跳至內容

有機鍶化學

維基百科,自由的百科全書

有機鍶化學是研究-鍵的化合物的化學分支。

金屬鍶和鹵代烴反應,可以得到RSrX,在反應中通常會先加入碘、鎂或將鍶製成汞齊來活化。[1]用氯代烴和溴代烴反應的產率都較低。用二烴基汞和鍶反應,可以得到二烴基鍶:

Sr + R2Hg —THF→ R2Sr + Hg

金屬鍶和環戊二烯在液四氫呋喃或DMF中反應,可以得到二茂鍶[2][3]


參考資料

[編輯]
  1. ^ Bryce-Smith D, Skinner A C. J Chem Soc, 1963. 577-585
  2. ^ Fischer E O, Stölzle G. Chem Ber, 1961, 94. 2187-2193
  3. ^ Kirilov M, Petrov G, Angelov C. J Organomet Chem, 1976, 113: 225-232
pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy