S.B.

Sharma Public
Date : 19/06/2025
School Chapter : 1, 2, 6 & 7
Time : 3 hours Std 12 : Chemistry Total Marks : 200

Practice Questions

Section A

Write the answer of the following questions : (Each carries 1 Mark) [200]

1. Match List-I with List-II.

List-I List-II

A. van't Hoff factor, i I. Cryoscopic constant

B. Kf II. Isotonic solutions

Solutions with same osmotic

C. III.
pressure

D. Azeotropes IV. Solutions with same composition of vapour above it

(A) A-III, B-I, C-II, D-IV (B) A-III, B-I, C-IV, D-II
(C) A-III, B-II, C-I, D-IV (D) A-I, B-III, C-II, D-IV

2. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of pure hydrocarbons at 200C are 440 mm Hg for pentane and 120
mm Hg for hexane. The mole fraction of pentane in vapour phase would be :
(A) 0.786 (B) 0.549 (C) 0.478 (D) 0.200
..

3. The boiling point of a solution containing 68.4 g of sucrose (molar mass = 342 g mol–1) in 100 g of water is
(Kb for water = 0.512 K kg mol–1)
(A) 98.98°C (B) 101.02°C (C) 100.512°C (D) 100.02°C

4. A 100 mL flask contained H2 at 200 torr, and a 200 mL flask contained He at 100 torr. The two flask were then connected so that each gas
filled their combined volume. Assume, no change in temperature, total pressure is
(A) 104 torr (B) 163.33 torr (C) 279 torr (D) 133.33 torr

5. Which one of the following solution of compounds shows highest osmotic pressure?
(AB, AB2 and A2B3 are ionic compounds)
(A) 5.0 M urea i = 1.0 and temperature is 67°C
(B) 1.5 M A2B3 type i = 4.1 and temperature is 27°C
(C) 3.0 M AB type i 1.6 and temperature is 27°C
(D) 2.5 M AB2 type i = 2.5 and temperature is 57°C

6. Which solution is isotonic with 6% w/v aqueous solution of urea ? [Molar mass of Urea = 60 gm. mol–1]
(A) 0.1 M NaCl (B) 0.5 M NaCl (C) 0.25 M NaCl (D) 1 M NaCl

7. The depression in freezing point of 0.01 m aqueous solution of urea, sodium chloride and sodium sulphate is in the ratio :
(A) 1 : 1 : 1 (B) 1 : 2 : 3 (C) 1 : 2 : 4 (D) 2 : 2 : 3

8. Assertion (A) : Molality of solution increases with temperature.

Reason (R) : Molality expression does not involve any volume term.
(A) Both A and R correct and R is the correction explanation of A.
(B) Both A and R are correct, R is not the correction explanation of A.
(C) A is correct, R is not correct.
(D) A is not correct, R is correct.

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9. If α is the degree of dissociation of Na2SO4 the Van’t Hoff factor (i) used for calculating the molecular mass is
(A) 1 – 2 α (B) 1 + 2 α (C) 1 – α (D) 1 + α

10. If two liquids A and B form minimum boiling azeotrope at some specific composition then ________.
(A) A-B interactions are stronger than those between A-A or B-B.
(B) Vapour pressure of solution increases because more number of molecules of liquids A and B can escape from the solution.
(C) Vapour pressure of solution decreases because less number of molecules of only one of the liquids escape from the solution.
(D) A-B interactions are weaker than those between A-A or B-B.

11. In which solution, solute is liquid and solvent is gas ?

(A) Chloroform mixed with nitrogen gas (B) Ethanol dissolved in water
(C) Camphor in nitrogen gas (D) Solution of hydrogen in palladium

12. Which of the following solution has highest boiling point ?

(A) 0.1 M urea (B) 0.1 M sucrose (C) 0.1 M NaNO3 (D) 0.1 M Al(NO3)3

13. Which of the following is true when components forming an ideal solution are mixed?
(A) ΔHm = ΔVm = 0 (B) ΔHm < ΔVm (C) ΔHm = ΔVm = 1 (D) ΔHm > ΔVm

14. The value of Henry’s constant KH is ________.

(A) Greater for gases with higher solubility. (B) Greater for gases with lower solubility.
(C) Constant for all gases. (D) Not related to the solubility of gases.

15. Which of the following is not correct for ideal solution?

(A) ΔVmix = 0 (B) ΔHmix = 0
(C) ΔSmix = 0 (D) Obeys Raoult’s law

16. The osmotic pressure (at 27°C) of an aqueous solution (200 ml) containing 6 g of a protein is 2 × 10-3atm. If R=0.080L atm mol-1 K-1, the
molecular weight of protein is
(A) 7.2 × 105 (B) 3.6 × 105 (C) 1.8 × 105 (D) 1.0 × 105

When 10 g of a non-volatile solute is dissolved in 100 g of benzene, it raises boiling point by 1oC then molecular mass of the solute is (Kb for
..

17.

C6H6 = 2.53K.kg.mol-1)
(A) 223 g (B) 233 g (C) 243 g (D) 253 g

18. The molal elevation constant of water is 0.52oC. The boiling point of 1.0 Molal aqueous KCl solution (assuming complete dissociation of
KCl), therefore, should be
(A) 98.96oC (B) 100.52oC (C) 100.04oC (D) 107.01oC

19. Which of the following statements is false ?

(A) Two different solutions of sucrose of same molality prepared in different solvents will have the same depression in freezing point.
(B) The osmotic pressure of a solution is given by the equation p = CRT (where C is the molarity of the solution).
(C) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium chloride, acetic acid and sucrose is
BaCl2 > KCl > CH3COOH > sucrose.
(D) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is directly proportional to its mole fraction in
the solution.

20. Which of the following statements is false ?

(A) Units of atmospheric pressure and osmotic pressure are the same.
(B) In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower concentration of solute to a region
of higher concentration.
(C) The value of molal depression constant depends on nature of solvent.
(D) Relative lowering of vapour pressure, is a dimensionless quantity.

21. Boiling point of water is defined as the temperature at which :

(A) Vapour pressure of water is equal to one atmospheric pressure
(B) Bubbles are formed
(C) Steam comes out
(D) None of the above

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22. 1.0 g of a non-electrolyte solute (molar mass 250 g mol-1) was dissolved in 51.2 g of benzene. If the freezing point depression constant of
benzene is 5.12 K kg mol-1, the lowering in freezing point will be :
(A) 0.5 K (B) 0.2 K (C) 0.4 K (D) 0.3 K

23. 0.1 Molal aqueous solution of NaBr freezes at –0.335oC at atmospheric pressure kf for water is 1.86 K.kg.mol–1. The percentage of
dissociation of the salt in solution is
(A) 90 (B) 80 (C) 58 (D) 98

24. If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be

(A) 0.25 (B) 0.5 (C) 5 (D) 10

25. Which of the following condition is correct for reverse osmosis?

[C = Concentration of solution in mol L–1; T = Temperature in Kelvin scale; n = no of moles of solute]
(A) Pext = CRT (B) Pext > CRT (C) Pext < CRT (D) Pext > nRT

26. How does the solubility of gas change in a liquid, as described?

(A) Increases with decreasing pressure (B) Increases with increasing temperature
(C) Decreases with increasing temperature (D) Decreases with increasing pressure

27. When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g benzene (Kf = 1.72 K kg mol-1), a freezing point depression of 2 K is observed.
The Van’t Hoff factor (i) is
(A) 0.5 (B) 1 (C) 2 (D) 3

28. The order osmotic pressure of isomolar solution of BaCl2, NaCl and sucrose is
(A) BaCl2 > NaCl > sucrose (B) NaCl > BaCl2 > sucrose
(C) sucrose > NaCl > BaCl2 (D) BaCl2 > sucrose > NaCl

29. An ideal solution is formed when its components

(1) can be converted into gases
(2) obey Raoult’s law
(3) have no change of volume
..

(4) have zero heat of mixing

Which of the above statements is/are correct?
(A) 1 only (B) 2, 3 and 4 (C) 2 only (D) 3 and 4 only

30. Vapour pressure of a solvent containing non-volatile solute is :

(A) More than the vapour pressure of a solvent (B) Less than the vapour pressure of solvent
(C) Equal to the vapour pressure of solvent (D) None of the above

31. If the various terms in the below given expressions have usual meanings, the Van’t Hoff factor (i) cannot be calculated by which one of the
expressions?
(A) πV = (B) ΔTf = ikf.m (C) ΔTb = ikb.m (D) = i

32. What will be the boiling point of 1m urea solution in k unit ? (kb = 0.52 k kg mol–1)
(A) 100.52 (B) 373.67 (C) 378.35 (D) 105.2

33. Two beakers of capacity 500 mL were taken. One of these beakers, labelled as “A”, was filled with 400 mL water, whereas the beaker labelled
“B” was filled with 400 mL of 2 M solution of NaCl. At the same temperature both the beakers were placed in closed containers of same
material and same capacity as shown in Fig.. At a given temperature, which of the following statement is correct about the vapour pressure of
pure water and that of NaCl solution.

(A) Vapour pressure in container (A) is more than that in container (B).
(B) Vapour pressure in container (A) is less than that in container (B).
(C) Vapour pressure is equal in both the containers.

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 (D) Vapour pressure in container (B) is twice the vapour pressure in container (A).

34. For an ideal solution, the correct option is : _______.

(A) Dmix S = 0 at constant T and P (B) Dmix V ≠ 0 at constant T and P
(C) Dmix H = 0 at constant T and P (D) Dmix G = 0 at constant T and P

35. The pressure required for the reverse osmosis is quite high. For this _______ membrane is used.
(A) Cellophane (B) Parchment (C) Cellulose acetate (D) Pig’s bladder

36. Colligative properties depend on ________.

(A) The nature of the solute particles dissolved in solution.
(B) The number of solute particles in solution.
(C) The physical properties of the solute particles dissolved in solution.
(D) The nature of solvent particles.

37. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _____.
(A) it gains water due to osmosis. (B) it loses water due to reverse osmosis.
(C) it gains water due to reverse osmosis. (D) it loses water due to osmosis.

