TA1 Temperature, Heat - Internal Energy
TA1 Temperature, Heat - Internal Energy
1.
A
Relationship between Kelvin scale and Celsius scale: θ T
10. kWh J
scale
Upper fixed point: Iti 49k celsius
HEEL # HI o
Absolute zero (0 K,-273 °C): Lowest temperature, average KE of molecules has a minimum value.
2. Thermometers:
(i) Requirement of a thermometer
The thermometer is a device with some measurable physical properties which change with
t
temperature. T leads to those properties
t
Physical properties that can be used to measure temperature:
.÷÷÷÷:
(a) liquid volume
inle
(b) gas volume or gas pressure
÷
(c) resistance
tt t3.y t , Ahthtka
. . .
.
.. in .
FedEx . .
Fap FA
blab gas EEE FIE glass tube
1
EA.AE#F4xYFIhMEEFEEt Tt Vt lt
(ii) Calibration of a liquid-in-glass thermometer jet Calibration
Liquids expand and contract uniformly with temperature. (ΔV ∝ ΔT) V π r2 l V∝l
not
length touching
at 0% water
to
IFE steam
T
melting
ice
𝒍 𝒍 ← oEEOEFa4¥Ee
𝒍 𝒍
-
oooocfa.hn#Ee0-Too=h-ho-
#
Example: When a mercury thermometer is immersed in melting ice and then in steam, the lengths of the
mercury thread in the stem are respectively cm and cm. When the thermometer is put in a
water bath, the length of the thread is cm, What is the temperature of the water bath?
← Fist . THE
boo -
lo
← 982¥ Subtext
= 22-2
0.45
% =
← Yf 3¥ Answer A- unit
0=4.58
(iii) Other types of thermometer Q7p9
Rotary thermometer
←
Expand
more
,
become
longer
think 'EE¥AEE ,
2
IEEE curve
Resistance is affected by temperature
Resistance thermometer
tB¥*I¥¥'*←*¥*
- variation of resistance R with temperature θ
Thermistor thermometer
Rob semiconductor 𝑹 𝑹 .
O O 𝑹 𝑹
izz Et # P'Here
-resistance of thermistor decreases when temperature increases .it#....l.38tHH
Example: The graph below show how the electrical resistance R of three different circuit elements change
PP with temperature θ. Which of the circuit elements can be used to measure temperature?
r r
x
Example:
Ftir gas →
=ztrILok ,
hE4YktmphE¥÷EiokFIE
glass
-
liquid in -
E)
-
The Figure above shows an air column trapped by a small mercury thread inside a uniform
capillary tube. The set-up is heated by a water bath. The length of the air column L is measured
at various temperature θ. Some of the results are tabulated below:
Assume that length L increases linearly with temperature θ throughout. Estimate the length of
the air column when the temperature indicated by the thermometer is C. ( marks)
Gift
soar
tg÷T=E4
:{I :c !
Foo -_
. So-64
74mm
in
.
3
3. Heat
(i) Definition of heat Q
Heat is the process to transfer energy as a result of temperature difference between two bodies.
The amount of energy that is transferred from high to low temperature is called heat.
heat up cold objects
Unit of heat: J (joule) I .
Heat always flows from high temperature region to low temperature region by heating.
hotter ,
faster,
KE
ET EN more
Internal energy E is the total energy stored inside the material of a body. (Heat cannot be stored) -
Etty store
internal
In Molecular Theory,
-
µ distance
a
Internal energy total kinetic energy of the molecules total potential energy of the molecules
Total number of molecules in the body depends on the mass of the body.
¥
energy.
( ) A copper block has greater internal energy when it is hot than when it is cold.
( ) Water at C has greater internal energy than a block of ice of the same mass at C.
Example: A bottle of . kg water and a bottle of . kg water have been stored in a refrigerator for a
few days. Which of the following statements are correct?
( ) The temperatures of the two bottles of water are equal.
¥
( ) The average kinetic energy of the water molecules in the two bottles is equal.
( ) The total potential energy of the water molecules in the two bottles is equal.
-
(ii) Change of internal energy different mass
← At '#aK¥i
The internal energy of a body can be increased by RT unchanged during
change of state changeof
state
or
- heating Q
- doing work w
5
Example: Which of the following statements about heat is/are true?
¥
( ) Heat is used to describe the total energy stored in a body.
( ) Heat is used to describe the energy transferred from one body to another as a result of a
temperature difference between them.
( ) A body's internal energy is increased when it is heated.
Example: When two objects are in contact, there must be heat transfer from the object with more
(T/F) internal energy to the one with less internal energy. F i
¥
( ) A measure of the degree of hotness of the object.
( ) A measure of the internal energy of the object.
( ) A measure of the average kinetic energy of the molecules of the object.
(iii) Measurement of energy transfer by a joulemeter
P unchanged
tr
A heater can give out heat at a steady rate when connected to a power supply.
The heater should get energy from the power supply through a joulemeter.
Procedure of measurement:
( ) Record the initial reading E1 and the final reading E2 on the joulemeter before and after heating.
5. Power Qcd
Pcw ) =
t
(i) Definition of power
W Is = -551
-
P V I, where V is the voltage given to the heater and I is the electric current through the heater
( ) Connect a voltmeter in parallel across the heater to measure the voltage V across the heater.
( ) Connect an ammeter in series with the heater to measure the current I through the heater.
19.2 =
z÷x6o
F- = 28803
(iii) Measure the power of a heater by use of a joulemeter
Measure the initial reading and the final reading of the joulemeter.
The difference of the two readings gives the energy E supplied by the heater.
7
From the graphs ,
6. Specific heat capacity
when DT and mA ,
FE 7¥ 5- Q,
5¥ Bks Fa k¥3 OT Ne m
material
Ff the
-
m tf 07 , FA abt
tank's material Eti
5¥ As hit
a Q ,
Rt baby Q
Specific heat capacity of a substance is the heat required to raise the temperature of 1 kg of the
𝑸
𝒄 , where unit of c : J kg-1 °C-1
𝒎∆𝑻
Relation between heat transferred Q or internal energy changed E with the change of temperature ΔT:
Different states of the same material have different specific heat capacity.
- mass
- temperature
- shape
- types of container
8
Example: Which of the following pairs of objects have different specific heat capacities?
A. kg of water and kg of water mass X
O
B. kg of liquid naphthalene and kg of solid naphthalene stater shape X
C. a rectangular block of aluminium of mass kg and a cylindrical block of aluminium of mass kg
D. kg of oil in a glass container and kg of oil in a metal container container X
Example: If there is no heat flow between two bodes when they are in contact, then the two bodies must
R
have the same
happen if there is
only temperature
0
A. temperature difference .
B. Internal energy.
C. specific heat capacity.
D. specific latent heat of vaporization.
Q
Example: An equal quantity of heat is supplied to each of the following substances and the corresponding
rises in temperature are recorded. Which of the following substances has the smallest specific
¥5
same
heat capacity? C
M OT W
Edita #
Substance Mass (kg) Rise in temperature ( C) MOT MOT Eth , c.
10
A. P .
12.5
B. Q .
12
C. R .
O
D. S . 13.5
𝑄 𝑃𝑡 or 𝐸 𝑃𝑡 ← EE
t
Assume that there is no heat lost to the surroundings.
𝑷 𝒎𝒄∆𝑻
- heat lost to the apparatus (the container, the stirrer, the thermometer, ... )
supplied 8%45417
'
E
'
d-
𝑷 𝒓% 𝒎𝒄∆𝑻 or 𝑷 𝒎𝒄∆𝑻 𝑬𝒍𝒐𝒔𝒔
where r is the heat loss percentage and Eloss is the heat loss
9
m c
Example: A heater supplies energy to a liquid of mass . kg and specific heat capacity J kg- C-
contained vessel of negligible heat capacity. Assume that the heat exchange with the
surroundings can be neglected. If the temperature of the liquid rises from C to C in s,
the power of the heater is OT t
P pf=mcoT
PC = 0.54000700 -
lo )
17=1200 W
p m c
Example: A heater of power W supplies energy to a liquid of mass . kg and specific heat capacity
J kg- C- contained in a vessel. The initial temperature of the liquid is C. The heater is
e
switched on for minutes. Calculate the final temperature θ of the liquid, if of heat supplied
TOT r
by the heater is lost to the surrounding air and the apparatus.
Ptcl -
r%)=mcDT
) ( 0--15 )
25014×6074-6%171.60500
23.6°C O -
A
3 Sig .tig take
m a t
Example: A copper wire of . kg is initially at the room temperature of C. A heater takes s to raise
OT
the temperature of the copper wire by C. If the total energy lost to the surroundings is
F-loss J, calculate the rate of energy supplied by the heater. Given at the specific heat capacity of
C-
copper is J kg- C- . ( p
Pe = MOOT + Floss
PG5O)= 0.81385×500 ) -18500
p
-
-
650W
i. the rate of energy supplied by the heater 13650W .
Example: In a hotel, the hot water in the central storage tank is supplied to the radiator in a room for
warming. The temperature of hot water ion ill the central tank is kept at C. In a time a hourst
m kg of water is circulated to the room. During the transfer, of the energy is lost. When the
water leaves the room, the temperature drops to C. OT E supplied -_ moot
Specific heat capacity of water is -
J kg C . (-
E= ? diet tho
(a) Find the heat given out by the hot water to the room during this time.
heat
loss
supplied
the
F- = MCDTCI 18%
-
) to
room
(85-50) Cl 18%)
75014200)
-
a-
9.0405×1073=9.04×1073
=
10
p =?
(b) Estimate the average power output by the hot water to the room.
E- PE
9.0405×102 =p (4×60×60)
17=6280 W
7. Heat capacity
(i) Definition of heat capacity C
Heat capacity C is the energy E required to raise the temperature of a body through 1°C
←
15¥48 A substance,
.
J
substance
E body
𝑪 𝒎𝒄
P = 1690W
11
C- me
Example: Which of the following can increase the heat capacity of a copper block?
¥
( ) Increase the mass of the block.
nEoq÷÷Ad}a=¥i÷¥E¥
E - COT
( ) Increase the temperature of the block.
x ( ) Change the shape of the block.
Example: A training pool B is located next to the main pool A. The training pool B has a smaller area and is
shallower. If the pools are under the sunlight at the same time, which of the following statements
about the rise in the water temperature of the two pools is correct? Assume that the initial water
temperatures of the pools are the same.
O
A. The water temperature of training pool B rises faster because it is shallower.
B. The water temperature of training pool B rises faster because it has a smaller surface area.
C. The water temperature of main pooI A rises faster because it is deeper.
D. The water temperature of main pool A rises faster because it has a larger surface area.
Example: Two liquids X and Y are heated by two different heaters. The energy supplied, the liquids' masses
G- ET
'
and temperature rises are recorded as follows.
Liquid X Liquid Y C×=24oo0_ eye 25
Energy supplied / J
Mass / kg . .
20--120 = 720
.
Temperature / C
Which of the following statements are correct?
G- a- ¥ ,
( ) The heat capacity of X is larger than that of Y.
if ( ) The specific heat capacity of X is larger than that of Y. Galton 4=3600
× ( ) The heat capacity of X determined remains the same if the experiment is repeated by doubling
the mass of X. G- me mA , CA
,
Water has an exceptionally high value of specific heat capacity of c 4200 J kg-1 °C-1
- water shows a smaller temperature rise when given the same amount of energy.
i.e. The body temperature changes slowly even when the surrounding temperature changes sharply.
