MOLE & EQT.

CONCEPT
(a) n – m = p – q
VDPP–1 (c) n = m
(b) n + m = p + q
(d) p = q
Subtopics: Dalton's Atomic Theory and Laws of 7. Which one is the best example of law of conservation
chemical combination; Atomic and Molecular of mass ?
Mass (a) 6 g of carbon is heated in vacuum, there is no
change in mass
(b) 6 g of carbon combines with 16 g of oxygen to
1. One of the following combinations illustrate law of
form 22 g of CO2
reciprocal proportions
(c) 6 g water is completely converted into steam
(a) N2O3 , N2O4 , N2O5 (b) NaCl, NaBr, Nal
(d) A sample of air is heated at constant pressure when
(c) CS2 , CO2 , SO2 (d) PH 3 , P2O3 , P2O5 its volume increases but there in no change in mass.
2. If water samples are taken from sea, river, clouds, lake 8. SO2 gas was prepared by (i) burning sulphur in
or snow, they will be found to contain H2 and O2 in the oxygen, (ii) reacting sodium sulphite with dilute
approximate ratio of 1 : 8. This indicates the law of H2SO4 and (iii) heating copper with conc. H2SO4. It
(a) Multiple proportion was found that in each case sulphur and oxygen
(b) Definite proportion combined in the ratio of 1 : 1. The data illustrates the
(c) Reciprocal proportions law of :
(d) none of these (a) conservation of mass
3. The law of multiple proportion is illustrated by (b) multiple proportions
(a) Carbon monoxide and carbon dioxide (c) constant proportions
(b) Potassium bromide and potassium chloride (d) reciprocal proportions
(c) Water and heavy water 9. A sample of CaCO3 has Ca = 40%, C = 12% and O =
(d) Calcium hydroxide and barium hydroxide 48%. If the law of constant proportions is true, then the
4. Two samples of lead oxide were separately reduced to mass of Ca in 5 g of CaCO3 from another source will
metallic lead by heating in a current of hydrogen. The be :
weight of lead from one oxide was half the weight of (a) 2.0g (b) 0.2g (c) 0.02g (d) 20.0g
lead obtained from the other oxide. The data 10. H2S contains 5.88% hydrogen, H2O contains 11.11%
illustrates. hydrogen while SO2 contains 50% sulphur. These
(a) law of reciprocal proportions figures illustrate the law of :
(b) law of constant proportions (a) conservation of mass
(c) law of multiple proportions (b) constant proportions
(d) law of equivalent proportions (c) multiple proportions
5. One part of an element A combines with two parts of (d) reciprocal proportions
another element B. Six parts of the element C combine 11. Hydrogen combines with chlorine to form HCl. It also
with four parts of the element B. If A and C combine combines with sodium to form NaH. If sodium and
together the ratio of their weights will be governed by chlorine also combine with each other, they will do so
(a) law of definite proportions in the ratio of their masses as :
(b) law of multiple proportions (a) 23 : 35.5 (b) 35.5 : 23
(c) law of reciprocal proportions (c) 1 : 1 (d) 23 : 1
(d) law of conservation of mass 12. Two different samples of distilled water were found to
6. n g of substance X reacts with m g of substance Y to contain same percentage of H and O. Which law of
form p g of substance R and q g of substance S. This combination does this data verifies?
reaction can be represented as follows : (a) Law of conservation of mass
X+Y=R+S (b) Law of definite proportions
The relation which can be established in the amounts (c) Law of multiple proportions
of the reactants and the products will be (d) Law of reciprocal proportions