38. Acetic acid dimerizes when dissolved in benzene. As a result boiling point of the solution rises by 0.36°C, when 100g of benzene is mixed
with “X” g of acetic acid. In this solution, if experimentally measured molecular weight of acetic acid is 117.8 and molar elevation constant of
benzene is 2.57 K kg mol–1, what is the weight % and degree of dissociation (in %) of acetic acid in benzene?
(A) 1.62 and 98.3 (B) 0.81 and 98.3 (C) 0.5 and 8.6 (D) 1 and 98.3

39. The movement of solvent molecules through a semipermeable membrane is called.

(A) Electrolysis (B) Electrophoresis (C) Osmosis (D) Cataphoresis

40. Vapour pressure of pure ‘A’ is 70 mm of Hg at 25o C. It from an ideal solution with ‘B’ in which mole fraction of A is 0.8. If the vapour
pressure of the solution is 84 mm of Hg at 25o C, the vapour pressure of pure ‘B’ at 25o C is.
(A) 28 mm (B) 56 mm (C) 70 mm (D) 140 mm

41. The elevation in boiling point for one molal solution of a solute in a solvent is called :
..

(A) Cryoscopic constant (B) Boiling point constant

(C) Molal ebullioscopic constant (D) None of the above

42. The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood. The
concentration of glucose solution in gL–1 is _______
(Molar mass of glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer)

43. A solution containing 1.8 g of a compound (empirical formula CH2O) in 40 g of water is observed to freeze at – 0.465 °C. The molecular
formula of the compound is (Kf of water = 1.86 kg K mol–1)
(A) C2H4O2 (B) C3H6O3 (C) C4H8O4 (D) C6H12O6

44. pH of a 0.1M monobasic acid is 2. Its osmotic pressure at a given temperature T(K) is (Given that the effective concentration for osmotic
pressure is (1 + a). x concentration of acid : a is the dissociation factor)
(A) RT (B) 0.11 RT (C) 0.01 RT (D) 0.001 RT

45. The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of
the substance will be :
(A) 180 (B) 18.0 (C) 342 (D) 60

46. The osmotic pressure of 0.5 M aqueous solution of CH3COOH having 2pH at temperature T is _______.
(A) 0.51 RT (B) 1.02 RT (C) 0.051 RT (D) 0.102 RT

47. 100 mL of 0.3 N HCl is mixed with 200 ml of 0.6N H2SO4. The final Normality of the resulting solution will be
(A) 0.3 N (B) 0.2 N (C) 0.5 N (D) 0.1 N

48. We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1 M, 0.01 M and 0.001 M, respectively. The value
of Van’t Hoff factor for these solutions will be in the order ________.
(A) iA < iB < iC (B) iA > iB > iC (C) iA = iB = iC (D) iA < iB > iC

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49. 5 L of a solution contains 25 mg of CaCO3. What is its concentration in ppm? (mol. wt. of CaCO3 is 100)
(A) 25 (B) 1 (C) 5 (D) 2500

50. An alloy of copper and zinc is called?

(A) Bronze (B) German silver (C) Brass (D) Solder

51. When 965 coulombs of electricity is passed through a solution of silver nitrate, the amount of silver deposited is
(A) 10.8 g (B) 2.16 g (C) 1.08 g (D) 0.54 g

52. The emf of the cell Mg | Mg2+ (0.01 M) || Sn2+ (0.1 M) | Sn at 298 K is (Given, E0Mg2+/Mg = – 2.34 V, E0Sn2+/Sn = – 0.14 V)
(A) 2.23 V (B) 1.86 V (C) 1.56 V (D) 3.26 V

53. Specific conductivity of 0.5 mol/dm³ AgNO3 solution at 298 K temperature is 5.76 × 10–3 cm–1, then molar conductivity is ______.
(A) 0.086 (B) 28.8 (C) 2.88 (D) 11.52

54. What is symbolic representation of given following reactions.

Fe(s) + Cd2+(aq) Fe2+(aq) + Cd(s)
6
(A) Fe(s) | Fe 2+
(1M) || Cd(s) | Cd2+(1M)⊕ (B) 6Cd(s) | Cd2+(1M) || Fe2+(1M) | Fe(s)⊕

(C) 6Cd(s) | Cd2+(1M) || Fe(s) | Fe2+(1M)⊕ (D) 6Fe(s) | Fe2+(1M) || Cd2+(1M) | Cd(s)⊕

55. I2(s) | I– (0.1 M) half-cell is connected to a H+(aq) | H2 (1 bar) | Pt half-cell and emf is found to be 0.7714 V. If E°I2/I– = 0.535 V, find the pH of
H+ / H2 half-cell
(A) 1 (B) 2 (C) 3 (D) 5

56. Given EoMn7+/Mn2+ = 1.51 V, EoMn4+/Mn2+ = 1.23 V

Calculate the EoMn7+/Mn4+

(A) 0.25 V (B) – 0.28 V (C) 1.7 V (D) 0.48 V

57. Using the data given below find out the strongest reducing agent.
= 1.33V; = 1.36V
..

= 1.51V; = –0.74V
–
(A) Cl (B) Cr (C) Cr3+ (D) Mn2+

58. Which instrument is used to measure electrical resistance ?

(A) Voltmeter (B) Wheatstone bridge (C) Galvanometer (D) Ammeter

59. Which of the following is true for construct cell by E6Cu2+ | Cu = + 0.34V and E6H+ | H2 = 0 ?
(A) Pt | H2(g) | H+(aq) (1M) || Cu2+(aq) (lM) | Cu(s)

(B) Pt | H2(g) (1 bar) | H+(aq) (1M) || Cu(s) | Cu2+(aq) (lM)

(C) Cu(s) | Cu2+(aq) (lM) || H+(aq) (1M) | H2(a) (1 bar) || Pt

(D) Pt | H+(aq) (1M) | H2(g) (1 bar) || Cu(s) | Cu2+(aq) (lM)

60. What is the approximate quantity of electricity (in coulomb) required to deposit all the silver from 250 mL of 1 M AgNO3 aqueous solution?
(A) 96500 (B) 24125 (C) 48250 (D) 12062.5

61. Specific conductivity of 0.1 M NaCl aqueous solution is 1.06 × 10–2 ohm–1 cm–1, then what is its molar conductivity in ohm–1 cm2 mol–1?
(A) 1.06 × 102 (B) 1.06 × 103 (C) 1.06 × 104 (D) 53

62. What will be the oxidation potential for the following hydrogen half cell at 1 bar pressure and 25°C temperature ?

(A) 0.177 V (B) 0.188 V (C) 0.059 V (D) 0.000 V

63. A certain current liberates 0.504 g of hydrogen in 2 hr. How many gram of copper can be liberated by the same current flowing for the same
time in solution?
(A) 12.7 (B) 16 (C) 31.8 (D) 63.5

64. Two electrolytic cells containing molten solutions of nickel chloride and aluminium chloride are connected in series. If same amount of
electric current is passed through them, what will be the weight of nickel obtained when 18 g of aluminium is obtained ? [Al = 27 g/mol, Ni =

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 58.5 g/mol ]
(A) 117 gm (B) 58.5 gm (C) 29.25 gm (D) 5.85 gm

65. What is to be done to stop corrosion of iron metal?

(A) It should be stored in saltless water (B) It should be stored in salted water
(C) Iron should be attached with cathode (D) Iron should be kept as anode

66. Consider a fuel cell supplied with 1 mol of H2 gas and 10 moles of O2 gas. If fuel cell is operated at 96.5 mA current, how long will it deliver
power? (Assume 1F = 96500 C/mole of electrons)
(A) 1 × 106 S (B) 0.5 × 106 S (C) 2 × 106 S (D) 4 × 106 S

67. Which of the following mixture is used as electrical paste in mercury cell ?
(A) Zn – Hg + KOH (B) KOH + ZnO (C) HgO + C (D) NH4Cl + ZnCl2

68. What is the value of n for

Mg(s) || Mg2+(aq) || Al3+(aq) | Al(s) ?
(A) 1 (B) 2 (C) 3 (D) 6

69. Find out molar conductivity of AgCl at infinite dilution given,

∧°m = 133.4 S.Cm2.mol–1 (AgNO3)
∧°m = 149.9 S.Cm2.mol–1 (KCl)
∧°m = 144.9 S.Cm2.mol–1 (KNO3)
(A) 140 S.Cm2 mol–1 (B) 138 S.Cm2 mol–1 (C) 134 S.Cm2 mol–1 (D) 132 S.Cm2 mol–1

70. Which of the following reaction does not occur in the given galvanic cell,
Al(s) | Al3+(aq) (1M) || Ag+(aq) (1M) | Ag(s)
(A) Al3+ + 3e– → Al (B) Al → Al3+ + 3e–
+ 3+
(C) 3Ag + Al → Al + 3Ag (D) Ag+ + e– → Ag

71. Which cell will measure standard electrode potential of copper electrode ?
(A) Pt(s) | H2(g, 0.1 bar) | || | Cu (B) Pt(s) | H2(g, 1 bar) | || | Cu
..

(C) Pt(s) | H2(g, 1 bar) | || | Cu (D) Pt(s) | H2(g, 1 bar) | || | Cu

72. Which of the following will give H2(g) at cathode and O2(g) at anode on g electrolysis using platinum electrodes?
(A) molten NaCI (B) concentrated aq solution of NaCl
(C) dilute aq. solution of NaCI (D) solid NaCl

73. The space in the dry cell is filled with

(A) paste of KOH and ZnO (B) MnO2, ZnCl2, a filter
(C) MnO2, ZnCl2, NH4Cl and a filter (D) MnCl2, ZnCl2, NH4Cl and a filter

74. Between 0.1 M KCl and 0.1 M NaCl, 0.1 M KCl is least conductor, because ________
(A) Size of Na+ is smaller than K+. (B) Size of Na+ is bigger than K+.
(C) Ionization of NaCl is more than KCL (D) None of above.

75. Some current should be passed for 2 hours to liberate 0.504 gm H2 gas. For same time if same current is passed then how much gram of
oxygen is liberated ?
(A) 2.0 gm (B) 0.4 gm (C) 4.0 gm (D) 8.0 gm

76. On electrolysis of aqueous solution of a halide of a metal ‘M’ by passing 1.5 ampere current for 10 minutes deposits 0.2938 g of metal. If the
atomic mass of the metal is 63 gm/mole, then what will be the formula of the metal halide ?
(A) MCl (B) MCl3 (C) MCl2 (D) MCl4

77. Consider the galvanic cell, Pt (s) | H2(1bar) | HCl (aq) (1M) | Cl2(lbar) | Pt(s). After running the cell for sometime, the concentration of the
electrolyte is automatically raised to 3M HCl. Molar conductivity of the 3M HCl is about 240 S cm2 mol–1 and limiting molar conductivity of
HCl is about 420 S cm2 mol–1. If Kb of water is 0.52 K kg mol–1, calculate the boiling point of the electrolyte at the end of the experiment
(A) 375.6 K (B) 376.3 K (C) 378.1 K (D) 380.3 K

78. Which of the following reactions is correct for a given electro chemical cell at 25°C ?

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 Pt / Br2(g) / // / Cl2(g) / Pt.
(A) + Cl2(g) → + Br2(g) (B) Br2(g) + → + Cl2(g)
(C) Br2(g) + Cl2(g) → + (D) + → Br2(g) + Cl2(g)

79. A silver cup is plated with silver by passing 965 C of electricity. The amount of Ag deposited is
(A) 107.89 g (B) 9.89 g (C) 1.0002 g (D) 1.08 g

80. Hydrofluoric acid is a weak acid. Molar conductivity of 0.002 M HF solution at 25°C is 176.2 Ω–1 cm2 mol–1. If its Λ°m = 405 Ω–1 cm2 mol–1,
then find out its equilibrium constant at given concentration.
(A) 6.7 × 10–4 M (B) 3.2 × 10–4 M (C) 6.4 × 10–5 M (D) 3.2 × 10–5 M

81. Which substance is used as oxidising agent in nickel-cadmium cell ?

(A) Ni(OH)3 (B) Cd (C) Ni (D) CdO

82. The standard free energy change of a reaction is ∆G° = -115 kJ at 298 K. Calculate the equilibrium constant kp in log kp (R = 8.314 Jk–1 mol–
1
).
(A) 20.16 (B) 2.303 (C) 2.016 (D) 13.83

83. In the electrolysis of aqueous sodium chloride solution which of the half-cell reaction will occur at anode ?
(A) + e– → Na(s); = –2.71V (B) 2H2O(l) → O2(g) + + 4e–; = –1.23V
– –
(C) +e → H2(g); = 0.00V (D) → Cl2(g) + e ; = 1.36V

84. If conductivity of 0.20M KCl solution at 298 K temperature is 0.0248 S cm–1, then find out its molar conductivity.
(A) 124 Ω–1 cm2 mol–1 (B) 224 Ω–1 cm2 mol–1
–1 2 –1
(C) 24 Ω cm mol (D) 1.24 Ω–1 cm2 mol–1

85. Zn(s)/ (1M) // (1M) / Ni(s)

Which is incorrect for the above given cell ?
(A) Electrochemical cell (B) Voltaic cell
(C) Galvanic cell (D) Daniel cell
..

86. Standard reduction potential of following reactions is given below :

Mn2+ + 2e– → Mn ; E0 = – 1.18V
and Mn3+ + e– → Mn2+; E0 = 1.51 V,
then what is the redox potential of reaction Mn3+ + 3e– → Mn ?
(A) 0.33 V (B) 1.69 V (C) – 0.28 V (D) – 0.85 V

87. Why conductivity of solution decreases on dilution ?

(A) Due to decrease in number of ions. (B) Due to increase in number of ions
(C) Due to number of ions remain constant. (D) None of the above

88. H2(g) + 2AgCl(g)  2Ag(s) + 2HCl(aq), E°cell at 25°C for the cell is 0.22V. The equilibrium constant at 25°C is
(A) 2.8 × 107 (B) 5.2 × 108 (C) 2.8 × 105 (D) 5.2 × 104

89. What is cell potential of cell 6Ni | Ni2+(1M) || Au3+(1M) || Au⊕ ?

[E°Ni+2 | Ni = – 0.25 V, E°Au+3 | Au = 1.5 V
(A) + 1.75 V (B) + 1.25 V (C) 3.25 V (D) – 1.75 V

90. The conductivity of N / 50 solution of KCl in a cell at 25° C is 0.002765 mho cm–1. If the resistance of a cell containing this solution is 400
ohm, the cell constant is :
(A) 1.106 cm (B) 1.106 cm–1 (C) 1 cm (D) 1 cm–1

91. Find the emf of the cell in which the following reaction takes place at 298 K.
Ni(s) + 2Ag+(0.001M) → Ni2+ (0.001 M) + 2 Ag(s) Given that = 1.5 V, = 0.059 at 298

(A) 1.0385 V (B) 1.385 V (C) 0.9615 V (D) 1.05 V

92. When a copper wire is immersed in a solution of AgNO3, the colour of the solution becomes blue because copper:
(A) Forms a soluble complex with AgNO3 (B) Is oxidised to Cu2+

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 (C) Is reduced to Cu2– (D) Splits up into atomic form and dissolves

93. Which of the following reaction is of Daniell cell ?

(A) Zn(s) + 2Ag+ → Zn2+(aq) + 2Ag(s) (B) Cu(s) + 2Ag2+(aq) → Cu2+(aq) + 2Ag(s)

(C) Zn(s) + Cu2+(aq) → Zn2+(s) + Cu(s) (D) Zn(s) + 2Hc+(aq) → Zn2+(aq) + H2(g)

94. If l = length, R = Resistance and A = Area of cross section, then

(A) R ∝ (B) R ∝ (C) R ∝ (D) R ∝ lA

95. A certain quantity of electricity is passed through aqueous solution of AgNO3 and CuSO4 connected in series. If Ag (at.wt.108) deposited at
the cathode is 1.08 g then Cu deposited at the cathode is (at. wt. of Cu is 63.53 ) :
(A) 6.354 g (B) 0.317 g (C) 0.6354 g (D) 3.177 g

96. What is the Ecell value of galvanic cell of redox reactions at equilibrium condition ?
(A) More than zero volt (B) Less than zero volt
(C) Zero volt (D) None of above

97. An electrochemical cell can behave like an electrolytic cell when ______.
(A) Ecell = 0 (B) Ecell > Eext (C) Eext > Ecell (D) Ecell = Eext

98. Use the data given in Q.8 and find out the most stable ion in its reduced form.
(A) Cl– (B) Cr3+ (C) Cr (D) Mn2+

99. Using the data given below find out the strongest reducing agent ?

(A) Cl– (B) Cr3+ (C) Cr (D) Mn2+

100. Invers of resistance is known as :

(A) Conductivity (B) Resistance
(C) Molar conductivity (D) Limiting molar conductivity
..

101. Which reaction gives the product 2, 2 di bromo propane ?

(A) CH3 – C ≡ CBr + HBr → (B) CH ≡ CH + 2 H⋅Br →
(C) CH3 – CH = CH2 + HBr → (D) CH3 – C ≡ CH + 2 HBr →

102. Among the following the most reactive towards alcoholic KOH is;
(A) CH2 = CHBr (B) CH3COCH2CH2Br
(C) CH3CH2Br (D) CH3CH2CH2Br

103. For the compounds CH3Cl, CH3Br, CH3I and CH3F, the correct order of increasing C-halogen bond length is;
(A) CH3F < CH3Cl < CH3Br < CH3I (B) CH3F < CH3Br < CH3Cl < CH3Cl
(C) CH3F < CH3I < CH3Br < CH3Cl (D) CH3Cl < CH3Br < CH3F < CH3I

104. Predict the product C obtained in the following reaction of butyne-1 ?

CH3 – CH2 – C ≡ CH + HCl B C
(A) (B) (C) (D)

105. Which of the following is an example SN2 reaction.

(A) CH3Br + OH– CH3OH + Br

– (B)

(C) CH3CH2OH CH2 = CH2 (D) (CH3)3C–Br + OH– (CH3)3COH + Br–

106. Mention common name of phosgene.

(A) Phosphonyl chloride (B) Carbon tetra chloride
(C) CO2 and PH3 (D) Carbonyl chloride

Page No.: 8
107. Give the IUPAC name of Br – CH2 – C ≡ C – CH2Br.
(A) 2-butyl 1, 4 dibromide (B) 1, 4-dibromo propyne
(C) 1, 3-di bromo, 2-butene (D) 1, 4-di bromo, but-2-yne

108. CH2 = CH – C⋅Cl3 + HBr → _______ product is obtained.

(A) CH2(Br) CH2CCl3 (B) CH3CH2 CCl3
(C) BrCH2CH Cl CHCl2 (D) CH3 CH Br CCl3

109. The order of reactivity of the following compounds towards dilute aqueous KOH in SN1 reaction is

(A) I > IV > III > II (B) IV < II < III < I (C) III < II < I < IV (D) I < III < II < IV

110. SN1 reaction is favoured by :

(A) Non-polar solvents
(B) More no. of alkyl group on the carbon atom attached to the halogen atom
(C) Small ore no. groups of alkyl on the group carbon on the attached carbon to atom
(D) None of the above

111. When ethyl alcohol (C2H5OH) reacts with thionyl chloride in the presence of pyridine, the product obtained is;
(A) CH3CH2Cl + HCl (B) CH3COCl + HCl + SO2
(C) CH3CH2Cl + H2O + SO2 (D) C2H5Cl + HCl + SO2

112. X C2H5Cl; Y CH3COCl identify X and Y.

(A) C2H5I and C2H5CHO (B) C2H5OH and CH3COOH
(C) (C2H5)2O and CH3COOH (D) C2H5OH and C2H5CHO

113. ?
(A) CCl4, CHl3, DDT, CHCl3 (B) CHCl3, CHl3, DDT, CCl4
(C) DDT, CHCl3, CCl4, CHl3 (D) CCl4, CHl3, CHCl3, DDT
..

114. Which of the following is an example of vic-dihallide ?

(A) Dichloromethane (B) 1,2-dichloroethane
(C) Ethylidene chloride (D) Allyl chloride

115. For a givem alkyl group, the reactivity order of halides in SN1 reaction is
(A) R – F > R – Cl > R – Br > R – I (B) R – Cl > R – F > R – Br > R – I
(C) R – Br > R – F > R – Cl > R – I (D) R – I > R – Br > R – Cl > R – F

116. Which of the following possesses highest melting point ?

(A) Chlorobenzene (B) m-dichlorobenzene (C) o-dichlorobenzene (D) p-dichlorobenzene

117. IUPAC names of ethylidene chloride is ______.

(A) 1-Chloro ethene (B) 1-Chloro ethyne
(C) 1, 2-Dichloro ethane (D) 1, 1-Dichloro ethane

118. The wurtz fitting reaction involves condensation of ________.

(A) Two molecules of aryl halides.
(B) One molecules of each of aryl halide and alkyl halide.
(C) One molecules of each of aryl halide and phenol.
(D) Two molecules of an alkyl halide.

119. Which substance has highest melting point ?

(A) (B) (C) (D)

120. X compound reacts with Na to give CH3 CH2 CH2 CH3, then compound X is

Page No.: 9
 (A) CH3 CH2OH (B) CH3 CH2 – Cl
(C) CH3 – CH3 (D) CH3CH2CH2CH2OH

121. Which of the following molecule is expected to rotate the plane polarized light ?
(A) (B) (C) (D)

122. The greater the ionic character of the carbon metal bond :
(A) The more reactive is the organometallic compound
(B) The less reactive is the organometallic compound
(C) Both are correct
(D) None of the above is correct

123. The order of reactivities of methyl halides in the formation of Grignard reagent is
(A) CH3I > CH3Br > CH3Cl (B) CH3Cl > CH3Br > CH3I
(C) CH3Br > CH3Cl > CH3I (D) CH3Br > CH3I > CH3Cl

124. Which substance is a primary halide ?

(A) iso propyl iodide (B) Secondary butyl iodide
(C) Tertiary butyl bromide (D) neo hexyl chloride

125. CCl4 is insoluble in water because :

(A) Water is non-polar (B) CCl4 is non-polar
(C) Water and CCl4 are polar (D) None of the above

126. Which two alkyl chloride on heating with Na metal in presence of dry ether give isobutane ?
(A) CH3Cl and CH3CH2CH2Cl (B) and CH3Cl
..

