Chapter 3 HEAT CAPACITY OF LIQUID Carl L. Yaws, Xiaoyan Lin, Li Bu, Sachin Nihawan, Deepa R. Balundgi, and Saumya Tripathi Lamar University, Beaumont, Texas ABSTRACT Results for heat capacity of liquid as a function of temperature are presented for major organic and inorganic chemicals. The results cover a wide temperature range and include many compound types. The agreement between correlation and data is quite good. INTRODUCTION Thermodynamic properties such as liquid heat capacity are important in the engineering design of chemical processes. In liquid-phase chemical reactions, the liquid heat capacity is required to determine the energy (heat) necessary to bring the liquid chemical reactants up to reaction temperature. Additional uses include heat exchanger and energy balance design calculations. In this article, correlation results for liquid heat capacity are provided in an easy-to-use tabular format that is especially applicable for rapid engineering use with the personal computer or hand calculator. HEAT CAPACITY CORRELATION The correlation for heat capacity of liquid is a series expansion in temperature’ Cp=A+BT+CT?+DT® (3-1) where Cp = heat capacity of liquid, joule/(mol K) A,B, C, and D = regression coefficients for chemical compound T = temperature, K The results for heat capacity of liquid are given in Tables 3-1 and 3-2. In preparing the compilation, a literature search was conducted to identify data source publications for organics (1-43) and inorganics (1- 104). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened for appropriate data The compilation resulting from the screening is based on both experimental data and estimated values. For organic compounds, most of the estimates were based on group contribution (Cheuh-Swanson, 29), corresponding states (Lee-Kesler, 29) and boiling point methods (Yaws and co-workers). The relation of (heat capacity)(density"}=constant was utilized to extend both experimental data and estimates. Values of n ranged from 1/2 to 1. Experimental data and estimates were then regressed to provide the same equation for all compounds. For inorganic compounds, many of the estimates are based on the JANAF tables (57-59), Bureau of Mines bulletins (60-63), and group contribution methods. The relation of (heat capacity)(density"}=constant was utilized to extend both experimental data and estimates. Very limited experimental data for liquid heat capacity are available at temperatures in the region of the melting point temperature. Data in the boiling-critical point temperature interval are also very scarce. Thus, the values in the region of the melting point and in the boiling-critical point temperature interval should be considered rough approximations. The values in the intermediate region (above melting and below boiling point) are more accurate. ‘A comparison of correlation and actual data for liquid heat capacity is shown in Fig. 3-1 for a representative chemical. The graph discloses good agreement of correlation and data EXAMPLES The correlation results maybe used for prediction and calculation of heat capacity and additional thermodynamic properties. Examples are given below. Example 1 Estimate the liquid heat capacity of pentane (C5H12) at 298.15 K. Substitution of the coefficients from the table and temperature into the equation for heat capacity yields C, = 80.641 + 6.2195€-01*298.15 ~ 2.2682E-03"298.15* + 3.7423E-06°298.15° Cp = 163.64 joule/(mol K) Example 2 Calculate the energy required to heat liquid toluene (C7H8) from 300 to 500 K. 56HEAT CAPACITY OF LIQUID From thermodynamics, the change in enthalpy, AH, at constant pressure is AH=[CpdT =[(A+BT+CT?+DT°) dT th AH = AT + (B/2)T?+ (C13) T* + (0/4) T* J % ‘Substitution of the coefficients from the table and the temperature limits into the equation yields ‘AH = (83.703) (500 - 300) + (5.1666E-01/2) (500? - 300°) — (1.4910E-03/3) (500° - 300°) + (1.9725E-06/4) (500* - 3004) {4H = 36,200 joule/mol Portions of this material appeared in Hydrocarbon Processing, 70, 73 (December, 1991) and Chem. Eng., 99, 130 (April, 1992). These portions are reprinted by special permission. REFERENCES — ORGANIC COMPOUNDS 1-36. See REFERENCES - ORGANIC COMPOUNDS in Chapter 2, HEAT CAPACITY OF GAS 37. Altunin, V. V., V. Z. Geller, E. K. Petrov, D. C. Rasskazov, and G. A. Spiridonov, THERMOPHYSICAL PROPERTIES OF FREONS, Methane Series, Part 1, Hemisphere Publishing Corporation, New York, NY (1987).. 38. Altunin, V. V., V. Z. Geller, E. A. Kremenevskaya, |. |. Perelshtein, and E. K. Petrov, THERMOPHYSICAL PROPERTIES OF FREONS, Methane Series, Part 2, Hemisphere Publishing Corporation, New York, NY (1987). 