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SOLUTION TO MODEL TEST PAPERS

EVERGREEN MODEL TEST PAPER-1
Subject : CHEMISTRY
Class : 12
PART-I
Answer 1.
(a) (i) negative, more (ii) molality, mass of solvent
(iii) acidic, first (iv) acidic, neutral (v) pH, dilution
(b) (i) 3 (ii) 2 (iii) 4 (iv) 4 (v) 2
(c) (i) MgCl2 undergoes dissociation but urea does not. Number of particles produced is more in MgCl2, hence
depression of freezing point is more as it is a colligative property.
(ii) [OH] = 102 M
pOH = log [OH] = 2
pH + pOH = 14
pH = 14 pOH or pH = 14 2 = 12
(iii) Red litmus will turn to blue as the solution is basic due to weak acid acetic acid and strong base sodium
hydroxide.
CH3COO + Na+ + H2O ZZX CH3COOH + Na+ + OH
YZZ
(iv) One Mg+2 can displace two Na+1 from crystal lattice of NaCl during doping. Out of two empty spaces one is
occupied by Mg+2 and other remains empty. This is called impurity defect.
(d) (i) c (ii) d (iii) e (iv) a (v) b

PART-II
SECTION - A
Answer. 2
(a) (i) Molality = No. of moles of solute/1000 g of solution
0.4445 = No. of moles of cane sugar/1 kg of solution

0.445
n of cane sugar/ (n of cane sugar + n of water) = = 0.0079
1000
0.445 
18

Mole fraction of cane sugar = 0.0079

wRT
(ii) V = M
B

= osmotic pressure = 0.014 atm,

V = volume of solution = 100 mL = 0.1 L
w = mass of solute = 3.5 g, MB = Mol. mass of solute
M = molecular weight of solute = ?
R = gas constant = 0.0821 dm3 atm K1 mol1
T = temperature = 298 K

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3.5 .0821 298

Putting all values MB = = 61164.5 a.m.u.
0.014 0.1

(b) (i) Cu2+ + 2Cl + 2H2O Cu (OH)2 + 2H+ + 2Cl

or Cu2+ + 2H2O Cu(OH)2 + 2H+
As a result of hydrolysis, there will be an excess of H+ ions and solution will be acidic.
Na+ + Cl + H2O ZZX Na+ + OH + H+ + Cl
YZZ
ZZX H+ + OH
or H2O YZZ
No hydrolysis, occurs. [H+] = [OH]
Hence the solution will be neutral.
(ii) (1) Homogeneous equilibrium (both are solid).
(2) Heterogeneous equilibrium (ice solid but water liquid).
(3) Homogeneous (all three are gases).

Answer 3.
(a) (i) Units of k = mol 1 n l n1 s1 n = order of reaction
For zero order reaction, k = mol1l 1s1 (n = 0)
For first order reaction, k = s1 (n = 1)
For second order reaction, k = mol1l1s1(n = 2)

d 2d
(ii) r= [N 2 O5 ] = [NO2]
dt 2dt

1 2d
k1[N2O5] = k [N O ] = [O2]
2 2 2 5 2dt
= 2k3
or 2k1 = k2 = 4k3 = 2k3
(iii) Here generally some cations are missing from their lattice sites
and occupy interstitial sites

+ +
A B A B
+ +
B A B +A
+ A
A B B
+ +
B A B A

Example : ZnS
(b) Sodium chloride undergoes dissociation (as it is an electrolyte) but glucose cannot (non-electrolyte). Experimental
molecular wt. of NaCl will be half of its theoretical molecular wt. as number of ions product after dissociation
will be double. molecular wt. of glucose will be nearby same as theoretical molecular weight.
Answer 4.
(a) (i) Solubility = S
Total chloride ions solubility = S + 0.2
Ksp of AgCl = S(S + 0.2) = 1.2 1010
S = 6 1010 M
(ii) (1) 2O2 4e O2
Total quantity of electricity passed = 10 A (80 60 + 27) sec. = 48270 C

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4 96500 C electricity can produce 1 mole O2

48270 C can produce 0.125 mole
(2) Zn+2 + 2e Zn
Total charge = 48270 C
2 96500 C can form 65 g Zn
48270 C can produce = 16.125 g

0.0591 C
(iii) Ecell = Ecell  log anode
n Ccathode

Ecell = E of copper E of zinc = +0.34 (0.76) = 1.10 V

0.0591 0.55
Ecell = 1.10  log = 1.08825 V
2 0.22
(b) (i) Specific conductance decreases with dilution because number of ions per cc. decreases. For equivalent
conductance, it increases because for weak electrolyte dissociation increases. For strong electrolyte
dissociation is not so affected by dilution as it is already dissociated. There is a slight increase in equivalent
conductance due to decrease in interionic attractive forces with dilutions.
(ii) Solubility product value of PbS is low whereas that of ZnS is high. In acidic medium, dissociation of H2S is
suppressed due to common ion effect. The low conc. of sulphide ion is enough for PbS to exceed the
solubility product and precipitates but not enough for ZnS.

SECTION-B
Answer 5.
(a) (i) sodium hexafluoroaluminate (III)
(ii) hexaaminecobalt (III) chloride
(b) (i) Electronic configuration of iron, Fe : 1s2 2s2 2p6 3s2 3p6 3d6 4s2
(ii) In the complex ions, the central metal ion is Fe3+

Outer electronic cofiguration

3d 4s 4p
Fe3+ (ground state)

Fe3+ (excited state)

d2sp3

CN CN CN CN CN CN

3
CN

CN CN

Fe

CN CN
CN
Regular octahedral geometry, (d2 sp3)
It is paramagnetic due to one unpaired electron.
(c) Water, H2O

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Answer 6.
(a) (i) PbS + 4O3 PbSO4 + 4O2

(ii) SO2 + Cl2 }}m SO C1

hv
2 2
(iii) 2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 8H2O + 5O2
(iv) S + O2 SO2

2SO2 + O2 }}}}}
k}}}}
Pt, 1075K
}m SO 3

SO3 + H2SO4 H2S2O7 (oleum)

H2S2O7 + H2O 2H2SO4
(b) 3HCl + HNO3 NOCl + 2H2O + 2[Cl]
Pt + 4[Cl] PtCl4
2HCl + PtCl4 H2[Pt Cl6]
Answer 7.

The resonance structures of ozone

+ +
O O
(a) O
O O O
I II

(b) (i) The colour of halogens is due to absorption of visible light. This results in the excitation of valence electrons
to higher energy level. Value of excitation energy depends on size or IE which is maximum in fluorine due to
small size and minimum in iodine due to largest size.
(ii) As the atomic number increases, the added electrons enter to (n l)d sub shell and shield the outermost
electrons. The screening effect increases with increase in atomic number or number of d electrons. Thus, the
effect of increased nuclear charge due to increase of atomic number is neutralized by increased screening
effect.

SECTION-C
Answer 8.
(a) (i) CH3Cl + KCN CH3CN + KCl

CH3CN + 2H2O }}}m CH3COOH + NH3

H

(ii) C6H6 + CH3Cl}}}}}}mC H CH + HCl

Anhyd. AlCl3
6 5 3

C H CH + 3[O] }}}}}}}m C H COOH + H O

Alkaline KMnO4
6 5 3 6 5 2

(iii) C H OH + 2[O] }}}}}}}}} m CH COOH +H O

 K 2 Cr2O7 Dil. H 2SO4
2 5 3 2

2CH3COOH + Ca(OH)2 (CH3COO)2Ca + 2H2O

(CH3COO)2Ca }}}}}}m (CH ) CO + CaCO

Dry distillation
32 3
(b) (i) Vitamin A (ii) Vitamin C
(c) (i) Victor Meyer Test blood red colour for 1-propanol, blue colour for 2-propanol.
(ii) Urea gives positive result with Biuret test but benzoic acid does not.
Violet colouration with Biuret reagent for urea.
NH2CONH2 + NH2CONH2 NH2CONHCONH2 + NH3

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Answer 9.
(a) (i) Condensation , amino acid (ii) Addition, ethene
(b) Glucose aldehyde, fructose ketone
Bromine water test Glucose decolourise bromine water but fructose cannot.
Glucose + [O] }}}}}}m Gluconic acid.
Bromine water

(c) (i) (CH3)2CO, Iodoform reaction.

(ii) C3H7NC, Carbylamine reaction.

(d) (i) Aldol condensation : 2CH3CHO }}}}}m

Dil. NaOH
CH3CHOHCH2CHO (aldol)
(ii) Reimer-Tiemann reaction :

OH OH
CHO
%
+ CHCl3 + 3NaOH + 3NaCl + 2H2O
Phenol Salicylaldehyde

(iii) Rosenmunds reduction : CH3COCl + H2 }}}}}}m CH3CHO + HCl

Pd, BaSO4
Xylene, 413 K

C6H5COCl + H2 }}}}}}m C6H5CHO + HCl

Xylene, 413 K

Answer 10.
(a) A = CH3COOH, B = C2H5Br, C = C2H5CN, D = LiAlH4, E = C2H5CH2OH, F = CH3CH2COOH
(b) (i) Chain isomerism CH3CH2CH2CH3, CH3CH(CH3)CH3
(ii) Geometrical isomerism cis and trans

H C Cl H C Cl

C C
H Cl Cl H
Cis-isomer Trans-isomer

(iii) Functional isomerism CH3CH2CH2CH2OH, C2H5OC2H5

or Position isomerism CH3CH2CH2CH2OH, CH3CH2CH(OH)CH3
(c) A = Ethyl amine, B = Ethyl alcohol, C = Acetaldehyde, D = Acetic acid, E = Ethyl acetate.
(i) C2H5NH2 + HNO2 C2H5OH + N2 + H2O
C2H5OH + [O] CH3CHO + H2O
CH3CHO +Ag2O 2Ag +CH3COOH
CH3COOH + C2H5OH CH3COOC2H5 + H2O
(ii) CH3CHO + NH3 CH3 CH = NH + H2O
Acetaldemine

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EVERGREEN MODEL TEST PAPER-2

CHEMISTRY-12
PART-I
Answer 1.
(a) (i) positive, negative (ii) propanoic acid, methanol
(iii) ideal, Raoults (iv) oxidizing, electron affinities
(b) (i) 3 (ii) 3 (iii) 2 (iv) 2 (v) 1
(c) (i) C12H22O11 will have minimum osmotic pressure, as no. of particles, which is minimum in sucrose.
(ii) Ostwalds dilution law.
(iii) To deposit 27 g, 3 96500 C required to deposit 20.25 g = 217125 C
(iv) 1s2 2s2 2p6 3s2 3p6 3d5 4s1 Exactly half-filled 3d subshell is extra stable, hence one electron shifts
from 4s to 3d orbital.

(v) 2SO2(g) + O2(g) }}}}m 2SO (g)

NO (g)
3

(d) (i) e (ii) d (iii) a (iv) c (v) b

PART-II
SECTION - A
Answer 2.
(a) (i) Tb = 100.303 100 = 0.303 K
Tb = Kb m
0.303 = 0.5 m
m = 0.606
Again, Tf = Kf m = 1.87 0.606 = 1.133 K
Freezing point = 273 1.133 = 271.86 K
(ii) wB = 1g, w A = 100 g
1000 s wB
Tf = Kf .
wA s M B
MB = 30.96
NaCl Na+ + Cl

M normal 58.5
=1+=
M observed 30.96

= 0.88 or 88%

Twice as almost double the fraction of molecules possess

(b) (i) the threshold kinetic energy at 35C
Fraction of Molecules

25C
35C

Threshold
Energy

Kinetic Energy

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(ii) H2 + Cl2 }}}}m 2HCl

Sunlight

0.693
(iii) k =
half life

0.693
k= = 0.2772 hr1
2.5

2.303 160
t10 = log
k W

2.303 160
10 = log
0.2772 W
W = 10.01 g.

Answer 3.
(a) (i) Loss in conc. of A in 1 hour = 0.6 0.5 = 0.1 mol
Gain in conc. of B in 1 hour = 0.2 0 = 0.2 mol
(1) Since 0.1 mole of A changes to 0.2 mol of B, so n = 2

[B]n (0.6)2
(2) Equilibrium const. k = = = 1.2 mol L1
[A] (0.3)

0.1
(3) Rate of conversion = = 0.1 mol L1 hour1
1

d [N 2 O5 ] 1 d [NO 2 ] 2d [O 2 ]
(ii) = =
dt 2 dt dt
Substituting the values, we get

1
k1 [N2O5] = k [N O ] = 2k3 [N2O5]
2 2 2 5
2k1 = k2 = 4k3
(iii) Rate constant increases with the increase of temperature.
(b) Sodium chloride undergoes dissociation (as it is an electrolyte) but sucrose cannot (non-electrolyte). Experimental
molecular weight of NaCl will be half of its theoretical molecular weight as number of ions produced after dissociation
will be double, but molecular mass of sucrose will be almost same as its theoretical molecular mass.
Answer 4.
(a) (i) In Schottky defects in a crystal of type A+B, equal no. of A+ and B ions are missing from their lattice
sites. Thus, the stoichiometry of the crystal remains unchange and crystal remains electrically neutral
For example Na+Cl.
1
(ii) bcc = 8 s +1=2
8

1 1
fcc = 8 s  6 s =4
8 2
(iii) In graphite, central carbon atom is covalently linked with three more carbon atoms and fourth one is free.
In graphite, the hexagonal layers are held together by weak van der Waals forces of attraction and then
layers can readily slip over each other. Therefore, graphite is soft and can be used as lubricant.
(b) (i) D < C < A < B
1 1 1
(ii) pH = (pKw + pKa pKb) = (log 1014 +3.8 4.8) = (14 + 3.8 4.8) = 6.5
2 2 2
(iii) Nature of metal electrode, concentration of metal ions in solution and temperature.
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SECTION-B
Answer 5.
(a) (i) Sodium hexafluoroaluminate (III)
(ii) Hexaamine cobalt (III) chloride
(b) (i) d2sp3, Octahedral
(ii) Diamagnetic because there is no unpaired electron.
(c) Fluoride ion (F)
Answer 6.
(a) (i) Cr+2 (3d4) is less stable than Cr+3(3d3), therefore, it loses electrons easily. Hence, it is a good reducing agent.
Mn+2(3d5) is stable due to half-filled d-orbital, therefore, it is not a reducing agent.
(ii) Cu+, Ag+ are colourless because they do not have unpaired electrons.
(b) (i) 2KI + H2O + O3 2KOH + I2 + O2

(ii) SO2 + Cl2 }}}}m

Sunlight
SO2Cl2
(iii) 2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 8H2O + 5O2
Answer 7.
(a) (i) 3HCl + HNO3 NOCl + 2H2O + 2[Cl]
Au + 3Cl AuCl3
AuCl3 + HCl H[AuCl4]
F
(ii) F F

Xe sp d
3 2

F F
F
Distorted octahedral geometry
(b) (i) Lanthanides = +3 (ii) Actinides = +3

SECTION-C
Answer 8.
+
N2 Cl Cl
Cu, HCl
(a) (i) + N2
Benzene Chlorobenzene
diazonium
chloride
(ii) When conc. sodium hydroxide (NaOH) reacts with formaldehyde (HCHO), the product formed is sodium
formate (HCOONa) and methanol (CH3OH). HCHO undergoes Cannizarros reaction as follows:
2HCHO + NaOH HCOONa + CH3OH
(b) (i) CH3 CH2 OH + Cl2 CH3 CHO + 2HCl
CH3 CHO + 3Cl2 CCl3 CHO + 3HCl
2CCl3 CHO + Ca(OH)2 2CHCl3 + Ca(COOH)2
NH 3 NH2
Br Br
(ii) + 3Br2 (aq) + 3HBr

Br
NO2 NO2

+ Br2 Fe + HBr
Br
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(c) (i) Victor Meyer Test blood red colour for 1-propanol, blue colour for 2-propanol.
(ii) Urea gives positive result with Biuret test but benzoic acid does not.
Violet colouration with Biuret reagent for urea.
NH2CONH2 + NH2CONH2 NH2CONHCONH2 + NH3
(d) Hexamethylenediamine and adipic acid.
Answer 9.
(a) (i) Condensation, amino acid (ii) Addition, ethene
(b) Glucose aldehyde , fructose ketone
Bromine water test Glucose decolourise bromine water but fructose can not.
Glucose + [O] }}}}}}m Gluconic acid.
Bromine water

(c) A = C6H5CH3 (Toluene), B = C6H5CHO (Benzaldehyde),

C = C6H5CH2OH (Benzyl alcohol), D = C6H5COONa (Sodium benzoate)
(d) (i) The Benzoin condensation is a coupling reaction between two aldehydes that allows the preparation of -
hydroxyketones. The first method was only suitable for the conversion of aromatic aldehydes.

O O

CN
H
H2O / EtOH OH 92%
Benzoin

(ii) C 2 H 5 Cl  NaI }}}}m C H I  NaCl

Acetone
2 5

(iii) Wurtz reaction reaction between alkyl halides in the presence of sodium and dry ether medium to form
alkane.

CH3 Cl + 2Na + Cl CH3 }}}}m CH CH + 2NaCl

Dry ether
3 3
Answer 10.
+
Cl2, hv H /H2O
(a) (i) C H C2 H 5 Cl KCN
C 2 H 5 CN C2H5COOH
2 6 HCl

(ii) C 6 H 5 NH 2 }}}}}}m C H N  Cl }}}}m C H CN }}}m

NaNO / HNO 2
6 5 % 2

C H COOH
CuCN
6 5
H3O 
6 5

(b) (i) Position isomerism CH3 CH2 CH2 Cl and CH3 CH CH3

Cl
(ii) Geometrical isomerism cis and trans isomers
H C Cl H C Cl

C C
H Cl Cl H
(cisisomer) (transisomer)
(iii) Functional or position isomerism CH3CH2CH2CH2OH, C2H5OC2H5
Or
CH3CH2CH2CH2OH, CH3CH2CH(OH)CH3
(c) A = Ethyl amine, B = Ethyl alcohol, C = Acetaldehyde, D = Acetic acid, E = Ethyl acetate.
C2H5NH2 + HNO2 C2H5OH + N2 + H2O
C2H5OH + [O] CH3CHO + H2O
CH3CHO +Ag2O 2Ag +CH3COOH
CH3COOH + C2H5OH CH3COOC2H5 + H2O
CH3CHO + NH3 CH3 CH = NH2 + H2O
Acetaldimine

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EVERGREEN MODEL TEST PAPER-3

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) sigma-bonded (ii) two
(iii) 2,4,6-Trinitrophenol (iv) sp 2
(v) Ethyl alcohol and Dimethyl ether
(b) (i) 3 (ii) 3 (iii) 3 (iv) 2 (v) 1
(c) (i) (a) Addition of ferric chloride solution (b) Iodoform test
(ii) Boiling point of NaCl is more due to more number of particles due to ionisation and elevation in boiling point
is a colligative property.
(iii) p-Nitrophenol, due to intermolecular hydrogen bonding.
(d) (i) b (ii) a (iii) c (iv) e (v) d

PART-II
SECTION - A
Answer 2.
(a) Catalyst is a substance which alters the rate of a chemical reaction without itself being used up and can be
recovered unchanged chemically at the end of a reaction.
Homogeneous catalysis

2CO + O2 }}}}m 2CO

NO ( g )
2
Heterogeneous catalysis

N2 + 3H2 }}}}m 2NH

Fe, Mo
3
(b) Strongest HF, weakest NH3 due to electronegativity differences.
(c) In hcp and ccp arrangement of spheres, some spaces or sites are left vacant, which are called voids.
The void surrounded by four spheres having tetrahedral arrangement is called tetrahedral voids or hole. The void
surrounded by six spheres arranged at the corners of a regular octahedron is called octahedral void.
Answer 3.

0.693 0.693 0.693

(a) (i) k = k1 = min1 k2 = min1
t1/ 2 20 5

k E a T2  T1
log 2 
k1 2.303R T1T2

Ea = 24.210 kJ mol1
(ii) Rate constant depends upon temperature and nature of reactants. For a particular reaction rate constant
value increases with an increase in temperature. This unit of rate constant depends upon the order of a
reaction.
(b) (i) Calcium chloride decreases the freezing point of snow. Therefore, snowmelts. Due to this calcium chloride
is used to clear snow on road.

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(ii) Tb = Kb m
Tf = Kf m
0.186 = 1.86 m
t = 0.512 m

0.18 1.86
=
t 0.512

0.186 s 0.512
t =
1.86
= 0.0512
Tba = 100 + 0.0512
= 100.0512 K
(c) Arrhenius equation :
Ea

k = A. e RT

k - rate constant
A - Arrhenius constant
Ea - Activation energy
R - universal gas
T - temperature
It is a proportionality constant and is equal to the rate of reaction when the molar concentration of each of
reactants is unity.
Unit of rate constant = sec1
A = Arrhenius constant or frequency factor.
It indicates the frequency of binary collisions of reactant molecules per second per litre.
Unit = sec1
E = Activation energy.
It is the excess energy that the reactant molecules (having energy less than threshold energy) must acquire in
order to cross the energy barrier and to change into the products.
Unit = J mol1 or cal mol1
R = Gas constant
Unit = 8.314 J mol1 K1 = 1.987 cal mol1 K1
T = Temperature
Unit = Kelvin (K)
Answer 4.
(a) (i) Reversible (ii) Exothermic
2
p NH 3

(iii) kp = 3
(iv) Law of chemical equilibrium
p N 2
pH 2

(v) Finely divided iron (vi) Heterogeneous

(vii) Maximum interaction due to large surface area
(b) PbCl2 ZZX Pb2+ + 2Cl
YZZ
S S 2S (S = Solubility in mol L1)
Ksp = (S) (2S)2 = 4S3
= 4 (1.5 1010)3
= 4 3.375 1030
= 13500 1030 = 1.35 1026

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SECTION-B

Answer 5.

(a) F F

Xe sp3 d 2

F F

Square Planar Geometry

(b) (i) Greater electronegativity of oxygen than sulphur, so strong hydrogen bond in H2O, stays as associated
molecules, hence liquid. In H2S, there are weak van der Waals forces of attraction, It has low boiling point
and is gas at room temperature.
(ii) Halogens are in short of electron to complete octet and hence strong tendency to share its unpaired electron
with another atom of same halogen to form diatomic molecule.

X X

Whereas noble gas atoms are stable, do not react with other and do not form diatomic molecule.
Answer 6.
(a) (i) Ni (28) = [ Ar] 3d8 4s2
Ni+2 [Ar] 3d8 4s0 4p0
[Ni(CN)4 ]2
Shape : Square planar
Magnetic property : Diamagnetic (_ there is no unpaired electron)
Hybridization : dsp2
(ii) cis and trans. isomers.
(b) (i) 2Na2S2O3 + I2 Na2S4O6 + 2NaI
(ii) Cl2 + 2NaOH NaCl + NaClO + H2O
Answer 7.
(a) Two halogens mutually combine with one another and form a series of compounds called interhalogen compounds.
The general formula of the interhalogen compound is XYn, where X and Y are halogens and n is an integer having
values 1, 3, 5 and 7. X is always larger halogen atom and Y is smaller halogen atom. The oxidation state of X is +1,
+3, +5, or +7 depending upon the value of n but the oxidation stat of Y is always 1.
(b) (i) [Co(NH3)4Cl2]Cl. Its IUPAC name is tetraaminedichlorocobalt (III) chloride.
(ii) Square planar and octahedral complexes show geometrical isomerism.

SECTION-C
Answer 8.
(a) C2H6O is formed by hydrolysis of X. An alcohol is obtained by hydrolysis of an ether.
X is an ether.
C2H5 OC2H5 + H2O 2C2H5OH + [O] CH3CHO + H2O
CH3CHO CH3CHOHCH2CHO + [O] CH3CHOHCH2COOH
X = Diethyl ether (ethoxy ethane)
Y = Acetaldehyde

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Z = Aldol ( 3Hydroxybutanal)
W = 3Hydroxybutanoic acid.
(b) (i) Due to oxidation phenol turns pink on exposure to air. Phenol forms complex mixture products on oxidation.
One of the oxidation product is quinone which give a brilliant red addition product with phenol by hydrogen
bonding called phenoquinone.
C6H 5OH + O2 Quinone + H2O
Quinone + 2C6H 5OH Phenoquinone
(ii) Monosaccharide : glucose, fructose
Disaccharide : Sucrose
Polysaccharide : Starch, Cellulose
(iii) Example of :
Co-polymer : Nylon 66 (adipic acid and hexamethylene diamine).
Synthetic polymer : Terylene, Dacron.

