Case Study Chem
Case Study Chem
Presented to
the Faculty of College of Engineering, Architecture and Fine Arts
BATANGAS STATE UNIVERSITY
Batangas City
December, 2019
INTRODUCTION
The diesel engine is the most efficient prime mover commonly available today. The
diesel engine is a major tool in the day-to-day life of modern society. Diesel fuel produces many
harmful emissions when it is burned, and diesel-fueled vehicles are major sources of harmful
pollutants, such as ground-level ozone and particulate matter. (ei.gov , 2019) Diesel emanations
add to the wellbeing impacts; contamination of air, water, and soil; reductions in visibility; and
BACKGROUND
Diesel fuel is refined from crude oil at petroleum refineries. The diesel engine is a major
tool in the day-to-day life of modern society. It powers much of our land and sea transport, gives
electrical power, and is utilized for many cultivating, development, and industrial activities. Most
major sources of diesel emissions, such as ships, trains, and trucks operate in and around ports,
rail yards, and heavily traveled roadways. Although they have many advantages, they have a
sector in producing global CO2 emissions with a range of 22%. Since 1970, vehicle’s exhaust
pollution have received increasing attention as a source of air pollution at both local (human
health concerns) and global (global warming) scales. ( Jie, 2011) It is considered as one of the
largest contributors to environmental pollution caused by exhaust emissions, and they are
responsible for several health problems as well. With diesel engines penetrating the private
transportation sector, their emissions are brought into urban centers, inevitably resulting in a high
and continuous exposure of a large part of the population. In 2010, 95 % of the urban
and 35 % of the atmospheric organic carbon mass in the ambient air of Birmingham (UK), could
be attributed to diesel engines (Yin et al. 2010) In 2018, diesel fuel accounted for about 20
percent of total U.S. petroleum use, or about 7 percent of American fuel consumption overall.
(Beck, 2019)
Primary pollutants emitted from diesel engines include: 1) Particulate emissions (PM)
which impair visibility, adversely affect plant growth and damage soil structure and property.
Black carbon particulates retain vitality, prompting air warming; 2) Carbon monoxide (CO) and
Carbon dioxide (CO2) which contributes to carbon dioxide, one of the ozone harming
substances prompting climate change; 3) Nitrogen oxides (NOx) which are the primary
pollutants that create low level ozone (smog), acid rain and nitrate particulates; 4) Volatile
Organic Compounds (VOCs) and nitrous oxides are the two leading pollutants that result in
ozone formation.
including climate change, acid rain and ground level ozone (smog). According to New
Hampshire Environmental Services (2014), diesel emissions adversely affect the environment by
interfering with climate, the physiology of plants, creature species and whole biological systems,
Despite the fact that progress has been made over the previous decade in diminishing
introduction to diesel exhaust, diesel exhaust still poses generous dangers to general wellbeing
and to the environment. Many agencies, organizations (EPA, OECD, IPCC, IEA, EEA, etc.)
worldwide were established and have been working to prevent air pollution and climate change
PRESENTATION OF FINDING
The advantages of diesel engine is that having high efficiency, durability, and reliability
together with their low operating cost. Because of these features, diesel engine is the most
preferred to be used especially for heavy duty vehicles. In the widespread use of diesel engine
with a lot of advantages, diesel engine play an important role in environmental pollution problem
word wide. Diesel engines are considered as one of the largest contributors to environmental
Air is the one who is suffering most from diesel exhaust emission. Diesel engine emits
nitrogen oxide which is common air pollutant. Polluted air contributes to the development of
diseases like cancer, and cardiovascular and respiratory problems. Diesel engines also is one of
the contributor for having global climate change. Due to increase demand of gasoline and diesel
To water and soil pollution,evaporative emission of diesel fuel constituents are lower
than those from gasoline due to closed system and low volatility. Because of that diesel fuel
spills, leaks from pipelines, tanks and roadways accidentally. The effects of fuel spills on aquatic
organisms include reproductive impairment, depressed growth rates, and increased susceptibility
ALTERNATIVES
There are different alternative solutions that the researchers found to lessen the harmful gases
that emits from diesel exhaust. The first one is the eco-friendly cars or electric cars. In this
generation, our technology is advanced and can make different things. There's one company
named Tesla, where they build an automobile that is powered by electricity. And by this electric
powered automobile, it does not emit harmful pollutants like nitrogen oxide. Electric vehicles as
they now stand are far less contaminating than their ignition motor partners. As the innovation
turns out to be more standard, it is probably going to turn out to be significantly progressively
effective and practical. Economies of scale will profit EV (electric vehicles) producing by giving
better framework, progressively effective assembling strategies, reusing alternatives and lessen
The second alternative solution that the researchers found is a method that uses an aqueous urea
solution that is used to lessen the emission of nitrogen oxide which they called the AdBlue.