(C) CH3CH2Cl and CH3Cl (D) CH3 CH ClCH3 and CH3CH2Cl

127. From which substance trihalogen haloform compound is obtained ?

(A) Propane (B) Ethane (C) Benzene (D) Methane

128. The given reaction is an example of,

C2H5Br + KCN (aq.) → C2H5CN + KBr :
(A) Elimination (B) Nucleophilic substitution
(C) Electrophilic substitution (D) Redox change

129. Which compound has highest reactivity towards SN2 reaction ?

(A) 1-Bromo butane (B) 1-Bromo 2-Methylbutane

(C) 1-Bromo 2,2-Dimethlpropane (D) 1-Bromo 3-Methyl butane

130. Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution reaction.
(i)

(ii)

(iii)

(A) (i) < (ii) < (iii) (B) (iii) < (ii) < (i) (C) (i) < (iii) < (ii) (D) (iii) < (i) < (ii)

Page No.: 10
131. Which two alkyl chlorides on heating with Na metal in presence of dry ether give isobutane?
(A) CH3Cl and CH3CH2CH2Cl (B)

(C) CH3CH2Cl and CH3Cl (D) CH3CH ClCH3 and CH3CH2Cl

132. Below reaction is known for what ?

C2H5OH + SOCl2 C2H5Cl + SO2 + HCl
(A) Kharasch effect (B) Darzens reaction
(C) Williamson synthesis (D) Hunsdiecker synthesis

133. The major product obtained when chlorobenzene is nitrated with HNO3 + conc. H2SO4 is
(A) 1-chloro-4-nitrobenzene (B) 1-chloro-2-nitrobenzene
(C) 1-chloro-3-nitrobenzene (D) 1-chloro-1-nitribenzene

134. Ethylidene chloride is a/an.

(A) vic-dihalide (B) gem-dihalide (C) allylic halide (D) vinylic halide

135. In which of the following molecules carbon atom marked with asterisk (*) is asymmetric ?

(A) (i), (ii), (iii), (iv) (B) (i), (ii), (iii) (C) (ii), (iii), (iv) (D) (i), (iii), (iv)

136. Which alkyl halide is preferentially hydrolysed by SN1 mechanism ?

(A) CH3Cl (B) CH3CH2Cl (C) CH3CH2CH2Cl (D) (CH3)3C⋅Cl

137. Which would undergo SN1 reaction faster in the following ?

(A) H2C = CH–CH2Cl (B) (C) CH2 = CHCl (D) CH3CH2Cl
..

138. Indicate the structural formula of 1-chloro-4-secbutyl-2-methyl benzene.

(A) (B) (C) (D)

139. C6H5CH2Br ...........?

(A) (B) (C) (D)

140. Which of the following reaction (s) can be used for the preparation of alkyl halides ?
(I) CH3 CH2 OH + HCl

(II) CH3 CH2 OH + HCl

(III) (CH3)3 COH + HCl
(IV) (CH3)2 CHOH + HCl

(A) only (I) (III) and (IV) (B) only (I) and (II)
(C) only (IV) (D) only (III) and (IV)

141.

Page No.: 11
 (A) Benzene (B) Phenol
(C) t-butyl benzene (D) t-butyl phenyl ether

142. Which of the following is halogen exchange reaction ?

(A) R X + NaI → RI + NaX (B)

(C) R – OH + HX R – X + H2O (D)

143. Compound ‘A’ reacts with alcoholic KOH to yield compound ‘B’ which on ozonolysis followed by reaction with Zn/H2O gives methanal and
propanal. Compound ‘A’ is
(A) 1-propanol (B) 1-butanol (C) l-chlorobutane (D) 1-chloropentane

144. Which halide does not get hydrolysed by sodium hydroxide ?

(A) Vinyl chloride (B) Methyl Chloride (C) Ethyl chloride (D) Isopropyl chloride

145. Match-I with II.

Match-I Match-II

(a) (i) Wurtz reaction

(b) (ii) Sand meyer reaction

..

(c) 2CH3CH2Cl + 2Na C2H5 – C2H5 + 2NaCl (iii) Fitting reaction

(d) 2C6H5Cl + 2Na C6H5 – C6H5 + 2NaCl (iv) Gattermann reation

Choose the correct option from below option.

(A) (a - ii), (b - i), (c - iv), (d - iii) (B) (a - iii), (b - iv), (c - i), (d - ii)
(C) (a - ii), (b - iv), (c - i), (d - iii) (D) (a - iii), (b - i), (c - iv), (d - ii)

146. When CH3CH2CHCl2 is treated with NaNH2, the product formed is;
(A) CH3 – CH = CH2 (B) CH3 – C ≡ CH (C) (D)

147. Which halogen element present in thyroxine ?

(A) F (B) Cl (C) I (D) Br

148. The alkyl halide is converted into an alcohol by;

(A) Addition (B) Substitution
(C) Dehydrohalogenation (D) Elimination

149. The major product Y in the following reaction is :

(A) (B) (C) (D)

150. Number of monochloro derivatives obtained when neo-pentane is chlorinated, is

(A) One (B) Two (C) Three (D) Four

Page No.: 12
151. Which of the following alcohol reacts faster during Lucas test? And by which mechanism?
(A) Secondary alcohol, SN1 (B) Tertiary alcohol, SN1
(C) Secondary alcohol, SN2 (D) Tertiary alcohol, SN2

152. Ethylene oxide when treated with grignard reagent yields;

(A) Secondary alcohol (B) Tertiary alcohol
(C) Cyclo propyl alcohol (D) Primary alcohol

153. Out of the following isomeric alcohols containing five carbon atoms, the alcohol that exhibits optical isomerism is
(A) 1-pentanol (B) 2-pentanol
(C) 3-pentanol (D) 2-methyl-2-butanol

154. Which one of the following compounds is steam distillable ?

(A) p-nitrophenol (B) o-bromophenol (C) o-cresol (D) o-nitrophenol

155. Consider the following compounds :

(I)

(II)

(III)

(IV)

In which of the above compounds –OH group is attached to secondary carbon atoms ?
(A) I and II (B) I, III, and IV (C) III and IV only (D) II and III
..

156. Alcohols and ethers are which type of isomers?

(A) Position (B) Tautomers (C) Metamers (D) Functional group

157. IUPAC name of (C2H5)2 – CH – CH2 – OH is _________.

(A) 2-Ethylbutan-2-ol (B) 1-Ethylbutan-2-ol (C) 2-Ethylbutan-1-ol (D) 1-Ethylbutan-1-ol

158. The reactivity order of hydrogen halide for the reaction of alcohol with hydrogen halide is _______.
(A) HF > HBr > HCl (B) HI > HBr > HCl (C) HI > HCl > HBr (D) HCl > HBr > HI

159. Which of the following compound does not react with sodium?
(A) CH3COOH (B) (C) C2H5OH (D) CH3OCH3

160. ‘‘X’’.

What is ‘‘X’’ in the reaction ?

(A) (B) (C) (D)

161. What will be obtained on catalytic dehydrogenation of primary alcohol ?

(A) Aldehyde (B) Ketone (C) Alkene (D) Acid

162. Glycerol is ________ type of alcohol.

(A) Primary (B) Monohydric (C) Secondary (D) Trihydric

Page No.: 13
163. Which of the following compound is not possible?
(A) Propan-1,3-diol (B) Butan-2,3-diol (C) Butan-2,2-diol (D) Pentan-1,2-diol

164. _______ CH3CH2 OH

(A) CH3CHO (B) CH3CH2CH2COOH

(C) CH3COOH (D) CH3OH

165. Ortho-nitro phenol is less soluble in water than para and meta-nitro phenols because :
(A) O-nitrophenol shows intramolecular H-bonding
(B) O-nitrophenol shows intermolecular H-bonding
(C) Melting point of O-nitrophenol is less than those m and p.
(D) O-nitrophenol is more volatile in steam than those of m-and p-isomer.

166. Industrially ethanol is prepared by ________.

(A) By hydration of ethene (B) By fermentation of sugar
(C) By both (A) and (B) (D) By none of the given

167. Willamson synthesis is which type of reaction?

(A) SN2 (B) SN1
(C) Electrophilic substitution (D) Elimination

168. What will we obtain on a reaction of methyl alcohol with 23 gm Na? (Atomic mass of
Na = 23 gm/mol)
(A) 1 mol O2 (B) 1 mol H2 (C) 0.5 mol H2 (D) 0.25 mol O2

169. In below reaction :

..

Identify the compound A and B.

(A) , CH3COOH (B) , CH3COCH3 (C) , CH3COCH3 (D) , CH3COCH3

170. 1 mol of metal ‘M’ reacts completely with alcohol to give 1.5 mol of H2. Then what will be the valency of metal ‘M’ ?
(A) 1 (B) 3 (C) 2 (D) 4

171. Which among the following alcohol has the least boiling point?
(A) CH3CH2C(CH3)(OH)CH3 (B) CH3CH2CH2CH2CH2OH
(C) CH3CH(CH3)CH(OH)CH3 (D) CH3CH2CH2CH(OH)CH3

172. CH3 – CH = CH2 _______.

(A) (B) CH3 – CH2 – CH2 – OH

(C) (D) CH3 – C ≡ C – OH

173. Compound B is obtained on a reaction of compound A with Na, while compound C is obtained on a reaction of A with PCl3. Moreover, on a
reaction of compound B with C forms diethyl ether, then identify compounds A, B and C respectively.
(A) C2H5OH, C2H5ONa, C2H5Cl (B) C2H5OH, C2H5Cl, C2H4Cl2
(C) C2H5OH, C2H5Cl, C2H5ONa (D) C2H5Cl, C2H5OH, C2H5ONa

174. Which of the following compounds is oxidised to prepare methyl ethyl ketone?
(A) 2-propanol (B) 1-butanol (C) 2-butanol (D) t - butyl alcohol

175. How much gram of ethanol is required to obtain 280 ml dihydrogen at S.T.P. by reaction of C2H5OH on with Na Metal ? (Mol.wt of ethanol =
46 g/mol)

Page No.: 14
 (A) 4.6 (B) 2.3 (C) 1.15 (D) 0.575

176. Reaction of Grignard reagent C2H5MgBr with C8H8O followed by hydrolysis gives compound “A” which reacts instantly with Lucas reagent
to give compound B, C10H13Cl. The compound B is:
(A) (B) (C) (D)

177. Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass it is due to their
(A) Formation of intramolecular H-bonding
(B) More extensive assocation of carboxylic acid via van der waals force of attraction.
(C) Formation of carboxylate ion
(D) Formation of inter molecular H-bonding

178. Which of the following processes does not give benzene as a product ?
(A) C6H5COONa + Sodalime (B) C6H5N2+Cl– + H3PO2 + H2O
(C) C6H5OH + Zn (D) C6H5OH + H2CrO4

179. IUPAC names of given compounds are respectively.

CH3CH2CH2CH(OCH2CH3)CH2CH3, CH2 = CHCH2CH2OCH3
(A) 3-ethoxyhexane, 4-methoxybut-1-ene (B) 4-ethoxyhexane, 4-methoxybut-1-ene
(C) 3-ethoxyhexane, 4-methoxybut-3-ene (D) 4-ethoxyhexane, 4-methoxybut-3-ene

180. Which of the following statement is not correct ?

(A) Phenol is used to prepare analgesic drugs.
(B) Phenol is neutralised by sodium carbonate.
(C) Solubility of phenol in water is more than that of chlorobenzene.
(D) Boiling point of o-nitrophenol is lower than that of p-nitrophenol.
..

