QUESTION BANK

CLASS: XII, CHEMISTRY

UNIT 2 SOLUTION
MULTIPLE CHOICE QUESTIONS

(1)Conc,H2SO4 has density of 1.9g mL-¹ and is99% by weight. Calculate the molarity of H2SO4(Mol wt.of H₂SO4= 98gmol-¹

(a) 24M (b) 242M (c) 19.1M (d) 9.8M

(2)A 500g tooth paste sample has 0.2g fluoride concentration.What is the concentration of fluoride in terms of ppm level?
(A) 250 (b) 200 (c) 400 (d) 1000

(3)With increase of temperature, which of these Changes

(a) Molality (b) Weight fraction of solute

(c) Fraction of solute present in water (d) Mole fraction

(4)Calculate the mole fraction of ethylene glycol an aqueous solution containing 20% of glycol by mass

(a) 0.68 (b) 0.068 (c) 0.932 (d)0.0932

(5)The amount of oxalic acid (mol.wt.63) required to prepare 500mLof its 0.10N solution is
(a) 0.315g (b) 3.150g

(c) 6.300g (d) 6.100g

(6) A supersaturated solution is a metastable state of solution in which solute concentration

(a) is equal to the solubility of that substance in water (b) exceeds its solubility

(c) less than its solubility (d) continuously changes.

(7) The solubility of gas in liquid increases with

(a) increase in temperature (b) reduction of gas pressure(c) decrease in temperature (d) amount of liquid taken.

(8)The Henry's law constant for the solubility of N₂ gas in water at 298K is 100000atm.The mole fraction of N₂ in air is 0.8.
The number of moles of N₂ from air dissolved in 10 moles of water at298K and 5atm pressure is

(a) 4.0× 10 -4(b) 5.0x10 4 (c) 4.0× 10-5(d) 4.0x10-6

(9)The volume of 0.1M H₂SO4required to neutralise 50ml.of 0.2M NaOH solution is

(a) 25Ml (c) 75ml.

(b) 50ml (d) 100mL

(10) 3.65grams of HCI is dissolved in 16.2g of water.The mole fraction of HCI in the resulting solution is

(a) 0.4 (b) 0.2 (c) 0.3 (d) 0.1

(11) Which of the following does not show positive deviation from Raoult'sLaw?
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(a) Benzene-chloroform (b) Benzene-acetone

(c) Benzene-ethanol (d) Benzene-carbon tetrachloride.

(12)Value of Henry's constant KH is

(a) Increases with increase in temperature (b) Decreases with increase in temperature
(c) Remains constant (d) First increases then decreases.

(13)Solubility of deliquescent substance in water is generally

(a) high (c) moderate

(b) low (d) cannotbe predicted.
(14)A beaker contains a solution of substance 'A'. Precipitation of substance 'A' takes place when small amount of 'A' is
added to the solution. The solution is

(a) saturated (b) supersaturated

(c) unsaturated (d) concentrated

(15)At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is
(a) less than the rate of crystallisation (b) greater than the rate of crystallisation

(c) equal to the rate of crystallisation (d) zero

16 Which one of the following is not the example of gaseous solutions?

(A) Air
(B) Humidity
(C) Carbonated drink
(D) Dust in air

17 Which of the following determines physical state of the solution?

(A) Nature of solute
(B) Nature of solvent
(C) Both A and B
(D) None

18
Alloys are the example of which type of solution?
(A) Gas in solid
(B) Solid in solid
(C) Solid in gas
(D) Liquid in solid

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19 Atmospheric pollution is expressed in terms of:
(A) ppm
(B) Mole fraction
(C) Mass percentage
(D) Molality

20 Which one of the following is temperature dependent?

(A) Mass percentage
(B) Molality
(C) Mole fraction
(D) Molarity
21
What is the molality of 2.5 g of ethanoic acid (CH3COOH) in 75 g of benzene?
(A)
0.556mol kg-1
(B) 0.556mol g-1
(C) 0.055mol kg-1
(D) 0.055mol g-1

22
Solubility of gas in liquid increases with
(A) Decreasing pressure
(B) Increasing pressure
(C) Increasing temperature
(D) Increasing temperature and decreasing pressure
23 The value of Henry’s constant KH is
(A) Greater for gases with higher solubility.
(B) Greater for gases with lower solubility.
(C) Constant for all gases.
(D) Not related to the solubility of gases.

24 Value of Henry’s constant KH

(A) Increases with increase in temperature.
(B) Decreases with increase in temperature.
(C) Remains constant.
(D) First increases then decreases

25. Considering the formation, breaking and strength of hydrogen bond, predict which of the
following mixtures will show a positive deviation from Raoult’s law?

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 (A) Methanol and acetone.
(B) Chloroform and acetone.
(C) Nitric acid and water.
(D) Phenol and aniline.
26. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to
(A) Low temperature
(B) Low atmospheric pressure
(C) High atmospheric pressure
(D) Both low temperature and high atmospheric pressure

27. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid
solvent does not depend upon
(A) Temperature
(B) Nature of solute
(C) Pressure
(D) Nature of solvent

28. A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when
small amount of ‘A’ is added to the solution. The solution is
(A) Saturated
(B) Supersaturated
(C) Unsaturated
(D) Concentrated

29. At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is __________.
(A) Less than the rate of crystallisation
(B) Greater than the rate of crystallisation
(C) Equal to the rate of crystallisation
(D) Zero

30. Which of the following units is useful in relating concentration of solution with its vapour
pressure?
(A) Mole fraction
(B) Parts per million
(C) Mass percentage
(D) Molality

