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Path to success KOTA (RAJASTHAN )

Path to success KOTA (RAJASTHAN)

RACE # 01 T HE RMOC HEM IS T RY PHYSICAL CHEMISTRY

Only One Correct Answer :

1. If temperature of the system remains constant during the course of change, the change is :
(a) isothermal (b) adiabatic (c) isobaric (d) isochoric
2. Thermodynamic equilibrium involves :
(a) chemical equilibrium (b) thermal equilibrium
(c) mechanical equilibrium (d) All the three
3. During an isothermal expansion of an ideal gas its :
(a) internal energy increases (b) enthalpy decreases
(c) enthalpy remains unaffected (d) enthalpy reduces to zero
4. Consider the reaction at 300 K
H2 (g) + Cl2 (g)  2HCl (g) ; Hº = – 185 kJ
If 2 mole of H2 completely react with 2 mole of Cl2 to form HCl. What is Uº for this reaction ?
(A) 0 (B) – 185 kJ (C) 370 kJ (D) – 370 kJ
5. The formation of water from H2(g) and O2(g) is an exothermic process because :
(a) the chemical energy of H2(g) and O2(g) is more than that of water.
(b) the chemical energy of H2(g) and O2(g) is less than that of water.
(c) the temperature of H2(g) and O2(g) is higher than that of water.
(d) the temperature of H2(g) and O2(g) is lower than that of water.
6. Reaction H2(g) + I2(g)  2HI; H = 12.40 kcal, according to this, heat of formation of HI will be:
(a) 12.40 kcal (b) –12.4 kcal (c) –6.20 kcal (d) 6.20 kcal
7. Heat evolved in calorie by the combustion of 1 gram of a fuel is called :
(a) its heat of combustion (b) its calorific value
(c) its heat of formation (d) none of these
8. A spontaneous change is one in which the system suffers :
(a) an increase in internal energy (b) lowering in entropy
(c) lowering in free energy (c) no energy change
9. The enthalpy change of a reaction does not depend on :
(a) State of reactants and products (b) Nature of reactants and products
(c) Different intermediate reactions (d) Initial and final enthalpy change of reaction
10. For which of the following change H  E ?
(A) H2(g) + I2(g)  2HI(g) (B) HCl(aq) + NaOH(aq)  NaCl(aq) + H2O()
(C) C(s) + O2(g)  CO2(g) (D) N2(g) + 3H2(g)  2NH3(g)
11. From Kirchoff's equation which factor effects the heat of reaction :
(a) Pressure (b) Temperature (c) Volume (d) Molecularity
12. The difference between heats of reaction at constant pressure and at constant volume for the reaction
2C6H6(l) + 15O2(g)  12CO2(g) + 6H2O(l) at 25ºC in kJ is :
(a) –7.43 (b) +3.72 (c) –3.72 (d) +7.43

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13. 2C  O 2  2CO; H  220 kJ Which of the following statement is correct for this reaction
(A) Heat of combustion of carbon is 110 kJ (B) Reaction is exothermic
(C) Reaction needs no initiation (D) All of these are correct
14. Change in enthalpy for the reaction,
2H2O2(l)  2H2O(l) + O2(g) is:
( ΔH of (H2O2) = –188 kJ mol-1, ΔH of (H2O) = –286 kJ mol-1)
(A) –196 kJ (B) +196 kJ (C) +948 kJ (D) –948 kJ
15. For which one of the following equations is ΔH oreact equal to ΔH of for the product?
(A) Xe(g) + 2F2(g)  XeF4(g) (B) 2CO(g) + O2(g)  2CO2(g)
(C) N2(g) + O3(g)  N2O3(g) (D) CH4(g) + 2Cl2(g)  CH2Cl2(l) + 2HCl(g)

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10
An s A D C D A D B C C D
Que. 11 12 13 14 15
An s B A B A A

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Path to success KOTA (RAJASTHAN )

Path to success KOTA (RAJASTHAN)

RACE # 02 T HE RMOC HEM IS T RY PHYSICAL CHEMISTRY

Only One Correct Answer :

1. The heat of combustion of yellow phosphorus and red phosphorus are –9.91 kJ and –8.78 kJ respectively.
The heat of transition of yellow phosphorus to red phosphorus is :
(a) –18.69 kJ (b) +1.13 kJ (c) +18.69 kJ (d) –1.13 kJ
2. If Hfº for H2O2(l) and H2O(l) are –188 kJ mol–1 and –286 kJ mol–1, what will be the enthalpy change
of the reaction 2H2O2(l)  2H2O(l) + O2(g)?
(a) 146 kJ mol–1 (b) –196 kJ mol–1 (c) –494 kJ mol–1 (d) –98 kJ mol–1
3. Given C(s) + O2(g)  CO2(g) ; H = –395 kJ
S(s) + O2(g)  SO2(g) ; H = –295 kJ
CS2(l) + 3O2(g)  CO2(g) + 2SO2(g) ; H = –1110 kJ
The heat of formation of CS2(l) is :
(a) 250 kJ (b) 62.5 kJ (c) 31.25 kJ (d) 125 kJ
4. Given,
NH3(g) + 3Cl2(g) NCl3(g) + 3HCl(g) ; –H1
N2(g) + 3H2(g) 2NH3(g) ; –H2
H2(g) + Cl2(g) 2HCl(g) ; H3
The heat of formation of NCl3(g) in terms of H1; H2 and H3 is :
(a) Hf = – H1 + 1
2 H2 – 3
2 H3 (b) Hf = – H1 + 1
2 H2 + 3
2 H3

