PC Questions
PC Questions
SECTION-A
.Fd!d~~EL
· (1) A only (2) B only (I) 0.1
(3)' both A and B (4) neither A nor B ,(2) 0.2
(3) 0.5
2. A time dependent force F = 3t (F in Newton and t in (4) I
second) ac~ on three blocks m 1, m 2 and m3 kept in
contact on a rough ground as shown. Co-efficie
block of mass I kg is placed on a rough incline as
friction between blocks and ground is 0 ,
· The coefficient of friction between block
and lllJ are 3 kg, 2 kg and I kg respe
is 0.4. The acceleration of block is
after which the blocks started to ·
.F=3t
m1
(1) 4 sec
(2) 8 sec
8
(3) - sec
3
4
, (4) -sec
3
3. A block of mass I kg is placed on a rough horizontal 7. ,' A mass m rests on a horizontal surface. The
surface connected by a light string passing over two coefficient of friction between the
mass and the .
· smooth pulleys as shown. Another block of I kg is . surface is µ. If the mass is pull~ by a force F as
· connected to the other end· of the string. The shown in figure, the limiting friction -between the
acceleration of the system is ( coefficient of friction inass and the surface will be
µ=0.2)
_f~A~
, , .·
(1)_ µmg
. (I) 0.8 g (2) 0.4 g (2) µ[mg-µ(~ F/2)]
(3) 0.5 g (4) ffl'O
[2]
8. .A wagon·of mass M has a block of mass m atttched 12 ... ·.consider. the situatioq shown· in figure, tlnd the
to it as shown in the figure. The coe~cient of. . , . •·tension .in· siring AB COQSlder pu~ley and, strina as
·fnction between the block and wagon is µ. Th~ · fiictio~ess and ~less: · ·
minimum acceleration of the wa~on so : that the
block m does not rail is
0.3.kg
. (t) 3 N ·(2) 2 N .
" (3) . 8 N (4) -~ '
(1) ·K (2) .!:
µ g
13.- A body Qfmass 60 kg is dra~ed ~ithJU$t ~nous}t.·
(4) Mµg force to sum moving on ·a. rough '~urface ' with '
(3) µg
m coefficient of static and ~netic _friction O.S-and 0.4 ·
' '
respectively. On applying th~ same fc;>rce·wbat is the
9. Thr~ bl9Cks of masses 2kg, 4kg· and . 6kg are -acceleration (g =.9.8 m/sec2):
connected by string .and resting .on a frictionless (1) 0.98m/s 2 .
· incline of60° as shown. A force of 120N is applied ·(2) 9.8 m/s2
.upward along the incline to the 6 kg block. If the (3) .54 m/s2
strings are ideal, ~e ratio TtlT2 will be
(g = 10 ms;2) ·
- .292 m/s2
(1) 1 : 1 (2)
. (3) 1 : 3 (4)
,_tH~P✓HlnH/~
Q~
(1) 17N (2) 9N
(3) SN (4) 1 N
11. A block of mass 0.1 kg is held against a wall by
{l) (P + Q sin 0) /(mg+ Q cos 0)
applying a horizontal force of 5 N on the block. If
- the coefficient of friction between the block and the (2) (P cos 8 + Q) / (mg- Q sin 8) ·
. wall is 0.5, the magnitude of the frictional force {3) (P + Q cos 8) /(mg+ Q sin 8)
· acting on the block is (4) (P sin 0-Q) / (mg-Q cos 9) • ·
(1) 2.5 N (2) 0.98 N
(3) 4.9N (4) 0.49 N
7
!
: .A lift is moving downwards with an acceleration 21. A ball of mass 1 kg is released from re~ .'8,shown
equal to acceleration du~ to gravity. A body of mas~ ~en final position of ball on ~k wiH be: (Collision
M kept on the floor of the lift is pulled horizontally. with the wall is elastic)
Ifth~ co-efficient of friction isµ, then the frictional I kg
resistance _offered by the body is
(1) Mg (i) µMg
(3) 2µMg (4) 2.ero
(1) . ✓3 :2 (2) F
[4)
,,,I .
