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Chemistry Co2 ms205

The document contains 25 chemistry problems involving calculations of mole fractions, mass percents, molarity, molality, concentrations, reactions, freezing point depression, boiling point elevation, vapor pressure, Henry's law constants, and osmotic pressure. The problems cover topics including solutions, electrolytes, solubility, gas laws, and thermochemistry.

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Thelma Cruz
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266 views9 pages

Chemistry Co2 ms205

The document contains 25 chemistry problems involving calculations of mole fractions, mass percents, molarity, molality, concentrations, reactions, freezing point depression, boiling point elevation, vapor pressure, Henry's law constants, and osmotic pressure. The problems cover topics including solutions, electrolytes, solubility, gas laws, and thermochemistry.

Uploaded by

Thelma Cruz
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Note: Highlight means that there is a different value

given
1. What is the mole fraction of urea, CO(NH2)2, in a solution prepared by dissolving 4.8g of urea in 30.3g
of methanol, CH3OH?

2. What is the mass


percent of an aqueous
sodium hydroxide
solution in 1000g of H2O
if the molality of NaOH is
10.7m?

3. How many grams of Al are required to react with 35mL of 2.0M hydrochloric acid, HCl?

__ HCl + __ Al → __ AlCl3 + __ H2

4. How many milliliters of 0.10M Pb(NO3)2 are required to react with 75mL of 0.20M NaI?

__ Pb(NO3)2 + __ NaI → __ PbI2 + __ NaNO3


5. The volume of a 32.4% (by mass) solution is 179.1mL. The density of the solution is 1.296 g/mL. What
is the mass of solute in this solution?

6. A 12.0% sucrose solution by mass has a density of 1.05g/cm3. What mass of sucrose is present in a
53.0mL sample of this solution?

7. Calculate the molarity of a solution of magnesium chloride with a concentration of 27.0mg/mL.


8. What is the molality of a 19.4M sodium hydroxide solution that has a density of 1.54g/mL?

9. If the concentration of sodium carbonate in water is 12.8ppm, what is the molarity of Na2CO3(aq)?
The molar mass of Na2CO3 is 106.0g/mol. Assume the density of the solution is 1.00g/mL.
10. A 15 meter by 12 meter pool of water has a depth of 2.2 meters. What mass of silver ion is present
in the reservoir if the concentration of silver ion is 0.14ppm? (1m3 = 1000L; assume the density of the
solution is 1.00g/mL)

11. What concentration of silver nitrate (in ppm) is present in 7.1 × 10–7 M AgNO3(aq)? For very dilute
aqueous solutions, you can assume the solution's density is 1.0g/mL. The molar mass of AgNO3 is 169.9
g/mol.

12. What mass of Zn(NO3)2 must be diluted to a mass of 1.00kg with H2O to prepare 97ppm Zn2+(aq)?

13. The solubility of 1-pentanol in water is 2.7g per 100g of water at 25°C. What is the maximum amount
of 1-pentanol that will dissolve in 2.1g of water at 25°C?
14. What is the freezing point depression (ΔT) of a 12.6-m solution of ethylene glycol (antifreeze) in
water? Ethylene glycol is a nonelectrolyte, and the freezing point depression constant of water is
1.86°C/m.

15. Propyl alcohol, C3H7OH, is a nonelectrolyte. A 0.370-mol sample of propyl alcohol is dissolved in
1.75 kg of water. If the boiling point elevation constant (Kb) of water is 0.512°C/m, what is the boiling
point elevation of the solution?

16. Rubidium chloride, RbCl, is a strong electrolyte. What is the freezing point of a solution formed by
dissolving 15.0 g of RbCl in 0.125 kg of water? The molar mass of RbCl is 121 g/mol, and the freezing
point depression constant (Kf) for water is 1.86°C/m.
17. Hydrogen bromide, HBr, is a strong electrolyte in water. What is the boiling point elevation (ΔT) of a
solution containing 125 g of HBr in 1.75 kg of water? The molar mass of HBr is 80.9 g/mol, and the
boiling point elevation constant (Kb) of water is 0.512°C/m.

18. What is the osmotic pressure (Π) of a solution containing 0.125 mol of a nonelectrolyte in 0.500 L of
solution at 25°C? R = 0.0821 L·atm/mol·K

19. Calcium nitrate, Ca(NO3)2, is a strong electrolyte. A solution contains 4.75 g of calcium nitrate in 125
mL of solution. What is the osmotic pressure (Π) of this solution at 37°C? The molar mass of calcium
nitrate is 164 g/mol, and R = 0.0821 L·atm/mol·K.
20. The partial pressure of O2 in your lungs varies from 25mmHg to 40mmHg. What mass of O2 can
dissolve in 1.0 L of water at 25 °C if the partial pressure of O2 is 40mmHg?

21. An unopened soda can has an aqueous CO2 concentration of 0.0506 m at 25°C. What is the pressure
of CO2 gas in the can?

22. A 35.0-g sample of ethylene glycol, HOCH2CH2OH, is dissolved in 500.0 g of water. The vapor
pressure of water at 32°C is 35.7 mmHg. What is the vapor pressure of the waterethylene glycol solution
at 32°C? (Ethylene glycol is nonvolatile.)
23. You add 0.255 g of an orange, crystalline compound whose empirical formula is C10H8Fe to 11.12 g
of benzene. The boiling point of the benzene rises from 80.10 °C to 80.26 °C. What are the molar mass
and molecular formula of the compound? (Kb of benzene is 2.53°C/m)

24. A solution is prepared by dissolving 0.6706 g of oxalic acid (H2C2O4) in enough water to make 100.0
mL of solution. A 10.00-mL aliquot (portion) of this solution is then diluted to a final volume of 250.0 mL.
What is the final molarity of the oxalic acid solution?

25. Nitrous oxide, N2O, laughing gas, is used as an anesthetic. Its Henry’s law constant is 2.4×
10−2mol/kg ∙ bar. Determine the mass of N2O that will dissolve in 500mL of water, under an N2O
pressure of 1.00 bar. What is the concentration of N2O in this solution, expressed in ppm (ρH2O= 1.00
g/mL)?

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