INORGANIC CHEMISTRY : V.K.

JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-1
Find missing product :
1. Pb(NO3)2 + 2NaOH  ............................. + 2NaNO3

2. Mn(NO3)2 + 2NaOH  ............................. + 2NaNO3

3. BaC2O4 + CH3 COOH ............................. + H2C2O4

4. CuSO4 + 2KCN  CuCN  + ............................. + K2SO4

5. Pb(NO3)2 + 2KI ............................. + 2KNO3

6. CuSO4 + 2KI .............................+ ½ I2 + K2SO4

7. FeCl3 + Na3PO4 .............................+ 3NaCl

8. 2AgNO3 + Na2C2O4  .............................+ 2NaNO3

9. PbCl2 + H2SO4 .............................+ 2HCl

10. Ba(NO3)2 + Na2SO4 ............................. + 2NaNO3

11. CaC2O4 + 2AcOH  .............................

12. BaSO3 + H2SO4 ..................... + H2SO3 (SO2 + H2O)

13. Pb(OAc)2 + H2S ..................... + 2AcOH

14. Pb(NO3)2 + H2SO4 ..................... + 2 HNO3

15. BaCrO4 + HCl ..................... + H2Cr2O7 + H2O

16. CH3COOAg + HNO3 ..................... + CH3COOH

17. BaSO4 + dil. HCl (exess) .....................

18. Pb(CH3COO)2 + K2SO4 ..................... + 2CH3COOK

19. BaCrO4 + 2CH3COOH (excess) .....................

20. SrC2O4 + 2HCl ..................... + H2C2O4

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-2
Find missing product :

1. Mg(OH)2 + 2HCl  .............................+ 2H2O

2. BaO + 2HCl  .............................+ H2O

3. BaO + 2AcOH  .............................+ H2O

4. BaO + H2SO4 .............................+ H2O

5. Ca(OH)2 + 2HF  ............................. + H2O

6. Ca(OH)2 + CO2  ............................. + H2O

7. CaO + H2SO4  ............................. + H2O

8. Ca(OH)2 + SO2  .............................+ H2O

9. NaOH + CH3COOH  .............................+ H2O

10. Mn(OH)2 + H2SO4  .............................+ 2H2O

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 ANSWER KEY ASSIGNMENT_TOR-1
1. Pb(OH)2 2. Mn(OH)2  3. Ba(CH3COO)2 4. (CN)2 
5. PbI2  6. CuI  7. FePO4 8. Ag2C2O4 
9. PbSO4 10. BaSO4  11. No Reaction 12. BaSO4 
13. PbS 14. PbSO4 15. BaCl2 16. AgNO3
17. No reaction 18. CH3COOK 19. No Reaction. 20. SrCl2

ANSWER KEY ASSIGNMENT_TOR-2

1. MgCl2 2. BaCl2 3. Ba(OAc)2 4. BaSO4 
5. CaF2  6. CaCO3  7. CaSO4 8. CaSO3 
9. CH3COONa 10. MnSO4

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-3

Complete the following reactions occur in aqueous solution :

1. ZnCO3 + 4NaOH (excess) 

2. PbCl2 + 4NaOH (excess) 

3. AgCl + HNO3 (dil) 

4. AgBr + HNO3 (dil) 

5. AgI + HNO3(conc.) 

6. SrCrO4 + CH3COOH 

7. BaC2O4 + CH3COOH 

8. NH4Cl + NaOH 

9. NH4NO3 + KOH 

10. (NH4)2CO3 + Ba(OH)2 

11. BaSO4 + HCl 

12. CH3COONa + H2CO3 

13. 2NH4Cl + Ca(OH)2 

14. ZnS + NaOH 

15. PbS + NaOH 

ANSWER KEY
1. Na2[Zn(OH)4] + Na2CO3 2. Na2[Pb(OH)4] + 2NaCl 3. No Reaction

4. No Reaction 5. No Reaction 6. No Reaction

7. No Reaction 8. NH3+ H2O + NaCl 9. NH3+ H2O + KNO3

10. NH3+ 2H2O + BaCO3 11. No Reaction 12. No Reaction

13. 2NH3 + CaCl2 + 2H2O 14. No Reaction 15. No Reaction

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-4
Find missing product :

