Student's Solution Copy

11th_ Batch (P1 P3 P5 P7) Eng_ [Main Pattern]

11th JEE (M) - Phase 1
KOTA

Date: 03-Jul-2022 Duration: 3 Hours Max Marks: 300

Maths - Section A

1. Answer: A 2. Answer: B
Sol: Sol:
P = 4 sin 17 . sin 43. sin 77
2 2 2 2
cos θcos θ sin θ.sin θ
2
+ 2
sin θ cos θ

= 4 sin 17 sin (60 − 17). sin (60 + 6

= =
6
sin θ+cos θ 1

17) sin
2
θcos θ
2
sin
2
θcos θ
2
− 3

= 4. 1

4
sin (17 × 3) = sin 51° =  k
4
2
−3

Therefore, the correct answer is (A) Therefore, the correct answer is

(B).
3. Answer: B 4. Answer: C
Sol: Sol:
T6 = sin6θ + cos6θ = 1 – 3sin2θ
2 2
sin x−2 cos x+1
= 4
cos2θ
2

2
sin x+2 cos x−1

sin x – 2cos2x + 1
2
T4 =
sin4θ + cos4θ = 1 – 2sin2θ
⇒

= 4sin2x + 8cos2x – 4

cos2θ
= 10cos2x + 3sin2x –5
= 0
2
2x) = 0 T2 =
sin2θ + cos2θ = 1
⇒ 10 + 3 tan x – 5(1 + tan T6 −T2
=
 = 1−3 sin
2
θcos θ−1
2

2tan2x = 5
T6 −T4
1−3 sin
2 2
θcos θ−(1−2 sin
2 2
θcos θ)

∴tan x = 

2 5
2 2

 =3
2 −3 sin θcos θ
2 2
− sin θcos θ

5. Answer: C 6. Answer: B
Sol:

 =
2 2 sin(57°+33°) sin(57−33°)
cos 33°−cos 57°

69°+21° 69°−21°
sin 21°−cos 21°
−2 sin sin
2 2

= sin 90°×sin 24°

−2 sin 45° sin 24°

 = −2×
1
1
 = −
1

√2
√2
 Sol:
Given expression
sin 300° tan 330° sec 420°

tan 135° sin 210° sec 315°

sin(360°−60°).tan(360°−30°).sec(360°+60°)
=
tan(180°−45°).sin(180°+30°).sec(360°−45°)

(− sin 60°).(− tan 30°).sec 60°

=
(− tan 45°).(− sin 30°).sec(45°)

= sin 60°.tan 30°.sec 30°

tan 45°.sin 30°.sec 45°

√3 1
. .2
2 √3

= 1
= √2
1. . √2
2

Therefore, the correct answer is (C)

7. Answer: C 8. Answer: C
Sol: Sol:
If, A + B = 45° tan ((θ°) + (30 − θ)°) = tan30°
tan(A + B) = 1 tanθ°+tan(30−θ)°
1
⇒ =
1−(tanθ°)(tan(30−θ)°) √3
tanA+tanB
∵ tan(A + B)=
1−tanAtanB
⇒√3 (tanθ° + tan(30 − θ)°)=

⇒ tan  A + tan  B =1 − tan  A  tan  B 1 − (tanθ°) (tan(30 − θ)°)

⇒ (1 + tanA)(1 + tanB) = 2
⇒(√3 + tanθ°) (√3 + tan(30 − θ)°)

LHS = 4

= [(1 + tan 1°) (1 + tan 44°)] 14

=4 (√3 + tan 15°)
[(1 + tan 2°) (1 + tan 43°)]

… [(1 + tan 45°)]

14 29
π
[  for   each  (1 + tanθ) [1 + tan ( − θ) = 2]] =4 (√3 + (2 − √3))= 2
4

22
= 2 (1 + 1)

23
= 2

λ
= 2

then, λ = 23 .
Hence the sum of digits of λ is 2 + 3
= 5

9. Answer: D 10. Answer: B

Sol:
sin 78° – sin 66° – sin 42° + sin 6°
⇒ (sin 78° – sin 42°) – (sin 66° –

sin 6°)
⇒ 2 cos
60° sin 18° – 2 cos 36° sin
30°

18° – cos 36°
⇒ sin

⇒ – 2 cos 36° sin 18°

⇒ 
−2 cos 36° sin 18° cos 18° −2 cos 36° sin 36°
⇒

cos 18° 2 cos 18°

   =−
sin 72° cos 18° 1
⇒   − = −
2 cos 18° 2 cos 18 2
 Sol:
Given sin6θ + cos6θ – 1 = λsin2θ
cos2θ
2 3 + (cos2θ)3 – 1 = λsin2
⇒     (sin θ)

θ cos θ
2
2 2 4 4
⇒     (sin θ+ cos θ)(sin θ + cos θ –

sin2θcos2θ) –1
           = λ sin2θcos2θ
2
⇒     [(sin θ + cos θ)
2 2 – 3sin2θcos2θ

]–1
          = λsin2θcos2θ
2 2
⇒     [1 – 3sin θ cos θ] – 1 = λ sin
2

θ cos θ
2
2 2 2 2
⇒     – 3sin θcos θ = λsin θcos θ  

           ∴ λ = – 3
11. Answer: B 12. Answer: B
Sol: Sol:
cos 3θ

cosθ
= 4 cos
2
θ − 3 = 2(1 + cos 2θ) − 3 sinx + sin2x = 1
2
⇒ sinx = 1 – sin x
= 2 cos 2θ − 1 = 2 cos(α − β) − 1 2
⇒ sinx = cos x

cos8x + 2cos6x + cos4x = sin4x +

Now, (cos 2
α + sin
2
α) +
2sin3x + sin2x
(cos
2
β + sin
2
β) + 2 cos(α − β) 2 2 2
⇒ sin x(sin x + sinx) + sinx(sin x
2 2
= a + b
+ sinx) = 1
2 2
⇒ 2 cos(α − β )= a + b − 2

cos 3θ 2 2
⇒    = a + b − 3
cosθ

13. Answer: B 14. Answer: C

Sol: Sol:
cosx+sinx =   =   = 
1 1 1+tanx a+1

2 π tanx−1 a−1
tan (x− )
4

squaring both sides , we get

2
2 2 1
⇒ cos x + sin x + 2 sin x. cos x = ( )
2

1
⇒ 1 + sin 2x =
4

          (⇒
−3 π
⇒ sin 2x = < x < π)
4 2

2 tan x −3
⇒ 2
=
1+tan x 4

⇒ 8 tanx = -3-3 tan2x

⇒ 3 tan2x+8tanx+3 = 0
−8±√64−4×3×3
⇒ tan x =
2×3

−8±√64−36
⇒ tan x =
6

−(4+√7)

⇒ tan x =
3
,

and  tan x =
−4+√7

15. Answer: C 16. Answer: A

 Sol: Sol:
cos273° + cos247° – sin243° + 2{
(sin 1°+sin 89°)+(sin 2°+sin 88°)+
}

sin2107°
                   ……+(sin 44°+sin 46°)+sin 45°

= cos273° + cos247° – sin2(90°–

cos 1°+cos 2°+cos 3°+
2( )+1
                         ……+cos 44°

47°) + sin2(180° – 73°)

= cos273° + cos247° – cos247° + 2{2 sin 45°(
cos 44°+cos 43°+
)+sin 45°}

sin273° = 1
                       ……+cos 1°
=
cos 1°+cos 2°+cos 3°+
2( )+1
                        …….+ cos 44°

cos 1°+cos 2°+

2 sin 45°{2( )+1}
               ……..+cos 44°
=
cos 1°+cos 2°+
2( )+1
              …….+ cos 44°

1
= 2 ⋅
√2

= √2

17. Answer: A 18. Answer: A

Sol: Sol:
cos1º cos2º     .... cos179º ∵ cos θ cos(60° − θ ) cos (60° + θ
=  cos1ºcos2º... cos 90º ...
cos ) =   cos3 θ
1

4
179º = 0
( cos 90°
= 0)  ∴  cos 12°.cos 48° cos 72°.cos24°
cos36° cos84°
    =    cos 36° ×   cos 72°
1

4
1

    =  16
1
 cos 36° cos 72°

   =    {using formula

2 sin 36° cos 36° cos 72°

32 sin 36°

2sinx.cosx = sin2x}
∘ ∘
2 sin 72 cos 72
=   ∘
64 sin 36

∘ ∘
sin 144 sin 36 1
=   ∘ = ∘ =
64 sin 36 64 sin 36 64

Therefore, the correct answer is

(A).
19. Answer: C 20. Answer: B
Sol: Sol:
sec 11° sec19° – 2 cot71° º
cos 20 +8 . sin 10 º sin 50º sin 70º