(c) Hf = H1 – 1

2 H2 – 3
2 H3 (c) None
5. The enthalpies of formation of C2H2(g) and C6H6(g) at 298 K are –230 and –85 kJ mol–1, respectively.
The enthalpy change, H, for the reaction 3C2H2(g)  C6H6(g) at 298 K is:
(a) +205 kJ mol–1 (b) –205 kJ mol–1 (c) +605 kJ mol–1 (d) –605 kJ mol–1
6. Following enthalpy changes are given :
–D glucose(s)  –D glucose(aq) H = 10.72 kJ
–D glucose(s)  –D glucose(aq) H = 4.68 kJ
–D glucose(s)  –D glucose(aq) H = 1.16 kJ
Calculate enthalpy change in, –D glucose(s)  –D glucose(s)
(a) 14.24 kJ (b) 16.56 kJ (c) –7.2 kJ (d) 4.88 kJ
7. H2(g) + 1
2 O2(g)  H2O(g) H = x
H2(g) + 1
2 O2(g)  H2O(l) H = y
Heat of vapourisation of water is :
(a) x + y (b) x – y (c) y – x (d) –(x + y)

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8. When a certain amount of ethylene was combusted, 6226 kJ heat was evolved. If heat of combustion of
ethylene is 1411 kJ, the volume of O2 (at NTP) that entered into the reaction is :
(a) 296.5 ml (b) 296.5 litres (c) 6226 × 22.4 litres (d) 22.4 litres
9. The enthalpies of combustion of C(graphite) and C(diamond) are –393.5 and –395.4 kJ mol–1 respectively.
The enthalpy of conversion of C(graphite) to C(diamond) in kJ mol–1 is :
(a) –1.9 (b) –788.9 (c) 1.9 (d) 788.9
10. The standard heat of combustion of solid boron is equal to :

1 1
(a) Hfº (B2O3) (b) Hfº (B2O3) (c) 2Hfº (B2O3) (d) – Hfº (B2O3)
2 2
11. Give that,
C(s) + O2(g)  CO2(g), H° = –x kJ
2CO(g) + O2(g)  2CO2(g), H° = –y kJ
The enthalpy of formation of carbon monoxide will be:
y  2x 2x  y
(A) y - 2x (B) 2x - y (C) (D)
2 2
12. In the reaction
3
S(s) + O (g)  SO3(g) + 2x kcal
2 2
1
and SO2(g) + O (g)  SO3(g) + y kcal
2 2
the heat of formation of SO2 is:
(A) (x + y) (B) (x – y) (C) (2x + y) (D) (y – 2x)
13. Heat of combustion H° for C(s), H2(g) and CH4(g) are -94, -68 and -213 kcal/mol. Then H° for C(s) +
2H2(g)  CH4(g) is:
(A) –17 kcal (B) –111 kcal (C) –170 kcal (D) -85 kcal
14. S + O2  SO2 + x kcal ...(1)
1
SO2 + O  SO3 + y kcal ...(2)
2 2
The heat of formation of SO3 in above reaction is:
(A) –(x + y) (B) (x – y) (C) (2x – y) (D) (2x + y)
15. The enthalipies for the formation of C2H4(g), CO2(g) and H2O(l) at 25°C and 1 atm. pressure are 52, -394
and -286 kJ/mol respectively. The total enthalpy of combustion of C2H4(g) is:
(A) +1412 kJ/mol (B) -1412 kJ/mol (C) +141.2 kJ/mol (D) -141.2 kJ/mol

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10
An s D B D A C D B B C B
Que. 11 12 13 14 15
An s C D A A B

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Path to success KOTA (RAJASTHAN)

RACE # 03 T HE RMOC HEM IS T RY PHYSICAL CHEMISTRY

Only One Correct Answer :

