2019 S Sip PSC I Learner
2019 S Sip PSC I Learner
GRADE 12
(Page 1 of 73)
SESSION 1: ELECTROSTATICS
TYPES OF CHARGES:
NB! Use the Van de Graaf generator to demonstrate the effect of charges.
Learners should be able to identify forces and be able to draw free body diagrams.
Coulomb’s Law
The electrostatic force of attraction or repulsion that two charges at rest exert on each other
is directly proportional to the product of the magnitude the two charges and inversely
proportional to the square of the distance between their centres.
KQ1 Q2
Fnet = No need to substitute the negative
r2
sign on the negative charge
Where:
charge.charge
F is the force in Newton’s (N)
Q1 and Q2are charges in coulombs (C)
r is the distance between the two charges in metres (m)
kis proportionality constant (Coulombs Law constant) with the value of
9x109N∙m2.C-2
Worked Example 1
Two point-like charges carrying charges of +3 nC and −5 nC are 2m apart. Determine the
magnitude of the force between them and state whether it is attractive or repulsive.
Solution 1
Step 1: Data
r = 2 m; k= 9x109N∙m2.C-2
r2
Step 3: Determine the magnitude of the force
F = kQ1Q2
r2
(2)2
Thus the magnitude of the force is 3, 38 × 10−8N. However since both point charges have
3, 38 × 10−8N
opposite signs, the force will=be attractive.
Worked example 2
Two tiny spheres A and B with charges – 4 nC and +4 nC respectively, are placed as in the
sketch. They are fixed while a third charge C of + 4 nC has its centre placed at a distance of
40 mm from the centres of both A and B. 1 nC = 1 nano coulomb = 1 x 10 – 9 C. (frictionless)
(a) Calculate the magnitude of the Coulomb force that exists between charge A of – 4 nC and
the charge C of +4 nC charge.
(b) In which direction will the sphere C move?
(c) Calculate the magnitude of the acceleration with which the sphere C will start moving
from its position as indicated, if it has a mass of 200 g.
Solution 2
Draw a free body diagram showing the forces acting on charge C. For C, take as positive the
direction to the left.
Let C interact with A first, and then with B
The magnitude of the electric field (electric field strength) at a point in an electric field is the
force per positive unit charge (thus + 1C) at that point.
force
Electric field strength=
charge
F
Or in symbols, E
q
Unit: if the electrostatic force F acts on the charge in Newton (N), the charge q is in coulomb
(C), then the electric field strength (E) is in N∙C-1 (Newton per Coulomb). As we will see later,
the electric field strength can also be measured in Volt per metre (V∙m -1).
Direction: electric field strength is a vector quantity because it has magnitude and direction.
A direction of electric field strength E at a specific point in an electric field is the same as the
direction of the electrostatic force that a positively charged particle will experience at that
point. The positively charged particle will thus move in the direction of the field and a
negatively charged particle will move against the field.
The force experienced by a test charge when placed in an electric field is given by;
F=qE
Worked example 3
If the magnitude of the electric field strength (intensity) is 3 x 10 6 N • C–1 at a point,
calculate the magnitude of the force acting on a charge of – 7 nC placed at that point.
F = qE
= 7 × 10-9 × 3 × 106
= 0.021 N
Electric field at a point due to a number of point charges
The force between two electric charges is given by:
kQq
F = r2 (If we make the one charge Q and the other q.)
Therefore, the electric field can be written as
𝑘𝑄
𝐸 = 𝑟2 (where Q is the charge setting the field)
N. B. As with Coulomb’s law calculations, do not substitute the sign of the charge into the
equation for electric field. Instead, choose a positive direction, and then either add or subtract
the contribution to the electric field due to each charge depending upon whether it points in
the positive or negative direction, respectively.
Worked Example 4
Question: Calculate the electric field strength 30cm from a 5nC charge.
Solution 4
Step 1:Data.
Q = +5nc = +5 × 10-9 C
r = 30 cm = 0.30 m
k = 9x109N∙m2•C-2
Step 2: Select a suitable equation
kQ
E=
r2
𝑘𝑄
𝐸=
𝑟2
= (9 x 10-9) (5 x 10-9
(0, 3)2
Worked example 5
R and S are two points in the electric field of a small negatively charged sphere Q, Two
=5 × 10-16 N∙C-1
charges of Q1 = +3nC and Q2 = −4nC are separated by a distance of 40cm. What is the
electric field strength at a point that is10cm from Q1 and 30cm from Q2? The point lies
between Q1 and Q2.
Solution 5
Step 1: Determine what is required:
We need to calculate the electric field a distance from two given charges.
We need to work out the electric field for each charge separately and then add them to get
the resultant field.
𝑘𝑄
𝐸=
𝑟2
= (9 × 109) (3 × 10−9)
(0, 1)2
= (9 × 109) (4 × 10−9)
(0.3)2
We need to add the two electric fields because both are in the same direction.
The field is away from Q1 and towards Q2.
Therefore, = 4,00× 102 N∙C−1
Etotal= 2,70 × 103 + 4,00× 102 = 3,10 × 103N∙C−1
POTENTIAL DIFFERENCE
The potential difference between two points in an electric field is defined as the work
required to move a unit positive test charge from the point of lower potential to that of
higher potential.
OR
The electrical potential difference is the difference in electrical potential energy per unit
𝑊
charge between two points ( 𝑉 = 𝑄 ).
𝑊
Unit: The electrical potential difference is measured in volts (V). Using the equation 𝑉 = 𝑄
the unit will be joule per coulomb (J∙C-1) which is the same as volt, thus electrical potential
difference is also called voltage.
Worked example 7:
What is the potential difference between two points in an electric field if it takes 600J of
energy to move a charge of 2C between these two points?
Solution 7
Step 1: Data.
QUESTION 1 GP 2015
Two identical conducting spheres A and B with charges of Q1and Q2respectively are placed
in fixed positions along the same straight line as shown in the diagram below.
Spheres A and B are placed 30 cm from each other. Point P is positioned 30 cm to the right
of sphere B on the same straight line.