39. Wilhoit, R. C. and B. J. Zwolinski, PHYSICAL AND THERMODYNAMIC PROPERTIES OF ALIPHATIC ALCOHOLS, American ‘Chemical Society, American Institute of Physics, National Bureau of Standards, New York, NW (1973). 40. Yaws, C. L. and others, Hydrocarbon Processing, 70, 73 (December, 1991). 41. Yaws, C. L. and others, Chem. Eng., 99, 130 (April, 1992). 42. Yaws, C. L., HANDBOOK OF THERMODYNAMIC DIAGRAMS, Vols. 1, 2, 3, and 4, Gulf Publishing Co., Houston, TX (1996). 43. Yaws, C. L., HANDBOOK OF CHEMICAL COMPOUND DATA FOR PROCESS SAFETY, Gulf Publishing Co., Houston, TX (1997). REFERENCES - INORGANIC COMPOUNDS 1-64. See REFERENCES - INORGANIC COMPOUNDS in Chapter 2 HEAT CAPACITY OF GAS 65. Lyon, R. N., ed., LIQUID-METALS HANDBOOK, 2nd ed., Atomic Energy Commission, Washington, DC (1954). 68. Janz, G. J. and C. B. Allen, PHYSICAL PROPERTIES DATA COMPILATIONS RELEVANT TO ENERGY ST ‘SALTS: DATA ON SINGLE AND MULTICOMPONENT SALT SYSTEMS, Nat. Bur.Stand., Molten Salts Data Center, Troy, NY (April 1979). 67. Fink, J. K., TABLES OF THERMODYNAMIC PROPERTIES OF SODIUM, Argonne National Lab., ANL-CEN-RSD-82-4, Chemical Engineering Division, Argonne, IL (June, 1982). 68. Mills, K. C., THERMODYNAMIC DATA FOR INORGANIC SULPHIDES, SELENIDES AND TELLURIDES, Butterworths, London, England (1974). 69. Tarakad, R. R. and R. P, Danner, AIChE J. 23(6), 944 (1977) and 23(5), 685, (197). 70. Chueh, C. F. and A. C. Swanson, Chem. Eng. Prog. 69(7), 83 (1973). 71, Glauque, W. F. and T. M. Powell, J. Amer. Chem. Soc. 61, 1970 (1939). 72. Davis, C. M.,Jr., J. Chem. Phys. 45(7), 2461 (1966). 73. Hu, J., D. White, and H. L. Johnston, J. Amer. Chem. Soc., 15, 5642 (1953) 74, Smith, T. O. and B. M. Fabuss, Wright Air Development Center, Technical Report 59-327 (1962). 75. Grosh, J. and M. S. Jhon, Proc. Nat. Acad. Sci. 54, 1004 (1965). 76. Hu, J. H. and D. White, J. Amer. Chem. Soc. 75, 1232 (1953). 77. Giauque, W. F. and R. Wieke, J. Amer. Chem. Soc., 541, 1441 (1929). 78. Forsythe, W. R. and W. F. Giauque, J. Amer. chem. Soc., 64, 48 (1948). 79. Evans, W. H. and R. Jacobson, J. Res. Nat. Bur. Stand., 55, 83 (1955). 80. Douglas, T. B. and A. F. Ball, J. Amer. Chem. Soc. 74, 2472 (1952). 81. Douglas, T. B. and L. F. Epstein, J. Amer. Chem. Soc., 77, 2144 (1955). Haar, L. and J. S. Gallagher, J. Phys. Chem, Ref. Data, 7(3), 635 (1978). Giauque, W. F. and J. 0. Clayton, J. Amer. Chem. Soc., 55, 4875 (1933). Wiebe, R. and M. J. Brevoort, J. Amer. Chem. Soc., 51, 622 (1930). Scott, D. W. and G. D. Oliver, J. Amer. Chem. Soc., 71, 2293 (1949). Giauque, W. F. and J.D. Kemp, J. Chem. Phys., 6, 40 (1938). 87. McCarty, R. D. and L. A. Weber, Nat. Bur. of Stand. Tech. Note 384, Washington DC (1971). 88. Giauque W. F. and H. L. Johnston, J. Amer. Chem. Soc., 51, 2300 (1929). 89. Jenkins, A. C. and F. S. Dipaolo, J. Chem. Phys., 25(2), 296 (1956) 90. Lee, B. I. and M. G. Kesler, AIChE J., 21(3), 510 (1975). 91. Ott, J. B. and W. F. Giauque, J. Amer. Chem. Soc., 82, 1308 (1960). 92, McDonald, R. A., J. Chem. Eng. Data, 12, 115 (1967). 93. Majer, V., V. Svoboda, and M. Lencka, J. Chem. Thermo., 17, 365 (1985). 94, Sherman, R. H. and W. F. Giaugue, J. Amer. Chem. Soc., 77, 2154 (1955). BRESK 57HEAT CAPACITY OF LIQUID 95. Clarke, J. T., E. B. Rifkin, and H. L. Johnston, J. Amer. Chem. Soc., 75, 781 (1953). 96, Jhon, J. S., J. Grosh, and H. Eyring, J. Phys. Chem.71(7), 2533 (1967). 97. Pace E. L. and M. A. Reno, J. Chem. Phys., 48(3), 1231 (1968). 98. Pace, E.L. and M. A. Reno, J. Chem. Phys., 48(3), 1231 (1968). 99, Clayton, J. O. and W. F. Giauque, J. Amer. Chem. Soc., 54, 2610 (1932). 100. Kaischeu, R., Z. Phys. Chem., 840, 273 (1938). 101. Kemp, J. D. and W. F. Giauque, J. Amer. Chem. Soc., 59, 79 (1937). 102. Void, R. D., J. Amer. Chem. Soc., 59, 1515 (1997). 103. Weissler, A., J. Amer. Chem. Soc. 71, 1272 (1949). 104, Pace, E. L. and J. S, Mosser, J. Chem. Phys., 19(1), 154 (1963). 58Heat Capacity of Liquid, joule/(mol K) HEAT CAPACITY OF LIQUID Figure 3-1 Heat Capacity of Liquid | ] I | | | | | C7H8 TOLUENE 1507 a 50: 0 -100 -50 0 50 100 150 200 Temperature, C = data —— equation 59Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS CpeA+BT+CT+DT = joule/(mol K), T = K) AME [= 3 eT TWIN | TWAX |G @756 ~_|BROMOGHLORODIFLUOROMETHANE Bead _| ARTES | A TERE 115] 304 |r 'BROMOTRICHLOROMETHANE 32.285 | 7.16286-01 | -19206E-05 | 253 | 545 | 13005, 'ROMOTRIFLUOROMETHANE [sass sae7se01_| -29009603 106 | 306 | 149.25 | [DIBROMODIFLUOROMETHANE 60.141 | 548376.01 | -199976-09 | 29 res | 430 | 12904 | [CHLOROTRIFLUOROMETHANE ater | ssarre-ot | -3.1163€-08 | e02e2€-06_ | 83_| 272 | [CYANOGEN CHLORIDE 130.070 | 20318E+00 | -66150E-05 | 7.708606 | 268 | 404 9408 DICHLORODIFLUOROMETHANE — "s0463__| 40919601 | 20770603 | 42508600 | 116 | 346 | 12107 | PHOSGENE Sore ceseeor[teseeros | sesrece [tue [ato nor "TRICHL OROFLUOROMETHANE 79.120 | 80976E-01 | -1.10666-05 | 1.716506 | 163 1 [CARBON TETRACHLORIDE ‘671 | 933636-01 | -26760E-03 | 304256-06 | 251 (CARBONYL FLUORIDE = “33419 | 19004600 | -4.00736-02 | 19136605 | 163 {canon TeTRAFLUORIDE _ 25305 sinsre-or | -rorste-0s | 212106-05 | ot are [796-01 | -1.969146-09 | 169146-06 | 202 | 620 | 120.84 CHLORODILUGRONE THANE ‘arrsreor | -22107eas | 457e6e-06 | 117,392 | 11160 [DICHLOROFLUOROMETHANE “£:15646-01 | -157306-03 | 270086-06 | 139 | 406 | 107.20 (CHLOROFORM Sso7E-o1 | -203596-03 ait | aa] t249 ~FIRFLUOROMETHANE 4326.01 +19_| 200 | — “TRIODOMETHANE [-9.16006-02 | se7_[ ser IHYOROGEN CYANIDE, wiaa.1s5 | 177esevo0 | -se0ese09 | 6orme08 | 261_| a1 | yaee ISOTHIOCYANIC-AGIO lems ee et Fe {BROMOCHLOROMETHANE ~ 49.459 | Sua79E-01 | -s67ee-05 | 15006E-06 | 1068 | Sot | 100.78 “JOIBROOMETHANE 38,738 | 48164E-01 | -1 2016-05 | 1.54496-06 | 222 | 550 “[on2ci (CHLOROFLUOROMETHANE 95.915 | -se02sc02 | 2eseieo4 | —— | 141) 204 | 24 [cH2ci2_[DICHLOROMETHANE si.o41 | 490086-01 | -162046-05 | 230096-06 | 178 | 459 25_|CH2F2 ___|DIFLUORONETHANE 21.196 | Toswe-or | -ssss7e-05 | 647s7E-05 | 138 | 316 | 107.05 25 cH DIODOMETHANE “49.827 | 5.56006-01 | -1.25006-03 | 1.16546-06 [700 | 672 | 1545, 27_[eH20 ‘ORMALDEHYDE — ——— —oe oo [25 |cr202 ———jFORMIC AciO_ 46.110 | 87220601 | -2s665e03 | ZaasiE05 | 209 | 622 29_(ck36r METHYL BROMIDE —_—— 25042 | 496126-01 | -176276-05 | 259036-06 | 161] 420, 30 _/oHSCi [METHYL CHLORIDE ~~} "irset | 6220-01 | -249s0€-03 | ses026-08 | 176 | 75 METHYL TRICHLOROSIANE Baie | 8.9604E-01 | -285096-05 | 35406606 | 196 | 465 (METHYL FLUORIDE. 9362 | 65962601 | -4.4087E-05 | 9.17086-06 (METHYL IODIDE 24.200 | AG450E-0t | -145036-05 | 1.8792€-06, [FORMAMIDE 30706 | s.1ese-o1 | -1.14226-03 | 1. 04006-08 INITROMETHANE | [-21677E-06 [METHYL-NITRITE —— i —— (METHYLNITRATE —— | = METHANE. [-oore | ‘r0826+00 | oe7z2e-03_| 3.167005 [METHYL DICHLOROSILANE, 65.100 | 6.8006-01 | -20767E-05. | 53997-06, METHANOL 40.152_| 3.10486-01 | -1.02916-09 | 14590606. ~]METHANESULFONIC ACID ——— — — IMETHYL MERCAPTAN ‘ae.a7z_| 370ss6-01 | -136656-05 | 2 70056-06 “as [cHSCISsi [METHYL CHLOROSILANE 8.909 _| 6036-01 | -2s067e-05 | «0231€-06 | “4 [CHEN /METHYLAMINE Fis cee 01 34881 09 | 52770608 —merive st -2.34406-03 —TTETRANITROMETHANE 1394602 ‘CARBON MONOXIDE -2.99706-02 (CARBONYL SULFIDE ATSITEGS ——TeARBON DIOXIDE lose ‘CARGON DISULFIDE (CoBrE3___|BROOTRIFLUOROETHYLENE $4074E+00 (CoBaF4 11 2.01BROMOTETRAFLUOROE THANE Ts843€-01 4.741608 “$3__|C2CiFs ——[CHLOROTRIFLUOROETHYLENE 649426-01 '59700E-06 | (CZCS |CHLOROPENTAFLUOROETHANE 18274100 1.268965 [Caar4 11 .DICHLOROTETRAFLUOROETHANE 821046-01 | 3.1766E-05 | 48217606 56 |C2GF3___|1,1 2-TRIGHLOROTRIFLUOROE THANE -S5.28046-03 | 65167606 | ‘51 [020% | TETRACHLOROETHYLENE ‘58 [G2GHF2 | 1,1.2.2-TETRACHLORODIFLUOROETHANE "TRICHLOROACETYL CHLORIDE 2:32506-06 'HEXACHLOROETHANE _——__| = |TETRAFLUOROETHYLENE "ya070E 03 | 1601605 | ar —HEXAFLUOROETHANE 152629 |"3.876E+00 | -1.94006-02 | s.s4806-05 | 173 | 264 [HALOTHANE — site | errive-ot | 2760s6-05 | sceste-06 | 201 | 460 | 169.18 [2-CHLORO-s,-DIFLUOROETHYLENE 49.550 | 6.05746-01 | 25501603 | 472716-05 | 196 | 360 | 12695 "TRICHLOROETHYLENE: 35.916 | 472s06-01 | -140356-05 | 1.83636-06 | 169 [514] 123.67 IDICHLOROACETYL CHLORIDE e.s00_| eanmae ot | -soasean | 2a%see-00 [201 [sat | ve420 | TRICHLOROACETALDEHYDE 51.169 | 7.72366-01 | -226066-05 | 2.7747E-06 | 217 | 600 | 169.22 —]PENTACHLOROETHANE —}ra'se0 7 99226-01 | -20081€-03 | 2.19956-06 | 245 | 590 | 100.8 "TRIFLUOROETHENE Toast | -1.7207E02 | 2asaeeos | — | 96 | 2st | —— TTRIFLUOROACETIC ACID ~rss27_| 206696+00 | -6.40866-08 | 7.52806-06 [259 | sea | 170.18 | [PENTAFLUOROETHANE 34.455 | 1.96396+00 | -082226.03 | 45512605 | 171 | 308 | 16085 [ACETYLENE — — mee | ee ee ee 1.2.2-TETRABROMOETHANE 42006601 | BBi09E-O4 | 7a7O8E-O7 | am | 702 | T0809 ~NDICHLOROETHYLENE. - “[aoss9e-0r | -14250609 | 227e1e08 [152 ae | 11243 (ds-1.DICHLOROETHYLENE '59100E-01 | -18794E-05 | 25208E-06 | 194 | 474 | 117-80 {yans-t.2-DICHLOROETHYLENE 8.reo4e-o1 | -277516-05 | 349326-06 | 224 | 45711637 |GHLOROACETYL CHLORIDE ‘S80066-01 | -2,raise-03 | 304536-06 | 252 | 523 | 292 Sar ee neeee Sereiror | ssemeos | samee ss [ane sar[ tat]‘Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) Cp=A+BT+CT+DT® (Cp - joule/(mol K), T- K) TO] FORMULA WANE a BT D TwIN_ | TWAX | C @25C 7@_|@2H26202 |DIGHLOROAGETIC AGIO T4071 | TOTS1E*00_| -25sT0EDS | 2aBBTE-DS | 266 | 617 | 17272 e0_ |C2n2cisr STRICHLOROFLUOROETHANE | 56.323 | 7.140201 | -2.tsa7E03 | 27150E-06 | 201 | 509 | 15142 a1 _lozizce 74301 | 86404601 | -15412E.03 | 1.05526-06 75463 (82 [C2H2Gi4 [1.1 2.2-TETRACHLOROETHANE [Tezisr | 6.7404e-01 | -1.75616-08 | 1 95826-06 “159.38 '63_[GaH2F2 —_1,.OIFLUOROETHYLENE San} “1907-05 — ‘4 _[G2HoF2 __|ds-1.201FLUOROETHENE: 79.384 (85 _|C2H2F2 _[wane-1,2-DiFLUOROETHENE 793846 _| -2.72406-02 | 25306604 8 [canara 1.1 2-TETRAFLUOROE THANE “14015 _| 1.430600 | -6.02206-05 37 KETENE 135905 | 435736-01 | -199506-09 88 'OXALIC AC — ee VINYL BROMIDE woes | sazsae-0F 0 {VINYL CHLORIDE 45.366 | 28792601 91 (G2HSGF2 | 1-CHLORO-1.1-DIFLUOROETHANE 40.990 | 7.30506-01 | -3.01726-03 $2” |C2H9GI0 |ACETYL CHLORIDE 35.906 | 443276-01 | -140856-03 $3_|C2HSGIO | CHLOROACETALDEHYDE 37.369 | 69407E-01 | -1.8003E-03 | 2.3175E-06. 