(c) (i) C6H 6 + HNO3

(conc.)
}}}}}}
%
m C H NO +H O
H 2SO 4 Conc.
6 5 2 2

}}}}}}m C H ClNO +HCl

C6H5NO2 + Cl2
Anhyd. FeCl3
6 4 2

C H OH + Zn }}} m C H + ZnO
Heat
(ii) 6 5 6 6
(iii) C6H5Cl + KCN C6H5CN + KCl
C6H5CN + 2H2O C6H5COOH + NH3
Answer 9.
(a) (i) Globular proteins have a : cross linked bonding and
weak intermolecular hydrogen bonding.
(ii) DNA RNA
1. It contains deoxyribose sugar. 1. It contains ribose sugar.
2. It contains thymine as pyrimidine base. 2. It contains uracil as pyrimidine base.
3. It has double helix structure. 3. It has single helix structure.
4. It can replicate. 4. It cannot replicate.

Nucleic acids are long chain polymers and they are present in the nucleic of cells. RNA and DNA are two
types of nucleic acid.
(b) (i) The sugar units present in DNA is D-2 deoxyribose and in RNA is D- ribose.

(ii) Enzyme Deficiency Diseases

1. Phenylalanine hydrolase. 1. Phenylketonurea.

2. Tryosinase. 2. Albinism.

(iii) Water soluble vitamins are vitamin B1 (Thiamine), Vitamin B2 (Riboflavin),

Vitamin B6 (Pyridoxine), Vitamin B12 (Cyanocobalamine), Vitamin C (Ascorbic acid).
(c) Both substitution and oxidation reaction take place when phenyl hydrazine reacts with glucose.

OH OH
HO H
N N
HO HO

The product name is Glucose phenylhydrazone.

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Answer 10.

+O H +O H +O H
(a) OH OH

(b) (i) CH3CONH2 +Br2 + 4NaOH

(aq.)
}}m
% CH NH + 2NaBr +Na CO +2H O
3 2 2 3 2

(ii) 2C6H5CHO }}}m C H CO CHOH C H (Benzoin)

KCN
6 5 6 5

(iii) C H + CH Cl }}}}}}
6 6 3 m C H CH + HCl
Anhyd. FeCl3
6 5 3

(iv) 2HCHO + NaOH (Conc.) HCOONa + CH3OH

2C6H5CHO +NaOH (Conc.) C6H5COONa + C6H5CH2OH
(c) A = Conc. nitric acid and conc. sulphuric acid.
B = Tin and conc. hydrochloric acid.
C = Hydrochloric acid.
D = Sodium nitrite and hydrochloric acid (nitrous acid) at 0 C.

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EVERGREEN MODEL TEST PAPER-4

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) cannot, rate (ii) anion vacancies, crystal
(iii) above, below (iv) oxidation, benzoic acid
(v) ionization , decreases
(b) (i) 3 (ii) 2 (iii) 1 (iv) 1 (v) 3
(c) (i) 12.
(ii) No, Number of particles will be more for sodium chloride.
(iii) p-Nitrophenol, due to intermolecular hydrogen bonding.
(iv) Toluene can be nitrated more easily because of the presence of ring activating group.
(v) (a) Addition of ferric chloride solution. (b) Iodoform test.
(d) (i) b (ii) a (iii) c (iv) e (v) d

PART-II
SECTION - A
Answer 2.
(a) (i) T1 = 273 K
T2 = 273 + 37 = 310 K
Eact = ?

k2 r2
k1 = r =2
1

k2 E act T2 T1
log =
k1 2.303R T1 T2

E act 310 300

log 2 = 310 s 300
8.314
2.303 s
1000

E act 10
0.3010 = 8.314 310 s 300

2.303 s
1000
Eact = 51.48 kJ mol1

(ii) Temperature, concentration, Presence of a catalyst.

(b) (i) Calcium chloride decreases the freezing point of the snow.
(ii) w B = 2.5g
w A = 100g
Tb = 0.42C
Kb = 2.67 Kkg mol1
MB = ?

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wB s 1000
Tb = Kb .
M B wA

2.5 s 1000
0.42 = 2.67
M B s 100

2.67 s 2.5 s 1000

MB = 042 s 100
= 158.9 amu
(c) Molecularity of a simple reaction is the number of species which collide together to bring about a reaction.
Order is the sum of the powers to which concentration terms are raised in the rate law for a reaction.
Answer 3.
12
(a) No. of moles of water = = 0.67
18

108
No. of moles of acetic acid = = 1.8
60

92
No. of moles of ethyl alcohol = =2
46

0.67
xH2 O =
0.67  1.8  2.0 = 0.15

(b) Strongest HF, weakest NH3, due to electronegativity differences.

(c) (i) When the product during the reaction is able to catalyse the reaction, it is known as autocatalysis.
(ii) The solution will contain excess of hydronium ion.
(iii) When oil or fats are heated with an alkali they are hydrolysed to form the sodium salt of higher fatty acids
called soap, this reaction is called saponification.
Answer 4.
(a) (i) Due to hydrolysis there will be excess OH ions
CH3COO + Na+ + H2OZZX CH3COOH + Na+ + OH
YZZ
ZZX CH3COOH + OH
or CH3COO + H2O YZZ
(ii) Due to presence of common H+ ions.
(iii) Due to formation of silver chloride, which is insoluble in water.
(b) CH3COOH ZZX CH3COO + H+
YZZ
C O O
C(1 B) CB CB

[H+] = C
0.002 s 2.0
=
100
[H ] = 4.0 105 M
+

pH = log[H+]
= [log 4.0 5 log10]
= 5 0.4771
= 4.5229
(c) (i) 4 times (ii) times (iii) 81 times

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SECTION-B
Answer 5.
(a) Br2 + H2O + Na2 SO3 Na2SO4 + 2HBr

(b) (i) F Xe F (ii) sp 3d

(iii) Linear
Answer 6.
(a) (i) The central metal ion is Nl2+ (3d8)

3d 4s 4p
2+
Ni(es) dsp2

2
[Ni(CN)4] dsp2

CN CN CN CN

[Ni(CN)4]2 has a square planar geometry.

Also it is diamagnetic because it has no unpaired electron.

2
NC CN

Ni

NC CN

(ii) cisdiammine dichloridoplatinum (II) and

transdiammime dichlorido platinum (II)
(b) (i) 2Na2S2O3 + I2 Na2S4O6 + 2NaI (ii) Cl2 + 2NaOH NaCl + NaClO + H2O
Answer 7.
(a) When a bidentate or a polydentate ligand is attached by two or more donor atoms to the same central metal ion
forming a ring structure, the ligand is called a chelating ligand.The resulting complex is called a chelate complex.
(b) (i) [Co(NH3)4Cl2]Cl, tetrammine dichlorido cobalt (III) chloride
(ii) (2) square planar.

SECTION-C
Answer 8.
(a) C2H6O is formed by hydrolysis of X. An alcohol is obtained by hydrolysis of an ether.
X is an ether.
C2H5 OC2H5 + H2O 2C2H5OH

C2H5OH + (O) }}}}}}m CH3CHO + H2O

K 2 Cr2 O 7 / H 

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CH3CHO }}}}}m CH CHOHCH CHO + }}}m CH CHOHCH COOH

Dil. NaOH
3 2
[O]
3 2
X = Diethyl ether (ethoxy ethane)
Y = Acetaldehyde
Z = Alodol (3Hydroxybutanal)
W = 3Hydroxy butanoic acid
(b) (i) Lone pair on N will attack the electrophile.
(ii) The organic compounds that cannot be produced in the body and must, therefore, be supplied in small
amounts in the diet for the good health and maintenance of animal body.
(iii) It is present in the nucleus of the living cell. It directs the synthesis of protein. They are responsible for the
transfer of genetic information.
(c) (i) Using sodalime.
(ii) Using lithium aluminium hydride.
(iii) Using MnO.
Answer 9.
(a) (i) (a) Globular proteins have :
Intermolecular Hbonds

(ii)

(b) (i) Adenine, Guanine, Cytosine, Thymine.

(ii) Enzyme deficiency Diseases
1. Phenylalanine hydrolase. 1. Phenylketonuria.
2. Tryosinase. 2. Albinism.
(iii) Vitamins-A, D, E, K
(c)
NHNH2
CHO CH = N NHC6H5
(CHOH)4 + (CHOH)4 + H2O
Water
CH2OH CH2OH
Glucose Glucose phenyl hydrazone

Answer 10.
NH2 + NH + NH + NH NH2
2 2 2

(a)

I II III IV V
(b) (i) Aldol condensation

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O OH O

HO
2CH3 C H CH3 C CH2 C H

H
Acetaldol

(ii) Benzoin condensation

O O

CN
2 H
H2O / EtOH OH
92% Benzoin

(iii) Friedel craft acylation

CH3
+CH 3Cl
+ HCl
AlCl3 catalyst, reflux
anhydrous conditions

(iv) Esterification reaction

O O
H ,%
+

CH3 C + CH3CH2OH Cl3 C + H2O

OH O CH2CH3

(c) A-oleum, B-conc. Sodium hydroxide, C-dil. acid/water, D CHCl3 + KOH

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EVERGREEN MODEL TEST PAPER-5

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) increases, lowering (ii) decreases
(iii) above, below (iv) oxidation, benzoic acid
(v) ionization, suppressed
(b) (i) 3 (ii) 1 (iii) 3 (iv) 2 (v) 4
(c) (i) FeCl3, because it has maximum number of particles in aqueous solution. (Osmotic pressure is a colligative
property)

1
(ii) 1 8 s  1

8

(iii) Ostwald dilution law.

(iv) The sum of the powers of the concentration terms in the rate law for a reaction.
(v) Chain, position, functional and geometric isomerism.
(d) (i) e (ii) d (iii) b (iv) c (v) a

PART-II

SECTION - A
Answer 2.
(a) It is a substance which can alter the rate of a reaction but itself remains unchanged in mass and composition
at the end of a reaction.

Homogeneous 2CO + O2 }}}m 2CO (catalyst is nitric oxide)

NO
2

Heterogeneous N2 + 3H2 }}}m 2NH (catalyst is iron dust)

k}}}
FeMo
3

(b) NH 4 HF and H3O+

(c) There are the vacant spaces left in a crystal as a result of closed packed structure.
Tetrahedral void : It is a void surrounded by four spheres (atoms) whose centres lie at the corners of a regular
tetrahedron.
Octahedral void : It is a void surrounded by six spheres (atoms) whose centres lie at the corners of a regular
octahedron.
Answer 3.
(a) (i) Given, [H+] = 3.8 103 M
pH value of soft drink = log [H+]
= log (3.8 103)
= log 3.8 log 103
= 0.58 + 3
= 2.42

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(ii) Relative lowering of vapour pressure is equal to the mole fraction of non-volatile solute.

%p 4
 0.1
= xB =
po 40

This means solution has 0.1 moles of solute present in 0.9 moles of water. Therefore, the mass of water in the
solution = No. of moles of water Molecular weight of water
= 0.9 18 = 16.2 g

Moles of solute 0.1

Molality of solution =   6.17 m
Mass of solvent in kg 16.2
1000

(b) (i) This is because in diamond there are strong covalent bonds and there is no free electrons left will any carbon
atoms as all the four valence electron of each carbon atom are involved in bond formation.
(ii) Nature of metal electrode, concentration of metal ions in solution and temperature
(iii) Given p = 0.850 bar, p = 0.845 bar
Molar mass of solvent (M1) = 78 g mol1
Mass of solvent w 1 = 39 g
Mass of solute w 2 = 0.5 g

po  p w2 M 1
=
po M 2 w1

1
(0.850  0.845) 0.5 s 78 g mol
=
0.850 M 2 s 39

M 2 = 170 g mol1
Answer 4.
(a) (i) During the formation of cuprous oxide at anode, Cu gets oxidized to Cu+1 which combines with O2 to form
Cu2O.
2Cu 2Cu+1 + 2e
O2 + 2e O2

2Cu + O2 2Cu+ + O2
Or Cu2O
Thus, there is involvement of two electrons i.e., 2F or 2 96500 C of electricity in the formation of one mol i.e.,
1, 43 g of Cu2O.
Quantity of electricity actually passed = 0.965 A 2500 s = 2412.5 C

143
Mass of Cu2O formed by 2412.5 C of electricity = s 2412.5 = 1.7875 g
2 s 96500

(ii) Molar conductance increases with increase in temperature.

(b) (i) Anodic reaction : Cu 2e Cu2+
Cathodic reaction : 2Ag+ + 2e 2Ag

Cell reaction : Cu + 2Ag+ Cu+2 + 2Ag
(ii) pH of the buffer before adding HCl

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[salt] 0.25
pH = pKa + log = log (1.8 105) + log
[Acid] 0.2

= (5 0.2552) + 0.0969
= 4.7448 + 0.0969
= 4.8417
After addition of 0.05 mol of HCl
[CH3COOH] = 0.2 + 0.05 = 0.25
[CH3COONa] = 0.25 0.05 = 0.20

[Acid] 0.25
Now, pH = 4.7448 log = 4.7448 log
[Salt] 0.2

= 4.7448 0.0969
= 4.6479
Change in pH = 4.8417 4.6479
= 0.1938
(c) (i) When oil and fats are heated with an alkali, they are hydrolysed to form the sodium salt of higher fatty acids
called soap. This reaction is called saponification.
(ii) When the product during the reaction is able to catalyse the reaction, it is known as auto catalysis.
(iii) Because no hydrolysis occurs.

SECTION-B
Answer 5.
(a) Ionization isomerism
(b) [Co(NH3)5Cl]SO4 gives white precipitate with BaCl2 solution but no precipitate with AgNO3 solutions whereas
[CO(NH3)5SO4]Cl gives no precipitate with BaCl2 solution but white precipitate with AgNO 3 solution.

[Co(NH3)5Cl] SO4 + Ba2+ BaSO 4 n

White precipitate

[Co(NH3)5Cl] SO4 + Ag+ No reaction

[Co(NH3)5SO4] Cl + Ba2+ No reaction

[Co(NH3)5SO4] Cl + Ag+ AgCl n

White precipitate

Cl NH3 Cl NH3
Pt Pt
(c) Cl NH3 H3N Cl
cis-isomer trans-isomer

(d) (i) [PtCl2(en)2] (NO3)2 (ii) Fe4 [Fe(CN)6]3

Answer 6.
(a) Linkage isomers can exist when one or more ambidentate ligands is bonded to a metal ion.
[Co(NH3)5 (SCN)]2+ and [(Co(NH3)5(NCS)]2+
(b) Ni (28) = [ Ar] 3d8 4s2
Ni+2 [Ar] 3d8 4s0
In [Ni(CN)4 ] 2 there is dsp2 hybridisation of Ni2+ ion.
Shape : Square planar
Magnetic property : Diamagnetic
Hybridization : dsp2
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Answer 7.
(a) (i) 3HCl + HNO3 = NOCl + 2H2O + [2Cl]
Pt + 4[Cl] = PtCl4
PtCl4 + 2HCl H2[PtCl6]

F Xe F

Linear molecule

Xe in XeF2 is in sp3d hybridisation state.

(b) (i) PbS + 4O3 PbSO4 + 4O2
(ii) 2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 8H2O + 5O2

SECTION-C
Answer 8.
(a) C2H6O is formed by hydrolysis of A. An alcohol is obtained by hydrolysis of an ether.
A is an ether.

}}}m 2C2H5OH }}}

C2H5 OC2H5 + H2O (O)
m CH3CHO +H2O
H

CH3CHO }}}m CH3CHOHCH2CHO }}}

OH (O)
m CH3CHOHCH2COOH
A = Diethyl ether (ethoxy ethane)
B = Acetaldehyde
C = 3 Hydroxy butanal (aldol)
D = 3Hydroxy butanal acid
(b) (i) Due to oxidation phenol turns pink on exposure to air. Phenol forms complex mixture products on oxidation.
One of the oxidation product is which gives a brilliant red addition product with phenol by hydrogen
bonding called phenoquinone.
C6H5OH + O2 Quinone + H2O

E+ E


E
E+
Quinone + 2C6H 5OH Phenoquinone, OHO= =OHO

(ii) Monosaccharide : Glucose, fructose

Disaccharide : Sucrose
Polysaccharide : Starch, Cellulose
(iii) Example of :
Co-polymer : Nylon 66 (adipic acid and hexamethylene diamine)
Synthetic polymer : Terylene, Dacron

(c) (i) C6H6 + HNO3 }}}}}}m C H NO + H O

(conc.) H 2SO4
6 5 2 2

C H NO + Cl }}}}}}}} m C H ClNO + HCl

(conc.) Anhyd. FeCl3
6 5 2 2 6 4 2

C H OH + Zn }}}
m C H + ZnO
Heat
(ii) 6 5 6 6
(iii) C6H5Cl + KCN C6H5CN + KCl
C6H5CN + 2H2O C6H5COOH + NH3

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Answer 9.
(a) (i) Globular proteins have intermolecular Hbonding.
(ii) DNA RNA
1. It contains deoxyribose sugar. 1. It contains ribose sugar.
2. It contains thymine as pyrimidine base. 2. It contains uracil as pyrimidine base.
3. It has double helix structure. 3. It has single helix structure.
4. It can replicate. 4. It cannot replicate.

Nucleic acids are long chain polymers and they are present in the nucleic of cells. RNA and DNA are two
types of nucleic acid.
(b) (i) The sugar units present in DNA is D-2 deoxyribose and in RNA is D- ribose.

(ii) Enzyme Deficiency Diseases

1. Phenylalanine hydrolase. 1. Phenylketonuria.

2. Tryosinase. 2. Albinism.

(iii) Water soluble vitamins are Vitamin B1 (Thiamine), Vitamin B2 (Riboflavin), Vitamin B6 (Pyridoxine), Vitamin
B12 (Cyanocobalamine), Vitamin C (Ascorbic acid).
(c) Starch is a polymer of -glucose units whereas cellulose is a polymer of -glucose units.

Answer 10.

OH +O H +O H +O H OH

(a)

(b) (i) CH3CONH2 + Br2 + 4NaOH

(aq)
}}m
% CH NH + 2NaBr +Na CO +2H O
3 2 2 3 2

(ii) 2C6H5CHO }}}m C H COCHOHC H

KCN
6 5 6 5

(iii) C6H6 + CH3Cl }}}}}m C H CH + HCl

Ahyd.AlCl3
6 5 3

(iv) 2HCHO + NaOH (Conc.) HCOONa + CH3OH

2C6H5CHO +NaOH (Conc.) C6H5COONa + C6H5CH2OH
(c) A = Conc. nitric acid and conc. sulphuric acid.
B = Tin and conc. hydrochloric acid.
C = Hydrochloric acid.
D = Sodium nitrite and hydrochloric acid (nitrous acid) at 0 5C.

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EVERGREEN MODEL TEST PAPER-6

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) Independent, reactant (ii) Anode, cathode
(iii) Cyanohydrins, -hydroxy carboxylic acid (iv) 0.05 F
(v) Fusion, helium
(b) (i) 2 (ii) 3 (iii) 3 (iv) 3 (v) 4
(c) (i) 12
(ii) Number of particles will be more for sodium chloride.
(iii) The flow of electrons will occur only momentarily. The voltage will drop to zero and the cell will stop working.
(iv) Toluene can be nitrated more easily because of the presence of ring activating methyl group.
(v) (a) addition of ferric chloride solution
(b) iodoform test
(d) (i) c (ii) e (iii) d (iv) a (v) b

PART-II
SECTION - A
Answer 2.
(a) (i) Tb = 100.303 100 = 0.303 K
Tb = Kb m
0.303 = 0.5 m
m = 0.606
Again, Tf = Kf m = 1.87 0.606 = 1.133 K
Freezing point = 273 1.133 = 271.86 K
(ii) wB = 1g, w A = 100 g

1000 s wB
Tf = Kf .
wA s M B

MB = 30.96
NaCl Na+ + Cl

M normal 58.5
=1+=
M observed 30.96

= 0.88 or 88%
Twice as many molecules possess
(b) (i) the threshold kinetic energy at 30C
Fraction of Molecules

TK
(T + 10)K

Threshold
Energy

Kinetic Energy

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(ii) H2 + Cl2 }}}}m 2HCl

Sunlight

0.693
(iii) k =
half life

0.693
k= = 0.2772
2.5

2.303 160
t10 = log
k W

2.303 32
10 = log
0.2772 W
W = 5 g.
Answer 3.
(a) (i) During the formation of cuprous oxide at anode, Cu gets oxidized to Cu +1 which combines with O2 to form
Cu2O.
2Cu 2Cu+1 + 2e
O2 + 2e O2

2Cu + O2 2Cu+ + O2 or Cu2O

1
Or 2Cu + O Cu2O
2 2
Thus, there is involvement of two electrons i.e., 2F or 2 96500 C of electricity in the formation of one mol
i.e., 143 g of Cu2O.
Quantity of electricity actually passed = 0.965 A 5000 s = 4825 C

143
Mass of Cu2O formed by 4825 C of electricity = s 4825 = 3.575 g
2 s 96500
(ii) Molar conductance increases with increase in temperature.
(b) (i) Anodic reaction : Cu 2e Cu2+
Cathodic reaction : 2Ag+ + 2e 2Ag

Cell reaction : Cu + 2Ag+ Cu+2 + 2Ag

= E Ag  E Cu

Ecell
= 0.80 0.34 = 0.46
(ii) pH of the buffer before adding HCl

[Salt]
pH = pKa + log
[Acid]

0.25
= log (1.8 105) + log
0.2
= (5 0.2552) + 0.0969
= 4.7448 + 0.0969
= 4.8417
After addition of 0.05 mol of HCl
[CH3COOH] = 0.2 + 0.10 = 0.30 M
[CH3COONa] = 0.25 0.10 = 0.15

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[Acid]
Now, pH = 4.7448 log
[Salt]

0.50
= 4.7448 log
0.15
= 4.7448 log2
= 4.7448 0.3010
= 4.3448
Change in pH = 4.8417 4.3448
= 0.4969
(c) (i) Salt of a strong acid and a weak base undergoes hydrolysis in water to give acidic solution.
e.g. Fe3+ + 3Cl + 3H2O ZZX Fe(OH)3 + 3H+ + 3Cl
YZZ
Or ZZX Fe(OH)3 + 3H+
Fe3+ + 3H2O YZZ
(ii) When the product during the reaction is able to catalyse the reaction, it is known as autocatalysis.
(iii) Acidic dehydration
When an alcohol is heated with conc. H2SO4 or H3PO4, it loses a molecule of water to give an alkene. This
reaction is called acidic dehydration.
CH2 CH2
}}}}}}
k}}}}}
Conc.H SO
433 443K
}m CH2 = CH2+ H2O
2 4

H OH

Answer 4.
(a) (i) 1 mole of water requires 2F electricity.

2H2O }}}}}m 2H + O
electrolysis
2 2
18g of water requires = 2 F

2 s 96500
t = (I = 2 amp)
2
= 96500s = 26.81 hrs.
(ii) Anodic reaction : Zn 2e Zn2+
Cathodic reaction : Cu2+ + 2e Cu

Ecell = ECu  EZn

= 0.34 ( 0.76)
= 1.10 V
(iii) A coulometer is an instrument, used to measure the quantity of electricity that flows in a given time by
connecting a silver or copper voltameter in series with the circuit.The working of a coulometer is based on
Faradays first law of electrolysis.
(b) 2H2O + 4e 2H2 + O2
Z = 2 (bcc)
a = 287 1010cm

3 a = 4r (for bcc)

3a 3 s 287
r = = pm
4 4
= 124.27 pm

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ZA
=
N 0a3

2 s 52
=
6.022 s 10 23
s (287 s 1010 )3

104 s 107
=
6.022 s (287)3
1040
=
6.022 s (287)3
= 7.3 g/cc
(c) Nature of electrolyte, concentration, temperature.