The charge on sphere B is positive. The net electric field Enetat point P as a result of the two
charges Q1and Q2is towards the right as shown in the diagram below.
1.1 What is the sign of the charge on sphere A? Give a reason for the answer. (3)
1.2 The net electric field at point P is 1 600 N⋅C-1 to the right and the charge on (7)
sphere B has a magnitude of +12 nC.
Calculate the magnitude of the charge on sphere A.
A proton is placed at point P without changing the charges and positions of spheres A and B.
1.3 Calculate the net electrostatic force experienced by the proton. (4)
[15]
When the spheres are separated it is found that 5 x 106 electrons were transferred from
sphere M to sphere N.
2.1 What is the net charge on sphere N after separation? (3)
2.2 Write down the net charge on sphere M after separation. (2)
The charged spheres, M and N, are now arranged along a straight line, in space, such that
the distance between their centres is 15 cm. A point P lies 10 cm to the right of N as shown
in the diagram below.
2.3 Define the electric field at a point. (2)
2.4 Calculate the net electric field at point P due to M and N. (6)
[13]
QUESTION 3 DOE FEB/MAR 2016
A sphere Q1, with a charge of -2,5 μC, is placed 1 m away from a second sphere Q2, with a
charge +6 μC. The spheres lie along a straight line, as shown in the diagram below. Point P
is located a distance of 0,3 m to the left of sphere Q1, while point X is located between Q1
and Q2 . The diagram is not drawn to scale.
3.1 Show, with the aid of a VECTOR DIAGRAM, why the net electric field at (4)
point X cannot be zero.
3.2 Calculate the net electric field at point P, due to the two charged spheres Q1 (6)
and Q2.
[10]
4.1 Calculate the magnitude of the force exerted by each sphere on the other. (4)
4.2 By what factor will the magnitude of the force in QUESTION 4.1 change if the distance
between the spheres is halved? (Do not calculate the new value of the force.) (1)
4.3 Calculate the net electric field at point P as shown in the diagram above. (6)
4.4 The spheres are now brought into contact with each other and then returned to their
original positions. Now calculate the potential energy of the system of two charges. (5)
[16]
SESSION 2 :CURRENT ELECTRICITY
PRIOR KNOWLEGDE
An atom is the smallest particle of an element.
CHARGE
The unit of charge is the Coulomb. A Coulomb ( C ) consists of 6,25 x 1018 electrons.
A coulomb is the quantity of charge that passes through a conductor when a current of one
ampere flows for one second.
Electrical charges may be positive or negative. A positively charged object is caused by a
deficiency of electrons while a negatively charged object is caused by an excess of electrons.
Charges carry energy to the components of a circuit.
ELECTRICAL SYMBOLS
The total emf of a battery of cells connected in series is equal to the algebraic sum of the
emf’s of the individual cells.
ℰT = ℰ1 + ℰ2 + ℰ3 + …
NB: The advantage of connecting cells in series is that the total emf is increased thus
producing a more energy.
Cells connected in parallel:
Cells are connected in parallel when their positive terminals are connected to each other and
the negative terminals are connected to each other as indicated in the sketch below:
The total emf of a battery of cells connected in parallel is equal to the emf of a single cell,
provided that all the cells have the same emf.
NB:The advantages of connecting cells in parallel are that the cells last longer.
The total emf of a battery of cells connected in parallel is equal to theemf of the individual
cells.
ℰT = ℰ1 = ℰ2 = ℰ3 = …
Examples:
Each of the cells below has an emf of 2 V. Calculate the emf of each of the following
batteries:
8V
2V
6V
SIMPLE CIRCUIT
The potential difference between two points in a circuit is the energy required to move one
coulomb of charge between the points.
It is measured using a voltmeter ‘v’ which should always be connected in parallel to the
component / resistor as illustrated in the diagram below.
As the charges move through a resistor,
from point A to B they release energy.
The voltmeter reads the difference in the
potential energy of the charges at point
A and point B. Current will not flow
through a voltmeter because the
voltmeter has a high resistance.
Example 1:
Calculate the potential difference between two points if 20 J of work are required to move a
charge of 2 C.
W 20
V 2V
Q 2
Example 2:
Calculate the work done in moving a charge of 5 C through a potential difference of 2V.
W = QV = 5 x 2 = 10 J
CURRENT (I)
An electric current is the rate of flow of charge (positive or negative) from one point to
another in an electrical circuit. It is measured in Amperes (A).
An ammeter measures the strength of an electric current. It has a low resistance and is
connected in series in a circuit.
Conventional current is the flow of positive charge and its direction is from the positive
terminal through the circuit to the negative terminal of a cell.
Since a current in a metal is conducted by negative electrons, the electron current flows from
negative to positive. However, current direction in metals is always based on the direction
that a positive charge would take and is therefore the direction of a conventional current, i.e.
from positive to negative.
Example 1:
Q 5
I 2,5 A
t 2
Example 2:
Calculate the quantity of charge passing a point in a circuit when a current of 5 A flows for 10
s.
Q = It = 5 x 10 = 50 C
CONDUCTION IN A METAL + - +- +- + -+ +- + - +
- - - -
+ +- + - +- +-+ + -+
- - - - - -
In a metal, the atoms are packed closely in a crystal + - + + + + - + -+ -+
lattice.
The outermost electrons of the metal atoms are
held loosely
and can escape the attractive forces of their nuclei
to form
Mobile electrons Positive atomic
positively charged metal ions. These electrons are residues (ions)
called free
(delocalized) electrons and move around at
random.
If a potential difference is applied across the ends of the conductor, an electric field is set up
in the conductor. Negatively charged electrons are attracted to the positive terminal while the
metal ions remain stationary because they are held in a crystal lattice. The movement of
electrons is impeded by collisions with the positive metallic ions causing resistance. Every
electron that leaves a conductor at the positive terminal is replaced by another from the
negative terminal. The overall charge of a conductor is therefore neutral.
RESISTANCE (R)
Resistance is the ratio of the potential difference across a resistor to the current in the
resistor. It is the opposition to the flow of charge.
A good conductor has a low resistance and a poor conductor has a high resistance.