115.19 $4 |C2HSCI02_|CHLOROAGETIC ACID 114722E +00 | -3.3749E-03 | 2.9610E-06 — 95 _[G2H3Gi02 [METHYL CHLOROFORMATE 47.268 | 73530601 | 23261603 | 3.0667E-06 i083 96 [C2HSCKS ___|[1.11-TRICHLOROETHANE 11.142 | 1.0501€+00 | -3.06206-03 | 3.59636-08 145.56 [97 [Gaiscis ——|1.12-TRICHLOROETHANE 34.994 | 850546-01 | -2:53006.03 | 2.6455E-05 98 (Case [VINYL FLUORIDE mere 99 [caHaFS 113367E 100 | -6.1220E-08. 700_[C2HaN [ACETONITRILE | “2087003 101 [G2HINO [METHYL ISOCYANATE 1.42066 +00_| -3.46996-03.| 102 [CoH [ETHYLENE 5 7078E-01 | -3:36206-03 | 105 [C2482 __|1,1-DIBROMOETHANE ‘SA074E.01 | 13765608. 104 |C2H«82__|1.2.01BROMOETHANE ‘31078601 | -2.00866-03 | 1.9604E-06 105 |62H4C2 1,1 DICHLOROETHANE B014E-01 | -1.6196E-03 | 256176-08 106 |G2H4C [1 2.DICHLOROETHANE [7 76586-01 | -2.2271€-03 | 261096-06 107_|C2H4Ci20__[BIS(CHLOROMETHYLIETHER 8.0721€-01 | -279616-03 | 2.6746E-06 7] 108 [G2#aF2 ——|1.1-DIFLUOROE THANE: 7.4043-01 | -3.02516-03 | 6.238560 108 |C2H4F2 | 1.-DIFLUOROETHANE 2349 | 936776-01 | 3.7570E.03 | 4.4459E-08 $10 [C2Hat2 IODOETHANE e557 | 0.006602 | 2401608) — Tait [eaH4o. "ACETALDEHYDE _——~—~—~S*d «0568 | 459-01 | -1 6076-09 | 2 7OO0E-08 112, [C2H40- |ETHYLENE OXIDE 35.720 | 42008601 | -1.5473E.03 | 24070E-08 113. [C2H40S___[THIOACETIC-AGIO ee 1 |CaHa02 [ACETIC ACIO “ese4 | Toeriewo | 20021603 | 20276606 115 [G2H402 [METHYL FORMATE 42381 | §7064E-01_| -19727E.03 | 2.80456-06 116 [CaaS |THIACYGLOPROPANE————SSSSSSS*d~C206 | etTavEO? | 37077E-04 | — 117 [C2H6r IBROMOETHANE 49401 | 36348601 | -1:0006.03 | 20048E-08 118 [C2HSCI [ETHYL CHLORIDE. 60.180 | 345536-01 | -120006-03 | 2.196306 “18 [C2HECIO_[2-CHLOROETHANOL secs | 4200701 | -124e7e03 | 1.52636-06 120_|COHSF [ETHYL FLUORIDE 47221 | BSSGEOT | -24970E03 | 48160606 "21 [c2s_ ETHYL IODIDE “58.413 _| 37396E-01 | -1.1485E-03 | 16516606 “22 |C2HSN |ETHYLENEIMINE “40.410 | 526356-01 | -1.67046-03 | 2.10606-06 125 [C2HSNO__[ACETAMIDE 42201 14311€+00_| 23734603 | 1.97266-06 "24 [CZHENO_|N-METHYLFORMAMIOE Tsar] 62201601 | -1.45736-03 | 14050606 "25 |CQHSNO_|NITROETHANE 70.386 | §6739E-01 | -1.6579E-03 | 2 4086-06 "26 |C2HSNOS__|ETHYLNITRATE — | — ——— 21 |C2H6. ETHANE Bas2 | 4H008E-0T | “2802605 | SSS47EOS 128 [C2HeAIGL [DIME THYLALUMINUM CHLORIDE 16451_| 9.25716-01 | -2.48286-03 | 26678E-08 | 129 (C2H60 DIMETHYL ETHER [ator | s02056-01 | -220156-03 | 44614608 | 130_(C2H60 ETHANOL sea] 3.63686-01 | -1.21646-03 | 1.80306-06 131 [C2H60S [DIMETHYL SULFOXIDE — 2re7e | 7.8628E-01 | -177626-03 | 16546E-05 | 293 | 653. | 14827 182 |[C2H602 ETHYLENE GLYCOL TseTe | 64162601 | -1.6499E.05 | 16997606 | 261 | se1_| 16552 185 |C2H6O4S [DIMETHYL SULFATE [88.080 |" s4aoee-or | -14260-03 | 14587606 | 242 | 682 | 108:12 | 94 [C2H6S____[DIMETHYL SULFIDE 50.108 | 556036-01 | -1a6iee-03 | 2e910E-06 | 176 | 453 | 12167 | 135 C2HeS {ETHYL MERCAPTAN Tage | 344isE0t | -119906-03 | 20330606 | 126 | 44912254 “96 [C2HES? [DIMETHYL DISULFIOE_—_———~—~S:~C0 206 | 970SE-OT | -1.30186-05 | 1.77626.06 197_[C2HIN [ME THYLAMINE 36962 | 95017601 | .5046E-09 | 529006-06 | 198_/C2H7N_[ETHYLAMINE 15794 | 87M4E.01 | 3.11096-05 | 4.4073E.06 | 199 | 188 [C2H7NO | MONOETHANOLAMINE: za.it1_| 1.22636+00 | -3.12186-03 | s.0714€-06 140_[C2HEN2 | ETHYLENEDIAMINE 801 | 1.5005E+00 | -4.01726-03 | 4.0670E-06 14i_[CzH6si [DIME 60.542 | 5.75006-01 | -245426-03 | 4.7258E-06 142_{Caht2__ CYANOGEN “224.800 | 3.6145E+00 | -1.3037E-02 | 1.6821E-05 [4s [care HEXAFLUOROPROPYLENE 58118 | 85810E-01 | -3.9961E-03 | 6.2639E-06 [i44 [c3r60 HHEXAFLUOROACETONE 30204 | 1,7703E+00_| 81260609 | 1.47346-05 “5 |caF8 (OGTAFLUOROPROPANE 65.135 | 1.21016+00 | -6.2622E-03 | 1.2066E-05 “48_[C3H2N___| MALONONITRILE —_ 5793 | 103546400 | -2.38026-08 | 2.147006 {a7 |coHich | PROPARGYL CHLORIDE Spaes | Sassoe-or [17087608 | 23406606 (C3HSN ACRYLONITRILE 33.362 | Se6MEOt | -1.86256.03 | 2.4956E-06 “wo |G3HINO|OXAZOLE 51.639 | 421176-01_| -1.26316-03 | 167236-06 160_|CaH6 -METHYLAGETYLENE 15304 | T.e4steot | -3.16656.03 | 5.15756-06 "151 [cane PROPADIENE 32395 | 48630601 | 20716603 | 3.86146-06 182 |CsHAG2___[2.