12
Temperature difference between winter and summer (or day and night) near the coastal area of
similar latitude and altitude is smaller compared with that of inland area,
c of aluminium
A heater connected to a power supply through a joulemeter is put into the water. The energy supplied
A thermometer is put into the water to record the change of temperature ΔT.
𝑸
The specific heat capacity c is then found by 𝒄
𝒎∆𝑻
A stirrer should be used to stir water before taking readings to ensure that the water has uniform
temperature.
- to reduce the heat absorbed by the cup since the specific heat capacity of polystyrene is negligible
13
A lid should cover the cup to reduce heat lost to surrounding air.
The heater should be completely immersed into water but do not touch the bottom of the cup.
Allowed for the water to reach the final maximum temperature after the heater is switched off.
Since there is heat lost to the surroundings, the value of the specific heat capacity measured in the
f. i. CT
←
𝑸 Q=mcOT + Floss
experiment would be higher than the actual value. (By 𝒄 )
𝒎∆𝑻
The reason is that the energy supplied by the heater is greater than the energy actually absorbed by
the water.
P M
Example: A W immersion heater is used to heat . kg of water, which is being stirred by a stirrer. After
t minutes, the water temperature increases from C to C. What is the estimated energy loss
in this period? Ecosse ? DT c
(Neglect the heat capacity of the beaker) Given: specific heat capacity of water J kg- C-
Pt -_mC0Tt Eioss
10013×607=0 .5C42oo ) (30-25)-1 Floss
F- loss '
- Hoo ]
14
(b) (i) Plot a graph of E against m in the following figure. A scale of cm to . kJ and . kg is
used.
Elk ]
"
t
x
5 -
x
4 -
f -
O #÷%TYkg
Two axes labelled with correct units Correct scales used y = m X t C
(ii) Using the graph plotted in (b)(i), find the specific heat capacity of liquid X.
slope 0¥ =
= I = 24500
Slope = ¥ = COT
= c (I O )
24500
' I
24505kg
- -
E = me OT
12300 = It (41-29)
too I Ft heat loss
kg c=¥of-
=
1025 J
- -
t
(b) The value obtained in (a) is found to be higher than the actual specific heat capacity of the
metal. Suggest a reason for this and explain your answer briefly. ( marks)
heat loss the
There is surroundings
to .
energy supplied by
so that the the heater
(c) Suggest TWO improvements on the set-up to increase the accuracy of the experiment. ( m)
thermal
insulating material
like cotton wool .
(d) Is the above method suitable for finding the specific heat capacity of wood?
Explain briefly. ( marks)
No .
Wood is a
poor conductor of heat .
16
Example:
Too =RRo_Ro
Roo -
=
42-102=140151 -
102.00
12=125 I 1 I .
energy supplied
the is smaller than the actual value ,
thus ,
the
experimental value of Cw is lower
than the actual value .
cw=E treat
40°C
17
10. Mixture of hot and cold substances
(i) Flow of heat
If bodies with different temperatures are put together, heat would flow from the high temperature
body to the low temperature body until they achieve thermal equilibrium, i.e., same temperature.
Energy lost by the hot body Energy gained by the cold body
Note that the temperature rise of the cold body may not be equal to the temperature drop of the
hot body.
Example: When hot water is mixed thoroughly with cold paraffin in a polystyrene cup, the energy gained by
(T/F) the paraffin is equal to the energy lost by the water. T
When hot water is mixed thoroughly with cold paraffin in a polystyrene cup, the changes in
temperature of the water and paraffin are identical. F
Example: The specific heat capacity of a metal is measured using the following method:
re
look
.
A metal block is first immersed in boiling water for some time. The block is then transferred to a
cup of cold water. After a while, the temperature of the water is measured. The result of the
experiment is as follows:
Mb Mw
Mass of metal block . kg Mass of water in the cup . kg
OTW
Initial temperature water in the cup C OTW Final temperature of water in the cup C
Find the specific heat capacity of the metal (in J kg- C- ). (Given: Specific heat capacity of water
J kg- C- .) Cb
Cw
Mw Cw OTW
Mb Cb OTB =
IET
18
Cb =MwCw0#
Mb OTB
Example: Example: The result obtained in the above example is found to be higher than the true value of
the specific heat capacity of the metal. Which of the following is a probable reason?
