + X +  – 159.5 = – 90.75 kcal/mol
DPP -05
(Other types of Enthalpies of reaction)
4
48. Number of moles of NH4NO3 dissolved = = 0.05 mole
80
Heat absorbed = CT
= 150 × 1.5 = 225 J
Enthalpy of solution = Heat absorbed by dissolution of 1 mole NH4NO3
225
= J / mole
0.05
= 4.5 kJ / mole
49.

44
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

2 = 772 + Hhyd Na+(g) + Hhyd Cl–(g)

3
–770 = Hhyd Cl–(g) + Hhyd Cl–(g)
2.5
−770  2.5
Hhyd Cl–(g) = = –350 kJ/mol
5.5

50.
–16 = 3 + rH
rH = –19 Kcal

51.
–2 = +772 – 390 + Hhyd Cl–(g)
Hhyd Cl– (g) = – 2 + 390 – 172 = – 384 kJ/mol

+2 = 699 – 390 + Hhyd I–(g)

Hhyd I–(g) = –307 kJ/mol
52. HCl (aq.) ⎯⎯→ HCl (aq.) –2.5
4M 2M
1000 5 mole
HCl (aq.) ⎯⎯→ HCl(aq.)
4M 2M
500 ml
45
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

53. HCl(g) + aq ⎯→ H+ (aq) + Cl– (aq)

rH = Hf Cl–(aq) – Hf HCl (g)
= –170 + 90= – 80 kJ/mol
DPP -06
(Resonance Enthalpy)
57. H = 50 – 70 = – 20 kJ
60. Resonance occurs in product but not in reactant.
61.
C(graphite,s) + O2 ⎯→ CO2(g) Hr = –390 kJ/mol
R.H.
+ 715 500 R.E.

CO2(g)
𝛥𝐻2
C(g) + 2O(g)→
R.S.

–390 = 715 + 500 + H2 + R.E.

Since H2 = –2 C=O = –2 × 675
–390 = 715 + 500 – 2 × 675 + RE
RE = –390 + 2 × 675 – 715 – 500 = –255 kJ/mol
62. CH2 = CH2 + H2 ⎯→ C2H6
rH = –132 kJ/mol

rH = – 140 – 115= –255

–255 = –RE –264  RE = 255 – 264= –9 kJ

+ H2 ⎯→
63. H = –28.6 Kcal/mol

46
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

rH

–RE
–7 × 28.6

–116.2 = – RE – 7 × 28.6
RE = –7 × 28.6 + 116.2= –84 Kcal mol–1

64
Hr = 6 × Hatom (graphite) + 3 × BE H–H – 3 × BEC–C
–3BEC = C – 6 BEC–H
= 6 × 700 + 3 × 440 – 3 × 350 – 3 × 600 – 6 × 400
= 4200 + 1320 – 1050 – 1800 – 2400
= 270 kJ/mol
Using above cycle
Hr + RE = 80
RE = 80 = 270 = – 190 kJ/mol
DPP -07
(Enthalpy of Neutralisation)
69. (i) HCl + NaOH ⎯→ NaCl + H2O rH1 = –13680 cal
(ii) NH4OH + HCl ⎯→ NH4Cl+ H2O rH2 = –12270 cal
(iii) NH4Cl + NaOH ⎯→ NH4OH + NaCl rH3 = ?
(iii) = (ii) – (i)
rH3 = rH2 – rH1= –12270 + 13680= +1410 cal
70. H+ + OH– ⎯→ H2O H° = –57 kJ/mol
H ion HCN = 45 kJ/mol
Ba(OH)2 + HCN
20m mol 50m mol
⎯→

m mol of H+ = 50 ; m mol OH– = 40

Hneut = –57 × 0.04 + 45 × 0.04 = –12 × 0.04 kJ = –480 J

47
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

500  2.11.2
72. q= kJ (for 80 m mole)
1000
500  2.11.2
q= (for 1 mole)
1000  0.08
= + 31.5 kJ mol–1
74. Na2CO3 + CaCl2 ⎯→ CaCO3  + 2NaCl
rH = Hƒº CaCO3 – Hƒ Ca2+ – Hƒ CO32–
= –288 + 129 + 161= + 2 kcal/mol
DPP -08
(Free Energy Change)
75. rHº= –635 – 394 – (– 1207) = 178 kJ/mole
rSº = Sº (CaO) + Sº(CO2) – Sº (CaCO3)
= 40 + 214 – 94 = 160 J/K
rGº = rHº – T. rSº
300 160
= 178 – = 178 – 48
1000
= 130 kJ/mole
76. G = Gº + RT ln Q
 