181. Which of the given alcohol is least acidic?

(A) Sec-Butyl alcohol (B) Butan-1-ol (C) tert-Butyl alcohol (D) iso-Butyl alcohol

182. Complete the reaction :

propan-2-ol _______.

(A) Propan-1-ol (B) Propane (C) Prop-1-ene (D) Propyne

183. Which reaction is suitable for the preparation of tert-butylmethylether?

(A) CH3Br + (CH3)3 CONa → (B) (CH3)3 CCl + CH3ONa →

(C) (CH3) C – OH + CH3Cl → (D) (CH3)3 C – Cl + CH3OH →

184. The correct order of solubility in water for given compound is…
(A) Toluene < Fluorobenzene < Phenol (B) Fluorobenzene < Toluene < Phenol
(C) Toluene < Phenol < Fluorobenzene (D) Fluorobenzene < Phenol < Toluene

185. The strongest acid from the following is

(A) (B) (C) (D)

186. Which reagent can convert acetic acid into ethanol ?

(A) Na + alcohol (B) LiAlH4 + ether (C) H2 + Pt (D) Sn + HCl

187. What is a by product of cumene method?

(A) Diethyl ether (B) Propanone (C) Propanal (D) Propan-1-ol

188. The reaction of which of the given compounds is difficult with Lucas reagent?

Page No.: 15
 (A) Propan-2-ol (B) 2-Methylpropan-2-ol
(C) Propan-1-ol (D) Butan-2-ol

189. Which is the most suitable reagent for the conversion: R – CH2 – OH → R – CHO.
(A) PCC (B) KMnO4 (C) K2Cr2O7 (D) CrO3

190. Which among the following is most preferable reagent for the reaction
R – CH2 – OH → R – CHO ?
(A) PCC (Pyridinium chlorochromate) (B) KMnO4
(C) K2Cr2O7 (D) CrO3

191. Which of the given alcohol is vinylic alcohol?

(A) H2C = CHCH2OH (B) HC ≡ C – CH2OH (C) H2C = CH–OH (D) HC ≡ C–OH

192. Which reagent is to be used to obtain but-2-en-1-ol from but-2-enal?

(A) H2/Ni (B) NaBH4 (C) Zn/HCl (D) Zn-Hg/HCl

193. ________ (major product)

(A) (B) (C) (D)

194. Ethanol is coverted into ethoxy ethane,

(A) by heating excess of ethanol with conc. H2SO4 at 140°C
(B) by heating ethanol with excess of conc. H2SO4 at 443 K
(C) by testing with conc. H2SO4 at room temperature
(D) by treating with conc. H2SO4 at 273 K

195. What is the hybridization of O-atom in ether?

..

(A) SP (B) SP2 (C) SP3 (D) SP3d

196. How many moles of bromine is required to prepare 2,4,6-tribromophenol from 1 mole phenol?
(A) 1.5 (B) 3 (C) 4.5 (D) 6

197. What is the C-O-H bond angle in phenol?

(A) 111.7° (B) 108° (C) 109° (D) 120°

198. The difference in the reaction of phenol with bromine in chloroform in water medium is due to :
(A) Hyper conjugation in substrate (B) Polarity of solvent
(C) Free radical formation (D) Electromeric effect of the substrate

199. The product formed in the reaction of cumene with O2 followed by treatment with dil. HCl are ?
(A) and (B) and (C) and (D) and CH3 – OH

200. Find the main product of the stable carbocation that is formed in the above process.

(A) CH3CH2 H2 (B) CH3 – H – CH3 (C) CH3 H2 (D)

Page No.: 16
 S.B.Sharma Public
Date : 19/06/2025
School Chapter : 1, 2, 6 & 7
Time : 3 hours Std 12 : Chemistry Total Marks : 200

Answer Key

Section A

Write the answer of the following questions : (Each carries 1 Mark) [200]

1. Match List-I with List-II.

List-I List-II

A. van't Hoff factor, i I. Cryoscopic constant

B. Kf II. Isotonic solutions

Solutions with same osmotic

C. III.
pressure

D. Azeotropes IV. Solutions with same composition of vapour above it

 Ans. (A)
 A-III, B-I, C-II, D-IV

2. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of pure hydrocarbons at 200C are 440 mm Hg for pentane and 120
mm Hg for hexane. The mole fraction of pentane in vapour phase would be :

 Ans. (C)
 0.478

3. The boiling point of a solution containing 68.4 g of sucrose (molar mass = 342 g mol–1) in 100 g of water is
(Kb for water = 0.512 K kg mol–1)

 Ans. (B)
 101.02°C

4. A 100 mL flask contained H2 at 200 torr, and a 200 mL flask contained He at 100 torr. The two flask were then connected so that each gas
filled their combined volume. Assume, no change in temperature, total pressure is

 Ans. (D)
 133.33 torr
 P1V1 + P2V2 = Pf Vf
100 × 200 + 200 × 100 = Pf × 300

Pf = torr
= 133.33 torr

5. Which one of the following solution of compounds shows highest osmotic pressure?
(AB, AB2 and A2B3 are ionic compounds)

 Ans. (D)
 2.5 M AB2 type i = 2.5 and temperature is 57°C

6. Which solution is isotonic with 6% w/v aqueous solution of urea ? [Molar mass of Urea = 60 gm. mol–1]

 Ans. (B)
 0.5 M NaCl
Page No.: 1
7. The depression in freezing point of 0.01 m aqueous solution of urea, sodium chloride and sodium sulphate is in the ratio :

 Ans. (B)
 1:2:3
 1 mole urea gives 1 mole
1 mole NaCl gives 2 mole
1 mole Na2SO4 gives 3 mole
∴ ΔT ratio 1 : 2 : 3

8. Assertion (A) : Molality of solution increases with temperature.

Reason (R) : Molality expression does not involve any volume term.

 Ans. (D)
 A is not correct, R is correct.

9. If α is the degree of dissociation of Na2SO4 the Van’t Hoff factor (i) used for calculating the molecular mass is

 Ans. (B)
 1+2α
 Na2SO4 → 2Na+ + SO4–2
(n = 3)

α= ∴α=
∴ 2α = i – 1 ∴ i = 1 + 2α

10. If two liquids A and B form minimum boiling azeotrope at some specific composition then ________.

 Ans. (D)
 A-B interactions are weaker than those between A-A or B-B.

11. In which solution, solute is liquid and solvent is gas ?

 Ans. (A)
 Chloroform mixed with nitrogen gas

12. Which of the following solution has highest boiling point ?

 Ans. (D)
 0.1 M Al(NO3)3

13. Which of the following is true when components forming an ideal solution are mixed?

 Ans. (A)
 ΔHm = ΔVm = 0

14. The value of Henry’s constant KH is ________.

 Ans. (B)
 Greater for gases with lower solubility.

15. Which of the following is not correct for ideal solution?

 Ans. (C)
 ΔSmix = 0

16. The osmotic pressure (at 27°C) of an aqueous solution (200 ml) containing 6 g of a protein is 2 × 10-3atm. If R=0.080L atm mol-1 K-1, the
molecular weight of protein is

 Ans. (B)
 3.6 × 105
 πV = RT

Page No.: 2
 M=

Here, w = 6 g, π = 2 × 10-3 atm, T = 300 K,

R = 0.080 L-atm mol-1 K-1, V = 200 mL = 0.2L

M= = 3.6 × 105

17. When 10 g of a non-volatile solute is dissolved in 100 g of benzene, it raises boiling point by 1oC then molecular mass of the solute is (Kb for
C6H6 = 2.53K.kg.mol-1)

 Ans. (D)
 253 g

ΔTb =

∴ M2 = = = 253 g

18. The molal elevation constant of water is 0.52oC. The boiling point of 1.0 Molal aqueous KCl solution (assuming complete dissociation of
KCl), therefore, should be

 Ans. (C)
 100.04oC
 ΔTb = imkb = 0.52 × 1 × 2 = 1.04

∴Tb = T + ΔTb = 100 + 1.04 = 101.04oC

19. Which of the following statements is false ?

 Ans. (A)
 Two different solutions of sucrose of same molality prepared in different solvents will have the same depression in freezing point.

20. Which of the following statements is false ?

 Ans. (B)
 In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower concentration of solute to a region of
higher concentration.

21. Boiling point of water is defined as the temperature at which :

 Ans. (A)
 Vapour pressure of water is equal to one atmospheric pressure

22. 1.0 g of a non-electrolyte solute (molar mass 250 g mol-1) was dissolved in 51.2 g of benzene. If the freezing point depression constant of
benzene is 5.12 K kg mol-1, the lowering in freezing point will be :

 Ans. (C)
 0.4 K

ΔTf =

= 0.4 K

23. 0.1 Molal aqueous solution of NaBr freezes at –0.335oC at atmospheric pressure kf for water is 1.86 K.kg.mol–1. The percentage of
dissociation of the salt in solution is

 Ans. (B)
 80
 ΔTf = ikf m
0.335 = i × 1.86 × 0.1
i = 1.80

Page No.: 3
 For NaBr, i = 1 + α
α = 0.80 = 80 %

24. If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be

 Ans. (A)
 0.25
 M=

= 0.25

25. Which of the following condition is correct for reverse osmosis?

[C = Concentration of solution in mol L–1; T = Temperature in Kelvin scale; n = no of moles of solute]

 Ans. (B)
 Pext > CRT

 Reverse osmosis occurs when pressure higher than osmotic pressure is applied on the solution.
Pexternal > CRT

26. How does the solubility of gas change in a liquid, as described?

 Ans. (C)
 Decreases with increasing temperature

27. When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g benzene (Kf = 1.72 K kg mol-1), a freezing point depression of 2 K is observed.
The Van’t Hoff factor (i) is

 Ans. (A)
 0.5

ΔTf = i. Kf

2 = i × 1.72 ×

∴i= = 0.5

28. The order osmotic pressure of isomolar solution of BaCl2, NaCl and sucrose is

 Ans. (A)
 BaCl2 > NaCl > sucrose

 The order of osmotic pressure of BaCl2, NaCl and sucrose is

BaCl2 > NaCl > sucrose
Since, BaCl2 gives maximum ion (3 ions) in the solution

29. An ideal solution is formed when its components

(1) can be converted into gases
(2) obey Raoult’s law
(3) have no change of volume
(4) have zero heat of mixing
Which of the above statements is/are correct?

 Ans. (B)
 2, 3 and 4

30. Vapour pressure of a solvent containing non-volatile solute is :

 Ans. (B)
 Less than the vapour pressure of solvent

31. If the various terms in the below given expressions have usual meanings, the Van’t Hoff factor (i) cannot be calculated by which one of the

Page No.: 4
 expressions?

 Ans. (A)
 πV =

32. What will be the boiling point of 1m urea solution in k unit ? (kb = 0.52 k kg mol–1)

 Ans. (B)
 373.67

33. Two beakers of capacity 500 mL were taken. One of these beakers, labelled as “A”, was filled with 400 mL water, whereas the beaker labelled
“B” was filled with 400 mL of 2 M solution of NaCl. At the same temperature both the beakers were placed in closed containers of same
material and same capacity as shown in Fig.. At a given temperature, which of the following statement is correct about the vapour pressure of
pure water and that of NaCl solution.

 Ans. (A)
 Vapour pressure in container (A) is more than that in container (B).

34. For an ideal solution, the correct option is : _______.

 Ans. (C)
 Dmix H = 0 at constant T and P

35. The pressure required for the reverse osmosis is quite high. For this _______ membrane is used.

 Ans. (C)
 Cellulose acetate

36. Colligative properties depend on ________.

 Ans. (B)
 The number of solute particles in solution.

37. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _____.

 Ans. (D)
 it loses water due to osmosis.

38. Acetic acid dimerizes when dissolved in benzene. As a result boiling point of the solution rises by 0.36°C, when 100g of benzene is mixed
with “X” g of acetic acid. In this solution, if experimentally measured molecular weight of acetic acid is 117.8 and molar elevation constant of
benzene is 2.57 K kg mol–1, what is the weight % and degree of dissociation (in %) of acetic acid in benzene?

 Ans. (A)
 1.62 and 98.3
 Experimental molecular weight of acetic acid = 117.8

i= = = 0.51

X = mole fraction
We know that, ∆Tb = iKb × m

0.36 = 0.51 × 257 × × 100

% weight of CH3COOH

= × 100

= × 100 = 1.62

Degree of dissociation (a) =

Page No.: 5
 (a) = = 0.98 = 98%

39. The movement of solvent molecules through a semipermeable membrane is called.

 Ans. (C)
 Osmosis

40. Vapour pressure of pure ‘A’ is 70 mm of Hg at 25o C. It from an ideal solution with ‘B’ in which mole fraction of A is 0.8. If the vapour
pressure of the solution is 84 mm of Hg at 25o C, the vapour pressure of pure ‘B’ at 25o C is.

 Ans. (D)
 140 mm
 p = PoAXA + PoBXB

84 = 70 × 0.8 + P0B × 0.2

84 = 56 × P0B × 0.2

P0B = = 140 mm

41. The elevation in boiling point for one molal solution of a solute in a solvent is called :

 Ans. (C)
 Molal ebullioscopic constant

42. The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood. The
concentration of glucose solution in gL–1 is _______
(Molar mass of glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer)

 Ans. 54
 p = C.R.T.
7.47 = C × 0.083 × 300
C = 0.3 M
= 0.3 × 180 gL–1
= 54 gL–1

43. A solution containing 1.8 g of a compound (empirical formula CH2O) in 40 g of water is observed to freeze at – 0.465 °C. The molecular
formula of the compound is (Kf of water = 1.86 kg K mol–1)

 Ans. (D)
 C6H12O6
 ∆Tf = Kf × M

0.465 = 1.86 × ×
M = 180 gm/mol
Now,
n= = =6

So, molecular formula of compound will be C6H12O6

44. pH of a 0.1M monobasic acid is 2. Its osmotic pressure at a given temperature T(K) is (Given that the effective concentration for osmotic
pressure is (1 + a). x concentration of acid : a is the dissociation factor)

 Ans. (B)
 0.11 RT
 Given, pH = 2
pH = –log [H+]
or [H+] = 0.01
For monobasic acid

Page No.: 6
 HX  H+ + X–
Initial conc. C 0 0
Final con. Ca a a
H+ = Ca
a = 0.01
 0.1
a = 0.1
By Vant Hoff’s principle-
i=1+a
i = 1 + 0.1
i = 1.1
Osmotic pressure -
Π = iCRT
Π = 1.1 × 0.1 × RT
Π = 0.11 RT

45. The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of
the substance will be :

 Ans. (A)
 180


∴ 0.00713 =

∴ m = 180 g.mol–1

46. The osmotic pressure of 0.5 M aqueous solution of CH3COOH having 2pH at temperature T is _______.

 Ans. (A)
 0.51 RT

47. 100 mL of 0.3 N HCl is mixed with 200 ml of 0.6N H2SO4. The final Normality of the resulting solution will be

 Ans. (C)
 0.5 N
 N1V1 + N2V2 = N3V3
0.3 × 100 + 0.6 × 200 = N3 × 300
0.3 + 1.2 = 3N3
N3 = 0.5

48. We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1 M, 0.01 M and 0.001 M, respectively. The value
of Van’t Hoff factor for these solutions will be in the order ________.

 Ans. (A)
 iA < iB < iC

49. 5 L of a solution contains 25 mg of CaCO3. What is its concentration in ppm? (mol. wt. of CaCO3 is 100)

 Ans. (C)
 5

ppm =

=5

Page No.: 7
50. An alloy of copper and zinc is called?

 Ans. (A)
 0.33 N
 M1V1 = M2 V2
(1) (1) = M2 (6)

M2 = M

Normality = 2 × Molarity

=2×

= 0.33 N

51. When 965 coulombs of electricity is passed through a solution of silver nitrate, the amount of silver deposited is

 Ans. (C)
 1.08 g

52. The emf of the cell Mg | Mg2+ (0.01 M) || Sn2+ (0.1 M) | Sn at 298 K is (Given, E0Mg2+/Mg = – 2.34 V, E0Sn2+/Sn = – 0.14 V)

 Ans. (A)
 2.23 V
 Cell reaction is Mg + Sn2+ → Mg2+ + Sn

Ecell = E0cell – log

= (2.34 – 0.14) – log = 2.23 V

53. Specific conductivity of 0.5 mol/dm³ AgNO3 solution at 298 K temperature is 5.76 × 10–3 cm–1, then molar conductivity is ______.

 Ans. (D)
 11.52

54. What is symbolic representation of given following reactions.

Fe(s) + Cd2+(aq) Fe2+(aq) + Cd(s)

 Ans. (D)
 6
Fe(s) | Fe2+(1M) || Cd2+(1M) | Cd(s)⊕

55. I2(s) | I– (0.1 M) half-cell is connected to a H+(aq) | H2 (1 bar) | Pt half-cell and emf is found to be 0.7714 V. If E°I2/I– = 0.535 V, find the pH of
H+ / H2 half-cell

 Ans. (C)
 3
 The cell reaction is
H2(g) + I2(s)  2H+(aq) + 2I– (aq)

0.7714 = 0.535 – log

\ pH = 3

56. Given EoMn7+/Mn2+ = 1.51 V, EoMn4+/Mn2+ = 1.23 V

Calculate the EoMn7+/Mn4+

 Ans. (C)
 1.7 V
 Mn+7 + 5e– → Mn2+
Mn+4 + 2e– → Mn2+
Required equation

Page No.: 8
 Mn+7 + 3e– → Mn4+
\ ∆G° = – 5F × 1.51
∆G° = – 2F × 1.23
∆G° = – 3FE°
\ – 3FE° – 5F × 1.51 + 2F × 1.23
E° = 1.69V ≈ 1.7V

57. Using the data given below find out the strongest reducing agent.
= 1.33V; = 1.36V
= 1.51V; = –0.74V

 Ans. (B)
 Cr

58. Which instrument is used to measure electrical resistance ?

 Ans. (B)
 Wheatstone bridge

59. Which of the following is true for construct cell by E6Cu2+ | Cu = + 0.34V and E6H+ | H2 = 0 ?

 Ans. (A)
 Pt | H2(g) | H+(aq) (1M) || Cu2+(aq) (lM) | Cu(s)

60. What is the approximate quantity of electricity (in coulomb) required to deposit all the silver from 250 mL of 1 M AgNO3 aqueous solution?

 Ans. (B)
 24125
 Moles of silver = ×1= mole
+ ­–
Ag + e → Ag
1 mole Ag requires 1 mole e–
\ mole Ag requires = mole electron

\ Total charge = × 96500 = 24125 C.

61. Specific conductivity of 0.1 M NaCl aqueous solution is 1.06 × 10–2 ohm–1 cm–1, then what is its molar conductivity in ohm–1 cm2 mol–1?

 Ans. (A)
 1.06 × 102
 Λm =
Try your self.

62. What will be the oxidation potential for the following hydrogen half cell at 1 bar pressure and 25°C temperature ?

 Ans. (A)
 0.177 V

63. A certain current liberates 0.504 g of hydrogen in 2 hr. How many gram of copper can be liberated by the same current flowing for the same
time in solution?

 Ans. (B)
 16
 Eq. of H2 = Eq. of Cu

\ =
\ Wcu = 16 g

64. Two electrolytic cells containing molten solutions of nickel chloride and aluminium chloride are connected in series. If same amount of

Page No.: 9
 electric current is passed through them, what will be the weight of nickel obtained when 18 g of aluminium is obtained ? [Al = 27 g/mol, Ni =
58.5 g/mol ]

 Ans. (B)
 58.5 gm
 Since, w = Zit

or = ⇒ =

⇒ (W)Ni = 58.5 g

65. What is to be done to stop corrosion of iron metal?

 Ans. (B)
 It should be stored in salted water

66. Consider a fuel cell supplied with 1 mol of H2 gas and 10 moles of O2 gas. If fuel cell is operated at 96.5 mA current, how long will it deliver
power? (Assume 1F = 96500 C/mole of electrons)

 Ans. (C)
 2 × 106 S
 w = zit and Z =

Since the cell is supplied with 1 mole of H2 gas and 10 mole of O2. H2 is the limiting reagent,
1 mole of H2 reacts with 10 mole of O2.
1 mole of H2 required 0.5 mol of O2
charge requirement = 2F
H2 → 2H+ + 2e–

I= , I = 96.5 mA

I= = = 2 × 106 S

67. Which of the following mixture is used as electrical paste in mercury cell ?

 Ans. (B)
 KOH + ZnO

68. What is the value of n for

Mg(s) || Mg2+(aq) || Al3+(aq) | Al(s) ?

