BAKLIWAL TUTORIALS

CHEMISTRY TEST
Mode: Main Level Time: 45 Min.
Marking Scheme: +4, -1 Total marks : 144

Q.1 According to octet rule SO3 contains …………. Number of dative bonds

(1) 1 (2) 2 (3) 3 (4) 4

Q.2 Which of the following has the lowest Lattice energy?

(1) LiF (2) LiCl (3) LiBr (4) Lil

Q.3 The correct order of increasing C – O bond length of CO, CO 32 − , CO 2 is

(1) CO2−
3 < CO2 < CO (2) CO2 < CO2−
3 < CO

(3) CO < CO2−

3 < CO2 (4) CO < CO2 < CO2−
3

Q.4 For which of the following molecule significant   0 ?

(1) A and B (2) Only C (3) C and D (4) Only A

Q.5 Total number of lone pair of electrons on Xe in XeOF4 is :

(1) 0 (2) 1 (3) 2 (4) 3

1 By Vipul Sir (C7)

 BAKLIWAL TUTORIALS

Q.6 H2 O and Cl2 O have different bond angles due to

(1) Number of lone pairs on central atom in H2 O and Cl2 O are different
(2) Hybridization is different
(3) Repulsions are more among bulky chlorine atoms in Cl2 O
(4) △ 𝐸𝑁 between central atom and bonded atoms is different.

Q.7 Which one of the following is the correct set with reference to molecular formula, hybridisation of
central atom and shape of the molecule?

(1) CO2 , 𝑠𝑝2 , bent (2) H2 O, 𝑠𝑝2 , bent

(3) BeCl2 , sp, linear (4) H2 O, sp 3 , linear

Q.8 The shape of 𝐴𝐵3 𝐸 molecule ( B = bond pair, 𝐄 = lonepair)

(1) Tetrahedral
(2) pyramidal
(3) Angular
(4) T-shape

Q.9 In which of the following molecules / ions or all the bonds not equal?

(1) XeF4 (2) BF4− (3) SF4 (4) SiF4

Q.10 On catalytic hydrogenation, ethylene gives ethane during this reaction

(1) Hybridization of carbon atoms changes from sp 2 to sp3

(2) Bond angle decreases from 120 to 109.5

(3) C – C bond length increases from 1.34 A to 1.54A

(4) All of these

Q.11 In which of the following dative bond is not present

(1) H3 O+ (2) NH4 + (3) Al2 Cl6 (4) N2 H4

2 By Vipul Sir (C7)

 BAKLIWAL TUTORIALS
Q.12 Which one of the following pairs of species have the same bond order?

(1) CN − and NO + (2) CN − and CN +

(3) O −2 and CN − (4) NO+ and CN +

Q.13 Which of the following species is paramagnetic?

(1) CO (2) NO (3) O2−

2 (4) 𝐶𝑁 −

Q.14 Stability of species Li 2 , Li 2+ , Li 2− increases in the order

(1) Li −2  Li 2+  Li 2 (2) Li 2  Li 2−  Li 2+

(3) Li −2  Li 2  Li 2+ (4) Li 2  Li 2+  Li 2−

Q.15 In which of the following ionization processes, the bond order has increased and the magnetic behavior
has changed?

(1) N2 → N2+ (2) C2 → C2 ∗ (3) NO → NO+ (4) O2 → O2+

Q.16 NH3 has a much higher boiling point than PH3 because

(1) NH3 has a larger molecular weight

(2) NH3 undergoes umbrella inversion
(3) NH3 contains hydrogen bonds
(4) NH3 contains ionic bonds where as PH3 contains covalent bonds

Q.17 The vapour pressure of

Is higher than due to

3 By Vipul Sir (C7)

 BAKLIWAL TUTORIALS
(1) Dipole moment (2) Dipole – dipole interaction
(3) Intra molecular hydrogen bonding (4) Intermolecular hydrogen bonding

Q.18 Molecule which contains 4 bond pairs and 2 lone pairs of electrons on the central atom is

(1) XeF2 (2) CO2 (3) XeF4 (4) 𝑆𝐹6

Q.19 BCl3 molecule is planar while NCl3 molecule is pyramidal because

(1) BCl3 does not have lone pair on B but NCl3 has one lone pair on 𝑁.
(2) B − Cl bond is more polar than N − Cl bond
(3) 𝑁 atom is smaller than 𝐵
(4) N − Cl bond is more covalent than B − Cl bond

Q.20 The pair of species having identical shapes

(1) XeF2 , CO2 (2) BF3 , PCl3 (3) 𝑃𝐹3 , 𝐼𝐹5 (4) 𝐶𝐹4 , 𝑆𝐹4

Q.21 The molecular shapes of 𝑆𝐹4 , 𝐶𝐹4 , and XeF4 are

(1) different with 1,0 and 2 lone pairs of electrons on the central atom, respectively
(2) different with 0,1 and 2 lone pairs of electrons on the central atom, respectively
(3) same with 1,1 and 1 lone pair of electrons on the central atom, respectively
(4) same with 2,0 and 1 lone pair of electrons on the central atom, respectively

Q.22 Which one of the following is the correct set with respect to molecule, hybridization and shape?