Gº = 2 G f (NO2) –  G f (N2O4) = O

G = 8 × 300 ln  2  = 3360 J
2

 1 

77. rG = rGº + RT ln Qp

rGº = rHº – T . rSº
300(2  210 − 205 − 190)
 2 × 90.5 –
1000
= 173.5 kJ/mol
2750 (10−5 ) 2
rG = 173.5 + log −4
1000 (10 )(10−2 )
rG = 150.5 kJ/mol Ans.

rG° = G f PCl3(g) – G f PCl5(g)

0 0
78.

= – 60 + 74 = + 14 Kcal/mol
rG° = –RT ln k
2 1000
14 = − ln k
1000

48
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

–7 = ln k
– 10 ln2 = ln k  k = 2–10

80 (i) rH° = Hf CO2(g) – Hf H2O(g) – Hf CO(g)

= – 94 + 57 + 26= – 11 Kcal mol–1

(ii) rGº = Gºf [H2 (g)] + Gºf [CO2 (g)] – Gºf [H2O (g)] – Gºf [CO(g)]
rG° = –94 + 32 + 54 = –8 kcal/mol
(iii) rS°298K
G° = H° – T S°
–8000 = –11000 – 298 × S°
298 × S° = –3000
3
S° = − × 1000 = –10.067 Cal K–1 mol–1
298
(iv) H = U + ngRT
U = –11 Kcal/mol
(v) rSº = SºH2 + SCO
º
2
− SºH2O − SCO
º

– 10.067 = 31+ 51 – SH2O – 47

SH2O = + 45.067Cal/ K mole

82. (i) Au(OH)3 + 4HCl ⎯→ HAuCl4 + 3H2O H = 28 kcal

(ii) Au(OH)3 + 4HBr ⎯→ HAuBr4 + 3H2O H = – 36.8 kcal
(i) – (ii) = (iii)
(iii) HAuBr4 + 4HCl ⎯→ HAuCl4 + 4HBr rH = 64.8 kcal
0.44
% conversion of HAuBr4 = 100 = 0.6 %
64.8
83. C (graphite, s) + O2(g) ⎯→ CO2(g) rH1
C (diamond, s) + O2(g) ⎯→ CO2(g) rH2
C (graphite, s) ⎯→ C (diamond, s) rH3 = rH1 – rH2= 1.9 kJ
C (diamond, s) ⎯→ C (graphite, s) rH3= – 1.9 kJ (for 1 mol)
rH3= – 0.95 kJ (for 6g)
1
84. C(s) + O2(g) ⎯→ CO(g) H = –110 kJ
2
C(s) + H2O(g) ⎯→ CO(g) + H2(g) H = +130 kJ
To keep the temp of reaction constant
220 x = 130 y x/y = 0.6
49
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

EXERCISE-II
Single Choice Question
1. from (d) Hƒ H2O() = – 285 kJ
(a) 2NH3(g) + 3N2O(g) ⎯→ 4N2(g) + 3H2O() rH = –1011 kJ
3Hƒ H2O() – 2Hƒ NH3(g) – 3Hƒ N2O(g) = –1011
2Hƒ NH3(g) + 3Hƒ N2O(g) = – 3 × 285 + 1011= 156 (i)
(b) N2O(g) + 3H2(g) ⎯→ N2H4() + H2O() rH = – 317 kJ
Hƒ N2H4() – Hƒ N2O(g) + Hƒ H2O()= – 317 kJ
Hƒ N2H4() – Hƒ N2O(g) = –32 (ii)
(c) 4NH3(g) + O2(g) ⎯→ 2N2H4() + 2H2O() rH = –286 kJ
2Hƒ N2H4() + 2Hƒ H2O() – 4Hƒ NH3(g) = –286 kJ
2Hƒ N2H4() – 4Hƒ NH3(g) = 284 (iii)
from (i), (iii) and (iii)
Hƒ N2H4() = 50.5 kJ/mol
Hƒ N2O(g) = 82.5 kJ/mol
Hƒ NH3(g) = – 45.75 kJ/mol
rH = 3Hƒ H2O() – Hƒ N2H4()
= – 3 × 285 – 50.5 = – 620.5 kJ/mol