=  –
80º
2
1 2 sin 19° sin

cos 11° cos 19° cos 19°

= º º sin(60º−10º) sin º º
1−2 sin 19° cos 11°

=
cos 20 + 8 sin 10 (60 +10 )

cos 11° cos 19°

sin
2
80 º
=
1−(sin 30°+sin 8°)

cos 11° cos 19°

º º
=
cos 20 + (8 sin 30 )/4

=  =
1−(1/2)−sin 8° sin 30°−sin 8°
cos
2
10 º
= 2tan11°

cos 11° cos 19° cos 11° cos 19°

= 2 sin 11°.cos 19°

º 2
º
= = =2
cos 11° cos 19° cos 20 +1 2 cos 10

cos
2
10 º cos
2
10º
 Maths - Section B

1. Answer: 3 2. Answer: 4
Sol: Sol:
cosA =  3

4
tan 9º – tan27º – tan63º + tan81º
= (tan 9º + tan 81º) – (tan 27º +
16 cos2 A

2
 − 32 sin  sin  A

2
5A

2 tan 63º)
= (tan 9º + cot9º) – (tan27º +
= (cos 2A − cos 3A)
16(1+cos A)

2
− 16 cot27º)
º 2
º º º 2

=  –   =  –
2 2
tan 9 +1 tan 27 +1 sec 9 sec 27

2
= − 16 {(2cos A − 1) − (4
16(1+cos A)
tan 9 º tan 27 º tan 9 º tan 27 º
=  –
2 1 1

cos3 A − 3 cosA)} sin 9 º cos 9º sin 27 º cos 27º

=  –  =
2(sin 54°–sin 18°)
2 2

= 8 (1 + 3

4
)− sin 18 º sin 54 º sin 18°×sin 54°

=  =2×2=4
2(2 cos 36° sin 18°)
9 27 3
16 {2 × − 1 − 4 × + 3 × }= 3 sin 18° sin 36°
16 64 4

Therefore, the correct answer is (C)

3. Answer: 1 4. Answer: 0
Sol: Sol:
(2 sin 50°.sin 40°) sin 10°
 = 
(cos 10°−cos 90°) sin 10°
sinα sin β – cosα cos β + 1 = 0
sin 10°.cos 10° sin 10°.cos 10°

⇒      – cos (α + β) + 1 = 0

=1

⇒      cos (α + β) = 1 ⇒   sin (α +

β) = 0

then  
1 + cot α tan β = 1 +
cosαsinβ

sinαcosβ

=  =  =0
sinαcosβ+cosαsinβ sin(α+β)

sinαcosβ sinα cosβ

5. Answer: 4 6. Answer: 4
Sol: Sol:
1−sin 2θ+cos 2θ
2 2 cosθ 1
f (θ) = 2 cos θ + cosθ + 1 = 2 (cos θ + + )
2 cos 2θ
2 2

2 2 2
(cosθ−sinθ) +(cos θ−sin θ)
= 2(cosθ−sinθ)(cosθ+sinθ) 2 {(cosθ +
1
)
2
+
7
} Given expression
4 16

= cosθ is maximum when cosθ = 1and

cosθ+sinθ
minimum when cosθ = − 1

= 1

1+tanθ 5
2
32
7
⇒ M = 2 (( ) + ) = 2( ) = 4
4 16 16

f(11°).f(34°) = (1+tan 11 )
1
∘
×
1

(1+tan 34 )
∘

and m = 2 ( 16
7
) =
7

= 1
∘ ×
1
∘ ∘

Hence, 
(1+tan 11 ) (1+tan(45 −11 )) 7M
= 4
8m

= 1

(1+tan 11 )
∘
×
1

1−tan 11
∘

(1+ ∘
)
1+tan 11

= 1 (1+tan 11 ) 1
∘ × =
(1+tan 11 ) 2 2

7. Answer: 1 8. Answer: 2
 Sol: Sol:
The given expression is If  sinθ 1 sinθ2 −cosθ1 cosθ2 = 1

3 [sin
4
(
3π

2
− α) + sin
4
(3π + α)] – ⇒cos (θ1 + θ2 )=−1

6 π 6
2 [sin ( + α) + sin (5π − α)]
2 ⇒ θ1 + θ2 = π   θ1 + θ2 ∈ (0,  2π)

=  3 [cos
4
α + sin
4
α] – 2 [cos 6
α + sin
6
α]
⇒
θ1 +θ2
=
π

4 4

–
2 2
2 2 θ2 π θ1
=  3 [(cos α) + (sin α) ] ⇒ = −
4 4 4

3 3
2 2
2 [(sin α) + (cos α) ] θ1 π θ1
∴ (1 + tan ) [1 + tan ( − )]
4 4 4

2
2 2 2 2
=  3 [(s in α + cos α) − 2  sin α  cos α]
θ1 2
∴ (1 + tan )( θ
) = 2
4 1

−2 (sin [ 2
α + cos
2
α)
1+tan
4

(sin
4
α + cos
4
α − sin
2
α cos
2
α) ]

Using formula  
a
4
+ b
4
= (a
2 2
+ b ) − 2a b  
2 2
 and 
3 3
6 6 2 2
a + b =(a ) + (b )
2 2 4 4 2 2
= (a + b ) (a + b − a b )