24. A particle is acted upon by a force of constant 29. A ~ comes to, skidding stop "in 1Sm. The force on
magnitud~ which is always perpendicular to the the ~ due to the road is 1000 N. The work done by
· velocity of the particle. The motion of the particle road on the car and car on the road respectively is.
· takes place in a plane. It follows that (1)-15 kJ, zero
(1) its velocity is constant (2). zero, 15 kJ .
(2) its acceleration is COJ1Stant (3) 15 kJ, zero
(3) its k:4ietic e.nergy is constant (4) -15 kJ, 15 kJ
(4) it moves in a straight line
30. A particle is. rel~ from ~ at origin. It move$
25. Two identical balls are projected, one verticaUy up under the influence of potential _field U = x2 ~ 3x,.
and the other at an angle of30° with the horizontal, where U is in Joule and x is in metre. Kinetic energy-
with same initial speed. The potential energy at the at x =2 m will be
hi~est point is in the ratio (I) 2 J . (2) 1 J
(l) 4: 3 (2) 3 : 4 . (3) 1.5 J (4) 0 J
(3) 4: 1 (4) 1 : 4
31. The potential energy of a paf(icle of inass m is given
A particle projected with an initial velocity u at . I . .
26.
by U =-kx 2 for x < 0 and U;:; 0 for x ~ 0. If total
angle 8 from the ground. What is the work done bx _ 2
gravity during the time it reaches the hi . _ . -~ : · · I energy of the particle is E. Then its
Pis:
/!is
Y.
. u p
'
(2) f!-
/E
(I)
-mus 2 sin 2 8
(2)
(4)
v~
j!lfj- - .
(3) 0 (4) ' ave ~ejr force constants as K1 an~
· he work done by external force, when
· sow tched by the same iimount of length,
27. A bl ock of mass m 1s 1 1y pu 'ii:i:J:.;..;,oili'-- . . _
(5)
· . . ted upon by a conserv11tive force
A particle is ac . . .
39
35. A particle of mass 2 kg starts moving in a straight z
f= ( 7i-6J ·
~)N
The work done by $e force when
line with an initial velocity of 2 mis at a constant
acceleration of2 m/s2 • The rate of change Qfkinetic the particle moves from origin (0, 0) to the position .
energy is (-3m, 4m) is given by ·
(I) four times the vel~city at any moment (I) 31 (2) lOJ
(2) two times the displacement at any moment ( ) _ (4) noneofthese
3 451
(3) four tin1es the rate of change of velocity at any
moment An object of mass 10 kg falls from rest thrci~gh a
40.
(4) const,ant throughout vertical distance of 10 m and acquires a velocity of
10 mis. The work done by the push of air on the
2
SECTION-B object is (g == IO m/s ) ·
36. A block of mass m = 0.1 kg is released from a height . (1) . 500 ! (2) -500 J
.of 4 m on a curved smooth surface. On the (3) 250 J (4) -250 J
horizontal smooth surface, it collides with a spring
of force constant 800 Nim. The maximum
41. · A particle is acted upon by a force F -= kx, (k > _O)
compression in spring will be (g = 10 m/s 2) •
where x is displacement of particle. If potential
•mI \___ ~.~~:~:.J energy at origin is zero, then the wtential energy of
_.,,,;,;~~~fS;~~~ the particle varies with x as
+·
(l) 1 cm (2) 5 cm
(3)° 10cm (4) 20c (2)
X
(1)
4Mg
k
(2)
(4)
*·
endent force F = x 2 - 3 newton acts
· ody of mass 2 kg and displaces it from
Mg (4) .
(3) = 5 m. The work done is
k
110 J (2) 80 J
3
38. ·A variable force F starts acting on a block of mass
- 5 kg resting on a smooth horizontal surface. F is (3) · 95 J (4) zero
2
varying with displacement x as shown in F-x curve.
