CHEMICAL BONDING 05

Q.1 Which of the following statements are not correct?

(A) All C–O bonds in CO 32 are equal but not in H2CO3.

(B) All C–O bonds in HCO 2 are equal but not in HCO2H

(C) C–O bond length in HCO 2 is longer than C–O bond length in CO 32 .

(D) C–O bond length in HCO 2 and C–O bond length in CO 32 are equal.

Q.2 In the structure of H2CSF4, which of the following statement is/are correct?
(A) Two C–H bonds are in the same plane of axial S–F bonds.
(B) Two C–H bonds are in the same plane of equitorial S–F bonds.
(C) Total six atoms are in the same plane.
(D) Equitorial S–F bonds are perpendicular to plane of –bond.

Q.3 Which statement is/ are correct

(A) Higher is the polarisation, higher will be relative solubility in non-polar solvent
(B) Higher is the polarisation, higher will be the intensity of colour
(C) Diamagnetic substances some times become coloured due to HOMO-LUMO transition
(D) Higher is the polarisation in metal oxide, higher will be the basic character

Q.4 Which of the following statements is/are not correct for following compounds.
(I) SCl2 (OCH3)2 and (II) SF2 (OCH3)2
(A) –OCH3 groups in both cases occupy the same position.
(B) Cl-atoms occupy equitorial position in case of (I) and F-atoms occupy equitorial position in case
of (II).
(C) Cl-atoms occupy axial position in case of (I) and F-atoms occupy equitorial position in case of (II)
(D) Cl and F-atom occupy either axial or equitorial position in case of (I) and (II) respectively.

Q.5 Select the correct statement about silicates.

(A) Cyclic silicate having three Si atoms contains six Si–O–Si linkages.
1
(B) 2 corner oxygen atoms of per tetrahedron unit are shared in double chain silicate
2
(C) (Si 2 O5 ) 2n n  is formula of double chain silicate
(D) SiO 44 units polymerize to form silicate because Si atom has less tendency to form  bond
with oxygen.

Q.6 Which of the following statement(s) is/are not correct.

(A) PCl2F3 and PCl3F2 both shows pseudorotation.
(B) melting point order of AgCl and KCl is KCl > AgCl
(C) If KI is colourless and KCl, KBr are also colourless
(D) Heat of vaporisation of HF is greater than H2O due to strong H–bonding in case of HF.

KUMAR SHISHIR
Q.7 Select correct statement:
(A) Thallous compounds are more stable than thallic compounds
(B) Pb4+ compounds have more oxidising property than Sn4+ compounds
(C) Cis-platin used in cancer-chemotherapy is a chelate
(D) Thermal stability of BaCO3 > BeCO3

Q.8 Which of the following statement is incorrect.

(A) O2 is paramagnetic, O3 is also paramagnetic
(B) O2 is paramagnetic, O3 is diamagnetic
(C) B2 is paramagnetic, C2 is also paramagnetic
(D) Different observation is found in their bond length when NO NO+ and CO  CO+

Q.9 Select the incorrect statements:

(A) Hydrogen peroxy phosphate ion contains one P–O–H bond.
(B) PH5 exists but NH5 does not.
(C)  Cl PCl and  Br PBr bond angles are equal in PCl3F2 and PF3Br2 molecule.
(D) According to MOT, in C2 molecule there are two covalent bonds between two C atoms in which
both are bonds.
Q.10 Select the correct statement.
(A) When d x 2  y 2 or dxy orbitals combine in parallel planes then  or  molecular orbitals form.

(B) When d x 2  y2 and dxy orbitals combine in parallel planes then NBMO formed.
(C) When dyz and dxz orbitals combine in along y-axis then NBMO orbitals formed.
(D) No interaction is possible when pz and dxz orbitals overlapped with collinear z-axis.

Q.11 Select the correct statement(s) for following molecules.

(I) PF2 (CH3)3 (II) PF2 (CF3)3
(A) Both have trigonal bipyramidal structure
(B) Both have same dipole moment
(C) P–F bond length is longer in PF2(CH3)3 than the PF2(CF3)3
(D) P–F bond length is longer in PF2(CF3)3 than the PF2 (CH3)3

Q.12 Which of the following properties are same for N2H2, N2F2 and H2N2O2.
(A) All are having two isomer.
(B) All are having equal number of bonds between two N-atoms.
(C) All are having equal bond strength of N–N bond.
(D) Oxidation state of N-atoms is same for all.

Q.13 Select the incorrect statement for adjacent bond angle

(A) In  CF2 and OF2, OF2 has higher bond angle
(B) PF4+ and PF4o, PF4o has higher bond angle
(C) ClF3 and BF3, ClF3 has lower bond angle
(D) NH3 and PH3 both have same bond angle

KUMAR SHISHIR
Q.14 Which of the following molecules is/are planar.
(A) BFCl Br (B) F2B–CC–BF2
(C) (SiH3)3N (D) H2N–NH2

Q.15 Which of the following molecule(s) has/have d – p bonding

(A) H2S2O3 (B) P4O10 (C) SO3 (D) P4S10

Q.16 Which of the following molecule(s) gives only acid(s) on hydrolysis

(A) PCl3 (B) SF4 (C) NCl3 (D) P4O6

Q.17 In which of the following process the value of magnetic moment is getting changed.
(A) N2  N2¯ (B) N2  N2+ (C) O2  O2+ (D) O2+  O2¯

Q.18 Which of the following are correct statement(s).