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13. The modern atomic weight scale is based on 8. The weight of a molecule of the compound C60 H122 is
12 16
(a) C (b) O (a) 1.4 10−21 g (b) 1.09 10−21 g
1 13
(c) H (d) C
(c) 5.025  1023 g (d) 16.023 1023 g
14. 1 amu is equal to
9. Cortisone is a molecular substance containing 21
1
(a) of C - 12 isotope atoms of C per molecule. The mass percentage of
12
carbon in cortisone is 69.98%. The molecular mass of
1 cortisone (in amu) is-
(b) of O – 16 isotope
14 (a) 176.5 amu (b) 252.2 amu
(c) 1 g of H2 (c) 287.6 amu (d) 360.1 amu
(d) 1.99 ×10-23 g 10. The largest number of molecules is in
(a) 36 g of water
VDPP–2 (b) 28 g of carbon monoxide
(c) 46 g of ethyl alcohol
Subtopics: Mole Concept
(d) 54 g of nitrogen pentoxide
11. The mass of 112 cm3 of CH4 gas at STP is
1. The number of water molecules present in a drop of (a) 0.16 g (b) 0.8 g
water (volume = 0.0018 ml) at room temperature is (c) 0.08 g (d) 1.6 g
(density of H2O = 1 g/mL) 12. Which of the following contains atoms equal to those
(a) 6.023 × 1019 (b) 1.084 × 1018 in 12 g Mg ? (At. wt. Mg = 24)
17
(c) 4.84 × 10 (d) 6.023 × 1023 (a) 12 gm C (b) 7 gm N2
2. M g of a substance when vaporised occupy a volume (c) 32 gm O2 (d) None of These
of 5.6 litre at NTP. The molecular mass of the 13. Which has the highest mass ?
substance will be : (a) 50 g of iron
(a) M (b) 2M (b) 5 moles of N2
(c) 3M (d) 4M (c) 0.1 mol atom of Ag
1 (d) 1023 atoms of carbon
3. If 1 moles of oxygen combine with Al to form
2 14. If NA is Avogadro’s number then number of valence
Al2O3, the weight of Al used in the reaction is (Al = electrons in 4.2 g of nitride ions (N3–) is
27) (a) 2.4 NA (b) 4.2 NA
(a) 27 g (b) 54 g (c) 1.6 NA (d) 3.2 NA
(c) 40.5 g (d) 81 g 15. Rearrange the following I to IV in order of increasing
4. Which of the following weighs the least ? masses and choose the correct answer [At. wt. of N =
(a) 2 g atom of N (at. wt. of N = 14) 14 u, O = 16 u, Cu = 63 u]
(b) 3 × 1023 atoms of C (at. wt. of C = 12) I. 1 molecule of oxygen
(c) 1 mole of S (at. wt. of S = 32) II. 1 atom of nitrogen
(d) 7 g silver (at. wt. of Ag = 108) III. 1 × 10–10 mol molecule of oxygen
5. The number of molecules in 4.25 g of ammonia is IV. 1 × 10–10 mol atom of copper
about (a) II < I < III < IV (b) IV < III < II < I
(a) 1.0 × 1023 (b) 1.5 × 1023 (c) II > I > III > IV (d) I < II < IV < III
(c) 2.0 × 1023 (d) 2.5 × 1023 16. Number of molecules in 1 litre of oxygen at NTP is :
6. The weight of a molecule of the compound C60H122 is 6.02  10 23 6.02  10 23
(a) (b)
(a) 1.4 × 10–21 g (b) 1.09 × 10–21 g 32 22.4
23
(c) 5.025 × 10 g (d) 16.023 × 1023 g 32
7. Choose the wrong statement : (c) 32 × 22.4 (d)
22.4
(a) 1 mole means 6.02 × 1023 particles (b) Molar mass
17. The number of moles of SO2Cl2 in 13.5 g of
is mass of one molecule
(c) Molar mass is mass of one mole of a substance SO2Cl2 is:
(d) Molar mass is molecular mass expressed in grams (a) 0.1 (b) 0.2
(c) 0.3 (d) 0.4

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18. 1 mol of CH 4 contains 2. If 20% nitrogen is present in a compound, its
minimum molecular weight can be
(a) 6.02 10 atoms of H
23

(a) 144 (b) 28

(b) 4 g atom of Hydrogen
(c) 100 (d) 70
(c) 1.811023 molecules of CH 4 (d) 3.0 g of carbon
3. The carbonate of a metal is isomorphous (similar
19. Total number of atoms present in CuSO4 .5H 2O is formula) with magnesium carbonate and contains
(a) 27 (b) 21 6.091 percent of carbon. The atomic weight of metal is
(c) 5 (d) 8 (a) 24 (b) 56
20. The number of atoms in 4.25 g of NH3 is (c) 137 (d) 260
approximately 4. Insulin contains 3.4% sulphur. What will be the
(a) 1.5 1023 (b) 2 1023 minimum molecular weight of insulin?
(c) 4 1023 (d) 6 1023 (a) 94.117 (b) 1884
(c) 941.176 (d) 976
21. The mass of a molecule of water is
(a) 3 10−26 kg (b) 3 10−25 kg
(c) 1.5 10−26 kg (d) 2.5 10−26 kg
VDPP–4
22. Which of the following has least mass Subtopics: Empirical and Molecular Formula
(a) 2g atom of nitrogen
(b) 3 1023 atoms of C 1. An oxide of metal (M) has 40% by mass of oxygen.
(c) 1 mole of S Metal M has atomic mass of 24. The empirical formula
(d) 8 g molecule of hydrogen gas of the oxide is
23. Which one of the following pairs of gases contains the (a) M2O (b) M2O3
same number of molecules (c) MO (d) M3O4
(a) 16 g of O2 and 14 g of N 2 2. What is the empirical formula of a compound
composed of O and Mn in equal weight ratio ?
(b) 8 g of O2 and 22 g of CO2
(a) MnO (b) MnO2
(c) 28 g of N2 and 22 g of CO2
(c) Mn2O3 (d) Mn2O7
(d) 32 g of O2 and 32 g of N2
24. The volume occupied by 4.4 g of CO2 at STP is 3. Determine the empirical formula of Kelvar, used in
(a) 22.4 L (b) 2.24 L making bullet proof vests, is 70.6% C, 4.2% H, 11.8%
N and 13.4% O
(c) 0.224 L (d) 0.1 L
(a) C7H5NO2 (b) C7H5N2O
25. The largest number of molecules is present in
(c) C7H9NO (d) C7H5NO
(a) 34 g of water (b) 28 g of CO2
4. Formula which represents a simple ratio of atoms
(c) 46 g of CH 3OH (d) 54 g of N 2 O5
different elements present in a molecule of the
26. The number of electrons in a mole of hydrogen substance is called :
molecule is - (a) Molecular formula
(a) 6.02 1023 (b) 12.044 ×1023 (b) Empirical formula
(c) 3.0115 1023 (d) Indefinite (c) Structural formula
(d) None of these

