Basic Fire Warden 2
Basic Fire Warden 2
Table of Contents
Theory of Fire Page 3
Fire Tetrahedron Page 4
Fire Development Page 12
Classification of Fires Page 15
Principles of Extinguishment Page 18
Extinguishing Agents Page 20
Fire Extinguishers Page 25
Fire Extinguisher Risk Assessment Page 28
Using a Fire Extinguisher Page 30
Fire Extinguisher Maintenance Page 31
Fire Safety Page 33
Rescue Drags and Carries Page 35
1 Theory of Fire
1.1 Fire, also called burning or combustion, is a rapid chemical reaction that results in the
release of energy in the form of light and noticeable heat. Most combustion involves
very rapid oxidation.
1.2 Oxidation The chemical reaction by which oxygen combines chemically with
elements of a burning substance. Even when oxidation proceeds very slowly, as in the
case of a piece of iron that is rusting, a small amount of heat is generated. However,
this heat is usually dissipated before there is any noticeable rise in the temperature of
the material being oxidized. With certain types of materials, slow oxidation can turn
into fast oxidation (fire) if the heat is not dissipated. When this occurs, it is said that
spontaneous combustion has occurred. Such things as rags or papers soaked with
animal or vegetable fats or with paints or solvents are particularly subject to
spontaneous combustion if stowed in confined spaces where heat of oxidation cannot
be dissipated rapidly enough.
Oxidation can occur at different rates.
1.3 Flash Point- is the lowest temperature at which a flammable substance gives off
vapors that will burn when a flame or spark is applied.
1.4 Fire Point, which is usually a few degrees higher than the flash point, is the
temperature at which the fuel will continue to burn after it has been ignited.
2 Fire Tetrahedron
A tetrahedron is simply a shape which has four parts.
We will use this model to describe fire. This is the
most important concept to understand when it comes
to understanding fire. The model states that it takes
four components for a fire to occur. The old model
used to be called the fire triangle which said that it
took the following for a fire to occur.
Fuel
Heat
Oxygen
We know now that in order for a substance to continue
to burn, one additional component must take place,
thus we get the tetrahedron.
2.1 Fuel- also called a reducing agent, is found in three physical states.
Solids
Liquids
Gases
2.1.1 Solids- Must first go through a process before the substance will burn. It must
go through pyrolysis.
As this ratio increases, the fuel particles become smaller (more finely divided)
increasing their ignitability. As the surface area increases, more of the material is
exposed to the heat and thus generates more burnable gases due to pyrolysis.
A solid fuels actual position also affects the way it burns. If a solid fuel is in a vertical
position, fire spread will be more rapid than if it is in horizontal position. The rapid
fire spread is due to increased heat transfer through convection as well as conduction
and radiation.
Vaporization- is the transformation of a liquid to its vapor or gaseous state. The rate
of vaporization is determined by the substance and the amount of heat energy
applied to it.
For example water left in a pan eventually evaporates. The energy required for this
process comes from the sun or surrounding environment. Water in the same pan
placed on a stove and heated to boiling vaporizes much more rapidly because there
is more energy being applied to the system. The rate of vaporization is determined
by the substance and the amount of heat applied to it.
Vaporization of liquid fuels generally requires less energy input than does pyrolysis for solid
fuels. This is primarily caused by the different densities of substances in solid and liquid
states and by the fact that molecules of a substance in the liquid state have more energy
than when they are in the solid state. Solids also absorb more of the energy because of their
mass. The volatility or ease with which a liquid gives off vapor influences ignitability.
Surface to Volume Ratio- is an important factor in their ignitability. A liquid assumes the
shape of its container. Thus, when a spill or release occurs, the liquid assumes the
shape of the ground, flows, and accumulates in low areas. So when a liquid is
released from its container, this ratio increases significantly as does the amount of
fuel vaporized from the surface.
2.1.3 Gases- Gaseous fuels can be the most dangerous of all fuel types because they
are already in the natural state required for ignition. No pyrolysis or vaporization is
needed to ready the fuel and less energy is required for ignition.
For combustion to occur after a fuel has been converted into a gaseous state, it must
be mixed with air (oxidizer) in the proper ratio. The range of concentrations of the
fuel vapor and air is called the Flammable Range.
Lower Flammable Limit (LFL)- is the minimum concentration of fuel vapor and air
that supports combustion. Concentrations that are below the LFL are said to be too
lean to burn.
