MBR Process Design Calculations-S.I
MBR Process Design Calculations-S.I
Tab 5. Denitrification
This workbook is provided "as is", without warranty of any kind, express or
implied.
Three worksheets are provided to carry out basin sizing and aeration calculations for the
membrane module(s), the aeration tank(s), and preanoxic tank(s) for denitrification, based
on the membrane module being immersed in the aeration tank.
There is also a worksheet for user input of wastewater flow and characteristics
and kinetic coefficients. The default values shown for the kinetic coefficients
are typical values.
The membrane module calculations require user input values of membrane modue
parameters that are typically available from the membrane module manufacturerer
or vendor.
The aeration tank and preanoxic tank calculations are based on the procedures
described for design of a completely mixed activated sludge system and for
design of an MBR system in the reference below.
Primary and secondary clarification are not typically used in an MBR wastewater
treatment system. Pretreatment of the raw wastewater must include fine screening
and if necessary, based on wastewater characteristics, coarse screening and grit
removal should be included.
MBR Process Design Calculations - S.I. units
User Inputs and Constants
Instructions: Enter values in blue boxes. Spreadsheet calculates values in yellow boxes
2. For Nitrification:
Synth. Yield Coeff, Yn = 0.15 g VSS/g NOx
Temp coeff, q, for mmn = 1.072 Max spec. grwth rate at 20oC, mmn20 = 0.9
Temp coeff, q, for kdn = 1.029 Endog. decay coeff. at 20 C, kdn20 =
o
0.17
Temp coeff, q, for Ksn = 1 Half Veloc. Coeff. At 20oC, Ksn = 0.5
Half Veloc. Coeff. At 20 C, Kso =
o
0.5
Constants Used in the Calculations
Ratio of BOD5 to BODu, f = 0.67 BODu equiv. of VSS = 1.4 g BODu/g VSS
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C
o
for mm dimensionless 1.03 - 1.08 1.07
for kd dimensionless 1.03 - 1.08 1.04
for Ks dimensionless 1.00 1.00
Adapted from: Metcalf & Eddy, Inc, (Revised by Tchobanoglous, G, Burton, F.L., Stensel, H.D.,
mg/L Wastewater Engineering, Treatment and Reuse, 4th Ed., New York, NY, 2003.
g VSS/d/g VSS
g VSS/d/g VSS Activated Sludge Nitrification Kinetic Coefficients at 20 oC
Adapted from: Metcalf & Eddy, Inc, (Revised by Tchobanoglous, G, Burton, F.L., Stensel, H.D.,
Wastewater Engineering, Treatment and Reuse, 4th Ed., New York, NY, 2003.
or BOD removal)
Instructions: Enter values in blue boxes. Spreadsheet calculates values in yellow boxes
(This is the scouring air flow rate needed for the membrane module,
typically provided by a coarse bubble diffuser system.)
Equations used for the calculations: (note that conversion factors are needed in some of
m
3
Am = Qo/J Vm = Am/f
vation in Worksheet 9)
9
MBR Process Design Calculations - S.I. units
BOD Removal and Nitrification
Instructions: Enter values in blue boxes. Spreadsheet calculates values in yellow boxes
User Inputs:
Target effluent concentrations:
BODe = 10 mg/L MLSS in Aer. Tank, XO = 10,000 mg/L
TSSe = 10 mg/L MLSS in Waste Sludge, XW = 10,000 mg/L
NH4-Ne = 0.5 mg/L Tank Freeboard = 0.5 m
DO in Aer. Tank, DOO = 2 mg/L Number of Aeration Tanks = 3
Influent TKN, TKNo = 35 mg/L Liquid Depth in Tank = 5.0 m
(value transferred from Worksheet 2) Tank L:W ratio = 1.0
Initial Estimate of NOx = 28.9 mg/L (target L:W - only used if tank is rectangular)
NOTE: An initial estimate is needed for NOx in cell C14 to start an iterative calculation
of NOx below. 80% of the influent TKN is suggested for this initial estimate.