-DICHLOROPROPENE 54917 | 652026-01 | -1.62726-03 | 2.1034E-06 165 [C3H4O __[ACROLEIN 48.243_| 5.81006-01 | -1.90956-03 | 2.68606-06 154_[C3H40, iPROPARGYL ALCOHOL 43653_| 8263901 | -2.5747E.03 | 26700E-06 [185 [oak4o2 [ACRYLIC AGI. 18242 | 1.2108E+00 | -.1160-08 | 8.140960 186 |csH402 Ibeta-PROPIOLACTONE 45.746 | 5.25936-01 | -1,3036E-03 | 1.37256-06 61Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) Gp=A+BT+CT+0T (Gp -Joulel{mol K), T -K) FORMULA] Tae ry 5 € D_ [TaN | THAX TC, @25C (canaoz [MINYL FORMATE [210 | saaeve-or | aost0eas | arveseoe | 201 [aaa | 41.89 TETHYLENE CARBONATE 36.596 | 7.7104E-01 | -1.62206.03 | 1,39756-06 | 311_| 711 | —— ~JPYRUVIC ACID 5286 | asee4E-01 | -24314E-03 | 239706-06 | 288) S71 19848 [SBROMO-1-PROPENE 413050 | -7.9600602_| 41977E04 | —— | 165) 973] 12735 "2-CHLOROPROPENE 64.195 | 407606-01 | -1.46756-03 | 246396-08 | 137 | «30_| 12087 'S — [CYANOGEN CHLORIDE iakare | -1orv0e-02 | 1 aea7E-0a | 3.16056.06 (CYANOGEN FLUORIDE 2aaae | -14S44E00 | 44216609 | 2.77056-06 | 350 [CARBON MONOXIDE 425.595 | -4.7022E+00 | 1.0707E-02 | 4.1854E-06 126 — (CARBONYL SULFIDE 96329 | 02100699 | -1.17306-09 | 410436-068 | 1a4_| 70) sat [CARBON OXYSELENDE 208.725 | 11581600 | 3077003 | 152096.06 | 200 | 986] 9608 ‘CARBON DIOXIDE = 73981,020 | 525116401 | -22708.01 | a.2868€04 | 220 | 290) —— (CARBON DISULFIDE = ‘34309 | 18209601 | 2105800 | 320606-07 | 164 | 640 | 7ea5 [atos2| -8.67s6-02 | -224006-04 | 82407607 | 190 | ~e8 | 99.08 273.325 | -1.8946€+00 | 4.1012E-03 | -1.9851E.06 | 239 380, 409.65 "CARBON SELENOSULFIDE [CYANOGEN ‘CARBON SUBSULFIDE — (CALUM 57358 | S.e504E-02 | 1750008 | -2.16466-00 (CALCIUM FLUORIDE 1123067 | -7.39726-03 | -6.74826-06 | 3.19506-00 ‘COLUMBIUM FLUORIDE — (CAOMIUM ‘37742 7186286-05 | 3 75346-09 oo —Jeabwium cAoRIGE ari @50796.05 | -9.00146-00 70 |Car2 [CADMIUM FLUORIDE s1946 | oess08 | 60000609 71 [ea |eabwiuw ope | tzzva 4206.06 | 16731608 [72 [eso [CADMIUM OXIDE — =e 73 [GF [CHLORINE MONOFLUORIDE Tae] aearaeas | Aaaoie.06 tae : 74 |GFOS_|PERCHLORYL FLUORIDE —=SSS~S~C«S8B 9.2470E-04 | 2.99806.08 | 125 76 [cars CHLORINE TRIFLUORIDE 27279 ‘B.9492E-04 | 6.1428E.07 | 190 78_|ors CHLORINE PENTAFLUORDE peaare '276006-08_| -1.08206-06 | 190 77_|oHoss TCHLOROSULFONIC ACID. 140.318 "| -3'51096-0¢ | 7.04856.07 | 193 78_|CiHOs TPERCHLORIC ACIO_ 97.789 _| 9.2028E-02_| -2.8693E-04 | 7.5547E-07 572. 78Table 3-2 HEAT CAPACITY OF LIQUID - INORGANIC COMPOUNDS (continued) CpeA+BT+CT+DT? (Cp -joule/(mot K), T - K) RO_[ FORMULA AME x o c 3 TWIN | TWAX | C @ 256 73 [CHLORINE DIOXIDE 786.165] BOSS7EDT | Ta0seEGS | GONE | 24 | 442) 9277 2 (CHLORINE ‘a7.601_| -60216e-01 | 1.5776E.05 | -6.30096-07 | 172 | 396 | 7425 a1 [CHLORINE MONOXIDE 114657 | -1.39586.01 | -1.0421E-04 | 1549608 | 157 | 422) 9640 a2 (CHLORINE HEPTOXIDE 176.297 | -251046.02 | -6.0716E-04 | 1.94426.06_ | 182) 537 | 189001 [es (COBALT 10.685 | -1.05656-02 | 3.14796-06 | -2.09506-10 | 4768 | 5919 4 (COBALT CHLORIDE — |/"aea72_ | -2.98086-01 | 2.54736-04 | -«.96906-08 | 1008 1724 88 [COBALT NITROSYL TRICARBONYL ——_————— [5 [cHROWUM ae7e2_| Bs207e-03 | 271836-06_| “i.7r04e-10 [ar [CHROMIUM CARBONYL — — | —— a [CHROMIUM OXYCHLORIDE 733278 | 67177602 | Sesoseo4 | 7.12016-08 8 [cESIUM 37.749 | -1.65626-02 | 1078-05 | 9.0457E-10 0 (CESIUM BROMIDE TF ste0s | “seoate-03 | -1.03646-05 | 6.543609 1 (CESIUM CHLORIDE ~| 96.256. | 5 51986.03 16.28506-09| 32 (CESIUM FLUORIDE -3.20106.02 '3.18706-09| 3 [CESIUM IODIDE “25220603 ‘[6:35656-09 34 [COPPER 4s707E 03 5.33826-10 3 [CUPROUS BROMIDE | 1.6494E-02 326.05. 7.54086-09 36 [CUPROUS CHLORIDE ~ “48240E.02 | 4.25526.05 | 120106-08 sr ICUPRIC CHLORIDE T1.89816-01 | 1.1396E.04 | -1.49896.06 38 [COPPER IODIDE TI 6.4358E-03 | -14481E-05 | 6.5529E-00 2 (DEUTERIUM CYANIDE = ~1.30026+00 |” 2.9514E-05 | -1.4668E-08 [DEUTERIUM -25061E+01 | 1.2676E+00 | -1.98556-02 (DEUTERIUM OXIDE -267S7E+00 | .3538E-05 | -3.43216-06 [EUROPIUM | .28556-02 | 5.65306-06 | -5.39606-10 [FLUORINE | “Te5iGE01 | 5.25056-03 | 46517E06 FLUORINE OXIDE ‘B6i17E02 | -1,7926E03 | 1.10996-05 IRON 15748602 | 3.81256-06 | -1.61106-10 | 1808 | 7472 RON PENTACARBONYL “S.18296-01 | 6.43256.04 | 3.60096-07 | 262 | 577 FERROUS CHLORIDE -2.68236-01 | 1.72606-04 | -3.08826-08 | 045 | 1683 [FERRIC CHLORIDE {096.001 | -4.3838€+00 | 65061603 | 31125606 |_577_| 772 FRANCIUM 32919 | -2.59906-03 | -2.96366-06 | 7.454909 | 300__| 1285 (GALLIUM 29.056 | -3.9678E-03 | 1.49126-06 _| -3.3660e-11_| 303 | 6096 [GALLIUM TRICHLORIDE 93.606 | 465106-01 | -16817E-03 | 1.82486-06 | 51 | 555 [GADOLINIUM 493258 | -14211€-01 | 66794605 | -9.60186-09 | 1567 | 2646 | —— [GERMANIUM 34.272 | -3.96826-03 | 1.10256-06 | -5.7618E-11 | 1211 | 6720 (GERMANIUM BROMIDE 209.163 | -9.3641€-01 | 