KATHFORD Int'l College of Engineering & Management Balkumari Lalitpur, Nepal, Tel: 5201241, 5201911

2081-5-01 Hints & Solution

Section – I 16.(b)
R A 17.(b) MHPO4 shows that valency of M = 2 (since HPO4
1.(d) cosα = = = cos60° has valency 2). Hence chloride will be MCl2
A 2A
18.(b)
α = 60°
19.(d)
∴ θ = 90° + α = 150°
20.(a) [FeF6]3- = sp3d2
dp
2.(a) F= = 2bt [NiCl4]2- = dsp2
dt
[Ni(CO)4] = sp3
∴ Fαt
21.(d) F¯ is the most electronegative element.
3.(c) As he contract arms the moment of inertia decreases
due to decrease in distribution of mass. 22.(c) The impurity in extraction of copper is FeO which is
1 MC2rms 2 removed by adding SiO2.
4.(c) P= = KE 23.(d) It obeys Huckel’s rule i.e. it contains (4n+2)
3 V 3V
delocalized π electrons e.g.10 π electrons.
P ∝ KE
5.(b) Platinum & glass has almost same expansivity.
2
I1 1
6.(a) = =
I2 9 (aa ) 1
2

a1 1
∴ =
a2 3
24.(a) It is known as enyne compound. Its IUPAC format is:
2 2
Imax a + a2 4 Alk-en-yne. Numbering is done by the lowest sum
∴
Imin
= ( ) = ( ) = 4:1
a1 – a2 2 rule.
12 × 7 × 10–6 × 10–6 25.(d) Carbonium ion e.g. CH3+ (6 electrons)
7.(b) F = 9 × 109
r2 Free radical e.g. .CH3 (7 electrons)
7 × 12 × 10–6 × 10–6 Nitrene e.g. CH3N (6 electrons)
F' = 9 × 109 ×
r2 Carbanion e.g. CH3- (8 electrons)
∴ F' = F 26.(d) (CH3)3CNO2, CCl3CHO and (CH3)3CHO do not have
8.(b) α hydrogen atoms so they do not show tautomerism.
mv2 27.(a) +R or +M groups viz. –OH, OR, –NH2, –X etc give
9.(b) Bqv = ortho and para substituted product due to mesomeric
r
effect or resonating effect.
or, Bqr = mrw
28.(c)
2π
or, Bq =m 29.(a) B⊂A, then A∪B = A
T
1 2–i 2–i 2–i
2πm 30.(a) z= × = =
or, T= 2 + i 2 – i 2 2 – i2 5
Bq
2+i
10.(c) When magnet is broken along length then cross z̄ =
5
sectional area remain i.e. pole strength remain same.
31.(c) AM × H.M = GM2
x λ
11.(b) = G2
D d or, H.M =
A
Dλ
or, x= 32.(c) θ lies on 3rd quadrant.
d
2Dλ π 7π
∴ 2x = ∴ θ=π+ =
d 6 6

On 'd' increases then width of central maxima 7π

Most general value = 2nπ +
decreases. 6
12.(d) Focal length of mirror is independent of colour. 33.(c) Slope of OP × slope of OQ
13.(c) On increasing current intensity of x-ray increases. 2 2
= × = –1
t1 t2
14.(b) 90% of Ie = Ic
10 6 6 6 6
or, Ie = = 11 mA 34.(b) Let a = a1 i + a2 j + a3 k
0.9
66 66 66
15.(a) No. of protons = No. of mole × NA × No. of protons Then, a . i = a1, a . j = a2, a .k = a3
in one molecule of CaCO3