The velocity of body when its displacement is 3m
will be 43. A block of mass 3 kg slides down a rough curved
path from point A as shown. If it stops at C, the work
F(N)
done by friction is (g = l O ms-2j
201-----, A m=3kg
[6]
· 44. A I kg block mov~s towards a lighf spring with a 47. A body of mass M is dropped from a height h on a
velocity of 8 mis. When the spring is compressed by sand floor. If the body penetr11tes x m into the sand, ·
3 m, its momentum becomes half of the original the average resistance offered by the sand to the
momentum. Spring constant of the spring is body is
45. A body of mass 5 kg is kept on rough horizontal 48. The average power of the pump which lifts 20 kg of
surface as shown in figure. The work done by water per second from a well l Om deep and projects
fri~tional force in time interval t =0 to t = 3s is (g := it with a velocity IO mis is (g = IO mls2)
IO ms-2) (1) 9KW (2) 4.5 KW
(3) 2.5 KW (4) 3 KW
[7]
SECTION-II (CHEMISTRY)
. 'SECTION-A
51. Which of the following is a polar molecule?
59 _ . Which of the following is least likely to behave as
(1) XeFi (2) BF3 · Lewis blll!e?
(3) SF◄ (4) SiF◄ (I) H2O (2) NHJ
(3) BFl (4) OH-
52. · Which is correct order of solubiHty in water?
· (I)' Ba(OH)2 <Mg(OH)2
60. In which of the following pairs, the two species are
(2) BaCO3 > CaCO3 is~-structural?
(3) CaSO◄ < MgSO4 (1) BJ'OJ- and XeOJ
(4) Ca(OH)2 < Mg(OH) .
2 (2) SF4 and XeF◄
· (3) sol- and NOJ-
53. Property of the alkaline earth metals that increases (4) BFJ and NFJ
with their atomic number:
(I) Electronegativity .
61. In which of the following molecule dipole moment
(2) Solubility of their hydroxides in water is more than zero but less than one? ·
(3) Solubility of their sulphates in water Nfu (2) Nf3
.(4) . Ionization energy
(4) Bf3
54. The correct order of increasing the following pairs of molecules will
K2~O3, M&CO~. CaCOJ and B t dipole moments for both members?
(1) K2COJ <MgCO3 < CaCO3 NOi (2) NCi and cei
(2) BeCO:i < M$CO3 < K2CO3 (4) Sif4and CQi
(3) BeCOJ < MgCOJ < CaCO3
(4) MgCO3 < BeCO3 < CaCOJ • the following molecules/ions, all the
·qual?
55. Lattice energy of an ionic com (2) SiF4
(1) Charge ori the ion and size of (4) BF4-
(2) Packing of ions only
·(3) Size ofthe ion only In CJF3 lone pair are present at approx:
(4) Charge on the ion only (I) 180° (2) 120°
(3) 90° (4) 60°
56; Among the following which one has the highest
cation to anion size ratio: 65. Which of the following has tetrahedral structure:
(1) CsF . (2) LiF (I) XeF4 (2) HJPo4
(3) . NaF (4) Cs! 3
( ) SF4 (4) ClF◄
57. Solubility of the alkaline earth's metal sulphates in 66. The molecular shapes of SF4, CF4 and XeF4are
water decreases in the sequence:
(I) different with I, 0 and 2 lone pairs of electrons
(I) Ca > Sr> Ba > Mg on the central atom, respectively
(2) Sr> Ca> Mg> Ba 2
( ) different with 0, 1 and 2 Ion~ pairs of electrons
(3) Ba> Mg> Sr> Ca on the central atom, respectively . ·,
(4) Mg> Ca> Sr> Ba 3 th
( ) e same with I, 1 and I lone p~ of electrons
58. · .The dipole moment is zero in: on th e central atoms, respectively · ·
. (1) . Nl:h ·.(4) th .
(2) Nf3 e same with 2, 0and I lone pairs of electrons
(3) SO3 (4) CIF1 ?n the central atom, respectively • .