Resistance is caused by collisions between electrons and metallic ions that interfere with the
flow of charge.
The following factors affect the resistance of a conductor:
(1) type of metal used e.g. copper wire has less resistance that nichrome wire.
(2) length of the conductor. The longer the conductor the higher the resistance.
(3) thickness (or cross-sectional area). The thicker the conductor the lower the resistance.
(4) temperature. The higher the temperature the higher theresistance.
An ohm is equal to one volt per ampere. It is the resistance of a conductor when a potential
difference of one volt causes a current of one ampere to flow through it.
Example:
Calculate the resistance of a conductor when a current of 2 A flows when the potential across
its ends is 10 V.
V 10
R 5
I 2
VT = V 1 + V 2 + V 3
The total resistance of a combination of resistors connected in series is equal to the algebraic
sum of the component resistors.
VT = V 1 + V 2 + V 3
IR = IR1 + IR2 + IR3(Divide by the common factor I.)
RT = R1 + R2 + R3
Example:
RT = R1 + R2 + R3= 2 + 3 + 9 = 14
In the accompanying diagrams, a cell with an emf of 10 V and negligible internal resistance is
connected in parallel with a 2 resistor and a rheostat. The resistance of the rheostat is
adjusted to vary the total resistance of the circuit thus varying the current and potential
difference.
Diagram 1 Diagram 2
10 V 10 V
0 0
3 8
2 2
V1 V2 V1 V2
The
resistance of the rheostat is increased from 3 in Diagram 1 to 8 in Diagram 2 causing a
different division in potential difference across the resistors.
V 10
In diagram 1: RT = R1 + R2 = 2 + 3 = 5 Ω I 2A
R 5
V1 = IR = 2 x 2 = 4 V and V2 = IR = 2 x 3 = 6 V
VT = 4 +6 = 10V
V 10
In diagram 2: RT = R1 + R2 = 2 + 8 = 10Ω I 1A
R 10
V1 = IR = 1 x 2 = 2 V and V2 = IR = 1 x 8 = 8 V
VT = 2 + 8 = 10V
OR This illustrates that when the
resistance of the rheostat
R 2 R 3
Diagram 1: v 1 V 10 4V v 2 V 10 6 V increases the potential
R 5 R 5 difference across the rheostat
R1 2 R2 8 also increases but the total
Diagram 2: v V 10 2 V v V 10 8 V
R 10 R 10 potential difference in the
circuit remains the same.
Resistors connected in parallel
IT = I1 + I2 + I3
The reciprocal of the total resistance is equal to the sum of the reciprocals of the resistances
of the component resistors.
IT = I1 + I2 + I3
VT V1 V 2 V3
(Divide by the common factor, V.)
RT R1 R 2 R 3
1 1 1 1
RT R1 R 2 R 3
Example:
6
1 1 1 1 1 1 1 1 2 6 9
R 0,67
3 RT R1 R 2 R 3 6 3 1 6 6
1
Consider the following combination of resistors connected in parallel that act as current
dividers.
The current flowing through resistors connected in parallel will be inversely proportional to
their resistances, i.e. the greater the resistance the smaller the current.
The ratio of the resistances is 2: 1 (total 3). Two-thirds of the current will therefore flow down
one resistor and the remaining one-third down the other resistor. The larger current will flow
down the resistor having the smaller resistance.
2
1 resistor: 3 2A
3
1
2 resistor: 3 1A
3
OHM’S LAW
Ohm’s Law states that current strength is directly proportional to the potential difference
between the ends of a given resistor provided that temperature remains constant.
Mathematical formula: V = IR
1 0,5 1,0 2
2 1,0 2,0 2
3 1,5 3,0 2
4 2,0 4,0 2
5 2,5 5,0 2
V = RI + 0
y = mx + c
POWER
Power is the rate at which work is done.
W
P , where P = power in watts (W), W = work in joules (J) and t = time (s).
t
Example 1:
Calculate the power when 100 J of electrical energy is used in 2 seconds.
W 100
P 50 W
t 2
Example 2:
Calculate the electrical energy used when a 100 W electric bulb burns for 2 minutes.
W = Pt = 100 x 2 x 60 = 12 000 J
Other formulae for power and work:
W = QV = VIt (Substituting It for V)
W VIt
P VI
t t
V V2 V
P VI V (Substituting forI )
R R R
Electricity Cost
Deduce that the kilowatt hour (kWh) refers to the use of 1 kilowatt of electricity for 1
hour.
Calculate the cost of electricity usage given the power specifications of the appliances
used, the duration and the cost of 1 kWh.
ESKOM or local municipality charges a tariff per kWh used. To calculate the cost of
electricity, we multiply the kilowatt-hour (energy units) reading on the meter by the unit
price per kilowatt-hour.
Energy units (E)= power(P) x time(t)
Where: energy units are measured in kWh, power in kW and Time in hours
Cost = E x price per kWh
Examples
1. A heater marked 2000W/ 3000W is switched on for 4 hours. For the first hour, it is on the
highest setting, and for the last 3 hours, it is on lowest setting.
1.1 How much energy does it transfer to the room in kWh? (9kWh)
1.2 What is the cost of heating the room if the electricity costs 70c per kWh? (R6.30)
2. The reading on the electricity meter shows that 30kWh of energy have been supplied to a
house during one day.
2.1 What is the average power consumption (per hour) of the house in this time?
(1,25 kW)
2.2 Electricity is charged at 70c per kWh. How much will the electricity bill be for that
day? (R21,00)
Emfis the maximum energy dissipated by a battery per coulomb / per unit charge passing
through it.
OR
The maximum work done by a battery per coulomb / per unit charge passing through it.
It is equal to the potential difference across the terminal of the battery when no charges are
flowing in the circuit.
Since a cell has resistance, energy is used to overcome the internal resistance when current
flows. This results in a decrease in potential difference across the terminals because less
energy per coulomb is available to drive a current around the external circuit. The decrease
in potential difference is called the lost volts effect.
Internal resistance is the opposition to the flow of charges within the cells that make up the
battery.
Emf = potential difference + energy used per coulomb to overcome internal resistance.