Upper Flammable Limit (UFL)- is the concentration above which combustion cannot
take place. Concentrations that are above the UFL are said to be too rich to burn.
Air + Combustibles
Too Lean Too Rich
LEL/LFL UEL/UFL
Remember that Gases is are the most dangerous type of fuel because they are already in
the phase of matter that burns. For this reason we store most gases that are used in
industry and residentially as a liquid under pressure. It is important to remember that
the only thing keeping the gas in its liquid form is it being under pressure. If a tank
ruptures during a fire, all the liquid will vaporize and expand which can cause a very big
explosion. It is commonly referred to as a BLEVE ( Boiling Liquid Expanding Vapor
Explosion).
2.2 Oxygen/Oxidizers
Oxygen is one of the more common elements in our atmosphere. Oxidizers are
those materials that yield oxygen or other oxidizing agents during the course of a
chemical reaction. Oxidizers themselves are not combustible, but they support
combustion when combined with a fuel. Oxygen is the most common oxidizer. The
following are some common oxidizers:
1. Causes the pyrolysis or vaporization of solid and liquid fuels and the production
of ignitable vapors or gases.
2. Provides the energy necessary for ignition
3. Causes the continuous production and ignition of fuel vapors or gases so that the
combustion reaction can continue.
For discussion on fire behavior, chemical, electrical, and mechanical energy are the
most common sources of heat that result in the ignition of a fuel.
2.3.1 Chemical
Chemical heat energy is the most common source of heat in combustion reactions.
When any combustible is in contact with oxygen, oxidation occurs. This process is
almost always results in the production of heat. The heat generated when a
common match burns is an example of chemical heat energy.
Heat of Friction- is created by the movement of two surfaces against each other. This
movement results in heat and/or sparks being generated.
Heat of Compression- is generated when a gas is compressed. Diesel engines use this
principle to ignite fuel vapor without a spark plug. The principle is also the reason that
SCBA cylinders feel warm to the touch after they have been filled.
2.3.3 Electrical
Electrical heat energy can generate temperatures high enough to ignite any combustible
materials near the heated area. Electrical heating can occur in several ways including
the following:
When all the components come together flaming combustion occurs. Heat produced by the
initial fire package is transmitted to additional fuel packages. The initial package creates a
plume of hot gases. Outside fires are spread primarily by winds, terrain, and other exposed
fuel packages. An enclosed fire is very complex and tends to be fuel or oxygen controlled.
When the existing reducing agents have been utilized, the fire is then fuel controlled. In a
fire that is ventilation controlled there is a limited source of oxygen.
When no intervention is taken the fire will develop through five stages
3.1 Ignition Stage
Ignition is defined as the period when all the components of the fire tetrahedron are
brought together and is piloted or non-piloted. The fire at this point is confined to the
initial package. Room temperature at this point is approximately 110 0F (380C).
Superheated gases generated by the combustion process are rising to the top of the
compartment. The air in the room has about 20% oxygen. The plume above the fire
entrains air from the compartment. This is the stage at which fire extinguishers are an
effective means of extinguishment. If the compartment is equipped with a sprinkler
system or other fire fighting system it is usually activated during this stage.
Another hazardous situation can occur during this time. If the fire consumes enough
oxygen to reduce the level below 14%, and there isnt an available source of oxygen,
the flames will go out and the fire begins to smolder. The heat is continuing to cause
the fuel to emit flammable vapors which gather in the space. If oxygen is rapidly
introduced back into the space, the flame will return and ignite the unburned
flammable gases causing a backdraft.
Low Oxygen
High Heat
Smoldering fire
High fuel vapor
concentrations
4 Classification of Fires
Fires are classified according to the nature of the combustibles or fuels involved. The
classification of any particular fire is important, since it determines the manner in which the
fire must be extinguished. Fires are classified as Class A, Class B, Class C, Class D, and Class K.
4.1 Class A
These are fires that occur in such ordinary combustible materials such as wood, cloth,
paper, upholstery, and similar materials. Class A fires are usually extinguished with
water, using high or low velocity fog or solid streams. Class A fire leaves embers or
ashes and they must always be broken up to ensure total extinguishment.
USA UK
4.2 Class B
These are fires that occur in a vapor-air mixture over the surface of flammable liquids
such as gasoline, jet fuels, diesel oil, paints, thinners, solvents, lubricating oils, and
grease. Dry chemical, foam, light water, carbon dioxide, or water fog can be used to
extinguish Class B fires. The choice of agents depends on the circumstances of the
fire.