Difference between estimated and calculated values for NOx = 0.000 mg/L
Goal Seek Result:
Amount of nitrogen oxidized to nitrate, NOx = 28.9 mg/L
NOTE: This is an iterative solution. You must use Excel's "Goal Seek" to find the NOx value as
follows: Place the cursor on cell G36 and click on "goal seek" (in the "tools" menu of older versions
and under "Data What If Analysis" in newer versions of Excel). Enter values to "Set cell:" G36, "To
value:" 0, "By changing cell:" C14, and click on "OK". The calculated value of NOx will appear in cell
E38 and cell G36 should be zero if the process worked properly. Note that cell C14 needs an initial
estimate for NOx in order for the iterative solution to work properly.
4. Determine the Production Rate and Mass of VSS and TSS in the Aeration Basin
5. Calculate Aeration Tank Volume and dimensions, Detention Time, and MLVSS
(User Input needed in Blue Cells)
Req. Aeration Vol., Vaer = 258 m3 Click on green box and then on
Aer. + Membr. Vol., Vtot = 269 m 3
arrow to Select Tank Shape: rectangular
Req. Vol. per tank, Vtank = 90 m3 Actual Tank Width: 16.0 m
Calculated Tank Width = 4.2 m Actual Tank Length: 16.0 m
Calculated Tank Length = 4.2 m Actual Aeration Volume/Tank = 1276 m3
Tank Wall Height = 5.5 m Membrane Module Vol. per Tank = 4 m3
i) INPUTS (Values of "Rule of Thumb" Constants for the Calculations - See info at right)
O2 needed per kg BOD = 1.30 kg O2/kg BOD Depth of Diffusers = 4.4 m
O2 needed per kg NH4-N = 4.57 kg O2/kg NH4-N Normal Temperature = 0
o
C
SOTE as Function of Depth = 6.56% % per m depth Normal Pressure = 1.000 bar
AOTE/SOTE = 0.33 Atmospheric Pressure = 1.014 bar
Press. Drop across Diffuser = 0.030 bar Air Density at STP = 1.275 kg/m3
(from mfr/vendor) O2 Content in Air = 0.2930 kg/m3
ii) Calculations
Press. at mid depth, PD = 1.2 bar NH3-N Removal Rate = 0.5 kg/hr
BOD Removal Rate = 3 kg/hr AOTE = 9.5%
Oxygen Requirement = 5.9 kg/hr Air Requirement = 210 Nm3/hr
SOTE = 29% Blower Outlet Pressure = 1.5 bar
(This is the air flow rate needed for the aeration tank,
typically provided by a fine bubble diffuser system.)
Calculations
Sodium bicarbonate needed per day to maintain alkalinity = 123 kg/day NaHCO3
Equations used for the calculations: (note that conversion factors are needed in some of the equations)
S/d/g VSS
COD/L PX,bio = QY(So - S)/(1 + kdSRT) + fdkdQY(So - S)SRT/(1 + kdSRT) + QYn(NOx)/(1 + kdnSRT)
nbVSS = [1 - (bpCOD/pCOD)VSSo]
V = Mass of MLSS/MLSS
F/M = QSo/V*MLVSS
Rules of Thumb for Estimating Oxygen/Air Requirements for Coarse or Fine Bubble Diffusers
Source:
http://www.xylemwatersolutions.com/scs/sweden/sv-se/produkter/cirkulationspumpar/documents/san3.pdf
1. The typical AOR/SOR (or AOTE/SOTE) is 0.50 for a coarse bubble aeration system.
2. The typical AOR/SOR (or AOTE/SOTE) is 0.33 for a fine bubble aeration system.
3. The typical SOTE is 0.75% per foot (2.46%/m) of diffuser submergence for a coarse bubble system
4. The typical SOTE is 2.0% per foot (6.56%/m) of diffuser submergence for a fine bubble system
5. Air weighs 1.275 kg/m3 (at 0oC and 1 bar) and contains 23% oxygen by weight, thus:
6. Air contains 0.2930 kg of oxygen/m3.
7. For biological treatment with SRT from 5 to 10 days, kg oxygen required /kg BOD removed
is typically in the range from 0.92 - 1.1 kg O 2/kg BOD. Higher SRT results in a higher value
of kg O2 required/kg BOD removed.