 Ans. (D)
 6

69. Find out molar conductivity of AgCl at infinite dilution given,

∧°m = 133.4 S.Cm2.mol–1 (AgNO3)
∧°m = 149.9 S.Cm2.mol–1 (KCl)

∧°m = 144.9 S.Cm2.mol–1 (KNO3)

 Ans. (B)
 138 S.Cm2 mol–1

70. Which of the following reaction does not occur in the given galvanic cell,
Al(s) | Al3+(aq) (1M) || Ag+(aq) (1M) | Ag(s)

 Ans. (A)
 Al3+ + 3e– → Al

71. Which cell will measure standard electrode potential of copper electrode ?

Page No.: 10
 Ans. (C)
 Pt(s) | H2(g, 1 bar) | || | Cu

72. Which of the following will give H2(g) at cathode and O2(g) at anode on g electrolysis using platinum electrodes?

 Ans. (C)
 dilute aq. solution of NaCI

73. The space in the dry cell is filled with

 Ans. (C)
 MnO2, ZnCl2, NH4Cl and a filter

74. Between 0.1 M KCl and 0.1 M NaCl, 0.1 M KCl is least conductor, because ________

 Ans. (A)
 Size of Na+ is smaller than K+.

75. Some current should be passed for 2 hours to liberate 0.504 gm H2 gas. For same time if same current is passed then how much gram of
oxygen is liberated ?

 Ans. (C)
 4.0 gm
 Eq.wt of H2 = Eq.wt of O2

= WO2
WO2 = 4.032 gm

76. On electrolysis of aqueous solution of a halide of a metal ‘M’ by passing 1.5 ampere current for 10 minutes deposits 0.2938 g of metal. If the
atomic mass of the metal is 63 gm/mole, then what will be the formula of the metal halide ?

 Ans. (C)
 MCl2

77. Consider the galvanic cell, Pt (s) | H2(1bar) | HCl (aq) (1M) | Cl2(lbar) | Pt(s). After running the cell for sometime, the concentration of the
electrolyte is automatically raised to 3M HCl. Molar conductivity of the 3M HCl is about 240 S cm2 mol–1 and limiting molar conductivity of
HCl is about 420 S cm2 mol–1. If Kb of water is 0.52 K kg mol–1, calculate the boiling point of the electrolyte at the end of the experiment

 Ans. (A)
 375.6 K
 Degree of ionization (a) =

a=

= 0.57
Van’t Hoff factor
i = 1 + (n – 1)a [for ionization]
i = 1 + (2 – 1) 0.57 = 1.57 [For HCl, n = 2]
Elevation in boiling
∆Tb = iKb × m = 1.57 × 0.52 × 3 = 2.45 K
Tb = Т°b + ∆Tb = 373.15 + 2.45 = 375.6

78. Which of the following reactions is correct for a given electro chemical cell at 25°C ?
Pt / Br2(g) / // / Cl2(g) / Pt.

 Ans. (A)
 + Cl2(g) → + Br2(g)

79. A silver cup is plated with silver by passing 965 C of electricity. The amount of Ag deposited is

Page No.: 11
 Ans. (D)
 1.08 g
 F=
= 0.01 F
Ag+ + e– → Ag
1F → 108 gm
0.01 F → (?)
WAg = 1.08 g

80. Hydrofluoric acid is a weak acid. Molar conductivity of 0.002 M HF solution at 25°C is 176.2 Ω–1 cm2 mol–1. If its Λ°m = 405 Ω–1 cm2 mol–1,
then find out its equilibrium constant at given concentration.

 Ans. (A)
 6.7 × 10–4 M
 α= = = 0.435

Ka = = = 6.7 × 10–4 M

81. Which substance is used as oxidising agent in nickel-cadmium cell ?

 Ans. (A)
 Ni(OH)3

82. The standard free energy change of a reaction is ∆G° = -115 kJ at 298 K. Calculate the equilibrium constant kp in log kp (R = 8.314 Jk–1 mol–
1
).

 Ans. (A)
 20.16

83. In the electrolysis of aqueous sodium chloride solution which of the half-cell reaction will occur at anode ?

 Ans. (D)
 → Cl2(g) + e–; = 1.36V

84. If conductivity of 0.20M KCl solution at 298 K temperature is 0.0248 S cm–1, then find out its molar conductivity.

 Ans. (A)
 124 Ω–1 cm2 mol–1
 Λm =

= 124 Ω–1 cm2 mol–1

85. Zn(s)/ (1M) // (1M) / Ni(s)

Which is incorrect for the above given cell ?

 Ans. (D)
 Daniel cell

86. Standard reduction potential of following reactions is given below :

Mn2+ + 2e– → Mn ; E0 = – 1.18V
and Mn3+ + e– → Mn2+; E0 = 1.51 V,
then what is the redox potential of reaction Mn3+ + 3e– → Mn ?

 Ans. (C)
 – 0.28 V
 Mn2+ + 2e– → Mn ∆G°1 = –2 × F × (–1.18)
= 2.36 F

Page No.: 12
 Mn3+ + e– → Mn2+ ∆G°2 = –1 × F × (1.51)
= –1.51 F
Mn3+ + 3e– → Mn ∆G° = –3 F × E°
∆G° = ∆G°1 + ∆G°2
–3FE° = 2.36F – 1.51F
E° = = –0.283 V

87. Why conductivity of solution decreases on dilution ?

 Ans. (A)
 Due to decrease in number of ions.

88. H2(g) + 2AgCl(g)  2Ag(s) + 2HCl(aq), E°cell at 25°C for the cell is 0.22V. The equilibrium constant at 25°C is

 Ans. (A)
 2.8 × 107

89. What is cell potential of cell 6Ni | Ni2+(1M) || Au3+(1M) || Au⊕ ?

[E°Ni+2 | Ni = – 0.25 V, E°Au+3 | Au = 1.5 V

 Ans. (A)
 + 1.75 V
 E°cell = E°(cathode) – E°(Anode)

= E° – E°
= 1.5 – (–0.25)
= 1.75 V

90. The conductivity of N / 50 solution of KCl in a cell at 25° C is 0.002765 mho cm–1. If the resistance of a cell containing this solution is 400
ohm, the cell constant is :

 Ans. (B)
 1.106 cm–1

91. Find the emf of the cell in which the following reaction takes place at 298 K.
Ni(s) + 2Ag+(0.001M) → Ni2+ (0.001 M) + 2 Ag(s) Given that = 1.5 V, = 0.059 at 298

 Ans. (C)
 0.9615 V
 Ni(s) + 2Ag+ (0.001 M) → Ni2+ (0.001 M) + 2 Ag(s)
= 1.5 V

Ecell = – log

= 1.5 – log

3
= 1.5 – log (10)
= 1.5 – 0.0295 × 3
= 1.5 – 0.0885
= 0.9615 V

92. When a copper wire is immersed in a solution of AgNO3, the colour of the solution becomes blue because copper:

 Ans. (B)
 Is oxidised to Cu2+

93. Which of the following reaction is of Daniell cell ?

 Ans. (C)
Page No.: 13
 Zn(s) + Cu2+(aq) → Zn2+(s) + Cu(s)

94. If l = length, R = Resistance and A = Area of cross section, then

 Ans. (C)
 R∝

95. A certain quantity of electricity is passed through aqueous solution of AgNO3 and CuSO4 connected in series. If Ag (at.wt.108) deposited at
the cathode is 1.08 g then Cu deposited at the cathode is (at. wt. of Cu is 63.53 ) :

 Ans. (B)
 0.317 g
 Eq. of Cu = Eq. of Ag
\ =
\ Wcu = 0.3175 g

96. What is the Ecell value of galvanic cell of redox reactions at equilibrium condition ?

 Ans. (C)
 Zero volt

97. An electrochemical cell can behave like an electrolytic cell when ______.

 Ans. (C)
 Eext > Ecell

98. Use the data given in Q.8 and find out the most stable ion in its reduced form.

 Ans. (D)
 Mn2+

99. Using the data given below find out the strongest reducing agent ?

 Ans. (B)
 Cr3+

100. Invers of resistance is known as :

 Ans. (A)
 Conductivity

101. Which reaction gives the product 2, 2 di bromo propane ?

 Ans. (D)
 CH3 – C ≡ CH + 2 HBr →

102. Among the following the most reactive towards alcoholic KOH is;

 Ans. (D)
 CH3CH2CH2Br

Page No.: 14
103. For the compounds CH3Cl, CH3Br, CH3I and CH3F, the correct order of increasing C-halogen bond length is;

 Ans. (A)
 CH3F < CH3Cl < CH3Br < CH3I

104. Predict the product C obtained in the following reaction of butyne-1 ?

CH3 – CH2 – C ≡ CH + HCl B C

 Ans. (C)


105. Which of the following is an example SN2 reaction.

 Ans. (A)
 CH3Br + OH– CH3OH + Br
–

106. Mention common name of phosgene.

 Ans. (D)
 Carbonyl chloride

107. Give the IUPAC name of Br – CH2 – C ≡ C – CH2Br.

 Ans. (D)
 1, 4-di bromo, but-2-yne

108. CH2 = CH – C⋅Cl3 + HBr → _______ product is obtained.

 Ans. (D)
 CH3 CH Br CCl3
 Markovnikov Rule

109. The order of reactivity of the following compounds towards dilute aqueous KOH in SN1 reaction is

 Ans. (D)
 I < III < II < IV

110. SN1 reaction is favoured by :

 Ans. (B)
 More no. of alkyl group on the carbon atom attached to the halogen atom

111. When ethyl alcohol (C2H5OH) reacts with thionyl chloride in the presence of pyridine, the product obtained is;

 Ans. (D)
 C2H5Cl + HCl + SO2

112. X C2H5Cl; Y CH3COCl identify X and Y.

 Ans. (B)
 C2H5OH and CH3COOH

113. ?

 Ans. (A)
 CCl4, CHl3, DDT, CHCl3

Page No.: 15
114. Which of the following is an example of vic-dihallide ?

 Ans. (B)
 1,2-dichloroethane
 1,2-Dichloroethane is a vic-dihallide since two Cl atoms are present on vicinal carbon atoms (adjacent).

115. For a givem alkyl group, the reactivity order of halides in SN1 reaction is

 Ans. (D)
 R – I > R – Br > R – Cl > R – F

116. Which of the following possesses highest melting point ?

 Ans. (D)
 p-dichlorobenzene

117. IUPAC names of ethylidene chloride is ______.

 Ans. (D)
 1, 1-Dichloro ethane

118. The wurtz fitting reaction involves condensation of ________.

 Ans. (B)
 One molecules of each of aryl halide and alkyl halide.

119. Which substance has highest melting point ?

 Ans. (D)


120. X compound reacts with Na to give CH3 CH2 CH2 CH3, then compound X is

 Ans. (B)
 CH3 CH2 – Cl

121. Which of the following molecule is expected to rotate the plane polarized light ?

 Ans. (A)


 Correct option is A has 1 Stereo Center. The Central Carbon is a chiral Carbon, So it is optically active. Optically active componds rotate the
plane of polarised light.

