锗杂苯

锗杂苯
	IUPAC名;
别名	Germanabenzene; Germin; Germanin
识别
CAS号	75920-32-0
PubChem	20056561
ChemSpider	16739132
SMILES	[GeH]1C=CC=CC=1;
性质
化学式	C5H6Ge
摩尔质量	138.74 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

锗杂苯 (C₅H₆Ge) 是一类有机化合物的母体，由苯环的一个碳原子被锗取代而成。锗杂苯本身已被理论研究，^[1] 含有 2,4,6-三[双(三甲基硅基)甲基]苯基或叔丁基基团的锗杂苯衍生物也是已知的。^[2] 此外，稳定的萘衍生物是存在的，像是含有 2-锗杂萘的物质（下图）。^[3] 锗杂苯中的锗碳键可通过叔丁基基团与潜在的反应物隔离。它是芳香族化合物，和硅杂苯和锡杂苯一样。

参见

苯环的一个碳原子被其它原子取代形成的化合物：硼杂苯、硅杂苯、锗杂苯、锡杂苯、吡啶、磷杂苯、砷杂苯、铋杂苯、氧杂苯𬭩离子（英语：pyrylium）、硫杂苯𬭩离子（英语：thiopyrylium）、硒杂苯𬭩离子（英语：selenopyrylium）、碲杂苯𬭩离子（英语：telluropyrylium）

参考资料

^ Ebrahimi, A. A.; Ghiasi, R.; Foroutan-Nejad, C. Topological Characteristics of the Ring Critical Points and the Aromaticity of Groups IIIa to VIa Hetero-Benzenes. Journal of Molecular Structure: THEOCHEM. 2010, 941 (1–3): 47–52. doi:10.1016/j.theochem.2009.10.038.
^ Nakata, Norio; Takeda, Nobuhiro; Tokitoh, Norihiro. Synthesis and Properties of the First Stable Germabenzene. Journal of the American Chemical Society. 2002-06-01, 124 (24): 6914–6920. ISSN 0002-7863. doi:10.1021/ja0262941.
^ Nakata, N.; Takeda, N.; Tokitoh, N. Synthesis and Structure of a Kinetically Stabilized 2-Germanaphthalene: The First Stable Neutral Germaaromatic Compound. Organometallics. 2001, 20 (26): 5507–5509. doi:10.1021/om010881y.

[1] Ebrahimi, A. A.; Ghiasi, R.; Foroutan-Nejad, C. Topological Characteristics of the Ring Critical Points and the Aromaticity of Groups IIIa to VIa Hetero-Benzenes. Journal of Molecular Structure: THEOCHEM. 2010, 941 (1–3): 47–52. doi:10.1016/j.theochem.2009.10.038.

[2] Nakata, Norio; Takeda, Nobuhiro; Tokitoh, Norihiro. Synthesis and Properties of the First Stable Germabenzene. Journal of the American Chemical Society. 2002-06-01, 124 (24): 6914–6920. ISSN 0002-7863. doi:10.1021/ja0262941.

[3] Nakata, N.; Takeda, N.; Tokitoh, N. Synthesis and Structure of a Kinetically Stabilized 2-Germanaphthalene: The First Stable Neutral Germaaromatic Compound. Organometallics. 2001, 20 (26): 5507–5509. doi:10.1021/om010881y.

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参见

参考资料

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