2 2
= 3 [1 − 2  sin  α  cos  α]

2
2 2
(sin α + cos α)
2 (1) ( )
2 2 2 2
          − 2  sin  α  cos α − sin  α  cos α

= 3 − 6  sin
2
 α  cos
2
 α –
2 2
2 (1) (1 − 3  sin  α  cos α)

= 3 − 6  sin
2
 α  cos
2
 α –
2 + 6  sin
2
 α  cos
2
α –
= 1

9. Answer: 8 10. Answer: 4

Sol: Sol:
We have, x = (tan 26° tan 86° tan 34°)
cos 39° cos 78°
2

260° =
sin 39° cos 39°

xsin45°cos
2
tan 60° cosec 30°
2

{using
sec 45° cot 30°
2

(√3) 2

⇒x.
1
.
1
 = 2
tanx ⋅ tan (60° − x) ⋅ tan (60° + x) = tan 3x}

√2 4
√2(√3)
°
2 tan 78° cos 78° 2 tan 78
= = 2
⇒
x
=
6
  2 sin 39° cos 39° tan 78
°

4 √2 3 √2

⇒   x = 6
× 4√2       ∴ x=8 ycos 81° =
√2
(cos 36° − sin 36°)
3 √2 √2

= √2 sin (45° − 36°)

= √2 sin 9° = √2 cos 81°

⇒ y = √2

⇒ x + y
2
= 4 Ans.
 Physics - Section A

1. Answer: A 2. Answer: B
Sol: Sol:
2
tanθ =
3

θ = tan
−1
(
2

3
)  

→ → →
Here  F 1 + F 2 + F 3 = 0

→ → →
F 1 + F 2 =– F 3

→
Since  F net  = 0 (equilibrium)

Both statements correct

3. Answer: B 4. Answer: A
Sol: Sol:

→ →
Angle between  and , θ = 60
→ o

F x  
= (−
5

2
√3 + 10 +
5

√2
) î
A B

→ → →
→ Angle between  A  and  A − B
F x = 9. 25 î
Bsinθ
tan  β =
→ A−Bcosθ

F y  
= (−
35
+
25

2
+ 10√3) ĵ
√2 3
B√
2

→ 1

= 5 ĵ
A−B× 2
2
F y

√3B
tanα =
2A−B

5. Answer: A 6. Answer: A
Sol: Sol:
→ a a → → → →∣
∣
r g = î + k̂
2 2 A. B = A × B∣
∣
∣ ∣
→ a a
r H = ĵ + k̂
2 2
ABcos θ = ABsin θ ⇒ θ = 45 º
→ → 1 → →∣
r H– r g = a( ĵ – î ) ∣
2 ∣ A − B ∣ = √A + B − 2 ABcos 45
2 2
º
∣ ∣

therefore the correct option is (A).

= √A + B − √2 AB
2 2

7. Answer: B 8. Answer: D
 Sol: Sol:
→ → → → → →
A = P + Q (B × A)  is perpendicular to  A
→ → → → → → → → →
B = P– Q          P ⊥ Q  and  B  so ( B × A) A .  = 0
→ →
∣ ∣ ∣ ∣ 2 2
∣ A ∣ = ∣ B ∣ = √P + Q
∣ ∣ ∣ ∣

→ →
∣ ∣ 2 2
∣ A + B ∣ = √2 (P + Q ) (1 + cosθ)
∣ ∣

→ →
∣ ∣
For ∣ A 2 2
+ B ∣ = √3 (P + Q )
∣ ∣

θ1 = 60°

→ →∣
∣
For  ∣ A + B ∣ = √2 (P2 + Q2 )
∣ ∣

θ2 = 90°

9. Answer: D 10. Answer: A

Sol: Sol:
x → →
y  =  e l  nx → →
* Projection of  a on  b  =  a . b

differentiate w.r.tx
(3 î +4 ĵ )

dy
= (2 î + 3 ĵ + 6k̂).
x d d x 5
= e (ln x) + ln x (e )
dx dx dx

x (6+12)
e x 18
+ e ln x = =
x 5 5

x 1 → → → →
* Projection of  b  on  a  =  b . a
e [ + ln x]
x

ˆ
(2 î +3 ĵ +6k)