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31 A molar solution is one that contains one mole of a solute in
(A) 1000 g of the solvent
(B) one litre of the solvent
(C) one litre of the solution
(D) 22.4 litre of the solution
32 In which mode of expression, the concentration of a solution remains independent of temperature?
(A) Molarity
(B) Normality
(C) Formality
(D) Molality
33 The increase in the temperature of the aqueous solution will result in its
(A) Molarity to increase
(B) Molarity to decrease
(C) Mole fraction to increase
(D) Mass % to increase
34 KH value for Ar(g), CO2(g), HCHO(g) and CH4(g) are 4.039, 1.67, 1.83 × 10–5, and 0.143, respectively.
Arrange these gases in the order of their increasing solubility (A) HCHO < CH4 < CO2 < Ar
(B) HCHO < CO2< CH4 < Ar
(C) Ar < CO2< CH4< HCHO
(D) Ar < CH4 < CO2< HCHO
35 A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount of
‘A’ is added to the solution. The solution is
(A) saturated
(B) supersaturated
(C) unsaturated
(D) concentrated
36 If two liquids A and B form minimum boiling azeotrope at some specific composition then
(A) A–B interactions are stronger than those between A–A or B–B.
(B) Vapour pressure of solution increases because more number of molecules of liquids A and B can escape
from the solution.
(C) Vapour pressure of solution decreases because less number of molecules of only one of the liquids escape
from the solution.
(D) A–B interactions are weaker than those between A–A or B–B.
37 For a dilute solution, Raoult’s law states that
(A) The lowering of vapour pressure is equal to the mole fraction of solute.
(B) The relative lowering of vapour pressure is equal to the mole fraction of solute. (C) The relative lowering of
vapour pressure is proportional to the amount of solute in solution.
(D) The vapour pressure of the solution is equal to the mole fraction of the solute.
38 . For a dilute solution, Raoult’s law states that (
A) The lowering of vapour pressure is equal to the mole fraction of solute.
(B) The relative lowering of vapour pressure is equal to the mole fraction of solute. (C) The relative lowering
of vapour pressure is proportional to the amount of solute in solution.
(D) The vapour pressure of the solution is equal to the mole fraction of the solute
39 Value of Henry’s constant KH is
(A) Increases with increase in temperature.
(B) Decreases with increase in temperature
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 (C) Remains constant
(D) First increases then decreases.
40 Which of the following units is useful in relating concentration of solution with its vapour pressure?
(A) Mole fraction
(B) Parts per million
(C) Mass percentage
(D) Molality
41 Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures
will show a positive deviation from Raoult’s law?
(A) Methanol and acetone.
(B) Chloroform and acetone.
(C) Nitric acid and water.
(D) Phenol and aniline.
42 If two liquids A and B form minimum boiling azeotrope at some specific composition, then.
(A) A–B interactions are stronger than those between A–A or B–B.
(B) vapour pressure of solution increases because more number of molecules of liquids A and B can escape
from the solution.
(C) vapour pressure of solution decreases because less number of molecules of only one of the liquids escape
from the solution.
(D) A–B interactions are weaker than those between A–A or B–B

43 Which of the following condition is not satisfied by an ideal solution?

(a) ΔHmixing = 0
(b) ΔVmixing = 0
(c) Raoult’s Law is obeyed
(d) Formation of an azeotropic mixture
44 Mole fraction of glycerine C3H5(OH)3 in solution containing 36 g of water and 46 g of glycerine is
(a) 0.46
(b) 0.40
(c) 0.20
(d) 0.36
45 Out of molality (m), molarity (M), formality (F) and mole fraction (x), those which are independent of
temperature are
(a) M, m
(b) F, x
(c) m, x
(d) M, x

46 Match the Column I with Column II and mark the appropriate choice.
Column I Column II
A) i) *
B) p0-ps ii)CRT
C) m iii) Lowering in vapour pressure
D) iv) No. of gram mole of solute per Kg solvent

a). A -> ii B -> iii C ->i D ->iv

b). A -> ii B -> iii C ->iv D ->i
c). A -> ii B ->i C ->iv D ->iii
d). A -> iii B -> ii C ->I D ->iv

47 What will be the molarity of 30ml of 0.5M H2SO4 solution diluted to 500ml?
a. 0.3M
b. 0.03M
c. 3M
d. 0.103M
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48 Solubility of a substance is it’s maximum amount that can be dissolve in a specified amount of solvent.It depends
upon
i) nature of solvent
ii) nature of solute
iii) temperature
iv) amount of solvent
a. i, ii & iii
b. I, iii & iv
c. I& iv
d. I, ii, iii & iv
49 People taking lot of salt experience puffiness or swelling of the body due to
a. water retention in tissue cells and intercellular spaces because of osmosis
b. water loss from cells through skin tissue
c. capillary action of water through skin pores
d. excessive thrust and drinking more water
50 What is the mass percentage of carbon tetrachloride if 22g of benzene is dissolve in 122g of carbon tetrachloride ?
a. 84.72%
b.15.28%
c.50%
d.44%
51 According to Henry’s law the partial pressure of gas in vapour phase is proportional to the mole fraction of the gas in
the solution. For different gases the correct statement about henry’s constant is
a .higher the value of KH at a given pressure higher is the solubility of the gas
b.higher the value of KH at a given pressure lower is the solubility of the gas
c.KH is not a function of nature of the gas
d.KH value for all gasses is same at a given pressure

52 When a solution of CHCl3 is mixed with a solution of acetone ∆ is

a. Positive
b. Negative
c. zero
d. cannot be predicted
53 Thelubricating action of an oil is more if it possesses
a. high vapour pressure
b. low vapour pressure
c. high surface tension
d. high density
54 During the evaporation of liquid
a. the temperature of the liquid will rise
b. the temperature of liquid will fall
c. may rise or fall depending on the nature
d. the temperature remains unaffected
55 Mole fraction of C3H5(OH)3in a solution of 36g of water and 46g of glycerine is
a. 0.46
b. 0.20
c. 0.36
d. 0.40
56 Increase of temperature of an aqueous solution will cause
a. decrease in molality
b. decrease in molarity
c. decrease in mole fraction
d. decrease in %(w/W)
57 Which of the following mixture will form maximum boiling azetrope ?
a. conc and water
b. acetone and benzene
c. OH and O
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 d. acetone and
58 The Henry’s law is applicable when
a. the gas under goes association or dissociation in solution
b. the gas undergoes any chemical change
c. the pressure of the gas is not too high and temperature is not too low
d. all of the above
59 An azeotropic solution of two liquids has boiling point lower than either of them when it
a. shows negative deviation from Raoult’s law
b. shows no deviation from Raoult’s law
c. shows positive deviation from Raoult’s law
d. is saturated
60 The factors ∆ / represents
a. molality
b. normality
c. formality
d. morality

61 Value of Henry’s constant KH

a) Increases with increase in temperature
b) Decreases with increase in temperature
c) Remains constant
d) First increases then decreases

62 Scuba divers may experience a condition called ______. To avoid this, the tanks used by scuba scuba divers are filled
with_______.
a) Migraines , Hydrogen
b) Cramps , Nitrogen
c) Nausea , Oxygen
d) Bends , Helium
63 The vapour pressure of two liquids “P” and “Q” are 80 and 60 torr, respectively. The total vapour pressure of solution
obtained by mixing 3 moles of P and 2 moles of Q would be
a) 72 torr
b) 140 torr
c) 68 torr
d) 20 torr

64) Which of the following mixture is (are) called solution ?

i) Water + Ammonia
ii) Water + Acetone
iii) Acetone + Alcohol
iv) Hexane + Water
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 a) (i), (ii) and (iii)
b) (i) , (iii) and (iv)
c) (i) and (iv)
d) (ii) and (iii)

65) The system that forms maximum boiling azeotrope is

a) Carbon disulphide – Acetone
b)Benzene- Toluene
c)Acetone – Chloroform
d) n-hexane – n-heptane

66) The molarity of the solution containing 7.1 g of Na2SO4 in 100 ml of aqueous solution is
a) 2M
b) 0.5 M
c) 1M
d) 0.05M

67) Which of the following statements is correct

a) A solution in which no more solute can be dissolved at the same temperature and pressure is called a saturated
solution
b) An unsaturated solution is one in which more solute can be dissolved at the same temperature.
c) The solution which is in dynamic equilibrium with undissolved solute is the saturated solution.
d) The minimum amount of solute dissolved in a given amount of solvent is its solubility.

6 8) Which is an application of Henry’s law ?

a) Spray paint
b) Bottled water
c) Filling up a tyre
d) Soft drinks (soda)

69) Which of the following liquid pairs shows a positive deviation from Raoult’s law?
a) Water-Nitric acid
b) Benzene-Methanol
c) Water-Hydrochloric acid
d) Acetone-Chloroform

70) The relative lowering of the vapour pressure is equal to the ratio between the number of
a) Solute molecules to the solvent molecules

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 b) Solute molecules to the total molecules in the solution
c) Solvent molecules to the total molecules in the solution
d) Solvent molecules to the total number of ions of the solute

71) Which of the following statements, regarding the mole fraction (x) of a component
in solution, is incorrect?
(a) 0 ≤ x ≥1
(b) x&lt; 1
(c) x is always non-negative
(d) None of these

72.) Equal masses of methane and oxygen are mixed in an empty container at 25°C.
The fraction of the total pressure exerted by oxygen is
(a) 1/2
(b) 2/3
(c) 3/1
(d) 1/3

73.) If two liquids A and B form minimum boiling azeotrope at some specific composition then
(a) A – B interactions are stronger than those between A – A or B – B
(b) vapour pressure of solution increases because a greater number of molecules ofliquids A and B can escape from the solution.
(c) vapour pressure of solution decreases because a smaller number of molecules of only one of the liquids escape from the
solution
(d) A – B interactions are weaker than those between A –A or B – B
74.) Someone has added a nonelectrolyte solid to the pure liquid but forgot thatamong which of the two beakers he has added
that solid. This problem can besolved by checking
(a) relative lower in vapour pressure
(b) elevation in boiling point
(c) depression in Freezing point
(d) all above

75.) Consider a and b are two components of a liquid mixture, their correspondingvapour pressure (mmHg) are respectively
450 and 700 in pure states and totalpressure given is 600. Then corresponding composition in liquid phase will be
(a) 0.4, 0.6
(b) 0.5, 0.5
(c) 0.6, 0.4
(d) 0.3, 0.7

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76 Which of the following is not a colligative property?
(a) Elevation in boiling point
(b) Depression in freezing point
(c) Lowering in vapour pressure
(d) Osmotic pressure.

77 The molal elevation constant is the ratio of elevation in boiling point to

(a) Molarity
(b) Boiling point of pure liquid
(c) Mole fraction of solute
(d) Molality of solution

78 Isotonic solutions have

(a) Same boiling point
(b) Same vapour pressure
(c) Same melting point
(d) Same osmotic pressure

79 What happens when blood cells are placed in pure water?

(a) The fluid in blood cells rapidly moves into water
(b) The water molecules rapidly move in to blood cells
(c) The blood cells dissolve in water
(d) No change takes place

80 Solution A contains 1 g of urea in 100 mL of solution and solution B contains 2 g of glucose in 100 mL solution.
Point out the correct statement:
(a) Boiling point of solution A will be less than solution B.
(b) Freezing point of solution A will be lower than solution B.
(c) Both will have same freezing point and boiling point.
(d) Osmotic pressure of solution A will be less than solution B
81 The mass of glucose that would be dissolved in 100 g of water in order to produce the same lowering in vapour
pressure as produced by dissolving 1.5 g of urea in 50 g of water is
(a) 10 g
(b) 0.6 M
(c) 15 g
(d) 9 g.

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82 The amount of solute (molar mass 60 gmol-1) that must be added to 80 g of water so that the vapour pressure of
water is lowered by 10% is
(a) 30 g
(b) 60 g
(c) 120 g
(d) 12 g

83 Colligative properties depend on

(a) The nature of solute particles dissolved in solution
(b) Number of solute particles in solution
(c) The physical properties of the solute particles dissolved in solution
(d) The nature of solvent particles.

84 Reverse osmosis is a process,

(a) In which applied pressure to the solution side, is larger than the osmotic pressure.
(b) In which solvent moves from solution of higher concentration to solution of lower concentration.
(c) Which is used for desalination of sea water.
(d) All of the above.

85 On dissolving 3.24 g of Sulphur in 40 g of benzene, boiling point of solution was higher than that of benzene by
0.81 K, Kb for benzene is 2.56 K Kg mol-1. The molecular formula of Sulphur is
(a) S2
(b) S4
(c) S6
(d) S8

86 An aqueous solution boils at 100.512 0C. the freezing point of the solution is (given Kf = 1.86 K m-1 and Kb =
0.512 K m-1).
(a) 0.93 0C
(b) - 1.86 0C
(c) - 0.93 0C
(d) 1.86 0C

87 If the molality of the dilute solution is doubled, the value of the molal elevation constant (Kb) will be
(a) Doubled
(b) Halved
(c) Remains unchanged
(d) Becomes four times

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 88 The amount of urea to be dissolved in 500 g of water to produce a depression of 0.186 0C in the freezing point is
(Kf for water = 1.86 Km-1)
(a) 0.6 g
(b) 60 g
(c) 3 g
(d) 6 g

89 Which of the following statements is not correct?

(a) Osmotic pressure is directly proportional to molar concentration.
(b) A hypertonic solution will be less concentrated with respect to other solution.
(c) Isotonic solutions have same molar concentration.
(d) Osmotic pressure depends upon temperature.

90 What happens to freezing point of benzene when naphthalene is added?

(a) decreases
(b) increases
(c) remains unchanged
(d) first decreases and then increases.

91. Consider the following statements below:-

Which statement(s) is /are true.
1. Hydration is a special case of solvation I which solvent is water.
2. The Oxygen end of water molecule is attracted toward cation of the salt.
3. The hydrogen end of water molecule is attracted toward anion of the salt.
a) 1 only
b) 2 only
c) 2 and 3 only
d) 1 , 2 and 3.
92. The vapour pressure of pure water at 85*C is 434 torr. What is the vapour pressure at 85*C
Of a solution prepared from 100 ml of water ( density=1.00g/ml) and 150 ml of diglyme(C6H14O3)
Which is a non-volatile substance.
a) 361 torr
b) 390 torr
c) 425 torr
d) 388 torr
93. The vapour pressure of a solution containing a non-volatile solute is directly proportional to:-
a) Molality of the solvent
b) Osmotic pressure of the solute
c) Mole fraction of solvent
d) Mole fraction of solute.
94. If 4.27g of Sucrose ( C12H22O11 0 ) dissolved in 15.2g of water, what will be the boiling point
Of the resulting solution? ( kb for water= 0.512*C/m )
a) 101.64*C
b) 100.42*C
c) 99.63*C
d) 100.8*C
95. A solution is made by dissolving 9.81g of a non-volatile non-electrolyte solute in 90.0g of water
Boiled at 100.37*C at 760 mmHg. What is the approximate molecular waight of the substance.
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( kbfor water=0.51C/m )
a) 240 g/mol
b) 150 g/mol
c) 79 g/mol
d) 61 g/mol
96. Calculate the osmotic pressure associated with 50.0 g of an enzyme of molecular weight
98000g/mol dissolved in water to give 2600 ml of solution at 30.0C.
a) 0.484 torr
b) 1.68 torr
c) 3.71 torr
d) 2.48 torr
97. In reverse osmosis,
a) A pressure larger than osmotic pressure is applied on the solution side
b) A pressure larger than osmotic pressure is applied on the solvent side
c) A pressure smaller than osmotic pressure is applied on the solution side
d) A pressure smaller than osmotic pressure is applied on the solvent side.

98. The shrinking of the vegetables kept in the salt water is due to:
a) The depression in the vapour pressure of water.
b) The elevation in the boiling point of water
c) The depression in the freezing point of water
d) Osmois
99. The decrease in the freezing point of solvent in the presence of a non-volatile solute is a consequence of:
a) Zero vapour pressure of solute
b) The elevation in the vapour pressure of solvent in presence of the solute
c) The lowering in the vapour pressure of solvent in presence of the solute
d) None of the above.

100. During depression of freezing point in a solution, the following are in equilibrium
a) Liquid solvent , solid solvent
b) Liquid solvent , solid solute
c) Liquid solute , solid solute
d) Liquid solute , solid solvent

101. Equimolal solutions in the same solvent have:-

a) Same boiling point but different freezing point
b) Same freezinh point but different boiling point
c) Same boiling point and same freezing point
d) Different freezing and boiling point.

102. 18g of glucose is added to 178.2g of water. The vapour pressure of water for this aqueous
Solution at 100C is
a) 759.00 torr
b) 7.60 torr
c) 76.00 torr
d) 752.40 torr

103. When mercuric iodide is added to the aqueous solution of potassium iodide then
a) Freezing point raised
b) Freezing point is lowered
c) Freezing point does not changed
d) Boiling point does not changed

104. Which of the following statement is correct?

a) 0.1m urea has low freezing point than 0.1m glucose solution
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 b) 0.1m urea has high freezing point than 0.1m glucose solution
c) Both the solution have the same freezing point
d) not predictable without data.

105. 0.1 M aqueous solution of glucose at 300K is isotonic with unknown concentration of
Urea solution at 400K. Then what is the concentration of that Urea solution?
a) 0.75
b) 0.075
c) 0.1
d) 0.01.

.
106.Colligative properties depend upon:
a) The type of solute particles b) The number of Solute particles c) The Number of Solvent particles d) Both the type
and number of solute particles

107.The boiling point elevation is defined as:

a) Tb - Tbo b) Tb + Tbo c) Tbo - Tb d) Tbo × Tb

108.What is the boiling point elevation ( ) of a solution containing 255 grams of non-electrolyte sucrose (molar mass=342
g/mole) in 812 g of water (Kb(water)= 0.520 oC/m)?
a) 0.477° b) 4.77° c) 0.047° d) 477.0°
o
109. The normal freezing point of ethanol is -117.30 C. How many grams of electrolyte KF (molar mass=58.1 g/mole) must be
added to 35.0 g of ethanol (Kf(ethanol)=1.99 oC/m) to change its freezing point to -120.25oC?
a) 151g b) 0.53g c) 1.51g d) 50g
110.At 75oC, the vapour pressure of pure water is 39 kPa. Which one of the following is the most likely vapour pressure for a 1.5
M solution of sucrose (aq) at the same temperature?
a) 37kPa b) 39kPa c) 0kPA d) 41kPa
111. State the van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide, Ba(OH)2
a) 0 b) 1 c) 2 d) 3
112.A cell is bathed is a solution that has a greater osmolarity than that of the cytosol. This solution is best described as which
one of the following?
a) Isotonic b) Hypertonic c) Hypotonic d) None of the above
113.Which observation(s) reflect(s) colligative properties?
(I) A 0.5 m NaBr solution has a higher vapour pressure than a 0.5 m BaCl2 solution.
(II) A 0.5 m NaOH solution freezes at a lower temperature than pure water.
(III) Pure water freezes at a higher temperature than pure methanol.
a) only I b) only II c) only III d) I and II
114.Colligative properties depend on
a) the nature of the solute particles dissolved in solution.
b) the number of solute particles in solution.
c) the physical properties of the solute particles dissolved in solution.
d) the nature of solvent particles
115.The unit of ebulioscopic constant is
a) K kg mol–1 or K (molality)–1
ZIET, Bhubaneswar, 5-Oct-21 Page 15 of 26
 b) mol kg K–1 or K–1(molality)
c) kg mol–1 K –1 or K–1 (molality)–1
d) K mol kg–1 or K (molality)
116.In comparison to a 0.01 M solution of glucose, the depression in freezing pointof a 0.01 M MgCl2 solution is
a) the same b) about twice c) about three times d) about six times
117. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because
a) it gains water due to osmosis.
b) it loses water due to reverse osmosis.
c) it gains water due to reverse osmosis.
d) it loses water due to osmosis.
118.At a given temperature, osmotic pressure of a concentrated solution of a substance
a) is higher than that at a dilute solution.
b) is lower than that of a dilute solution.
c) is same as that of a dilute solution.
d) cannot be compared with osmotic pressure of dilute solution.
119.The values of Van’t Hoff factors for KCl, NaCl and K2SO4 , respectively, are
a) 2, 2 and 2 b) 2, 2 and 3 c) 1, 1 and 2 d) 1, 1 and 1
120.Relative lowering of vapour pressure is a colligative property because
a) It depends on the nature of the solute molecules.
b) It depends on number of particles of electrolyte solute in solution and does not depend on the nature of the solute particles.
c) It depends on the concentration of a non-electrolyte solute in solution as well as on the nature of the solute molecules.
d) It depends on the concentration of an electrolyte or nonelectrolyte solute in solution as well as on the nature of solute
molecules.