SECTION-B
Answer 5.
(a) It is the formation of ozonide (from alkene or alkyne) and its cleavage by heating will zinc dust and water to give
carbonyl compounds.
(b) (i) Oxidation number of S in H2SO4(+6) is higher than in H2SO3(+4)
(ii) Silicon dioxide acts as a flux and combines with ferrous oxide to form ferrous silicate as a slag.
(iii) In d-block elements electrons of both (n 1)d and ns orbitals take part in bonding. But in
f-block elements due to poor shielding effect of f electrons effective nuclear charge increases, therefore,
lesser number of oxidation states.
Answer 6.
3
(a) (i) In <Cr(NH3 )6 > the central metal ion is Cr3+
Cr3+ = 1s2 2s2 2p6 3s2 3p6 3d3
3d 4s 4p
3
Cr ( gs )

Cr3 (d 2 sp3 ) d 2 sp3

3
<Cr(NH3 )6 > d 2 sp3

NH3 NH3 NH3 NH3 NH3 NH3

Due to d2sp3 hybridization, the complex has regular octahedral geometry.
NH3
3+
H3N NH3

Cr

H3N NH3

NH3
There are 3 unpaired electrons
The complex is paramagnetic.
(ii) Cis and trans dichloridodioxalato cobaltate (III) ions.
(b) (i) K2Cr2O7 treated with sulphur dioxide.
K2Cr2O7 + H2SO4 + 3SO2 K2SO4 + Cr2(SO4)3 + H2O
(ii) Na2SO3 + Br2 + H2O Na2SO4 + 2HBr

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Answer 7.
(a) When a bidentate or a polydentate ligand is attached by two or more donor atoms to the same central metal ion
forming a ring, the ligand is called a chelating ligand.The resulting complex is called a chelate compound.
(b) (i) [Co(NH3)4Cl2]Cl its IUPAC name is tetramminedichlorocobalt (III) chloride.

H3N
+
H3N NH3

Co

Cl NH3

Cl

(ii) (2) Square planar.

SECTION-C
Answer 8.
(a) C2H6O is formed by hydrolysis of X. An alcohol is obtained by hydrolysis of an ether.
X is an ether

C2H5 OC2H5 + H2O 2C2H5OH }}}m CH CHOHCH COOH

(O)
3 2
(Dil NaOH)

CH3CHO CH3CHOHCH2CHO }}}m CH CHOHCH COOH

(O)
3 2
X = Diethyl ether (ethoxy ethane)
Y = Acetaldehyde
Z = Aldol (3Hydroxybutanal)
W = 3Hydroxybutanoic acid.
(b) (i) Lone pair on N will attack the electrophile.
(ii) The organic compounds that cannot be produced in the body and must, therefore, be supplied in small
amounts in the diet for the growth and maintenance of animal body.
(iii) It is present in the nucleus of the living cell. It directs the synthesis of protein. They are responsible for the
transfer of genetic information.
(c) (i) Using sodalime (ii) Using lithium aluminium hydride
(iii) Using MnO
Answer 9.
(a) (i) Globular proteins have a inter molecular H-bonds.

(ii)

34A

20A

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The double helical structure of DNA consists of two right handed helical polynucleotide chains coiled
around the same central axis. The two strands are antiparallel. The nucleotides making up each strand of
DNA are connected by Phosphate ester bonds. This forms the backbone of each DNA strand from which the
bases extend. The two strands are held together by hydrogen bonds. Thymine and adenine are joined by
two hydrogen bonds while cytosine and guanine are joined by three hydrogen bonds. The two strands of
DNA are said to be complementary to each other. In the sense that the sequence of basis in one strands
automatically determines that of other.
(b) (i) Adenine,Guanine,Cytosine and Uracil.
(ii) Vitamins-A, D, E and K
(c) Isoelectric point : It is the pH at which there is no net migration of zwitter ion (or dipolar ion) of amino acid
under the unfluence of electric field e.g., Isoelectric point of zwitter ions, of glycine is 6.1

O

H3N CH 2 C O
Zwitter ions of
glycine

Answer 10.
(a) (i) A = Acetic anhydride
B = Acetic acid
C = Ethylacetate
D = Ethyl alcohol
E = Acetone
(ii) (CH3)2CO + 3I2 + 4KOH CHI3 + CH3COOK + 3KI + 3H2O, Iodoform reaction
(b) (i) Glucose Aldehydic group
Fructose Ketonic group
Glucose decolourises bromine water, but fructose does not.
(ii) Polymers having ester linkage called polyester. They are formed by condensation polymerization of alcohol
and acid.
Example : Terylene or Dacron, its monomers are 1, 2 Ethane diol and Terepthalic acid.
(c) (i) C6H5NH2 + C6H5COCl C6H5NHCOC6H5 + HCl
Product name Phenyl benzamide or benzanilide.
(ii) C2H5OC2H5 + HI C2H 5I + C2H 5OH
Ethyl iodide Ethyl alcohol

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EVERGREEN MODEL TEST PAPER-7

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) Sodium, hydrogen (ii) Electrons, cathode
(iii) Anions, tetrahedral (iv) Directly, active masses
(v) sp3, sp2
(b) (i) 1 (ii) 2 (iii) 2 (iv) 4 (v) 4
(c) (i) In acetamide, the electron pairs on nitrogen is involved in resonance, hence not available for donation, so
less basic.
(ii) In presence of light chlorine molecules undrgo homolytic fission to give chlorine free radicals, which is
involved in the chlorination reaction.
(iii) As the halogen atom is more electronegative than carbon, the bond between carbon and halogen is polar.
Due to presence of partial positive charge on carbon, the nucleophile can attack the electron deficient
carbon.
(iv) Phenol is acidic in nature.
(v) Water is in liquid state, where particles can move and randomness is more, hence entropy is more than ice.
(d) (i) d (ii) e (iii) a (iv) c (v) b

PART-II

SECTION - A
Answer 2.
(a) (i) Tb = 100.303 100 = 0.303 K
Tb = Kb m
0.303 = 0.5 m
m = 0.606
Again, Tf = Kf m = 1.86 0.606 = 1.132 K
Freezing point = 273 1.132 = 271.88 K
(ii) wB = 2g, w A = 200 g

1000 s wB
Tf = Kf .
wA s M B

MB = 30.98
NaCl Na+ + Cl

M normal 58.5
=1+=
M observed 30.9

= 0.87 or 87%

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(b) (i) Rate of a reaction Rate constant of a reaction
1. It is the rate of change of concent- 1. It is equal to the rate of a reaction
ration of any one of the reactants or when the molar concentration of each
products at a particular instant of time. reactant is unity.
2. Its units are mol L1 s1 2. Its units depend upon the order of
reaction.
3. It depends upon the concentrations 3. It is independent of concentration of
of reactants. reactants.

(ii) H2 + Cl2 }}}}m 2HCl

Sunlight

0.693
(iii) k =
half life

0.693
k= = 0.2772
2.5
2.303 120
t10 = log
k W
2.303 120
10 = log
0.2772 W
W = 7.5 g.
Answer 3.
(a) (i) This type of defect is caused by a hole in cationic lattice site and the cation occupies interstitial position as
size of the cation is smaller than anion. Example : crystal of ZnS and AgBr.
1
(ii) bcc 8 s +1=2
8
1 1
 6 s = 4
fcc 8 s
8 2
(iii) In graphite central carbon atom is covalently linked with three more carbon atoms and fourth one is free
resulting in the formation of hexagonal layers. These layers are held together by weak van der Waals forces
of attractions. Therefore, these layers can readily slip over each other. Here graphite to soft, slippery and can
be used as a solid lubricant.
(b) (i) S < R < P < Q
1 1 1
(ii) pH = (pKW + pKa pKb) = (log 1014 + 3.8 4.8) = (14 + 3.8 4.8) = 6.5
2 2 2
(iii) Concentration of metal ions, temperature.
Answer 4.
(a) (i) During the formation of cuprous oxide at anode, Cu gets oxidized to Cu+1 which combines with O2 to form
Cu2O.
2Cu 2Cu+1 + 2e
O2 + 2e O2

2Cu +O2 2Cu+ + O2 or Cu2O
Thus, there is involvement of two electrons i.e., 2F or 2 96500 C of electricity in the formation of one mol i.e.,
1.43 g of Cu2O.
Quantity of electricity actually passed = 0.965 A 1250 s = 1206.25 C

143
Mass of Cu2O formed by 1206.25 C of electricity = s 1206.25 = 0.8938 g
2 s 96500
(ii) Molar conductance increases with the decrease in concentrations of the electrolyte.

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(b) (i) Anode reaction : Zn Zn2+ + 2e
Cathode reaction : Cu2+ + 2e Cu

Cell reaction : Zn + Cu2+ Zn+2 + Cu
(ii) pH of the buffer before adding HCl

[Salt]
pH = pKa + log
[Acid]

0.25
= log (1.8 105) + log
0.2

= (5 0.2552) + 0.0969
= 4.7448 + 0.0969
= 4.8417
After addition of 0.04 mol of HCl
[CH3COOH] = 0.2 + 0.04 = 0.24
[CH3COONa] = 0.25 0.04 = 0.21

[Acid]
Now, pH = 4.7448 log
[Salt]

0.24
= 4.7448 log
0.21

= 4.7448 0.0581
= 4.6867
Change in pH = 4.8417 4.6867 = 0.1550
(c) (i) It is a substance which can decrease the rate of a reaction.
(ii) This is because it does not undergo hydrolysis in water and [H+] = [OH] = 107M
Hence the aqueous solution is neutral.
(iii) When an alcohol is heated with monocarboxylic acid in the presence of conc. H2SO4, an ester is produced.
This reaction is called esterification.

SECTION-B
Answer 5.
(a) The addition of hydrogen to an unsaturated compound (alkene or alkyne) in the presence of catalyst such as Ni
to give saturated compound is called catalytic hydrogenation.
(b) (i) Oxidation number of S in H2SO4 is + 6 and is H2SO3 is + 4 therefore, H2SO4 is a stronger acid than H2SO3.
(ii) Silicon dioxide acts as a flux and combines with ferrous oxide to form ferrous silicate as a slag.
(iii) This be because 5f electrons in actinides cause poor shielding as compared to 4f electrons in lanthanides.
Answer 6.
(a) (i) Regular octahedron and d2sp3 hybridisation.
(ii) Cis, trans. dichloridodioxalato cobaltate (III) ions.
(b) (i) K2Cr2O7 + H2SO4 + 3SO2 K2SO4 + Cr2(SO4)3 + H2O
(ii) Na2SO3 + Br2 + H2O Na2SO4 + 2HBr

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Answer 7.
The resonance structures of SO 2
4 ion are

(a) O O O O

S
O
S S O
S O
O O
O O O O O O O
(I) (II) (III) (IV)

(b) (i) The colour of halogens is due to absorption of light in the visible spectrum. This results in the excitation
of valence electrons to higher energy level. Value of excitation energy depends on size, which is maximum in
fluorine due to small size and minimum in iodine due to largest size.
(ii) As the atomic number increases, the added electrons enter to (n 1)d subshell and shield the outermost
electrons. The screening effect increases with increase in atomic number or number of d electrons. Thus, the
effect of increased nuclear charge due to increase of atomic number is compensated by the increase in
shielding or screening effect.
SECTION-C
Answer 8.
(a) (i) CH3Cl + KCN CH3CN + KCl
(alc.)

CH3CN + 2H2O }}}

%
m CH COOH + NH
H+
3 3

(ii) C H + CH Cl }}}}}}
6 6 3 m C H CH + HCl
anhyd. AlCl3
6 5 3

C H CH + 3(O) }}}}}}} m C H COOH +H O

Alkaline KMnO4
6 5 3 6 5 2

(iii) C H OH + 2(O) }}}}}}}}} m CH COOH +H O

K 2 Cr2O7 + Dil. H 2SO4
2 5 3 2

2CH COOH + Ca(OH) }}

3 m
% (CH COO) Ca + 2H O
2 3 2 2

(CH COO) Ca }}}}}}m (CH ) CO + CaCO

Dry distillation
3 2 32 3
(b) (i) Vitamin D (ii) Vitamin A
(c) (i) Victor Meyer Test blood red colour for 1-butanol, blue colour for 2-butanol.
(ii) Urea gives positive result with Biuret test but benzoic acid does not.
Violet colouration with Biuret reagent for urea.
NH2CONH2 + NH2CONH2 NH2CONHCONH2 + NH3
Answer 9.
(a) (i) Condensation, Addition, Tetrafluoroethylene
(ii) condensation, Phenol and formaldehyde
(b) Glucose Aldehyde, fructose Ketone Bromine water test Glucose decolourise bromine water but fructose
cannot.

Glucose + [O] }}}}}}m Gluconic acid

Bromine water

(c) A = C6H5CH3 (Toluene), B = C6H5CHO (Benzaldehyde)

C = C6H5CH2OH (Benzyl alcohol), D = C6H5COONa (Sodium benzoate)
(d) (i) The Benzoin condensation is a coupling reaction between two aldehydes that allows the preparation of -
hydroxyketones. The first method was only suitable for the conversion of aromatic aldehydes.

O O

CN
H
H2O / EtOH OH Benzoin

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(ii) Finkelsteins reaction

C2H5Br + NaI }}}}m C H I + NaBr

Acetone
2 5

(iii) Franklands reaction : Reaction between alkyl halides in the presence of zinc and dry ether medium to form
alkane.

CH3 Cl + Zn + Cl CH3 }}}m CH CH + ZnCl

Ether
3 3 2

Answer 10.
+
Cl2, hv KCN H
(a) (i) C 2H 6 C2H5Cl C 2H5CN H O C2H5COOH
2

}}}}}}} m C6H5 N +2 Cl }}}} m C6H5CN }}}m


NaNO / HNO CuCN H O
(ii) C6H5NH2
3
C6H5COOH
2 2
05 C o

(b) (i) Chain isomerism CH3CH2CH2CH3, CH3CH(CH3)CH3

(ii) Geometrical isomerism Cis and trans isomers.

H C Br Br C H

C C
H Br H Br
(Cis-isomer) (Trans isomer)

(iii) Functional or position isomerism CH3CH2CH2CH2OH, C2H5OC2H5

or CH3CH2CH2CH2OH, CH3CH2CH(OH)CH3
(c) A = Ethyl amine, B = Ethyl alcohol, C = Acetaldehyde, D = Acetic acid, E = Ethyl acetate.
C2H5NH2 + HNO2 C2H5OH + N2 + H2O
C2H5OH + [O] CH3CHO + H2O
CH3CHO +Ag2O 2Ag +CH3COOH

CH3COOH + C2H5OH }}}}}}m CH COOC H + H O

Conc.H 2SO4
3 2 5 2

CH3CHO + NH3 CH3 CH = NH + H2O

Acetaldimine

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EVERGREEN MODEL TEST PAPER-8

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) decreases, increases (ii) Ksp, low
(iii) anode, cathode (iv) isocyanide, carbylamine reaction
(v) gluconic, saccharic
(b) (i) 3 (ii) 4 (iii) 3 (iv) 3 (v) 4
(c) (i) If activation energy zero, then according to Arrhenius theory,
Rate constant = Collision frequency, which means every collision results into a chemical reaction. It
is not possible, hence Ea 0.
(ii) Zinc oxide loses oxygen on heating and vacant sites of the anions are occupies by the electrons, which
absorbs light from visible light and emit complementary colour, i.e., yellow.
(iii) During reaction, ion concentration in one half-cell increases, while in other decreases. Hence, their electrode
potential also keep changing unless they become equal and e.m.f. become zero.
(iv) Carboxylic acid has stronger and more hydrogen bonds than alcohol.
(v) p-nitrophenol , due to intermolecular hydrogen bonding.
(d) (i) e (ii) d (iii) a (iv) c (v) b

PART-II

SECTION - A

Answer 2.

nsucrose 5 5
(a) (i) Xsucrose = n = 1000 = 5  55.55 = 0.083
sucrose  nH2 O 5
18

p
pA A
= 0.083

pA

457 pA
= 0.083
457

p A = 457 4.19
= 452.81 mm
(ii) Tb = i kb m
1.88 = i 0.52 2
i = 1.82

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Ea

(b) (i) k = Ae RT

k = rate constant
A = collision factor
Ea = activation energy

Ea
(ii) Slope =
2.303R
(iii) Ea = 2.303 slope R
= 2.303 5841 8.314 J mol1
= 111.8 kJ mol1
(c) In a solid crystal lattice when a cation (smaller ion) leaves its original site and moves to an interstitial position, this
defect is known as Frenkel defect.
Answer 3.
(a) (i) Ionic solids are bad conductors in the solid state because their constituent ions are held together in fixed
positions by strong attractive forces. However, they conduct electricity in the molten state because of the
presence of free ions.
(ii) ZnCl2 is a salt of weak base and strong acid and undergoes cation hydrolysis to give acidic solution. NaCl
is a salt of strong acid and strong base and does not hydrolyse.
(b) In diamond crystal,
(i) Eight carbon atoms are present in a unit cell of diamond.
(ii) Face centred cubic (fcc) structure.
(iii) Four carbon atoms surround each carbon.
(iv) They are arranged in a tetrahedral manner.
(c) (i) Standard Hydrogen Electrode (SHE) : Standard hydrogen electrode is set-up by passing pure hydrogen gas
at 1 atm pressure in a solution of H+ or (H3O+) ions of concentration of 1 mol L1in contact with a platinum
foil coated with platinum black at 25C. A standard hydrogen electrode can be represented as :
Pt, H2 (g) (1 atm) /H+(1 M) at 25C

1 1
(ii) Conductance =  ohm 1
R 31.6

1
Specific conductance , = ohm1 ( 0.367 cm1)
31.6
Molar conductance = 1000/C = 232 ohm1 cm2 mol1
Answer 4.

1
(a) (i) n = 1 1.5 = 0.5 =
2
Units = (mol/L)
n = 1 1.5 = .0.5
Kp = Kc (RT)n
Kp = 11.797 atm
(ii) When a catalyst is added, the state of equilibrium is not disturbed but equilibrium is attained quickly. This is
because the catalyst increases the rate of forward and backward reaction to the same extent.
(b) (i) Temperature is increased the equilibrium will shift to the backward direction as the increase in temperature
will be compensated by absorbing heat.
(ii) The equilibrium will shift in the forward direction; i.e.; conc. of SO3 will increase.

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(iii) Pressure is decreased the equilibrium will shift to the left to produce more number of moles.
(iv) Helium is added at constant pressure it will result in increase in volume. As a result, the number of
molecules per unit volume will decrease. This stress is relieved by the formation of more molecules and the
equilibrium will shift to the left.
(c) (i) I = 12 amperes
t = 15 60 = 900 C
Q = It = 12 900 = 10800 C
10800 C deposit metal = 0.3605 g
0.3605
96500 C will deposit metal = 96500 = 32.21 g
10800
Eq. wt. of metal = 32.21
96
Valency = =3
32.21
(ii) Phenolphthalein is a weak organic acid which changes its colour between pH value of 8.3 to 10. It gives pink
colour in alkaline medium but is colourless in acidic medium due to common ion effect.

SECTION-B
Answer 5.
(a) (i) [Cr(NH3)3 (H2O)3]Cl (ii) K3 [Fe(CN)6]
(b) (i) Hydrate isomerism or solvate isomerism (ii) Coordination isomerism
(c) (i) d2sp3 (ii) Diamagnetic
Answer 6.
(a) (i) PbS + 4O3 PbSO4 + 4O2

(ii) 3Cl2 + 6NaOH

(Hot and conc.)
}}
%
m 5NaCl + NaClO + 3H O
3 2

(iii) 5H2SO4 + 2P 2H3PO4 + 5SO2 + 2H2O

Or
P4+10H2SO4 2H3PO4+10SO2+ 4H2O
(b) (i) Cu2+ salts are coloured because they absorb visible light for excitation of electrons to partly filled d-orbitals.
Zn2+ salts are colourless because of the absence of partly filled d-orbitals to which the electrons can be
excited.
(ii) Fluorine does not have d orbital.Chlorine has vacant 3d orbital. Electrons jump from 3s and 3p orbitals to 3d
orbitals.
Answer 7.
(a) (i) Conversion of chromite ore into sodium chromate : Finely powdered chromite ore is mixed with soda ash
and quick lime. The mixture is then roasted in a reverberatory furnace in presence of excess of air, a yellow
mass containing sodium chromate is obtained.

4FeCr2O4 + 8Na2CO3 + 7O2 }}

+
m 2Fe O +
2 3 8Na2CrO4
(Sodium chromate)
+ 8CO2

(ii) Conversion of sodium chromate to sodium dichromate :

Sodium chromate is treated with concentrated sulphuric acid to form sodium chromate.
2Na2CrO4 + H 2SO 4 Na2Cr2O7 + Na2SO4 + H2O
(Conc.)
(iii) Conversion of sodium dichromate to potassium dichromate :
Sodium dichromate solution is concentrated by heating. Now, add a calculated quantity of potassium chloride
is added. On cooling, the least soluble potassium dichromate separate out as crystals.
Na2Cr2O7 + 2KCl K2Cr2O7 + 2NaCl

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F
F F

(b) (i) I F (ii) sp3d3 (iii) Pentagonal bipyramidal

F F
F

SECTION-C
Answer 8.
(a) (i) CH3COOH + NH3 CH3COONH4
CH3COONH4}}}
+
m CH CN P2 O5
3

CH CHO }}}}}}m CH COOH }}}} m


(O) NH 3
(ii) 3 K 2 Cr2O 7 |H 
+ 3 CH3CONH2
% Br2 + KOH
(aq.)

HCHO k}} CH3OH k}}}}}}

O2
Cu
HONO
NaNO  Dil. HCl
} CH3NH22

NO2 NH2 NH2

Br Br
Sn/HCl Br2 (aq)
(iii)
Reduction 298 K

Br
2, 4, 6 tribromoaniline
(b) A = Sn/HCl
B = NaNO2 + HCl and 0C 5C
C = CuCN
D = H+/H2O
E = NH3, Heat
F = Br2/KOH (aq)
Answer 9.
(a) (i) Vitamin C
(ii) Vitamin K
(b) (i) Lucas Test With concentrated HCl + ZnCl2 no turbidity is formed Ethanol.
Whereas Turbidity appears within five minutes propan-2-ol.
(ii) Azo dye test Dissolve the given amine in dil. HCl and cool it in ice-cold water.
Now, add ice-cold solution of NaNO2 and HCl followed by an ice-cold -naphthol solution. The appearance
of brilliant orange-red indicates that the given amine is aniline.
Ethylamine does not form any dye and, therefore, does not show any colour when treated similarly. (or any
other suitable test)

(c) CH3 CH3

OH H
H COOH OH COOH
d-Lactic acid l-Lactic acid
Hypothetical
mirror

(d) (i) CH3CHO + 4HI }}}}

+
m CH CH + H O + 2I
Red P
3 3 2 2

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(ii) (CH3COO)2Ca }}}}}}m (CH ) CO + CaCO

Dry distillation
32 3
(iii) C2H5ONa + C2H5Br C2H5OC2H5+NaBr

H SO3 Na
| |
(iv) C6H 5  C  O + NaHSO3 C6 H5  C  OH
|
H

Answer. 10
(a) A = Toluene, C6H5CH3
B = Benzaldehyde, C6H5CHO
C = Benzyl alcohol, C6H5CH2OH
D = Benzoic acid, C6H5COOH
E = Benzene, C6H6
F = Nitrobenzene, C6H5NO2
(b) (i) CH3CHO + 4(H) }}}}}}

m CH CH + H O
Zn conc HCl
3 3 2

ZZX 2CH3COO + 2K+

(ii) 2CH3 COOK YZZ 2H2O ZZX 2H++ 2OH
YZZ
At anode : 2CH3COO 2e = C2H6+CO2
At cathode : 2H+ + 2e = H2

N 2 Cl
+
N2 BF4 F

HCl %
(iii) + HBF4 + N2 + BF3

Benzene
Fluorobenzene
diazonium chloride

(c) (i) Urea on heating strongly (above 132C) gives biuret, alkaline solution of biuret gives a violet colouration
with dilute copper sulphate solution.
(ii) NH2CONH2+NH2CONH2
%
}}mNH2CONHCONH2 + NH3
(d) (i) Decolourises bromine water.(Red colour of bromine water disappear)
Or
CH2OH(CHOH)4CHO }}}}}m CH OH(CHOH) COOH
Br2 / H 2O
2 4
(glucose) (gluconic acid)
(ii) Isoelectric point At a particular pH of a solution the amino acid molecule does not migrate to either
electrode and exists as a neutral dipolar ion. This pH is known as isoelectric point.