' . (8)
67. In which one of the following species the ~entral . 75. Which one of the following species does no~ exist
atom has the type of hybridiz.ation which is not the under normal conditions?
same as that present in the other three? (1) Lh
(I) PCls (2) SF◄ (3) Be2
(3) h- (4) SbCls2-
76. Identify the incorrect match.
68. The maximum number of90° angles between bond Name IUPAC Official Name
pair-bond pair of electrons is observed in: · (a) Unnilunium IOI (i) Mendelevium
(I) sp3hybridization (b) Unniltrium 103 (ii) Lawrencium
(2) sp~d2hybridization (c) Unnilhexium 106 (iii) Seaborgium
(3) sp2hybridization (d) Unununnium 111 (iv) - Danristadtium
(4) sp3d hybridisation (1) (a), (i) (2) (b), (ii)
(3) (c), (iii) (4) (d), (iv)
69. In which of the following pairs of molecules/jpns,
· the central atoms have sp2 hybridization? _
77. If n = 6, the correct sequence for filling of
(I) BFJ and NHf (2) NO2- and Nl-JJ electrons will be:
(3) BFJ and NOi'" (4) NH2- and H2O · (1) ns.,... (n-2)f-+ (q- J)d-+ np
ns-+ (n -l)d-+ (n..:. 2)f-+ np .
70. In which of the following molecules th....~,,;1 -+ (n -2)f-+ np-+ (n- J)d
atom does not have sp3hybridizati p(n-l)d-. (n-2)f
(1) SF◄ (2) BF4-
(3) NH/ (4) C e correct order of inc~ing energy of
itals in the atom pf titanium?
71. The bond order in NO is 2.5 wh' · 4s (2) 3s 3p 4s 3d
the
3. Which of following state (4) 4s 3s 3p 3d
these two species?
(1) Bond lerigth in NO+is gr ond period element the correct
(2) Bond length in NO is grea _rder of first ioni:zation enthalpy, is:
(3) Bond length in NO+is equal t '< Be < B < C < N < 0 < F < Ne
(4) Bond length is unpredictable Li <B < Be < C < 0 < N <F < Ne
(3) Li <B <Be<C <N <O<F<Ne
72. The correct order of C--0 bond length among CO, _(4) Li<Be<B<C<O<N<F<Ne
l -
iI COJ 2-, COi is:
.1 (I) CO<COi<COJ2- 80. The element Z = 114 has been discovered recently.
i . (2) COi < COJ:z.-.< CO It will belong to which of the following
1 (3) CO< COJ:z.- < COi . family/group and electronic configuration?
. (4) CO32,- < COi < CO (1) Carbon family, [Rn] 5f1 4 6d 10 7s2 7p2
4
(2) Oxygen family, [Rn] 5fl 4 6d 10 7s; 7p ·
6
73. The molecule having smallest bond angle is: (3) Nitrogen family, [Rn] 5fl 4 6d 10 7s 2 7p
5
(I) NCb . (2) AsCb (4) Halogen family, [Rn] 5t1 4 6d' 0 7s2 7p
(3) SbCb (4) PCb
81. The correct order. of atomic radii in group 13
74. · Which one -of the following compoµnds has the _- elements is:
smallest bond angle in its molecule? (1) B<Af<In<Ga<TI
(1) SOi (2) OHi (2) B < Al <Ga< In < TI
. (3) SH2 (4) NHJ (3) B < Ga< Al < TI < In .
~4) B<Oa<Al<In<TI
. .
82. The pai_r of amphoteric hydroxide is 89. Identify the correct order of the size of the
(1) . Al(OH)~, LiOH .. following:
(2) Be(OH)2, Mg(Oli)l <
(1) Ca2+ K+ <Ar< c1-< s2-
(3) . B(OH)3, B~OH); (2) Ar < ca2+ < K+ < c1- < s2-
(4) Be(0~2~ Zn(OH)2 (3) Ca2+ <Ar< K+ < c1- < s2-
(4) ca2+ < K+ <Ar< s2- < c1-
83 . . \Vhich of the followhtg is the most basic oxi~e?