OA. Some hot water is still adhered to the metal block when the block is transferred to the cold
water. E OTWKK - OTB ha # E
{
-
B. Some energy is lost to the surroundings when the metal block is transferred to the cold water.
OTW C. Some energy is absorbed by the cup.
Eretz D. The temperature of the metal block is still higher than C when the final temperature of the
water in the cup is measured.
075k¥
Example: Yunnan Guoqiao-mixian is a famous Chinese food. Customers ordering the food are served with
the following:
a bowl of hot soup with a layer of oil on the surface,
a dish of thin slices of raw meat, and
a bowl of pre-cooked mixian (noodles)
The meat is first put into the soup. Later, the mixian is also added.
(a) Explain why the meat has to be sliced into thin pieces.
To increase the surface area between the meat and
the for faster heat transfer
soup .
(b) What is the purpose of adding a layer of oil to the bowl? ( marks)
Reduces the heat lost the soup to the
surrounding air .
From
(d) A customer places the mixian into the soup before adding the meat. Explain why this is
undesirable. ( marks)
the soup first
If the miyan is placed into would ,
the
temperature of the soup largely drop ,
19
11. Temperature against time graph
(i) Features of a temperature - time graph
A temperature-time graph shows the variation of the temperature of a substance with time when the
When the heater is just switched off, temperature still rises for a short period of time since the
heater is still hotter than the substance, heat continues to transfer from the heater to the substance.
A short while after the heater is off, temperature starts to fall since there is heat lost to the
surroundings.
After the power supply is switched off, the temperature rise should not be recorded immediately but
After a long time of cooling, the temperature should drop down to the room temperature (R.T.).
∆
By 𝐸 𝑃𝑡 𝑚𝑐𝛥𝑇, 𝑦 𝑚𝑥 𝑐, 𝑠𝑙𝑜𝑝𝑒
∆
I pq=mcbT
⸫ 𝑠𝑙𝑜𝑝𝑒
Pac =
For the same power supplied and with the same mass: slope ∝
⸫ A substance with greater specific heat capacity gives a smaller slope of temperature - time graph.
) larger P
) smaller m
) smaller c
20
Pt = moot
Example: The graph shows the variation of the temperature of liquid with time when the liquid is heated by
in
Pa W heater. The mass of the liquid is kg. Find the specific heat capacity of the liquid. Assume
all the energy given out by the heater is absorbed by the liquid. G- ?
stipe
=
If Emc =
Eo=4I
12003kg tool
-
e. =
Example: Equal masses of liquids X, Y and Z are separately heated. The graph shows the variation of the
energies absorbed by the liquids with their temperatures. Let cx, cy and cz be the specific heat
capacities of X, Y and Z respectively. Which of the following relations is correct?
A. cx cy cz
B. cx cy cz
slope = Inc
O
C. cx cy cz
D. cx cy cz
If a substance is at a higher temperature than the surrounding room temperature, it will lose heat
The rate of heat loss depends on the temperature difference. The greater the temperature difference,
the greater is the heat loss. Thus, the rate of heat loss is not constant.
If a substance is at a lower temperature than the surrounding room temperature (R.T.), it will gain heat
21
Example:
f- my
tr
E -
- me DT
P tf
m = PV = 1000 X 15 =
1500kg
E =
mo OT ( t -
15%7
= 4500 ) ( 4200 ) ( fo -60 ) ( t 15% )
-
= 1 .
071 X 108 J
= I 07 X
,
108 ]
22
4.5×103
E =
Pt
to 071×108=4.5 X 103 t
i t =
23800 S
= 6.61 h
23