CHEMICAL BONDING

** SINGLE OPTION CORRECT :-

Q.1 MF + XeF4  'A' . (M+ = Alkali metal cation). The state of hybridisation of the central atom in 'A' and
shape of the species are
(A) sp3d, TBP (B) sp3d3, distorted Octahedral
3 3
(C) sp d , Pentagonal Planar (D) No compound formed at all
Q.2 The maximum no of atoms in a plane for the compound formed by reaction of SbF5 with SO2 is :
(A) 8 (B) 6 (C) 7 (D) 9
Q.3 Select correct statement(s):
(A) Acidic strength of HBr > HCl but reverse is true for their reducing property
(B) Basic strength of PH3 > AsH3 but reverse is true for their Bond angle
(C) Dipole moment of CH3Cl > CH3F but reverse is true for their HCH ^ bond angle

(D) K a1 of fumaric acid is higher than maleic acid but reverse is true for their K a
2

Q.4 According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic
orbitals through LCAO (linear combination of atomic orbitals). The correct statement(s) about molecular
orbitals is/are
Statement (a) : bonding molecular orbitals are formed by addition of wave-functions of atomic orbitals
Statement (b) : anti-bonding molecular orbitals are formed by subtraction of wave-functions of atomic
orbitals
Statement (c) : non-bonding molecular orbitals do not take part in bond formation because they belong to
inner shells
Statement (d) : anti-bonding molecular orbitals provide stability to molecules while bonding molecular
orbitals make the molecules unstable.
(A) Statement a, d (B) Statement a, b, c (C) Statement a, b, d (D) Statement a, b
Q.5 Which is incorrect in the following :
(A) Ionisation energy of F2 molecule is more that of F-atom.
(B) Ionisation energy of F-atom is more them that of Cl-atom
(C) Electron gain enthalpy of F-atom is less (–)ve than that of Cl-atom
(D) Ionic mobility of fluoride ion is less than chloride ion in water.
Q.6 In which the following interaction form nonbonding molecular orbital, when z-axis is the bonding axis.
(A) d yz  d z 2 (B) d yz  d xy (C) d x 2  y 2  d xy (D) All are form N.B.M.O.

Q.7 Which of the following shape can not be obtained from sp3d2 hybridisation.
(A) Square planar (B) Square pyramidal (C) Tetrahedral (D) Octahedral
Q.8 The orbitals occupy more space will have more “s” character and accordingly which is incorrect statement.
(A) l.p. will go to the axial position of PBP (pentagonal bipyramidal) geometry.
(B) l.p.will go to the equitorial position of TBP (trigonal bipyramidal) geometry.
(C) Axial bond lengths of PBP geometry is longer than equatorial.
(D) Equatorial bond lengths of TBP geometry are shorter than axial.
Q.9 In the formula of PF2Cl3 (A) and PF3Cl2 (B), if all F-atoms are replaced by Br-atom, then which of the
product will show zero dipole moment.
(A) Product from 'A' (B) Product from 'B'
(C) Product from both 'A' and 'B' (D) Products from none