USA UK
In The USA the classification consists of flammable liquids and gases. They are classified
together as most flammable gases are stored as a liquid under pressure. The UK system
splits these into two separate classes, Class B being flammable liquids and Class C being
Flammable gases. It is split in the UK as there are certain techniques which can be used
to fight these types of fires and they have some characteristics which are unique to
flammable gas fires.
4.3 Class C
These fires are those occurring in energized electrical equipment. Non-conducting
extinguishing agents such as dry chemicals, carbon dioxide, and halogenated agents
are used for extinguishing Class C fires. Carbon dioxide or a halogenated agent is
preferred because they leave no residue. Halogenated agents are usually only in
special applications as it is expensive and not environmentally friendly as they are
fluorocarbons. Once the energy source is de-energized the fire becomes a Class A or B
fire.
USA UK
4.4 Class D
These fires are those occurring in combustible metals such as magnesium, titanium,
zirconium, sodium, potassium, calcium, lithium and Zinc. Special techniques have been
developed for the control of this type of fire. Class D fires have extremely high
temperatures, in excess of 2000 0F. Most combustible metals are reactive to water.
USA UK
4.5 Class K
Class K is a newer class recognized by NFPA 10 which involves Cooking Oils or Fats. The
special characteristics of these types of fires are considered important enough to
classify them separately. Do not attempt to fight a class K fire with water or CO 2 as an
adverse reaction can occur which can cause injury or the fire to spread. Class K
extinguishers should be used which will be more effective than dry powder
extinguishers and also there is less potential of splashing. It is referred to as class F in
the UK.
5 Principles of Extinguishment
Overall, Fires may be extinguished by removing a component of the fire tetrahedron (fuel,
heat, oxygen or chemical chain reaction) or by slowing the rate of combustion. The method
of extinguishment used in any specific instance depends on the classification of the fire and
the circumstances surrounding the fire.
5.1 Removal of Fuel
Although removing the fuel to control a fire is not usually possible, there may be
circumstances in which fuel removal is possible. Firefighting parties might have to shift
combustibles to safe areas and to take whatever measures which are possible to
prevent additional fuel from coming into contact with the fire. Supply valves in fuel
and oil lines must be closed immediately which is an example of fuel removal. A
common technique used in wild land firefighting is called back-burning. This is
intentionally burning the fuels in front of a progressing fire to make a fire break
preventing fire spread past the back burned area.
If enough heat can be removed by cooling the fire to a temperature below that at
which it will support combustion, the fire will go out. Water is the most commonly
used cooling agent. Water may be applied as a solid stream, as fog, or incorporated as
foam. The way in which the water or other cooling agent is applied depends on the
nature of the fire.
If fire occurs in a closed space, it can be extinguished by diluting the air with Carbon
Dioxide (CO2) gas. This dilution of the air must reach a certain point before the flames
are extinguished. A large volume of CO2 must be used to reduce the oxygen content to
15 % or less. Oxygens normal concentration in the atmosphere is 21%.
6.1 Water
Cooling is the most common method of fire extinguishment, and water has the
greatest capacity for heat absorption. Most burning substances can be cooled below
their ignition points by the application of water.
With two fire fighters or more the following technique should be used.
6.2 Foam
Foam is a highly effective extinguishing agent for smothering large fires, particularly
flammable liquids.
6.2.1 Aqueous Film Forming Foam (AFFF) / Lightwater
Is a synthetic, film forming foam liquid. The unique action of light
water stems from its ability to make a light water film float on
flammable fuels. As foam is applied over the flammable liquid
surface, an aqueous solution drains from the bubbles and floats out
over the surface to provide a vapor seal. This aqueous film forming
action enhances extinguishment and prevents reflash.
Foam works in the following way:
Carbon dioxide is a dry, non-corrosive gas that is inert when in contact with most
substances. Carbon dioxide does not damage machinery or other equipment. Since it
is a non-conductor of electricity, carbon dioxide can safely be used in fighting fires that
might present electric shock hazards. However, the frost that collects on the horn of a
carbon dioxide cylinder is a conductor of electricity.
Although carbon dioxide is nonpoisonous, it is dangerous to the firefighter because it
does not provide a suitable atmosphere for breathing. Asphyxiation can result from
breathing carbon dioxide.
