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Electrochemistry Mittal Sir: Worksheet-I Objective Questions

1. The document contains 17 multiple choice questions related to electrochemistry. The questions cover topics like Kohlrausch's law, standard reduction potentials, electrochemical series, molar conductivity, degree of dissociation, and oxidizing agents. 2. Key concepts assessed include equivalent and molar conductivity, oxidation-reduction reactions, galvanic cells, and relationships between standard potentials and redox strength. 3. The questions are from various medical and engineering entrance exams in India and assess understanding of foundational electrochemistry principles.

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120 views3 pages

Electrochemistry Mittal Sir: Worksheet-I Objective Questions

1. The document contains 17 multiple choice questions related to electrochemistry. The questions cover topics like Kohlrausch's law, standard reduction potentials, electrochemical series, molar conductivity, degree of dissociation, and oxidizing agents. 2. Key concepts assessed include equivalent and molar conductivity, oxidation-reduction reactions, galvanic cells, and relationships between standard potentials and redox strength. 3. The questions are from various medical and engineering entrance exams in India and assess understanding of foundational electrochemistry principles.

Uploaded by

tarun
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ELECTROCHEMISTRY ( Worksheet-I Objective Questions) Mittal Sir

1. Equivalent conductivity of NaCl, HCl and 5. Kohlrausch’s law states that at :


CH3COONa at infinite dilution are 126.45, (a) finite dilution, each ion makes definite
426.18 and 91 ohm-1 cm2 respectively, the pH contribution to equivalent conductance of an
of 0.1 M solution of CH3COOH if conductivity electrolyte, whatever be the nature of the other
of 0.1 M solution is 39.071 ohm-1 cm2 ion of the electrolyte.
(a) 2 (b) 3 (c) 4 (d) 5 (b) infinite dilution each ion makes definite
contribution to equivalent conductance of an
2. Which reaction is not feasible electrolyte depending on the nature of the other
(a) 2KI + Br2 → 2KBr + I2 ion of the electrolyte.
(b) 2KBr + I2 → 2KI + Br2 (c) infinite dilution, each ion makes definite
(c) 2KBr + Cl2 → 2KCl + Br2 contribution to conductance of an electrolyte
(d) 2H2O + F2 → 2HF + O2 whatever be the nature of the other ion of the
electrolyte.
3. Which of the following expressions correctly (d) infinite dilution, each ion makes definite
represents the equivalent conductance at infinite contribution to equivalent conductance of an
electrolyte, whatever be the nature of the other
dilution of Al2 (SO4)3. Given that Λ° Al 3+ and
ion of the electrolyte.
Λ° SO 2− are the equivalent conductances at [AIPMT 2008]
4

infinite dilution of the respective ions?


6. The sequence of ionic mobility in aqueous
(a) Λ° Al 3+ + Λ° SO 2− solution is :
4

(b) Λ° Al 3+ + Λ° SO 2− × 6 (a) K+ > Na+ > Rb+ > Cs+


4
(b) Cs+ > Rb+ > K+ > Na+
Λ° Λ°
1 1 (c) Rb+ > K+ > Cs+ > Na+
(c) Al3+ + SO42–
3 3 (d) Na+ > K+ > Rb+ > Cs+
(d) 2Λ° Al 3+ + 3Λ° SO 2− [AIPMT 2008]
4

[AIPMT mains - 2010] 7. Standard enthalpy potential of three metals X,


Y and Z are –1.2 V, +0.5 V and –3.0 V
4. For the reduction of NO3– ion in an aqueous
respectively. The reducing power of these
solution, E° is + 0.96V. Values of E° for some
metal ions are given below metals will be :
V2+ (aq) + 2e– → V E° = –1.19 V (a) Z > X > Y (b) X > Y > Z
3+ –
Fe (aq) + 3e → Fe E° = –0.04 V (c) Y > Z > X (d) Y > X > Z
3+ –
Au (aq) + 3e → Au E° = +1.40 V [AIPMT - 2011]
Hg2+ (aq) + 2e– → Hg E° = +0.86 V
The pair(s) of metals that is(are) oxidized by 8. Limiting molar conductivity of NH4OH
NO3– in aqueous solution is(are) i.e. Λm(NH4OH) is equal to :
(a) V and Hg (b) Hg and Fe
(a) Λm(NaOH) + Λm(NaCl) – Λm(NH4Cl)
(c) Fe and Au (d) Fe and V
(Note : Question has one or more than one correct choice) (b) Λm(NH4OH) + Λm(NH4Cl) – Λm(HCl)
[IITJEE - 2009]
(c) Λm(NH4Cl) + Λm(NaOH) – Λm(NaCl)
(d) Λm(NH4Cl) + Λm(NaCl) – Λm(NaOH)
[AIPMT - 2012]

BMC CLASSES PVT. LTD. Page No - 1


III-A/172, Nehru Nagar Ghaziabad. Ph : 9811212090, 9818922090 Email : bmcchemistry@gmail.com web : www.bmcchemistry.com
ELECTROCHEMISTRY ( Worksheet-I Objective Questions) Mittal Sir