1. Cu(OH)2+ 4NH4OH soln. .............................+ 2OH–

2. Fe(CN)2  + 4KCN .............................

3. Fe(CN)3  + KCN .............................

4. K4[Fe(CN)6] + ZnSO4 .............................

5. K4[Fe(CN)6] + 2CuSO4  .............................

6. AgCl  + 2KCN (Excess) ......................... + KCl

7. Cd(CN)2 +2KCN .............................

8. AgI + 2Na2S2O3(Excess) .............................+ NaI

9. Cr(OH)3 + NH4OH (Excess NH3 solution) .............................

10. NiCl2 + NH4OH (Excess NH3 solution) .............................

11. Hg(NO3)2 + NH4OH (Excess NH3 solution) .............................

ANSWER KEY
1. [Cu(NH3)4]2+ 2. K4[Fe(CN)6] 3. K3[Fe(CN)6] 4. Zn2[Fe(CN)6]
5. Cu2[Fe(CN)6] 6. K[Ag(CN)2] 7. K2[Cd(CN)4] 8. Na3[Ag(S2O3)2]
9. No Dissolution 10. [Ni(NH3)6]2+ 11. HgO.HgNH2NO3

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-5
Complete & balance the following reactions :
1. Fe + 6HNO3 (conc)  Fe (NO3)3 + ...................... + 3H2O

2. 4Fe + 10 HNO3 (dil) 4Fe(NO3)2 + ...................... + 5 H2O

3. 4Fe + 10 HNO3 (very dil) 4Fe(NO3)2 + ......................+ 3H2O

4. Cu + (2 + 2) HNO3 (conc) ......................+ 2NO2 + 2H2O

5. 3Cu + HNO3 (dil) ......................+ 2NO + 4H2O

6. Hg + (2 + 2) HNO3 (conc)  Hg (NO3)2 + ......................+ 2H2O

7. 6Hg + 2HNO3 (dil) 3Hg2(NO3)2 + ......................+ 4H2O

8. Pb + HNO3 (conc) Pb (NO3)2 + ......................+ H2O

9. Pb + HNO3 (dil)  Pb(NO3)2 + ......................+ H2O

500ºC 1
10. PbO2   ......................+ O / [O].
 2 2

11. PbO2 + low H+ ......................

12.

13. Sn + HNO3 (conc.)  SnO2 + 2H2O / H4SnO4 + .................

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14. Sn + HNO3 (very dilute) Sn(NO3)2 + ............... + H2O

15. B + 3HNO3 (conc) 

R.T.
 H3BO3 + ..................

16. C + 4HNO3 (conc) 

R.T.
 .............+ 2H2O + 4NO2

17. Si + 4HNO3 (conc.) 

R.T.
 H4SiO4 / H2SiO3 + H2O / SiO2 + 2H2O + ...........

18. P4 + 20HNO3 (conc.) 

R.T.
 ...............+ 20NO2 + 4H2O

19. S8 + 48HNO3(conc.) 

R.T.
 ................. + 48NO2 + 16H2O

20. X2( = Cl2, Br2, I2) + 10HNO3 (conc) 

R.T.
 ............... + 10NO2 + 4H2O

21. RT
As + 5HNO3 (conc)   H3AsO4 + ............... + H2O
Arsenic acid

22. RT
Sb + 5HNO3 (conc)   ................. + 5NO2 + H2O

ANSWER KEY
1. NO2 2. N2O 3. NH4NO3 4. Cu (NO3)2

5. Cu(NO3)2 6. NO2 7. NO 8. NO2

9. NO 10. PbO 11. No reaction 12. NO2, PbO2

13. NO2 14. NH4NO3 15. NO2 16. CO2

17. 4NO2 18. 4H3PO4 19. 8H2SO4 20. 2HXO3

21. 5NO2 22. H3SbO4

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-6
Write the balanced equation for the following reactions

(i) 3HXO  HXO3 + ..................

(ii) 3HClO3   HClO4 + ............. + H2O

(iii) 4Na2SO3   ............... + Na2S
Sodium Sulphide

(iv) NaH2PO3   Na3PO4 + ................