273566.06 | “299 | 703 [GERMANIUM CHLORIO 42720| 3 0086-01 | 2s749e 224 | 45 | 12801 ITRICHLORO GERMANE 140.720 _| -1.46166-01 | -1.1764E-04 202 [532 | 1471_| [GERMANE 74.535 | -197MEO1 | 2.7066E-06 107 | 28, IDIGERMANE 134.195 | 6.977902 | -4.40326-06 16) 465 | —_[TRIGERMANE. a _[erae-o1 168_| 586 HHYOROGEN BROW 207356 +00 SE HYOROGEN CYANIDE 252213 | 141446100 | 3.06256-03 | ~1.18276-06 | HYDROGEN CHLORIDE [73.983 | -1.25466-01 | -7.e0606.05 | 26409606 | 165 | 308 ——JHYDROGEN FLUORIDE 7 24418 | 203826-01 | -9.49906-06 | 1.8975E-06 | 190 | «38 4 HYDROGEN IODIDE 196,724 | -7.27056-01 | 1.9425E.03 | -1.07796-06| 222” | 403 NITRIC ACID 214478_| -7.6762-01 | 14970603 | 3.02086-07 | 259_| 494 HYDROGEN 30.607 | -6.11366+00 | 30880601 | 41480605 [14 | 32 | — WATER. 9205] -2.99696-02 | -2.11036.04 | S24606.07 | 273 | 61s | 7555 [HYDROGEN PEROXIDE - =15240_| 67699E-01 | -1.4940E-03 | 1.20106.06 | 273 | 604 | 05.55_| HYDROGEN SULFIDE 20.905 | -1.2464E-0f | -3.60556-05 | ‘604206 | 191 | 355 | 9552 SULFURIC ACID 25.006 | 7.039701 | -13956e-03 | 7.0342e-06 | 268 | a79 | 139.05 HYOROGEN DISULFIDE yas.e04 | -6.49656-02 | 32435606 | 1.1672606 | 163 | 515 | 10858 HYDROGEN SELENIDE 336.560 | -3.0726E+00_|_1.12666-02 | ~1.29866-06 [HYDROGEN TELLURIDE [aoasra | -.t0t0Ev00 |2.76106-09 | -142%26-06 ISULFAMIC ACID ———— HELIUM Fa0ot | -Lasosesor | 1a067E+ot | 21265600 HELIUM ‘B4008E+00_|-7.S597E¥00 | 1.5064E+00 137 [Hf HAFNIUM -2.20636-05 | S.64086-07 | ~1.47096-11 136 [Hg iMERCURY — =1.09006.02 | 9.46126-08 | 67418E-10 199_[Hg82 'MERCURIC BROMIDE 230636100 | 5.598503 _| -1 7298606 ‘0 Hgoiz IMERCURIC CHLORIDE ——t “B72T1E*00 | 6.6892E-03_| -2.60026-06 at Hola IMERCURIC IODIDE | ~15511€+00 | 2.1514E-05 | -9.36706-07 27 IODINE HEPTAFLUORIOE 748,653 | 4 7652E+00 | 1.17506-02 | -7.93686-06 32 IODINE 314.003 | -1.3711E+00 | 256576-03_| -14916-06 14 INDIUM 9003603 | 230816-08 | -87I1TE-11 45 |i im1UM A7750E-03 | essrie-o7 | 3.7H76E-t 6k [POTASSIUM =1.68706-02 | 1.39136-05 | -7.60006-08 147 KBr IPOTASSIUM BROMIDE “15270602 | -127696-06 | 3.7604E-09 48 [Kr [POTASSIUM CHLORIDE =1.8986E.01 | 87872605 | -891T1E09 48K iPOTASSIUM FLUORIDE “42559602 | 1.41026-05 | 42341E-10 150k [POTASSIUM IODIDE "2.73696-02 | 6.2787E-06 | 8.0067E-09 151 KOH [POTASSIUM HYDROXIDE 42195602 | 4001705 | 1.716266 _| 182 [kr KRYPTON 7.96286-03 | -1.19906-05 | 6.69506-06 155 [la LANTHANUM 4.13756.03 | 10178606 | 4.132111 | i193 7609 | — ou iLTHIUM, 74.3610E.02 | 7.10026-06 | -27361E-10 | 454 75. [UBr [LITHIUM BROMIDE 1.16086-02 | -1.80016-06 | 7.4021€-08 | 620 “6 [uct [LITHIUM CHLORIDE ‘e.1102e-03 | -1449se-05 | 6.073209 | 687Table 3-2 HEAT CAPACITY OF LIQUID - INORGANIC COMPOUNDS (continued) Ce=A+BT+CT+DT? (Cp - Joule/(mot K), T- K) TAME x 5 © THIN TWAX | @25C THOM FLUORIDE 7.688 | 45726E-03_| 45210606 | 270I2E09 | _1143_| 2546 | — UTHIUM IODIDE ‘easzr | 17582602 | 26138605 | 1.12657E-08 | Tis | 1882 | — LUTEUM ~~ | sr.002 [9036-07 | 2se5se-05 | 2552609 | i996 | s303 | ——] [MAGNESIUM T1613 | -6.24946-02 | 1.63956.05 | 6.67226-00 | 923 | 1789 [MAGNESIUM CHLORIDE 102.000 | -635166-03 | -03042E-06 | 6.12116-00 | 085 [MAGNESIUM OXIDE 602235 | -a64s7E-01 | 7.57966-05 | -4.43066-00 | 9105 MANGANESE 56.925 | 1.235802 | 39700E-06 | -26267E-10_| 1519 [MANGANESE CHLORIDE 173626 | 46248602 | 130106-05 | 4.071609 | 973 MOLYBDENUM 152.902 | -a.8860e-03 | 1.45426-06 | -5.2798E-11 | 2005 [MOLYBDENUM FLUORIDE -03 708 | -1.8884E+00 | .60236-03 | -1.57636-08 | 200 [MOLYBDENUM OXIDE 382496 | -4.01996.01 | 242406-08 | -42007E.08 | 1066 NITROGEN TRICHLORIDE 192643 | -6.10996-01 | 1.0601E-09 | -6.674E-06 | 246 “THEAVY AMMONIA za7.e4 [144956000 | 40877600 | 29781E-06 | 199 NITROGEN TRIFLUORIDE 72458 | 3.9006€-02 | -1.60126-03 | 1.03346-05 | 66 [AMMONIA 492.167 | 39618600 | 430902 | 20971605 165 HYOROXYLAMINE 499.200 | -2 1067e+00 | 398026.09 | -1.50726-06 | 306 TaMMONIUM IODIDE TAMMONIUM HYDROXIDE: "AMMONIUM HYDROGENSULFIDE =| — 7 [NITRIC OXIDE '9960.145 | -21310E+02 | 1610700 | -3.4579E03 NITROSYL CHLORIDE 761.178 | -82714E-01 | 1.94516-03 | -6.30036-07 INITROSYL FLUORIDE: 736501 _| 45008601 | 3706-04 | 1.7172E-06 INITROGEN DIOXIDE 916.569. | 9.0560E¥00_| -2.5096E-02 | 2.52576-05 INITROGEN — 76A82_| -3.5726E.01_| -2.66906-03 | 5.0087E-05 ITETRAFLUOROHYORAZINE 411.713 | -2:38006.02 | -145186-03 | 6.64836.06 HYDRAZINE __ 71,025 | 24089501 | -82065E-04 |” 1.4247E-06 [AMMONIUM CYANIDE 407.226 | -1.9783E100 | 4.0513E.05 | ~1.62246-08 [AMMONIUM CARBAMATE —— | — — INITROUS OXIDE 7220901 | “169086100 | 5.63206-03 | .65006-06 INITROGEN TRIOXIDE 149.038 _| -449666-02 | -15130-03 | 4.96206-06 [NITROGEN TETRAOXIDE | se7.s02_|-2.0627€+00 | “4.s1686-03_| -0.99106.07 iTROGEN PENTOXIDE [343.405 | -1.4532+00 | 2.89966-03 | -0.42406-07 [som ‘zeasi_| 852116-02 | -4440te-05 | 16921600 ‘SODIUM BROMIDE 495901 | -1.1628E-01 | §:59016.05 | -5.31096.09 ‘SODIUM CYANIDE. 