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EVERGREEN MODEL TEST PAPER-9

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) High, hydrogen (ii) Electrical conductivity, mobile electrons
(iii) strands, hydrogen bonding (iv) Less, ionic
(v) HCl, anhydrous ZnCl2
(b) (i) 4 (ii) 1 (iii) 1 (iv) 2 (v) 2
(c) (i) pH of the solution will remain same because it acts as a buffer.

k s 1000
(ii) m =
Molarity

units of m = ohm1cm2 mol1

(iii) In phenol electron releasing OH group activates the benzene ring towards electrophilic substitution reaction
and directs the substituent at ortho and para positions.
(iv) First order.
(v) It occurs for those crystals which are highly ionic compound, in which the sizes of cation and anion do not
differ. e.g., NaCl, KCl etc.
(d) (i) e (ii) c (iii) b (iv) a (v) d

PART-II

SECTION - A
Answer 2.
(a) (i) Tb = 100.303 100 = 0.303 K
Tb = Kb m
0.303 = 0.5 m
m = 0.606
Again, Tf = Kf m = 1.87 0.606 = 1.133 K
Freezing point = 273 1.133 = 271.86 K
(ii) w B = 1 g, w A = 100 g

1000 s wB
Tf = Kf .
wA s M B

MB = 30.96
NaCl Na+ + Cl
Let vant Hoff factor = i

M normal 58.5
i= = = 1.88
M observed 30.96

i = 1.88

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(b) (i) Velocity coefficient Temperature coefficient
1. It is equal to rate of reaction when 1. It is the ratio of rate constants of
molar concentration of each reactant reactions at 35C and at 25C.
is unity.
2. Its units depend upon order of reaction. 2. It has no units.

(ii) NH4NO2 }}m

% N
2 + 2H2O
0.693
(iii) k =
half life
0.693
k = = 0.3465
2
2.303 200
t 10 = log
k W
2.303 160
200 = log
0.3465 W
W = 25.01 g.
Answer 3.
(a) (i) This type of defect caused by a hole in cationic lattice site and the cation occupies interstitial position as size
of the cation is smaller than anion. Example : crystal of ZnS and AgBr.
1
(ii) Simple cubic crystal = 8
=1
8
1 1
face centred cubic crystal = 8 + 6 = 1 + 3 = 4
8 2
(iii) This is because in diamond, there are strong C C covalent bonds.
(b) (i) C < D < B < A
1
(ii) pH = ( pKW + pKa pKb)
2
1
= (log 1014 + 3.8 4.8)
2
1
= (14 + 3.8 4.8) = 6.5
2
(iii) Concentration of metal ions in solutions, Nature of the electrods.
Answer 4.
(a) (i) Al3+ + 3e Al
1 mol 3F
27g
27g of Al3+ requires electricity = 3F
3
2.7g of Al3+ requires electriicty = 2.7
27
= 0.3 F
(ii) Cu2+ + 2e Cu
1 mol 2F
63.5 g
63.5 g of Cu2+ requires electricity = 2F
(iii) Molar conductance increases with increase in dilution.
(b) (i) Anode reaction : Zn Zn2+ + 2e
Cathode reaction : Cu2+ + 2e Cu

Cell reaction : Zn + Cu2+ Zn2+ + Cu

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(ii) pH of buffer solution is given as :

[Salt]
pH = pKa + log
[Acid]

0.5
= log (1.8 105) + log
0.4
= (5 0.2552) + 0.0969
= 4.7448 + 0.0969
= 4.8417
(c) (i) A substance which can alter the rate of a reactions but itself remains unchanged in mass and composition at
the end of a reaction is called catalysis.
(ii) When oil and fats are heated with an alkali, they are hydrolysed to form soap, the sodium salt of higher fatty
acids.
(iii) Buffer solution : It is a solution whose pH remains unchanged on the addition of a small amount of acid or
base or on dilution.

SECTION-B
Answer 5.
(a) Draw the structure of XeF2

Structure of XeF2

sp3 d
F Xe F

Linear geometry

(b) (i) Greater electronegativity of oxygen than sulphur, so strong hydrogen bond in H2O, stays as associated
molecules, hence liquid.
(ii) Halogens are in short of electron to complete octet and hence strong tendency to share its unpaired electron
with another atom of same halogen to form diatomic molecule (X2)
Whereas noble gas atoms are stable because of complete octet do not react with other and do not form
diatomic molecules.
Answer 6.
(a) (i) [Ni(CN)4]2 has a square planar geometry due to dsp2 hybridise also of Ni2+ ion.
Also it is diamagnetic because there is no unpaired electrons.
(ii) Cisdichloridobis (ethylene diamine) cobalt (III) ion and
Transdichloridobis (ethylene diamine) cobalt (III) ion.
(b) (i) 2Na2S2O3 + I2 Na2S4O6 + 2NaI
(ii) Cl2 + 2NaOH NaCl + NaClO + H2O
(Cold and dil.)

Answer 7.
(a) Binary compounds of halogens among themselves are called interhalogen. The general formula of the interhalogen
compounds is XYn , where X and Y are halogens y is more electronegative than X and n is an integer having values
1, 3, 5 and 7. X is always larger halogen atom and Y is smaller halogen atom. The oxidation state of X is +1, +3, +5,
or +7 depending upon the value of n but the oxidation state of Y is always 1.
(b) (i) [Co(NH3)4Cl2]Cl. Its IUPAC name is tetramine dichlorocobalt (III) chloride.
(ii) Square planar and octahedral complexes show geometrical isomerism.
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SECTION-C
Answer 8.
(a) C2H6O is formed by hydrolysis of X. An alcohol is obtained by hydrolysis of an ether.
X is an ether.

C2H5 OH}}}m CH CHO

(O)
3

CH CHO }}}m CH CH CH

OH
3 3 2 CHO
OH
(O)
CH3 CH CH2 CHO
OH CH3 CH CH3 COOH
OH
X = Diethyl ether (ethoxy ethane)
Y = Acetaldehyde
Z = Acetaldol
W = 3Hydroxy butanoic acid
(b) (i) In air and light, phenol is oxidised to phenoquinone which is red in colour.

E+ E E E+
OHO OHO

Phenoquinone
(ii) Monosaccharide : Glucose, fructose
Disaccharide : Sucrose
Polysaccharide : Starch, cellulose
(iii) Example of :
Co- polymer : Nylon 66
Synthetic polymer : Terylene, Dacron

(c) (i) C6H6 + HNO3 }}}}}}

Conc. H SO
m C H NO +H O
2 4
6 5 2 2
(Conc.) (Dark)

NO2

C6H5NO2 + Cl2 }}}}}}m

Anhyd. FeCl3 + HCl
Cl
(ii) C6H5OH + Zn }}}m C H + ZnO
Heat
6 6

(iii) C H Cl + CuCN }}}}m C H CN

Pyridine
6 5 473K 6 5

C6H5CN + 2H2O }}}

%
m C H COOH + NH
H
6 5 3

Answer 9.
(a) (i) Intermolecular H-bonds
(ii) DNA RNA
1. It contains deoxyribose sugar. 1. It contains ribose sugar.
2. It contains thymine as pyrimidine base. 2. It contains uracil as pyrimidine base.
3. It has double helix structure. 3. It has single helix structure.
4. It can replicate. 4. It cannot replicate.

This is because nucleic acids are polynucleotides and they are present in the nuclei of cells.

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(b) (i) The sugar units present in DNA is D-2 deoxyribose and in RNA is D- ribose.
(ii) Enzyme deficiency Diseases
1. Tryosinase. 1. Phenylketonuria.
2. Phenylalanine hydroxylase. 2. Albinism.

(iii) Water soluble vitamins are Vitamin B1 (Thiamine), Vitamin B2 (Riboflavin),

Vitamin B6 (Pyridoxine), Vitamin B12 (Cyanocobalamine), Vitamin C (Ascorbic acid).
Red P + HI
(c) (i) C6H12O6 n C6H14 + CH3 CH (CH2)3 CH3
373 K
I
nHexane 2Iodohexane

(ii) CHO
H+
(CHOH)4 + H2N OH CH = N OH + H2O

CH2OH (CHOH)4
CH2OH
Glucose Glucosamine

(iii) C 6H 12O6 }}}}}

%
m
Br2 / H2O
CH2OH

Glucose
(CHOH)4

COOH
Gluconic acid

Answer 10.

(a) O O O O O

I II III IV V
(b) (i) CH3CONH2 + Br2 + 4NaOH
(aq)
}}m
% CH NH + 2NaBr +Na CO +2H O
3 2 2 3 2

(ii) 2C6H5CHO }}}m C H COCHOHC H

KCN
6 5 6 5

(iii) C6H6 + CH Cl }}}}}m C H CH + HCl

3
Ahyd AlCl3
6 5 3
(iv) 2HCHO + NaOH (Conc.) HCOONa + CH3OH
2C6H5CHO +NaOH (Conc.) C6H5COONa + C6H5CH2OH
(c) A = Conc. nitric acid and conc. sulphuric acid.
B = Tin and conc. hydrochloric acid.
C = Hydrochloric acid.
D = Sodium nitrite and hydrochloric acid (nitrous acid) at 0 C.

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EVERGREEN MODEL TEST PAPER-10

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) Sodium, hydrogen (ii) Electrons, cathode
(iii) Anion, tetrahedral (iv) Directly, active masses
(v) sp3, sp2
(b) (i) 3 (ii) 4 (iii) 3 (iv) 2 (v) 1
(c) (i) Zinc oxide loses oxygen on heating and vacant sites of the anions occupies by the electrons, which
absorbs light from visible light and radiate complementary colour, i.e., yellow.
(ii) If activation energy 0, then according to Arrhenius theory, Rate constant = Collision frequency, which means
every collision results into a chemical reaction. It is not possible, hence Ea 0.
(iii) During reaction, concentration of metal ions in one oxidation half-cell increases, while in other decreases.
Hence, their electrode potential also keep changing unless they become equal and e.m.f. become zero.
(iv) p-nitro phenol, due to intermolecular hydrogen bonding.
(v) Carboxylic acid have more and stronger hydrogen bond than alcohols.
(c) (i) e (ii) d (iii) a (iv) c (v) b

PART-II
SECTION - A
Answer 2.
(a) (i) The molecular mass of KCl in aqueous medium has been observed to be almost half than expected and it has
been explained as dissociation of KCl into K+ ions and Cl ions when actual number of particles become
double and so becomes the colligative properties but since molecular mass is always inversely proportional
to colligative property it becomes almost half. In case of benzoic acid in benzene, association of molecules
takes place when they dimerise and their number becomes almost half and so molecular mass doubles as a
result.
(ii) m = 0.5
Kf = 1.80 K kg mol1
Tf = Kf m
= 1.86 0.5 = 0.93C
or Tf = Tf Tf
= 0 0.93 = 0.93C
(b) (i) Atoms and ions are spherical in shape. A crystal is formed by close packing of atoms or ions. Since spheres
almost touch each other and some empty space is left between them. This space is called void or hole.
(ii) A tetrahedral void is surrounded by four spheres (atoms), whose centres lie at vertices of regular tetrahedron
whereas an octahedral void is surrounded by six spheres whose centres lie at corners of a regular octahedron.
(iii)
Octahedral
Tetrahedral hole
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Answer 3.
(a) (i) Given, [H+] = 3.8 103 M
pH value of soft drink = log [H +] = log (3.8 103) = log 3.8 log 103
= log 3.8 + 3 = 0.58 + 3 = 2.42
(ii) Relative lowering of vapour pressure is equal to the mole fraction of non-volatile solute.
%p 4
 xB   0.1
po 40
This means solution has 0.1 moles of solute present in 0.9 moles of water. Therefore, the mass of water in the
solution = No. of moles of water Molecular weight of water = 0.9 18 = 16.2g
Moles of solute 0.1
Molality of solution =   6.17 m
Mass of solvent in kg 16.2
1000
(b) (i) This is because in graphite there are free electrons (due to sp2 hybridisations of C-atom) but in diamond there
are no free electrons (due to sp3 hybridisations of C-atoms)
(ii) Nature of electrode, concentration of ions in solution.
(iii) Given, p = 0.850 bar, p = 0.845 bar
Molar Mass of solvent (M1) = 78 g mol1,
Mass of solvent w 1 = 39 g
Mass of solute w 2 = 0.5 g
p0  p w2 M1
= M M
p0 2 1

(0.850  0.845) 0.5 s 78 g mol 1

=
0.850 M 2 s 39
M 2 = 170 g mol1
Answer 4.
(a) Volume of unit cell = (288 pm)3 = 28.8 1024 cm3
Mass 208
Volume of 208 g of element = = = 28.8 cm3
Density 7.2
Volume of element
No. of atoms in 208 g of element =
Volume of unit cell
28.8
=  1 s 1024
28.8 s 1024
Q In bcc unit cell has 2 atoms.
Total number of atoms in 208 g of element = 2 1 1024 = 2 1024 atoms

k2 r2
(b) (i) Let k1 = r1 = 2

T1 = 298 K
T2 = 308 K
According to Arrhenius equation :

k2 E a T2 T1
log =
k1 2.303R T1T2

Ea 10
log2 =
2.303 s 8.314JK 1mol 1 298 s 308

0.3010 s 19.147 J mol 1 s 298 s 308

Ea = = 26.4 kJ mol1
10

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(ii) Molecularity Order

1. It is the total number of molecules as 1. It is the sum of the powers of the concentration
present in balanced chemical reaction terms in rate law for the reaction.
leading to formation of products in case
of a simple reaction.
2. Molecularity of reaction can never be 2. Order of reaction can be in fractions.
in fractions.
3. Molecularity of reaction cannot be zero. 3. Order of reaction can be zero.

(iii) 1. When the product during the reaction is able to catalyse the reaction, it is known as autocatalysis.
2. It is a substance which is added to a photochemical reactions which absorbs light, gets activated and
transfers to one of the reactants. It can start a photochemical reaction.

SECTION-B
Answer 5.
(a) (1) hexaamminecobalt (III) chloride (2) pentaamminechloridocobalt (III) chloride
(3) potassium hexacyanoferrate (III)
(b) (1) [Co(H2O)2(NH3)4]Cl3 (2) K2 [Ni(CN)4]
Answer 6.
(a) When ionization isomers are dissolved in water, they ionize to give different ions. These ions then react differently
with different reagents to give different products.

[Co(NH3)5Cl] SO4 + Ba2+ BaSO 4 n + [Co(NH3)5Cl]+

White precipitate

[Co(NH3)5Cl] SO4 + Ag+ No reaction

[Co(NH3)5 SO4] Cl + Ba2+ No reaction

[Co(NH3)5 SO4] Cl + Ag+ AgCl n + [Co(NH3)5SO4]+

White precipitate

(b) (i) Both geometrical (cis-, trans-) isomers for K[Cr(H2O)2 (C2O4)2] can exist. Also, optical isomers for cis-isomer
exist.
OH2
OH2

OH2
C2O4 Cr C2O4 Cr C2O4

C2O4 OH2
Cis-isomer Trans isomer
Cis-isomers shows optical isomerism

OH2 OH2
OH2 OH2
C2O4 Cr C2O4 Cr

C2O4 C2O4
Hypothetical
mirror
d-isomer l-isomer
(Non-superimposable mirror image)
Cis isomer is optically active whereas trans isomer is optically inactive because it is superimposable over its
mirror image.
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(ii) Two optical isomers for [CO(en)3]Cl3 exist.
en 3+ en 3+

en CO en CO en

en en
disomer lisomer

Answer 7.
(a) When O3 is passed through the solution of an alkene or alkyne in CCl 4 at low temperature an ozonide is produced
which on warming with zinc dust and water undergo cleavage to give carbonyl compound. The complete reaction
i.e., formation of an ozonide and is cleavage is called ozonolysis.

e.g. CH3 CH = CH2 + O3 }}}}}m CH CHO OO CH

CCl4
low temp.
3
2

O water
CH3 CH CH2 + Zn CH3 C H + CH2 + ZnO
O O warm
O O
Acetaldehyde Formaldehyde
(b) (i) Oxidation number of S in sulphuric acid (+ 6) is higher than oxidation number S in H2SO3 (+4)
(ii) Silicon dioxide acts as a flux and combines with ferrous oxide to form ferrous silicate as a slag.
(iii) In d-block elements electrons of both (n 1)d and ns electrons take part in bond formation due to small
energy difference. But in f-block elements due to poor shielding effect of (n 2)f electrons effective nuclear
charge increases, therefore, lesser number of oxidation states.

SECTION-C
Answer. 8
(a) (i) CH3Cl + KCN CH3CN + KCl
(alc.)

CH3CN + 2H2O }}}}m CH3COOH + NH3

alc. H +

(ii) C6H6 + CH3Cl }}}m C6H5CH3 + HCl

AlCl 3

C6H5CH3 + 3[O] }}}}}}}}} m C6H5COOH + H2O

Ahyd Alkaline KMnO 4

(iii) C2H5OH +2[O] }}}}}}}} m CH3COOH +H2O

K Cr O + H SO
2 2 7 2 4

2CH3COOH + Ca(OH)2 (CH3COO)2Ca + 2H2O

(CH3COO)2Ca }}}}}}m (CH ) CO + CaCO
Dry distillation
32 3
(b) (i) Vitamin A (ii) Vitamin C
(c) (i) Urea gives positive result with Biuret test but benzoic acid does not.
Violet colouration with Biuret reagent for urea.
NH2CONH2 + NH2CONH2 NH2CONHCONH2 + NH3
(ii) Victor Meyer Test blood red colour for 1-propanol, blue colour for 2-propanol
Answer 9.
(a) (i) Condensation , amino acids (ii) Addition, Ethene
(b) Starch DGlucose
Cellulose DGlucose
(c) A = C6H5CH3 (Toluene), B = C6H5CHO (Benzaldehyde),
C = C6H5CH2OH (Benzyl alcohol), D = C6H5COONa (Sodium benzoate)

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(d) (i) The Benzoin condensation is a coupling reaction between two aldehydes that allows the preparation of -
hydroxyketones. The first methods were only suitable for the conversion of aromatic aldehydes.
O O
KCN
H
H2O / EtOH OH 92%
(ii) Reimer-Tiemann reaction :
OH OH
CHO
+ CHCl3 + 3NaOH % + 3NaCl + 2H2O
(aq)
(salicylaldeleyde)
(iii) Wurtz reaction Reaction between alkyl halides in the presence of sodium and dry ether medium to form
alkane.

CH3 Cl + 2Na + Cl CH3 }}}}}% m

Dry ether, CH3 CH3 + 2NaCl
Answer 10.
(a) (i) A = Acetic anhydride (CH3CO)2O
B = Acetic acid, CH3COOH
C = Ethyl acetate, CH3COOC2H5
D = Ethylalcohol, CH3CH2OH
E = Acetone, (CH3)2CO

(ii) (CH3)2CO + 3I2 + 4KOH

(aq)
%
}}m CHI + CH COOK + 3KI + 3H O, (Iodoform reaction)
3 3 2

Iodoform reaction
(b) (i) Glucose Aldehyde group
Fructose Ketonic group
Glucose decolourises bromine water, but fructose does not.
(ii) Polymers having ester linkage called polyesters. They are formed by condensation polymerization of alcohol
and acid.
Example Terylene or Dacron, its monomer are Ethane 1, 2 diol and terepthalic acid.
(c) (i) C6H5NH2 + C6H5COCl C6H5NHCOC6H5 + HCl
Benzanilide

(ii) C2H5OC2H5 + HI }m C H OH 2 5 + C 2H5I

Ethyl Ethyliodide
alcohol

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EVERGREEN MODEL TEST PAPER-11

Subject : CHEMISTRY

Class : 12

PART-I
Answer 1.
(a) (i) strong, increases (ii) glycine, zero
(iii) azeotrope (iv) electrochemical equivalent
(v) carbanion
(b) (i) 1 (ii) 2 (iii) 1 (iv) 2 (v) 1
(c) (i) Glucose aldehyde, fructose Ketone

O
O
(ii) CH3 C CH3 C
OH O + H

p0 p
(iii) = xB
p0

76 72.2
= = xB = 0.05
76
Molality of the solution = 0.05
0.693 0.693
(iv) t = = = 0.1386 min
K 5
(First order reaction)
(v) The rate constant of a reaction increases with the increase in temperature.
(d) (i) e (ii) a (iii) d (iv) c (v) b

PART-II
SECTION - A
Answer 2.
28
(a) No. of moles of X = = 0.2
140
72
No. of moles of solvent (water) = =4
18
0.2
Mole fraction of X = = 0.0476
0.2  4
p0 p
Raoults law : p0 = xB

p0 160
p0 = 0.0476

p0(0.0476) p0 = 160
= p0 0.9524 = 160
p 0 = 167.997 nm

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(b) C6 1s2 2s2 2px1 2py1 2pz0

2s and 2p are used in hybridization. C atom can be sp3, sp2 or sp hybridised in organic compounds.
(c) (i) Rate of N2 + 3H2 2NH3
d [N 2 ] 1 d [H 2 ] 1 d [NH3 ]
Rate = = =+
dt 3 dt 2 dt
(ii) Sodium chloride Ionic bond.
Copper Metallic bond
Diamond Covalent bond
Graphite 3 carbons in the same layer covalent bond and 4th carbon in different layers with van der
Waals forces of attraction.
(iii) A catalyst is a substance which can alter the rate of a reaction but itself remains unchanged in mass and
composition at the end of a reaction.
Homogeneously Catalysis

2SO2 + O2 }}}
%
m 2SO3
NO

Heterogeneously catalysis

N2 + 3H2 }}}}
k}}}
Fe, Mo
}m 2NH , 2SO + O }}m
3 2 + 2SO
2
Pt
3

Answer 3.
(a) (i) A + B ZZX 2C
YZZ
Initial no. of moles 2 3 0
No. of moles at equilibrium 2 x 3x 2x
Let vol. of vessel = V
At equilibrium
2x
[A] =
V

3x
[B] =
V

2x
[C] =
V

2
2x
(C)2 V

KC = = 2 x 3 x
(A)(B) s
V V

4 x2
4 =
(2 x )(3 x)
= (2 x) (3 x)
= 6 5x + x2
2
x 5x + 6 =0

5 p 25 24 5  7 2
x = = = =1
2 2 2

12
= = 6 (Rejected)
2
No. of mole of C at equilibrium = 2 1 = 2
(ii) Yes, _ SRP of Na is less than that of F2.

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(b) (i) HCl being strong acid initially releases large number of H+ ions; but CH3COOH doesnt as it is an weak acid.
On dilution weak acid releases more H+ ions.
(ii) Due to common ion effect.

E . It
(c) (i) w = z. It or
F
z = proportionality constant and is called electrochemical equivalent of substance.
F = Faraday (96500 coulombs)
E = Equivalent weight of the substance.
(ii) Importance of salt bridge
1. It completes the cell circuit.
2. It maintains the electrical neutrality of the solutions in two half-cells.
3. It increases the life of the cell.
Answer 4.
S s a3 s N A 8 s (250 s 10 10 )3 s 6.023 s 1023
(a) (i) z = = =2
A A
8 s (250)3 s 6.023 s 107
A=
2
= 3.764 10 = 37.64 g mol1
(ii) [Fe(CN)6]4 the central metal is Fe2+ (Fe2+ has 24 electrons)
3d 4s 4p

Fe2+ (d2sp3) d2sp3

No unpaired electron; It is diamagnetic

In [Fe F6]4, the central metal ion is Fe2+ (24 electrons)
3d 4s 4p 4d

Fe2+ (sp3 d2)

sp3 d2
It has 4 unpaired electrons, It is paramagnetic.
(b) (i) CH3COOH ZZX CH3COO + H+
YZZ
0.002 s 2.3
[H+] = C = = 4.6 105
100
pH = log[H+] = log(4.6 105)

2
2.3
ka = C2 = 0.002 = 5log 10 log 4.6 = 5 0.6028
100

= 10.6 = 4.3372
(ii) It is based upon the principle of adsorption.

(c) dm [Al2(SO4)3] = 2 Mmd (Al3+) + 3 Mmd SO2

4

858 = 2x + 3 160
858 = 2x + 480
2x = 858 480 = 378
x = 189 S cm2 mol1

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SECTION - B
Answer 5.
(i) Ag2S + 4NaCN 2Na[Ag(CN)2] + Na2S
(ii) AgCl + 2NaCN Na[Ag(CN)2] + NaCl
(iii) Na2S + 2H2O + O2 Na2SO4 + 2H2
(iv) 4Ag + 2H2S + O2 2Ag2S + 2H2O
(v) 2Na[Ag (CN)2] + Zn 2Ag + Na2 [Zn(CN)4]
Answer 6.