AdBlue is a clear liquid solution which consists of dematerialized water (67.5%) and the raw
material automotive urea (32.5%). To use AdBlue it is injected to the exhaust emissions of a
diesel-powered engine to reduce the harmful gas which is the nitrogen oxides that causes damage
to the environment into harmless nitrogen and water vapor. The exhaust gasses mixed with the
AdBlue vapor flow into a SCR (selective reduction catalyst) where a chemical reaction takes
SCR systems in gasoline engines, however, are considerably more complex than a
traditional three-way catalytic converter. For example, it is necessary to set the AdBlue dosage
precisely to the amount of NOx produced by the engine. Too small a dose does not yield the law
mandated NOx reduction and too high a dose leads to harmful emissions of ammonia. AdBlue
Proposed Solution
As the technology advances, pollution has been one of the most significant issues that
affect a person’s health. Air pollution is a type of environmental pollution that affects the air and
is usually caused by smoke or harmful gases. According to the article in HowStuffWorks, written
by Brinson, L. entitled “How much air pollution comes from cars?” in our modern civilization,
fossil fuel combustion is the biggest contributor to air pollution. Mobile vehicles combust fossil
fuels to produce energy emits hazardous gases such as oxides of nitrogen, Carbon Monoxide,
particulates, and hydrocarbons into the air. The quantity of vehicles on our roads today are
continuously increasing and expanding, with an expected number of the greater a billion vehicles
are on the road. Trucks, shipping vessels, trains, and planes likewise combust loads of non-
renewable energy sources to work. All these transportation technologies are power-driven by
The diesel engine is the most efficient prime mover for vehicles commonly available
today. Diesel engines technology are utilizing a huge part of the world's products and generate
electricity more economically than any other device in their size range. However, the diesel fuel
is perhaps the biggest contributors of natural and environmental pollution issues around the
world. With huge expands expected in the number of vehicles and many vehicles traveled miles
a way, causing ever-increasing global emissions (California Air Resources Board, Sacramento,
USA). Notwithstanding on that fact that diesel engines are one of the most efficient mover for
vehicles other than any types of engine for such using diesel fuels, as research shows that diesel
engines are contributing to harmful air pollution, which is a particular problem in congested
areas, such as our towns and cities. Diesel engines emit nitrogen oxide and particulate matter into
the air we breathe. The particulate matter contains hundreds of tiny particulates, which easily
enter our lungs. These particulates are made of many chemical elements, harmful enough for the
World Health Organization to declare that diesel emissions contribute to the development of
cancer; cardiovascular and respiratory health effects; contamination of air, water, and soil and
Due to its efficiency, many researchers, engineers and developers have been effectively
studying and researching on ways on how to improve and develop diesel engines as well as
diesel fuels in such a way of reducing diesel fleet emissions, fuel changes, such as reduced sulfur
and aromatics content, that have resulted in immediate improvements across the entire diesel on-
and off-road fleet,and promised for more improvements with future control. In addition to the
efficiency of diesel engines, Automakers have already relied on diesel to help the industry meet
limits on carbon dioxide emissions, a contributor to global warming. But while it emits less CO2
than gasoline-fueled engines, the technology generates nitrogen oxides that help create harmful
One of the best possible solutions that the researchers considered was the Bosch Diesel
Technology. This new Bosch diesel technology was developed by a German engineer, Robert
Bosch. As stated on the article of Automotive News, written by Christoph Rauwald, Robert
Bosch Inc. believed that this new diesel technology could save diesel from its death throes. The
Bosch company claimed in late April its new exhaust system could slashed deadly nitrogen oxide
emissions from diesel engines far below legal limits taking effect in 2020 and can promotes
automakers with maintaining a strategic distance from city driving bans which take steps to
developing the innovation. The new system enhances thermal management of exhaust,
temperatures, cutting nitrogen oxide emissions to one-tenth of the lawfully allowed points of
confinement and doesn't require new equipment. The new system process keeps emissions stable
even at low temperatures. Bosch claimed, since 2017, European legislation has necessitated that
new traveler vehicle models tested by a RDE-consistent blend of urban, extra-urban, and
expressway cycles discharge close to 168 milligrams of NOx for every kilometer. As of 2020,
in Stuttgart. Many journalists, from both Germany and abroad, had the chance to drive test
vehicles furnished with portable estimating gear in substantial city traffic, under particularly
testing conditions. As the measures to reduce NOx emissions do not significantly impact
consumption, the diesel retains its comparative advantage in terms of fuel economy, CO₂
In the United States, for example, 49-state (non-California) non-urban diesel fuel sulfur
content is multiple times higher than that of national on-road diesel fuel. Significantly, altogether
decreasing this sulfur substance would minimize the secondary particulate matter (PM) build up
and permit the utilization of control advancements that have demonstrated successful in the on-
street field. The utilization of essentially zero-sulfur fuels, for example, engine modifications,
Innovation changes, such as motor adjustments, exhaust gas distribution, and exhaust gas
aftertreatment, take more time to completely implement, for the reason of slow fleet turnover.