VDPP–3 5. The empirical formula of hydrogen which has 75% C

and 25% H by mass is
Subtopics: Percentage Composition (a) CH4 (b) CH3
(c) CH2 (d) CH
1. Haemoglobin contains 0.33% of iron by weight. The 6. A compound having empirical formula AB2 has
molecular weight of haemoglobin is approximately molecular mass equal to 18 amu. If the atomic masses
67200. The number of iron atoms (at. wt. of Fe = 56) of A and B are 16 and 1 respectively, what is its
present in one molecule of haemoglobin is molecular formula?
(a) 6 (b) 1 (a) AB2 (b) A2B4
(c) 4 (d) 2 (c) A3B6 (d) A4B8

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7. Formula mass is defined for 6. When 2 moles of N2 gas and 9 moles of H2 gas are
(a) All types of covalent compounds mixed and reaction is completed to form NH 3 gas then
(b) Non-polar covalent compounds reaction mixture will contain:
(c) Polar covalent compounds (a) 11 moles of NH3
(d) Ionic compounds (b) 4 moles of NH3 + 3 moles of H2
8. Two different ion A2+ and B2– are 40 and 16 times (c) 6 moles of NH3 + 3 moles of H2
heavier than 1/12th of mass of C-12 isotope. What is (d) 2 moles of NH3 + 1 mole of N2
the formula mass of compound AB?
(a) 56
(c) 102
(b) 28
(d) 84
VDPP–6
Subtopics: Mass-Volume Analysis & Mole-
Volume Analysis
VDPP–5
Subtopics: Chemical Reaction & Equation,
1. Assuming full decomposed, the volume of
Stoichiometry
CO2 released at STP on heating 9.85 g of BaCO3 (Ba =
137, C = 12, O = 16) will be
1. If 0.5 mol of BaCl2 is mixed with 0.2 mol of Na3PO4, (a) 0.84 L (b) 2.24 L
the maximum number of mole of Ba3(PO4)2 that can be (c) 4.06 L (d) 1.12 L
formed is 2. The mass of C consumed (giving only CO2) in the
(a) 0.7 (b) 0.5 production of 270 kg of aluminium metal from bauxite
(c) 0.30 (d) 0.10 by Hall’s process is
2. Iron (III) oxide can be reduced with CO to form 2Al2O3 + 3C → 4Al + 3CO2↑
metallic iron as described by unbalanced chemical (at mass of Al = 27 gm)
reaction (a) 90 kg (b) 540 kg
Fe2O3 + CO → Fe + CO2 (c) 180 kg (d) 270 kg
The number of moles of CO required to form one mole 3. Two litre of oxygen was reacted with five litre of CO
of Fe from its oxide is at STP. Find mass of CO2 produced.
(a) 1 (b) 1.5 (a) 1.8g (b) 2.0g
(c) 2 (d) 3 (c) 7.86g (d) 3.93g
3. Which of the following information extracted is 4. 2Na + 2H2O → 2NaOH + H2
incorrect regarding the given reaction? How much NaOH can be formed on reaction of 23 g
A + 2B → AB2 of sodium with sufficient amount of water?
(a) One atom of A combines with 2 atoms of B to give (a) 80 g (b) 40 g
one molecule of AB2 (c) 20 g (d) 46 g
(b) One mole of A combines with 2 moles of B to give 5. 2Na + 2H2O → 2NaOH + H2
one mole of AB2 How much hydrogen gas can be formed from 1 mole
(c) 1 mole of A on reaction with excess B can give one of sodium at STP?
mole of AB2 (a) 22.4 L (b) 11.2 L
(d) 1 g of A combines with 2 g of B to give 3 g AB2 (c) 5.6 L (d) 44.8 L
4. What is the sum of x + y + z in the balanced reaction – 6. What is the weight of oxygen required for the
C4H10 + xO2 → yH2O + zCO2 complete combustion of 2.8 kg of ethylene ?
(a) 18 (b) 16 (a) 2.8 kg (b) 6.4 kg
(c) 15.5 (d) 15 (c) 9.6 kg (d) 96 kg
5. For the given reaction – 7. 30g of magnesium and 30g of oxygen are reacted, then
2A + 3B → 4C + 5D the residual mixture contains
How many moles of D are formed when 6 moles of B (a) 60g of Magnesium oxide only
react with excess of A? (b) 40g of Magnesium oxide and 20 g of oxygen
(a) 10 (b) 5 (c) 45 g of Magnesium oxide and 15g of oxygen
(c) 4 (d) 2 (d) 50 g of Magnesium oxide and 10g of oxygen

