Safety Data Sheet - Version 5.

0
Preparation Date 3/19/2015
Latest Revision Date (If Revised)
SDS Expiry Date 3/17/2018

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product Identifier
Chemical Name Sodium Hydroxymethanesulfinate

Catalogue # S634950
1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against
Product Uses To be used only for scientific research and development. Not for use in humans or animals.
1.3 Details of the Supplier of the Safety Data Sheet
Company Toronto Research Chemicals
2 Brisbane Road
Toronto, ON M3J 2J8
CANADA
Telephone +14166659696
FAX +14166654439
Email orders@trc-canada.com
1.4 Emergency Telephone Number
Emergency# +14166659696 between 0800-1700 (GMT-5)

2. HAZARDS IDENTIFICATION
WHMIS Classification (Canada) WHMIS Symbols (Canada)
D2B Toxic Material Causing Other Toxic Effects
Mutagen

2.1/2.2 Classification of the Substance or Mixture and Label Elements

GHS Hazards Classification (According to EU Regulation 1272/2008 and US OSHA 1910.1200)
Acute Toxicity, Oral (Category 5)
Germ Cell Mutagenicity (Category 2)

EU Classification (According to EU Regulation 67/548/EEC)

Possible risk of irreversible effects.
EU Risk and Safety Statements (According to EU Regulation 67/548/EEC)
Hazard Statements Hazard Codes
Harmful Xn
Risk Codes and Phrases
R68 Possible risk of irreversible effects.
Safety Precaution Codes and Phrases
S53 Avoid exposure - obtain special instruction before use.
GHS Hazards Identification (According to EU Regulation 1272/2008 and US OSHA 1910.1200)
Signal Word Warning

GHS Hazard Statements

H303 May be harmful if swallowed.
H341 Suspected of causing genetic defects.

Toronto Research Chemicals - S634950 Page 1

This Safety Data Sheet contains 16 sections. All 16 sections must be present for this document to be valid.
 GHS Precautionary Statements
P201 Obtain special instructions before use.
P281 Use personal protective equipment as required.

2.3 Unclassified Hazards/Hazards Not Otherwise Classified

No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Molecular Formula: CH3NaO3S Molecular Weight: 118.10
CAS Registry #: 149-44-0 EC#: 205-739-4
Synonyms
1-Hydroxymethanesulfinic Acid Sodium Salt (1:1); Hydroxymethanesulfinic Acid Monosodium Salt; Sodium
Formaldehydesulfoxylate; Aldanil; Bleachit D; Bruggolit C; Bruggolit E 01; Bruggolit SFS; C.I. Reducing Agent 2;
Cosmolit; Formaldehyde Sodium Sulfoxylate; Formaldehyde-sodium Hydrogen Sulfite; Formaldehydesulfoxylic Acid
Sodium Salt; Formapon; Formopan; Hydrolit; Hydroxymethanesulfinic Acid Sodium Salt; Langqielie C; Leptacid;
Leptacit; NSC 4847; NSC 78331; Redol C; Rodite; Rongalit; Rongalit C; Rongalite; Rongalite C; Sodium
(hydroxymethyl)sulfinate; Sodium Hydroxymethanesulfinate; Sodium Methanalsulfoxylate; Sodium Sulfoxylate
Formaldehyde; Superlite C
3.2 Mixtures
Not a mixture

4. FIRST AID MEASURES

4.1 Description of First Aid Measures
General Advice
If medical attention is required, show this safety data sheet to the doctor.

If Inhaled
If inhaled, move casualty to fresh air. If not breathing, give artificial respiration and consult a physician.

In Case of Skin Contact

Wash affected area with soap and water. Consult a physician if any exposure symptoms are observed.

In Case of Eye Contact

Immediately rinse eyes with plenty of water for at least 15 minutes. Consult a physician.

If Swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Do NOT induce vomiting unless
advised to do so by a physician or Poison Control Center. Seek medical attention.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
No data available
4.3 Indication of any Immediate Medical Attention and Special Treatment Needed
No data available

5. FIREFIGHTING MEASURES
5.1 Extinguishing Media
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special Hazards Arising from the Substance or Mixture
Carbon oxides, Nitrogen oxides
5.3 Advice for Firefighters
Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further Information

No data available
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions, Protective Equipment and Emergency Procedures

Toronto Research Chemicals - S634950 Page 2

This Safety Data Sheet contains 16 sections. All 16 sections must be present for this document to be valid.
Use recommended personal protective equipment (see Section 8). Prevent the formation of dusts and mists. Adequate
ventilation must be provided to ensure dusts or mists are not inhaled.