8. The oxidation of 1 kg of ammonia nitrogen typically requires 4.1 to 4.6 kg of oxygen.
Equations used for Oxygen/Air/Blower calculations: (note that conversion factors are needed in some o
O2 Requirement = (BOD Rem Rate)(kg O2/kg BOD) = (NH3-N Rem. Rate)(kg O2/kg NH3-N)
Blower Outlet Pressure = Patm + Press. Drop across Diffuser + g(Diffuser Depth)
Equations used for Alkalinity Requirement calculations: (note that conversion factors are needed in so
Alk. Conc. needed = Alk. used for Nitrification + Target Effl. Alk. - Alk
(mg/L
o
as CaCO3)
Sodium Bicarbonate Flow needed = (Alk. Flow needed)(Equiv Wt. of NaHCO 3)/(Equiv. Wt. of CaCO3)
1. Metcalf & Eddy, Inc, (Revised by Tchobanoglous, G, Burton, F.L., Stensel, H.D.),
Wastewater Engineering, Treatment and Reuse, 4th Ed., New York, NY, 2003.
2. Judd, Simon, "The MBR Book, Principles and Applications of Membrane Bioreactors
in Water and Wastewater Treatment," 2nd Ed, Elesvier.
kdnSRT)
users
needed in some of the equations)
of CaCO3)
MBR Process Design Calculations - S.I. units
BOD Removal Nitrification, & PreAnoxic Denitrification
This worksheet makes the design calculations for preanoxic denitrification basin(s) to
go with the Aeration Tank(s) designed for BOD removal and Nitrification in Worksheet 4.
(The wastewater parameters/characteristics and biological kinetic coefficients entered
on Worksheet 2 will also be used in this worksheet.)
Instructions: Enter values in blue boxes. Spreadsheet calculates values in yellow boxes
NOTE: A preliminary estimate for anoxic detention time is needed in cell C19 to start an
iterative calculation of minimum anoxic detention time below.
Prelim. est. of det. Time, tan: 0.704 hr
2. Calculate feed rate of NO4-N to anoxic tank and anoxic tank volume
Recycle flow
rate to anoxic tank = 2,945 m3/d NOX rate to anoxic tank = 12,370
(flow containing nitrate) Anoxic tank volume, Van = 15
(based on detention time value in cell C19)
3. Calculate the F/M ratio
SDNR for rbCOD/bCOD = 0.357 is equal to: 0.4446 g NO3-N/day/g biomass (at 20oC)
NOTE: This is an iterative solution. You must use Excel's "Goal Seek" to find the V an vand tan
values as follows: Place the cursor on cell H58 and click on "goal seek" (in the "tools" menu of
older versions and under "Data What If Analysis" in newer versions of Excel). Enter values to
"Set cell" H58 "To value:" 0, "By changing cell:" C19, and click on "OK". The calculated values
of Van and tan will be in cells C61 and H61. Cell H58 should be zero if the process worked properly.
A preliminary estimate for tan is needed in cell C19 in order for the iterative solution to work.
6. Recalculate the oxygen/air requirement due to the nitrate reduction oxygen credit
Equations used for the calculations: (note that conversion factors are needed in some of the equat
m
Active biomass conc: Xb = [ Q(SRT)/V ][ Y(So - S)/(1 + kd(SRT) ]
s rectangular) RAS Ratio: RAS = (NOx/Ne) - 1.0
kg/d
F/M = QSo/XV
hr
he V an vand tan
"tools" menu of
nter values to
culated values
worked properly.
on to work.
rectangular
m
m
m3
kg/day as CaCO3
kg/day NaHCO3
Qw = [((Vaer*MLSS + Vanox*Xb)/SRT)]/(TSSw)
ation & Denitrification
Temperature
Membrane Flux
o
C L/m2/h
Design Membrane Flux vs Temperature
5 11 30
10 14.5
10
The source for the Membrane Flux vs
Temperature data was: 5
0
Metcalf & Eddy, Wastewater Engineering 0 5 10 15 20 25
Treatment and Resouce Recover, 5th Ed, 2014 Temperature, degrees C
Figure 8-57
lux vs Temperature
835
15 20 25 30
ture, degrees C