ℰ = V + Ir where ℰ is the emf (V), V is the potential difference (V), Iis the current (A) and r is
internal resistance ().
Example 1
In the accompanying circuit diagram, a battery has an emf of 30V. Resistance of the battery
and wires is negligible
4
6 6,6
X Y
6
30 V
Calculate:
Example 2: V1
0,5
2. Calculate the following when switch S is closed:
2.1 the total resistance of the circuit.
2.2 the reading on A
2.3 the reading on V2
2.4 the charge passing through A in 2 minutes.
2.5 the power used by the 0,5 resistor.
Solutions
1. V1 = 5 x 2 = 10 V V2 = 0 V and A = 0 A
1 1 1 1 1 1 2 3
Resistance of resistors in parallel: R // 2
R// R 1 R 2 6 3 6 6
V 10
2.2 A: I 2A
R 5
2.3 V2: V = IR = 2 x 2 = 4 V
(The resistance between the points to which the voltmeter is connected is equivalent
to the resistance of the parallel combination of resistors. The total current flowing
through the two resistors is 2 A.)
2.4 Q = It = 2 x 2 x 60 = 240 C
QUESTION 1
Two identical resistors P and Q are connected in the circuit as shown below. The
cell has an emf ‘ℰ’ and negligible internal resistance. Switch ‘s’ is initially CLOSED.
Which ONE of the following combinations of changes will occur in Q and V when
switch ‘s’ is OPENED?
Two identical resistors P and Q are connected in the circuit as shown below. The
cell has an emf ‘ℰ’ and an unknown internal resistance. Switch ‘s’ is initially
CLOSED.
Which ONE of the following combinations of changes will occur in Q and V when
switch ‘s’ is OPENED?
6.1 In the circuit in Figure 1, the battery, of emf 15 V and negligible internal
resistance, is connected in series with two lamps and a resistor. The three
components each have a resistance of 12 Ω.
6.1.1 Write down the voltage across each lamp (no working required) (1)
6.1.2 Calculate the current through the lamps. (3)
6.2.1 State what is meant by the emf of the battery and under what (2)
conditions is this achieved by the battery, assuming the battery
has internal resistance.
6.2.2 Explain why the voltmeter must be connected as shown in the (2)
diagram above?
6.3 A student wishes to measure ℰ and r. Using the circuit shown in the figure
above the value of R is decreased in steps and at each step the readings V
and I on the voltmeter and ammeter respectively are recorded. These are
shown in the table.
The circuit diagram below shows a battery, with internal resistance r, connected to
three resistors M, N and Y. The resistance of N is 2 ohms and the reading on the
voltmeter V is 14 V. The reading on ammeter A1 is 2A and the reading on
ammeter A2 is 1A. (The reading of the ammeter and wires may be ignored).
7.1 State Ohms law in words. (2)
7.2 How does the resistance of M compare with that of N? Explained how you
arrived at the answer. (2)
7.3 If the emf of the battery is 17 V, calculate the internal resistance of battery. (5)
7.4 Calculate the potential difference across resistor N. (3)
7.5 Calculate the resistance of Y. (4)
Tommy has a toy ambulance which has a light, a siren and a motor. The circuit
diagram for the electric circuit of the ambulance is given below. The resistances of
the battery, ammeter, switches and connecting wires can be ignored.
When Tommy closes ONLY switch 1 (S1) and keeps switch 2 (S2) open, the light
bulb comes on while the ambulance moves at a constant speed.
5.1 Calculate the reading on the ammeter when only switch 1 (S1) is closed.
Give your answer to 2 decimal places. (4)
5.2 Calculate the rate of energy transfer (power) in the bulb when only switch 1
is closed. (4)
When Tommy closes both switches 1 (S1) and 2 (S2) the siren sounds and the
reading on the ammeter is 200 mA.
5.3 Calculate the potential difference across the motor. (3)
5.4 Calculate the new current through the bulb. (3)
5.5 Calculate the total resistance of the circuit. (3)
5.6 Calculate the resistance of the siren. (4)
5.7 How will the following change when the siren sounds? (Write only increase,
decrease or no effect).
5.7.1 The brightness of the bulb. (1)
5.7.2 The speed of the ambulance. (1)
5.8 Explain your answer to Question 5.7.1 with reference to one or more
suitable formulae. (2)
5.9 Explain your answer to Question 5.7.2 with reference to one or more
suitable formulae. (2)
(a) Will the reading on the voltmeter 1 V connected across the terminals
of the battery increase, decrease or remain the same? (1)
(b) Explain your answer to Question 7.1.6 (a), making reference to
relevant formulae. (4)
7.2 An electric kettle is rated 240 V; 1 800 W.
7.2.1 What does 'rated 240 V; 1 800 W' mean in regard to how this
kettle works? (2)
7.2.2 Calculate the current drawn by the kettle when connected to a
240 V source. (3)
7.2.3 Calculate the cost of using the kettle for 15 minutes if electricity
costs R1,40 per kWh. (3)
With switch S closed, the current passing through the 8 Ω resistor is 0,5 A.
8.1 The graph below is obtained from an experiment to calculate the internal
resistance of a battery
8.1.1 Calculate Vinternal if the current in the circuit is equal to 0,2 A. (2)
8.1.2 Calculate the internal resistance of the battery. (4)
Concentration of solutions
Calculate the molar concentration of a solution.
Intermolecular Forces
Example:
State the relationship between intermolecular forces and molecular size. For non-polar
molecules, the strength of induced dipole forces increases with molecular size.
Explain the effect of intermolecular forces on boiling point, melting point and vapour
pressure.
Boiling point:
The temperature at which the vapour pressure of a substance equals atmospheric pressure.
The stronger the intermolecular forces, the higher the boiling point.
Melting point:
The temperature at which the solid and liquid phases of a substance are at equilibrium.
The stronger the intermolecular forces, the higher the melting point.
Vapour pressure:
The pressure exerted by a vapour at equilibrium with its liquid in a closed system.
The stronger the intermolecular forces, the lower the vapour pressure.