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8. Silicon carbide, is produced by heating SiO2 and C to
high temperatures according to the equation :
VDPP–7
SiO2 (s) + 3C (s) → SiC (s) + 2CO (g) Subtopics: Limiting Reagent & Sequential
How many grams of SiC could be formed by reacting Reaction
2.00 g of SiO2 and 2.0 g of C ?
(a) 1.33 (b) 2.56
1. If 9 moles of O2 and 14 moles of N2 are placed in a
(c) 3.59 (d) 4.0
container and allowed to react according to the
9. Given the reaction
equation:
Pb(NO3)2 (aq) + 2KI → PbI2 (s) + 2KNO3 (aq)
3O2 + 2N2 → 2N2O3
What is the mass of PbI2 that will precipitate if 10.2 g
The reaction proceeds until 3 moles of O2 remain, how
of Pb(NO3)2 is mixed with 5.73 g of KI in a sufficient
many moles of N2O3 are present at that instant?
quantity of H2O ?
(a) 6 (b) 3
(a) 2.06 g (b) 4.13 g
(c) 4 (d) 12
(c) 7.96 g (d) 15.9 g
2. If AgBr is assumed to be completely insoluble, What
10. How many grams of NaBr could be formed if 14.2 g of
mass of AgBr precipitates when 30.0 mL of a 0.500
NaI are reacted with 40.0 mL of a 0.800 M Br 2 ?
mol/L solution of AgNO3 is added to 50.0 mL of an
2NaI + Br2 → 2NaBr + I2
0.400 mol/L solution of NaBr ?
(a) 3.30 (b) 4.80
(a) 3.76 g (b) 1.28 g
(c) 6.59 (d) 9.75
(c) 2.82 g (d) 3.76 kg
11. A hydrate of Na2SO3 losses 22.2% of H2O by mass on
3. 10 mL of 1 M BaCl2 solution and 5 mL 0.5 M
strong heating. The hydrate is
K2SO4 are mixed together to precipitate out BaSO4.
(a) Na2SO3.4H2O (b) Na2SO3.6H2O
The moles of BaSO4 precipated will be
(c) Na2SO3.H2O (d) Na2SO3.2H2O
(a) 0.005 mol (b) 0.00025 mol
12. Calculate the weight of iron which will be
(c) 0.025 mol (d) 0.0025 mol
converted into its oxide by the action of 18g of
4. Equal weights of zinc and iodine react together and the
steam on it in the given reaction.
iodine is completely converted to Znl2. What fraction
by weight of the original zinc remains unreacted? (Zn
2 Fe + 3H 2 O ⎯⎯
→ Fe2 O3 + 3H 2 .
= 65, I = 127g/mol)
(a) 37.3 g (b) 3.73 g
(a) 0.6 (b) 0.74
(c) 56 g (d) 5.6 g
(c) 0.47 (d) 0.17
13. LiOH reacts with CO2 to form Li2CO3 (atomic mass of
5. When a mixture of 10 moles of SO2, 15 mole of
Li = 7). The amount of CO2 (in g) consumed by 1 g of
O2 was passed over a catalyst, 8 moles of SO3 was
LiOH is closest to
formed. How many moles of SO2 & O2 did not enter
(a) 0.916 (b) 1.832
into combination?
(c) 0.544 (d) 1.088
(a) 2 & 11 (b) 3 & 14
14. 10 g CaCO3 gives on strong heating CO2 . It gives
(c) 8 & 12 (d) 2 & 5
quicklime (in grams) 6. A mixture of N2 and H2 is allowed to react in a closed
(a) 5g (b) 4.4 g container to form NH3. The reaction ceases before
(c) 5.6 g (d) 4 g either reactant has been totally consumed. At this
1 stage, 4 moles each of N2, H2 and NH3 are present.
15. If 1 moles of oxygen combine with Al to form
2 Which of the following statements are correct
Al2O3 , the weight of Al used in the reaction is (Al = regarding above experiment?
27) 1) Initial moles of N2 were 6.
(a) 27 g (b) 54 g 2) Initial moles of H2 were 10.
(c) 40.5 g (d) 81 g 3) Initial moles of H2 were 8
4) For complete reaction to occur, H2 gas would have
been the limiting reagent.
(a) 1, 2 & 3 (b) 2, 3 & 4
(c) 1, 2 & 4 (d) 1, 3 & 4

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7. 10g of hydrogen and 64g of oxygen were filled in a 3. NH3 is produced according to the following reaction :
steel vessel and exploded. Amount of water produced N2(g) + 3H2(g) → 2NH3(g)
in this reaction will be: In an experiment 0.25 mol of NH3 is formed when 0.5
(a) 3 mol (b) 4 mol mol of N2 is reacted with 0.5 mol of H2. What is %
(c) 1 mol (d) 2 mol yield ?
8. An element 'A' reacts with the compound BO3 to (a) 75% (b) 50%
produce A3O4 & B2O3. The no. of mole of (c) 33% (d) 25%
A3O4 produced if 1 mole each of A and BO 3 are 4. The mass of CaO that shall be obtained by heating 20
allowed to react, is- kg of 90% pure lime-stone (CaCO3) is
(a) 3 (b) 1 (a) 11.2 kg (b) 8.4 kg
1 2 (c) 10.08 kg (d) 16.8 kg
(c) (d)
3 3 5. 2Na + 2H2O → 2NaOH + H2
9. If 0.50 mole of BaCl2 is mixed with 0.20 mole of 40 g NaOH is formed on reaction of 46 g of impure
Na3PO4, the maximum number of moles of sodium sample with sufficient amount of water. What
Ba3(PO4)2 that can be formed is is the percentage purity of the sample? Given Atomic
(a) 0.10 (b) 0.20 mass of Na = 23g, O = 16g, H = 1g
(c) 0.30 (d) 0.40 (a) 50% (b) 100%
10. NaOH is formed according to the reaction (c) 25% (d) 12.5%
1 6. 2A + 3B → 4C + 5D
2 Na + O2 → Na2O On reaction of 2 moles of A with 3 moles of B, 2.5
2
moles of D are formed, what is the percentage yield of
Na2O + H 2O → 2 NaOH
the reaction?
To make 4g of NaOH, The amount of Na required is (a) 50% (b) 100%
(a) 4.6g (b) 4.0g (c) 25% (d) 12.5%
(c) 2.3g (d) 0.23g 7. The volume (in litres) of CO2 liberated at STP when
11. x g of Ag was dissolved in HNO3 and the solution was 10 g of 90% pure lime stone (CaCO3) is heated
treated with excess of NaCl when 2.87 g of AgCl was completely is
precipitated. The value of x is (a) 2.016 (b) 20.16
(a) 1.08 g (b) 2.16 g (c) 2.24 (d) 22.4
(c) 2.70 g (d) 1.62 g 8. On heating 4.9 gm of impure KClO3, its mass is
reduced by 0.384 gm and converted into a gas. The
VDPP–8 percentage of original KClO3 that has been
decomposed is –
Subtopics: Percent Yield and Purity
(At. wt. of K = 39, Cl = 35.5, O =

16) KClO3 ⎯⎯ → KCl + O2
1. If potassium chlorate is 80% pure, then 48 g of oxygen
(a) 20% (b) 30%
would be produced from (atomic mass of K = 39)
(c) 14.7% (d) 12.25%
(a) 153.12g of KClO3
9. A 1.50 g sample of an ore containing silver was
(b) 122.5 g of KClO3
dissolved, and all the Ag+ was converted to 0.125 g
(c) 245 g of KClO3
Ag2S. What was the percentage of silver in the ore ?
(d) 98.0 g of KClO3
(a) 14.23% (b) 10.8%
2. Antimony reacts with sulphur according to the
(c) 8.27% (d) 7.2%
equation
2Sb(s) + 3S(s) → Sb2S3(s)
The molar mass of Sb2S3 is 340 g mol–1.
What is the percentrage yield for a reaction in which
1.40 g of Sb2S3 is obtained from 1.73 g of antimony
and a slight excess of sulphur ?
(a) 80.9 % (b) 58.0 %
(c) 40.5 % (d) 29.0 %

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 VDPP–9 VDPP–10
Subtopics: Solution and Concentration Terms Subtopics: Mole fraction and Molarity

1. A molal solution is one that contains one mole of a 1. Calculate the molarity of NaOH in solution prepared
solute in by dissolving 4 g in enough water to form 250 mL of
(a) 1000 g of the solvent the solution.
(b) one litre of the solvent (a) 0.4 (b) 0.9
(c) one litre of the solution (c) 1.2 (d) 3.4
(d) 22.4 litres of the solution 2. With increase in temperature, which of these changes?
2. In which mode of expression, the concentration of a (a) molality (b) % by mass
solution remains independent of temperature? (c) Molarity (d) mole fraction
(a) Molarity (b) Normality 3. 25 ml of 3M HNO3 is mixed with 75 ml of 4M HNO3.
(c) Formality (d) Molality Then, the molarity of the final mixture is
3. With increase of temperature, which of these changes? (a) 3.75M (b) 2.62M
(a) molality (c) 4.31M (d) 5M
(b) weight fraction of solute 4. A solution contains 2.80 moles of acetone
(c) fraction solute present in unit volume of water ( CH 3COCH 3 ) and 8.20 mole of CHCl3 . Calculate
(d) mole fraction
the mole fraction of acetone.
4. Molarity and Normality changes with temperature
(a) 0.333 (b) 0.222
because they involve :
(c) 0.255 (d) 0.111
(a) Moles (b) equivalents
5. 3.5 litre of 0.01 M NaCl is mixed with 1.5 litre of 0.05
(c) weights (d) volumes
M NaCl. What is the concentration of the final
5. A solution is prepared by adding 2 g of a substance A
solution?
to 18 g of water. Calculate the mass percent of the
(a) 0.022 (b) 0.012
solute.
(c) 0.067 (d) 0.072
(a) 12 (b) 10
6. The volume of 0.25 M NaOH to be added to 250 mL
(c) 17 (d) 78
of 0.15 M NaOH so that the resultant solution is 0.2 M
6. Calculate the molality of KCl solution prepared by
would be
dissolving 7.45 g of KCl in 500 mL of the solution.
(a) 250 mL (b) 350 mL
(d sol = 1.2 g mL−1 ) (c) 450 mL (d) 550 mL
(a) 0.168 (b) 0.178 7. A mixture of ethanol & water contains 54% water by
(c) 0.121 (d) 0.112 mass. Calculate the mole fraction of alcohol in this
7. Calculate the molality (m) of 3M solution of NaCl solution.
whose density is 1.25 g mL-1. (a) 0.25 (b) 0.95
(a) 1.23 (b) 2.79 (c) 1.65 (d) 3.25
(c) 1.11 (d) 1.78 8. When 500.0 mL of 1.0 M LaCl3 and 3.0 M NaCl are
8. The component of solution present in greater quantity mixed. What is molarity of Cl– ion ?
is called ___ (a) 4.0 M (b) 3.0 M
(a) Solute (b) Solvent (c) 2.0 M (d) 1.5 M
(c) Dissolute (d) Dissolvent 9. What is the concentration of nitrate ions if equal
9. In 22 carat gold, ___ is solute and ___ is solvent volumes of 0.1 M AgNO3 and 0.1 M NaCl are mixed
(a) copper, gold (b) gold, gold together ?
(c) gold, copper (d) iron, gold (a) 0.1 M (b) 0.2 M
10. 214.2g of (sucrose) sugar syrup contains 34.2g of (c) 0.05 M (d) 0.25 M
sugar. The molality of the solution is – 10. When 50 mL of 2.00 M HCl, 100 mL of 1.00 M HCl
(Formula of sucrose is C12H22O11) and 100 mL of 0.500 M HCl are mixed together, the
(a) 0.55 (b) 1.5 resulting HCl concentration of the solution is
(c) 6.6 (d) 4.72 (a) 0.25 M (b) 1.00 M
(c) 3.50 M (d) 6.25 M