1. The lattice energy of KCl is 202 kcal/mol. When KCl is dissolved in water 2 kcal/mol is absorbed. If the
sol energies of K+ and Cl– are in the ratio 2 : 3 then Hhydration of K+ is :
(a) –80 kJ/mol (b) –120 kJ/mol (c) –150 kJ/mol (d) 133.3 kJ/mol
2. The enthalpies of neutralization of HCl and HCN by NaOH are –55.9 and –12.1 kJ mol–1, respectively.
The enthalpy of ionization of HCN is :
(a) –43.8 kJ mol–1 (b) –68.8 kJ mol–1 (c) 43.8 kJ mol–1 (d) 68 kJ mol–1
3. Heat evolved when 1 gm equivalent of NH4OH is neutralised with 1 gm equivalent of H2SO4, is less than
the heat evolved when 1 gm equivalent of H2SO4 is neutralised with 1 gm equivalent of NaOH because:
(a) Heat of dissociation of NH4OH i.e., H has negative sign
(b) Heat is absorbed in the process of dissociation of NH4OH
(c) H2SO4 is a dibasic acid
(d) None of the above
4. Given,
S I
Na(s) 
 Na(g) Na(g) 
 Na+(g) + e–
D E
Cl2(g)  2Cl(g) Cl(g) + e–  Cl–(g)
U
Na+(g) + Cl–  NaCl(s)
(Letter above arrow () are energy parameters) Hf of NaCl is :

D
(a) S + I + D – E – U (b) S + I + + E + U
2

D D
(c) S + I + – E – U (d) S + I + – E + U
2 2
5. A solution of 500 mL of 0.2 M KOH and 500 mL of 0.2 M HCl is mixed and stirred; the rise in temperature
is T1. The experiment is repeated using 250 mL each of solution, the temperature raised is T2. Which of
the following is true :
(a) T1 = T2 (b) T1 = 2T2 (c) T1 = 4T2 (d) T2 = 9T1
6. The mutual heat of neutralisation of 40 gm NaOH and 60 gm CH3COOH will be :
(a) 57.1 kJ (b) less than 57.1 kJ (c) more than 57.1 kJ (d) 13.7 kJ
+ –
7. If H + OH  H2O + 13.7 kcal, then the heat of neutralisation for complete neutralisation of one mole
of H2SO4 by base will be :
(a) 13.7 kcal (b) 27.4 kcal (c) 6.85 kcal (d) 3.425 kcal
8. Heat of neutralisation for the reaction
NaOH + HCl  NaCl + H2O
is 57.1 kJ mol–1. What will be the heat released when 0.25 mole of NaOH is titrated against 0.25 mole
of HCl :
(a) 22.5 kJ mole–1 (b) 57.1 kJ mole–1 (c) 14.3 kJ mole–1 (d) 28.6 kJ mole–1

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9. Based on the following thermochemical equations :

H2O(g) + C(s)  CO(g) + H2(g) ; H = 131 kJ

1
CO(g) + O (g)  CO2(g) ; H = –282 kJ
2 2

1
H2(g) + O (g)  H2O(g) ; H = –242 kJ
2 2
C(s) + O2(g)  CO2(g) ; H = X kJ
The value of X will be :
(a) –393 kJ (b) –655 kJ (c) +393 kJ (d) +655 kJ
10. The heat of neutralisation of a strong acid and a strong alkali is 57.0 kJ mole–1. The heat released when
0.5 mole of HNO3 solution is mixed with 0.2 mole of KOH is :
(a) 57.0 kJ (b) 11.4 kJ (c) 28.5 kJ (d) 34.9 kJ
11. If the bond energies of H-H, Br-Br and H-Br are 433, 192 and 364 kJ mol-1 respectively, then H° for the
reaction:
H2(g) + Br2(g)  2HBr(g) is:
(A) -261 kJ (B) +103 kJ (C) +261 kJ (D) -103 kJ
12. Calculate the lattice energy for the reaction
Li+(g) + Cl–(g) — LiCl(s)
given that
Hsub (Li) = 160 ; Hdiss (Cl2) = 244 ; IP(Li) = 520 ;
EA (Cl) = –365 and DHf (LiCl) = – 400 (all in kJ mole–1)
(A) –837 (B) –959 (C) –1567 (D) –37
13. The enthalpy of formation of C2H6(g) is -2826 kJ mol . The bond energy of C-H bond is 416 kJ mol-1. The bond
-1

energy C-C is:

(A) 330 kJ/mol (B) -330 kJ/mol (C) 5312 kJ/mol (D) -5312 kJ/mol
14. The enthalpies of formation of C2H2(g) and C6H6(g) at 298 K are 230 and 85 kJ/mol respectively. The enthalpy
change for the reaction, 3C2H2(g)  C6H6(g):
(A) 605 kJ/mol (B) 865 kJ/mol (C) -605 kJ/mol (D) -865 kJ/mol
15. Given that bond energies of H – H and Cl – Cl and 430 kj mol–1 and 240 kj mol–1 respectively and  f H for HCl
is – 90kj mol–1, Bond enthalpy of HCl is :
(a) 290 kj mol–1 (b) 380 kj mol–1 (c*) 425 kj mol–1 (d) 245 kj mol–1

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10
An s A C B D A B B C A B
Que. 11 12 13 14 15
An s D A A C C

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