Organic Molecules
Molecular formula: A chemical formula that indicates the type of atoms and the correct
number of each in a molecule.
Example: C4H8O
Structural formula: A structural formula of a compound shows which atoms are attached to
which within the molecule. Atoms are represented by their chemical symbols and lines are
used to represent ALL the bonds that hold the atoms together.
Example:
H H O H
H C C C C H
H H H
Condensed structural formula: This notation shows the way in which atoms are bonded
together in the molecule, but DOES NOT SHOW ALL bond lines.
Example:
CH3CH2COCH3 OR
Structural isomer: Organic molecules with the same molecular formula, but different
structural formulae
Identify compounds (up to 8 carbon atoms) that are saturated, unsaturated and are
structural isomers.
Restrict structural isomers to chain isomers, positional isomers and functional isomers.
Chain isomers: Same molecular formula, but different types of chains, e.g.
butane and 2-methylpropane.
H H H H H H H
H C C C C H H C C C H
H H H H H H
H C H
H
butane 2-methylpropane
Positional isomers: Same molecular formula, but different positions of the side
chain, substituents or functional groups on the parent chain, e.g. 1-choropropane
and 2-chloropropane or but-2-ene and but-1-ene
H H H H H H
H C C C H H C C C H
H H Cl H Cl H
1-chromopropane 2-chromopropane
H H H H H H
C C C C H H C C C C H
H H H H H H H
but-1-ene but-2-ene
Functional isomers: Same molecular formula, but different functional groups, e.g.
methyl methanoate and ethanoic acid
H H H O
H C O C H H C C O
H H H
H
methyl methanoate ethanoic acid
Write down the IUPAC name when given the structural formula or condensed
structural formula for compounds from the homologous series above, restricted
to one functional group per compound, except for haloalkanes. For haloalkanes,
maximum two functional groups per molecule.
Write down the structural formula when given the IUPAC name for the above
homologous series.
Identify alkyl substituents (methyl- and ethyl-) in a chain to a maximum of THREE
alkyl substituents on the parent chain.
When naming haloalkanes, the halogen atoms do not get preference over alkyl
groups – numbering should start from the end nearest to the first substituent,
either the alkyl group or the halogen. In haloalkanes, where e.g. a Br and a
Cℓ have the same number when numbered from different ends of chain,
Br gets alphabetical preference.
When writing IUPAC names, substituents appear as prefixes written alphabetically
(bromo, chloro, ethyl, methyl), ignoring the prefixes di- and tri.
Structure and physical properties (boiling point, melting point, vapour pressure)
relationships
For a given example (from the above functional groups), explain the relationship
between physical properties and:
Strength of intermolecular forces (Van der Waal's forces), i.e. hydrogen bonds,
dipole-dipole forces, induced dipole forces
Type of functional groups
Chain length
Branched chains
1. Surface area
For compounds that belong to the same homologous series, the larger the
surface area the higher the Melting and the Boiling point and the lower the
Vapour pressure.
The more branched the organic molecules are, the more compact it becomes.
The surface area is smaller and less Van der Waals forces are available.
The IMF are weaker resulting in lower boiling points and melting points.
The vapour pressure will increase.
Carboxylic acid > Alcohol > Ketone, Aldehyde & Ester > Alkyne, Alkane & Alkene
The stronger the intermolecular force the higher the boiling point and
melting point, lowervapourpressure
The strength of Melting Point and Boiling Point increases and the Vapour pressure decreases
The strength of Melting Point and Boiling Point decreases and the Vapour pressure increases
ORGANIC REACTIONS
Oxidation of alkanes
State the use of alkanes as fuels.
Write down an equation for the combustion of an alkane in excess oxygen.
Esterification
Write down an equation, using structural formulae, for the formation of an ester.
Name the alcohol and carboxylic acid used and the ester formed.
Write down reaction conditions for esterification.
H H H H H
H H H H H
H C C C C C H H C C C H + C C
H H H H H H H H H H
REACTIONS OF ALKENES
ADDITION REACTION 1 (Halogenation) Conditions: Unreactive solvent
H H
H H
H H
H H
Reactants: alkene + H2
Product: Alkane
Application: Hydrogenation of unsaturated vegetable oils is used to manufacture
margarine.
ADDITION REACTION 3 (Hydrohalogenation)
H H H H
H H H H C C C C H
H H Br H
H C C C major product
+H Br
H H C H H H H H
H H C C C C H
H H H Br
minor product
H C C C C H
H H H H H OH H
H C C C major product
+ H OH
H H C H H H H H
H
H C C C C H
H H H OH
minor product
Major product: The H-atom attaches to the C-atom already having the greater number of H-
atoms. (Markovnikov’s rule)
Addition reaction will only occur when the compound is unsaturated.
REACTIONS OF HALOALKANES
1. ELIMINATION
Haloalkane → alkene
H H H
H C C C C H
H H H
H H H H
major product
H C C C C H + Na OH heat + NaBr + H2O
H Br H H H H H
H C C C C H
H H H
minor product
H C C C C H
H C C C C H + Na OH + Na Br
H H Br H H H OH H
H
H C C C C H + OH
H C C C C H + HBr
H H Br H H H OH H
REACTIONS OF ALCOHOL
1. ELIMINATION
Alcohol → alkene
H H
H C C C C H
H H H H
H H H H
H C C C C H
major product + H OH
H H H
H OH H H
C C C C H
H H H
H
minor product
2. SUBSTITUTION
Alcohol → haloalkane
H H H H
H C C H + HBr H C C H + H2O
H OH H Br
Conditions: Heat
Reactants needed: Alcohol + HX
For primary & secondary alcohols: NaBr + conc H2SO4 is used to prepare HBr in reaction
flask.
For tertiary alcohols: HBr (or HCl) are directly applied.
Products: Haloalkane + H2O
ESTERIFICATION
O H
H H H H
H H H H H C C H
O H
H C C C C O
+ C C H H C C C C O H
+ O
O H H
H H H H H
H H H H H
Condensation
Polylactic acid -O-C(CH3)- OC-
(PLA)
Question 1
Multiple-choice Questions
A CH3CHO
B CH3COCH3
C CH3COOH
D CH3OH (2)
1.2 The reaction represented by the equation below takes place in the presence
of a catalyst.
𝐶13 𝐻28(ℓ) ⟶ 𝐶2 𝐻4(𝑔) + 𝐶3 𝐻6(𝑔) + 𝐶8 𝐻18(ℓ)
This reaction is an example of …
A addition.
B cracking.
C substitution.
D polymerisation. (2)
H H
H C H H C H
H H H
H C C C C C H
H H
H C H
H
Which ONE of the following is the correct IUPAC name of this compound?
A 2,2,4-trimethylpent-2-ene
B 2,2,4-trimethylpent-3-ene
C 2,4,4-trimethylpent-2-ene
D 2,4,4-trimethylpent-3-ene (2)
Alkenes …
A Prop-1-ene.
B Propane.
C Ethene.
D Ethane. (2)
A but-1-ene.
B but-2-ene.
C butan-1-ol.
D butan-2-ol. (2)
A Pentanal
B Pentan-2-ol
C Pentan-2-one
D Ethyl propanoate (2)
A hydration.
B dehydration.
C substitution.
D hydrogenation. (2)
H H H O H
H C C C O C C H
H H H H
Which ONE of the following pairs of reactants can be used to prepare this
compound in the laboratory?
1.10. Which ONE of the following compounds has dipole-dipole forces between
its molecules?
A Ethanal
B Ethane
C Ethene
D Ethyne (2)
1.11. Which ONE of the following is a product formed during the hydrolysis of
bromoethane?
A Water
B Ethene
C Ethanol
D Bromine (2)
A 𝐶𝐻𝐶ℓ
B 𝐶𝐻2 𝐶ℓ
C 𝐶𝐻𝐶ℓ2
D 𝐶2 𝐻4 𝐶ℓ2 (2)
A 𝐶𝐻3 𝐶𝑂𝐶𝐻3
B 𝐶𝐻3 𝐶𝐻2 𝐶𝐻𝑂
C 𝐶𝐻3 𝐶𝐻2 𝐶𝑂𝑂𝐻
D 𝐶𝐻3 𝐶𝐻2 𝐶𝐻2 𝑂𝐻 (2)
Question 2
H
H C H
H H H
A B
H C C C C C H
H H O H H
H
H H H O
H H H
H C C C O
H C C C C H
C H H H D
H C H H H H
H C H
H
H
H H
E Butane F H C C C C H
H H
G Ethyl propanoate
[19]
Question 3
Consider the organic compounds represented by the letters A to F in the table below.
A 2,2,4-trimethylhexane B CH3CH2CH2CH2CHO
H H Cl Br H
H C C C C C H
C H H H H D
H C H
H
E F Pentan-2-one
H H
C
H H
A B 2-methylbutanoic acid
H C C C H
H H
H H O H H H2C CH3
H CH3 H
H C C C C C H
C D H C C C C H
H H H
H2C CH3 H CH3 H H2C CH3
E But-2-ene F
4.3. Write down the NAME or FORMULA of each product formed during the
complete combustion of compound D. (2)
H H3C H H H H O H
A H C C C C C C H B H C C C C H
CH3 H CH2 CH3 H H H H
C CH3CH2CHO D Butane
Use the information in the table to answer the questions that follow.
Question 6
The table below shows the results obtained from experiments to determine the boiling
point of some alkanes and alcohols of comparable molecular masses.
CH3CH2CH3 44 -42
CH3CH2OH 46 78
CH3CH2CH2CH3 58 0
CH3CH2CH2OH 60 97
CH3CH2CH2CH2CH3 72 36
CH3CH2CH2CH2OH 74 117
6.2 Consider the boiling points of the four alkanes in the above table.
6.2.1 Describe the trend in their boiling points. (1)
6.2.2 Fully explain the trend in QUESTION 6.2.1. (3)
6.3 The boiling point of each alcohol is much higher than that of the alkane
of comparable relative molecular mass. Explain this observation by referring
to the type and strength of the intermolecular forces in alkanes and alcohols. (2)
[8]
Question 7
7.1 Give a reason why alkanes are saturated hydrocarbons. (1)
7.3 Learners investigate factors that influence the boiling points of alkanes
and alcohols. In one of the investigations they determine boiling points
of the first three alkanes.
7.3.1 Write down an investigative question for this investigation. (2)
7.3.2 Fully explain why the boiling point increases from methane to propane. (3)
7.4 The learners find that the boiling point of propan-1-ol is higher than that
of propane.Explain this observation by referring to the TYPE of
INTERMOLECULAR FORCES present in each of these compounds. (3)
[12]
Questions 8 to 16 are Examples of Questions on Types of Organic Reactions.
Question 8
The flow diagram below shows the preparation of the organic compounds using
CH3CH=CH2 as starting material. X, Y, Z and P represent different organic reactions.
CH3CH=CH2
CH3CHCCH3
H2SO4
An alcohol An Alkene
Y
8.1 To which homologous series does CH3CH=CH2 belong? (1)
The diagram below shows the preparation of an ester using prop-1-ene as a starting
reagent. P, Q, R and S represent different organic reactions.
P Q
Prop-1-ene Propane Haloalkane
C2
Propan-1-ol
Ester
9.1 Write down the type of reaction represented by:
9.1.1 Q (1)
9.1.2 R (1)
9.3 Write down the structural formula of the haloalkane formed in reaction Q.
(2)
9.4 In reaction S propan-1-ol reacts with ethanoic acid to form the ester.
For this reaction write down the:
9.4.1 Name of the reaction that takes place (1)
9.4.2 FORMULA or NAME of the catalyst needed (1)
9.4.3 Structural formula of the ester formed (2)
9.4.4 IUPAC name of the ester formed (2)
Momentum
Impulse
The spring is released and the trolleys move apart. Which ONE of the
following statements is TRUE?
A (i) only
B (ii) only
C (ii) and (iii) only
D (i) and (ii) only
[4 2 = 8]
Questions 2-6 is possible examples of question 4 from final exam papers
on Momentum and Impulse
Question 2
Two boys, each of mass m, are standing at the back of a flatbed trolley of mass
4m. The trolley is as at rest on a frictionless horizontal surface.