121 . 200mL of an aqueous solution of a protein contains its 1.26 g. The osmotic pressure of this solution at300 K is
found to be 2.57 × 10–3 bar. The molar mass of protein will be (R=0.083Lbarmol–1K–1)

(a)51022gmol–1 (b)122044gmol–1(c)31011g mol–1 (d)61038g mol–1

122 . If molality of the dilute solution is doubled, the value of molal depression constant (Kf)will be
(a) halved (b)tripled (c)unchanged (d)doubled.

123 Pure water can be obtained from sea water by

(a)centrifugation (b)plasmolysis (c) reverse osmosis (d)sedimentation.

124 If 0.1 M solution of glucose and 0.1 M solution of urea are placed on two sides of the semipermeable membrane to
equal heights, then it will be correct to say that
(a) There will be no net movement across the membrane
(b) Glucose will flow towards glucose solution
(c) Urea will flow towards glucose solution
(d) Water will flow from urea solution to glucose.

125 Duringosmosis,flowofwaterthroughasemipermeablemembraneis
(a) Fromsolutionhavinglowerconcentrationonly
(b) Fromsolutionhavinghigherconcentrationonly
(c) from both sides of semipermeable membranewithequalflowrates
(d) from both sides of semipermeable membranewithunequalflowrates.
126 Therelationshipbetweenosmoticpressureat273Kwhen10gglucose(p1),10gurea(p2),and10gsucrose(p3)aredissolvedin25
0mLofwateris
(a)p2>p1>p3 (b)p2>p3>p1(c)p1>p2>p3 (d)p3>p1>p2

ZIET, Bhubaneswar, 5-Oct-21 Page 16 of 26

127 A 5%solutionofcanesugar(mol.wt.=342)is isotonic with 1% solution of a substance X. Themolecularweightof
Xis
(a)68.4 (b)171.2 (c)34.2 (d)136.8

128 Therelativeloweringofthevapourpressureisequaltotheratiobetweenthenumberof
(a) Solutemoleculestothesolventmolecules
(b) Solutemoleculestothetotalmoleculesinthesolution
(c) Solventmoleculestothetotalmoleculesinthesolution
(d) Solventmoleculestothetotalnumberofionsofthesolute.
129 Thefreezingpointdepressionconstant(Kf)ofbenzeneis5.12Kkgmol–1.Thefreezingpointdepression for the solution of
molality 0.078 mcontaining a non-electrolyte solute in benzene is(roundedoffuptotwodecimalplaces)
(a)0.20K (b)0.80K (c)0.40K (d)0.60 K

130 An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because

(a) it gains water due to osmosis.

(b) it loses water due to reverse osmosis.

(c) it gains water due to reverse osmosis.

(d) it loses water due to osmosis.

131 The molal elevation constant depends upon
(a) nature of solute.
(b) nature of the solvent.
(c) vapour pressure of the solution.
(d) enthalpy change.
132 Equimolar solutions in the same solvent have
(a) Same B.Pt but different F.Pt
(b) Same F. Pt, but different B.Pts.
(c) Same Boiling and same freezing point
(d) Different boiling and different freezing points.
133 If an aqueous solution of glucose is allowed to freeze, then crystals of which substance will be separated and first?
(a) glucose
(b) water
(c) both of these
(d) none of these
134 Which of the following statements is false?
(a) Units of atmospheric pressure and osmotic pressure are the same.
(b) In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower
concentration of solute to a region of higher concentration.
(c) The value of molal depression constant depends on nature of solvent.
(d) Relative lowering of vapourpressure, is a dimensionless quantity.
135 At a given temperature, osmotic pressure of a concentrated solution of a substance _____________.
(a) is higher than that at a dilute solution.
(b) is lower than that of a dilute solution.
(c) is same as that of a dilute solution.
(d) cannot be compared with osmotic pressure of dilute solution.

ZIET, Bhubaneswar, 5-Oct-21 Page 17 of 26

136 Ideal solutions are formed when its components
(a)Have zero heat of mixing only
(b)Have zero volume change on mixing only
(c)Have zero heat of mixing and zero volume change on mixing
(d)Have strong force of attraction than individual components
137 The solubility of a gas in a liquid increases with
(a) Increase in temperature
(b) Decrease in pressure
(c) Decrease in temperature and increase in pressure
(d) Amount of liquid taken
138 A molal solution is one that contains one mole solute in
(a) 1 L of solution
(b) 1 L of solvent
(c) 1 kg of solution
(d) 1 kg of solvent
139 The molarity of pure water is
(a) 100M
(b) 55.6M
(c) 50 M
(d) 18 M
140 Two solutions of a substance (non electrolyte) are mixed in the following manner. 480 mL of 1.5 M first
solution + 520 mL of 1.2 M second solution. What is the molarity of the final mixture?
(a) 1.20 M
(b) 1.344 M
(c) 1.50 M
(d) 2.70 M
141 With increase in temperature, which of these changes?
(a) molality
(b) mole fraction of solute present in water
(c) weight fraction of solute
(d) mole fraction

142 The total volume of the solution may not be equal to the sum of volumes of solute and solvent. This is because
(a) volume depends on temperature
(b) solute particles may occupy empty space structure of liquids
(c) solute particles are larger in size than solvent
(d) all of these
143 Oxygen molecules has less solubility in water. This is because the oxygen molecule is
(a) non polar in nature
(b) polar in nature
(c) strong electrolyte
(d) amphoteric in nature
144 An aqueous solution of glucose is 10% in strength. The volume in which 1 gm mole of it is dissolved will be
(a) 0.9 Litre (b) 1.8 Litre (c) 9 Litre (d) 18 Litre
145 When ethanol mixes in cyclohexane; cyclohexane reduces the intermolecular forces between ethanol
molecules. In this, liquid pair shows?
(a)No deviation from Raoults law
(b) Positive deviation by Raoult's law
(c) Negative deviation from Raoults law
(d) Decrease in volume
146 A 500 g tooth paste sample has 0.2 g fluoride concentration. What is the concentration of F in terms
of ppm level
(a) 200 (b) 250 (c) 400 (d) 450
147 At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is
(a) less than the rate of crystallisation
(b) greater than the rate of crystallisation
(c) equal to the rate of crystallisation
(d) zero
148 Maximum amount of a solid solute that can be dissolved in a specified
amount of a given liquid solvent does not depend upon
(a) temperature (b) nature of solute
(c) pressure (d) nature of solvent
149 The value of Henry’s constant KH is
ZIET, Bhubaneswar, 5-Oct-21 Page 18 of 26
 (a) greater for gases with higher solubility
(b) greater for gases with lower solubility
(c) constant for all gases
(d) not related to the solubility of gases
150 KH value for Ar(g),CO2(g), HCHO(g) and CH4(g) are 40.39, 1.67, 1.83 x 10.5and 0.413 respectively.
Arrange these gases in the order of their decreasing solubility.
(a) CO2> HCHO > CH4>Ar
(b) Ar>CO2> HCHO > CH4
(c) CH4> CO2> CH4 >Ar
(d) HCHO > CH4> CO2>Ar

151 Which of the following is not a colligative property

(a) Elevation in boiling point
(b) Osmotic pressure
(c) Depression in freezing point
(d) Vapour pressure.
152 Relative lowering of vapour pressure is equal to
(a) Mole fraction of solvent
(b) Mass of solvent
(c) Mole fraction of solute
(d) Molar mass of solute
153 The temperature at which the vapour pressure of a liquid is equal to atmospheric pressure is known as.
(a) Molality
(b) Boiling point
(c) Freezing point
(d) Osmosis
154
Tb  K b . m , in this formula the unit of Tb can be expressed as:
(a) K
(b) OC
(c) Both in K and OC
(d) None of these
155 A 5 % solution of cane sugar(molar mass 342) is isotonic with 1 % of a solution of an unknown solute. The
molar mass of unknown solute in g/mol is
(a) 34.2
(b) 68.5
(c) 171.2
(d) 136.2

ZIET, Bhubaneswar, 5-Oct-21 Page 19 of 26

 156 The depression in freezing point for 1 M urea,1 M glucose and 1M NaCl are in the ratio
(a) 1:2:3
(b) 3:2: 2
(c) 1:1:2
(d) None of these
157 An aqueous solution of glucose is allowed to freeze, then crystals of which will be separated out first?
(a) Water
(b) Glucose
(c) Both of these
(d) None of these

158 Colligative properties depend on ____________.

(a) The nature of the solute particles dissolved in solution
(b) The number of solute particles in solution.
(c) The physical properties of the solute particles dissolved in solution.
(d) The nature of solvent particles.
159 Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0 M NaOH
(b) 1.0 M Na2SO4
(c) 1.0 M NH4NO3
(d) 1.0 M KNO3
160 The unit of ebulioscopic constant is _______________.
(a) K kg mol–1 or K (molality)–1
(b) Mol kg K–1 or K–1(molality)
(c) kg mol–1 K–1 or K–1(molality)–1
(d) K mol kg–1 or K (molality)
161 In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is
(a) The same
(b) About twice
(c) About three times
(d) About six times
162 An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because
(a) it gains water due to osmosis.
(b) it loses water due to reverse osmosis.
(c) it gains water due to reverse osmosis.
(d) it loses water due to osmosis.
163 What is the osmotic pressure of a 0.0020 mol/dm3 sucrose (C12H22O11) solution at 20 0C? (R = 8.314 J/mol.K)
(a) 4870 Pa
(b) 4.87 Pa
(c) 0.00487 Pa
(d) 0.33 Pa

ZIET, Bhubaneswar, 5-Oct-21 Page 20 of 26

 164 Osmosis always takes place from
(a) hypotonic to hypertonic solution
(b) hypertonic to hypotonic solution
(c) both of them
(d) none of these
165 What is the name of process as shown in the diagram given below?

(a) Osmosis
(b) Reverse osmosis
(c) Boiling
(d) Diffusion
(e) None of these

166 Colligative properties depend on

(a) the nature of the solute (b) the number of solute particles in solution

(c) the physical properties of solute (d) the nature of the solvent

167 The unit of ebullioscopic constant is

(a) K kg mol-1 (b) K-1 kg mol (c) K kg-1mol-1 (d) K kg-1mol

168 In comparision to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is
(a) the same (b) about twice (c) about three times (d) about six times

169 An unripe mango placed in a concentrated salt solution to prepare pickles because
(a) it gains water due to osmosis

(b) it loses water due to reverse osmosis

(c) it gains water due to reverse osmosis
(d) it looses water due to osmosis
170 Which of the following is a colligative property?
(a)Osmotic pressure (b) Boiling point ( c) Vapour pressure (d)Electrical conductivity

171 Which of the following solution has highest freezing point?

(a)0.1 MNaCl (b)0.1MBaCl2 (c )0.1MAl2(SO4)3 (d)O.1M Urea

172 Which of the following solution 0.1M aqueous solutions have the lowest freezing point?
(a) Potassium sulphate(b)Sodium chloride(c )Urea(d) Glucose

173 6.02x1020 molecules of urea are present in 100ml.of its solution. The concentration of urea solution is
(a) 0.001M (b) 0.01 M (c )0.02 M (d) 0.1M

174 The vapour pressure of the two liquids P and Q are 80 and 60 torr respectively.The total pressure of the solution
obtained by mixing 3 mole of P and 2 mole of Q would be
(a) 68 torr (b) 140 torr ( c) 72 torr (d) 20 torr

175 During Osmosis ,flow of water through semipermeable membrane is

(a) from solution having lower concentration only
(b) from solution having higher concentration
( c) from both sides of semipermeable membrane with equal flow
( d)from both sides semi permeable membrane with unequal flow rates
ZIET, Bhubaneswar, 5-Oct-21 Page 21 of 26
176 Density of 2.05 M solution of Acetic acid in water is 1.02 g/ml.The Molality of solution is
(a) 2.28 molkg-1 (b) 0.44 molKg-1 (c ) 1.14 molKg-1 (d) 3.28 molKg-1

177 A 1% aqueous solution (mass-volume) of certain substance is Isotonic with 3% solution of glucose (molar mass
180).The molar mass of substance is
(a) 60 (b) 120 (c ) 180 (d) 540

178 The vapour pressure of solvent decreased by 10 mm of Hg when a non-volatile solute was added to the solvent.
The mole fraction of the solute in the solution is 0.2what should be the mole fraction of solvent if the decrease in
vapour pressure is required to be 20mm of Hg?
(a)0.6 (b) 0.8 (c )0.4 ( d)0.2

179 If two substances A and B have pAo:pBo=1:2 and also XA:XB in solution as 1:2 then mole fraction mole fraction of
A in vapour phase is
(a) 0.33 (b)0.25 (c )0.52 (d) 0.2

180 If liquid A and B form ideal solutions

(a) The enthalpy of mixing is zero
(b) the entropy of mixing is zero
(c )the free energy of mixing is zero
(d)the free energy as well as entropy of mixing are each zero.

181 An aquous solution freezes at -0.1860C(Kf =1.86;Kb=0.512). What will be the elevation in boiling point?

(a) 0.186 (b) 122044 0.512(c) 0.86 (d) 0.0512

182 Assuming the complete dissociation, the van”t Hoff factor for a dilute solution of sodium chloride
is

a. 2 (b) 1 (c) 0 (d) 1.5

183 Blood cell do not shrink in blood because blood is

a. Hypotonic (b) isotonic (c) equimolar (d) hypertonic

184 Which of the statements given below concerning properties of solutions describe a colligative effect?

a. Boiling point of pure water decreases by addition of ethanol

b. Vapour pressure of pure water decreases by the addition of nitric acid
c.Vapour pressure of pure water decreases by the addition of naphthalene
d Boiling point of pure water increases by the addition of toluene..

185.Molal elevation constant is defined as the ratio of elevation in boiling point to :

(a) molality (b) molarity (c) mole fraction of solute (d) mole fraction of solvent

186 10 g of a non-volatile solute was dissolved in 100 g of water and the vapour pressure of water was found
to lower from 100 mm to 99 mm of Hg. The molecular mass of the solute is:

(a) 90n (b) 360 (c) 150 (d) 180

187 A 5.25% solution of a sub stance is isotonic with a 1.5% solution of urea (Molar mass=60g/mol) in the
same solvent. If the density of the both the solution are assumed to be equal to 1.0gcm-3molar mass of the
substance will be

(a) 210.0gmol-1 (b) 90.0gmol-1 (c) 115.0gmol-1 (d) 1.5.0gmol-1

ZIET, Bhubaneswar, 5-Oct-21 Page 22 of 26

 188 What is the molarity of pure water?

a. 1 (b) 18 (c) 55.5 (d) None of thes

189 1.0 g of a non-volatile solute (molar mass 250 g mol–1) was dissolved in 51.2 g of benzene. If the
freezing point depression constant, Kf of benzene is 5.12 K kg mol–1, the freezing point of benzene will be
lowered by:

(a) 0.3 K (b) 0.5 K (c) 0.2 K (d) 0.4 K.

190 Reverse osmosis is a process,

a. In which applied pressure to the solution side, is larger than the osmotic pressure.

b. In which applied pressure to the solution of higher concentration to the solution of lower concentration

c. Which is used for desalination of sea water.

d. All of the above

191 Which relationship is not correct?

192. Which has the lowest boiling point at 1 atm pressure?

(a) 0.1 M KCl
(b) 0.1 M Urea
(c) 0.1 M CaCl2
(d) 0.1 M A1Cl3
193 Sprinkling of salt helps in clearing the snow-covered roads in hills. The phenomenon involved in the
process is
(a) depression in freezing point of snow
(b) lowering in vapour pressure of snow
(c) melting of ice due to increase in temperature by putting salt
(d) increase in freezing point of snow
194 The osmotic pressure of a solution can be increased by
(a) increasing the volume
(b) increasing the number of solute molecules
(c) decreasing the temperature
(d) removing semipermeable membrane

195 1 M, 2.5 litre NaOH solution is mixed with another 0.5 M, 3 litre NaOH solution. Then find out the
molarity of resultant solution
(a) 0.80 M
(b) 1.0 M
(c) 0.73 M
(d) 0.50 M.

196. Which of the following units is useful in relating concentration of solution with its vapour pressure?
a) mole fraction b) parts per million c) mass percentage d) molality
197. Colligative properties depend on
a) the nature of solute particles dissolved in solution b) the number of solute particles in solution c) the physical
properties of the solute particles dissolved in solution d) the nature of solvent particles
198. Which of the following aqueous solutions should have the highest boiling point?
a) 1.0 M NaOH b) 1.0 M Na2SO4 c) 1.0M NH4NO3 d) 1.0 M KNO3
199. The unit of ebulioscopic constant is
a) K kg mol-1 b) mol kg K-1 c) kg mol-1K-1 d) K mol kg-1
200. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is
a) the same b) about twice c) about three times d) about six times
201. An unrupe mango placed in a concentrated salt solution to prepare pickle, shrivels because
a) it gains water due to osmosis b) it ioses water due to reverse osmosis
c) it gains water due to reverse osmosis d) it loses water due to osmosis
202. At a given temperature, osmotic pressure of a concentrated solution of a substance
a) is higher than that at a dilute solution
ZIET, Bhubaneswar, 5-Oct-21 Page 23 of 26
b) is lower than that at a dilute solution
c) is same as that of a dilute solution
d) can not be compared with osmotic pressure of dilute solution
203. 16. When 1 mole of benzene is mixed with 1 mole of toluene (vapour pressure of benzene –
12.8 kPa, Toluene = 3.85 kPa)
(a) The vapour will contain equal amount of benzene and toluene.
(b) Not enough information is given for prediction.
(c) The vapour will contain a higher percentage of benzene.
(d) The vapour will contain higher percentage of toluene.
204. At 100°C, the vapour pressure of a solution of 6.5 g of solute in 100 g of water is 732 mm. If
K is 0.52 K/m, the boiling point of solution will be
(a) 102°C
(b) 103°C
(c) 101 °C
(d) 100°C

205. If molality of dilute solution is doubled, the value of molal depression constant (Kf ) will be
(a) halved
(b) tripled
(c) unchanged
(d) doubled
206. The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic
pressure of 16.4 atom is (R = 0.082 L atom K mol )
(a) 360°C
(b) 180 K
(c) 300 K
(d) 360 K
207. Which has the highest freezing point?
(a) 1 M glucose
(b) 1 M NaCl
(c) 1 M CaCl2
(d) 1 M AlF3

208. Relative lowering of vapour pressure is a colligative property because ________.

(а) It depends on the concentration of a non-electrolyte solute in solution and does not dependon the nature of the
solute molecules
(b) It depends on number of particles of electrolyte solute in solution and does not depend onthe nature of the
solute particles
(c) It depends on the concentration of a non-electrolyte solute in solution as well as on thenature of the solute
molecules
(d) It depends on the concentration of an electrolyte or nonelectrolyte solute in solution as wellas on the nature of
solute molecules
209. Which has the lowest boiling point at 1 atm pressure?
(a) 0.1 M KCl
(b) 0.1 M Urea
(c) 0.1 M CaCl2
(d) 0.1 M A1Cl3
210. People add sodium chloride to water while boiling eggs. This is to
(a) decrease the boiling point.
(b) increase the boiling point.
(c) prevent the breaking of eggs.
(d) make eggs tasty.