2. –16 = 2 – 2 Uf NO2(g)

0

U0f NO2(g) = 9 Kcal mol–1

1
N2(g) + O2(g) ⎯→ NO2(g)
2
ng = –0.5
0.5  2 1000
U0f NO2(g) = − = +8 Kcal mol–1
1000
4. KOH → 0.1 M, 224 ml
meq of KOH = 0.1 × 224 × 1
= 22.4 meq
H2SO4 → 0.1 M, 50 ml
meq of H2SO4 = 0.1 × 50 × 2
= 10 meq
H+ + OH– → H2O H = 13.7 Kcal/eq
heat liberated by the reaction = heat absorbed by the solution
13.7 × 103 × 10–2 = mST
50
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

13.7 103 10−2

T =
1 274
T = 0.5 K Ans.
Multiple Choice Question
7. H2(g) ⎯→ 2H(g)
rH = H atom. H2(g) = 2 Hƒ H(g) = H – H
1
H2(g) + O2(g) ⎯→ H2O()
2
rH = Hƒ N2O() = Hc H2(g)
Match the column :
16. (A) C (graphite, s) + O2(g) ⎯→ CO2(g)
rHº = Hºƒ CO2(g) = Hºc C (graphite, s)
(B) C (graphite, s) ⎯→ C(gas)
rHº = Hº atom. = Hº sub.
(C) CH3COOH(aq) + OH– (aq) ⎯→ CH3COO– (aq) + H2O()
rHº = Hº neat.
(D) CH4(g) = C(g) + 4H(g)
rHº = Hº atom. CH4(g) = 4 C – H

Match list
17. (P) O2(g) Hƒº = 0 ; ƒSº = 0
(Q) O3(g) Hƒ = + ve ; ƒSº = –ve
2
O2(g) ⎯→ O3(g) rH = +ve
3
(R) Br2() ⎯→ Br2(g) rH = +ve
Sƒº = +ve
(S) H2(g) ⎯→ H2() rH = – ve
Sƒ = – ve

18. (1) H = (–57.3) + 15 = – 42.3 kJ

(2) H = –42.3 – 70.7 + 20 = – 93.0 kJ
(3) H = –70.7 + 15 = – 55.7 kJ
(4) H = 0

51
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

Assertion and Reason

19. Absolute entropies of ions are relative to H+ (aq)

Numerical Value:
rH
22. C2H5OH(l) ⎯⎯⎯
→ CH3–O–CH3 (l)
CH3–O–CH3(l) + 3O2(g) ⎯→ 2CO2(g) + 3H2O(l)
–348 = 2Hf CO2(g) + 3Hf H2O(l) – Hf CH3–O–CH3
Hf CH–O–CH3 = –2 × 94 – 3 × 68 + 348= –44 Kcal mol–1
rH = –44 + 66= 22 kcal mol–1

1
23. H2(g) + O2(g) ⎯→ H2O(g)
2
rH = HƒºH2O(g) = – 241.8
– 241.8 = 2 × 218 + 249.2 – 2 O – H
O – H = 463.5 kJ/mol
H = U + ngRT
2  8.314  298
2 × 463.5 = U +
1000
U = 922 (for 2 O – H bond)
922
= (for 1 O – H bond) = 461 kJ/mol
2