122. The greater the ionic character of the carbon metal bond :

 Ans. (A)
Page No.: 16
 The more reactive is the organometallic compound

123. The order of reactivities of methyl halides in the formation of Grignard reagent is

 Ans. (A)
 CH3I > CH3Br > CH3Cl

124. Which substance is a primary halide ?

 Ans. (D)
 neo hexyl chloride

125. CCl4 is insoluble in water because :

 Ans. (B)
 CCl4 is non-polar

126. Which two alkyl chloride on heating with Na metal in presence of dry ether give isobutane ?

 Ans. (B)

and CH3Cl

127. From which substance trihalogen haloform compound is obtained ?

 Ans. (D)
 Methane

128. The given reaction is an example of,

C2H5Br + KCN (aq.) → C2H5CN + KBr :

 Ans. (B)
 Nucleophilic substitution

129. Which compound has highest reactivity towards SN2 reaction ?

 Ans. (A)
 1-Bromo butane

130. Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution reaction.
(i)

(ii)

(iii)

 Ans. (C)
 (i) < (iii) < (ii)
 Presence of an electron withdrawing group (–NO2) at ortho and para position facilitates nucleophilic substitutions. The effect of presence of
electron withdrawing group is very less at meta position.

131. Which two alkyl chlorides on heating with Na metal in presence of dry ether give isobutane?

 Ans. (B)


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132. Below reaction is known for what ?
C2H5OH + SOCl2 C2H5Cl + SO2 + HCl

 Ans. (B)
 Darzens reaction

133. The major product obtained when chlorobenzene is nitrated with HNO3 + conc. H2SO4 is

 Ans. (A)
 1-chloro-4-nitrobenzene

134. Ethylidene chloride is a/an.

 Ans. (B)
 gem-dihalide
 Ethylidene chloride is a gem-dihalide, CH3–CHCl2 in which both halogen atoms are attached to the same carbon atom.

135. In which of the following molecules carbon atom marked with asterisk (*) is asymmetric ?

 Ans. (B)
 (i), (ii), (iii)
 Asymmetric/chiral carbon atom is that in which all of its four valencies are with four different groups or atoms.
 In molecules (i), (ii) and (iii) all have asymmetric carbon as each carbon has satisfied all four valencies with four different groups of atoms.
 In molecule (iv), carbon satisfies two of its valencies with two hydrogen atoms. i.e. similar atom So, it is not an asymmetric carbon atom.

136. Which alkyl halide is preferentially hydrolysed by SN1 mechanism ?

 Ans. (D)
 (CH3)3C⋅Cl

137. Which would undergo SN1 reaction faster in the following ?

 Ans. (A)
 H2C = CH–CH2Cl

138. Indicate the structural formula of 1-chloro-4-secbutyl-2-methyl benzene.

 Ans. (D)


139. C6H5CH2Br ...........?

 Ans. (B)


140. Which of the following reaction (s) can be used for the preparation of alkyl halides ?
(I) CH3 CH2 OH + HCl

(II) CH3 CH2 OH + HCl

(III) (CH3)3 COH + HCl
(IV) (CH3)2 CHOH + HCl

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 Ans. (A)
 only (I) (III) and (IV)

141.

 Ans. (A)
 Benzene

142. Which of the following is halogen exchange reaction ?

 Ans. (A)
 R X + NaI → RI + NaX
 Halogen exchange reaction are those reactions in which one halide replaces another. This reaction is known as Finkelstien reaction. In this
(a) Halogen (–X) is replaced by iodine.
(b) Addition of hydrogen halide on alkene.
(c) Halogen replaces alchoholic group.
(d) Halogen replaces the hydrogen of benzoic ring.

143. Compound ‘A’ reacts with alcoholic KOH to yield compound ‘B’ which on ozonolysis followed by reaction with Zn/H2O gives methanal and
propanal. Compound ‘A’ is

 Ans. (C)
 l-chlorobutane


144. Which halide does not get hydrolysed by sodium hydroxide ?

 Ans. (A)
 Vinyl chloride

145. Match-I with II.

Match-I Match-II

(a) (i) Wurtz reaction

(b) (ii) Sand meyer reaction

(c) 2CH3CH2Cl + 2Na C2H5 – C2H5 + 2NaCl (iii) Fitting reaction

(d) 2C6H5Cl + 2Na C6H5 – C6H5 + 2NaCl (iv) Gattermann reation

Choose the correct option from below option.

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 Ans. (C)
 (a - ii), (b - iv), (c - i), (d - iii)

146. When CH3CH2CHCl2 is treated with NaNH2, the product formed is;

 Ans. (B)
 CH3 – C ≡ CH

147. Which halogen element present in thyroxine ?

 Ans. (C)
 I

148. The alkyl halide is converted into an alcohol by;

 Ans. (B)
 Substitution

149. The major product Y in the following reaction is :

 Ans. (B)


150. Number of monochloro derivatives obtained when neo-pentane is chlorinated, is

 Ans. (A)
 One

151. Which of the following alcohol reacts faster during Lucas test? And by which mechanism?

 Ans. (B)
 Tertiary alcohol, SN1

152. Ethylene oxide when treated with grignard reagent yields;

 Ans. (D)
 Primary alcohol


153. Out of the following isomeric alcohols containing five carbon atoms, the alcohol that exhibits optical isomerism is

 Ans. (B)
 2-pentanol

154. Which one of the following compounds is steam distillable ?

 Ans. (D)
 o-nitrophenol

155. Consider the following compounds :

(I)

(II)

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 (III)

(IV)

In which of the above compounds –OH group is attached to secondary carbon atoms ?

 Ans. (C)
 III and IV only

156. Alcohols and ethers are which type of isomers?

 Ans. (D)
 Functional group

157. IUPAC name of (C2H5)2 – CH – CH2 – OH is _________.

 Ans. (C)
 2-Ethylbutan-1-ol

158. The reactivity order of hydrogen halide for the reaction of alcohol with hydrogen halide is _______.

 Ans. (B)
 HI > HBr > HCl

159. Which of the following compound does not react with sodium?

 Ans. (D)
 CH3OCH3

160. ‘‘X’’.

What is ‘‘X’’ in the reaction ?

 Ans. (C)


 NaBH4 only do reduction of ketone.

161. What will be obtained on catalytic dehydrogenation of primary alcohol ?

 Ans. (A)
 Aldehyde

162. Glycerol is ________ type of alcohol.

 Ans. (D)
 Trihydric


163. Which of the following compound is not possible?

 Ans. (C)
 Butan-2,2-diol

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164. _______ CH3CH2 OH

 Ans. (C)
 CH3COOH

165. Ortho-nitro phenol is less soluble in water than para and meta-nitro phenols because :

 Ans. (A)
 O-nitrophenol shows intramolecular H-bonding

166. Industrially ethanol is prepared by ________.

 Ans. (C)
 By both (A) and (B)

167. Willamson synthesis is which type of reaction?

 Ans. (A)
 SN2

168. What will we obtain on a reaction of methyl alcohol with 23 gm Na? (Atomic mass of
Na = 23 gm/mol)

 Ans. (C)
 0.5 mol H2


169. In below reaction :

Identify the compound A and B.

 Ans. (C)

, CH3COCH3

170. 1 mol of metal ‘M’ reacts completely with alcohol to give 1.5 mol of H2. Then what will be the valency of metal ‘M’ ?

 Ans. (B)
 3


171. Which among the following alcohol has the least boiling point?

 Ans. (A)
 CH3CH2C(CH3)(OH)CH3

172. CH3 – CH = CH2 _______.

 Ans. (B)
 CH3 – CH2 – CH2 – OH

173. Compound B is obtained on a reaction of compound A with Na, while compound C is obtained on a reaction of A with PCl3. Moreover, on a

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 reaction of compound B with C forms diethyl ether, then identify compounds A, B and C respectively.

 Ans. (A)
 C2H5OH, C2H5ONa, C2H5Cl

174. Which of the following compounds is oxidised to prepare methyl ethyl ketone?

 Ans. (C)
 2-butanol


175. How much gram of ethanol is required to obtain 280 ml dihydrogen at S.T.P. by reaction of C2H5OH on with Na Metal ? (Mol.wt of ethanol =
46 g/mol)

 Ans. (C)
 1.15

176. Reaction of Grignard reagent C2H5MgBr with C8H8O followed by hydrolysis gives compound “A” which reacts instantly with Lucas reagent
to give compound B, C10H13Cl. The compound B is:

 Ans. (D)


177. Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass it is due to their

 Ans. (D)
 Formation of inter molecular H-bonding

178. Which of the following processes does not give benzene as a product ?

 Ans. (D)
 C6H5OH + H2CrO4

179. IUPAC names of given compounds are respectively.

CH3CH2CH2CH(OCH2CH3)CH2CH3, CH2 = CHCH2CH2OCH3

 Ans. (A)
 3-ethoxyhexane, 4-methoxybut-1-ene

180. Which of the following statement is not correct ?

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 Ans. (B)
 Phenol is neutralised by sodium carbonate.

181. Which of the given alcohol is least acidic?

 Ans. (C)
 tert-Butyl alcohol

182. Complete the reaction :

propan-2-ol _______.

 Ans. (C)
 Prop-1-ene

183. Which reaction is suitable for the preparation of tert-butylmethylether?

 Ans. (A)
 CH3Br + (CH3)3 CONa →

184. The correct order of solubility in water for given compound is…

 Ans. (A)
 Toluene < Fluorobenzene < Phenol

185. The strongest acid from the following is

 Ans. (A)


186. Which reagent can convert acetic acid into ethanol ?

 Ans. (B)
 LiAlH4 + ether

187. What is a by product of cumene method?

 Ans. (B)
 Propanone

188. The reaction of which of the given compounds is difficult with Lucas reagent?

 Ans. (C)
 Propan-1-ol

189. Which is the most suitable reagent for the conversion: R – CH2 – OH → R – CHO.

 Ans. (A)
 PCC

190. Which among the following is most preferable reagent for the reaction
R – CH2 – OH → R – CHO ?

 Ans. (A)
 PCC (Pyridinium chlorochromate)

191. Which of the given alcohol is vinylic alcohol?

 Ans. (C)
 H2C = CH–OH

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192. Which reagent is to be used to obtain but-2-en-1-ol from but-2-enal?

 Ans. (B)
 NaBH4

193. ________ (major product)

 Ans. (A)


194. Ethanol is coverted into ethoxy ethane,

 Ans. (A)
 by heating excess of ethanol with conc. H2SO4 at 140°C

195. What is the hybridization of O-atom in ether?

 Ans. (C)
 SP3

196. How many moles of bromine is required to prepare 2,4,6-tribromophenol from 1 mole phenol?

 Ans. (B)
 3

197. What is the C-O-H bond angle in phenol?

 Ans. (C)
 109°

198. The difference in the reaction of phenol with bromine in chloroform in water medium is due to :

 Ans. (B)
 Polarity of solvent

199. The product formed in the reaction of cumene with O2 followed by treatment with dil. HCl are ?

 Ans. (B)

and

200. Find the main product of the stable carbocation that is formed in the above process.

 Ans. (B)
 CH3 – H – CH3

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