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Chapter Practice Problems TCTD

This document contains multiple chemistry practice problems related to thermodynamics concepts like standard enthalpies of formation, heat capacities, work done by gases in isothermal and isobaric processes, heat transfer between bodies, and representation of processes on P-V diagrams. It asks the student to calculate thermodynamic quantities, match equations/graphs to explanations, and identify correct statements. The problems cover various thermodynamic cycles, processes and calculations.

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133 views3 pages

Chapter Practice Problems TCTD

This document contains multiple chemistry practice problems related to thermodynamics concepts like standard enthalpies of formation, heat capacities, work done by gases in isothermal and isobaric processes, heat transfer between bodies, and representation of processes on P-V diagrams. It asks the student to calculate thermodynamic quantities, match equations/graphs to explanations, and identify correct statements. The problems cover various thermodynamic cycles, processes and calculations.

Uploaded by

pankaj16fb
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOC, PDF, TXT or read online on Scribd
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CH

Chapter Practice Problems TCTD


Single Option Correct: (. Calc!late H *., 5or the reaction: * >i(s ? *H*O (l *;? (a@ ? *%H) (a@ ? H*(g 1i4en that the stan#ar# enthalpies o5 5ormation o5 >i?(a@ , OH)(a@ , H*O (l are )*7,.', )**,.. an# )*,'., kA mol)( respecti4el8 (all at *., k . (A );;+.*kA (B ;;+.*kA (C )7.+.*kA (6 none Calc!late the enthalp8 o5 4aporiBation o5 /O* at )*'oC, it the same at its <.p. (i.e. : (%oC <e '.'% cal mol)(. 1i4en that the molar heat capacit8 Cp(l C *%.& cal mol)( an# Cp(g C..+ cal mol)( (A &((..' cal mol)( (B '7,%.' cal mol)( )( (C '.'% cal mol (6 none
o

*.

+.

A sample o5 an i#eal gas with initial press!re $ an# 4ol!me 9 is taken thro!gh an isothermal process #!ring which entrop8 change is 5o!n# to <e /. The !ni4ersal gas constant is ". Then, the work #one <8 the gas is gi4en <8 (A
$9 / n"

(B n"/ (6
$ / n"T
$

(C $9 ;.

A thermo#8namic s8stem is taken 5rom state A to B along ACB an# is <ro!ght <ack to A along B6A as shown in the $ : 9 #iagram. The net work #one #!ring the complete c8cle is gi4en <8 the area (A $(ACB$*$( (B ACBB(A(A (C ACB6A (6 A6BB(A(A

$*

B C A 6

$( O

A(

B(

A ertion Rea on !"pe: (A (B (C (6 '. /tatement D is tr!e, statement DD is tr!eE statement DD is a correct e0planation 5or statement D. /tatement D is tr!e, statement DD is tr!eE statement DD is #O! a correct e0planation 5or statement D. /tatement D is tr!e, statement DD is 5alse /tatement D is 5alse, statement DD is tr!e. /tatement D : The enthalp8 o5 ne!traliBation o5 strong aci# an# strong <ase is alwa8s constant, which has 4al!e )(+.7 kcal mol)(. /tatement DD : Aci# <ase ne!traliBation alwa8s in4ol4e a common reaction : H?(a@ ? OH) (a@ H*O (l /tatement D: The enthalp8 o5 ne!tralisation o5 (e@. o5 HF an# ( e@. 2aOH is (; kcal mol)(, which is higher than HCl an# 2aOH. /tatement DD: The enthalp8 o5 h8#ration o5 F) is higher than that o5 its heat enthalp8 o5 #issociation.

&.

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Womens College, Arts Block , Circ!lar "oa#, "anchi, $h : %&'() *'&+(,7-,,-,.-.%. Ranchi (SOP, Doranda): /amri##hi Comple0, 1ro!n# Floor, 2ear /t. 3a4iers /chool, /o!th O55ice $ara 6oran#a, "anchi. Corp. off. : FIITJEE Ho!se *.)A, 7al! /arai, /ar4apri8a 9ihar, 2ew 6elhi : (&. $h : ;&(%&%%%-(%-(+-(', Toll Free 2o. (,%%((;*;*. Fa0 : %(()*&'(+.;*, We<:www.5iit=ee.com

CH Su%&ecti'e t"pe: 7.

( mole o5 an i#eal gas is allowe# to e0pan# isothermall8 at *' oC 5rom a press!re o5 ( atm to a press!re o5 %.( atm. Calc!late the change in thermo#8namic @!antities when..(A the gas e0pan#s re4ersi<l8 F (B when the gas e0pan#s in 4ac!!m. Heat s!pplie# to a cannot engine is ;'+.& 7cal. How m!ch !se5!l work can <e #one <8 the engine which work <etween %oC an# (%%oCG Calc!late the entrop8 change accompan8ing the trans5er o5 (%;&% =o!les o5 heat 5rom a <o#8 @ re4 ( T* T( ) A at +%%oC to a <o#8 B at 77oC. 2ote : Here / C . T( T*

,. ..

(atching t"pe: (%. Hatch the 5ollowing: Hatch the graph, e@!ations an# #ata o5 col!mn)D with the in5erence in col!mn)DD Colu)n * + Colu)n * ++ (A ($ Work #one C )' litre atm. A B (.% %.' $ (in atm C *% ;% 9 (in l (B (.% %.' $ (in atm *% ;% 9 (in l (" A#ia<atic change. $( . $* (6 An i#eal gas e0pan#s 5rom ; l to &l (/ Dsothermal change against a constant e0ternal press!re o5 *.' atm heats !p ( mole o5 water at *.+7. (sp. heat o5 water C ;.* Ag)(k)( (C W C )*.+%+ n"T log A B (I "epresentation o5 iso<aric process.

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Womens College, Arts Block , Circ!lar "oa#, "anchi, $h : %&'() *'&+(,7-,,-,.-.%. Ranchi (SOP, Doranda): /amri##hi Comple0, 1ro!n# Floor, 2ear /t. 3a4iers /chool, /o!th O55ice $ara 6oran#a, "anchi. Corp. off. : FIITJEE Ho!se *.)A, 7al! /arai, /ar4apri8a 9ihar, 2ew 6elhi : (&. $h : ;&(%&%%%-(%-(+-(', Toll Free 2o. (,%%((;*;*. Fa0 : %(()*&'(+.;*, We<:www.5iit=ee.com

CH A#S-.R ( & (A (B * 7 (B ('7, % + , (A ((*(.& ; . (C ((;.* ' (% (A (A)I,/ (B)I (C)/ (6)"

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