(v) NaClO  ............... + NaCl


(vi) H4SiO4  ............. + 2H2O
(non-oxidizing acid)

 Warm 7
(vii) 2HClO4   H2O + ..............   .............. + O2
2
(oxidising acid)


(viii) 2H3BO3 (conc.)   ............ + 3H2O
(non oxidixing acid)

(ix)

(x)


(xi) 4Na2S2O3 3Na2SO4 +..............
Sodium Redox Reaction
Thiosulphate

ANSWER KEY
(i) 2HX (ii) 2ClO2 (iii) 3Na2SO4 (iv)PH3 (v) NaClO3
(vi) SiO2 (stable oxide) (vii)Cl2O7, Cl2 (viii) B2O3 (stable oxide)

(ix) Mn2+ (aq), MnO2 (x) (less stable oxide) (xi) Na2S5

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-7
Predict the products of following redox reactions :

(i) MnO4– (aq) Red.Agt./H+ ...............

(ii) MnO4– (aq) Red. Agt./Strongly Basic medium ...............

– Red. Agt./neutral or weakly basic medium

(iii) MnO4 (aq) ...............

(iv) Cr2O72– (aq) Red. Agt. / acidic medium .................

Red. Agt. (any)

(v) HNO3 (conc) ..................

+3 Red. Agt.
(vi) HNO2 (better oxd. agent ..................
weaker red. agent)

(vii) O 3 Red. Agt.

........... + [O]

Red. Agt.
(viii) H2O2 (Better Oxd. Agt. and Weaker Red. Agt.) ...............

+6 Red. Agt. Red. Agt. [H]

(ix) Conc. H 2SO 4(Mild Oxd. Agt.) S
St. Red. Agt.

Red. Agt. Red. Agt.

(x) HXOn=1, 2,3,4(St. Oxd. Agt.)
(X2=Cl2,Br2,I2)

ANSWER KEY
(i) Mn2+ (aq) (ii) MnO42– (green colour) (iii) MnO4 2H2O / Mn(OH)4 (Brown) (iv) Cr3+ (aq)
(Hydrated pyrolusite)

+4 –2
+2
(v) (vi) NO (vii) O2 (viii) H2O (ix) SO2 , H2S (x) X2 and HX / X¯(aq)

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-8
Predict product of following reaction
Oxd. Agt.
(i) s-block metals ...............

Oxd. Agt.
(ii) NH3 ..............

Oxd. Agt.
(iii) N2H4 ............

Oxd. Agt.
(iv) HNO2 ................

+3
Oxd. Agt.
(v) HPO32– (aq) ..............

+1 Oxd. Agt.
(vi) H 2PO 2– (aq) ..............

Oxd. Agt.
(vii) AsO33–(aq) ...............

Oxd. Agt.
(viii) SO2 .................

Oxd. Agt.
(ix) SO32– (aq) ...............

Oxd. Agt. Oxd. Agt.

(x) H2S .............. H2SO4

Oxd. Agt. Oxd. Agt. +5

(xi) HX (X=Cl, Br, I) ............ HXO3

Strong Oxd. Agt. ............

(xii) X2

Strong Oxd. Agt. 2–

2– – .......... + SO4 (aq)
(Cr2O7 , MnO4 , Cl2, Br2) (turbidity)
2– Oxd. Agt.
(xiii) S2O3 (aq)
(S=+6, S=–2) Weak Oxd. Agt./ Mild Oxd. Agt.
(better Red. Agt. but ................
3+ 2+
very weak Oxd. Agt.) (I2, Fe , Cu (aq))

10% H2O2 (oxidising agent)/OH¯

3+
Cr (aq) 2–
CrO4 (aq)
(xiv) (Reducing agent)
+
3% H2O2/H
(reducing agent)
Redox .....................
Rxn.

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 Oxd. Agt. Cl2/O3
................
Strongly Basic Medm.

2+ Strong Oxd. Agt. (PbO2, Pb3O4, NaBiO3) +7

–
(xv) Mn (aq) +
MnO4 (aq)
H / acidic medium

Oxd. Agt. ................ Oxd. Agt. / H+

Weak Basic Medium Acidic Medium
(by NH3 gas)

[H] (Strong Red. Agt.) .............. NaOH

(xvi) SO2 Na2S
(Zn + NaOH soln.)

2– [H] (Strong Red. Agt.)

(xvii) SO3 .........
(Al + dil. HCl)

dil HCl
(xviii) Na2S (salt decomposition rxn)

[H] (Strong Red. Agt.) H2SO4

(xix) NaNO3 .............................. (NH4)2SO4
Zn + H2SO4 (dil)

[H]/Strong Red. Agt.