24. n CH2 = CH2 ⎯→ {CH2 – CH2}n

rH = C=C – 2C–C = 590 – 2 × 331= –72 kJ/mol

25.
H H H
B B
H H H

3
B(s) + H2(g) ⎯⎯⎯ → BH3(g)
100KJ

2
 565  1.5×436 0
B(g) + 3H(g) ⎯→ BH3(g)
rHº = Hƒº BH3(g) = 100 kJ

52
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

100 = 565 + 1.5 × 436 – 3× B – H

3× B – H = 565 + 1.5 × 436 – 100
 B – H = 373 KJ/mol

2B(s) + 3H2(g) ⎯⎯→ B2H6(g)

36

 2×565  3×436 0
2B(g) + 6H(g) ⎯→ B2H6(g)
rHº = HƒºB2H6(g) = 36 kJ/mol
36 = 2 × 565 + 3 × 436 – 4 × 373 – 2  B – H – B
2  B – H – B = 910 kJ
 B – H – B = 455 kJ/mol

53
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

EXERCISE JEE-MAIN

1. rH = C – C + H – H – C – C – 2 C – H
= 615 + 435 – 347 – 2 × 414= – 125 kJ

2. C (graphite, s) + O2(g) ⎯→ CO2(g)

rH = – 393.5
1
CO(g) + O2(g) ⎯→ CO2(g)
2
rH = – 283 kJ
– 283 = – 393.5 – Hƒ CO(g)
Hƒ CO(g) = – 110.5 kJ

1 1
3. X2(g) + Y2(g) ⎯→ XY(g)
2 2
1 1
rH = X – X + Y – Y – X – Y
2 2
1 1
– 200 = × a + × 0.5a – a
2 2
A = X – X = 800

1 1 rH1
4. I2(s) + Cl2(g) ⎯⎯⎯ → ICl(g)
2 2
 62.76/2  0 0
1 1 rH 2
I2(g) + Cl2(g) ⎯⎯⎯ → ICl(g)
2 2
62.76
rH2 + = rH1
2
1 1
rH2 = × 151 + × 242.3 – 211.3 = 196.65 – 211.3 = – 14.65
2 2
62.76
rH1 = – 14.65 + = 16.73 kJ/mol
2

5. C (graphite) + 2H2(g) ⎯→ CH4(g)

1
6. rH = × 240 – 349 – 381= – 610 kJ/mol
2

54
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

7. rGº = – 394.4 – 2 × 237.2 + 166.2

= – 702.6 kJ/mol
= W non – PV
H = – 726 kJ/mol = q
465.4
= 100  97%
726

8. 57.32 = Hƒ OH– (aq) – Hƒ H2O()

57.32 = Hƒ OH– (aq) + 286.2

Hƒ OH– (aq) = – 228.88 kJ

1 3
9. N2(g) + H2(g) ⎯→ NH3(g)
2 2
3 1
– 46 = × 436 + × 712 – 3 N – H
2 2

3 N – H = 1056   N – H = 352 kJ mol–1

10.

rH + 2 × 54 = – 111rH = – 219 kJ

11. – 51.46 = – 55.90 + H ion

H ion. = + 4.44 kJ mol–1

1 −617
12. Li(s) + F2(g) ⎯⎯⎯ → LiF(s)
2
 161  77
Li(g) F(g) –1047
 520  egH
Li+(g) + F–(g)
161 + 520 + 77 + egH F(g) – 1047 = – 617
egH F(g) = –328 kJ/mol

13. H2O() ⎯→ H2O(g)

rH = b – a = – 241.8 + 285.9 = + 44.1 kJ

55
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

14. C (graphite) + 2H2(g) ⎯→ CH4(g)

rH = H sub. C(graphite) + 2 H – H – 4 C – H

15. C2H5OH() + 3O2(g) ⎯→ 2CO2(g) + 3H2O()

U = – 1364.47 kJ/mol
H = U + ngRT
1 8.314  298
= – 1364.47 – = – 1366.95 kJ/mol
1000

16. 4 C – H = 360 kJ
C – H = 90 kJ/mol
C – C + C – H = 620
80
C – C = 80 kJ/mol = ev / bond
96.5
1240
 =  96.5 nm = 1.493 × 03 nm
80