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11. What volume of 0.4 M FeCl3 . 6H2O will contain 600 11. Find the normality of 1 M H3BO3 (n factor for
mg of Fe3+ ? H3BO3=1)
(a) 49.85 mL (b) 26.78 mL (a) 5N (b) 2N
(c) 147.55 mL (d) 87.65 mL (c) 3N (d) 1N
12. Calculate the normality of NaOH solution formed by
dissolving 0.2 gm NaOH to make 250 ml solution

VDPP–11 (a) 0.5 N

(c) 0.02 N
(b) 0.8 N
(d) 0.1 N
Subtopics: Normality 13. Calculate the number of moles & molarity of N/2 500
ml solution of H2SO4 .
1. 1L solution of NaOH contains 4.0 g of it. What shall (a) 1/4 & 1/8 (b) 1/8 & 1/4
be the difference between molarity and the normality ? (c) 1/3 & 1/5 (d) None of these
(a) 0.10 (b) zero 14. A 5 molar solution of H2SO4 is diluted from 1 L to 10
(c) 0.05 (d) 0.20 L. What is the normality of the solution?
2. Normality of 0.74 g Ca(OH)2 in 5 mL solution is (a) 0.25 N (b) 1 N
(a) 8 N (b) 4 N (c) 2 N (d) 7 N
(c) 0.4 N (d) 2 N 15. Find out the sum of volumes of two HCl solutions P
3. Normality of a 2 M sulphuric acid is (0.5 N) and Q (0.1 N) to be mixed for preparing 2 L of
(a) 2 N (b) 4 N 0.2 N HCI solution
(c) N / 2 (d) N / 4 (a) 4 (b) 5
4. 1 L of a normal solution is diluted to 2000 ml. The (c) 2 (d) 3
resulting normality is : 16. 1 M of Fe(OH)3 Solution is
(a) N / 2 (b) N/ 4 (a) 2 N (b) 3 N
(c) N (d) 2 N (c) 1 N (d) 0.333 N
5. What volume of 0.232 N solution contains 3.17 17. 300 ml 0.2 M HCI and 200 ml of 0.03M H 2SO4 are
milliequivalent of solute ? mixed. The normality of the resulting mixture will be
(a) 137 mL (b) 13.7 mL (a) 0.044 N (b) 0.72 N
(c) 27.3 mL (d) 12.7 mL (c) 0.84 N (d) 0.144 N
6. Normality of a mixture of 30 mL of 1N H 2SO4 and 20 18. Find the Normality of the solution containing 0.5 gm
mL of 4N H2SO4 is of NaOH in 1 L solution
(a) 1.0 N (b) 1.1 N (a) 0.0125 N (b) 0.1 25 N
(c) 2.0 N (d) 2.2 N (c) 0.5 N (d) 0.0250 N
7. How much H2O should be added to 200 c.c. of semi- 19. How much water is to be added to prepare a 0.25N
normal solution of NaOH to make it exactly HCl solution from 0.5 N HCl 1 L solution
decinormal? (a) 500 ml (b) 100 ml
(a) 200 cc (b) 400 cc (c) 1000 ml (d) 250 ml
(c) 600 cc (d) 800 cc 20. What is the normality of 1 M H2SO4 ?
8. What is the normality of 1 M H3PO4? (a) 1N (b) 2N
(a) 2 (b) 4 (c) 3N (d) 4N
(c) 1 (d) 3 21. 100 ml of 0.3 N HCl is mixed with 200 ml of 0.6 N
9. Calculate the normality of 0.321 g sodium carbonate H2SO4. The final normality of the resulting solution
when it is mixed in a 250 ml solution. will be
(a) 0.812 N (b) 0.355 N (a) 0.1 N (b) 0.2 N
(c) 0.024 N (d) 0.122 N (c) 0.3 N (d) 0.5 N
10. What is the normality of the following respectively? 22. Normality of solution obtained by mixing 10 mL of
0.1381 M NaOH 1N HCl, 20 mL of 2N H2SO4 and 30 mL of 3N
0.0521 M H3PO4 HNO3 is
(a) 0.1381 N, 0.156 N (b) 0.2 N, 0.4 N (Use the Final volume as sum of all volumes).
(c) 0.85 N, 0.9 N (d) None of these (a) 1.11 N (b) 2.22 N
(c) 2.33 N (d) 3.33 N