6.5 Halon
Halon is an excellent extinguishing agent that extinguishes by interrupting the chemical
reaction. Halon has an ozone-depletion potential and has been phased out of
production. The only exception that has been made is if no other alternatives are
available. Halon 1211 and Halon 1301 are the two most common halogenated
compounds used for fire extinguishment. Halogenated vapor is nonconductive and is
effective in extinguishing Class B and Class C fires.
7 Fire Extinguishers
A fire extinguisher is an active firefighting device used to extinguish or control small fires,
often in emergency situations. They are effective in the incipient or ignition phase of a fire.
There are two main types of extinguishes, the stored pressure and the cartridge operated
types.
Multi-Purpose Dry
Breaks Chain Reaction
Chemical
Isolating
Foam Fuel/Cooling/Smotherin
g
To extinguish a fire with a portable extinguisher, a person must have immediate access to
the extinguisher, know how to actuate the unit, and know how to apply the agent effectively.
Attempting to extinguish even a small fire carries some risk. Fires can increase in size and
intensity in seconds, blocking the exit path of the fire fighter and creating a hazardous
atmosphere. In addition, portable fire extinguishers contain a limited amount of
extinguishing agent and can be discharged in a matter of seconds. Therefore, individuals
should attempt to fight only very small or incipient stage fires.
Prior to fighting any fire with a portable fire extinguisher you must perform a risk
assessment that evaluates the fire size, the fire fighters evacuation path, and the
atmosphere in the vicinity of the fire.
Characteristics of incipient stage Characteristics of fires that SHOULD
fires or fires that can be NOT be fought with a portable fire
Risk Assessment Question
extinguished with portable fire extinguisher (beyond incipient
extinguishers stage) - evacuate immediately
The fire is limited to the original The fire involves flammable solvents,
material ignited, it is contained (such as has spread over more than 60 square
Is the fire too big? in a waste basket) and has not spread feet, is partially hidden behind a wall or
to other materials. The flames are no ceiling, or cannot be reached from a
higher than the firefighter's head. standing position.
The fire has not depleted the oxygen in Due to smoke and products of
the room and is producing only small combustion, the fire cannot be fought
Is the air safe to breathe?
quantities of toxic gases. No respiratory without respiratory protection.
protection equipment is required.
Heat is being generated, but the room The radiated heat is easily felt on
temperature is only slightly increased. exposed skin making it difficult to
Smoke may be accumulating on the approach within 10-15 feet of the fire
Is the environment too hot or ceiling, but visibility is good. No special (or the effective range of the
smoky? personal protective equipment is extinguisher). One must crawl on the
required. floor due to heat or smoke. Smoke is
quickly filling the room, decreasing
visibility.
There is a clear evacuation path that is The fire is not contained, and fire, heat,
Is there a safe evacuation
behind you as you fight the fire. or smoke may block the evacuation
path?
path.
9 Using a Fire Extinguisher
The Following Steps Should be followed when responding to an incipient stage fire:
Sound the fire alarm and call the fire department, if appropriate
Identify a safe evacuation path before approaching the fire. Do not allow the fire,
heat, or smoke to come between you and your evacuation path
Select the appropriate type of fire extinguisher
Discharge the extinguisher within its effective range using the P.A.S.S Technique
(PULL, Aim, Squeeze, Sweep)
Back away from an extinguished fire in case it flames up again
Evacuate immediately if the extinguisher is empty and the fire is not out
Evacuate immediately if the fire progresses beyond the incipient stage
11 Fire Safety
Fire prevention is the best way to prevent loss of property and life. A big part of prevention
is the identification of fire hazards.
11.1 Fire hazards
A fire hazard is a condition that encourages a fire to start or increases the extent or severity
of a fire. Basic fire chemistry suggests a fire cannot survive without a fuel supply, sufficient
heat source, oxygen supply, and a self-sustained chemical reaction. Therefore, hazardous fire
conditions can be prevented by eliminating one or all of these elements.
Control of the oxygen supply hazard is only practical under special circumstances because 21
percent oxygen is normally present in air. Control of the hazards associated with fuel supply
and heat sources are the most manageable.
Flammable and combustible gases such as natural gas, liquefied petroleum gas
(LPG), and compressed natural gas (CNG). (NFPA 30 for storage info)
Mechanical heat energy- Moving parts on machines, such as belts and bearings,
are a source of mechanical heating
11.1.3 Common Fire Hazards
A common fire hazard is a condition that is prevalent in almost all occupancies and
encourages a fire to start. Be alert for the following common hazards: