HSatS

Series SSRR3/3 SET-3

IIIIIIIIHIIIIIIIIIHI
Q.P. Code 56/3/3
Tt^T H. 3rR-5f^R
Roll No.
Candidates must write the Q.P. Code
on the title page of the answer-book.

NOTE
(I) 'JiH'Ml fcF (I) Please check that this question paper
TJB 27 t I contains 27 printed pages.

(II) ^m<mi (II) Please check that this question paper

•X* 33TWf I contains 33 questions.

(III) ^1 3Jk (III) Q.P. Code given on the right hand

Tftsusff 3xR-HfKI«hl side of the question paper should be
written on the title page of the
X answer-book by the candidate.
(IV) wr 3tR frUsHI (IV) Please write down the serial
•z* M£<H, ■3TR-H)f?rlchl if TTH sbHIch number of the question in the
answer-book before attempting it.
(V) frR 15 fFTJ (V) 15 minute time has been allotted to
■HH'M f^T JHI 1? I cFj |c|d<ul read this question paper. The
3
10.15 f^TT ^1^11 I question paper will be distributed
10.15 $ 10.30 at 10.15 a.m. From 10.15 a.m. to
10.30 a.m., the students will
^1 TqFt 3Tk
read the question paper only and
Tl cfrnj |
will not write any answer on the
answer-book during this period.

R$iH (^iPricb)
CHEMISTRY (Theory)
■srf&fKm 37^: 70
Time allowed : 3 hours Maximum Marks : 70

56/3/3-13 1 x/VsA^yWWWWWXAAA/^V^^
P.T.O.

■
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(i) FT $33 3rf$cn$ f /

(U) $ - <s/u£ TTf Vf /

(Hi) &&& $^T 1 $ 16 ^7T $ XPT 1 3^

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(iv) ^7^ $l°zn 17 $ 21 3$$ cf^-3dVd / jMsb 37?¥2
/
(v) ?§^ R- JRR fRsRl 22 $ 28 Hdd rn^-3x1<]q RdRT $ 3 RR $ /
(vi) W- Wd WsRT29 cfflT 30 ^R-3RRT$R JRR $ / RRT4 3$f$ RR $ /
(vii) TsR'S' 1RR $l°RT 31 $ 33 $t$-3xi(ld Xd>H $ RRJ $ / xd<*> RRT 5 37^$ RR $ /
(viii) $ TRRl fc/7>rR 1^71 Jldl $ / <sfu~S $ 3j[df{Tt> 3R^r WTt <du$) $
9^£S> Wd) $ 3TRff7R> RR ddH [^d! RRT $ /

(ix) q T& g'/°cf<^//£7?7 '7</^777^^

(x) <^c3^c?dTf ctlZfn /

<91

16x1=16

1. Ph Id fed ffel-^ $ ^H-1riT 7W[<ft ffelH t ?

(A) co (B) SCN"
•(C) nh3 (D) h20

2. C0CI3.4NH3 WT 4 AgNOs fd<ddd fatfP AgCl ^T ^"fe

s^srffef 1 t:
(A) 6 (B) 4
(C) 3 (D) 7
3. ’HsbHul TT^f 3d Mt 3 PtHfefe?! 3 3 IMf ^t AaH° t ?
(A) Sc (B) Cr
(C) Cu (D) Zn
vaIaMAAt/A^vTWV^VW/WvWVV
56/3/3-13 2

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I
General Instructions:
Read the following instructions carefully and follow them :
(i) This question paper contains 33 questions. All questions are compulsory.
(ii) This question paper is divided into five sections - Section A, B, C, D and E.
(Hi) Section A - questions number 1 to 16 are multiple choice type questions. Each
question carries 1 mark.
(iv) Section B - questions number 17 to 21 are very short answer type questions.
Each question carries 2 marks.
(v) Section C - questions number 22 to 28 are short answer type questions. Each
question carries 3 marks.
(vi) Section D - questions number 29 and 30 are case-based questions. Each
question carries 4 marks.
(vii) Section E - questions number 31 to 33 are long answer type questions. Each
question carries 5 marks.
(viii) There is no overall choice given in the question paper. However, an internal
choice has been provided in few questions in all the sections except Section A.
(ix) Kindly note that there is a separate question paper for Visually Impaired
candidates.
(x) Use of calculators is not allowed.

SECTION A

Questions no. 1 to 16 are Multiple Choice type Questions, carrying 1 mark

each. 16'X.1=16
1. Which of the following ligands is an ambidentate ligand ?
(A) CO (B) SCN “
(C) NH3 (D) h2o

2. On adding AgNO3 solution to 1 mole of CoCl3.4NH3, one mole of AgCl is

precipitated. The secondary valency of Co is :
(A) 6 (B) 4
(C) 3 (D) 7
3. Which of the following elements of 3d series of transition elements has
the lowest AaH° ?
(A) Sc (B) Cr
(C) Cu (D) Zn
56/3/3-13 3 P.T.O.
l£
4. PlHRlRsId 3lf^f?hqI fc|-c||< ;
ch2oh
SOC12
?

OH

CH2 -Cl ch2 - Cl

(A) (B)

Cl OH

CH2OH CHoOH
Cl
(C) (D)

Cl OH

5. \ /~ CH2 - OH fol* fanRlfed 3 3

3Tf^Mi4<=h TFJrfi K^TT ?

(A) CH2MgBr (B) <QJ)- CH2CH2MgBr

(C) MgBr (D) MgBr

6. CH3 - O - CH3 HI af^TT t, ?it ^TT

t:
(A) CH3 - OH + CH3 - I
(B) 2CH3 - OH
(C) 2CH3 -1
(D) ch3 - I + ch4
56/3/3-13 4
KI
4. Consider the following reaction :
CH2OH
SOC12
» 9

OH
The major product obtained is :
CH2 - Cl CH2 - Cl

(A) (B)

Cl OH

CH2OH CHoOH
Cl
(C) (D)

Cl OH

5. Which of the following Grignard reagent will be used with methanal to

prepare CH2-OH ?

(A) CH2MgBr (B) CH2CH2MgBr

(C) MgBr (D) MgBr

6. CH3 - O - CH3 when treated with excess HI gives :

(A) CH3 - OH + CH3 -1
(B) 2CH3 - OH
(C) 2CH3 -1
(D) CH3 - I + CH4

56/5/3-13 5 P.T.O.
®aS5

7. PiHltffisid 41 Rid?! 4 4 ■^k-irr 4<-41h nrH>)Pid

^TTT ?

(A) (C2H5)3N

(B) C2H5 - NH2

(C) (C2H5)2NH

(D) nh2

8. f'b'H fctdlftd ^41 chl<ljl ^-bcTl’ it7! ^tdl 1? ?

(A) E
(B) A
(C) c
(D) D

9. Rb41 14‘X’ 1% Rid'MH ^sbln (hIcK = 3(42 g mol 1) 6% fdd'MH

ITT^ ■HHMllHlO | I (4RM ‘X.’ WR | :

(A) 34-2 g mol1

(B) 57 g mol-1

(C) 114 g mol-1

(D) 3-42 g mol-1

10. 3 min-1 flWfi (k) folft 3I3W ^tfs ^t <£t 3T4-3JT5 t :

(A) 0-693 min
(B) 2-31 min
(C) 6-93 min
(D) 0-231 min

56/3/3-13 6 A/W/vVv-AA/WWv\AAA^/VWVV\/
I
g|
7. Which of the following compounds will not react with benzene sulphonyl
chloride ?
I
f (A) (C2H5)3N
I

(B) c2h5 - nh2

(C) (C2H5)2NH

(D) NH2

8. ‘Scurvy’ is caused by the deficiency of vitamin :

(A) E
(B) A
(C) c
(D) D

9. A 1% solution of solute ‘X’ is isotonic with a 6% solution of sucrose (molar

mass = 342 g mol 11). The molar mass of solute “X’ is :

(A) 34-2 g mol 1

(B) 57 g mol 1

(C) 114 g mol 1

(D) 3-42 g mol 1

-1.
10. The half life of a first order reaction with rate constant (k) of 3 minl is:

(A) 0-693 min

(B) 2-31 min

(C) 6-93 min

(D) 0-231 min

56/3/3-13 7 xA/VWWWWSaA/VwVWAAAa/^^
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sass
11. PlHfdRad wn ?

(B)

(C)

(D) i^R^T

12. sTl^Th <5id RT^I ^Ih^h a^fsbill cb<^> ^=ft ;

(A) o-sTlHl^Plcrfl’l

(B)

(C) m-jfWWd
(D) P-

TT^T THs^n 13 16 fiftr 7777 f 1^1 STfittZT? (A) (TSJT

chHut (R) 3)fchn [chill rpjr f TvR eh)g)
(A), (B), (C) 3m(D) n /
A

(A) artasH (A) afk rrrt (R) ^hfr f a^r rrrt (R), arf^sR (A) <t
oil 1^-11 RRRT t I

(B) arfteiH (A) affr RRRT (R) f, RRg W^T (R), (A)
oMI^I RRRT t I

(C) 34f^SM (A) t, ^FRUT (R) WH | I

(D) (A) RRrT f, RFg RWT (R) t I

56/3/3-13 8 \/W\aAAAaAA/VA/vVA/V^^
11. Which of the following cells is used in hearing aids ?

(A) Dry cell

(B) Mercury cell

(C) Nickel-cadmium cell

(D) Fuel cell

12. Aniline on reaction with Bromine water gives :

(A) o-bromoaniline

(B) 2,4,6-tribromoaniline

(C) m -bromoaniline

(D) p-bromoaniline

For Questions number 13 to 16, two statements are given — one labelled
as Assertion (A) and the other labelled as Reason (R). Select the correct
answer to these questions from the codes (A), (B), (C) and (D) as given
below.

(A) Both Assertion (A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).

(B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not
the correct explanation of the Assertion (A).

(C) Assertion (A) is true, but Reason (R) is false.

(D) Assertion (A) is false, but Reason (R) is true.

56/3/3-15 9 >A/V\a/VVSaAAAa/WwWVAAA^^
P.T.O.
13. (A) : 37T^f AfjjspjyH sfk Aft^V ^T f I

9W7 (R) : ^TT fdtf'Md Wft <di£dl3jf Tl TT3'<?2 fa-N 471 'WH 4-><dl
t
3dIcJSff fad44 ^h^dldl t I

14. (A) : (TN 3 arrWbNT ^TT 5PT Efjai 11

9W7 (R) : w 3 c|fig ^rrar wr «l<o({i t I

15. 37/W^7 (A) : #TM NaOH HIST 3TMTNT #TRKT^

^TTt I

(R) : Arf^rfjFNT 'JtIhTd 3H-dl<q M<2>fd 4><<{| f I

16. 3Tl^3H(A): ®2^T-1-W dyMI ®^'d-l-3TTd' 4>T 3^dT

9W7 (R) : <3<rHI ©i^H-l-STfol 3Tf^NT ^TNi

ysfoldT 3T d< 13d I pJci q, 515^) mH 3TN^r 'sAT'T! t I

^J^TsF

17. ’c^bi'H srHifstTMi^ RiR'N; : 2x1=2

(^) HI

(^) Wsj^A^VWT'/VWWXW^VW^
(CH3CO)2O

56/3/3-13 10
IS
13. Assertion (A) : AmixH and AmixV are zero for an ideal solution.

Reason (R) : The solution which obeys Raoult’s law over the entire
range of concentration is called an ideal solution.

14. Assertion (A) : Rate of reaction decreases with increase in temperature.

Reason (R) : Number of effective collisions increases with increase in

temperature.

15. Assertion (A) : Phenol on reaction with aqueous NaOH gives sodium
phenoxide.

Reason (R) : This reaction supports the acidic nature of phenol.

16. Assertion (A): Boiling point of butan-l-ol is higher than that of

butan-l-amine.

Reason (R) : Being more polar, butan-l-ol forms stronger

intermolecular hydrogen bonds as compared to
butan-l-amine.

SECTION B

17. Write the reactions of glucose with : 2x1=2

(a) HI

(b) (CH3CO)2O

56/3/3-13 11 xA/WsAAA^AAAaAAA^Vs/WS/VV/SA/V
P.T.O.
18. Hlrdd 3lcHHd 57f ^rferrf’Td 4/lffe. I RRH fe-H McbK
2

3121^7

(^) vferfe 3fk fen did few £RT ffeTT TFFR 55 Id 5 cd d ^ifel ^TRTT t ? 55W
41fei< I Id5cdd if fen 5557 55 feW5Tfe few fefecT fecTT | ? 2

19. (^) fe<fl stf^dfedl if, stf^cblTcfr ‘X’ <ii^dl rfe ipn 5>7 Mfldl t, <Tt

STfTdfedl ^T TTrlT^T UHT fft -d Id I I ST^dfedl ^>[ child 551 t ?

(^) ^dl^Q, Pl'Hd 1^3dIfud3^fshdl dfd^d: 5I2W

srfafshdi ^tcft | i srftfjh'Mi -d^vn cOf^iu, I 1+1=2

20. Pi H Rd fed <W|i|R* efit ^juf 3ffr ^feferf : 2x1=2

(^) SMnO^' + 4H+ +

(^) Cr2O2- + 14H++6Fe2+ +

21. IdHfefed TpiRf 3 ^fe-^rr ffetad 4)^1* sn2 srfewn 3 cftsrai

3rfe fed i d-feii sfk cfe ?

37W
Cl
Cl

(75) affsfi- fek ^IT- fWcfei 57 7T^ 35fe§rfe lafeddi Hlf^cKPfl

5fepWT 3rf5fe5T fe 5fe aiftfedl^ddl 551 |? 1+1=2

56/3/3-13 12 W A^WwVWAVwWvMWM

I
 in
18. (a) Define molal depression constant. How is it related to enthalpy of
fusion ? 2

OR

(b) What type of deviation is shown by ethanol and acetone mixture ?

Give reason. What type of azeotropic mixture is formed by that
deviation ? 2

19. (a) In a reaction, if the concentration of reactant ‘X’ is tripled, the rate
of reaction becomes twenty-seven times. What is the order of the
reaction ?

(b) State a condition under which a bimolecular reaction is kinetically

a first-order reaction. Give an example of such a reaction. 1+1=2

20. Complete and balance the following chemical equations : 2x1=2

(a) 3MnO^ + 4H+ ■»

(b) Cr2O2- + 14H+ + 6Fe2+

21. (a) Which halogen compound in the following pair will react faster in
8^2 reaction and why ?

OR
Cl
Cl

(b) Why does the presence of nitro groups at ortho- and para- positions
in haloarenes increase their reactivity towards nucleophilic
substitution reaction ? 1+1=2

56/3/3-13 13 P.T.O.

l
Has?
TaRTg TF

22. (^) 2-51)41 ^F-STWFT $ (±)-®^-2-3lfrr 4 f^T WR

nRfFWFT (SN1 342Fn Sn2) itcft t ? Wl I

(^) 4^TT Rid I t ckl'l<|s|’-?fl'i sfF irfsM dril<l55 if RfPs'MH ^TTg

HTS[ arf^FT W4T ^PTT | ? 2+1=3

23. cfitfe eft arRfen 25% 4 40 Rrz f I

kh nRchRid i Rhd’) 4 3rRifsh4i 80% 4ljn ? 3

[f^n TRI t : log 2 = 0-30, log 3 = 0-48, log 4 = 0-60, log 5 = 0-69]
•* I
24. (^) PiHftffcdd atfHlsb'MISJt 3 HfwrfrRT «^<=h<ul IdRsiU, :

(i) <i5h<-<Dhh srf^fsb^i

(ii) cblr^ 3T^fsb4l

(^) 'Pldld sPiRIhh 4 2/4,6-£l55R4l'£lHTd 4 yrjrF 3jf444<=b ^FT HTH

i 2+1=3

25. PihRiR^T 3rf^lfsh'Ml3Tt if A, B C 'HfcHI't ({IRiQ, : 2x1-=3

2
KCN LiAlH4 HNOo
(^) CH3CH2C1 > A -------- B --------- =-+ C
o°c
no2

(^)
Fe/HCl NaNOo + HC1
■> A------------------- > B
c6h 5°h » C
273 K

56/3/3-13 14 WaVAs//AWv/WvvVA>MA
i
I

SECTION C

22. (a) What type of nucleophilic substitution (S^l or 8^2) occurs in the
hydrolysis of 2-Bromobutane to form (±)-Butan-2-ol ? Give reason.

(b) What happens when chlorobenzene and methyl chloride are

treated with sodium metal in dry ether ? 2+1=3

23. A first-order reaction is 25% complete in 40 minutes. Calculate the value

of rate constant. In what time will the reaction be 80% complete ? 3

[Given : log 2 = 0-30, log 3 = 0-48, log 4 = 0-60, log 5 = 0-69]

24. (a) Write the reactions involved in the following :

(i) Reimer-Tiemann reaction

(ii) Kolbe’s reaction

(b) Name the reagent used in the bromination of phenol to form

2,4,6-Tribromophenol. 2+1=3

25. Give the structures of A, B and C in the following reactions : 2x1 - =3

2

KCN LiAlH4 hno2

(a) CH3CH2C1 + A-------- B +C
o°c
no2
Fe/HCl NaNOo + HOI C6H5OH
(b) ■> A-------------- ------------ * B 6 >c
273 K

56/3/3-13 15 v\A/\/s/VWs/V\AzvV\AaAA/V/\/\/VAAA/
P.T.O.
 1

|g
s3S5

26. 3B IdHldfed WRR^ fel W dTRd ? (d^ <W?) 3x1=3

(d>) ^--41$cb 31 Kd 4 4'-414s5I$S

(n) 4 44did
(d) 4414 £1 d"! d 4 ^r-4l^cb 31 Kd
(,d) 9T14'A-41d 4 i-£ldd^4441

27. 200 g -^Id 4 kb41 3TdW?ft?T 14A'M 5 g dR fact’MH dHTdl W I

300 K di Sd^bl cO^U did 31-84 mm Hg t I klrl’M dd 4d< #>4HM 414b(rid

<£114 4, I 3
(300 K di 4M did = 32 mm Hg)

28. 0-2 M KC1 Idrtdd £t ■dKd'bdi 2-48 x 10-2 S cm 11 ■RT^I WR ■ciM'bdl 3^7

ld4ldd Hldl (a ) M 14bGrid <£ll4i< I 3

fgdT W | :
X° = 73-5 S cm2 moF1
K+

X° = 76-5 S cm2 mol 1

cr

^Fr-3TT^lfid J7?7 7^ 3fa fa? WTl I

29. <isb^lJl dx^ ^^n°f % *f (n - l)d ^^iHl ^lJflc;i<l ^T cTr^l j£?5>

fafw yr xh t I aid: dfwff awfrwr aidFnajf aifdfrxfi dWd

nyr atk arik* ^pr ^ildl f dsn Wh 3TRH ddR M^frl dli

'JllcTl |> | <ishHul tft ai^TRpjt, 31^41 ?rsn Bdl'»i’il

aikfen drdt f I KMnO4 a^T K2Cr2O7 WfFd f I

16 vs/Kvwvwwa^a^^
56/3/3-13
I

81
llJSlkS

26. How will you bring about the following conversions ? (any three) 3x1=3
(a) Benzoic acid to Benzaldehyde
(b) Ethanal to Propanone
(c) Acetophenone to Benzoic acid
(d) Bromobenzene to 1-Phenylethanol

27. A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of

water. It has a vapour pressure of 31-84 mm Hg at 300 K. Calculate the
molar mass of the solute. 3
(Vapour pressure of pure water at 300 K = 32 mm Hg)

28. The conductivity of 0-2 M solution of KC1 is 2-48 x 10’2 S cm 1. Calculate

its molar conductivity and degree of dissociation (a). 3

Given :
z° = 73-5 S cm2 mol 1
K+
X° = 76-5 S cm2 mol 1
cr

SECTION D

The following questions are case-based questions. Read the case carefully and
answer the questions that follow.