The boys jump of simultaneously at one end of the trolley with a horizontal
velocity of 2m·s-1. The trolley moves in the opposite direction.
2.3. The two boys jump of the trolley one at a time. How will the velocity of
the trolley compare to that calculated in QUESTION 2.2? Write down
only GREATER THAN, SMALLER THAN or EQUAL TO. (1)
[8]
Question 3
Dancers have to learn many skills, including how to land correctly. A dancer of
mass 50 kg leaps into the air and lands feet first on the ground. She lands on
the ground with a velocity of 5 m·s-1. As she lands, she bends her knees and
comes to a complete stop in 0,2 seconds.
3.1. Calculate the momentum with which the dancer reaches the ground.
(3)
3.3. Calculate the magnitude of the net force acting on the dancer as she
lands. (3)
Assume that the dancer performs the same jump as before but lands
without bending her knees.
3.4. Will the force now be GREATER THAN, SMALLER THAN or EQUAL TO
the force calculated in QUESTION 3.3? (1)
A bullet of mass 20 g is fired from a stationary rifle of mass 3 kg. Assume that
the bullet moves horizontally. Immediately after firing, the rifle recoils (moves
back) with a velocity of 1,4 m·s-1.
4.1. Calculate the speed at which the bullet leaves the rifle. (4)
4.2. Calculate the magnitude of the average force exerted by the block on the
bullet. (5)
4.3. How does the magnitude of the force calculated in QUESTION 4.2
compare to the magnitude of the force exerted by the bullet on the block?
Write down only LARGER THAN, SMALLER THAN or THE SAME.
(1)
[10]
Question 5
The diagram below shows two trolleys, P and Q, held together by means of a
compressed spring on a flat, frictionless horizontal track. The masses of P and Q
are 400 𝑔 and 600 𝑔 respectively.
When the trolleys are released, it takes 0,3 𝑠 for for the spring to unwind to its
natural length. Trolley Q then moves to the right at 4 𝑚 ∙ 𝑠 −1 .
NOTE:
If a force, F, applied to a body parallel to the surface does not cause the
object to move, F is equal in magnitude to the static frictional force.
The static frictional force is a maximum (𝑓𝑠𝑚𝑎𝑥 ) just before the object starts
to move across the surface.
If the applied force exceeds 𝑓𝑠𝑚𝑎𝑥 , a resultant (net) force accelerates the
object.
Solve problems using fk = μkN, where fk is the kinetic frictional force and μk
the coefficient of kinetic friction.
State Newton's first law of motion: A body will remain in its state of rest or
motion at constant velocity unless a non-zero resultant/net force acts on it.
Discuss why it is important to wear seatbelts using Newton's first law of
motion.
State Newton's second law of motion: When a resultant/net force acts on an
object, the object will accelerate in the direction of the force at acceleration
directly proportional to the force and inversely proportional to the mass of the
object.
Draw force diagrams and free-body diagrams for objects that are in
equilibrium or accelerating.
Apply Newton's laws of motion to a variety of equilibrium and non-equilibrium
problems including:
A single object:
Moving on a horizontal plane with or without friction
Moving on an inclined plane with or without friction
Moving in the vertical plane (lifts, rockets, etc.)
Two-body systems (joined by a light inextensible string):
Both on a flat horizontal plane with or without friction
One on a horizontal plane with or without friction, and a second
hanging vertically from a string over a frictionless pulley
Both on an inclined plane with or without friction
Both hanging vertically from a string over a frictionless pulley
State Newton's third law of motion: When one body exerts a force on a
second body, the second body exerts a force of equal magnitude in the
opposite direction on the first body.
Identify action-reaction pairs.
List the properties of action-reaction pairs.
𝐺𝑚
Calculate acceleration due to gravity on a planet using: 𝑔 =
𝑟2
Describe weight as the gravitational force the Earth exerts on any object on
or near its surface.
Calculate weight using the expression w = mg.
Calculate the weight of an object on other planets with different values of
gravitational acceleration.
Distinguish between mass and weight.
Explain weightlessness.
Question 1
Multiple choice questions
The magnitude of the force the spheres now exerts on each other is:
A ½F
B F
C 2F
D 4F
1.2. Which one of the following physical quantities is a measure of the inertia
of a body?
A Mass
B Energy
C Velocity
D Acceleration
1.3. The magnitude of the gravitational force exerted by one body on another
body is F. When the distance between the centres of the two bodies is
doubled, the magnitude of the gravitational force, in terms of F, will now
be …
A ¼F
B ½F
C 2F
D 4F
1.4. Which ONE of the following forces always acts perpendicular to the
surface on which a body is placed?
A Normal force
B Frictional force
C Gravitational force
D Tension force
1.5. Two isolated bodies, A and B, having masses m and 2m respectively, are
placed a distance r apart.
Consider the following statements regarding the gravitational force
exerted by the bodies on each other.
1.6. Two forces, F1 and F2, are applied on a crate lying on a frictionless,
horizontal surface, as shown in the diagram below.
C W
5
D W
4
1.8. The simplified diagram below shows a rocket that has been fired
horizontally, accelerating to the west.
Which ONE of the statements below best explains why the rocket accelerates?
A The speed of the exhaust gases is smaller than the speed of the rocket.
B The pressure of the atmosphere at the back of the rocket is less than at
the front.
C The air outside the rocket exerts a greater force on the back of the rocket
than at the front.
D The rocket pushes the exhaust gases to the east and the exhaust gases
push the rocket to the west.
1.9. A net force 𝐹 which acts on a body of mass 𝑚 causes an acceleration 𝑎. If
the same net force 𝐹 is applied to a body of mass 2 𝑚, the acceleration of
the body will be …
1
A 𝑎
4
1
B 𝑎
2
C 2𝑎
D 4𝑎
1.10. Two objects of masses 2𝑚 and 𝑚 are arranged as shown in the diagram
below.
Which ONE of the changes below will produce the GREATEST increase
in the gravitational force exerted by the one mass on the other?
Question 2
The coefficient of kinetic friction for the 3 kg object and the 6 kg object is 0,1
and 0,2 respectively.
2.2 How will the coefficient of kinetic friction be affected if the angle between
the incline and the horizontal increases? Write down only INCREASES,
DECREASES or REMAINS THE SAME. (1)
2.3 Draw a labelled free-body diagram indicating all the forces acting on the
6 kg object as it moves up the inclined plane. (4)
2.4.1. Tension in the string if the system accelerates up the inclined plane at
4 m·s-2. (5)
2.4.2. Magnitude of F if the system moves up the inclined plane at
CONSTANT VELOCITY. (6)
2.5 How would the tension in the string, calculated in QUESTION 2.4.1, be
affected if the system accelerates up a FRICTIONLESS inclined plane at
4 m·s-2? Write down only INCREASES, DECREASES or REMAINS
THE SAME. (1)
[19]
Question 3
3.2. Draw a labelled free-body diagram indicating ALL the forces acting on the
5 kg block. (3)
3.4. When the 250 N force is replaced by a sharp pull on the string, one of the
two strings break.
Which ONE of the two strings, P or Q, will break? (1)
[12]
Question 4
The magnitude of the kinetic frictional force between the surface and the 4 kg
block is 10 N. The coefficient of kinetic friction between the 1 kg block and the
surface is 0,29.
4.2. Draw a labelled free-body diagram showing ALL forces acting on the 1 kg
block as it moves up the incline. (5)
4.3.1. Kinetic frictional force between the 1 kg block and the surface. (3)
The coefficient of static friction (μs) between the unknown mass M and
the surface of the table is 0,2.
5.1.3. Calculate the minimum value of M that will prevent the blocks from
moving. (5)
5.2. A small hypothetical planet X has a mass of 6,5 × 1020 kg and a radius of
550 km.
State the Doppler effect as the change in frequency (or pitch) of the
sound detected by a listener because the sound source and the
listener have different velocities relative to the medium of sound
propagation.
Explain (using appropriate illustrations) the change in pitch observed
when a source moves toward or away from a listener.
𝑣 ± 𝑣𝐿
Solve problems using the equation 𝑓𝐿 = 𝑓𝑠 , when EITHER the
𝑣 ± 𝑣𝑠
source or the listener is moving.
State applications of the Doppler effect.
With light – red shifts in the universe (evidence for the expanding
universe)
Explain red shifts and blue shifts using the Doppler Effect.
Use the Doppler effect to explain why we conclude that the universe is
expanding.
Question 1
Multiple choice questions
1.3. Which ONE of the following CANNOT be explained using the Doppler
effect?
1.4. A line emission spectrum is formed when an excited atom moves from
a…
1.5. Light reaching the Earth from a galaxy moving away is shifted towards
…
A greater velocities
B higher frequencies
C longer wavelengths
D shorter wavelengths
Questions 2-5 is possible examples of question 6 from final exam papers
on Doppler effect.
Question 2
The siren of a stationary police car emits sound waves of wavelength 0,55 m.
With its siren on, the police car now approaches a stationary listener at constant
-1
velocity on a straight road. Assume that the speed of sound in air is 345 m·s .
2.1. Will the wavelength of the sound waves observed by the listener be
GREATER THAN, SMALLER THAN or EQUAL TO 0,55 m?
(1)
2.3. Calculate the frequency of the sound waves observed by the listener if
-1
the car approaches him at a speed of 120 km·h . (7)
2.4. How will the answer in QUESTION 2.3 change if the police car moves
-1
away from the listener at 120 km·h ? Write down only INCREASES,
DECREASES or REMAINS THE SAME. (1)
[10]
Question 3
3.1.2. Is the ambulance moving towards or away from the observer? Give a
reason for the answer. (2)
3.1.3. Calculate the speed at which the ambulance is travelling. Take the
-1
speed of sound in air as 343 m∙s . (5)
3.2. A study of spectral lines obtained from various stars can provide
valuable information about the movement of the stars.
Is the star moving towards or away from the Earth? Explain the
answer by referring to the shifts in the spectral lines in the two
diagrams above. (2)
[11]
Question 4
The Doppler effect is applicable to both sound and light waves. It also has very
important applications in our everyday lives.
4.1. A hooter on a stationary train emits sound with a frequency of 520 Hz,
as detected by a person standing on the platform. Assume that the
-1
speed of sound is 340 m∙s in still air.
Calculate the:
4.1.2. Wavelength of the sound detected by the person when the train moves
-1
towards him/her at a constant speed of 15 m∙s with the hooter still
emitting sound. (6)
4.3. Use your knowledge of the Doppler effect to explain red shifts.
(2)
[12]
Question 5
5.1. The data below was obtained during an investigation into the
relationship between the different velocities of a moving sound source
and the frequencies detected by a stationary listener for each velocity.
The effect of wind was ignored in this investigation.
Experiment number 1 2 3 4
-1
Velocity of the sound source (m·s ) 0 10 20 30
Frequency (Hz) of the sound
900 874 850 827
detected by the stationary listener
5.1.1. Write down the dependant variable for this investigation. (1)
5.1.3. Was the sound source moving TOWARDS or AWAY FROM the
listener? Give a reason for the answer. (2)
5.1.4. Use the information in the table to calculate the speed of sound during
the investigation. (5)
5.2. The spectral lines of a distant star are shifted towards the longer
wavelengths of light. Is the star mowing TOWARDS or AWAY from
the Earth. (1)
[11]
Question 6
Reflection of sound waves enables bats to hunt for moths. The sound wave
-3
produced by a bat has a frequency of 222 kHz and a wavelength of 1,5 x 10
m.
6.1. Calculate the speed of this sound wave through the air. (3)
6.2. A stationary bat sends out a sound signal and receives the same
signal reflected from a moving moth at a frequency of 230,3 kHz.
6.2.1. Is the moth moving TOWARDS or AWAY FROM the bat? (1)
.
6.2.2. Calculate the magnitude of the velocity of the moth, assuming that the
velocity is constant. (6)
[10]