(a) 2ZnS + 3O2 }}}}

%
 ,
m 2ZnO + 2SO , or 2

ZnO + C Zn + CO
ZnO + CO Zn + CO2
Refining of zinc :
(i) By distillation
(ii) Electrorefining : Further refining of zinc is carried out electrolytically. Impure zinc is made as anode. Pure
zinc acts as cathode. The electrolyte is acidified ZnSO4 solution.

Pure Zn gets deposited at cathode ZnSO4 ZZX Zn2+ + SO 2

YZZ 4

At anode Zn Zn2+ + 2e
At cathode Zn2+ + 2e Zn
(ii) Cr2+ readily loses one electron because Cr3+
(t2g3+) is more stable requires less energy. Mn3+(3d4)gains
one electron because Mn2+(3d5) is more stable requires more energy.
Answer 7.
(a) Elements in which last electron enters one of the 5f-orbitals called actinoids.
Common oxidation state is (+3)
(i) Used as nuclear fuel
(ii) Used for cancer treatment
(iii) For making atomic bombs.
(b) Paramagnetic substances are those substances which are slightly attracted by a magnet. This property is due to
the presence of one or more unpaired electrons.
Ferromagnetic substances are those substances which are strongly attracted by a magnet. This property is due to
the spontaneous alignment of domains in the same directions under the influence of applied magnetic field.
3d
Cr3+ is 3d3

No. of unpaired electrons, n = 3

s = n(n  2)

= 3s5
= 3.83 BM
Cu2+ is 3d9
n =1
s = 1(1 2)

= 3

= 1.732 BM

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SECTION - C
Question 8.

HNO2
(a) (i) and (ii) CH3 CH2CH2 NH2 CH3CH2CH2OH
(X) (Y) Propan1ol
nPropylamine CH3COCl
O
CH3 C O CH2 CH2 CH3
(Z)
n-propylacetate

(b) (i) 2CH3 CH2 Br + Ag2O }}m

% 2Ag Br + CH
3 CH 2 O CH 2 CH3

(Diethyl ether)

(ii) ethanol, acetone, acetaldehyde

CH3CHO + 3I2 + 4NaOH}}%

m CHI + HCOONa + 3NaI + 3H O
3 2

CH COCH + 3I + 4NaOH }}
3 3 2 m
% CHI + CH COONa + 3NaI + 3H O
3 3 2

CH CH OH + 4I + 6NaOH }} m
% CHI + HCOONa + 5NaI + 5H O
3 2 2 3 2

COOH
(c) 5
COOH
+ 2KMnO4 + 3H2SO4 }}}}}m 10CO
60 70oC
2 + K2SO4 + 2MnSO4 + 8H2O

Answer 9.

O O
+
NO2 N

(a) (i) Nitrobenzene or

(ii) C2H2 or Ethyne (addition polymer)

(iii) (C6H10O5)n + nH2O }}}}}m n C H

Dil H2SO4
6 12O6

Glucose

COOH
(iv) C12H22O11 + 36HNO3 6 + 36NO2 + 23H2O
COOH

(b) (i) C2H5NH2 + CH3COCl C6H5NHCOCH3 + HCl

(Acetanilide)

(ii) CH3CONH2 + Br2 + 4KOH }}

%
m CH 3NH 2 + 2KBr + K2CO3 + 2H2O
(aq) Methyl amine

(iii) C6H5NH2 + CHCl3 + 3KOH

(alc.)
}}m
% CH CH NC + 3KCl + 3H O
3 2
Ethyl isocyanide
2

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(c) Ethyl alcohol C2H5OH
Dimethyl ether CH3 O CH3
C2H5OH + PCl5 C2H5Cl + POCl3 + HCl
CH3OCH3 + PCl5 2CH3Cl + POCl3
Answer 10.
CH3
(a) C7 H8 Or

Toluene
(A)
Conc. HNO 3 + Conc. H 2SO4

CH3 CH3
NO2
+

NO2
pNitrotoluene o-Nitrotoluene
(More) (Less)
(B)
Sn/HCl

CH3

NH2
pToluidene
(C)
(i ) NaNO 2 + Dil HCl, 05C
(ii ) CuCl/HCl

CH3

Cl
p-chlorotoluene
(D)

(O)
COOH

Cl
p-chlorobenzoic acid
(E)

(b) (i) Aliphatic amine does not oxidise easily aromatic amine readily oxidises to give a brown coloured compound.

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Na/alc
(ii) C2H5CN 4(H)
C2H5CH2NH2
Ethyl
Cyanidc HNO 2

(O)
C2H5COOH + C2H5CH2OH
K2Cr2O7/H

% NH3
Br2 + KOH(aq)
C2H5CONH2 % C2H5NH2
Ethyl
amine

(iii) CH3CN + 2H2O }}}

) m
%

CH COOH + NH
3 3
(Acetic acid)
(c) (i) Ethyl alcohol gives iodoform test
Diethyl ether does not
(ii) Urea gives biuret test
Acetic acid does not
(iii) Phenol turns purple with FeCl3
Aniline does not give this test.

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EVERGREEN MODEL TEST PAPER-12

CHEMISTRY-12

PART-I
Answer 1.
(b) (i) adipic acid, hexamethylene diamine
(ii) lower, cyanides
(iii) glucose, fructose
(iv) monochloroacetic acid, inductive
(v) decreases, increases
(b) (i) 4 (ii) 3 (iii) 4 (iv) 3 (v) 3

k35C
(c) (i) It is the ratio of rate constants of reaction at 35C and 25C. Mathematically temperature coeff =
k 25C

(ii) It is an electrochemical cell in which both the electrodes are of same material but are dipped in solutions of
different concentrations.
(iii) Starch, cellulose
(iv) Butadiene and styrene
(v) The introduction of foreign impurity in a crystal to modify its properties is called doping.
(d) (i) c (ii) d (iii) e (iv) a (v) b

PART-II

SECTION - A
Answer 2.
(a) (i) Property which depends on the number of solute particles present in the given concentration of solution,
not on its nature.
Example : Relative lowering of vapour pressure
Elevation of boiling point.
(ii) = CRT
7.55 = C 0.0821 300
C = 0.307 mol L1
0.307 mol L1 = (0.307 180)g L1 = 55.26 gL1

[SO 2 ][O 2 ] [SO3 ]2

(b) (i) k1 = k2 =
[SO3 ] [SO2 ]2 [O2 ]

[SO 2 ][O 2 ]
0.15 =
[SO3 ]

[SO3 ] 100
=
[SO2 ][O2 ] 15

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2SO2 + O2 ZZX 2SO3

YZZ
[SO3 ]2
k1 =
[SO2 ]2 [O2 ]

2
k 2 = 100 = 44.44
15

Answer 3.
(a) In Na+Cl crystal, coordination of Na+ as well as Cl is 6. Cl are in ccp arrangement and Na+ ions are in octahedral
holes. Therefore, a unit cell of sodium chloride cant be a simple cube of four sodium and four chloride ions.

1 d[ICl] d [H 2 ] d [I2 ] 1 d [HCl]

(b) (i) (1) Rate = = =+ +
2 dt dt dt 2 dt

1 d [NH3 ] 1 d (O2 ) 1 d (NO) 1 d [H 2 O]

(2) Rate = = =+ =+
4 dt 5 dt 4 dt 6 dt

a
(ii) For fcc, 2 a = 4r or r =
2 2

a = 2 2 .r

= 2 2 0.144 nm
= 0.407 nm.
Answer 4.

(a)

o = Na+
O = Cl
unit cell of Na+Cl crystal
(i) Electrostatic forces of attraction
(ii) fcc
(iii) Six
(b) (i) Soap is a sodium or potassium salt of long chain fatty acid.
e.g. : Sodium stearate. Sodium chloride is added to precipitate out soap due to common ion effect.
(ii) Copper is more reactive than silver, hence it can displace Ag from AgNO3, hence Ag precipitates down.
Cu + 2AgNO3 Cu(NO3)2 + 2Ag
(iii) This is because phenolphthalein has different colours in acidic and basic solutions and end point can be
easily detected from colour change during acidbase titrations.

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SECTION - B
Answer 5.
(a) (i) In [Cr(NH3)6]3+, the central menal ion is Cr3+. Cr3+ has 21 electrons.

3d 4s 4p
3+
Cr

3+ 2 2
Cr (d sp3) d sp3

3+ 2 3
[Cr(NH3)6] d sp

NH3 NH3 NH3 NH3 NH3NH3

Hybridization sp3d2
Paramagnetic, Shape octahedral.
(ii) [Co(NH3)4 Cl2]Cl
tetraammine dichlorido cobalt (III) chloride.

(b) (i) Cl2 + Ca(OH)2 }}}}}m CaOCl + H O

40 50oC
2 2
(ii) BrF5 + 3H2O 5H+F + HBrO3
Answer 6.
(i) Organometallic compound : Compounds containing atleast one direct bond between a carbon atom of an
organic group and a metal atom.
(ii) Copper sulphate prepared by copper metal with hot concentrated H2SO4 or its oxides with dil. H2SO4.

Cu + 2H2SO4 }}
%
m CuSO + 2H O + SO
4 2 2
(conc.)
(iii) This is because AgNO3 gives different coloured precipitates with soluble halides.

NaCl + AgNO3 }m (white

AgCl + NaNO3
ppt)
NaBr + AgNO3 }m AgBr + NaNO3
(Pale yellow ppt.)

NaI + AgNO 3 }m (Yellow

AgI
ppt)
n + NaNO 3
+ AgNO3 can be used to detect Cl, Br and I ions.
Answer 7.
(a) (i) 2Na2 S2O3 + I2 Na2 S4O6 + 2NaI
(ii) AgCl + 2KCN K[Ag(CN)2] + KCl
(iii) 10 O3 + 6H2O + P4(s) 4H3PO4 (aq) + 10O2(g)
(b) O3 application used for bleaching delicate fabrics
Property : Acts as an oxidising agent
H2SO4 used in leather industry for tanning.
Property : Conc. H2SO4 used as oxidising agent.

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SECTION - C
Answer 8.

(a) (i) COOH

473 K
COOH HCOOH + CO2
Br2/H2O
(ii) CH2 OH(CHOH)4 CHO (O)
(Glucose) CH2OH(CHOH)4 COOH
(Gluconic acid)
(iii) 6HCHO + 4 NH3 (CH2)6N4 + 6H2O
(urotropine)

(iv) CH3CONH2 }}}}}}m CH CH NH + H O

4[H]
Sn / conc.HCl 3 2 2 2
OH OH
NO2 NO2
(v) + 3HNO3
Conc. H2SO4
+ 3H2O
Conc. 295K

NO2
Answer 9.
Br 2/KOH
(a) C6H5CONH C6H5NH2 (A)
CHCl3 + KOH (alc.)
Cl
St 2 /H
O

C6H5 N y C + 3H2O + 3KCl

N
ea
Na
(i)

Methyl isocyanide (D)

(i i

+
C 6H 5N2Cl 05C
C6H5OH N=N OH
(B) (C)
Azo dye
CH3COCl (D)

O
CH3 C O C6H5
(E)
(b) (i) Hinsbergs reagent
End product soluble in KOH For aniline
End product insoluble in KOH For dimethylamine
(ii) Acetone gives iodoform test, but acetaldehyde does not.
CH3COCH3 + 3I2 + 4NaOH CHI3 + CH3COONa + 3H2O + 3NaI
Answer 10.

H3C CH2 CH2 CH3

(a) (i) C4H10 Chain isomerism
CH3 CH CH3

CH3
(ii) CHCl = CHCl Geometric isomerism (cis, trans)
H Cl H Cl
C C
C C
H Cl Cl H
Cis Trans

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(iii) CH3CHOH COOH Optical isomerism.

CH3 CH3

OH H
OH
H COOH COOH
d-lactic acid l-lactic acid

(v) C2H 6O Functional group isomerism

C2H5OH and H3C O CH3
(b) (i) Zwitter ion : The amphoteric compounds, which have both acidic group and basic group in them called
zwitter ion. e.g. :- -Amino acid exists as zwitter ion.

O

CH2 C O
+
NH3
Zwitter ions
structure of glycine

(ii) Copolymer : When more than one type of monomer units combine together to form polymer, the polymer is
called copolymer.
e.g. :
Nylon 66 is made up of Hexamethylene diamine and adipic acid.
Nylon 66 is a copolymer.
(iii) Electrophile : Molecule or ion or radical in which an atom is electron deficient called electrophile.

eg. N O , BF3 etc.
2

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EVERGREEN MODEL TEST PAPER-13

CHEMISTRY-12

PART-I
Answer 1.
(a) (i) silver, lower
(ii) anhydrous ZnCl2, HCl
(iii) basic, +I
(iv) Sidewise, p
(v) liquids, oils
(b) (i) 4 (ii) 2 (iii) 4 (iv) 4 (v) 4
(c) (i) The decrease in the degree of dissociation of a weak electrolyte in the presence of a strong electrolyte having
a common ion is called common ion effect.

(ii)
St rong elec
trolyte (HCl
)

conc.

(iii) Aniline
(iv) It is the sum of the powers of the concentration terms in the rate law for a reaction.
(v) For a spontaneous reaction, G should be negative.
(d) (i) d (ii) a (iii) e (iv) b (v) c

PART-II

SECTION - A
Answer 2.
(a) (i) Tf = Kf . m
Tf = 278.8 276.8 = 2.0
2.0 = Kf 0.25

2
Kf =
0.25

= 8 K kg mol1
(ii) = i CRT
= 1 0.01 0.0821 300
= 0.2463 atm.

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(b) Diamond sp3, Graphite sp2
Diamond has tetrahedral/ close-packed structure, where central carbon atom is covalently bonded with four other
carbon atoms and there is no free electron left with carbon atoms. In graphite central carbon atom covalently
bonded with three more carbon atoms in the same layers and these layers are held together by Van der Waals force
of attraction. Hence, it is soft and due to fourth free electron it can conduct electricity.
Answer 3.
kw
(a) (i) kh = k
b

10 14 10 9
kh = = = 0.0555 1010 = 5.55 1012
1.8 s 10 5
1.8

kw
h = Ck b

10 9 108
= =
0.1 s 1.8 1.8

10 4
= = 7.5 105
1.8
(ii) pH = 3
[H+] = 103
C = 103
HA ZZX
YZZ H+ + A
Initial molar conc. C 0 0
Equilibrium conc. C(1 ) C C
Ka ZZX C2
YZZ
C2 B2
=
C

C2 B2
=
C
Ka = 105

[NO2 ]2 (mol / l )2
(b) (i) Kc = 2 = = mol1 l1
[NO] [O2 ] (mol / l ) 2 (mol / l )

pNO2 (atm) 2
2
kp = p s pO2 = = atm1
NO2 (atm) 2 s atm

(ii) 1. If temperature is increased, equilibrium will turn to that direction where that extra heat is generally backward
direction is absorbed.
2. If pressure is increased the equilibrium will shift in the forward direction.
(iii) It is given by vant Hoff equation.

K2 %H T2 T1
log K = TT
1 2.303K 1 2

K1 is equilibrium constant at T1K

K2 is the equilibrium constant at T2K

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Answer 4.
(a) (i) Rate law is
1 1
r = k < NO 2 > <F2 >

(ii) order = 1 + 1 = 2
(iii) F
(iv) 2NO2 + F2 2NO2F
(b) W = 1.8 g
I = 0.5 amp
t = 36 60 = 2160s
Q = 2160 0.5 = 1080 C
W s 96500
E =
1080
1.8 s 96500
=
1080
E = 108
Atomic mass (A) = 108 g mol
A
Charge on metal ion =
E
108
=
108
=+1
(c) (i) Phenolphthalein
KOH Strong base, CH3COOH weak acid
(ii) Methyl orange
Na2CO3 weak base, H2SO4 strong acid
SECTION - B
Answer 5.
(a) (i) 2F2 + conc. 4NaOH 4NaF + 2H2O + O2
(ii) Br2 + 2NaOH NaBr + NaBrO + H2O
(cold and dil)
(iii) XeF6 + 3H2O XeO3 + 6HF
6 2
3d 4s 4p
(b) (i) [Co(NH3)6 ]+3
2 3
d sp
No unpaired electronsDiamagnetic

6
3d 4s 4p 4d
[CoF6 ]3
3 2
sp d

From unpaired electronsparamagnetic

3d 4s 4p 4d
(ii) [Fe(H2O)6]+3
3 2
sp d

5 unpaired electrons, so more paramagnetic

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[Fe(CN)6]3
2 3
d sp

1 unpaired electron, so less paramagnetic

Answer 6.
(a) Two ores (i) Argentite (Ag2S), (ii) Horn silver (AgCl)
Steps :
Argentite ore and Horn silver

Crushing of the ore

Ore + NaCN soln + Air
Ag2S + 4NaCN + O2 2Na[Ag(CN)2] + Na2SO4
AgCl + 2NaCN Na[Ag(CN)2] + NaCl

Treatment with zinc shavings
2Na[Ag(CN)2] + Zn 2Ag + Na2 [Zn(CN)4]

Refining
Cathode : Pure silver
Anode : Impure silver
Electrolyte : Acidified silver nitrate solution
(b) Uses : (i) Used as an electrolyte
(ii) Used as in laboratory a reagent
Answer 7.

(a) (i) Fe + CuSO4 }m FeSO4 + Cu n

Blue coloured Green coloured Reddish-brown
soln. soln. ppt

(ii) 2KI + CuSO4 K2SO4 + CuI2

2 CuI Cu2I2 + I2 (Blue colourations)
(iii) No reaction
(b) (i) 4f 214 5d01 6s2
(ii) Cu2+ has 9 electrons in 3d subshell, It is a transition metal..

SECTION - C
Answer 8.
H

+H2O
CH3 CHO + CH3 MgI CH3 C OMgI CH3 CH OH + Mg OH

(a) (i) I

CH3 CH3

(ii) CH3COOH + NaOH (excess) CH3COONa + H2O

CH3COONa + NaOH }}}

%
m CH4 + Na2CO3
CaO

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+
NH2 N2 Cl
(iii)
0 5C
+ NaNO2 + 2HCl + NaCl + 2H2O
(Dil)
+ Cl
N2 Cl
CuCl/HCl

+ NH 3
(iv) CH3 COOH CH3COONH4
% P2O5

Na/alc
CH3CH2NH2 CH3CN
HONO
PCl5
CH3CH2OH CH3CH2 Cl
KCN

CH3 CH2COOH +
CH3 CH2 CN
H 2O + H

Question 9.

OH
(a) (i) 2CH3CHO + NaOH
(Dil)
}m CH3 Actaldol
CH CH2 CHO

(ii) 2C6H5CHO + conc. NaOH C 6H 5COONa + C 6H5CH 2OH

Sod. benzoate Benzyl alcohol

(iii) C6H5NH2 + CHCl3 + 3KOH}}}}}}m C H NC + 3KCl + 3H O

(alc.)
sod. benzoate
6 5 2

CH CONH + Br + 4KOH }}m

(iv)
% CH NH + 2NaBr + Na CO + 2H O
3 2 2 3 2 2 3 2
(aq)
(b) X = CH3CN
Y = CH3 CH2 NH2
Z = CH3CH2OH
Answer 10.
(a) CH3 CH2 CH2 NH2 (1)
H3C CH CH3 (1)
NH2
CH3 CH2 NH CH3 (2)
CH3
(3)
CH3 N CH3

(b) (i) chain isomerism

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e.g. CH3 CH2 CH2 CH3, and CH3 CH CH3

Butane
CH3
2Methyl propane

Functional isomerism
CH3 O CH3 and CH3 CH2 OH
Dimethyl ether Ethyl alcohol
(ii) It is a compound which is chiral and rotate the plane polarised light through a certain angle towards l. h. s. or
r.h.s.
(iii) Polarimeter
(c) (i) uera and oxalic acid
Biuret test given +ve by urea, not by oxalic acid.
(ii) Formic acid and Acetic acid.
Formic acid reduces ammoniacal silver nitrate solution, but acetic acid does not.

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EVERGREEN MODEL TEST PAPER-14

Subject : CHEMISTRY
Class : 12

PART-I
Answer 1.
(a) (i) condensation, amino acids (ii) independent
(iii) twelve (iv) position
(v) vicinal, adjacent
(b) (i) 1 (ii) 1 (iii) 3 (iv) 2 (v) 1
(c) (i) This is due to lanthanide contraction.
(ii) Sodium reacts with C2H 5OH to form C2H5ONa, but there is no reaction with ether.
(iii) Due to inter molecular Hbonding.
(iv) Due to common ion-effect dissociation of NH4OH decreases, hence less OH ions release, hence less pH.
(d) (i) d (ii) e (iii) c (iv) b (v) a

PART-II
SECTION - A
Answer 2.
(a) (i) N2O4 ZZX 2NO2 Heat
YZZ
1. Formation of NO2 will increase with increase in temperature.
2. By decreasing of pressure, formation of NO2 will increase.
(ii) 2N (N = No. of spheres)
(iii) An acid can donate proton to anode substance and a base can accept proton from another substance.

(b) G = Gof (Products) Gof (Reactants)

1
= 52 87  s 0

2
= 35 kJ mol1
G = 2.303 RT log K
35000 = 2.303 8.314 298 log K
log K = 6.1341
K = antilog (6.1341)
K = 1.301 106
(c) (i) 373K = 100C
Vapour pressure of pure water at 100C = 1 atmospheric pressure
= 760 mm of Hg

760 750
= xcane sugar
760

10
x =
760

1
= = 0.013
76

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(ii) V = nRT = osmotic pressure

w
V = M RT V = volume
B

n = No. of moles of solute

R = Universal gas constant

w
MB = RT T= Temp. (Kelvin scale)
QV
M = Mol. wt. of solute
Answer 3.
(a) (i) Crystalline solids : Building constituents arrange themselves in a 3D-recurring regular geometric pattern
which extends to very large distance compared to inter-particle distances, thus, they are of long-range
order. They have fixed melting points and definite heats of fusion. These are anisotropic.
Amorphous solids : Arrangement of different building blocks are not regular, i.e. the constituents are
arranged randomly. There are of short range order they dont have fixed melting points and definite heats
of fusion. These are isotropic.
(ii) The number of ions surrounding the oppositely charged ion in ionic crystal is determined by the relative
size and charge of the ion, which can not have coordination no. 12 due to large sizes of ions.

1
(iii) Simple cubic = 8=1
8

1 1
fcc = 8+ 6=4
8 2
(iv) 3 in the layer lattice

(b) (i) Order Molecularity

1. Sum of the powers of concentration terms in the Total number of the particles take part in the
rate law for a reaction. elementary reaction.
2. Order can be 0, or fraction. Molecularity can not be 0 or fraction.
3. Experimentally determined. Theoretically determined.

k2 E act T2 T1
(ii) log k = TT
1 2.303 R 1 2

E act 308 298

log 2 = 308 s
8.314 298
2.303 s
1000
Eact = 51.48 kJ mol1
(c) (i) Rate of a chemical reaction is proportional to the product of active masses of reactant molecules are
anisotropic with active mass of each substance raised to the power equal to its coefficient in the balanced
chemical equation for the reaction.