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23. 10 mL of a base reacts with 20 ml of decinormal base 8. Mole fraction of ethanol in ethanol-water mixture is
solution. What is the normality of base? 0.25. Hence, percentage concentration of ethanol
(a) 0.2 N (b) 2 N ( C2 H 6O ) by weight of mixture is
(c) 20 N (d) 0.02 N
(a) 25 (b) 75
(c) 46 (d) 54
VDPP–12 9. 2−
What is the molarity of SO4 ion in aqueous solution
Subtopics: Relations between Concentration that contain 34.2 ppm of Al2(SO4)3 ? (Assume
terms complete dissociation and density of solution 1 g/mL)
(a) 3 × 10–4 M (b) 2 × 10–4 M
–4
(c) 10 M (d) None of these
1. An element A has two isotopes A – 35 and A – 37. 10. Molarity of 20% of H2SO4 by mass whose density is
The average atomic mass of the element is 35.5. What 1.02 g/cc is
are the percentage abundance of A – 35 and A – 37 (a) 8.4 M (b) 2.08 M
respectively? (c) 7.28 M (d) 1.7 M
(a) 75, 25 (b) 25, 75 11. A 6.90 M solution of KOH contains 30% by weight of
(c) 70, 30 (d) 30, 70 KOH. Calculate the density of the solution.
2. An aqueous solution of ethanol has density 1.025 (a) 1.288 (b) 1.333
g/mL and it is 2 M. What is the molality of this (c) 1.54 (d) 1.76
solution ? 12. The relation between molarity(C) and molality(m) is
(a) 1.79 (b) 2.143 given by (d = density of solution, M = molar mass of
(c) 1.951 (d) None of these solute):
3. The density (in g mL–1) of a 3.60 M sulphuric acid 1000CM
solution that is 29% H2SO4 (molar mass = 98 g mol-1) (a) m =
1000C − d
by mass will be
1000C
(a) 1.45 (b) 1.64 (b) m =
(c) 1.88 (d) 1.22 1000d − CM
4. An antifreeze mixture contains 40% ethylene glycol Cd
(c) m =
(C2H6O2) by weight in the aqueous solution. If the 1000d − CM
density of this solution is 1.05 g/mL, what is the molar CMd
(d) m =
concentration? 1000 − dM
(a) 6.77 M (b) 6.45 M
(c) 0.0017 M (d) 16.9 M
5. The mole fraction of a given sample of I2 in C6H6 is VDPP–13
0.2. The molality of I2 in C6H6 is Subtopics: Equivalent concept
(a) 0.32 (b) 3.2
(c) 0.032 (d) 0.48
1. For acids, the number of equivalents represents
6. What is the weight % sulphuric acid in an aqueous
(a) The number of moles of H+ ions obtained from the
solution which is 0.502 M in sulphuric acid ? The
acid
specific gravity of the solution is 1.07
(b) The number of moles of the anion it furnishes
(a) 4.6 % (b) 5.67 %
(c) The charge on the anion
(c) 9.53 % (d) 22.0 %
(d) None of these
7. A sample of H2SO4 (density 1.8 g mL–1) is 90% by
2. The ratio of number of equivalents to the number of
weight. What is the volume of the acid that has to be
moles is called
used to make 1 L of 0.2 M H2SO4 ?
(a) n-factor
(a) 16 mL (b) 18 mL
(b) equivalent weight
(c) 12 mL (d) 10 mL
(c) valency
(d) oxidation number
3. What is the number of equivalents in 80 g NaOH?
(a) 2 (b) 1
(c) 4 (d) None of these

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 4. What is the number of equivalents of H3PO4 when 98 10. 74.5 g of a metallic chloride contains 35.5 g of
g of it forms a salt containing HPO42– ion? chlorine. The equivalent weight of the metal is
(a) 1 (b) 2 (a) 19.5 (b) 35.5
(c) 3 (d) 0.5 (c) 39.0 (d) 78.0
11. 0.5 g of a metal on oxidation gave 0.79 g of its oxide.