= (3 î + 4 ĵ ) .
√4+9+36

(6+12) 18
= =
7 7

18
( )
5
7
=
18 5
( )
7

11. Answer: B 12. Answer: B

Sol: Sol:
y = log(x
2
+ 1) y  =   tan  [log  (x )]
2
 differentiate w.r.t
dy 1 2x
x
= 2
. 2x = 2
dx (x +1) (x +1)
dy d 2
= [tan {log (x )}]
dx dx

dy 2 d
2 2
= sec (logx ). [log (x )]
dx dx

dy 2 1 d
2 2
= sec (logx ). 2
. (x ) 
dx x dx

dy 2 1
2
= sec (logx ). 2
. 2x
dx x

dy 2 2
2
= sec (logx )
dx x

13. Answer: A 14. Answer: A

 Sol: Sol:
d 2 → →∣ → →
[x .   sin  x.   log  x] ∣
dx ∣ A × B ∣ = √3 A . B
∣ ∣
d 2 2 d
[sin  x. log  x]  (x ) + [x .   log  x] (sinx)
dx dx

2 d ABsinθ = √3ABcosθ
+[x . sinx] (log  x)
dx

tanθ = √3
2
⇒ 2x.   sinx.   logx   + x .   logx. cosx
1 o
2
+x .   sinx. ( ) θ = 60
x

→ →∣
2 ∣ o
⇒ 2x.   sinx.   logx   + x . logx.   cosx   ∣ A + B ∣ = √A2 + B2 + 2 ABcos 60
+ x. sinx ∣ ∣

= √A2 + B2 + AB

→ →∣
∣ 2 2
1/2
= ∣ A + B ∣ (A + B + AB)
∣ ∣

15. Answer: A 16. Answer: A

Sol: Sol:
x2 cos x ∣ î ĵ k̂ ∣
→ → ∣
∣

= 2x cos x − x2 sin x
ω × r = ∣
1 –2 3 ∣

∣ ∣
∣1 1 1 ∣
Therefore, the correct answer is (A)
= î (– 2– 3)– ĵ (1– 3) + k̂(1 + 2)

=– 5 î + 2 ĵ + 3k̂

 
17. Answer: A 18. Answer: C
Sol: Sol:
differentiation of constant value will Since, the third vector has a
be zero. component which lies outside the
plane of the remaining two, hence
this extra component can not be
cancelled by any other component
during addition, so sum can never
be zero.
19. Answer: C 20. Answer: A
Sol: Sol:
→ →∣ → →
∣
(2 î + 3 ĵ + 8k̂) . (4 ĵ − 4 î + αk̂) = 0 ∣ A × B ∣ = √3 A . B
∣ ∣

-8+12+8α=0 ABsinθ = √3ABcosθ

4+8α=0 tanθ = √3

1 o
α = − θ = 60
2
 Physics - Section B

1. Answer: 15 2. Answer: 0
Sol: Sol:

Let  A
→ →
= 2 î + 2 ĵ ,   B = î + √3  ĵ
The sin 60  has a constant value.
∘

The derivative of a constant value

→ →
is zero.
θ  be the angle between A  &  B
∘
d(sin 60 )
⇀⇀
A B 2+2√3 = 0
dt
cos  θ = =
|A||B| √8.2

√3+1
 
cos  θ =
2√2

o
 θ = 15

3. Answer: 1 4. Answer: 1
Sol: Sol:
P + Q = 23 ∣â − b̂∣ = √a2 + b2 − 2 ab   cos  θ
∣ ∣

P − Q = 7

∴   2P = 30

⇒   P = 15

∴   Q = 23 − 15 = 8

→ →
If  p ⊥ Q , R = √P2 + Q2 o
θ = 60 ⇒ ∣ ∣
∣â − b̂∣ = 1
= √225 + 64 = 17

5. Answer: 3 6. Answer: 2
Sol: Sol:
Direction of    A and B will be parallel if 
→ →
ˆ A  ×  B  =  0
A×B î − ĵ +k
P = v̂1 = ± → →
= ±
∣ ∣ √3
∣A×B∣ ∣ î
∣ ∣ ĵ k̂ ∣
∣
∣

Now  A  ×  B  =   ∣
2 2 p ∣

Direction of Q =  ∣ ∣
→ →
∣1 1 1 ∣
A×C 2k̂
v̂2 = ± → →∣
= ± = ±k̂
∣ 2
∣A×C∣
∣ ∣
= i(2 − p) + j(p − 2) + k(2 − 2)

Angle between v̂  and v̂ 1 2

= i(2 − p) + j(p − 2)

v̂ 1 .v̂ 2
=
±1/√3
= ±
1 For A  ×  B  =  0, we must have each
|v̂ 1 ||v̂ 2 | (1)(1) √3
component to be zero. That is 
0  =  2  −  p , and
⇒ x=3
0  =  p  −  2  (both conditions similar).
Thus p  =  2.

