10.3-1. 10.3-1. Equilibrium stage contact for Gas-Liquid system.

A gas mixture at
2.026 x 105 Pa total pressure containing air and SO2 is contacted in a single-stage
equilibrium mixer with pure water at 293 K. The partial pressure of SO2 in the
original gas is 1.52 x 104 Pa. The Inlet gas contains 5.70 total kg mol and the inlet
water 2.20 total kg mol. The exit gas and liquid leaving are in equilibrium. Calculate
the amounts and compositions of the otulet phases. Use equilibrium data from Fig.
10.2-1

Ans. XA1 =0,00495, YA1 = 0,0733, L1 =2,211 kg mol, V1 =5,69 kg mol.

Penyelesaian:
Fase gas ( A-B)
V2 = 5,70kg.mol/h
Ptot = 2,026 x 105 Pa
PA = 1,52 x 104Pa
V1= ?
yA2= = 0,075
yA1= ?
ABSORPSI
V1= ?
xA1= ?
L0 = 2,20kg.mol/h
xA0= 0

Fase cair( A-C)

 Laju alir cairan masuk(Lˈ)

 Lˈ = L0(1- xA0)

Lˈ = L0(1- xA0)
Lˈ = 2,20(1- 0)
Lˈ = 2,20kg.mol/h

 Menentukan fraksi gas SO2 keluar (xA1)

Dari tabel Appendix A. 3-19 Geankoplis dengan interpolasi diperoleh xA1

pada T = 293 K
Yaitu:

x A 1−0,0042 114−92
=
0,00698−0,0042 161−92

x A 1 −0,0042 22
=
0,00278 69
 x A 1=0,005

 Lajualir gas inert masuk (Vˈ)

Vˈ = V2 (1- yA2)
= 5,70 ( 1- 0,075)
= 5,272 kg.mol/h

Dengan menggunakan persamaan (1) dapat diperoleh nilai yA1;

(1)

0 + 5,272 [ 0,075
1−0,075
=2,20 ]0,005
1−0,005 [
+5,272
y A1
]
1− y A 1[ ]
0,427 = 0,11 + 5,272 [ y A1
1− y A 1 ]
0,416 = [ 5,272 y A 1
1− y A 1 ]
0,416 - 0,416 yA1 = 5,272 y A 1

0,416 = 5,688 yA1

yA1= 0,073

 Lajualir gas keluar (V1)

V'
V1=
1− y A 1
5,272
V1 =
1−0,073
V1 = 5,69kg.mol/h
 Laju alir cairan keluar (L1)

L'
V1 =
1−x A 1

2,20
L1 =
1−0,005
L1 = 2,211kg.mol/h
10.4.2
Interface Concentrations and Overall Mass-Transfer Coefficients. Use the same
equilibrium data and film coefficient k'y and k'x as in Example 10.4-1:
However, use bulkconcentration of yAG = 0,25 and xAL = 0.05. Calculate the
following.
a) Interface concentrations yAi and xAi and flux NA.
b) Overall mas-transfer coefficient k'y and ky and flux NA.
c) Overall mas-transfer coefficient k'x and flux NA.

k'y = 1,465 x 10-3 kg.mol A/s.m3 fraksi mol

k'x = 1,967 x 10-3 kg.mol A/s.m3 fraksi mol
Kins bulk yAG = 0,25
xAL = 0.05

Trial 1
Korelasi v́ (1-yA)iM dan (1-yA)iM Z|
Asumsi: (1-yA)iM = 1 dan (1-yA)iM = 1
Maka slope garis PM dari pers: (Grafik terlampir)

k' x / ( 1−x A )iM −3

1,967.10 /1
slope = − =-
k' y / ( 1− y A )iM −3
1,465.10 /1
= -1,342

Maka
Slope = tan θ
-1,342 = tan θ
1
θ= (−1,342)
sin
θ = Cotan (1,342) = 53,3
yAG = 0,25 XAL = 0.05
Dari grafik diperoleh XAi = 0.17 YAi = 0.095
Trial 2
yAG = 0,25 XAL = 0.05
YAi = 0.095 XAi = 0.17
Substitusikan pers:
( 1− y Ai) −( 1− y AG )
( 1− y A )iM =
ln [ ( 1− y Ai ) / ( 1− y AG ) ]

( 1−0,095 )−( 1−0,25 )

=
ln [ ( 1−0, 095 ) /( 1−0,25 ) ]
0,905−0.75
=
[ 0,187 ]
= 0,828

( 1−x AL ) / ( 1−x A )
¿
¿
ln ¿
( 1−x AL )−( 1−x A )
( 1 – x A )rA = ¿
( 1−0,05 )− (1−0,17 )
¿
( 1−0,05 )
ln[ ]
(1−0,17 )

0,12
¿
0,135

¿ 0,888

k 1x
−
( 1 – x A )rA −1,967 ×10 /0,888
−3
slope= =
k 1y 1,465 ×10−3 /0,888
( 1 – y A )rA
−3
2,215 ×10
¿− −3
1,764 × 10