17. (i) C (graphite) + O2(g) ⎯→ CO2(g)

H = – 393.5 kJ mol–1
1
(ii) CO(g) + O2(g) ⎯→ CO2(g)
2
H = – 283.5 kJ/mol
1
(iii) C (graphite) + O2(g) ⎯→ CO(g)
2
(iii) = (i) – (ii)
rH = – 393.5 + 283.5 = –110.0 kJ/mol

18. C (graphite) + 2H2(g) ⎯→ CH4(g)

rH = Hƒ CH4(g)
890.3 = Hƒ CH4(g) – Hƒ CO2(g) – 2 Hƒ H2O()
890.3 = Hƒ CH4(g) + 393.5 + 2 × 285.8
rH = Hƒ CH4(g) = – 74.8 kJ/mol

19. C6H6() + 7.5 O2(g) ⎯→ 6CO2(g) + 3H2O()

ng = – 1.5
H = U + ngRT

56
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

1.5  8.314  298

H = – 3263.9 – = –3267.6 kJ
1000

20. (i) C (graphite) + O2(g) ⎯→ CO2(g)

rHº = x kJ/mol
1
(ii) C (graphite) + O2(g) ⎯→ CO(g)
2
rHº = y kJ/mol
1
(iii) CO(g) + O2(g) ⎯→ CO2(g)
2
rHº = 2 kJ/mol
(i) = (ii) + (iii) x = y + z

21. I2(s) ⎯→ I2(g)

( Cp)r = 0.031 – 0.055 = – 0.024 cal g–1 k–1
rH 523 k – rH 473 k = – 0.024 × (523 – 473)
rH 523 k – 24 = – 0.024 × 50
rH 523 k = 22.8 cal g–1

22. H2 O(I) → H2 O(g)

ΔHvap = ΔU + Δng RT

ΔU = ΔHvap − RT

= 41,000 − 8.314 × 373Jmol−1

= 37898.878

For 5moles, ΔU = 37898.878 × 5 J = 189494 J

23. ΔSol H ∘ = Δlattice H∘ + ΔHyd H ∘

4 = 788 + ΔHyd. H ∘

ΔHyd H ∘ = −784 kJ/mol

24. 𝐴 + 𝐵𝑂2 → 𝐵 + 𝐴𝑂2

Δ𝐺 = −𝑣𝑒

Only above 1400∘ C

57
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

25. According to the given data of I.E,

This element must belong to group 1 and thus is monovalent and form hydroxide of the type
𝑀(𝑂𝐻).

MOH + HCl → MCl + H2 O

1 mole 1 mole

2MOH + H2 SO4 → M2 SO4 + H2 O

1 mole 1/2 mole

1  
27. f HKCl = sub H(K)

+ ionization H(K) +  bond H(Cl2 ) + electron gain H ( Cl) +  lattice H (KCl)
2
1
 – 436.7 = 89.2 + 419.0 + (243.0) + {–348.6} + lattice H(KCl)
2

 lattice H(KCl) = −717.8kJ mol−1

The magnitude of lattice enthalpy of KCl in kJ mol–1 is 718 (Nearest integer).

28. H =HCombustion (Reactant) – HCombustion

(Product)

= 3 × (–1300) – [–3268]

= – 632 kJ mol –1

29. C(s) + O2(g) → CO2 (g) ; H = – x kJ/mole

Q = CT = 20 kJ × 2

40 kJ heat is released for 2.4 g of C

40
For 1 mole ‘C’ : Q = 12
2.4

400
= 12 = 200 kJ/mole
24

Q=E = H = 200 kJ ( ng = 0)

x = 200
30. Hionisation of CH3COOH = | – 57.3 – (– 55.3)|

= 2 kJ/mol
31. HNO3 NaOH

600 mL × 0.2 M 400 mL × 0.1 M

58
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

= 120 m mol = 40 m mol

HNO3 + NaOH → NaNO3 + H2O

Bef. 120 40

Aft. 80 0 40 m mol

(
Δ r H = 40mmol  57 103 ) mol
J

J
= 40 10−3 mol  57 103
mol

=2280 J

mST = 2280

1gm
 1000mL   4, 2  ΔT = 2280
mL

2280
ΔT = 10−3
4.2

22800
= 10−3 = 542.86 10−3
42

ΔT = 54.286 10−2 K

ΔT = 54.286 10−20 C

Ans. 54.286
Answer mentioned as 54 (Closest integer)

1 − −
32. Cl2(g) → Cl(g) → Cl(g) → Cl(aq.)
2
1
ΔH =  240 + (−350) + (−380)
2
= – 610 Ans.