9. Molar conductivities (Λ°m) at infinite dilution of 13. At 25° C molar conductance of 0.1 molar
NaCl, HCl and CH3COONa are 126.4, 425.9 aqueous solution of ammonium hydroxide
2 –1
and 91.0 S cm mol respectively. Λ°m for is 9.54 ohm–1 cm2 mol–1 and at infinite
CH3COOH will be dilution its molar conductance is 238 ohm–1
(a) 425.5 S cm2 mol–1 cm2 mol–1. The degree of ionisation of
(b) 180.5 S cm2 mol–1 ammonium hydroxide at the same
2 –1
(c) 290.8 S cm mol concentration and temperature is :
(d) 390.5 S cm2 mol–1 (a) 2.080 % (b) 20.800 %
[AIPMT - 2012] (c) 4.008 % (d) 40.800 %
[AIPMT - 2013]
10. Li occupies higher position in the
electrochemical series of metals as compared to 14. Aluminium displaces hydrogen from acids, but
Cu since copper does not. A Galvanic cell prepared by
+
(a) the standard reduction potential of Li /Li is combining Cu/Cu2+ and Al/Al3+ has an emf of
+2
lower than that of Cu /Cu 2.0 V at 298 K. If the potential of copper
(b) the standard reduction potential of Cu2+/Cu electrode is + 0.34 V, that of aluminium
+
is lower than that of Li /Li electrode is
+
(c) the standard oxidation potential of Li/Li is (a) – 2.3 V (b) + 2.34 V
2+
lower than that of Cu/Cu (c) – 1.66 V (d) + 1.66 V
(d) Li is smaller in size as compared to Cu [KCET 2013]
[WBJEE - 2012]
15. The molar conductivity of a 0.5 mol/dm3
11. Read the following statement and predict the solution of AgNO3 with electrolytic
corresponding law. “At infinite dilution when conductivity of 5.76 × 10–3 S cm–1 at 298 K is
dissociation is complete, each ion makes a (a) 0.086 S cm3/mol
definite contribution towards total equivalent (b) 28.8 S cm2/mol
conductance of the electrolyte irrespective of (c) 2.88 S cm2/mol
the nature of the ion.” (d) 11.52 S cm2/mol
(a) Ostwald’s dilution law [NEET (II)- 2016]
(b) Kohlrausch’s law
(c) Nernst equation 16. Λ°m for NaCl, HCl and NaA are 126.4, 425.9
(d) Ohm’s law and 100.5 S cm2 mol–1, respectively. If the
[OJEE - 2012] conductivity of 0.001 M HA is 5 × 10–5 S
cm–1, degree of dissociation of HA is :
12. Given (a) 0.75 (b) 0.50
E° Cr 3+ / Cr = – 0.74 V; (c) 0.125 (d) 0.25
E° MnO4− / Mn2+ = 1.51 V [JEE Main (online) - 2019]
2 − 3+
E° Cr2 O7 / Cr = 1.33 V; E°Cl/Cl– = 1.36 V
Based on the data given above, strongest 17. Given that
oxidising agent will be : / = +1.23 V; / = 2.05 V
(a) Cr3+ (b) Mn2+
(c) MnO4– (d) Cl / = + 1.09 V; / = + 1.4 V
[JEE Main - 2013] The strongest oxidizing agent is –
(a) Au3+ (b) O2
(c) S2O82– (d) Br2
[JEE Main (online) - 2019]

BMC CLASSES PVT. LTD. Page No - 2


III-A/172, Nehru Nagar Ghaziabad. Ph : 9811212090, 9818922090 Email : bmcchemistry@gmail.com web : www.bmcchemistry.com
ELECTROCHEMISTRY ( Worksheet-I
Worksheet Objective Questions) Mittal Sir

18. Which one of the following graphs between


molar conductivity (Λm) versus √ is correct?

(a) (b)

(c) (d)

[JEE
JEE Main (online) - 2019]

19. The decreasing order of electrical conductivity


of the following aqueous solution is :
0.1 M Formic acid (A),
0.1 M Acetic acid (B),
0.1 M Benzoic acid (C).
(a) A > C > B (b) C > B > A
(c) A > B > C (d) C > A > B
[JEE
JEE Main (online) - 2019]

20. The equation that is incorrect is –


(a) (Λm0)NaBr – (Λm0)NaI = (Λm0)KBr – (Λm0)NaBr
(b) (Λm0 = (Λm0)HCl + (Λm0)NaOH – (Λm0)NaCl
(c) (Λm )KCl – (Λm0)NaCl = (Λm0)KBr – (Λm0)NaBr
0

(d) (Λm0)NaBr – (Λm0)NaCl = (Λm0)KBr – (Λm0)KCl


[JEE
JEE Main (online) - 2020]

21. Amongst the following, the form of


water with the lowest ionic
conductance at 298 K is :
(a) distilled water
(b) water from a well
(c) saline water used for intravenous
injection
(d) sea water
JEE Main (online) - 2020]
[JEE

BMC CLASSES PVT. LTD. Page No - 3


III-A/172,
A/172, Nehru Nagar Ghaziabad.
Ghaziabad Ph : 9811212090, 9818922090 Email : bmcchemistry@gmail.com web : www.bmcchemistry.com

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