(1) BeCl2 , 𝑠p2 , linear (2) BeCl2 , sp2 , triangular planar

(3) BCl3 , 𝑠p2 triangular planar (4) BCl3 , 𝑠𝑝3 , tetrahedral

4 By Vipul Sir (C7)

 BAKLIWAL TUTORIALS
Q.23 The following is soluble in water
(1) C2 H5OC2 H5 (2) C2 H5OH

(3) C2 H5COOC2 H5 (4) C6 H 6

Q.24 Even though electronegativity of chlorine is equal to that of nitrogen, chlorine is unable to form
hydrogen bonds. It is due to

(1) 𝐶𝑙 has three lone pairs on it

(2) Atomic size of Chlorine is comparatively large.
(3) Atomic size of nitrogen is comparatively large
(4) Electron affinity of chlorine is highest
Q.25 Which property is not due to Hydrogen bonding?

(1) High boiling point of water

(2) Solubility of NH3 in H2 O
(3) Polar nature of halogen acid
(4) High viscosity of H3 PO4

Q.26 In correct statement about the structure of PCl5

(1) axial P-Cl bonds have more bond length than equatorial P-Cl bonds

(2) d 2z orbital is involved in Sp3d hybridization

(3) The no. of planar atoms in PCl5 is 4

(4) Phosphorous is in 2nd excited state

Q.27 The mode of hybridization of central carbon in C3O 2 is

(1) sp (2) sp3 (3) sp 2 (4) sp3d

5 By Vipul Sir (C7)

 BAKLIWAL TUTORIALS
Q.28 Which of the following statements is not correct from the viewpoint of molecular orbital?

(1) Be2 is not a stable molecule

(2) He2 is not stable but He+
2 is expected to exist

(3) Bond strength of 𝑁2 is maximum amongst the homonuclear diatomic molecules belonging to the
second period.
(4) The order of energies of molecular orbitals in 𝐹2 molecule is
𝐸(𝜎2𝑠) < 𝐸(𝜎 ∗ 2𝑠) < 𝐸(𝜋2𝑝𝑥 ) = 𝐸(𝜋2𝑝𝑦 )
< 𝐸(𝜎2𝑝𝑧 ) < 𝐸(𝜋 ∗ 2𝑝𝑥 ) = 𝐸(𝜋 ∗ 2𝑝𝑦 ) < 𝐸(𝜎 ∗ 2𝑝𝑧 )

Q.29 Which formulae does not correctly represents the bonding capacity of the atom involved:

Q.30 Which statement is incorrect for OSF4 ?

(1) S atom has sp3d hybridization

(2) OsF4 have distorted trigonal pyramidal geometry

(3) O atom at one of the two axial positions having S=O bond
(4) O atom at one of the equatorial position having S=O bond

+
Q.31 Consider the chemical species NO− −
3 , NO2 and NO2 and point out the correct statement given below.

(1) The hybrid state of N in NO+

2 is 𝑠𝑝
2

(2) The hybrid state of N in all the species is the same

(3) The shape of both NO+ − −
2 and NO2 is bent while NO3 is planar

(4) The hybrid state of N in NO− −

3 and NO2 is the same.

6 By Vipul Sir (C7)

 BAKLIWAL TUTORIALS
Q.32 Which of the following statements is/are true

(1) PH5 and BiCl5 donot exist (2) 𝑝𝜋 − 𝑑𝜋 bond is present in SO2
(3) 𝐼3+ has bent geometry (4) SeF4 and CH4 have same shape
(1) 1,2,3 (2) 1,3 (3) 1 and 2 (4) 1,2,4

Q.33 Which of the following molecules is polar

(1) XeF4 (2) IF5 (3) SbF5 (4) CF4

Q.34 The nodal plane in the 𝜋 − bond of ethene is located in

(1) The molecular plane

(2) A plane parallel to the molecular plane
(3) A plane perpendicular to the molecular plane which bisects the carbon-carbon sigma bond at right
angle
(4) A plane perpendicular to the molecular plane which contains the carbon - carbon 𝜎 − bond.

Q.35 Which of the following overlap is correct?

Q.36 Which one of the following arrangements of molecules is correct on the basis of their dipole moments?
(1) BF3  NF3  NH3 (2) NF3  BF3  NH3

(3) NH3  BF3  NF3 (4) NH3  NF3  BF3

7 By Vipul Sir (C7)