(A) Bond angle order (X–S–X) is OSF2 < OSCl2 < OSBr2
(B) (O–O) bond length in O22– is more than O2F2
(C) dC–Cl bond length in CH3Cl > CF3Cl
(D) 4 P–P–P angles are equal to 90° in P4 molecule.

Q.19 Choose the incorrect order of bond angle?

(A) H2S < H2O < NH3 (B) NO2 > NO2¯ > NO2
(C) OF2 < OH2 < O(CH3)2 (D) BF3 < BCl3 < BBr3

Q.20 Which of the following species have O–O bond length longer than that in O2 molecule?
(A) H2S2O8 (B) H2SO5 (C) H4P2O8 (D) O2[BF4]

Q.21 Which of the following molecules does not consist intermolecular H-bonding?
(A) Chloral hydrate (B) Acetic acid (Vapour)
(C) Ortho chlorophenol (D) Para-hydroxy benzaldehyde

Q.22 Which of the following statements are correct for H2CSF4?

(A) Both hydrogens and axial fluorine atoms are in the same plane
(B) Both hydrogens and equatorial fluorine atoms are in the same plane.
(C) Maximum number of atoms present in a single plane is 6.
(D)  FeSFe is less than 120°.

Question No. 23 & 24 (2questions)

According to Bent's rule, more electronegative atom decreases s-character and increases p-character
in its bond whereas it decreases p-character and increases s-character in its adjacent bond or orbital.
As s-character increases, angular volume of bonding or non-bonding orbital increases and bond length
decreases.
Q.23 Which of the following has minimum N–S bond length?
(A) NSF3 (B) NSF (C) (NSF2)– (D) All have equal bond length

KUMAR SHISHIR
Q.24 Which of the following is the correct order of C–Cl bond length?
(A) CH3Cl > CH2Cl2 > CHCl3 (B) CH3Cl < CH2Cl2 < CHCl3
(C) CH2Cl2 > CH3Cl > CHCl3 (D) CHCl3 > CH3Cl > CH2Cl2

Question No. 25 to 27 (3 questions)

Hydrogen bonding originates from the dipole-dipole interaction between H-atom and any of the other
atom like F, O, N and in somecases with Cl atom. There are two types of H-bonding like intermolecular
and intramolecular H– bonding.
Q.25 Which of the following molecule does not consist of intramolecular H–bonding.
(A) chloral (B) chloral hydrate
(C) ortho hydroxy benzaldehyde (D) ortho chlorophenol

Q.26 Which of the following plot for  (density) v/s T (temperature) for liquid H2O is correct:

   

(A) (B) (C) (D)

4°C 4°C 4°C 4°C
0°C T 0°C T 0°C T 0°C T

Q.27 Which of following statement is incorrect.

(A) Boiling point of H2O2 is greater than that of H2O
(B) Ethylene glycol is less viscous than glycerol.
(C) o-nitrophenol can be separated from its meta and para isomer using its steam volatile property.
(D) In ice each 'O' atom is tetrahedrally arranged by four H-atoms which are all equidistant.

Question No. 28 to 30 (3 questions)

Bridge bonding is a specific kind of bonding in pages of chemistry. In general -bond pair delocalisation
is very difficult. But electron deficiency of the central atom forces to delocalise and forms this kind of
bond.
Q.28 The B2H6 molecule is dissolved in tetrahydrofuran. Which atom(s) is/are having changes of hybridisation
with respect to reactant and final product of the process given.
(A) B only (B) B and O (C) B, O and C (D) None of these

Q.29 In which of the dimerisation process, the achievement of the octet is not the driving force.
(A) 2AlCl3  Al2Cl6 (B) BeCl2  BeCl2 (solid)
(C) 2ICl3  I2Cl6 (D) 2NO2  N2O4

Q.30 The molecule is not having 3c–2e bond.

(A) BeH2 (dimer) (B) BeH2 (solid) (C) C2H6 (D) B2H6

KUMAR SHISHIR
Q.31 Match the column.
Column I Column II
(A) H2C = C = CHF (P) Nonpolar and planar
(B) B3N3H6 (Q) Nodal planes of -bonds are lying in the molecular
plane.
(C) XeO3F2 (R) Nonpolar and nonplanar
(S) Polar and nonplanar

Q.32 Column I Column II

(A) Ionic compound (P) HCl (vap)
(B) Non-polar covalent compound (Q) SiO2
(C) Polar covalent compound having (R) KNO 3
sigma bond only (S) NO

Q.33 Column-I Column-II

(A) XeF5 (P) Central atom is having two lone pairs.

(B) XeF5 (Q) Only five atoms are lying in the one plane.

(C) XeF4 (R) Species is not having any  - bond.

(D) XeO64 (S) The central atom is having oxidation state of + 4.

(T) The species is sp3d2 hybridised having either zero or one lone pair
on the central atom.
Q.34 If the molecule S4N4 has the following topology, find out the number of 5-membered ring in this
structure.
O O

O O O O

O O

Q.35 Which of the following molecule has less than 100° bond angle?
(a) H2S (b) H2Se (c) H2Te (d) PH3 (e) AsH3 (f) SbH3
(g) P4 (h) CH4 (i) NH3 (j) H2O

Q.36 Find the number of species having two p-p bonds.

SO2, SO3, XeOF4, XeO2F2, POCl3, CO32–, NO3¯

KUMAR SHISHIR