The Mass of A Neutral Atom
The Mass of A Neutral Atom
1
Unified mass unit, u 12 the mass of a neutral C12 atom
1u c = 1.6604310
2 c2
-27
kg
1.60210-19 joule/eV
= 1.6604310 -27
kg (2.99810 8
m/sec) 2
1.60210-19 joule/eV
1u = 931.58 MeV/c 2
Rest mass energy can be measure in terms of eV or MeV.
Sometime mass is measure in the convenient unit of MeV/c2.
1 keV = 103 eV
1 MeV = 106 eV
1 GeV = 109 eV
1 TeV = 1012 eV
electron e 0.5109989
muon 105.658357
proton p 938.27200
neutron n 939.56533
deuteron H2 1875.580
triton H3 2808.873
c
v 2
or E2 = p2c2 + Eo2 2 1 / 1 2
c
and so: T KE = moc2 ( - 1) = c2 m
2
' ( 2m0 )c
2 2
E final m0c m0c
2 2
' (2m0 )c (1 )m0c ' (1 ) / 2
revealing the intermediate state of “bound” protons to have a mass of
' ( 2m0 ) (1 )m0 > 2m0 !!!
or consider the same collision in the center of momentum frame:
E=m0c2 E=m0c2
2 2
E 2m0c 2m0c
The intermediate system of protons has more mass than two protons!
For a repulsive potential
combined rest mass > sum of the individual rest masses
2.22464 MeV
B
2
Zm p ( A Z ) mn M nucleus ( A, Z )
c
B
2
Z ( m p me ) ( A Z ) mn M neutral atom ( A, Z )
c
B
2
Zm H ( A Z ) mn M neutral atom ( A, Z )
c
Working in atomic mass units, u
M ( A, Z ) Au
for A>50
~constant
8-9 MeV
Binding energy per nuclear
particle (nucleon) in MeV
Mass Number, A
This confirms the short range ascribed to the nuclear force…
it must involve only nearest neighbor nuclei
B/A (keV/A)
62
Ni 8794.60 +/- 0.03
58
Fe 8792.23 +/- 0.03
56
Fe 8790.36 +/- 0.03
60
Ni 8780.79 +/- 0.03
EV av A ~proportional to volume
B/A (MeV)
A
But the nuclei at the surface have fewer nearest-neighbor bonds!
So we’ve obviously over-estimated!
by something the nucleus’ surface area
recall
2/3
Es as A r A1 / 3
kQ 2 2 kQ 4 5
Vdq 3 r 4r dr 3
r dr
R R
Coulomb Energy
kQ 4 R 5 kQ 4 Q 1 5
Integrating: 3 0 r dr 3 3
R
R R 4R / 3 5
1 3Q 2 1
4 0 5 R
Motivating us to add a correction term for this Coulomb energy
e2 Z(Z-1)e2 Q2
Z ( Z 1)
R
number of pairings RA1/3
1/ 3
Ec ac Z ( Z 1) A
B av A a s A ac Z ( Z 1) A
2/3 1 / 3
Coulomb term
volume term accounts for
grows with (repulsive) energy
addition of built up in the
each interacting accumulation
nuclei of protons
surface term
corrects for
nuclei at the
surface (not
completely
surrounded by
nearest neighbors)
A = 127
Mass defect (MeV) isobars
-80 -80
-84 -84
-86 -86
-88 -88
50 52 54 56
Atomic number, Z
Think of
the stability band
as a contour map
of a valley:
2
(A/ 2 Z)
a
symmetry sym
A
Like the “closed shell” electronic configurations of the noble gases
we see “magic numbers” recurring…marking tightly bound,
extraordinarily stable nuclear configurations.
=4He (with Z=N=2) and 16O (Z=N=8) are doubly magic!
B av A a s A ac Z ( Z 1) A
2/3 1 / 3
2
(A/ 2 Z)
asym ( A)
A
symmetry term pairing energy term
drives number of increased stability
protons ≈ neutrons for paired nuclei
2
M ( A, Z ) Zm p ( A Z )mn B( A, Z )c
2/3 1 / 3
B( A, Z ) av A as A ac Z ( Z 1) A
2
asym ( A / 2 Z ) / A ( A, Z )
d3/2
d: ℓ = 2
d5/2
f 5/2
f: ℓ = 3
f 7/2
There is a 1f5/2 energy level that can hold
5
2( ) ????
1 6 protons with different mj values
2
and another that can hold 6 neutrons.
Consider:
27
13 Al (ground state)
2 4 2 5
Protons: (1s1/2) (1p3/2) (1p1/2) (1d5/2)
2 4 2 6
Neutrons: (1s1/2) (1p3/2) (1p1/2) (1d5/2)
1 un-paired proton with j=5/2
so aluminum: I=5/2
Consider:
9
Be (ground state)
2 2
p: (1s1/2) (1p3/2) (1p1/2) (1d5/2)
2 3
n: (1s1/2) (1p3/2) (1p1/2) (1d5/2)
1 un-paired neutron with j=3/2 so: I=3/2
Consider:
9
B (ground state)
2 3
p: (1s1/2) (1p3/2) (1p1/2) (1d5/2)
2 2
n: (1s1/2) (1p3/2) (1p1/2) (1d5/2)
1 un-paired proton with j=3/2 so: I=3/2
Magnetic Dipole Moment
classically B
1
= c q
v
r
2 1 qvr
= c =
q
(mvr )
2r 2 2mc
L
q
L but maybe too classical!
2mc
We still expect J quantum mechanically
and write e g measures the
g J (expected)
2mc deviation from
quantum mechanically
J is quantized! e g 0 j
J j g j
2mc 0 = “magneton”
For atomic physics (involving electrons)
“Bohr magneton”
e 14
B 0.5788 10 MeV / G
2me c
5
5.7885 10 eV / T
For nuclear physics
“nuclear magneton”
e
N 3.1525 1018 MeV / G
2m p c
3.15255 108 eV / T