7. Answer: 1 8. Answer: 3
 Sol: Sol:
Two vectors are perpendicular if From the informatoin given above,
their dot product is zero. the resultant for squared for all the
→ →
tree forces can be given as
Given, A  and B  are two forces.
R
2
= P
2
+ Q
2
+ 2P Qcosθ       ...
The sum of these forces are,  (1)
−
→ → →
F1 = A + B
(2R)
2
= P
2
+ (2Q)
2
+ 4P Qcosθ      
The difference between these two ...(2)
−
→ → →
forces are, F 2 = A − B (2R)
2
= P
2
+ (Q)
2
− 2P Qcosθ

        ...(3)
Since, the sum of the two forces is
perpendicular to their differences ⇒ P
2 2 2
  :  Q   :  R   =  2 : 3 : 2 . 
as given,
−
→ −
→ → → → →
F1 . F2 = ( A + B ). ( A − B ) = 0

→ → → →
2 2
⇒ A − A. B + B. A − B = 0 
→ →
2
(Since,   A . A = A )

→ → → →
2 2
⇒ A − B = 0  (Since,   A . B = B . A )

2 2
⇒ A = B

∣→∣ ∣→∣
⇒ ∣A∣ = ∣B∣
∣ ∣ ∣ ∣

According to the question, 

→ →
∣ ∣ ∣ ∣
∣ A ∣ = k∣ B ∣
∣ ∣ ∣ ∣

∴ k = 1 (Answer)

9. Answer: 2 10. Answer: 5

Sol:
Given that,
y  =   sin  5x

Also, it is given that:

y  =   sin  u,   u  =  5x

Then, differentiation gives us:

dy du
= cos  u,    = 5
du dx

By applying chain rule, we can

write the following expressions:
dy dy du
= .
dx du dx

dy
= 5  cos  u  =  5  cos  5x.  
dx

To find the value of n,

5  cos  5x  =  n  cos  5x  
⇒ n = 5.
Sol:
Given,
→
Vector  P  makes angles α, β, and γ
with the X, Y, and Z-
axis respectively.
→
The component of the vector  P
along the x-axis = cosα
→
The component of the vector  P
 along the y-axis = cosβ
→
The component of the vector  P
 along the z-axis = cosγ

According to the question,

2 2 2
cos α + cos β + cos γ = 1

2 2 2
1 − sin α + 1 − sin β + 1 − sin γ = 1

2 2 2
3 − (sin α + sin β + sin γ) = 1

2 2 2
sin α + sin β + sin γ = 3 − 1

2 2 2
sin α + sin β + sin γ = 2
 Chemistry - Section A

1. Answer: B 2. Answer: C
Sol: Sol:
Vapour density (A) = 2 × Vapour Given; wt. of Al = 54 gm
density (B)                 ...(1)
At wt. = 27
Using vapour density (VD) = given wt.
Molar  mass mole =
at wt.
2

54

Using in (1) =
27
= 2 mol

(MM)
A
mole of Al = mole of Mg
 =
(VD)
A 2

(MM)
(VD) B
B given wt.
2
2 =
At wt.

 =
VDA (MM)
A

VDB (MM)
B
∵  At wt. of Mg = 24

Using (1)
given wt.
2 =
24

 =
2×(VD) (MM)
24 × 2 = wt.
B A

(VD) M
B

(MM)A = 2M wt. = 48 gm

3. Answer: A 4. Answer: A
Sol: Sol:
mass of 12
6
C = 12 gm For the following reaction,

mole = mass

mol. mass
= no. of atom
2C57H110O6 + 163O2 ➝ 114CO2 +
NA

110H2O
No of 12
C atom = 12
× NA = NA
6 12
Mass of C57H110O6 = 445g
1 carbon C contain 6 each
12
6
Molar mass of C57H110O6 = 890
electrons , protons and neutrons.
Moles of C57H110O6 = mass
=
So, Total No. of e–, P+ and n° = 18
molar mass
445
= 0.5 mole
NA = 1.084 × 1025 890

So, 2 moles of C57H110O6 produce

110 moles of H2O
0.5 mole of C57H110O6 produce 110

× 0.5 = 55

Mass of water = moles of H2O ×

molar mass of water
= 55

2
× 18 = 495g

5. Answer: C 6. Answer: A
Sol:
CaCO3 ( s) → CaO(s) + CO2 ( g)

5
10 ×95
 mass  = × 56 gm
100×100

= 53. 2  kg
 Sol:
​Given, sample of ferric sulphate (
Fe (SO ) ) contains 7.2 moles of O-
2 4 3

atoms.
In, Fe (SO ) , number of O-atoms
2 4
3

= 12 and, number of S-atoms = 3.

