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Final Partical Exam

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15 views2 pages

Final Partical Exam

Uploaded by

altawilm93
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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1. A solution containing 4.48 ppm KMnO, had a % transmittance of 30.

9%
in a 1.00 cm cell at 520 nm. Calculate the molar ahsorptivity of KMnO, at
520 nm.

2. A solution containing 3.75 mg/100 mL of X (335 g/mol) has a


transmittance of 39.6% in a 1.50-cm cell at 425 nm. Calculate the molar
absorptivity of X at this wavelength.

3. A 2.50-mL aliquot of a solution that contains 3.8 ppm iron(III) is treated with
an appropriate excess of KSCN to form the Fe(SCN)2+ complex (molar
absorptivity of 7.00x103 L cm-1 mol-1) and diluted to 50.0 mL. What is the
absorbance of the resulting solution at 580 nm in a 2.50cm cell.

4. Describe the differences between the following and list any particular
advantages possessed by one over the other.
a. hydrogen and deuterium discharge lamps as sources for ultraviolet
radiation.
b. filters and monochromators as wavelength selectors.
c. photovoltaic cells and phototubes as detectors for electromagnetic
radiation.
d. photodiodes and photomultiplier tubes.
e. double-beam-in-space and double-beam-in-time spectrophotometers.
f. spectrophotometers and photometers.
g. single-beam and double-beam instruments for absorbance measurements.
h. conventional and multichannel spectrophotometers.

5. A portable photometer with a linear response to radiation registered 73.6 pA


with the solvent in the light path. The photometer was set to zero with no light
striking the detector. Replacement of the solvent with an absorbing solution
yielded a response of 24.9 pA. Calculate
a. the percent transmittance of the sample solution.
b. the absorbance of the sample solution.
c. the transmittance to be expected for a solution in which the concentration
of the absorber is one third that of the original sample solution.
d. the transmittance to be expected for a solution that has twice the
concentration of the sample solution.

6. A photometer with a linear response to radiation gave a reading of 685 mV


with the solvent in the light path and 179 mV when the solvent was replaced
by an absorbing solution. The photometer was set to zero with no light
striking the detector. Calculate
a. the percent transmittance and absorbance of the absorbing solution.
b. the expected transmittance if the concentration of absorber is one half that
of the original solution.
c. the transmittance to be expected if the light path through the original
solution is doubled.

7. Why is iodine sometimes introduced into a tungsten lamp

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