29. The involvement of (n - l)d electrons in the behaviour of transition

elements impart certain distinct characteristics to these elements. Thus,
in addition to variable oxidation states, they exhibit paramagnetic
behaviour, catalytic properties and tendency for the formation of coloured
ions. The transition metals react with a number of non-metals like
oxygen, nitrogen and halogens. KM11O4 and KgC^Oy are common
examples.

56/3/3-13 17 W\A^/VtVA/VWV\/W
P.T.O.
 srid^ch" crrI eWn #Ran i^4r Slide? RRRft' % f-®<rlTd>
^TRft f | ^dM 3 4f-^8^ SRjpf RfteS-PT RW

(imperfect shielding effect) % RRTRT RRTPJ 9PW -JL? ^FR RWJ STRHR
R 5bfw <RT RtRT f fsRRR WR SR^RR Wl f I

PthRi feel RW % RfR <{] ;

(RT) RRRTR WR W RtRleh ST^ SrilRb Rffd RRT RTR? RRrf | ? 1

C®) #WRii 4 RWJ STRTTR (size) 3 SO^-cR RR W R7RUT | ? 1

(R) SO-jrcH RTt RRRlfRR | ^RR|U| fgefk
'MShH’JI ^fft WTTJ fllWSJt R7I fw WR RRRT t ? 2

3T2Icn

(R) WRR R, Cr2+ 3TW Fe2+R R RftR-?R RRW STR^TTW t StR RRT ? 2

30. yrf^H 3 ^cr 3fj f i yfnffa otth a-wftrt

3TRTf SWT 3 3TT4^ ^RT KM f | ^T -W
Sdlcf^cp

311^^ STRFfa RT 3RRR Rt rW? dR RR? if RRTRRT IRRTT RRH | : ‘WRR sffr
RtiriRRW rW) I RWff ^1 RRRRT RR SR^fd RR STWH W ?RR Wl RI IRRR
■^TT RRxTT't : RTRfRR, , ejefldcb RR RRRRTR I RTR ReR
^RHT 3 SjRre; srfel' ^Rn t I pH 3TWT W 3 mIWh $ SJltfldi fgcftw RT
WxHKt w ^nrft f 3Tk 3FFT WrJ 3 WR I iWl
RTT ■fR^cftw3! RTKrF f |

56/5/3-13 18 VA/^A/^/sA'Vlzyv'v\^v\/\VW\.vVv'V
ii
The two series of inner transition elements, lanthanoids and actinoids,
constitute the f-block of the periodic table. In the lanthanoids, there is
regular decrease in atomic size with increase in atomic number due to the
imperfect shielding effect of 4f-orbital electrons which causes contraction.

Answer the following questions :

(a) Why do transition metals and their compounds act as good

catalysts ? 1

(b) What is the cause of contraction in the atomic size of lanthanoids ? 1

(c) Define lanthanoid contraction. How does it affect the atomic radii of
the third transition series and the second transition series ? 2

OR

(c) In aqueous media, which is a stronger reducing agent —

Cr2+ or Fe2+ and why ? 2

30. Proteins are the most abundant biomolecules of the living system.
Proteins are the polymers of about twenty different a-amino acids which
are linked by peptide bonds. Ten amino acids are called essential amino
acids. In zwitter ionic form, amino acids show amphoteric behaviour as
they react both with acids and bases.

On the basis of their molecular shape, proteins are classified into two
types : Fibrous and Globular proteins. Structure and shape of proteins can
be studied at four different levels i.e., primary, secondary, tertiary and
quaternary, each level being more complex than the previous one. The
secondary or tertiary structure of proteins get disturbed on change of pH
or temperature and they are not able to perform their functions. This is
called denaturation of proteins.