So, 12 oxygen atom = 7.2 mole,
then 1 oxygen atom = 
= 0. 6  mole.
7.2

12

So, 3 atom of Sulphur = 0. 6 × 3 =

1.8 mole of oxygen = 1. 8N  no. of A

atoms. (Since, no. of atoms =

mole ×N ). A

Therefore, option - (1) 1. 8N is the A

correct ans.
7. Answer: D 8. Answer: C
Sol: Sol:
Given, 25% of Z  and, 75% of Z .
65 67
Volume of vapour = 112 ml
Now, average atomic mass of Z = moles of vapour =
given   volume(ml)

% abundance of Z  + %
22400(ml)
65

abundance of Z . 67
= 112
= 5 × 10
−3

22400

So, average atomic mass of Z =  i.e. 5 × 10−3 moles weight 0.39g

(25% × 65) + (75% × 67)

1 mole weight 0.39

= 78 g
                     5×10
−3

25 75
= ( × 65) + ( × 67)
100 100

= 66. 5

Therefore, option - (4) 66.5 is the

correct ans.
9. Answer: B 10. Answer: D
 Sol: Sol:
Weight of C4H10 = 1kg = 1000g, Mole = mass in grams/Atomic mass
Mw = 58g mol–1 (g/mol)
∴moles of C4H10 = 1000

58
= 17.24 Given :
Moles
Mass of iodine = 254  grams
Combustion reaction of C4H10
Atomic mass of iodine =
follow as: 127gm/mol
13
 
mole of iodine =
C4 H10 + O2 → 4 CO2 + 5H2 O 254
2
127

{n butane & isobutane both have                        = 2 mol

same molecular formula C4H10}
Mass of oxygen = 80 gm
From above equation
Atomic mass of oxygen =
1 moles of C4H10 combustion
16gm/mol
required Moles of O2.
13

mole of oxygen = 80
  = 5 mol
Combustion of 17.24 moles of
16
∴

C4H10 required moles of O2. Thus,mole ratio of iodine and

oxygen is 2:5.
              = 17.24 × 13

2
= 112.06

moles of O2 So, they will form compound I2O5.

∵  We know that at NTP volume of

1 mole gas = 22.4 L
∴ Volume of 112.06 moles of O2 =
112.06 × 22.4 = 2510L.
Therefore the correct option is (2).
11. Answer: B 12. Answer: B
Sol: Sol:
Atomic Simple n =
5.6
=
1

  % age Moles 22.4 4

mass ration
w
C   40% 12 1
40

12
= 3 .33 n =
Mw

H   6.7 % 1 2
6.7
= 6 .7
1 1 20
=
O   53.3% 16 1
53.3
4 Mw
= 3 .33
16

∴ EF = CH2O Mw = 80 gm
13. Answer: B 14. Answer: D
Sol: Sol:
                        O2                :              N2      From equation 15 × 22.4 L of O2 is
mass                1                :                4 required for = 156 g of benzene
moles            
1

32
               :              
4

28
i.e., 156 g benzene for complete
                        7                  :               32
combustion required O2(STP) = 15

× 22.4 L
39g benzene for complete
combustion required O2(STP) = 
× 39 = 84 LO2
15×22.4

156

15. Answer: B 16. Answer: A

 Sol: Sol:
Given, Zn + Fe + 2S → ZnFeS2
W(Zn)  =  9. 75 g     2      3      5
 M (Zn) =  65          
Find the limiting reagent
Number of moles(Zn)=
w/m    =  9. 75/65
2

1
             
3

1
5

                  =  2         3       2.5

0.15
LR
Number of atoms 1 mole Zn give 1 mole Zn(FeS2)
(Cr)   =  1. 8  ×  10
23
  (given)  
2 moles Zn give 2 mole Zn(FeS2)
Number of atoms(
Cr)   =  6. 023  ×  10
23
 (I mole)

Number of moles- 
23 23
(Cr)  =  1. 8  ×  10  /6. 023  ×  10

                                       =
0.3
Number of moles (O)  =  0. 6

We can simplify the ratio by

dividing all by 0. 15
Zn =  0. 15/0. 15  = 1 

  Cr   =  0. 3/0. 15  =  2  

O  =  0. 6/0. 15  =  4

Therefore ,the Emprical formula –

ZnCr2 O4

Answer-  2
17. Answer: A 18. Answer: A
Sol:
Let mss of insulin = x
Minimum moleculatr weight of
insulin will be when insulin contains
minimum 1 sulphur
3.4
× 32
100

3200
x = = 941 .176 g
3.4

Therefore the correct option is (1).

