Band Gap
Band Gap
Name: ID No.:
Determine the band gap energy of the given semiconductor using standard
procedure.
Marks Distribution
Observation 15
Graph 10
Calculation 10
________________________________________________
Result 05
Total 50
Aim:
To determine the band gap energy of the given semiconductor by studying the variation
of reverse saturation current of point contact diode with temperature.
Apparatus Required
Formula
logIs
= 0.198 x in eV
10
3
T
where Is = Saturation current (µA); T = Absolute Temperature (K)
Theory
A semiconductor has the energy band structure similar to an insulator with the forbidden
energy gap less than 2 eV. For germanium the, energy gap is 0.7 eV and that for silicon it
is 1.1 eV at 0 K. Energy of this magnitude cannot be imparted to an electron by an
applied electric field. Hence the valance band remains full and conduction band empty.
Thus these substances are nearly insulators at room temperatures.
If the temperature is increased some of the valance electrons may gain enough thermal
and move into the conduction band. Now these free electrons can move through the
crystal under the action of a small electric field. When an electron moves from the
valance band to the conduction band an electron vacancy is created in the valance band.
This is called as a Hole. When some of the electrons move from the valance into the
conduction band, equal number of holes are created in the valance band. Therefore
conduction is possible in the valance band too.
The current flowing through a diode in the reverse bias condition is
eV
I = {Is exp ( )} - 1 (1)
kT
Eg
log Is = log A - (3)
2.303 kT
Eg
log Is = log A -
2.303 8.616 10 5 T
log Is = log A -
Eg
0.198
10 T 3
(4)
As the saturation current is in μA, rewriting eqn. (4) with saturation current in amperes,
we get
log Is – 6 = log A -
0.198
10 T
Eg 3
0.198 T
E 3
log I = log A + 6 -
s 10 g
log Is = A’ -
Eg
0.198 10 T
3
where A’ = log A + 6 a constant.
A graph of log Is along y-axis versus 103/T along x-axis will be a straight line with a
negative slope.
Eg
The slope = (in K) Eg = 0.198 x Slope in eV
0.198
logIs
The slope from the graph is in K .
10
3
T
log Is
103/T (K-1)
Procedure
The given thermometer is inserted into the oven. The reverse biased PN junction circuit
and the oven is switched on. When the current reaches around 48 µA, the oven is
switched off. Thereafter, the temperature is noted for every 5 µA fall in current from 45
µA to 15 µA.A graph is drawn between 103/T on the x- axis and log Is on the y-axis. The
slope of the line is determined and substituted in the formula for band gap.
Observation:
Temperature
Current Is Temperature (t) 103 / T
T = 273 + t log Is
in µA in centigrade in K-1
in K
Calculation:
(log Is )
The slope from graph = =
(10 3 / T )
Result