E a
(ii) Slope =
2.303R l
log k
Ea = 2.303 R Slope
m
1/T

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Answer 4.
(a) (i) Weak acid on dilution releases less H+ ion, as compared to a strong acid. Hence pH value is high. Acetic
acid is a weak acid and HCl is strong.
(ii) CaC2O4
In acidic medium ionic product of CaC2O4< ksp of CaC2O4. Therefore, CaC2O4 dissolves.
(iii) This is because on dilution its degree of ionisation increases.
0.0591 0.2
(b) (i) Nernst equation Ecell = log
3 0.1
0.0591
= log 2
2
0.0591
= 0.3010
2
= 0.0295 0.3010
= 0.0089
(ii) (a) A2+/A and C+2/C, Ecell = 0.337 (0.763) = 1.10 V
(b) When B is added to a solution containing C2+ ion, C gets precipitated similarly when B is added to
solution containing H+ ion., H2 is produced.
(c) On mixing equal volumes of two solutions
0.015
[NH4OH] = = 0.0075 N
2
0.15
[NH4NO3] = = 0.075 N
2
Now, for a basic buffer
[Salt]
pOH = pkb + log
[Base]

0.075
= log(1.8 105) + log
0.0075
= 4.7447 + 1
= 5.7447
pH = 14 pOH
= 14 5.7447
= 8.2553

SECTION - B
Answer 5.
(a) Copper pyrites
CuFeS2

Crushed and sieved

Concentrated by froth floatation

Roasting in the reverberatory furnace
S + O2 SO2

4As + 3O2 }}
%
m 2As O 2 3

2Cu FeS2 + O2 }}
%
m Cu S + 2FeS + SO
2 2

Silica + coke + Roasted ore Matte
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Smelting in the blast furnace in O2
2FeS + 3O2 2FeO + 2SO2
Cu2O + FeS Cu2S + FeO
FeO + SiO2 FeSiO3

Molten matte

Bissemerisation in O2

Blister copper (98% Cu + 2% impurities)
(Electrolytic refining)

Pure Cu
(b) (i) 2Cu + 4HCl + O2 2Cu Cl2 + 2H2O
(dil)
(ii) 3Cu + 8HNO3 3Cu (NO3)2 + 2NO + 4H2O
(dil)
(iii) Cu + 2AgNO3 Cu (NO3)2 + 2Ag
(iv) Fe + CuSO4 FeSO4 + Cu
Answer 6.
(a) (i) Due to strong H-bonding (intermolecular) In HCl, lowest van der waals forces of attraction.
(ii) Zinc is more active, hence it can displace Ag from argentocyanide.
(b) (i) Oxidation of MnO2
2MnO2 + 4KOH + O2 }}}m 2K MnO
Fuse
2 4 + 2H2O
(ii) Conversion of K2MnO4 to KMnO4 Mixed with H2O and then filter, then oxidation.
3K2MnO4 + 2CO2 2KMnO4 + MnO2 + 2K2 CO3
Or
by electrolytic oxidation method
2K2MnO4 + 2H2O 2KMnO4 + 2KOH + H2
Answer 7.
(a) (i) 2KMnO4 + 3H2SO4 + 5NaNO2 K2SO4 + 2 MnSO4 + 3H2O + 5NaNO3

(ii) K2Cr2O7 + 4NaCl + 6H2SO4 }}m

% 2 CrO Cl
2 2 + 6NaHSO4 + 3H2O

(iii) 3Fe + 4H2O }}m

% Fe O + 4H
3 4 2
(Red Hot)
(b) (i) It is used to prepare silver halides used in photography.
(ii) It is used for making hair dyes.
(iii) It is used for preparing silver mirrors.
(iv) It qualitative and quantitative analysis.

SECTION - C
Question 8.

(a) (i) CH3COOH + C2H5OH }}}}}

k}}}}
H SO
}m CH COOC H
2 4 %
3 2 5 + H2O

NO2
Conc H2SO4
(ii) + HNO3
%
+ H2O

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}} m
% CHI + HCOONa + 5NaI + 5H O
(iii) C2H5OH + 6NaOH + 4I2 3 2

3 m CH CONH }}}
(iv) CH COOH }}}}
 NH3
%
m CH CN3 2
P2 O5
3

(b) DNA RNA

1. The sugar portion is 2-Deoxyribose. 1. The sugar portion is ribose.
2. Heterocyclic bases present are adenine, 2. Heterocyclic bases present are adenine, guanine
guanine, cytosine and thymine cytosine and uracil
3. It has double stranded -Helix structure. 3. It has single stranded -Helix structure.
4. It has no further types. 4. It is further of three types : m = RNA, r = RNA
and t = RNA.

(c) Vitamin Chemical name Deficenly disease

A Retinol Xerophthalmia

D Ergocalciferol Rickets

E Tocophenol Sterlity

Answer 9.
(a) (i) X = CH3 CH = CH2
Y = CH3 CH = CH2
(ii) X = CH3CN, Y = CH3COOH
(iii) Y = C6H5Cl
Y = C6H5CN

(b) (i) Neutral C6H5NO2 + 4[H] }}}}}

%
m C6H5 NHOH + H2O
Zn / NH 4Cl

(ii) Acidic C6H5NO2 + 6[H] }}}} m C6H5NH2 + 2H2O

Sn / HCl

(iii) Catalytic reduction C6H5NO2 + 3H2 }}m C6H5NH2 + 2H2O

Pt

(O)
(c) CH3 CH CH2 CH3 % CH3 C CH2 CH3
OH O
(A) Butan 2-one
Sec. butyl alcohol (B)

Butan-2-one gives iodoform test (It gives CHI3 on heating with I2 and NaOH)

CH3 CH3
m
OMgI
C = O + CH3 MgI C
CH3 CH2 C2H5 CH3
(B)
+ H2O
+
H

CH3 OH I
C + Mg
C2H5 CH3 OH
(C)
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Answer 10.
(a) (i) (a) RNH2 + CHCl3 + 3KOH (alc.) R N
Primary
m C + 3KCl + 3H2O
Alkyl
amine isocyanide

(b) RI + AgCN
Alkyl
}}}}}}}

m
C2 H5OH H 2O
RNC
Alkyl
+ AgI
iodide isocyanide

(ii) Primary amine : Forms monoalkyl sulphonamide which on treatment with alkali gives a water soluble salt.
Secondary amine : Forms dialkyl sulphonamide which does not dissolve in alkali.
Tertiary amine : does not react with Hinsbergs reagent.
(b) (i) Carbohydrates which reduce Tallens reajent or Fehlings solutions are called reducing sugars whereas
the carbohydrates or sugars which do not reduce these regjents are called non-reducing carbohydrates.

(ii) C6H12O6 }}}}}}}m 2C2H5OH + 2 CO2

Enzyme Zymase
Fermentation
(Glucose)

(c) (i) Globular Proteins Fibrous Proteins

1. These are cross-linked condensation 1. These are linear condensation polymers of -amino
polymers of -amino acids. acids.
2. These are soluble in water. 2. These are insoluble in water.
3. These cannot resist changes in pH 3. They cannot resist small changes in pH and temperature.
temperature.
4. These are in the form of globules. 4. These are in the form of fibres.

(ii) It is the pH of the solution at which there is no net migration of -amino acid molecules towards any
electrode under the influence of electric field.

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EVERGREEN MODEL TEST PAPER-15

Subject : CHEMISTRY

PART-I
Answer 1.
(a) (i) inductive effect, more (ii) condensation, amino acids
(iii) Friedel Crafts, toluene (iv) no -hydrogen atom, Cannizzaros
(v) copper sulphate, violet
(b) (i) 2 (ii) 3 (iii) 2 (iv) 3 (v) 4
(c) (i) No, H-bonding for H2S and intermolecular H-bonds in water.
(ii) Because ionic product of soap exceeds its ksp value.
(iii) OH group has +R effect.
(iv) This is due to more and stronger H-Bonds in organic acids, than in alcohols.
(v) Copper is more reactive and its reduction potention is less than silver, hence it displaces silver from AgNO3
and itself oxidises.
(d) (i) e (ii) a (iii) d (iv) b (v) c

PART-II

SECTION - A
Answer 2.

0.5
p0 p 72.8 72 M
(a) p0 = XB Or = 100
72.8
88

0.8 100 0.5

=
72.8 88 M

0.5 s 72.8 s 88 9.1 s 22

M = =
0.8 s 100 5
= 9.1 4.4 = 40.04 g mol1
(b) = i CRT l =1

100
7.65 = 1 0.0821 300
M

7.65 s 180
=W
0.0821 s 300

7.65 s 180
W = = 57.4 g
0.821 s 300

(c) At equilibrium both the forward and backward reactions continue to take place at same speeds.
State of chemical equilibrium is dynamic in nature.

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Answer 3.

S s N A s a3
(a) (i) A =
Z

7.2 s 6.022 s 1023 s (2.88 s 10 10 )3

=
2
A = 51.8 g mol1
(ii) The solids in which building constituents are not regularly arranged, but randomly, called amorphous
substances.
e.g.. : rubber, wood etc.
(b) (i) Face centered cube.
(ii) Electrostatic force of attraction.
(iii) 6
(iv) Octahedral.
(c) (i) l Concentration of reactants Rate of reaction increases, with increase of reactant concentration.
l Catalyst Presence of positive catalyst increases the rate of reaction.
(ii) Arrhenius equation is

k = Ae E a / RT
k = Rate const.
A = Frequency factor of Arrhenius const.
Ea = Activation energy
R = Universal gas const.
T = Absolute tranp.
Answer 4.
(a) (i) Cu Cu2+ + 2e
2Al+ + 2e 2Ag
Cu + 2Ag+ Cu2+ + 2Ag Cell reaction n = 2
x =2
(ii) Eocell = EoAl E oCu = 0.80 0.34 = 0.48 V
Nernst equation is :
2
Ag 
0.0591
Ecell = Eocell + log Cu 2 
2

0.0591 (102 )2
= 0.46 + log
2 101
0.0591
= 0.46 + log 103
2
3 s 0.0591
= 0.46 log10
2
0.1773
= 0.46
2
= 0.460 0.0887
= 0.460 0.089
= 0.371 V
G = nF Eocell
= 2 96500 0.371
= 77.2 kJ
= ve in the cell reaction is spontaneous

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(b) (i) Ksp = [Ag+] [Cl] 1.0 1010 = S S

S = 10 10

= 105M
(ii) NaCl Na+ + Cl
[Cl] = 0.2 M
Ksp = [Ag+][Cl] = 1.0 1010

10 10
[Ag+] =
0.2

= 5 1010
Solubility of AgCl = 5 1010M
(c) (i) This is because in graphite each C-atom is left with one free electrons.
(ii) This is because Ionic product of BaSO4 exceeds its Ksp value.

SECTION - B
Answer 5.
(a) (i) [Co(NH3)3 (H2O)2Cl]+2
1. NH3 = No charge
H2O = No charge
Cl = 1
2. Octahedral
(ii) K+ [Fe(CN)6]4
K4[Fe(CN)6]
(b) (i) F2 + 2NaCl 2NaF + Cl2
(ii) Due to absence of d orbital in the valence shell of F-atom, Fluorine is not able to form polyhalides.
Answer 6.
Two important ores of zinc are
zinc blende ZnS
Calamine ZnCO3
The various steps involved in the extraction of Zn from zinc blende are :
1. Crushing of ore
2. Grinding of ore
3. Concentration of the ore by Froth floatation process.
4. Roasting : The concentrated ore is then roasted at 1200 K.

2ZnS + 3O2 }}
%
m 2ZnO + 2SO 2
5. Reduction of ZnO

ZnO + C }}}}m Zn + CO
1673K

6. Refining of Zn
The impure zinc obtained above is refined by distillation and then by electrorefining.
Here impure zinc is made as anode and pure zinc acts as cathode. The electrolyte is an acidified solution of zinc
sulphate.

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On passing electric current, the following reactions take place.

ZZX Zn2+ + SO 4
ZnSO4 YZZ
2

At Cathode
Zn2+ + 2e Zn
At anode
Zn 2e Zn2+
Therefore, pure zinc from amode gets deposited at cathode through the electrolyte.
Answer 7.
(a) (i) Zn + 2NaOH
(conc.)
}} m
% Na ZnO + H
2 2 2

2 Al + 2NaOH + 2H O }}}m 2NaAlO + 3H

Boil
(ii) 2 2 2
(iii) Fe + CuSO4 FeSO4 + Cu
(b) (i) As electronegativity decreases down a group, hence tendency to show-2 state also decreases.
(ii) Going down a group, size of atoms increases, hence, ionisation decreases, hence compound formation is
possible.

SECTION - C
Answer 8.
(a) (i) (a) CH3 CH2 CH2 O CH3
1Methoxy propane
(b) CH3 CH2 O CH2 CH3
Ethoxy ethane
(c) CH3 O CH CH3
CH3
2Methoxy propane
(ii) 6HCHO + 4NH3 (CH2)6 NH4 + 6H2O
Hexamethylene tetramine
CH3CHO + NH3 CH3 CH = NH + H2O
Acetaldimine
NH3 Br2/KOH
C6H5COOH C6H5CONH2 C6H5NH2
%
(A) (Aniline) 68% NaOH
(B) 573 K
NaNO2 + HCl + CuCl + Dil HCl 300 atm.
(b) C6H5NH2 C6H5NCl C6H5Cl C6H5OH
0 5C Chlorobenzene Phenol
(C)
A Benzamide
B Benzonitrile
C Benzene diazonium chloride
D Chlorobenzene
E Phenol
Answer 9.

(a) (i) CH3 COCl + H2 }}}}}}}m CH CHO + HCl

PdBaSO 4
S, Xylene, 413K 3

(ii) CH3CONH2 }}}}}

%
m CH NH
Br2 / KOH 3
3 2

(b) (i) Thermoplastic Thermosetting

Softens on heating, hardens on cooling On heating. On heating, they decompose and can not
can be remoulded e.g. : teflon, PVC be remoulded e.g. : Phenol-formaldehyde and Bakelite

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(ii) Sec butyl alcohol represents two enantiomers.

CH3 CH3

OH H
HO
H C2H5 C2H5
Hypothetical
mirror
d-sec. butyl l-sec. butyl
alcohol alcohol
(Enantiomers)
(Non-superimposable
mirror images of each
other)
Answer 10.
(a) The monomers are :

Polymer Monomers Use

(i) Bakelite Phenol and formaldehyde Electrical goods, mica
OH
+ (H CHO)

(ii) Teflon Tetrafluoroethylene (CF2 = CF2) Coating non-stick frypans

(iii) PVC Vinyl Chloride (CH2 = CH Cl) Shoe soles

CH = CH2
(iv) Polystyrene Styrene Radio and television bodies.

(v) Buna-S Butadiene and styrene Tyres of automobiles

CH = CH2
(CH2 = CH CH = CH2),

(b) (i) CH3CN + 2H2O }}}}

%
m CH COOH + NH
Dil HCl
3 3
Acetic acid

CONH2 CN
P2 O 5
(ii) %
+ H2O
Benzonitrile

%
(iii) C2H5 NH2 + CHCl3 + 3KOH C 2H5NC + 3KCl + 3H2O
(alc.) (Ethylisocyanide)

OH
alc.
(iv) + Zn
%
+ ZnO
(dust) Benzene

+
N y N Cl Cl
CuCl/HCl
(v) + N2
Chlorobenzene

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EVERGREEN MODEL TEST PAPER-16

Subject : CHEMISTRY
Class : 12

PART-I
Answer 1.
(a) (i) Rate constant (ii) sodium alkoxide, alkyl halide
(iii) eight (iv) sp 2
(v) Faster
(b) (i) 4 (ii) 2 (iii) 3 (iv) 3 (v) 2
(c) (i) After releasing H+, phenoxide ion is resonance stablised, hence H+ release is facilitated. But after releasing
H+, ethoxide ion becomes unstable due to +I effect of C2H 5 group, hence not facilitated. Therefore, phenol
is more acidic than ethanol and can change blue litmus solution red.
(ii) F2 forms oxyacid under ice-cold condition, but the compound is not stable, it decomposes immediately to HF.
Also F does not have any vacant d-orbital in its valence shell.
(iii) They form azeotropic mixture and produce a constant boiling mixture.

0.693
(iv) t = , k(Rate constant) t is independent of initial concentration.
k
(v) This is because of concentrations of the reactants goes on decreasing.
(d) (i) c (ii) d (iii) a (iv) e (v) b

PART-II

SECTION - A
Answer 2.

3 3.42

60 342
(a) (i) = CRT = 0.150 0.0821 300

(V = 100 + 50 = 150 mL)

1 1

20 100
= 0.0821 300
0.150

= 0.0985 atm
(ii) With increase of pressure, boiling point increases, hence cooking becomes faster.
(b) AB ZZX A + B
YZZ
1 1 1
No. of moles at equilibrium
2 2 2

1 1 1 3
Total Number of moles at equilibrium = + + =
2 2 2 2

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At equilibrium

1
2 1
pAB = 3 . P = P
3
2

1
1
pA = 23 . P = P
3
2
1
2 1
pB = 3 . P = P
2 3

pA s p B
Kp =
pAB
1 .P. 1 .P
3 3
= 1P
3
1
Kp = P
3

3
4 64
3 3
[C] 27 32 2
(c) (i) QC = = = = = 10 = 10.67
[A][B] 1 2 2 3 3
3 3 9

1. QC < KC, hence the eqbm will shift in the forward direction.
2. QC > KC, hence the eqbm will shift in the backward direction.
3. QC = KC It is a state of chemical eqbm.
(ii) There is no effect of temperature on the yield of reaction. With the increase in temperature the rate of
forward (exothermic) reaction will decrease and that of backward reaction will increase.
Answer 3.
(a) (i) This is because Ksp for CuS is low whereas Ksp for ZnS is high. In acidic basic solution, [S2] is low but
ionic product for CuS > Ksp CuS gets precipitated. In alkaline medium [S2] is more and Ionic product
of ZnS exceeds its Ksp, This gets precipitated.
(ii) NaCl gives two ions after dissociation, hence i > 1, hence depression of freezing point more, then urea
does not undergo any change.
(iii) k f = 5 103
k b = 3 102

5 s 10 3
kc =
3 s 102
= 1.67 105
(b) (i) It is the number of oppositely charged ions surrounding an ion in a crystalline solid.

(ii) Covalent crystals Metallic crystals

(a) Made-up of neutral atoms. (a) Made-up of postively charged ions and surrounded by
free electrons.
(b) Covalent Bond (b) Metallic bond.
(c) Poor conductors of electricity. (c) Good conductors of electricity.

(iii) With the increase in temperature electrical conductivity of metallic conductors decrease.
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(c) (i) Head on overlapping of p-orbitals produce -bond.

Lateral overlapping of p-orbitals produce -bond
(ii) 1. Similarities :
(a) Both are made-up of ions
(b) +ve ion is surrounded by ve ions or electrons.
Differences :
(a) Ionic crystals are made of +ve and ve ions, Metallic crystals +ve metal ions and electrons.
(b) Ionic crystal has strong electrostatic force of attraction, ionic bond or metallic bond is present in
metallic crystal is weak bond.
2. This is due to the presence of strong electrostatic forces of attraction between oppositely charged ions.
(iii) The more is the interparticle attractive forces in a crystal, then more will be its stability and more will be its
melting point.

Answer 4.

(a) (i) dm (CH3COOH) = dm (CH3COONa) + 0m (HCl) dm (NaCl)

= 91 + 426.2 126.5
= 390.7 ohm1 cm2 mol1
(ii) Charge on O2 ion = 2 1.602 1019C
= 3.204 1019C
(iii) pH of a solution is the negative logarithim of molar concentration of its H+ ions.
Initial molar conc. HA ZZX
YZZ H+ + A
C 0 0
Equilibrium molar concentration C(1 ) C C
= Degree of dissociation
C = 0.1 M
= 1%

1
=  102
100
[H+] = C
= 0.1 102
= 103M
pH = log [H+]
= log 103
= +3 log 10
=31
=3
(b) Buffer solution : It is a solution which resists the change of pH of a solution on addition of small amount of
acid or base or on dilution.
CH3COONa CH3COO + Na+
CH3COOH ZZX CH3COO + H+
YZZ
On addition of base, H+ react OH, hence increases further dissociation of CH 3COOH, so as to maintain
original [H+] and does not change pH.
H + ions combine with CH3COO and forms CH3COOH (unionised). [H+] remains same, hence pH remains
unchanged.

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(0.40)
(c) (i) pH = 14 (log 1.8 105) + log
(0.20)
On addition of acid
= 14 (4.7447) + log 2
= 14 4.7447 + 0.3010 = 9.5503
(ii) These are the curves obtain by plotting solubility against temperature. The sharp break in solubility
curve indicates there is a sudden change in solubility i.e., first it increases and than starts decreases as
temperature increases.

SECTION - B
Answer 5.
(a) (i) Concentration of chromite ore.
(ii) Conversion of concentrated chromite ore into Na2CrO4

4FeCr2O4 + 8Na2CO3 + 7O2 }}}m 8Na CrO + 2Fe O + 8CO

Fuse
2 4 2 3 2
(iii) Conversion of Na2CrO4 into Na2Cr2O7

2Na2CrO4 + H 2SO 4 Na2Cr2O7 + Na2SO4 + H2O

(Conc.)

(iv) Conversion of Na2Cr2O7 into K2Cr2O7

Na2Cr2O7 + 2KCl 2NaCl + K2Cr2O7
Uses :
(a) Used in quantitative analysis
(b) Used in analytical chemistry.
(b) (i) Br2 + 2NaOH NaBr + NaOBr + H2O
(Dil)

(ii) 3Cl2 + 8NH3 N2 + 6NH4Cl

Answer 6.

(a) (i) H2S + 2HNO 3 3H2O + 2NO + 3S

(Dil)

(ii) I2 + 5O3 + H2O 2HIO3 + 5O2

(b) (i) [Fe(CN)6]3 has one unpaired electron hence paramagnetic.
[Fe(CN)6]4 has no unpaired electrons, hence diamagnetic.
(ii) In Ni(CO)4 Ni is in sp3 hybridisation state, hence tetrahedral.
In [Pt (NH3)2Cl2] Pt is in dsp2 hybridisation state.
(iii) Due to splitting up of five d orbitals in an octahedral field, electrons get promoted to higher level, d d
transition. Light blue-green colour is absorbed and purple light is emitted for [Ti(H2O)6]3+.
But for [Sc(H2O6]3+ no light or colour from to visible region is absorbed.
because Sc3+(3d0) has no unpaired electron and no d d transition is possible.
Answer 7.

(a) }}
(i) 2AgNO3 m
% 2AgNO + O
2 2

(ii) Cu + 2H SO }} m
% CuSO + SO + 2H O
2 4 4 2 2
(Conc.)

(iii) CuSO4 + 2NH4OH Cu(OH) 2 + (NH4)2SO4

(Blue ppt.)

Cu(OH)2 + 4NH4OH [Cu(NH3)4]SO4 + H2O

Deep blue solution

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(b) XeO3
XeF6 + 3H2O }}}}}}}m XeO
Complete hydrolysis
3 + 6HF

sp3
Xe

Trigonal Pyramidal

XeOF4
XeF6 + H2O }}}}}m XeOF
Partial hydrolysis
4 + 2HF

Xe sp3d 2

Square pyramidal

SECTION - C
Answer 8.
(a) (i) When steam is passed through heated coke, water gas (H2 + CO) is produced.

C(s) + H2O(g) }}
%
m CO + H 2
Water gas
CH2 CoO
CH3
+ H2 + CO C=O
180 C, 150 atm
CH2 Water gas CH3
Acetone

CO + 2H2 }}}}}}m
ZnO  Cr2 O3
573K, 300atm
CH 3OH
Methyl alcohol

OH O
CH3 Ba(OH) 2
(ii) 2 C=O CH3 C CH2 C CH3
CH3
CH3
Acetone 4-Hydroxy-4methyl pentan2one
(b) CH3  CH 2  CH 2  CH 2  CH 2 CH3  CH 2  CH  CH  CH3
Pent 1ene Pent 2 ene
Pent-2-ene showsgeometrical isomerism
H5C2 H H5C2 H
C C

C C
H3C H CH3 H
Cis-Pent-2-ene Trans-Pent-2-ene
(c) Ethyl amine (C2H5 NH2) is more basic than NH3. This is because C2H5 group has +I effect and therefore
electron density is increased over N-atom and the lone pair of electrons on N-atom is more available for sharing
with proton.

Answer 9.
(a) (i) (C2H5)3 N > (C2H5)2NH > C2H5NH2 > NH3
(ii) Due to electron withdrawing effect of NO 2 group, the electron density over benzene ring is very much
decreased.
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(iii) As lone pair on nitrogen delocalised in benzene ring, hence it is less available, hence less basic than
aliphatic amine.

(b) (i) CH3COCH3 + 3I2 + 4NaOH }}

%
m CHI + CH COONa + 3NaI + 3H O
3 3 2

(ii) 2HCHO + NaOH HCOONa + CH3OH

(Conc.)