(xx) NH4NO x=2,3 NH3 (Basic gas turns red litmus blue)
(Zn+ KOH)

Strong alkali solution (NaOH / KOH soln.)

Non-redox salt decomposition rxn.

CuSO4 Sol. ........................

testing of Glass rod dipped ........................

(xxi) NH3gas
NH3 gas in dil HCl
Nesselar's reagent ........................
K2 [HgI4]+OH¯

ANSWER KEY
M+ (alkali
(i) metal cation) /M2+ (alkali earth metal cation)
(ii) N2
(iii) N2
(iv) HNO3 (v) H3PO4 (vi) H3PO4 (vii) AsO43– (aq)
(viii) H2SO4 (ix) SO42– (aq) (x) S (xi) X2
+5 +6
(xii) HXO3 (xiii) S, S4O62– (aq) (xiv) O O Blue color
Cr
O O (unstable in aq-sol)
O
+6 +4
(xv) MnO42–(green) MnO2 (Brown) (xvi) H2S (acidic gas with rotten egg smell)

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 (xvii) H2S (acidic gas turns blue litmus red) (xviii) H2S (acidic gas with rotten egg smell)
–3
(xix) NH3 (Basic gas with pungent smell) (xx) NH3 (Basic gas with pungent smell)
2+
(xxi) [Cu(NH3)4] , NH4Cl (White dense fumes), HgO. Hg(NH2) I (Basic amido-mercury iodide)
deep blue solution (Brown ppt)

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 INORGANIC CHEMISTRY : V.K. JAISWAL(VKJ SIR)

ASSIGNMENT_TOR-9
More than One correct :
1. On heating Pb(NO3)2 gives :
(A) PbO (B) NO2 (C) O2 (D) NO

2. Nitrogen gas is liberated by thermal decomposition of :

(A) NH4NO2 (B) NaN3 (C) (NH4)2Cr2O7 (D) All

3. Among the following compounds, which on heating do not produce N2 ?

(A) (NH4)2Cr2O7 (B) NH4Cl + NaNO2 (C) NH4Cl + Ca(OH)2 (D) Ba(N3)2

Paragraph (4 to 6) :
Most metal oxides are thermally stable at temperature upto 1000°C but the oxide of metals below hydrogen
in the electrochemical series decompose fairly easily. Thus HgO and Ag2O decompose on heating.

4. Which of the following salt does not give NO2 gas on heating ?
(A) Pb(NO3)2 (B) Zn(NO3)2 (C) AgNO3 (D) KNO3

5. Which of the following compound cannot be thermally decomposed even at high temperature ?
(A) CsHCO3 (B) Rb2CO3 (C) Li2CO3 (D) (NH4)2CO3

6. Correct code for following thermal decomposition reaction(s) evolving gas having equal number of -and
-bonds is :

 
(i) BeCO3   (ii) ZnSO4 
T  800C

(iii) FeSO4 

300 C 
(iv) (NH4)2Cr2O7 
 

(A) (i), (ii) (B) (i), (iii), (iv) (C) (i), (ii), (iii) (D) All of these

Subjective :
7. How many following Ammonium salts will evolve N2 gas on heating ?
(NH4)2CO3, (NH4)2Cr2O7, NH4NO2, NH4ClO4, NH4Cl , (NH4)2S, (NH4)2C2O4

8. How many following Ammonium salts will evolve NH3 gas on heating ?
(NH4)2CO3, (NH3)2Cr2O7, CH3COONH4, NH4ClO4, NH4Cl, (NH4)2S, (NH4)2C2O4, (NH4)2SO4, NH4NO3

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Match the column :
9. Match the column :

Column-I Column-II
(Reactions) (Characteristics of any one product)

(A) 
(NH4)2Cr2O7  (P) Amphoteric species


(B) 
FeSO4  (Q) Basic species


(C) 
Pb(NO3)2  (R) Non-polar gas


NaOH
(D) P4   (S) Polar acidic gas

(T) Coloured residue

ANSWER KEY
1. ABC 2. ABCD 3. C 4. D
5. B 6. C 7. 3 8. 6
9. A-PRT; B-QRST; C-PRST; D-Q
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