56/3/3-13 19 \AA/WWVA^^AA/W/v^/^^
P.T.O.
S®5

(^) 34ici^ii'+> iJ,4lhI 3Fcf ■^n |> ? 1

(75) ^4)4l 3dkdl % f?4d< 3^Mpi'+> 4 WI Slf^OIM ? 1

(TT) (i) ^tcjl 4W{ w 4tf^cbl=bl< 4Wl ^T <$^1^1 I

(ii) 41 <114 U5bd°bi 5^ 15>¥ ^5>l< 5tT -dl^ iwr t ? 2x1=2

sjarai

(tt) (i) 4<-ddlrH'+> idfooddl t SH SN i4t ?r4nj

^ii4i t ?

(ii) artr "!{G?d3ildi$s 4 w 4<iHirH«t> 4(K t? 2x1=2

<9^3 ■§?

31. (5?) (i) PiHldferl 3Tf4f4>■Misti 3cMld [riftslU. :

ch2ch3 a) KMnO4 , KOH

(1) o b)H+
71H NaOH^ ,?
(2) CHO + CHo3 - C - CHo
3 II
0
COOH
;L Br2 / FeBro
(3) n —------ ?

56/3/3-13 20 VWvWWsWvxA^/wVWWWVWV
El
Answer the following questions :

(a) What are essential amino acids ? 1

(b) What is meant by zwitter ionic form of amino acids ? 1

(c) (i) Give one example each for Fibrous protein and Globular
protein.

(ii) What type of linkages hold monomers of proteins together ? 2x1=2

OR

(c) (i) What is the structural feature which characterises a reducing

sugar ?

(h) What is the structural difference between nucleoside and

nucleotide ? 2x1=2

SECTION E

31. (a) (i) Write the major product(s) in the following reactions :

ch2ch3 a) KMnO4 , KOH

(1)
b) H+
dilNaOH n
(2) OHO + CHo3 - C - CHo ------------ > ?
II
0
COOH
Br2 / FeBro
(3) —?•

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(ii) pHfdPdd 41 PH fdU WT

COCH3 COCH2CH3
(1) I

(2) 3+2=5

srarai

(^) (i) Pf H fd d PhU, Mi K111 ({IfdM, :

(1) 4 TJe^ - nh2 <l4)«hl«lWH Pk-cH

<lpiifdd WT | I

(2) Wfr HCN WT3T 3rfa

(ii) (1) fdHfdf^d ^>T 3TKTNT ’ddrl sbH

<£1PK :
CHgCOOH, O2N - CH2 - COOH, HCOOH

(2) srfW^n f^v. srfkWF ^r hth R-ifeo. ■.

CH3 - CH = CH - CH2 - CN -4^

CH3 - CH = CH - CH2 - CHO

(iii) 3jfW^n 3 ’Mf^Hf^id 3tfW^T fdftsl^ I 2+2+1=5

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(ii) Give simple chemical tests to distinguish between the

following pairs of compounds :

COCH3 COCH2CH3
(1) and

(2) Pentanal and Pentan-3-one 3+2=5

OR

(b) (i) Give reasons for the following :

(1) In semicarbazide, only one - NH2 group is involved in

the formation of semicarbazone.

(2) Acetaldehyde is more reactive than acetone towards

addition of HON.

(ii) (1) Arrange the following in decreasing order of their acidic

strength :
CH3COOH, O2N - CH2 - COOH, HCOOH

(2) Name the reagent in the following reaction :

?
CH3 - CH = CH - CH2 - CN -—>
CH3 - CH = CH - CH2 - CHO

(iii) Write the reaction involved in Hell-Volhard-Zelinsky reaction.

2+2+1=5
%

56/3/3-13 23 P.T.O.
32. IdHRlfisM 4 3rR ftf RsIU, : 5x1=5

(^) [Co(H20)(CN)(en)2] 2+^t iupachut tfPsIM, I

(u) ■4dic>'+>dcA4 McbK 4F M.'bqkl MTRS ^■>•-$4 WJ 3TRH

Kf, ifdrTl’M -H*4Icl’Mctdl Hjft t ?