6.2 Environmental Precautions

Material should not be allowed to enter the environment. Prevent further spillage or discharge into drains, if safe to do
so.

6.3 Methods and Materials for Containment and Cleaning Up

Contain the spill and then collect using non-combustible absorbent material (such as clay, diatomaceous earth,
vermiculite or other appropriate material). Place material in a suitable, sealable container and then dispose according to
local/national regulations and guidance (see Section 13).

For protective equipment, refer to Section 8. For disposal, see Section 13.
7. HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact with skin and eyes. Ventilation and proper handling are to be used to prevent the formation of dusts and
mists. Normal measures for preventative fire protection. No smoking, eating or drinking around this material. Wash
hands after use.

7.2 Conditions for Safe Storage, Including any Incompatibilities

Ensure container is kept securely closed before and after use. Keep in a well ventilated area and do not store with
strong oxidizers or other incompatible materials (see Section 10).
Storage conditions: Hygroscopic, Refrigerator, under inert atmosphere
7.3 Specific End Uses
For scientific research and development only. Not for use in humans or animals.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control Parameters
Contains no components with established occupational exposure limits.
8.2 Exposure Controls
Appropriate Engineering Controls
A laboratory fumehood or other appropriate form of local exhaust ventilation should be used to avoid exposure.

Personal Protective Equipment

All recommendations below are advisory in nature and a risk assessment should be performed by the employer/end
user prior to use of this product. The type of protective equipment must be selected based on the amount and
concentration of the dangerous material being used in the workplace.

Eye/Face Protection
Safety glasses or safety goggles. All equipment should have been tested and approved under appropriate standards,
such as NIOSH (US), CSA (Canada), or EN 166 (EU).

Skin Protection
Gloves should be used when handling this material. Gloves are to be inspected prior to use. Contaminated gloves are
to be removed using proper glove removal technique so that the outer surface of the glove does not contact bare skin.
Dispose of contaminated gloves after use in compliance with good laboratory practices and local requirements.

Gloves used for incidental exposures (splash protection) should be designated as “low chemical resistant” or
“waterproof” by EU standard EN 374. Unrated gloves are not recommended.
Suggested gloves: AnsellPro nitrile gloves style 92-500 or 92-600, 5 mil thickness.
Penetration time has not been determined.

Gloves used for prolonged direct exposure (immersion) should be designated “chemical resistant” as per EN 734 with
the resistance codes corresponding to the anticipated use of the material.
Suggested gloves: AnsellPro Viton/Butyl gloves style 38-612, 4/8 mil thickness.
Penetration time has not been determined.

These recommendations may not apply if the material is mixed with any other chemical, or dissolved into a solution. A
risk assessment must be performed to ensure the gloves will still offer acceptable protection.

Body Protection
Fire resistant (Nomex) lab coat or coveralls.

Respiratory Protection

Toronto Research Chemicals - S634950 Page 3

This Safety Data Sheet contains 16 sections. All 16 sections must be present for this document to be valid.
 Recommended respirators are NIOSH-approved N95 or CEN-approved FFP2 particulate respirators. These are to be
only used as a backup to local exhaust ventilation or other engineering controls. If the respirator is the only means of
protection, a full-face supplied air respirator must be used.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical and Chemical Properties
A) Appearance B) Odour
White Solid No data available
C) Odour Threshold D) pH
No data available No data available
E) Melting Point/Freezing Point F) Initial Boiling Point/Boiling Range
120-125°C No data available
G) Flash point H) Evaporation Rate
No data available No data available
I) Flammability (Solid/Gas) J) Upper/Lower Flammability/Explosive Limits
No data available No data available
K) Vapour Pressure L) Vapour Density
No data available No data available
M) Relative Density N) Solubility
No data available Methanol, Water
O) Partition Coefficient: n-octanol/water P) Auto-Ignition Temperature
No data available No data available
Q) Decomposition Temperature R) Viscosity
No data available No data available
S) Explosive Properties T) Oxidizing Properties
No data available No data available
9.2 Other Information
no data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
No data available
10.2 Chemical Stability
Stable at recommended storage conditions.
10.3 Possibility of Hazardous Reactions
No data available
10.4 Conditions to Avoid
No data available
10.5 Incompatible Materials
Strong oxidizing agents.
10.6 Hazardous Decomposition Products
No data available