%
(iii)
OH + CHCl3 + 3NaOH OH + 3NaCl + 2H2O
CHO

Phenol Salicylaldehyde

(iv) C H N Cl
6 5 2
+
}}}}}m C H Cl + N
CuCl / HCl
6 5 2

(c) (i) Acetic acid gives CO2 with NaHCO3 solution but acetone does not.
CH3COOH + NaHCO3 CH3COONa + H2O + CO2
CO2 turns freshly prepared lime water milky.
(ii) Acetaldehyde reduces Fehling solution to give red precipitate of Cu2O but benzaldehyde does not

CH3CHO + 2Cu 2  5OH

(From Fehling's solution)
}}
%
m Cu 2O n + CH3COO + 2H2O
(Red ppt.)

Answer 10.
(a) (i) A = CH3CH2COOH (Propanoic acid)
B = CH3CH2CONH2 (Propanamide)
C = CH3CH2CN (Propane nitrile)
A = CH3CH2COOH (Propanoic acid)
D = CH3CH2CH2NH2 (Propan-1-amine)
E = CH3CH2CH2 OH (Prepan-1-ol)
The reactions taking place as :
+NH3
CH3CH2COOH % CH3CH2CONH2
(A) (B)
% P2O5

+2H 2O
CH3CH2COOH CH3CH2CN
H+, %
(A) (C)
Li[AlH4]
Oxidation (O)
HONO
CH3CH2CH2 OH CH3CH2CH2NH2
(E) (D)

O H
Monomer
C N
CH2
(b) (i) Nylon-6 is polymer of Caprolactam H2C
CH2
CH2 CH2 Caprolactam

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O H
C N O H
CH2 Polymerisation
CH2 C (CH2)5 N n
CH2
Nylon-6
CH2 CH2
Caprolactam
Nylon-66 is a copolymer of adipic acid and hexamethylene diamine Monomers are Adipic acid,
HOOC (CH2)4 COOH and Hexamethylene diamine H2N (CH2)6 NH2
O O
n HO C ( CH2)4 C OH + n H2N ( CH2)6 NH2
Polymer

O O
O C (CH2)4 C NH (CH2)6 NH + (2n 1)H2O
n
Nylon-66

(ii) On the basis of sources polymers can be classified as :

(a) Natural polymers e.g. rubber, wood etc.
(b) Semi-Synthetic polymers e.g. vulcanised rubber.
(c) Synthetic polymers e.g. Nylon-66, Bakelite etc.
(c) (i) HCHO + 4NH3 (CH 2)6N4 + 6H2O
Hexamethylene tetramine

CH3CHO + NH3 CH3 CH = NH + H2O

Acetaldimine

(ii) (a) CH3NC + H2O }}}m

%H , CH3NH2 + HCOOH
Methylamine

(b) CH3NC }}}}}


m CH NH CH
Li(AlH4 )
4(H)
3 3
Dimethyl amine

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EVERGREEN MODEL TEST PAPER-17

Subject : CHEMISTRY

PART-I
Answer 1.
(a) (i) greater (ii) 1
(iii) negative, greater (iv) tin, pigment
(v) zero
(b) (i) 2 (ii) 2 (iii) 1 (iv) 2 (v) 3
(c) (i) Starch is a linear polymer of -D-glucose units whereas cellulose is a polymer of -D-glucose units.

(ii) Functional isomers have different functional groups e.g., CH3 CH2 CHO and CH3 C CH3

O
In position isomers, functional group occupy different positions.

CH 3  CH 2  CH 2  OH and CH3 CH CH3

Pr opan 1 ol
OH
Propan-2-ol

(iii) A white precipitate is obtained.

OH OH
Br Br
298 K
+ 3Br2 + 3HBr
(aq)
Br
2,4,6Tribromophenol
(White ppt)

(iv) Acetylene, C2H2

Ethyne is a monomer of benzene

Fe tube
3CH y CH C 6H 6 Or
775K
Benzene

Addition polymerisation
(v) Aniline is obtained

OH NH2
Anhyd. ZnCl2
+ NH3 + H2O
(alc.)
Phenol Aniline

(d) (i) (d) (ii) (b) (iii) (c) (iv) (a) (v) (e)

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PART-II
SECTION - A
Answer 2.
(a) (i) According to Raoults law, the relative lowering in vapour pressure of a solution is equal to the mole
fraction of the solute i.e.,
0
pA  pA
0
= xB
pA

nB nB
= n  n = n (For dilute solutions)
B A A

0 = V.P. of pure solvent

pA
pA = V.P. of solution.
nB = No. of moles of solute
nA = No. of moles of solvent
relative lowering in vapour pressure of solution depends upon the number of moles of solute dissolved in a
given amount of solvent and is independent of nature of solute particles, therefore, it is colligative property.
(ii) X undergoes dissociation, hence i > 1.
Y undergoes association, hence i < 1.
urea doesnt undergo any change, hence i = 1.
(b) (i) N2 + 3H2 ZZX
YZZ 2NH3
Initial no. of moles 1 3 0
No. of moles at equilibrium 0 0 2
4 2
Ratio of initial and final volumes = 
2 1
(ii) Concentration, Temperature and Pressure.
(c) (i) It indicates reduction potential of anode is more than cathode and the cell will not function.
(ii) Number of atoms or ions surrounding another atom or ion of opposite charge.
(iii) ve slope

log k
E a
Slope =
2.303R

m 1/T
Ea = 2.303 R slope.
Answer 3.

Ea
(a) (i) Slope =
2.303 R
Ea = 2.303 R slope
2.303 s 8.314 s (584)
=
1000
= +111.838 kJ mol1

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(ii) (a) N2 + 3H2 }}}}}m 2NH3

k}}} Fe, Mo
(775K)
400 atm

}}m 2SO3
(b) 2SO2 + O2 k}}
Pt

}}}}}
(c) 4NH3(g) + 5O2(g) k}}}}
Pt, 800 C
}m 4NO + 6H2O
o

(iii) -molecular orbital is formed by the axial overlapping of atomic orbitals whereas -Molecular orbital is
formed by the sidewise overlapping of atomic orbitals.
(b) (i) Fe(OH)2 will be precipitated out first because it has lower Ksp value as compared to Mg(OH)2.
(ii) [NH4OH] = 0.45 M
[NH4Cl] = 0.75 M
[Salt]
pH = 14 pk b log
[Base]
5 0.75
= 14  log(1.8 s 10 )  log
0.45
= 14 [4.7447 + 0.2218] = 9.00
(c) (i) Q = I t = 0.2 10 60 C = 120 C
96500C 6.023 1023 electrons
120C 7.488 1020 electrons
Cu2+ + 2e
Cu
2 electrons deposit = 1 Cu atm
7.488 1020 electrons will deposit = 3.744 1020 Cu atoms
(ii) M(OH)2 }}}m M
Water 2+ + 2OH

[OH] = 2 0.01 M = 2 102

1014
[H+] = = 5 1013
2 s 102
pH = log[H+] = log (5 1013)
= 13 log 10 log 5 = 13 1 0.699
pH = 12.301
Answer 4.
(a) (i) fcc. type; metal atoms occupy the corners of the cube and the centres of its faces of a cube.
Closest neighbour 12.
fcc. type

ClE
(ii)
4E+
C ClE , Regular tetrahedral geometry, N = 0
ClE
ClE

2E+
E E , Linear geometry, N = 0
O=C=O

2E

O , Bent or angular geometry, N = 0

E+
H HE+

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[salt]
(b) (i) pH = pka + log
[acid]
(ii) Factors affecting electrode potential-
(a) Nature of electrode.
(b) Concentration of metal ions in the solution
(c) Temperature.
(iii) The conductance of a solution containing 1 gm equivalent of dissolved substance
Units S cm2 equiv1 or ohm1 cm2 equiv1
(iv) Electrochemical equivalent of a substance is the amount of it produced by a current of one ampere
strength in one second. The amount decomposed by one coulomb of electricity through the solution of
the electrolyte.

r 60
(c) (i) Here  = = 0.442
r 136

Radius ratio lies in the range. 0.414 0.732 is for octahedral structure, hence co-ordination no. is for
Li+ ion = 6 and F ion = 6.

89
(ii) Solubility of NaCl at 10C = s 1000
200
= 445 gL1

172
Solubility of NaCl at 70C = s 1200
200
= 860 gL1
On cooling from 70C to 10 C = 860 445
= 415 gL1 of NaCl will precipitate out

415
Hence, on cooling 200 mL of solution = s 200
1000
= 83 g of NaCl will precipitate out.

SECTION - B

Answer 5.
(a) (i) Copper is extracted from low grade ores by hydrometallurgy. The ore is powdered and is reduced with dil
H2SO4 or bacteria when copper goes into solution as Cu 2+ ions. This solution is then treated with scrap
iron.
2Cu + 2H 2SO 4 + O2 2CuSO4 + 2H2O
(dil)

CuSO4 + Fe FeSO4 + Cu
Fe can displace copper from CuSO 4 because Fe lies above copper in the electro chemical series.
(b) (i) 2KMnO4 + H2O + KI 2MnO2 + 2KOH + KIO3

(ii) 2KMnO4 + 3H 2SO 4 + 5H2S K2SO4 + 2MnSO4 + 3H2O + 5S

(dil.)

Answer 6.
(a) (i) Ionization energy 1st, 2nd electrons release is normal, IP gradually increases. 3rd IP is abnormally
low as they get half-filled or fullfilled 3d subshell after releasing 2nd electron.
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(ii) They normally have high melting point and boiling point due to metallic bonds and covalent bonds
formed by the overlapping of half filled (n-1)d orbitals.
(iii) Since in case of transition metals, orbital motion of the electron is quenched by the electric field of the
environment, the magnetic moment value is given by spin-only formation.

eff = n(n  2) BM
(b) (i) 2KMnO4 + 3H2SO4 + 5C2H5OH K2SO4 + 2MnSO4 + 5CH3CHO + 8H2O
(ii) FeSO4 + Cu FeSO4 + Cu

Answer 7.

(a) (i) NaCl + Conc H2SO4 }}}}

 o
m NaHSO
200 C
4 + HCl
(b) (i) Above 200C, Na2SO4 is produced which is sticky and create a hard coating at the bottom of the jar. It
resists uniform heating of mixture and removing of Na2SO4 becomes difficult.
(ii) It decomposes under sunlight.

SECTION - C
Answer 8.
(a) (i) Because amino group is susceptible to oxidation and NH2 group activates the benzene ring for
polysubstitution during electrophilic substitution reactions.
Hence, nitration can be accomplished first by protection of NH 2 group gr by acetylation. On nitration of
acetyl derivative and subsequent hydrolysis NH2 group is restored.
(ii) Aniline Ethylamine
(i) Give yellow dye with benzene (i) Does not give this test.
diazonium chloride.
(ii) Gives white precipitate with (ii) Does not give this test.
aqueous Br2.

OH

(b) (i) 3 + FeCl3 (C6H5O)3Fe + 3HCl

(Purple colouration)
Neutral Ferric phenoxide

(ii) (CH3COO)2Ca
% (CH3)2CO + CaCO3
PCl5

(CH3)2CCl2 + POCl3

(iii) 4K2Cr2O7
%
}}m
4K4CrO4 + 2Cr2O3 + 3O2
(c) (i) Monosaccharides : Simplest carbohydrates which cant be hydrolysed further. e.g. glucose, fructose
Oligosaccharides : They give 2-10 molecules of monosaccharides on hydrolysis. e.g. sucrose, lactose etc.
Polysaccharides : They give a large number of molecules of monosaccharides on hydrolysis. e.g., starch,
cellulose etc.
(ii) CH2OH
COOH
CO (O) CH2OH
Conc. HNO3
+ (CHOH)2
(CHOH)3 COOH
Glycollic COOH
CH2OH acid Tartaric acid

(iii) (C6H10O5 )n + nH2O }}}m

H ,
% nC6 H12 O 6
C D Glucos e
Cellulose

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Answer 9.

(a) (i) H3 N  CH 2  COO
(ii) It is the pH of solution at which there is no net migration of -amino acid towards cathode as well as
anode.
(b) (i) Glucose forms a brown resinous mass with warm NaOH solution but fructose does not form.
(ii) Ethyl alcohol forms ester having fruity smell with acetic acid and conc. H2SO4. Diethyl ether does not.
(iii) Aniline forms yellow coloured azo-dye with benzene diazonium chloride but nitrobenzene does not
(c) Element % age At. mass % age At. mass Simplest Simplest whole
atomic ratio number ratio
C 68.32 12 5.69 8 8
H 6.4 1 6.4 9 9
Cl 25.26 35.5 0.71 1 1

Empirical formula = C8H9Cl

Empirical formula mass = 96 + 9 + 35.5 = 140.5
Mol mass = 140.5

140.5
n= 1
140.5
Mol formula = 1 C8 H9Cl 4 = C8H9Cl
CH CH3

X= Or CH CH3
Cl

Cl
H2O/H +
CH CH3 CH CH3

Cl OH
X Y

K 2Cr 2O 7/H +

I2 + NaOH
CHI3 C CH3
%
Iodoform
(Yellow ppt) O
Z
Fehlings
solution

No reaction
Answer 10.
(a) (i) Sec. butyl chloride or 2 chlorobutane

CH3 C* Cl

C2H5

CH3 CH3

(ii) + KOH
(alc.)
}}m + KCl
HO H
H Cl C2H5
C2H5
d-sec. butyl chloride l-sec. butyl alcohol

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(iii) Mesotartaric acid has the structure

COOH

H C OH

H C OH

COOH

(b) (i) 2C6H5CHO + NaOH C6H5COONa + C6H5CH2OH

(conc.)

(ii) C6H5Cl + CH3Cl + 2Na }}}m

%
Ether C6 H5CH3 + 2NaCl
Toluene

(iii) C2H5NH2 + CHCl3 + KOH

(alc)
}}
% m C H NC + 3KCl + 3H O
6 5 2

(c) Compounds which are non-superimposable on its mirror image called optically active and this property is called
optical activity. For the molecule to be optically active, it must be chiral i.e. non-superimposable over its mirror
image. e.g. sec. butyl alcohol.

CH3 CH3

H OH HO H
C2H5 C2H5
d-sec. butyl alcohol l-sec. butyl alcohol
Hypothetical mirror

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EVERGREEN MODEL TEST PAPER-18

Subject : CHEMISTRY
Class : 12

PART-I
Answer 1.
(a) (i) ionic product, solubility product (ii) alcoholic
(iii) Friedel crafts, toluene (iv) four
(v) acetone
(b) (i) 1 (ii) 3 (iii) 2 (iv) 3 (v) 1
(c) (i) Nitrobenzene produced, it is substitution reaction.
Intermediate Carbocation

(ii) CH3CHO }}}}}}m CH COOH

(O)
KMnO4 / OH  3
Acetic acid
LiAlH4 2 [H]

C2H5OH
Ethyl alcohol

(iii) Silver mirror is produced due to deposition of Ag.

(iv) C2H5 O C2H5 + PCl5 2C2H5 Cl + POCl3

}}
(v) (NH4)2SO4 + 2KCNOm
% 2NH CNO + K SO
4 2 4

NH CNO }}}}}}m
Rearrangement
4 % H NCONH 2 2

(d) (i) c (ii) a (iii) b (iv) e (v) d

PART-II

SECTION - A
Answer 2.
(a) (i) 2% urea solution.
Mol. mass of Glucose = 180
Mol. mass of urea = 60
Glucose Urea
1 = 2

w /180 2 / 60
=
100 /1000 100 /1000

w 2
=
180 60

w = 6 g/100 mol
Percent strength of glucose = 6%.

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(ii) No, they will have different boiling points.
Urea < NaCl < AlCl3 (Increasing order of boiling points)
Urea doesnt undergo any association or dissociation, hence i = i.
NaCl and AlCl3, i > 1.
NaCl will create 2 ions whereas AlCl3 will create 3, hence elevation in b.pt. will be maximum for AlCl3 as
osmotic pressure is a colligative property.
(b) ( i) For Ist case
[HI]2
KC = = 60
[H 2 ] [I 2 ]
[HI]
For 2nd case K Ca = = 60
[H 2 ]1/2[I2 ]1/2
= 2 15
= 2 3.89 = 7.78
(ii) Addition of NaOH absorbs H3O+, hence equilibrium shifts in the forward direction and it becomes colourless.
Due to addition of HCl, H3O+ conc. increases hence equilibrium shifts backward and get back brown colour
of Br2.
MZ MZ
(c) (i) = 3 , NA = 3
a s NA Sa
58.5 s 4
= (a = 2 281 1010m)
2.165 s (2 s 281 s 1010 )3
= 6.09 1023
(ii) According to Vant Hoff, For dilute solution osmotic pressure
C
nB

V
i.e., osmotic pressure depends upon the number of moles of solute dissolved in a given amount of solution (or
solvent) and is independent of nature of solute particles, it is a colligative property.
Answer 3.
(a) k = 4.5 102 S1
2.303 a
t= log
k a x
2.303 0.4
= log
4.5 s 102 0.2
2.303
= log 2
4.5 s 102
2.303 s 0.3010
=
4.5 s 102
= 15.4 s
(b) (i) No, this is because in an open container gas will escape out and the equilibrium is disturbed.
(ii) 2Cl Cl2 + 2e
2 35.5 g 2 moles of e
71 g of Cl lose electrons = 2 6.022 1023
2 s 6.022 s 1023
1g Cl will lose electrons = = 1.697 1022
71
 
(c) Total number of atoms in one unit cell = 8 +6 =1+3=4
 
Answer 4.
(a) (i) Uncharged atoms or molecules can not maintain the lattice point, hence simple cubic lattice not possible.

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(ii) A unit cell is the smallest repeating unit of the crystal which, when repeated again and again in all the three
dimensions gives the crystal of the given substance.
(iii) In pure water
AgCl ZZX Ag+ + Cl
YZZ
S S S
Let solubility of AgCl = S mol L 1

Ksp = S2
3.6 109 = S2
S = 6 105 mol L1
In 0.05 M AgNO3
AgNO3 ZZX Ag+ + NO3
YZZ
S = Solubility of AgCl
= 0.05 S
0.5 S = 3.6 109 (Ksp)
3.6 s 10 9
S=
0.05
360
= s 109
5
= 7.2 108 mol L1
(b) (i) 6.023 1023 electrons carry charge = 9,65,00 C
96500
Charge on one electron = C
6.023 s 1023
= 1.602 1019C
(ii) Zn2+ + 2e
1 mol
}m Zn
2 moles of
electron
= 65 g
2 mol of electrons reduce Zn2+ ion = 65 g
65
1 mol of electrons will reduce Zn2+ ions = = 32.5g
2
(iii) (Electrochemical cell)
Cell reaction is Zn + Cl2 Zn2+ + 2Cl
Zn(s) | Zn+(aq) || Pt Cl2 | Cl
ECell = + 1.36 ( 0.76) V
= (1.36 + 0.76) V
= 2.12 V
(c) (i) Let edge length of cubic unit cell = a cm
Volume of the unit cell = a3 cc
Let number of atoms in one unit cell =Z
Z A
Mass of one unit cell =
N0
A = Atomic mass of the element
N0 = 6.022 1023
Density of cubic unit cell
Or
Z A
Density of crystal, =
N0 s a3
S N 0 s a3
A=
Z
(ii) (a) hexaamminecobalt (III) chloride
(b) pentacarbonyl iron (0)
(iii) It is a ligand which when bonded to metal atom or ion results in the formation of a ring. e.g. C2 O 24 
(Oxalate ion).
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SECTION - B
Answer 5.
(a) Extraction of silver from argentite ore (Ag2S). The various steps involved are :
1. Mining
2. Crushing
3. Grinding
4. Concentration of the ore by Froth floatation process.
5. Cyanide treatment : The concentrated cyanide ore is treated with a concentrated solution of NaCN
(0.4 0.7%) and air is passed through it.
The reactions taking place are :
Ag2S + 4NaCN ZZX 2Na[Ag(CN)2] + Na2S
YZZ
Na2S + 2O2 Na2SO4
Ag2S + 4NaCN + 2O2 2Na[Ag(CN)2] + Na2SO4
6. Treatment with Zn
2Na[Ag(CN)2] + Zn 2 Ag + Na2 [Zn (CN)4]
7. Refining of Ag : Silver is refined by parlses process and by electrorefining.
(b) Because, N2 gas gets dissolved in blood under high pressure and when pressure is released, it comes out as
bubbles, which creates pain, hence helium is used which is only very slightly soluble in blood.
Answer 6.
(a) (i) CuSO4 + 2HCl CuCl2 + H2SO4
(ii) Na2S2O3 + Cl2 + H2O Na2SO4 + 2HCl + S
2Na2S2O3 + I2 Na2S4O6 + 2NaI
(iii) 3Cu + 8HNO3 }}
% m 3Cu(NO ) + 2N O + 4H O
32 2 2
(b) (i) Ozone has a bent or angular structure.
+
sp2
O +
O

O O O O
O3 molecule has two resonating structures given above.
(ii) These are :
1. Cast iron.
2. Wrought iron.
3. Steel
Answer 7.
(a) By heating Cu with conc. H2SO4.
Cu + 2H2SO4 (Conc.) }}m
% CuSO + SO + 2H O
4 2 2

Or Cu + 4H+ + SO 24 Cu2+ + SO 2 + 2H2O

(b) (i) Compounds having same molecular formula but give different ions in solution although they have same
composition are called ionization isomerism.
Example :
[Co(NH3)5Cl] SO4 and
[Co(NH3)5 SO4] Cl
sp3 Cl 2
(ii) 3s 4s 4p 3
2+ sp
Co =
sp3 Co Cl
2
[CoCl4] = Cl Cl

Cl Cl Cl Cl
(CoCl4)2 a regular tetrahedral geometry and it is paramagnetic due to the presence of unpaired electrons.
(iii) p-ligand : It is a ligand which can form as well as -bond with the metal atoms/ion. e.g. CO, NO etc.

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SECTION - C
Answer 8.
(a) H2C2O4 ZZX
YZZ HC2 O24  + H+ (K a )
1

ZZX
HC2O4 YZZ C 2 O 24  + H+ (K a2 )
There is a large difference between K a and K a because the loss of H+ ion from the negative ion formed after the
2 1

loss of proton is difficult.

(b) (i) Phenol oxidised to phenoquinone which is pink in colour
E+





E E
E
+
(i) O H ........ O O........ H O

(ii) Alcohols have higher boiling points due to intermolecular H-bonding whereas in ether there are weak dipole-
dipole forces.
(iii) This is because of resonance which decreases the positive charge on C-atom.

O

O
CH3 C CH3 C
NH2 NH2

OH

}} m
CHO
(c) (i) C6H5OH + CHCl3 + 3NaOH % + 3NaCl + 2H2O
(aq.)
Salicylaldehyde

(ii) CCl3CHO + NaOH CHCl3 + HCOONa

(iii) C6H6 + CH3Cl }}}m C H CH + HCl

AlCl3
6 5 3
Answer 9.
(a) A is CH3CN (Methyl Cyanide)
B is CH3CH2NH2 (Ethylamine)
C is CH3CH2OH (Ethyl alcohol)
D is CH3CH2NC (Ethyl isocyanide)

CH3CN }}}}m
4(H)
Na/alc
CH3CH 2 NH 2 }}}}}}}}
%
m CH3CH2 NC
CHCl3 + KOH (alc.)

B C
A

HONO

CH 3CH2OH
(b) (i) (a) CH3 CH2 CH2 CH2 OH
n-Butyl alcohol

(b) CH3 CH2 CH CH3

OH
Sec. butyl alcohol
(c) CH3 CH CH2 OH Alcohols
|
CH3
Isobutyl alcohol

CH3
|
(d) CH3  C  CH3
|
OH
Tertiary-butyl alcohol

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(e) CH3 CH2 O CH2 CH3

(f ) CH3 O CH2 CH2 CH3 Ethers
(g) CH3 O CH CH3
|
C H3
H H H CH3
(ii) (a) C=C and C=C
H3CH2C CH3 H3CH2C H
Cis-Pent-2-ene Trans-Pent-2-ene
These are geometrical isomers.

CH3 CH3

Optical isomers
(b) H Br Br H
COOH COOH
d l
Hypothetical mirror
(c) (i) Benzene, a mixture of conc. HNO3 and Conc. H2SO4.
(ii) Reflux the reactants at 50C

(iii) To increase conc. of electrophile / 0 and to increase the rate of a reaction.

