Test name: SACC-QP-CET-C-Solutions Standard: MHT-CET

Subjects: Chemistry Duration: 1Hr

Marks: 50

Questions

(D) 0.75 g
1. The van't Hoff factor (i) for a dilute
aqueous solution of the strong 4. The solubility of nitrogen gas in
electrolyte barium hydroxide is water at 2 bar pressure at 25 °C is
_______. [NEET P-II 2016] 13.6 × 10–4 mol L–1. Calculate the
solubility of N2 gas in water at 25 °C,
(A) 3
when the partial pressure of N2 gas
(B) 0 in the atmosphere is 1.56 bar.

(C) 1 (A) 1.60 × 10–3 mol L–1

(D) 2
(B) 2.16 × 10–3 mol L–1
2. The statement “If 0.003 moles of a
gas are dissolved in 900 g of water (C) 1.06 × 10–3 mol L–1
under a pressure of 1 bar, 0.006
moles will be dissolved under a (D) 2.60 × 10–3 mol L–1
pressure of 2 bar”, illustrates:
_______. 5. The osmotic pressure of a solution at
276 K is 2.5 atm. Its osmotic
(A) Dalton’s law of partial pressure pressure at 546 K under similar
conditions will be _______.
(B) Graham’s law
(A) 0.5 atm
(C) Raoult’s law
(B) 1.0 atm
(D) Henry’s law
(C) 2.5 atm
3. To observe an elevation of boiling
point of 0.05 °C, the amount of (D) 5.0 atm
solute (Mol. Wt. = 100) to be added
to 100 g of water (Kb = 0.5) is 6. 0.1 m solution each of glucose,
_______. [WB JEEM 2014] sodium chloride, sodium sulphate
and sodium phosphate are taken;
(A) 2 g the ratio of depression in freezing
point is _______.
(B) 0.5 g
(A) 1 : 3 : 2 : 1
(C) 1 g
(B) 1 : 2 : 3 : 4
 (C) 4 : 3 : 2 : 1 (A) 0.01 m

(D) 1 : 1 : 2 : 4 (B) 1 m

7. Solubilities of _______ in water (C) 0.001 m

increase appreciably with increasing
temperature. (D) 100 m

(A) NaBr, NaCl and KCl 11. At 300 K, when a solute is added to
a solvent, its vapour pressure over
(B) KNO3, NaNO3 and KBr mercury reduces from 50 mm to 45
mm. The value of mole fraction of
(C) NaBr, NaNO3 and KBr solute will be _______.

(D) NaCl, KCl and KNO3 (A) 0.005

(B) 0.01
8. Which one of the following
statements is FALSE? (C) 0.1
(A) The correct order of osmotic (D) 0.9
pressure for 0.01 M aqueous
solution of each compound is BaCl2 12. For a dilute solution of non-volatile
> KCl > CH3COOH > Sucrose. solute, the Raoult’s law states that,
_______.
(B) The osmotic pressure (π) of a
solution is given by the equation π = (A) the lowering of vapour pressure
MRT where M is the molarity of the is equal to mole fraction of solute
solution.
(B) the relative lowering of vapour
(C) Raoult’s law states that the pressure is equal to mole fraction of
vapour pressure of a component solute
over a solution is proportional to its
mole fraction in the solution. (C) the relative lowering of vapour
pressure is equal to number of moles
(D) Two sucrose solutions of same of solute
molality prepared in different
solvents will have the same freezing (D) the vapour pressure of the
point depression. solution is equal to mole fraction of
the solute
9. The vapour pressure will be lowest
for _______. 13. Gases such as CO2 and NH3 are
more soluble in water than N2,
(A) 0.1 M sugar solution because _______.
(B) 0.1 M NaCl solution (A) both have low boiling points
(C) 0.1 M Cu(NO3)2 solution (B) both are able to form hydrogen
bonds with water
(D) 0.1 M AgNO3 solution
(C) they undergo chemical reaction
10. What is the molality of solution of a with water
certain solute in a solvent, if there is
a freezing point depression of 0.184 (D) they displace air from water
°C, and if the freezing point
depression constant is 18.4 K kg 14. The molar mass of the solute using
depression of freezing point may be
mol–1?
 calculated using the formula, is isotonic with 3% (W/V) solution of
_______. a non-volatile solute. The molecular
weight of the solute will be _______.
Kf W21000
(A) M2 =
(A) 267.2 g mol–1
ΔTf m