¿−1,252
slope=tanθ

−1,252=tan θ (grafik terlampir)

o
θ=51, 38

didapat x A =0,18 ; y A =0,1

Trial 3

y Ah=0,25 x AL=0,05

y Ai=0,1 x Ai =0,18

substitusi ke

( 1− y Ai) −( 1− y AL )
(1− y A ) ℑ=
( 1− y Ai )
ln[ ]
( 1− y Ah )
( 1−0,1 )−( 1−0,25 )
¿
(1−0,1 )
ln[ ]
( 1−0,25 )

0,15
¿
0,182

¿ 0,824

( 1−x Ah ) / ( 1−x Ai )
¿
¿
ln¿
( 1−x Ah )−( 1−x Ai )
( 1 – x A )mA = ¿
0,13
¿
0,147

¿ 0,884
 NA
−
( 1 – x A ) ℑ 1,967 × 10−3 / 0,884
slope= =
Ky −3
1,465 × 10 / 0,824
( 1 – y A )ℑ
−3
2,215 ×10
¿− −3
=−1,252
1,773 ×10

Nilai slope = -1,252, nilainya sudah sama dengan nilai slope pada traial 2 yaitu

-1,252. Jika niali fraksinya : yAi = 0,1

Nilai diatas ditinjukkan sebagai titik M dalam grafik.

Substitusikan ke:
k' y
NA = ( y AG− y Ai)
( 1− y A )iM

−3
1,465 .10
= ( 0, 25−0,1 )
0, 824
= 1,777 . 10−3 ( 0,15 )
−4 kg . mol A
= 2,665 .10
s . m2 fraksi mol

Dan
k'X
NA = ( x Ai −x AL )
( 1−x A ) iM
-3
1,967 . 10
= ( 0,18−0,05 )
0, 884
= 2, 225 .10−3 ( 0,13 )
−4 kg . mol A
= 2,892 .10 2
s . m fraksi mol

b. Zat terlarut A mendifusi melalui B yang stagnant dalam fasa gas dan kemudian
melalui cairan yang stagnant.
Dari grafik diperoleh y* = 0,02 setimbang dengan xAL = 0,05 dan yAG = 0,25

x*= 0,35

Slope garis (m') antara E dan M pada grafik,untuk yAi = 0,1 xAi = 0,173
¿
y Ai − y A 0,1−0, 02
m' = =
x Ai −x AL 0, 173−0,05
= 0,65

y AG −¿ y 0,25−0,1
¿
Ai
= =0,84 7
x − x Ai
A
0,35−0,173
m' ' =¿
¿
( 1−x AL ) −( 1−x A ) ( 1−0,05 )−(1−0,35) 0,3
(1−x A )¿ M = = =
( 1−x AL ) ( 1−0,05 ) 0,379
ln[ ] ln ⁡[ ]
¿
( 1−x A ) ( 1−0,35 )

¿ 0,791

Dengan menggunakan persamaan berikut

1 1 m'
= +
K' x /( 1−x A )¿ M m'' k' y / ( 1− y A )iM k' X / ( 1−x A ) iM
1 1 0, 65
= +
K'x /0,791 -3
0,847x1,465 .10 /0, 824 1,967 . 10-3 /0, 891
1 1 0, 65
= +
K' x /0,791 1,505 .10 -3 2,207 .10-3
1
= 664 , 451 + 294 , 517
K' x /0,791

1
= 958 , 968
K' x /0,791

1
. 0, 791 = 958 ,968
K' x
0,791 = 958,968 K' x

K' x =8, 248 .10−4

k' X
NA = ( x Ai −x AL )
( 1−x A ) iM
 8,248 .10 -4
= (0,35−0,05)
0,791
=1,042.10−3 (0,3 )
−4 2
¿3,126.10 (kg.mol A )/( s.m fraksi mol)

10. 3-3 Stripping Taint from Cream by Steam. Countercurrent stage strippinh is to be
used to remove a taint from cream. The taint is present in the original cream
to the stripper at a concentration of 20 parts per million (ppm). For every 100
kg of cream entering per unit time, 50 kg of steam will be used for stripping.
It is desired to reduce the concentration of the taint in the cream to 1 ppm.
The equilibrium relation between the taint in the steam vapor and the liquid
cream is y A =10 x A , y A is ppm of taint in the steam and x A ppm in
the cream (E1). Determine the number of theoritical stages needed. [Hint: In
this case, for stripping from the liquid (L) stream to the vapor (V) stream the
operating line will be below the equilibrium line on the y A −x A diagram.
It is assumed that none of the steam condenses in the stripping. Use ppm in
the material blances].

kg
 Diketahui : V 1=50
ppm
y 1=θ

kg
L0=100
ppm

X A 0=20 ppm

y A =10 x A

m=10

 Ditanya : N..?
 Dijawab :
 100 kg Uap 50 kg

50 ppm 19 ppm

100 kg Uap 50 kg

2 ppm

L
A 1=
m. v

Lv
¿
mV 1

100
¿
10 . 50

¿ 0,2

(Grafik Terlampir)
 ( )
( y m ) ( 1−A ) + A
A N+ 1
x A0−
log
y
−(
m )
AN +1
x AN
N=
1
log
A

20− ( 100 )
0
1−( )
10
(¿)( ( 1−0,2 )+ 0,2)
log
1
log
0,2
¿¿
log(20 ( 0,8+0,2 ) )(1)
¿
log 5

log20
¿
log5

1,30103
¿
0,698

¿ 1,86