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 KATHFORD Int'l College of Engineering & Management Balkumari Lalitpur, Nepal, Tel: 5201241, 5201911
2081-5-01 Hints & Solution
666 666 666
So, (a . i ) i + (a . j ) j + (a .k )k
6 6 6 6
=– 0– ( 12) + (42 – 02)
= a1 i + a2 j + a3 k = a 1 5
= +2=
lim loga(1 + x) 2 2
35.(b)
x→0 x 46.(b) Obvious
lim loge(1 + x) 47.(a) Here, a = cos2θ – 1 = –sin2θ
= logae.
x→0 x b = sin2θ
= logae and a+b=0
36.(b) Let y = sec2x, z = tanx So, the lines are perpendiculars
dy 48.(a) Obvious
= 2secx.secx tanx
dx 49.(b) 50.(a) 51.(c) 52.(d) 53.(d) 54.(c)
dz 55.(a) 56.(b) 57.(a) 58.(d) 59.(c) 60.(a)
& = sec2x
dx
Section – II
dy
∴ = 2 tanx d
dz 61.(c) vR =
t
π
37.(b) sin (cosx) = – cos–1(cosx)
–1
1
2 = = 4 km/hr
150
π 60
= –x
2
∴ vr = vb2 – vR2 = 52 – 42 = 3 km/hr
π x2
Now, I sin–1(cosx) dx = x– +c 62.(c) wt = Ff
2 2
or, mg = µF
38.(c) xy = 1 which is rectangular hyperbola. So, e = 2.
dy/dx 40 × 10
39.(a) y=e F= = 500 N
0.8
dy
or, logy =
dx YAe πd2
63.(b) F= = 9 × 1010 × × 0.2%
l 4
∴ Degree = 1
π(0.6 × 10–3)2 0.2
40.(b) dr's of PQ = 0 – 0, 0 – 1, 1 – 0 = 9 × 1010 × ×
4 100
= 0, –1, 1 = 51 N
dr's of line ⊥r to plane = 1, 1, 1
64.(c) Volume overflow (∆V)a = V0γa∆θ
Now, a1a2 + b1b2 + c1c2 = 0 × 1 + (–1)×1+1 × 1 = 0
= 200 (γr – γg) (80 – 20)
i.e. line PQ is parallel to plane projection of PQ
= 200(18 × 10–5 – 27 × 10–6) × 60
on this plane is just the length of PQ.
= 1.84 cc
= (0 – 0)2 + (0.1)2 + (1 – 0)2 = 2
65.(a) P = σAT4 = σ 4πR2T4
41.(d) Greatest coefficient is the coeff. of mid term.
P σ 4πR2T4
1 E= =
42.(d) f(x) = will be minimum when 4πr2 4πr2
3sinx – 4cosx + 7
2 4
E'
3sinx – 4cosx + 7 is maximum.
Maximum of denominator
∴
E
= (2RR) (2TT) = 64:1
= 32 + 42 + 7 = 5 + 7 = 12 2x 2y
66.(b) t1 + t2 = +
v v
43.(c) The given equation are intersecting lines.
v
44.(c) ax + by = 2ab or, x + y = (1.5 + 3.5)
2
x y
or, + =1 340
2b 2a or, d=5× = 850 m
2
1 1
A= × b × h = . 2b.2a = 2ab 67.(c) Diagonal (d) = 3 a
2 2
2 0 2 1 Q
45.(a) I –1
|x| dx = I –1
(–x) dx + I xdx
0
V=8×
4πε0 d
2
2 0 2 2
x x
= [ ] +[ ]
–
2 –1 2 0 =
4Q
πε0 3 a
=
4Q
3 πεra