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Q.10 Nodal planes of  bond(s) in CH2 = C = C = CH2 are located in
(A) All are in molecular plane
(B) Two in molecular plane and one in plane perpendicular to molecular plane which contains C–C -bond
(C) One in molecular plane and two in plane perpendicular to molecular plane which contains C-C -bond
(D) Two in molecular plane and one in plane perpendicular plane which bisects C-C -bond at right angle
Q.11 The correct increasing order of extent of hydrolysis is
(A) CCl4 < MgCl2 < AlCl3 < SiCl4 < PCl5 (B) CCl4 < AlCl3 < MgCl2< PCl5 < SiCl4
(C) CCl4 < SiCl4 < PCl5 < AlCl3 < MgCl2 (D) CCl4 < PCl5 < SiCl4 < AlCl3 < MgCl2
Q.12 Which of the following order is correct of the given property.
(A) LiCl >NaCl > KCl > RbCl > CsCl : Thermal stability order
(B) BeF2 < MgF2 < CaF2 < SrF2 < BaF2 : solubility order
(C) NO2– > NO— > NO = NO2+ > NO+ : bond length order
(D) BaO > SrO > CaO > BeO > MgO : basic character order
Q.13 The strength order of  bond is
(A) 2p–2p > 2p–3d > 2p–3p > 3p–3p (B) 2p–2p < 2p–3d < 2p–3p < 3p–3p
(C) 2p–2p < 2p–3d < 2p–3p > 3p–3p (D) 2p–2p < 2p–3d > 2p–3p < 3p–3p
Q.14 Select the correct statement :
(A) HSO 5 ion has one S–O–H linkage
(B) Number of B–O–B linkages in Borax is equal to number of P–O–P linkages in P4O10
(C) Hybridisation of both sulphur in H2S2O5 (pyrosulphurous acid) is same but oxidation state of both
sulphur are different
(D) Tetra phosphoric acid has four P–O–P and no P–P linkage
Q.15 Cyclic polymetaphosphates have the general formula of [PnO3n]n–. Cyclic trimeric polymetaphosphate
(P3O9)3– has commercial importance. Which of the following is not true regarding P3O93– :
(A) It has 3 P–O–P linkage
(B) It has 3 p–d bonds
(C) Each phosphorous is sp3 hybridised
(D) Number of P–O–P linkage is not equal to number of sp3 hybridised phosphorous atom.
Q.16 Choose the correct statement from the following :
(A) Bonds associated in a bridge are of identical length in case of B2H6 and Al(BH4)3.
(B) Bonds associated in a bridge are of different length in case of B2H6 and Al(BH4)3.
(C) Bonds associated in a bridge are of identical length in case of B2H6 but different in case of Al(BH4)3.
(D) Bonds associated in a bridge are of identical length in Al(BH4)3 but different in case of B2H6.
Q.17 The type of overlap in the bridge bond existing in Al2(CH3)6 is
(A) sp3 – sp3d – sp3 (B) sp3 – sp2 – sp3
(C) sp3 – s – sp3 (D) sp3 – sp3 – sp3
Q.18 Compound which form least H-bonding with water is :
(A) KHCO3 (B) NaHCO3 (C) CsHCO3 (D) RbHCO3
Q.19 The correct order of bond angle in the compounds given below would be
O O O
H3C 1 CH3 H3Si 2 SiH3 Ph3Si 3 SiPh3
(A) 1 > 2 > 3 (B) 1 < 2 < 3 (C) 1 > 3 > 2 (D) 1 < 2 = 3

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Q.20 The decreasing order of :- Xe > Kr > Ar > Ne > He, is correct for
(1) Boiling point (2) Solubility in water
(3) Polarisability (4) Ease of liquification
(A) Only 1 (B) 1, 2, 3, 4 (C) 1, 2, 4 (D) 2, 4

** NUMERICAL BASED QUESTIONS :- (TO BE TRUNCTATED AND WRITTEN UPTO 2

Q.22 Find the number of molecule have d z2 - orbitals taking part in hybridisation:
XeOF4 , XeO2F2, XeF6, PCl5, PCl5(solid), SF6, SF4, SF2, P4O10, C2N2
Q.23 How many following compounds which has/have electrovalent, covalent and coordinate bonds.
NH4Cl, NaCl, NaOH, Na[BF4], CaCO3, Complex of NH3 and BF3, NaCN, HNC, Ca(NO3)2
Q.24 The maximum number of halogen atoms are present in one plane for dimer of ICl3
Q.25 In following option how many total number of statements are correct:
(I) H-bond is also a one type of dipole – dipole interaction.
(II) Hybrid orbital always form sigma bond.
(III) If molecule is polar then it must be planar.
(IV) If bond is polar then compound must be polar.
(V) In chloral hydrate molecule intramolecular H-bond is present.
(VI) More electronegative element always has more electron affinity.
(VII) Hardness present in water is due to presence of D2O.
(VIII) Order of boiling point H2 < D2 < T2.
Cl Cl

=
(IX) Order of dipole moment.
Cl Cl
Cl