Kf W11000
(B) M2 =
ΔTf W2 (B) 587 g mol–1

(C) 567 g mol–1

ΔTf W21000
(C) M2 =
Kf W1

(D) M2 = Kf W21000 (D) 5.87 g mol–1

ΔTf W1

19. Which of the following solutions

15. A non-volatile solute, ‘A’ tetramerises exhibits positive deviation from
in water to the extent of 80%. 2.5 g Raoult’s law?
of ‘A’ in 100 g of water, lowers the
freezing point by 0.3 °C. The molar (A) Chloroform + Acetone
mass of A in g mol–1 is _______.
(B) Ethanol + Acetone
(Kf for water = 1.86 K kg mol–1) (C) Aniline + Phenol
[KCET 2019]
(D) Benzene + Toluene
(A) 155
20. Which of the following statements is
(B) 354 CORRECT regarding a solution of
two components A and B exhibiting
(C) 62 positive deviation from ideal
behaviour? [NEET (Odisha) 2019]
(D) 221
(A) Intermolecular attractive forces
16. Which of the following solution has between A–A and B–B are equal to
highest osmotic pressure? those between A–B.
(A) 1 M NaCl (B) Intermolecular attractive forces
between A–A and B–B are stronger
(B) 1 M urea than those between A–B.
(C) 1 M sucrose
(C) ΔmixH = 0 at constant T and P.
(D) 1 M glucose
(D) ΔmixV = 0 at constant T and P.
17. 18 g of glucose is dissolved in 90 g
of H2O. Relative lowering of vapour 21. The molal boiling point elevation
pressure is _______. [Molar mass of constant for water is 0.513 °C
glucose = 180] kg/mol. When 0.1 mole of sugar is
dissolved in 200 g of water, the
(A) 0.0196 solution boils under a pressure of 1
atm at _______.
(B) 0.180
(A) 100.513 °C
(C) 0.0990
(B) 100.0513 °C
(D) 0.510
(C) 100.256 °C
18. A solution of glucose containing 9.2
g/litre (molecular weight: 180 g/mol) (D) 101.025 °C
22. 0.6 g of a solute is dissolved in 0.1 L 26. Which of the following has the
of a solvent, which develops an highest boiling point?
osmotic pressure of 1.23 atm at 27
°C. The molar mass of the substance (A) 1 m glucose solution
is _______.
(B) 1 m CH3COOH solution
(A) 149.5 g/mol
(C) 1 m Na2SO4 solution
(B) 120.15 g/mol
(D) 1 m urea solution
(C) 430 g/mol
27. Boiling point of water is defined as
(D) 60 g/mol the temperature at which _______.
23. The vapour pressure of pure (A) vapour pressure of water equals
benzene at 25 °C is 180 mm Hg. The to that of atmospheric pressure
vapour pressure lowering caused by
the addition of 25 g of a solute (B) bubbles are formed
(molar mass = 342) to 250 g of
benzene is _______. (C) steam comes out
(A) 1.4 mm Hg (D) vapour pressure of water is
higher than that of atmospheric
(B) 2.6 mm Hg pressure
(C) 4.1 mm Hg 28. The freezing point of 0.05 molal
solution of non-electrolyte in water is
(D) 3.2 mm Hg _______.
24. Aqueous solutions containing 1.63 g
of boric acid in 450 mL and 20 g of (Kf = 1.86 K kg mol–1)
sucrose (molecular mass = 342) per
litre are isotonic. The molar mass of (A) 271.3 K
boric acid is _______.
(B) – 0.93 K
(A) 342×1.63
20 (C) 272.907 K

(B) 1.63×1000×342
(D) – 0.093 K
20×450

29. The vapour pressure of a solvent A is

(C) 1.63×342×450
0.80 atm. When a non-volatile
1000×20

substance B is added to this solvent

(D) 20×342×450
1000×1.63
its vapour pressure drops to 0.6 atm.
What is the mole fraction of B in
25. The temperature at which the vapour solution?
pressure of a solid is equal to the
vapour pressure of liquid is called (A) 0.25
_______.
(B) 0.50
(A) elevation of boiling point
(C) 0.75
(B) freezing point
(D) 0.90
(C) boiling point
30. Which is NOT a colligative property?
(D) depression of freezing point
(A) Refractive index
 (B) Relative lowering of vapour (B) 0.78
pressure
(C) 78
(C) Depression of freezing point
(D) 23.33
(D) Elevation of boiling point
35. Which of the following behaves as
31. On dissolving 18 g solid in 100 g an ideal solution?
H2O at 20 °C, water vapour pressure
decreases from 17.53 mm to 17.22 (A) Ethanol + acetone
mm. The molecular weight of solid is
_______. [BCECE 2014] (B) Carbon disulphide + acetone

(C) Benzene + toluene

(A) 18 g mol–1
(D) Chloroform + acetone
(B) 183 g mol–1
36. The molal elevation constant is the
ratio of the elevation of boiling point
(C) 27 g mol–1
to _______.
(D) 274 g mol–1 (A) molarity of the solution