VDPP–14 The equivalent weight of the metal is

(a) 10 (b) 14
Subtopics: n–factor and Equivalent Weight (c) 20 (d) 40
12. 0.84 g of a metal hydride contains 0.042 g of
1. The Equivalent weight of an element is 13. It forms an hydrogen. Its equivalent weight is :
acidic oxide which with KOH forms a salt (a) 80 (b) 40
isomorphous with K2SO4. The atomic weight of (c) 60 (d) 19
element is 13. 27 g of a metal combines with chlorine to form 133.5 g
(a) 13 (b) 26 metal chloride. Thus, equivalent weight of the metal is
(c) 52 (d) 78 (a) 9 g (b) 27 g
2. The Equivalent weight of H3PO4 in the reaction is (c) 18 g (d) 36 g
Ca(OH)2 + H3PO4 → CaHPO4 + 2H2O 14. 40 g of a metal combines with oxygen to form 56 g of
(Ca = 40, P = 31, O = 16) oxide. Equivalent weight of metal is
(a) 49 (b) 98 (a) 40 (b) 20
(c) 32.66 (d) 147 (c) 10 (d) 80
3. 0.1 g of metal combines with 46.6 mL of oxygen at 15. 0.116 g of C4H4O4 (A) is neutralised by 0.074 g of
STP. The equivalent weight of metal is Ca(OH)2. Hence, protonic hydrogen ( H  ) in (A) will
(a) 12 (b) 24 be
(c) 6 (d) 36 (a) 1 (b) 2
4. What weight of a metal of equivalent weight 12 will (c) 3 (d) 4
give 0.475 g of its chloride ? 16. Find the equivalent Weight of Potassium
(a) 0.12 g (b) 0.24 g permanganate(KMnO4) in redox reaction with Oxalic
(c) 0.36 g (d) 0.48 g Acid (H2C2O4 . H2O) in presence of dilute H2SO4
5. The chloride of a metal has 52.8% chlorine by mass. MnO −4 + 8H+ + 5e– → Mn2+ + 4H2O
The equivalent wt. of metal is
(a) 31.6 (b) 40
(a) 31.7 (b) 35.2
(c) 39 (d) 37.6
(c) 63.5 (d) 20
17. Equivalent weight of a bivalent metal is 37.2. The
6. When a metal is burnt, its weight is increased by 24%.
molecular weight of its chloride is
The equivalent weight of the metal will be
(a) 15.87 gm (b) 145.4 gm
(a) 66.67 (b) 16.67
(c) 22.35 gm (d) 120.7 gm
(c) 33.3 (d) 24
18. The equivalent weight of an element is 4. Its chloride
7. 0.5 grams equivalent of H2S is equal to?
has a V.D 59.25. Then the valency of the element is
(a) 0.25 Moles of H2S
(a) 4 (b) 3
(b) 1 moles of H2S
(c) 2 (d) 1
(c) 0.05 moles of H2S
19. What is the n factor of H3PO4?
(d) None of the above
(a) 3 (b) 4
8. A metallic oxide contains 60% of the metal. The
(c) 1 (d) 0
equivalent weight of the metal is
20. A bivalent metal has an equivalent mass of 32. The
(a) 12 (b) 24
molecular mass of the metal nitrate is
(c) 40 (d) 48
(a) 182 (b) 168
9. The equivalent weight of iron in Fe2O3 would be
(c) 192 (d) 188
(a) 18.6 (b) 28
21. 4 moles of a substance having n-factor 2 will have
(c) 56 (d) 112.0
(a) 2 equivalents (b) 8 equivalents
(c) 4 equivalents (d) 1 equivalent

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 22. What is the n-factor of H3PO4 when it forms a salt 7. The equivalent weigh of H3PO4 in the following
containing HPO42– ion? reaction is
(a) 1 (b) 2 H3PO4 + Ca(OH)2 → CaHPO4 + 2H2O
(c) 3 (d) 0 (a) 98 (b) 49
23. One mole of a base gives 3 moles of OH– ions, what is (c) 32.66 (d) 40
the n-factor? 8. An oxide of metal has 20% oxygen (by wt.), the
(a) 1 (b) 2 equivalent wt. of metal and metal oxide are,
(c) 3 (d) 0 respectively
24. A gas having n-factor = 2 will have equivalent volume (a) 32, 40 (b) 30, 46
(a) 11.2 L (b) 22.4 L (c) 38, 42 (d) 38, 38
(c) 5.6 L (d) 44.8 L 9. The number of moles of H2SO4 that will react with 3
equivalents of base will be?
VDPP–15 (a) 3
(c) 6
(b) 1.5
(d) 2
Subtopics: Law of Chemical Equivalence 10. What weight of NaOH will react with 4 equivalents of
acid?
1. In a titration, 15.0 cm3 of 0.100 M HCl neutralizes (a) 160 g (b) 40 g
30.0 cm3 of Ca(OH)2. What is the molarity of (c) 80 g (d) 320 g
Ca(OH)2 solution ?
(a) 0.0125 (b) 0.0250
(c) 0.0500 (d) 0.200
2. When 100 ml of 1 M NaOH solution and 10 ml of 10
N H2SO4 solution are mixed together, the resulting
solution will be :
(a) alkaline (b) acidic
(c) strongly acidic (d) neutral
3. 100 cm3 of 0.1 N HCl is mixed with 100 cm 3 of 0.2 N
NaOH solution. The resulting solution is
(a) 0.1 N and the solution is basic
(b) 0.1 N and the solution is acidic
(c) 0.05 N and the solution is basic
(d) 0.05 N and the solution is acidic
4. 4.2 g of metallic carbonate MCO3 was heated in a hard
glass tube and CO2 evolved was found to have 1120
mL of volume at STP. The Equivalent weigth of the
metal is
(a) 12 (b) 24
(c) 18 (d) 15
5. 1.0 g of a monobasic acid when completely reacted
with Mg gave 1.301 g of anhydrous Mg salt.
Equivalent weight of acid is
(a) 35.54 (b) 36.54
(c) 17.77 (d) 18.27
6. How many grams of phosphoric acid would be needed
to neutralise 100 g of magnesium hydroxide ? (The
molecular weights are : H3PO4 = 98 and Mg (OH)2 =
58.3)
(a) 66.7 g (b) 252 g
(c) 112 g (d) 168 g

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