(’T) fdHfdfisId 3WTt fjb'Wd IdMIdd (Ao)

[Co(NH3)6]3+, [CoF6]3-
3-, [Co(CN)6]3“

(^) -wWl^cbdi 3TT«pi tera arm ■qr #5^ [Ni(CO)4]

[Ni M<HI'J|> Sb^lsh = 28]

(^) [CoFg]3- sfk [Co(C2O4)3]3“ -4 :

(i) 3Tf^ FSTFft | ?
(ii) 3tx| q-c|9bul rl Jd ?

(^) i^FFg 3 W 3FR t9

(^) 3 d5 5<*]<r^TPl'h fd'-dio t2g sfk Oj!„ 0

■'T^t F Id[<£'■<

(i) A0>P, (ii) Ao < P

33. (^) (i) 25°C Hl fdHfdfed f^.^T. sRd (eipf) :

Zn (s) | Zn2+ (0-001M) I I Cd2+(O-1M) | Cd(s)

i^n W t : E° ,2+/Zn = -0-76V, E° 9 = o-4O V [log 10 = 1]

Zn' cd2-;/Cd

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32. Attempt any five of the following : 5x1=5

(a) Write the IUPAC name of the complex :

[Co(H2O)(CN)(en)2]2+

(b) Why is geometrical isomerism not possible in tetrahedral complexes

having two different types of unidentate ligands coordinated with
the central metal ion ?

(c) Arrange the following complex ions in increasing order of their

crystal field splitting energy (Ao):
[Co(NH3)6]3+, [CoF6]3- [Co(CN)6]3-

(d) Write the hybridization and magnetic character of the complex

[Ni(CO)4] on the basis of valence bond theory.

[Atomic No. : Ni = 28]

3— 3—
(e) Out of [CoFg] and [CofC^O^] , which one complex is :

(i) more stable ?

(ii) the high spin complex ?

(f) What is the difference between an ambidentate ligand and

bidentate ligand ?

(g) Write the electronic configuration of d5 in terms of t2g and e,!g in an

octahedral field when :

(i) Ao>P, and (ii) A0<P

33. (a) (i) Calculate emf of the following cell at 25°C :

Zn(s) | Zn2+(0-001M) | | Cd2+(O-1M) | Cd (s)

Given : E° =- 0-76 V, E°
-O76V, E „ = - 0-40 V [log 10 = 1]
Zn2+/Zn Cd2+/Cd

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(ii) iWT 'sld'I^U, I NaCl faddH

pH fer wr $ 3mrf^T iRft WR fega-srwR f^RT ^nar

|? 3+2=5

3T2I^T

(^) (i) IdHfdfisa stfRfsfRn fcn* ArG° log K^. ifWdd :

Fe (s) + Ag+ (aq) # Fe2+(aq) + Ag (s)
1^TTWt:E° =-044V, E° = + 0-80 V
Fe.2+,
2+/Fe AgVAg
1 F = 96500 C mol-1

(ii) RT3rfR^> fgrte 3ri8JT RTRF

I
(iii) 1 RtRI H2O O2 3 3dd4idRq frH* iRRF) ^RT^ ?
3+l+l=5

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 (ii) State Faraday’s second law of electrolysis. How will the pH of
aqueous NaCl solution be affected when it is electrolysed ? 3+2=5

OR

(b) (i) Calculate the ArG° and log Kf. for the following cell reaction :

Fe (s) + Ag+ (aq) # Fe2+(aq) + Ag (s)

Given: E° „ =-0-44V, E A +/A = + 0-80 V,

= -0-44V, E°
Fe^/Fe
2+/Fe Ag+/Ag
1 F = 96500 C mol 1

(ii) Write any two advantages of the fuel cells over primary and
secondary batteries ?

(iii) How many Faradays are required for the oxidation of 1 mole
ofH2OtoO2? 3+1+1~5

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