33. rH = Hp – HR

= (–394 + 4 × –92) – (–105 + (2 × –242)
= –173 kJ/mol

34. 2H2O(g) → 2H2(g) + O2(g) + (242 × 2) kJ mol–1

H2(g) + O2(g) → 2OH + 78 kJ mol–1
59
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

H2(g) → 2H + 436 kJ mol–1

2H2O → 2H + 2OH + 998 kJ mol–1
1
H2O → H + OH 998 × = + 499 kJ mol–1
2

60
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

EXERCISE JEE-ADVANCE
−1100
1. S(s) + 3F2(g) ⎯⎯⎯ → SF6(g)
 275  6×80 0
S(g) + 6F(g) ⎯→ SF6(g)

– 1100 = 275 + 6 × 80 – 6 S – F

6 S – F = 275 – 6 × 80 + 1100

S – F = 309.16 kJ/mol
2. Combustion is exothermic reaction
3. rH = Hƒ B2O3(s) + 3Hƒ H2O(g) – Hƒ B2H6(g)
Hƒ B2O3(s) = – 1273 kJ
44 = Hƒ H2O(g) + 286
Hƒ H2O(g) = – 242 kJ
Hƒ B2H6 = 36 kJ
rH = – 1273 – 3 × 242 – 36= – 2035 kJ/mol

4. rH = Hƒ CO(g) + Hƒ H2O(g) – Hƒ CO2(g)

= – 110.5 – 241.8 + 393.5 = 41.2 kJ/mol
6. 9 = 2.5 × 0.45 kJ
2.5  0.45
H = −  28 = – 9 kJ/mol
3.5

7. 2C(s) + H2(g) ⎯→ C2H2(g) H = 225 kJ /mol

 1410  330 0
2C(g) + 2H(g) ⎯→ C2H2(g)
225 = 1410 + 330 – 2 × C – H – C  C

225 = 1740 – 2 × 350 – C  C

C  C = 1740 – 700 – 225 = + 815 kJ

8. C6H12O6(s) + 6O2(g) ⎯→ 6CO2(g) + 6H2O()

rH = – 6 × 400 – 6 × 30 + 1300
= – 2700 kJ/mol
2900
=− kJ (per gram) = – 16.11 kJ
180

61
DOWNLOAD
IIT SCHOOL APP NOW
 THERMOCHEMISTRY (Physical Chemistry)

10. SnO2 ( s) + C(s) ⎯→ CO2 + Sn

∆H = (∆f H)P − (∆f H)R
= −394 + 581
= +187KJ/mol
∆S = (∆S)P − (∆S)R
= 210 + 52 − 56 − 6
= 200 J/kmol
∆G = 187 × 1000 − 200 × T
T = [187 × 1000]/200 = 935 K
11. 2Hg(g) + O2 ( g) − 2HgO(s)
Heat capacity of calorimeter = 20 kJ K −1
Rise in temperature = 14.8 K
Heat evolved = 20 × 14.8 = 296 kJ
ΔH ∘ = ΔU ∘ + Δng RT
= −296 − 3 × 8.3 × 298 × 10−3
≃ −303.42 kJ
ΔH ∘ = ΔHfo (HgO(s)) − ΔHfo (Hg(g))
−303.42 = ΔHfo (HgO(s)) − 2 × 61.32
ΔHfo (HgO(s)) = −303.42 + 122.64
= −180.78 kJ
|ΔHfo (HgO(s))| = 90.39 kJ mol−1

62
DOWNLOAD
IIT SCHOOL APP NOW