 Sol:
(A) CH COOH 3

      M.W. = 60
24
%C  =   × 100 = 40%
60

C6 H12 O6

 M.W. =
180
%C = 72

180
.
4

10
=  0.4 × 100 = 40
%
Both have same mass % of carbon.
(B) CH 3 COOH

24
%C = × 100 = 40%

60

(C) C2H5OH
M.W = 46
24
%C = × 100 = 52. 17%

46

(C) HCOOCH3
24
%C = × 100 = 40%
60

C12H22O11

M.W = 342
 %C  =   144
× 100  = 42. 1% not same

342

(D) C H 6 12 O6

M.W = 180
%C =
72

180
× 100  =  40%   
C12 H22 O11

%C =
144

× 100 = 42. 1% 
342

Hence, option (1) is correct.

19. Answer: D 20. Answer: A
Sol: Sol:
Al4 C3 + 12H2 O → 3 CH4 + 4 Al (OH3 ) X a atomic mass
So 67. 2  LCH4 evolved by 144  gAl4 C3 Y b atomic mass

11. 2  LCH4 will be evolved a + 2b = 100           ........1

144
= × 11. 2 = 24 g
67.2
3a + 2b = 180         ........2
by solving 1 and 2
a = 40
b = 30
 Chemistry - Section B

1. Answer: 4 2. Answer: 2
Sol: Sol:
Molar mass of BaCl  = V 5.6
2. 2H2 O no.   of   moles   =   =   moles
Vm 22.4

244g/mol.
Mol. wt. of gas is =   mass
=
So, moles of BaCl ​in 488g= 
no.  of   moles
2 . 2H2 O
 = 64 g
16×22.4

5.6

moles.
given weight 488
= = 2
molecular weight 244
32 + 16x = 64
from the molecular formula we x=2
know that, 1 mole of BaCl . 2H O 2 2

 contains 2 moles of water,

So, 2 moles of BaCl . 2H 2 2O  have
water = 2 × 2 = 4moles.
Therefore required ans = 4 moles.
3. Answer: 1 4. Answer: 4
Sol: Sol:

M ass %  =
M ass of  subs tan ce

T otal mass of  compound
× 100 Given Data: Caffein has molecular
weight = 194
18x 13
=
24+32+(4×16)+18x 100
Therefore,
18x 13

120+18x
=
100 Mass of nitrogen in caffeine = 
194×28.9
= 56  amu
120+18x 100 100
=
18x 13

120 100
No. of atom in one molecule =
= 4 atoms of nitrogen
= − 1 56
18x 13
14

120 87

18x
=
13 Ans is 4
120×13
x =
18×87

x = 0. 99 ≈ 1

5. Answer: 3.4 6. Answer: 4

Sol: Sol:
N2         +        3H2       →    2 NH3 Mass of iron present in one
molecule of heamoglobin = 
2800g          1000g 0.33
× 67200 =  221. 76g
100

100 mol       500 mol

Atomic weight of iron = 56g
Here the limiting reagent is N2
Therefore, number of iron atoms
mole of NH3 produced = 200 mol present in one molecule of
heamoglobin =  221.76
= 3. 96 ≈ 4
mass of NH   = 3400 g = 3.4kg 56

 (ans).
3

Answer: 3.4

7. Answer: 11 8. Answer: 48
 Sol: Sol:
The number of oxygen atoms in hepta ∴ density of H2 O(l) = 1 g/ mL

hydrated magnesium sulfate is

7 + 4 = 11 1  mL  contains  = 1  gH2 O

Thus one mole of MgSO4.7H2O has 108  mL  contains  = 108  gH2 O

11 oxygen atoms.
Number of moles of H2 O(l) =
108

18
= 6

Three moles of MgSO4.7H2O will

contain 3 × 11 = 33 oxygen atoms. H has no neutron, Number of
neutrons in O = 16 − 8 = 8
Now one mole of ozone has three
oxygen atoms. Number of moles of neutrons in 1

mole of H O = 0 + 8 = 8
2

33 oxygen atoms will have  33

= 11
Number of moles of neutrons in
3
6
mole
mole of H O = 6 × 8 = 48
2

Thus 11NA or 11 × 6.023 ×

1023molecules of oxygen atoms will
formed.
​Ans is 11 NA
9. Answer: 1 10. Answer: 8
Sol: Sol:
The reaction will proceed further as Let the relative abundance of
follows: O − 17 be x%

So,

2KClO3 → 2KCl + 3O2

90(16)+[17x+18(10−x)]
16.12 =
100

3O2 + 4Al → 2Al2O3 x = 8

Thus, by the above reaction, it is Answer: 8

clear that for the first reaction the
ratio is 2:3 which means for 1 mole
KClO3 mole O2 produced.
3

The molar ratio for the second

reaction is 3:2 which means for 3
mole O2 it produces 2 mole Al2O3
formed.
Now, we have 1.5 moles of oxygen,
number of moles of Al2O3 produced
is
2 moles   Al2 O3
= 1. 5 moles   of  O2 ×
3  moles   of  O2

= 1  mole   of   Al2 O3