69.087 | 3.00876-02 | -4.1570E05 | 1.5878E-06 ‘SODIUM CHLORIDE, 95.016 | -3.10816-02 | 9.6789E-07 | 55116609 TSODIUM FLUORIDE. 47.103 | 1.9241E-02 | -6.2069E-06 SODIUM IODIDE — ‘yasio | ~#.10766-00 | 67740608 ~|Soo1um HvoRoxiE 454296-00 [1 180 |Na2S04 SODIUM SULFATE “346656.05 | 157716.08 NosuM 38068 | az2siea3 | Sstsie07 | 23666-11 NEODYMIUM sass] evedeas | 11701608 [5 106-11 NEON [hztisesor | aosoee 01 | 1 s0e6e-03 IicKEL 3ea8 | -.zed0ea2 | asn2se08 | 28218E-10 [NICKEL CARBONYL — 794.160 | -4.68206+00_ | 1.30296-02 | -1.10776-05 NICKEL FLUORIDE 658.200 | -7Sseie01 | S5074E04 | 46049500 INEPTUNIUM we [OXYGEN [~aeaaz | saeneeai | roseae-0s | Saeere 06 (OZONE ao.27o | e.j2046-01 | -460096-03 | 1.30396.05 (OSMIUM 45.089 | -5.1072E-03 | 6.4646E-07 | -3.6497E-11 (OSMIUM OXDE PENTAFLUORDE [OSMIUM TETROXIDE - YELLOW [OSMIUM TETROXIDE - WHITE SS ;PHOSPHORUS - WHITE sear0 | Saotoa | woeeaees | aeaereoe | a |_7e8 | — [PHOSPHORUS TRIBROMIDE 431.023 | 4.0737E-02_| -3.5824E-04 | 6.7756E-07 233 675, 120.34 PHOSPHORUS DICHLORIDE TRFLUORIDE | “o40.002 | -150026+00_| Set02e-03 | -152266 08 [PHOSPHORUS TRICHLORIDE 5096-01 | 8.20006.04 | 105486.07 [PHOSPHORUS PENTACHLORIDE =| ——— a [PHOSPHINE = 420475 | -7.7634E-01 | 26214603 | -1.6233E-06 [PHOSPHONIUM BROMIDE * [109.186 | 6.3133E-02 | -7.3609E-04 | 1.7678E-06 TT 'PHOSPHONIUM CHLORIDE Bari s7e | -2.76G4Ev01 | 91040602 | 9.49056-05 | 245 | 206 | 20070 ;PHOSPHONTUM IODIDE 322737 | 14722600 | BoRDIEOs | -13427E-08_ ~ [PHOSPHORUS OXYCHLORIDE 4169 | 4.76046-01 | 104676.09 2. "2626.07 ‘PHOSPHORUS THIOBROMIDE ———— [PHOSPHORUS THIOCHLORIDE 170.596 | -1,8690E-01 | -3.1267E05 | 6.9512E07 [PHOSPHORUS TRIOXIDE 341.331 | -6.3516E-01 | 6.3560E-04 | 4.0286E.07 'PHOSPHORUS PENTOXIDE ipriaos | 2ie7seoo | Azee808 | Gasi7E07 {LEAD basi | -77ebiea3 | sats2e-06 | 0 [LEAD BROMIDE: 114.209 | 1.53836-02_| -4.5212E-05 | 2.7510E-08 Ttexo crtoRDE 145720 | 60046-02 | 2.17916-05 | 0.162460 [LEAD FLUORIDE, = 232.369 | -2.1673E-01_| 1.1455E.04 | -1.63646-08 Tess oo faa [treater | isemees | BTSs [LEAD OXIDE on 2s 257ee a2 206706. 05 | -0,480%e-10 [LEAD SULFIDE 490.517 | -7.4455E-01 | 4.2487E-04 | -7.7903E-06 | [PALLADIUM 39,908 | 4.3823€-03 | 1.01196.06_ ts 4 5196E-11, 80Table 3-2 HEAT CAPACITY OF LIQUID - INORGANIC COMPOUNDS (continued) Gp=A+BT+CT +P {C5 ~Joulel(mot K), T-K) TaN = c O—— [TaN [TAK TC @2EC Beare | aawroeae | Tasweas | aavoe Do 527 | 2470 — | doses | .s007e-05 [4 t2a0e-07 | S367ae-11 2002 | s58e — ee a7? | aaserea | terzreas | Saooee.00 319 | 1600 | —— [RUBIDIUMBROMDE —[os38 [eae “6.15796-08 | 477926-09 | 955 | 2117 | ——_ RUBIDIUM CHLORIDE 74.42 | -tzese-a2- | -3.57086-06 | 3.0es7e-09 | 98 | 2165 | — ~JRUSIOUM FLUORIDE e016 | -20se2e.a2 | 1 s4G2e.08 | 9.21406-00 = 7a7a_| .08096-99 | -6.90596-06 | 6.50876-08 RHENIUM _— = —— ;RHENIUM HEPTORIDE — [RHODIUM wane? | aaaoreo | G7eneo7 | Seo76e-1t | [RADON _ _ 53.121 | 42264601 | 1.20966-04 | 8.26606-07 {RUTHENIUN — 3g860_| 5000603 | e27ec07 | -27066-11 | [248 [Rus | RUTHENIUM PENTAFLUORDE ———— on 20's ‘SULFUR = 406080. | 2srese.0i | 27729e.04 | 59964E-08 | 208° {SULFUR TETRAFLUORDE 161210 | 47364-01 | 20706E-O4 | 2666-06 [SULFUR HEXAFLUORIDE ets 199 | -s9046Eor | 57400602 | -5.95106-05 “THIONYL BROMIDE 35269602 | -26i186-04 | 7.21906-07 —TTTHIONYE CHLORIDE “20ssee-02 | -3705tE-04 | 1.05596-06 a 'SULFUROUS OXVFLUORIDE “77319601 | 19849603 | 0606-08 | 169 | 958) 106.15 [SULFUR DIOXIDE. 10597600 |-26t¥36-03 | 10807606 a0) 9308 | a56-[soaca~SULFURYL CHLORIDE “21659601 | -8.0T886-05 | 1.04046-06- ~as6 | 195.40 257 {80a SULFUR TRIOXIDE: 190101 | 1.19506-01 | A11T7E08 as3_| 25697 358_[s202 SULFUR MONOCHLORIDE 4517902 | 46947604 | 85402607 626 _| 11033, 250_[sb ANTIMONY .12026-02 | 40016-08 | -4.97626-10 1056 — | a0 [sear ANTIMONY TRIBROMIDE. “B0276.01 | 489796 04 | -104196-07 74) = 261_[Sbci8 "ANTIMONY TRICHLORIOE “4.4830E-01 | 4.33656-04 | 15743607 754 262 [S005 TANTIMONY PENTACHLORIDE SATIIEO1 | 590096.04 | 920296.07 [saa] saa 263_[soro ‘STINE w= af90E-04 | 1.10526-09_| -290596-07 ai) 7072 ets [ANTIMONY TRIODIDE BEn0E01 | 215NEOF | CoRREDS er [25 |se208_[awriwony Teioxiog — _ sl [ase Ise {SCAND 7a9ese-08 | 20970608 | .pe6eE-10 a 287 [Se TSELENIUM ‘50628 | 49298602 | 41165605 | -5.20866-08 ig | — 260_[se0ie [SELENIUM TETRACHLORIDE 410.204 | 49045600 | 20811609 | semte-o7 | 400 | 707 | 20 Sor 'SELENUUM HEXAFLUORIDE ‘Sa1sta_| aosedeso0 | 11778602 | 94a4tE-06 250 | 210 [seoc [SELENIUM OXYCHLORIDE t7eszi_| 2 76036-01 | 20s066-04 | 329006.07_ a as [se02 [SELENIUM DIOXIDE a ee = aa |S —Jsiticon — seem | ‘36se02 | 5706-06 | TeaTve-10 a7 273|sibrGaF__ |ROWODICHLOROFLUOROSILANE jeozs2 | azasre-a2 | 63060604 | 17311606 a2 27st TTRIFLUOROBROMOSILANE 758919 | -1.7sase100 | 60455608 | 19086-06 357 275_sier2c | DIBROMOCHLOROFLUOROSILANE 5161 | -224586-02 | -5.19046-04 | 1.55096-06 “509 276 SiC TTRIFLUOROCHLOROSILANE 99074 | -6.17606-01 | 1.07356-05 | 1.9250€-06 “au 2T1_|SiG2F2__[DICHLORODILUOROSLANE | taaaTo | -1eree-ot |. asre-o¢ | 27500605 an “z7e_‘'SicaF ~~ TRICHLOROFLUOROSILANE "tas ses -sccsee-o2 | S2ese.o« | 0016.06 | ar | a8 Isica ISICON TETRACHLORIDE 70,175 | -1.70266-01 | 40824604 | 1 841%E: 260 |SiF4 [SILICON TETRAFLUORIDE 7140.08 | 2enveEsor | 11689601 | -16114E-04 206 ets TRIBROMOSILANE “95597 | -15975e02 | 9.45816-04 | e6z266-07 580 262 [SHOS_ TRICHLOROSILANE 15924 | 9.49926-02 | -1.04606-03 | 2.5710E-06. 5 209_SHFS TRIFLUOROSILANE ‘f7aa04 | -13900E+00 | 4s4sie03 | a3017e06 | 142) 276 2e4_|sii2a@ —[DIgROMOSILANE 157771 | -1.64066-01 | -488436-05 | 6.65996-07 | 208) 623 [25 |sitzci2 ~~ TDICHLOROSILANE 16138 | -207656-02 | 56554604 | 19909605 | 151/427 206 _/SiH2F2 IDIFLUOROSILANE 547 ["ss4rae-00 | -.60486-06_[ 302 2er_|siH2i2 DIODOSILANE [7506 ‘6846.06 | 494506-07 [er 288_|SIH3Br [MONOBROMOSILANE | 127.539 ‘5.9B77E-04 | 6.1058E-07 | 179 | 431 29 Ist3Ci IMONOCHLOROSILANE 114792 49100604 | 1.15186.08.) 155377 790 _[SHaF IMONOFLUOROSILANE {tetisa2 | -1.3957e+00-}"s 1056-03 | ~4.00286-06 | 150272 201 [sina ODOSILANE. — 160.602” | 4.66426-01 | 7.23906-04 | 97261607 | 216 | 489 2 SLANE 5067 | sa7ase.01 | es7oe-os | 2.01s56-06 | 08 | 256 3 SILICON DIOXIDE 349910 -2a2996.01 | 944996.05 | -9.006E-09_| i903 | 261 ze IHEXACHLORODISLANE: ana025_| 60011601 | ea8est.os | 472656-07 295 |HEXAFLUORODISILANE _— 567.874 | -3.6969E+00 | 9.6960E.03 | -6.3074E.06 | 255 | IISLANYL CHLORIDE 302094 -4.9590E+00 | 26779609 | ~1.1406E-06 | 250 [297 DISILANE 20754 | -1.62596-01 | 90012605 | 185206.00 | _v41 2 'TRICHL OROTRIFLUORODISILOXANE i7n7es | S763s.02 | 99406604 | 25162605 | 150 8 IHEXACHLORODISILOXANE 754705) 22799601 | 141E-O4 | 9st03e.07 | 240 00 DISILOXANE 17796 | 52777608 | -79248E-04 | 281206-06 | 129 01 lOCTACHLOROTRISHANE [asa 720 | -Sataae-as |'5.11056-04 | 9.59526-07 250) ‘302 ITRISILANE _ 34.027 | 4.06846-02 | -7.21056-046 | 1.761606 | 156 [303 'TRISILAZANE _—_ —irrara [3.720602 |"-6.86546-04 | 2.10506-06 | 167 | 4 ETRASIANE e770 | S19016.02 | 7 7967E04 | 16714605 | 180 28 ISAMARIUM Teast | -2azdbe.a2 | 4.14B4e-05 | ~1.11476-00 | 7945 | 306 TIN ~ 32.185 | -3.61026-03 | 1.1207-08 | 9.7579E-12 | 505 307 |snBre [STANNIC BROMIDE ~~ [26.159 | -3.04856-01 | 1.98926.06 | 3.31256-07 | 304 300_[sncia ISTANNOUS CHLORIDE 1 asr 3 70056-05 | 3 5000-05 | 4 19026-08 | 520 309 [snce ISTANNIC CHLORDE 197452 | -A6s076-01 | 6206.06 | @80956.07 243 30S [STANNIC HYDRIDE secu | Azre7eai | 3.1Ms7e-04 | 270166-06 | 123 [ oir Isnie ISTANNIC IODIDE sre sE-ot | 4s074E-04 | -0A751E-08 | 418 312 [Sr [STRONTIUM _ 52462 | -2.1746E-02 | 1.0468€-05 | -1.2018E-09 | 1050 81Table 3-2 HEAT CAPACITY OF LIQUID - INORGANIC COMPOUNDS (continued) CpsA+BT+CT+DT? (Cp - Joule/(mot K), T- K) WANE aT 5 c D THIN | TMAX [C/@ 25] [STRONTIOM ODE FBORGGE | DTAEVOO | ATIe2EOS | ASERSEGS | 2703] sate) — "TANTALUM [7 50312 | «5960603 | 7.15536-07 | -200526-11 | 3290 | 9900 | 4 "TECNNETIUN [47st | -s4901€-03 | 6.21496-07 | 26t086-11 | 2430 | 9900 iUM 444055 |-74313E.03 | 4.39666-06 | -44035E-10_| 723 | se72 | TTELLURIUM TETRACHLORIDE _____—_—_—|_ 571.987 _|-1.4606E+00_|1.68996-05 | 7.07136-07 | 497/667 "TELLURIUM HEXAFLUORIDE 416.124 | 296436100 | 8576103 | -606s1E-08 | 205 | a61 12138 STITANIUM 64.088 | -1.51286-02 | 35761606 | -1.7230E-10 “TITANIUM TETRACHLORIDE _ 628 -1.33446.01 | '8.7598E-07 a777 | “1.897602 | 105945 ” -99797e-02 | 605 03 “102519 | -701696-02 | 361146.05 _ 1.47286.09 #3955 | 3 41409. | “28172603 06-07 “[ -s.5a266+01 |"1.47266-01 “5:42606-03. | 1.13046-06 -2.2849E-01 | 1.86956-04 | 3.1641E-07 o6._| -4.a6866-10 | \LLOUS BROMIDE VANADIUM TETRACHLORIDE [VANADIUM OXYTRICHLORIDE ‘22e906-02 | 4.91886-06 | 103136-06 ‘TUNGSTEN — “TAT44E-08_|1.0698E-06 | -4.2705E-11 TUNGSTEN FLUORIDE 4,6493E+00 | 4.05586-03 | -1.69316-06 "XENON "7.0584E-02 | -27036-04 | 26119606 ROI -202066-62 | 9.4676E-06 | -1.06776-09 iyTRIUM “6.9676E-03 | 1.7585E-06 | -9.18206-11 zinc “3.5075E.02_|1.59966-05 | -1,6076E-09 INC CHLORIDE =T.88006.02 | 3.5706E-05 | 1.14106.08 | [ZINC FLUORIDE -B.85286-02 | 1.88006-05 | 8.14136-10 [ZINC OXIDE ee ar ‘SULFATE ———— (ZIRCONIUM 49.471 | -6.1487E03 | 85190607 "ZIRCONIUM BROMIDE 71882.940 | -44975E+01 | 5.75146-02 | -2.4424E-05 "ZIRCONIUM CHLORIDE 594.087 | -20485E+01 | 25705E-02 | -1.0725E-05 ZIRCONIUM IODIDE [s621.see [-1.9348e+01 | 22655602 | -8.77326-06 fT=temperature,K ITMIN - minimum temperature, K [TMAX - maximum temperature, K 82