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 KATHFORD Int'l College of Engineering & Management Balkumari Lalitpur, Nepal, Tel: 5201241, 5201911
2081-5-01 Hints & Solution
68.(c) Across CD 9
λP R
R = =9
R=
3 λL 1
R
Along AD
2R R ∴ λP = 4 × λL = 9 × 912 = 8208 Å
R' = + =R
3 3 74.(a) MnO4- + 8H+ + 5e- → Mn2+ + 4H2O]×3
R Fe2+ → Fe3+ + 1e-]×5
∴ Req =
2
As 5 moles of Fe(C2O4) = 3 moles of KmnO4
BANcos60°
69.(d) E= So, 1 mol of Fe(C2O4) = 3/5 moles of KmnO4 = 0.6
t
–4 –4 mol
4 × 10 × 20 × 10 × 100
= × cos60
0.2 75.(a) Nmix = (N1V1 + N2V2+ N3V3)/Vtotal
–3
= 2 × 10 V 76.(b) 71 parts of chlorine combine with 32 parts sulphur
= 2 mV 35.5 parts of chlorine combine with 16 parts of
sulphur
70.(d) 10 + 8 – x = 12 + x
or, 2x = 6 Hence, eq.wt of S in SCl2 = 16
or, x = 3 cm 77.(d) 1mol of Au = 197g = 0.197kg = 6.02 × 1023 atoms so,
19.7 kg Au = 6.02 × 1025 atoms
( µ1)
d=t 1–
78.(a) No. of mol × NA
1 79.(c) Bond length order: Single bond > bond created by
or, 3 = 8(1 – ) resonance > double bond > triple bond
µ
8 80.(c)
or, 3=8–
µ 81.(c) B shows + I effect and hyperconjugation
8 C shows - I effect D shows -R and -I effect
or, =5
µ
dy fx 2ax + 2hy
8 82.(a) =– =–
or, µ= = 1.6 dx fy 2hx + 2by
5
ax + hy
λ =–
71.(b) Path difference for 3rd minima = (2n – 1) hx + by
2
6000 83.(a) f(x) = y = x2 – 6x + 9 – 3
= (2 × 3 – 1) ×
2 y + 3 = (x – 3)2 ≥ 0
= 1.5 × 10–6 m
y+3≥0
t 2T
m 1 T1/2 1 T1/2 y ≥ –3
72.(d)
m0
= ( ) =( )
2 2
84.(b) z is a locus of a point whose distance from a point (3,
2×1.44 T1/2 4) is always 5 unit. So, locus of z is a circle.
1 T1/2
= ()
2
= 0.135 OR, put z = x + iy and solve.
∴ m = 0.135 × 10 = 1.35g We get; (x – 3)2 + (y – 4)2 = 25
73.(d) For Lyman series 85.(a) Since, one of the lines bisects the angle b/w the axes
1 1 1 so the line is either y = x or
λL
=R –
1 ∞ [ ] y = –x
1 Then the eqn is
or, λL = ... (i)
R
ax2 ± 2hx2 + bx2 = 0
For Paschen series
or, a + b = ± 2h
1 1 1
λp
=R 2–
3 ∞ [ ] ∴ (a + b)2 = 4h2
9 86.(d) The line passes through the centre of the circle. So, it
or, λp = ... (ii) is a diameter.
R
Dividing (ii) by (i) ∴ Angle between diameter and tangent of
circle is 90°

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 KATHFORD Int'l College of Engineering & Management Balkumari Lalitpur, Nepal, Tel: 5201241, 5201911
2081-5-01 Hints & Solution
87.(a) If a = 0, by + cz + d = 0 is a plane parallel to x-axis. 92.(b) No of diagonals, nC2 – n = 144
6 6 6
6 6 i j k It is true when n = 11
88.(b) a ×b =1 1 1
–2 3 1 93.(d)
4
V = πr3
3
6 6 6 dv 4 dr
= –2 i – 3 j + 5k = π 3r2
dt 3 dt
1 6 6 38
Area = |a × b | = dv
2 2 18 = 4πr2
dt
89.(b) a1/x = b1/y = c1/z = k
dr 9
Then, a = kx, b = ky, c = kz = cm/sec
dt 128π
Since, a, b, c are in G.P. 94.(a) Let y = sinx
b2 = ac Then dy = cosx dx
k2y = kx.ky = kx+y π
When x = 0; y = 0 and when x = , y = 1
or, 2y = x + y 2
∴ π/2 1 1
π
2
x, y, z are in A.P.
Then I 0
cosx
1 + sin2x
dx = I 1 dy+ y = [tan
0
2
–1
y] =
0 4
90.(a) Σnn! = Σ(n –n 1)! a

n–1+1
95.(c) Area = 2 I ydx
=Σ
0

(n – 1)! a

1 1
= 2 4a I 21 dx
=Σ +Σ
x
(n – 2)! (n – 1)!
a3/2 8 2
= 4 a. = a
= 2e 3/2 3
91.(c) f '(x) = 4x3 + 12x2 96.(c) Apply, R2 → R2 – R1
f"(x) = 12x2 + 24x and R3 → R3 – R1
= 12x(x + 2)
1
∆= 0
1
x
1
0 = xy
Point of inflection, x = 0, x = –2
0 0 y
i.e. x ∈ (–∞, –2)∪(0, ∞)
i.e. ∆ is divisible by both x & y
97.(d) 98.(d) 99.(b) 100.(c)

…The End…