11. TOXICOLOGICAL INFORMATION

11.1 Information on Toxicological Effects
A) Acute Toxicity
LD50 (oral - rat) >2000 mg/kg
B) Skin Corrosion/Irritation
No data available
C) Serious Eye Damage/Irritation
No data available
D) Respiratory or Skin Sensitization
No data available
E) Germ Cell Mutagenicity
Possible human mutagen. Laboratory results have shown mutagenicity in several model systems.
F) Carcinogenicity
No data available

Toronto Research Chemicals - S634950 Page 4

This Safety Data Sheet contains 16 sections. All 16 sections must be present for this document to be valid.
 G) Reproductive Toxicity/Teratogenicity
No data available
H) Single Target Organ Toxicity - Single Exposure
No data available
I) Single Target Organ Toxicity - Repeated Exposure
No data available
J) Aspiration Hazard
No data available
K) Potential Health Effects and Routes of Exposure
Inhalation
May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion
Harmful if swallowed.
Skin
May be harmful if absorbed through skin. May cause skin irritation.
Eyes
May cause eye irritation.
L) Signs and Symptoms of Exposure
No data available
To the best of our knowledge, the chemical, physical, and toxicological properties of this material have not been
thoroughly investigated.
M) Additional Information
RTECS: PB0380000
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No data available
12.2 Persistance and Degradability
No data available
12.3 Bioaccumulative Potential
No data available
12.4 Mobility in Soil
No data available
12.5 Results of PBT and vPvB Assessment
No data available
12.6 Other Adverse Effects
No data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
A) Product
Product may be burned in an incinerator equipped with afterburner and scrubber. Excess and expired materials are to
be offered to a licensed hazardous material disposal company. Ensure that all Federal and Local regulations regarding
the disposal and destruction of this material are followed.
B) Contaminated Packaging
Dispose of as above.
C) Other Considerations
Product is not to be disposed of in sanitary sewers, storm sewers, or landfills.
14. TRANSPORT INFORMATION
14.1 UN Number
DOT (US): N/A IATA: N/A IMDG: N/A ADR/RID: N/A
14.2 UN Proper Shipping Name
DOT (US)/IATA:
Not dangerous goods
IMDG/ARD/RID:
Not dangerous goods
14.3 Transport Hazard Class(es)
DOT (US): N/A IATA: N/A IMDG: N/A ADR/RID: N/A
14.4 Packing Group

Toronto Research Chemicals - S634950 Page 5

This Safety Data Sheet contains 16 sections. All 16 sections must be present for this document to be valid.
 DOT (US): N/A IATA: N/A IMDG: N/A ADR/RID: N/A
14.5 Environmental Hazards
DOT (US): None IATA: None IMDG: None ADR/RID: None
14.6 Special Precautions for User
None
15. REGULATORY INFORMATION
This safety data sheet complies with the requirements of WHMIS (Canada), OSHA 1910.1200 (US), and EU Regulation
EC No. 1907/2006 (European Union).
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture
A) Canada
DSL/NDSL Status: This product or a component of this product is registered on the Canadian DSL/NDSL.
B) United States
TSCA Status: This product or a component is listed on the US EPA TSCA.
C) European Union
ECHA Status: This product or a component is registered with the EU ECHA.
15.2 Chemical Safety Assessment
No data available
16. OTHER INFORMATION
16.1 Revision History
Original Publication Date: 3/19/2015
16.2 List of Abbreviations
LD50 Median lethal dose of a substance required to kill 50% of a test population.
LC50 Medial lethal concentration of a substance required to kill 50% of a test population.
LDLo Lowest known lethal dose
TDLo Lowest known toxic dose
IARC International Agency for Research on Cancer
NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
16.3 Further Information
Copyright 2015. Toronto Research Chemicals Inc. Copies may be made for internal use only. The above information is
believed to be correct to the best of our knowledge, but is to be only used as a guide. To the best of our knowledge, the
chemical, physical, and toxicological properties have not been thoroughly investigated. Please take all due care when
handling this product.

Toronto Research Chemicals - S634950 Page 6

This Safety Data Sheet contains 16 sections. All 16 sections must be present for this document to be valid.