(1) Se~ (2) Ah03 · 90. . With which of the following electronic
(3) Sb:z03 . (4) BhOl configuration an atom has the lowest ionisation
enthalpy?
.84. In which of the following options the order of : (1) ls2 2s 2 2p3 (2) ls2 2s 2 2p6 3s1
arrangement does not agree with the variation of (3) · ls2 2s2 2p6 (4) ls2 2s 2 2p5
prQperty indicated against it?
(1) . I < Br < Cl < F (increasing electron gain 91. Which o~e of the following ionic species has the
enthalpy) · · · · · greatest proton _affinity to form stable compound?
(2) Li .< N~ <K ~ Rb (increasing metallic radius) · · (1) NH2- (2) P-
(3) · Ap3 + < Mg2+ <Na+< P-(increasing ionic size) (3) 1- (4) HS-
(4) B < C < 0 < N (increasing first io
enthalpy) · :· · " one of the following orders is not in
8~. 2
The species Ar, K+ and Ca + c ·. · e with the property stated against it?
numb~r of eiectrons. In which . > Br2 > h : Bond dissociation energy
incr',_a se?
2 · Br2 > h : Oxidising power
(1) Ca + < K+ < f'\r
2
r > HCl > HF : Acidic property in
(2) K+ <~ < Ca2+
.(3) Ar < K+ < Ca2 + > Br2 > h : Electronegativity
(1) ea2+< .Ar<lC
of the . following arrangements
SECTION-B c1;>rrect orcter of electron gain
86. Which of. the foliowing orders o negative sign) of the given atomic
correctly represented? _~~,.,...'-·-~
·--.:. · ~~!
(1) · H->H+>H (2) Na+<P-<02- .. :: 1) S<O<Cl<F (2) Cl<F<S<O
(3) P->02->Na+ (4) · Al3+>Mg +>N3-2 (3) F<Cl<O<S (4) O<S<F<Cl
87. Which .one · of the f~llowing arrangements 94. The ions 02-, P-, Na+, Mg2+ and Al 3 + are
represents the correct order ofleast negative to most · isoelectronic. Their ionic radii show ·
negative electron gain enthalpy for C, Ca, Al, F and . (1) A significant increase from 0 2- to AI 3 +
O? (2) A significant decrease from 02- to Al 3+
(1) Al< Ca< 0 < C < F (3) An increase from 02- to P- and then decrease
(2) Al < 0 <C < Ca < F from Na+ to A)l+
(3) C < F < 0 < Al < Ca (4) A decrease from 02- to P- and then increase
(4) Ca<Al<C<O<F from Na+ to Al3+
88. Which one of the following arrangements does not
give the correct picture of the trends indicated 95. Which statement is wrong?
against it? (I) Bond energy ofF2 > Ch
( 1) F 2 > Ch > Br2 > h : Bond dissociation energy (2) Electronegativity ofF > Cl
(2) F 2 > Ch > I3r2 > h : Electronegativity (3) F is more o?{idising than Cl
(3) F2 > .Ch >Br > l:z : Oxidizing power
2 (4) Electron affinity of Cl> F
· ( 4) Ch > .F 2 > Br2 > l2 : Electron gain enthalpy
[10)
96. Which of the following elements has the maximum 99. Which of the following ion is the largest in size?
electron affinity? (1) K+ (2) Ca2+
(I) I · (2) Br II s2-
(3) ci- (4)
It
(3) Cl (4) F
100. The electronic configuration of an element is
97. The first ionization potentials (eV) of Be and B ls22s22p6 3s23p3• What is the atomic number of the
respectively are element, which is just below the above element in
(1) 8.29,8.29 (2) 9.32, 9.3~ the periodic table?
(3) 8.29, 9.32 (4) 9.32, 8.29 (1) 33 (2) 34
(3) 36 (4) 49
98. Which one of the following is correct order of the
size of iodine species?
(1) i+ > 1-> I (2) 1-> I> 1+
(4) I > J+ > J-
I•