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4-氯乙苯

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4-氯乙苯
识别
CAS号 622-98-0  checkY
SMILES
 
  • ClC1=CC=C(C=C1)CC
性质
化学式 C8H9Cl
摩尔质量 140.61 g·mol−1
沸点 185 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4-氯乙苯是一种有机氯化合物,化学式为C8H9Cl。它可由乙苯次氯酸叔丁酯沸石存在下于乙腈中反应制得,该反应会产生少量的2-氯乙苯[2]

反应

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4-氯乙苯和过氧化叔丁醇氯化铜新铜试剂的催化下反应,可以得到4'-氯苯乙酮維基數據所列Q27295903[3]

参考文献

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  1. ^ Ignacio Aracil, Rafael Font, and Juan A. Conesa. Chlorinated and Nonchlorinated Compounds from the Pyrolysis and Combustion of Polychloroprene. Environ. Sci. Technol. 2010, 44, 11, 4169–4175. doi:10.1021/es100023a. S.I. pp S4.
  2. ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
  3. ^ Md. Munkir Hossain, Shin-Guang Shyu. Biphasic copper-catalyzed C–H bond activation of arylalkanes to ketones with tert-butyl hydroperoxide in water at room temperature. Tetrahedron. 2016. 72 (29). doi:10.1016/j.tet.2016.05.066.
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