有机锶化学是研究-键的化合物的化学分支。

金属锶和卤代烃反应,可以得到RSrX,在反应中通常会先加入碘、镁或将锶制成汞齐来活化。[1]用氯代烃和溴代烃反应的产率都较低。用二烃基汞和锶反应,可以得到二烃基锶:

Sr + R2Hg —THF→ R2Sr + Hg

金属锶和环戊二烯在液四氢呋喃或DMF中反应,可以得到二茂锶[2][3]


参考资料

编辑
  1. ^ Bryce-Smith D, Skinner A C. J Chem Soc, 1963. 577-585
  2. ^ Fischer E O, Stölzle G. Chem Ber, 1961, 94. 2187-2193
  3. ^ Kirilov M, Petrov G, Angelov C. J Organomet Chem, 1976, 113: 225-232
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