211 On which of the following factor the maximum amount of solid solute dissolved in a specified amount of a given
liquid solvent does not depend?
(a) Temperature (b) Nature of solute
(c) Pressure (d)Nature of solvent
212 KH value for Ar(g), CO2(g), HCHO(g) & CH4(g) are 40.39, 1.67, 1.83 x 10-5 and 0.413 respectively. Arrange
these gases in the order of their increasing solubility.
(a)HCHO < CH4< CO2< Ar (b) HCHO < CO2< CH4< Ar
(c) Ar < CO2< CH4< HCHO (d) Ar < CH4< CO2< HCHO
213 If Po A = 100mm, PoB = 200mm and mole fraction χA = 0.4 , what will be yA(mole fraction) in vapour phase ?
(a)0.25 (b) 0.30
(c)0.75 (d) 0.50
ZIET, Bhubaneswar, 5-Oct-21 Page 24 of 26
214 The pgas dissolved in a liquid is directly proportional to its
(a)mole fraction (b) molar mass
(c ) boiling point of liquid (d) molar mass of solvent
215 4 g NaOH(s) is dissolved in 250 ml solution. The density of the solution is 1g/ml. Find the concentration of the
solid solute in the solution in terms of molality.
(a)0.57(m) (b) 0.39(m)
(c ) 0.406 (m) (d) 0.55(m)
216 The molarity of pure water is
(a)18 (b) 55.6
(c ) 5.56 (d) 100
217 The number of moles of NaCl in 3 litres of 3 M solution is
(a)1 (b) 3
(c ) 9 (d) 27
218 For a binary ideal liquid solution , the total pressure of the solution is given as
(a)ptotal = poA + (poA - poB)χA (b) ptotal= poB + (poA - poB)χA
o o o
(c ) ptotal = p A + (p B - p A)χA (d) ptotal = poA + (poB - poA)χA
219 The mole fraction of methanol in its 4.5 molal aqueous solution is
(a)0.250 (b) 0.125
(c ) 0.100 (d) 0.075
220 A pressure cooker reduces cooking time because
(a)heat is more evenly distributed (b) the high pressure tenderises the food
(c ) the boiling point of water inside the cooker is elevated (d) the boiling point of water inside the cooker is
depressed.
221 The vapour pressure of two liquids P & Q are 80 and 60 torr respectively. The total vapour pressure of solution
obtained by mixing 3 mol of P and 2 mol of Q would be
(a)72 torr (b) 140 torr
(c ) 68 torr (d) 20 torr
222 An aqueous solution containing 6 g of urea in 500ml of solution has a density equal to 1.05. If the molar mass of
urea is 60, then the molality of the solution is
(a)0.20 (b) 0.19
(c ) 0.10 (d) 1.2
223 Which pair will not form an ideal solution?
(a)C2H5Br and C2H5I (b) C6H5Br and C6H5I
(c ) C6H6 and C6H5CH3 (d) C2H5I and C2H5OH
224 Concentrated aqueous sulphuric acid is 98% H2SO4 by mass and has a density of 1.80 g /ml. Volume of acid
required to make one litre of 0.1 M H2SO4 is
(a)5.55 ml (b) 11.10 ml
(c ) 16.65 ml (d) 22.20 ml
225 An aqueous solution is 1.00 molal in KI. Which change will cause the vapour pressure of the solution to
increase?
(a)addition of 1.00 molal KI (b) addition of water
(c ) addition of NaCl (b) addition of Na2SO4

ANSWER -KEY
1 C 41 A 81 D 121 D 161 C 201 D
2 C 42 A 82 B 122 C 162 D 202 A
3 C 43 D 83 B 123 C 163 A 203 C
4 B 44 C 84 D 124 A 164 A 204 C
5 B 45 C 85 D 125 A 165 B 205 C
6 B 46 B 86 B 126 A 166 B 206 D
7 C 47 B 87 C 127 A 167 A 207 D
8 A 48 D 88 C 128 B 168 C 208 A
9 B 49 A 89 B 129 C 169 D 209 B
10 D 50 A 90 A 130 D 170 C 210 B
11 A 51 B 91 A 131 D 171 A 211 C
12 A 52 D 92 B 132 C 172 B 212 C
13 A 53 B 93 A 133 B 173 B 213 A
14 B 54 B 94 B 134 C 174 C 214 A
15 C 55 C 95 B 135 A 175 A 215 C
16 C 56 B 96 C 136 C 176 A 216 B
17 B 57 A 97 A 137 C 177 A 217 C
18 B 58 C 98 D 138 D 178 A 218 B
ZIET, Bhubaneswar, 5-Oct-21 Page 25 of 26
19 A 59 C 99 C 139 B 179 B 219 D
20 D 60 A 100 A 140 B 180 A 220 C
21 A 61 A 101 C 141 C 181 D 221 A
22 B 62 D 102 D 142 B 182 A 222 B
23 B 63 A 103 A 143 A 183 B 223 D
24 A 64 A 104 C 144 B 184 C 224 A
25 A 65 C 105 B 145 B 185 A 225 B
26 B 66 B 106 B 146 C 186 D
27 C 67 D 107 A 147 C 187 A
28 B 68 D 108 A 148 C 188 C
29 C 69 B 109 C 149 B 189 D
30 A 70 B 110 A 150 D 190 D
31 C 71 A 111 D 151 D 191 B
32 D 72 D 112 B 152 C 192 B
33 B 73 A 113 D 153 B 193 A
34 C 74 D 114 B 154 C 194 B
35 D 75 A 115 A 155 B 195 C
36 C 76 C 116 C 156 C 196 A
37 D 77 D 117 D 157 A 197 B
38 B 78 D 118 A 158 B 198 B
39 A 79 B 119 B 159 B 199 A
40 A 80 D 120 B 160 A 200 C

The questions submitted by the PGTs (Chemistry) of KVs of Bhubaneswar, Guwahati,

Kolkata, Ranchi, Silchar and Tinsukia Regions.
Vetted by: Guwahati Region

ZIET, Bhubaneswar, 5-Oct-21 Page 26 of 26

 As Per Revised
CBSE Curriculum
2024-25
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 ANIMATED & CLASSROM TEACHING VIDEOS PLAYLISTS
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