However, they eventually result in significant emission reductions and will be continued on an
ever-widening basis.
CONCLUSION
While progress in reducing exposure to diesel exhaust has been made over the past
decade, diesel exhaust still poses significant risks to public health and the environment. It has
been identified in this study that diesel engine is the world’s most efficient prime mover for
vehicles commonly available today. It is very evident that diesel engines are being used in the
world’s generation of power and goods. With the rising rate of people having private vehicles
and the growing population of the world, diesel engine is still one of the largest contributors to
environmental pollution from happening for the past years until the present time. But most car
companies now are putting effort in making their products eco-friendly, especially the ones that
have diesel engines. This is because of the rampant occurrence of environmental destruction
happening right in front of the eyes of the whole world. With the help of our advanced
technology, it has been very helpful for different scientists to find an alternative source of power
for cars that can help address the environmental effects of diesel engines. The reductions
achieved in recent years in emissions of toxic exhaust materials were remarkable. Due to the
high complexity of the diesel engine emissions and the biological systems with which they
interact, predicting exhaust toxicity from the composition of exhaust is unlikely to be possible in
the near future, so thorough toxicological studies are still needed. Given the rapid changes in
exhaust composition due to new technology, this need will become even more important. Recent
developments in the field of in vitro toxicology, coupled with the availability of sophisticated
aerosol exposure devices, give hope that although exhaust toxicity will not be straightforward in
the near future, rapid and accurate evaluation of new technologies will be possible and will allow
legislation on exhaust emissions to be put in place which effectively protects public health.
RECOMMENDATIONS
Based on the conclusions drawn, the researchers would like to give several
recommendations that will not only address to this paper but also to future studies.
In order to improve the proposed solution, the researchers recommend to have a more
comprehensive data gathering procedure prior to the making of this research study. Likewise,
expounding of the data gathering procedures will ensure the accuracy and reliability of the data
that will be analyzed. More types of data gathering procedures, involving more respondents will
help in doing this. In the same context, it is important that the researchers consider and explore
other types of research method that could be more suitable in analyzing the variables and
achieving the desired outcome. Also, a greater amount of time duration for the development of
information. By doing so, it creates an opportunity for researchers to enhance and fully develop
the study to its greatest extent. Moreover, future researchers should investigate implications and
bridge the gaps that exist within the research study, specifically by finding a room for
researchers should give high priority to effective scheduling and time management in order to
Brinson, L.. How much air pollution comes from cars? Retrieved from HowStuffWorks:
https://auto.howstuffworks.com/air-pollution-from-cars.htm
Cackatte. T & Lloyd. A (2011) Diesel Engines: Environmental Impact and Control, Journal of
the Air & Waste Management Association, 51:6, 809-847, DOI:
10.1080/10473289.2001.10464315
California Air Resources Board, S. U. (2001, june 5). NCBI. Retrieved from PubMed.gov:
https://www.ncbi.nlm.nih.gov/pubmed/11417675
Diesel exhaust gases without any nitric oxides – is that possible? (n.d.). Retrieved from
https://m.phys.org/news/2015-10-diesel-exhaust-gases-nitric-oxides.html
Ellsmoor, J. (2019, May 21). Are Electric Vehicles Really Better For The Environment?
Retrieved from https://www.forbes.com/sites/jamesellsmoor/2019/05/20/are-electric-vehicles-
really-better-for-the-environment/#5803375876d2
Jie, J (2011) Environmental Effects of Vehicle Exhausts, Global and Local Effects – A
Comparison between Gasoline and Diesel Retrieved from
https://www.eia.gov/energyexplained/diesel-fuel/diesel-and-the-environment.php
Rauwald, C. (2018). Bosch claims a 'breakthrough' that could save diesel engines. Automotive
News.