32. The van’t Hoff factor (i) for a dilute (B) molality of the solution
aqueous solution of the strong
electrolyte barium hydroxide is (C) mole fraction of the solute
_______. [NEET P-II 2016]
(D) mole fraction of the solvent
(A) 3
37. For sodium chloride dissolved in
(B) 0 water, the van’t Hoff factor (i)
accounts for the extent of _______
(C) 1 of the solute.
(D) 2 (A) solubility
33. The vapour pressure of ethyl alcohol (B) mobility
at 298 K is 40 mm Hg. Its mole
fraction in a solution with methyl (C) dissociation
alcohol is 0.40. What is its vapour
pressure (in mm Hg) in solution if the (D) mole fraction
mixture obeys Raoult’s law?
38. A solution contains 0.524 g of
(A) 16 camphor (molar mass = 152 g/mol)
dissolved in 36.8 g of ether (boiling
(B) 40 point = 34.6 °C). The molal elevation
constant of ether is 1.94 K kg mol–1.
(C) 56 The boiling point of the solution is
(D) 160 _______.

34. van’t Hoff factor of centimolal (A) 317.68 K

solution of K3[Fe(CN)6] is 3.333. (B) 307.78 K
Calculate the percent dissociation of
K3[Fe(CN)6]. [MH CET 2015] (C) 307.6 K

(A) 33.33 (D) 317.6 K

39. Cryoscopic constant is the freezing _______. [MHT CET 2019; Similar
point depression when the in Assam CEE 2015]
concentration of solution is _______.
(A) 90%
(A) 1 M
(B) 100%
(B) 1 m
(C) 87%
(C) 1 ppm
(D) 75%
(D) 1% (W/V)
44. Which of the following is
40. The boiling point of a solution of 0.11 INCORRECT?
g of a substance in 15 g of ether was
found to be 0.1 °C higher than that of (A) Ideal solutions obey Raoult’s law.
the pure ether. The molecular weight
of the substance will be _______. (B) No heat is evolved or absorbed
when two components forming an
(Kb = 2.16 K kg mol–1) ideal solution are mixed.

(A) 148 g mol–1 (C) The vapour pressure of ideal

solution always lies between vapour
(B) 158 g mol–1 pressures of pure components.

(D) Solution of phenol + aniline

(C) 168 g mol–1 behaves nearly as ideal.

(D) 178 g mol–1 45. Which of the following statements is

INCORRECT?
41. If 3 g of glucose (molecular mass =
180) is dissolved in 60 mL of water at (A) NaCl dissolves in water.
15 °C, then the osmotic pressure of
this solution will be (R = 0.0821 L (B) Cholesterol dissolves in
benzene.
atm K–1 mol–1) _______.
(C) Sugar does not dissolve in water.
(A) 0.34 atm
(D) Naphthalene dissolves in
(B) 0.36 atm benzene.
(C) 6.57 atm
46. Relative lowering of vapour pressure
(D) 5.57 atm of a dilute solution of glucose
dissolved in 1 kg of water is 0.002.
42. Which of the following shows
The molality of the solution is
negative deviation from Raoult’s
law? _______. [KCET 2019]

(A) Benzene + toluene (A) 0.111

(B) 0.021
(B) Phenol + aniline
(C) 0.004
(C) Ethanol + acetone
(D) 0.222
(D) Carbon disulphide + acetone

43. vant Hoff’s factor for 0.1 m 47. Addition of common salt to a sample
Ba(NO3)2 solution is 2.74. The of water will _______.
percentage dissociation of it is
 (A) increase its freezing point and 49. Benzene and toluene form nearly
increase the boiling point ideal solutions. At 20 °C, the vapour
pressure of benzene is 75 torr and
(B) decrease its freezing point and that of toluene is 22 torr. The partial
increase the boiling point vapour pressure of benzene at 20 °C
for a solution containing 78 g of
(C) increase both the boiling point benzene and 46 g of toluene in torr
and freezing point is _______.
(D) decrease both the boiling point (A) 50
and freezing point
(B) 25
48. The elevation in boiling point of a
solution of 13.44 g of CuCl2 in 1 kg (C) 37.5
of water will be _______ K.
(Molecular mass of CuCl2 = 134.4 (D) 53.5

and Kb = 0.52 K m–1) 50. Pure water can be obtained from sea
water by _______. [BCECE 2015]
(A) 0.16
(A) centrifugation
(B) 0.05
(B) plasmolysis
(C) 0.1
(C) reverse osmosis
(D) 0.2
(D) sedimentation