NO2

(iv) + HN O 3 }}}}}}}}m
conc. H 2SO 4 ,50oC
Reflux
+ H2O
(Conc.)
Nitrobenzene

Answer 10.
(a) (i) In this type of polymerisation, monomers molecules get added without the elimination of simple molecules.
The molecular mass of polymer is an exact multiple of mass of monomer.
(ii) The monomers must have multiple bonds.
e.g. polythene, polystyrene etc.
(iii) (i) Tetrafluoro ethylene, CF2 = CF2

OH

(ii) Phenol, and Formaldehyde (HCHO)

(iii) Terephthalic acid HOOC COOH and ethylene glycol, HO CH2 CH2 OH

(b) (i) CH3COOH }}}}m (CH COO) Ca

Ca(OH)2
3 2
Dry distillation
CH3COCH3
Acetone
Acetic acid

(ii) 3CH CH }}}m Fe

875 K
Benzene
OH NH2

(iii) + NH3 }}}}}}

% m
Anhyd.ZnCl2

Aniline
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(c) (i) C4H9 NH2 represents

CH3

NH2
H
C2H5 This molecule is chiral and is optically active.
Sec. butyl amine
or
Butan-2-amine

(ii) This is because NH2 group bonded to the benzene ring activates it towards electrophilic substitution
reactions and polysubstitution occurs.
(iii) Acetamide is obtained.
CH3 COONH4 % CH3CONH2 + H2O
Ammonium Acetamide
acetate

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EVERGREEN MODEL TEST PAPER-19

Subject : CHEMISTRY
Class : 12

PART-I
Answer 1.
(a) (i) nuclear fusion, helium
(ii) 0.05 F
(iii) Independent, reactant
(iv) Anode, cathode
(v) cyanohydrins, hydroxy carboxylic acid
(b) (i) 2 (ii) 4 (iii) 2 (v) 4
(c) (i) (a) addition of ferric chloride solution
(b) iodoform test
(ii) Toluene is more easily nitrated than benzene due to +I effect of CH3 group.

NO2

Nitro benzene

CH3 CH3
NO2
and

ONitro toluene NO2

pNitro toluene

(iii) 12
(iv) Elevation in boiling point will be more in NaCl due to more number of particles in solution.
(v) The flow of electrons will stop. The voltage will fall to zero and electrochemical cell will stop working.
(d) (i) 2 (ii) 1 (iii) 4 (iv) 5 (v) 3

PART-II
SECTION - A
Answer 2.
(a) (i) Given, [H+] = 3.8 103 M
pH = log [H+]
= log (3.8 103)
= log 3.8 log 103
= log 3.8 + 3
= 0.58 + 3
= 2.42

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(ii) Relative lowering of vapour pressure is equal to the mole fraction of non-volatile solute.

%p = x = 4 = 0.1
B 40
po
0.1 This means solution has 0.1 moles of solute present in 0.9 moles of water.
Therefore, the mass of water in solution = 0.9 18 = 16.2 g (No. of moles of water is 0.9 Molecular weight of
water = 18)
Moles of solute 0.1
Molality of the solution = = = 6.17 m
Mass of solvent in kg 16.2/1000

(b) (i) In graphite central carbon atom is covalently linked with three more carbon atoms forming hexagonal rings
which are held together by weak van der Waals forces of attraction. Graphite has a layer structure, hence one
layer can readily move over other. Hence graphite is soft, slippery and can be used a lubricant.
(ii) Nature of metal electrode, concentration of metal ions and temperature.
(iii) Given p = 0.850 bar, p = 0.845 bar
Molar Mass of solvent (M1) = 78 g mol1
Mass of Solvent w 1 = 39 g
Mass of Solute w 2 = 0.5 g

p  p w2 M1
= M w
p 2 1

(0.850  0.845) 0.5 78

=
0.850 M 2 39

M 2 = 170 g mol1
Answer 3.
(a) (i) Let k1 = k
k 2 = 2k
T1 = 298 k
T2 = 308 k
By using

k2 Ea 1 1
log k = 
1 2.303 R T1 T2

2K Ea 10
log = 2.303 s 8.314 JK 1 298 s 308
K

log 2 s 19.147J s 298 s 308

Ea =
10
= 53.48 kJ mol1

(ii) Molecularity Order

1. It is the total number of molecules as present in It is the sum of the powers of the concentration terms
balanced chemical reaction leading to formation in the rate law for a reaction.
of products for a simple reaction.
2. Molecularity of reaction can never be in fraction. Order of reaction can be in fractions.
3. Molecularity of reaction cannot be zero. Order of reaction can be zero.

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(iii) (1) Salts of strong acids and weak base form acidic solution because they undergo hydrolysis to give strong
acids and weak bases.
(2) Autocatalysis
[When the product during the reaction is able to catalyse the reaction, it is known as autocatalysis]
Volume of unit cell = (288 pm) 3 = (288 1010)3 cm3
mass 208
(b) Volume of 208 g of element = = = 28.8 cm3
density 7.2
Volume of element
Total no. of unit cells =
Volume of unit cell
28.8 cm3
= = 1024
(28.8 s 1010 )3
_ In bcc unit cell has 2 atoms.
Total number of atoms in 208 g of element = 2 1 1024 = 2 1024 atoms.
Answer 4.
(a) (i) The molecular mass of KCl in aqueous medium has been observed to be almost half than expected and it has
been explained as dissociation of KCl into K+ ions and Cl ions when actual number of particles become
double and so become the colligative properties but since molecular mass is always inversely proportional
ZZX K+ + Cl
to colligative property it becomes almost half. KCl YZZ
In case of benzoic acid in benezene, association of molecules takes place when they dimerise and their
number becomes almost half and so molecular mass doubles as a result.
(ii) 2C6H5COOH (C6H5COOH)2
Tf = Kf m
= 1.86 0.5
= 0.93C
Tf = Tf Tf
= 0 0.93 = 0.93C
(b) (i) Atoms and ions are spherical in shape. A crystal is formed by close packing of atoms or ions. Since, spheres
touch each other only at points, and some empty space is left between them. This space is called void or hole.
(ii) A tetrahedral void is surrounded by four spheres (atoms), whose centres lie at vertices of regular tetrahedron
whereas an octahedral void is surrounded by six spheres whose centres lie at the corners of a regular
octahedral.

Tetrahedral Octahedral
hole hole

(iii) To prove
Roct. = 0.414 radius of sphere
A cross-section of octahedral hole can be represented as :

C
R R Oct. hole
r
R R
A R R B

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In the right angled triangle ABC,
AC2 =AB2 + BC2
(R + r + r + R)2 = (R + R)2 + (R + R)2
22(R + r)2 = 8 R2
R+r = 2R
2 RR =r
R( 2 1) = r
R(1.414 1) = r
r
= 0.414
R
or r = 0.414 R
or roct. = 0.414 R

SECTION - B
Answer 5.
(a) 1. [Co(NH3)4 (H2O)2]Cl3
2. K2[Ni(CN)4]
(b) 1. hexaamminecobalt(III) chloride
2. pentaamminechloridocobalt (III) chloride
3. potassium hexacyanoferrate (III)
Answer 6.
(a) Ozonolysis : An alkene or alkynes react with ozone to form ozonide which on warming with zinc dust and water
undergoes cleavage to give carbonyl compounds. The complete reaction that is the formation of ozonide and its
cleavage is called ozonolysis.

CCl4 O
C=C + O3 C C
Low temp.
OO

O Water
C C + Zn Warm
C=O+O=C + ZnO
OO (dust)

(b) (i) f-block elements exhibit less oxidation states than that d-block elements.
In d-block elements electrons of both (n 1) d and ns orbitals take part in bonding. But in f-block elements
due to poor shielding effect of 5f electrons effective nuclear charge increases, therefore, lesser number of
oxidation states are shown.
(ii) H2SO4 is a stronger acid than H2SO3, because oxidation number of S in sulphuric acid is higher (+6) than in
H2SO3( + 4).
(iii) SiO2 is used in the extraction of copper because silicon dioxide acts as a flux and combines with ferrous oxide
to form ferrous silicate as a slag.

SiO2 + FeO }}m

% FeSiO
3
Question 7.
(a) (i) Both geometrical (cis-, trans-) isomers for K[Cr(H2O)2 (C2O4)2] can exist. Also, optical isomers for cis-isomer exist.

OH2 OH2
OH2
C2O4 Cr C2O4 C2O4 Cr
Geometrical isomers
OH2 C2O4
Trans Cis
Trans-isomer is optically inactive. On the other hand, cis-isomer is optically active.

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OH2 OH2 OH2

OH2
OH Cr Cr OH

OH OH
d- l-
Hypothetical mirror
(ii) Two optical isomers are [Co(en)3]Cl3 exist.
3+ 3+
en en

en Co Co en

en en
d l
(b) [Co(NH3)5Cl]SO4 gives white precipitate with BaCl2 solution

[Co(NH3)5Cl]SO4 + BaCl2 [Co(NH3)5Cl]Cl2 + BaSO4n

(White ppt)

[Co(NH3)5SO4] Cl does not give white ppt. with BaCl 2 solution

[Co(NH3)5Cl]SO4 gives no precipitate with AgNO3 solution
[Co(NH3)5Cl]SO4 + AgNO3 No ppt.
[Co(NH3)5SO4)Cl gives white ppt. with AgNO 3 solution

[Co(NH3)5SO4]Cl + AgNO3 AgCln + [Co(NH3)5SO4]NO3

(White pH)

ZZX [Co(NH3)5Cl]2+ + SO42

[Co(NH3)5Cl]SO4 YZZ

[Co(NH3)5 SO4)Cl ZZX [Co(NH3)5SO4]+ + Cl

YZZ
[Co(NH3)5 Cl] SO4 and [Co(NH3)5SO4] Cl are ionisation isomers.

SECTION - C
Question 8.
(a) (i) A = Acetic anhydride, (CH3CO)2O
B = Acetic acid, CH3COOH
C = Ethyl acetate, CH3COOC2H5
D = ethyl alcohol, C2H5OH
E = Acetone, CH3COCH3
(CH 3CO) 2 O + C2H5OH CH COOH + CH 3COOC 2 H 5
3
(A) (B) (C)

+
H2O/H

CHI 3 k}}}}}
I  KOH ( aq )
2
} CH 3COCH 3 k}}}}
% } CH COOH
Ca(OH) 2+ C H OH
3 2 5
(D)
Iodoform (E) (B)
(Yellow ppt.)
(%) K2Cr2O7/H
+
Tollens reagent

No reaction CH3COOH
(B)

(ii) (CH3)2CO + 3I2 + 4KOH CHI3 + CH3COOK + 3KI + 3H2O

Iodoform reaction

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(b) (i) C6H5NH2 + C6H5COCl C6H5NHCOC6H5 + HCl
Product is NPhenyl benzamide or benzanilide
(ii) C2H5OC2H5 + HI C2H5OH + C2H5I
Products are ethyl alcohol and ethyl iodide
(c) (i) Glucose aldehyde group
Fructose ketonic group
Glucose decolourises bromine water, but fructose does not.
(ii) Polymers having ester linkage called polyesters. They are formed by condensation polymerization of alcohol
and acid.
Question 9.
(a) (i) CH3Cl + KCN CH3CN + KCl
(alc.)

}}}m CH COOH + NH
CH3CN + 2H2O
H
3 3

(ii) C H + CH Cl }}}}}} m C H CH + HCl

Anhyd. AlCl3
6 6 3 6 5 3

C H CH + 3[O] }}}}}}} m C H COOH + H O

Alkaline KMnO4
6 5 3 6 5 2

(iii) C H OH + 2[O] }}}}}}}}} m CH COOH + H O

 K 2Cr2O7 Dil. H 2SO4
2 5 3 2
2CH3COOH + Ca(OH)2 (CH3COO)2Ca + 2H2O

(CH3COO)2Ca }}}}}}}m (CH ) CO + CaCO

Dry Distillation
32 3
(b) (i) Vitamin A (ii) Vitamin C
(c) (i) VICTOR MEYER TEST : blood red coloration for 1-propanol, blue coloration for 2-propanol.
(ii) Urea gives positive result with Biuret test but benzoic acid doesnot.
NH2CONH2 + NH2CONH2 NH2CONHCONH2 + NH3
Question 10.
(a) (i) Condensation, -amino acids
(ii) addition, ethene
(b) A = C6H5CH3 (Toluene), B = C6H5CHO (Benzaldehyde)
C = C6H5CH2OH (Benzyl alcohol), D = C6H5COONa (Sodium benzoate)

CH3

+ CH 3Cl
Anhyd. AlCl3

(A)

CCl4 CrO2Cl2

NO2 COONa CHO

NO2
conc. NaOH
+

(D) (C) (B)

(c) DNA RNA

1. Sugar portion is 2-Deoxyribose 1. Sugar portion is ribose.
2. It has double stranded -Helix structure. 2. It has single stranded -Helix structure.
3. Molecular mass is 6 16 million. 3. Molecular mass is 20,000 40,000.
4. It shows the property of replication. 4. It does not show the property of replication.

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(d) (i) The Benzoin condensation is a coupling reaction between two aldehydes that allows the preparation of -
hydroxyketones.The first methods were only suitable for the conversation of aromatic aldehydes.

O O

H KCN
2
H2O/EtOH
OH 92%
Benzoin
(ii) Reimer-Tiemann reaction :
OH OH
CHO

%
+ CHCl3 + 3NaOH + 3KCl + 2H2O
(aq)

Salicylaldehyde

(iii) Wurtz reaction : reaction between alkyl halides in the presence of sodium and dry ether medium to form
alkane.

CH3 Cl + 2Na + Cl CH3 }}}}}m

%
Dry ether,
CH CH + 2NaCl
3 3

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EVERGREEN MODEL TEST PAPER-20

Subject : CHEMISTRY
Class : 12

PART-I
Answer 1.
(a) (i) sodium, hydrogen (ii) electron, cathode
(iii) anion, tetrahedral (iv) directly, active masses
(v) sp3, sp2
(b) (i) 2 (ii) 3 (iii) 2 (iv) 4 (v) 4
(c) (i) In acetamide, the electron pairs on nitrogen is involved in resonance, and is hence not available, less basic.
(ii) In presence of light, Cl2 undergoes homolytic fission to give chlorine free radicals, which is involved in
chlorination reaction.
(iii) As the halogen atom is more electronegative than carbon, the bond between carbon and halogen is polar.
Due to presence of partial + ve charge on carbon, the nucleophile can attack the electron deficient carbon,
giving substitution product.
(iv) Phenol is acidic in nature.
(v) Water is in liquid state, where particles can move freely, hence entropy is more than ice.
(d) (i) d (ii) e (iii) a (iv) c (v) b

PART-II

SECTION - A
Answer 2.
(a) (i) It states that the relative lowering in vapour pressure of a solution containing a non-volatile solute is equal to
the mole fraction of solute in it.

i.e. }}}}m
pA
p

pA
A
= XB

p = V.P. of pure solvent

pA = V.P. of solution
XB = Mole fraction of solute
(ii) It is the excess pressure which must be applied to the solution so as to prevent the entry of solvent into it
through a semi-permeable membrane.
It is denoted by .
Experimentally, it has been found out that
C C = Molarity of solution

n
or B nB = No. of moles of solute
V
V = Volume of the solution
depends upon the number of moles of solute dissolved in a given amount of solvent and is independent
of nature of solute particles, it is a colligative property.

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(b) H2 + I2 ZZX 2HI

YZZ
[HI]2
KC =
[H 2 ][I 2 ]
= 49

HI ZZX
YZZ 1 1
H 2 + I2
2 2
[H 2 ]1/2 [I 2 ]1/2
KC =
[HI]
[H 2 ][I2 ] 1 1
(KC)2 = = 
[HI]2 K C 49
1/ 2
1
KC = 49
1
= = 0.143
7
(c) (i) HSO4 , H 2O, H 2S
(ii) OH, NH 2 , CH3COO
Answer 3.
(a) (i) Simple cubic unit cell :
1
Total number of atoms in one unit cell = 8 s =1
8
(ii) Body centred cubic unit cell :
1
Total number of atoms in one unit cell = 8 s +1
8
=1+1= 2
(iii) Face centred cubic unit cell :
1 1
Total number of atoms in one unit cell = 8 s 6s
8 2
=1+3=4
(b) (i) PCl5 ZZX
YZZ PCl3 + Cl2
d
r = [PCl5] w.r.t. reactants
dt
d
=+ [PCl3]
dt
d
= [Cl2 ] w.r.t products
dt

(ii) 2NO + O2 2NO2
d
r= [NO] w.r.t reactant
dt

=
d
[O ]
dt 2
1 d w.r.t products
=+ [NO 2 ]
2 dt
(c) For fcc unit cell
3a = 4r
4 r 4 s 125
a= 
53 3
500 s 3
=
3
500 s 1.732
=
3
= 500 0.577
= 288.5 pm
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Answer 4.
(a) Unit cell of Cs+ Cl is as shown below

(i) Electrostatic forces of atractions are present between the oppositely charged Cs+ and Cl ions.
(ii) Simple cubic unit cell. Cl ions are present at the corners of a cube whereas Cs+ ions are present at the body
centre of a cube.
(iii) Number of nearest neighbours of Cs+ (CN) = 8
Number of nearest neighbours of Cl(CN) = 8
(b) (i) The decrease in degree of ionisation of a weak electrolyte in the presence of a strong electrolyte having a
common ion is called common ion effect.
e.g., the degree of ionisation of H2S is decreased in the presence of HCl due to common H+ ions.
H2S ZZX 2H+ + S2
YZZ
HCl H+ + Cl
(ii) Zn can displace Fe from FeSO4 solution. This is because standard reduction potential of Zn is less than
(more ve) than that of Fe.
Zn + FeSO4 ZnSO4 + Fe
(c) pH of a solution is the negative logarithm of molar concentrations of its H +(aq) or H3O+ ions.
i.e., pH = log [H+(aq)]
or pH = log [H3O+]

}}}m
0.01M Water Na+ + OH
NaOH 0.01 M 0.01 M
[OH] = [NaOH] [_ NaOH is a strong electrolyte]
= 0.01 M
= 102 M
[H+] [OH] = Kw = 1014

1014
[H+] =
10 2
= 1012 M
pH = log [H+]
= log 1012
= 12 log 10
= 12 1
= 12

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SECTION - B
Answer 5.
(a) (i) In [Fe(CN)6]4, the central metal ion is Fe2+. Fe2+ has 24 electrons outer electronic configuration.
3d 4s 4p
2+
Fe(g.s)

2+
Fe(e.s)

Fe2+ (d 2 sp3 )
d 2 sp3

[Fe(CN)6]4 
d 2 sp3

CN CN CN CN CN CN
2 3
Due to d sp hybridisation, the complex has regular octahedral geometry.
CN 4

NC CN
Fe
NC CN
CN
Also there is no unpaired electron, hence the complex is diamagnetic.
(ii) The formula of the complex should be [Co(NH3)5Cl]Cl2 and its structure should be octahedral
Cl
H3N NH3
Co Cl2
H3N NH3
NH3
(b) (i) Cl2 + 2NaOH NaCl + NaClO + H2O (ii) XeF6 + 3H2O XeO3 + 6HF
Answer 6.
(a) The important ore of silver is argentite ore, (Ag2S).
Silver obtained from argentite ore is refined electrolytically using acidified silver nitrate solution as an electrolyte.
On passing an electric current pure Ag from anode gets deposited over cathode.
AgNO3 ZZX Ag+ + NO3
YZZ
At cathode
Ag+ + e Ag
At anode
Ag e Ag+

Pure silver cathode

Impure silver anode

Acidified AgNO3 solution

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(b) Transition elements form complexes due to the following reasons :
(i) They have small sizes.
(ii) They have high charges.
(iii) They have a number of vacant d-orbitals of suitable energies in their valence shells.
(iv) They have a tendency to acquire the effective atomic number of nearest noble gas.
(c) The gradual decrease in the sizes of atoms or tripositive ions as move from left to right in the lanthanides is called
lanthanide contraction. The cause of lanthanide contraction is improper shielding by intervening 4f electrons.
Answer 7.
(a) (i) SO2 is produced.
Cu + 2H 2SO 4 }}
% m CuSO + SO + 2H O
4 2 2
(Conc.)
(ii) FeSO4 is oxidised to ferric sulphate [Fe2(SO4]3

0 2FeSO4 + H2SO4 Fe2(SO4)3 + H2O + O2

(iii) Oleum is produced.
SO3 + H 2SO 4 H 2S2 O 7
(Conc.) (Oleum)
(b) (i) Uses of O3 :
1. As a bleaching agent.
2. As an oxidising agent.
3. As a disinfectant and germicide.
(ii) Uses of sulphuric acid :
1. As a laboratory reagent.
2. In the manufacture of lead storage batteries.

SECTION - C
Answer 8.
OH

(a) (i) + Zn }}}}

(Dust)
% m
Alcohol
+ ZnO

OH Cl

(ii) + PCl5 + HCl + POCl3

(iii) CH4 }}}}m CH Cl }}}}}m CH OH

+ Cl2 , hv
3
KOH( aq )
3
COCH3

(iv) + CH3COCl }}}}}m

Anh. AlCl3
+ HCl

(v) CH3CHO + PCl5 CH3 CHCl2 + POCl3

(b) A CH3COOH
B CH3COCl
C CH3CO NH2
D CH3 CH2 NH2
E C2H5OH
F CH3COOC2H5

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K2Cr 2O 7/H + SOCl2

CH3CHO CH3 COOH CH3COCl
(%)
(A) (B)

NH 3 (%)

NaNO2 + Dil HCl LiAlH4

CH3 CH2OH CH3CH2NH2 CH3 CONH2
(E) (D) (C)
CH3COCl
CH3CH2OH CH3COOC2H5
(E) (F)

(c) (i) C 2 H5Cl + 2Na + C2H5Cl }}}}}

% m
Dry ether
C 2 H 5  C2 H 5
Ethyl n -Butane
chloride

(ii) 2 HCHO + KOH(aq) HCOOK + CH3OH

(50%)

Answer 9.

(a) (i) C 2 H5 NH 2 + CHCl3 + 3KOH

(alc.)
}}
%m C2H5 NC + 3KCl + 3H O
2
Ethyl Ethyl
amine Carbylamine

(ii) CH3COCl + H2 }}}}}}}


m
Pd BaSO4
S, Xylene, 413 K CH 3CHO + HCl
Acetyl chloride Acetaldehyde

(iii) C 2 H 5Cl + NaI

Ethyl
}}}}m
Acetone C2H 5I
Ethyliodide
+ NaCl
chloride

+
N2 Cl Cl

(iv) }}}}}m
CuCl/HCl

Benzene diazonium chloride Chlorobenzene

(b) (i) Propan-1-ol gives blood red colouration in Victor-Meyers test whereas Propan-2-ol gives deep blue coloration.
(ii) Acetaldehyde gives red precipitate on warming with Fehlings solution whereas acetone does not.
(c) (i) Monomers of glyptal are ethylene glycol and Phthalic acid.
It involves condensation polymerisation.
(ii) Monomers of melmac are Melamine and formaldehyde. It involves condensation polymerisation.
Answer 10.

(a) (i) 6HCHO + 4NH3 (CH 2 )6 N 4 + 6H2O

Hexamethylene tetramine

+
NH2 N2 Cl

(ii) + NaNO2 + 2HCl

(Dil)
}}}}

m 0 5oC
+ NaCl + 2H2O

Benzene diazonium chloride

(iii) CH3CONH2 + Br2 + 4 4KOH

(alc.)
}}
%m
CH3 NH 2 + 2KBr + K2CO3 + 2H2O
Methyl amine
(b) (i) Adenine, Guanine, Cytosine and Thymine.

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(ii) CH 3Cl }}}}}m

KCN(alc.)
CH3CN
Methyl chloride
Na/alc + 4[H]

CH3CH2NH2
(Ethylamine)

(iii) These are the -amino acids which are not sythesised in the body but are supplied from outside.
(c) (A) CH3  CH 2  CH  CH3 (Butan-2-ol)
|
OH
(B) CH3  CH 2  C  CH3 (Butan-2-one)
||
O
(C) CH3 CH2 CH2 CH3 (Butane)
KMnO4/H +
CH3 CH2 CH CH3 CH3 CH2 C CH3
| ||
OH O
(A) (B)

ZnHg
+ 4[H] +
Conc. HCl

CH3 CH2 CH2 CH3 + H2O

Butane
(C)

B gives iodoform test became it has CH 3  C group but it does not give Fehlings solution test.
||
O

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