1

Class 11th JEE

MRJM/11 Milestone Test-1 Phase-4

DATE: 25/08/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (4) 31. (1) 61. (1)
2. (1) 32. (2) 62. (1)
3. (1) 33. (2) 63. (4)
4. (2) 34. (1) 64. (1)
5. (3) 35. (2) 65. (2)
6. (4) 36. (3) 66. (4)
7. (3) 37. (1) 67. (4)
8. (3) 38. (3) 68. (1)
9. (3) 39. (1) 69. (3)
10. (1) 40. (1) 70. (4)
11. (2) 41. (1) 71. (4)
12. (3) 42. (3) 72. (3)
13. (1) 43. (3) 73. (1)
14. (1) 44. (2) 74. (1)
15. (1) 45. (3) 75. (3)
16. (3) 46. (1) 76. (1)
17. (3) 47. (4) 77. (3)
18. (3) 48. (2) 78. (1)
19. (3) 49. (4) 79. (2)
20. (1) 50. (2) 80. (4)
21. (7) 51. (10) 81. (8)
22. (0) 52. (4) 82. (60)
23. (19) 53. (6) 83. (21)
24. (36) 54. (602) 84. (1)
25. (50) 55. (102) 85. (9)
26. (1) 56. (10) 86. (13)
27. (3) 57. (2) 87. (9)
28. (3) 58. (6) 88. (4)
29. (2) 59. (202) 89. (4)
30. (2) 60. (7) 90. (2)
 SECTION-I (PHYSICS)
1. (4) 5. (3)
Given y3 = 4x2 Volume = a3 = (7.203)3 = 373.715m3
dy In significant figures, the volume of cube will be
⇒ 3y2 = 8 x (taking derivative of both sides)
dx 373.7m3 because the side of the cube has four
dy 8 x significant figures
⇒ =
dx 3 y 2
6. (4)
 8
At the point 1,
  π 2 
3   3 (a − b )h  =
2
 Volume
 
dy
=1
dx 7. (3)
⇒ tanθ = 1 GM
g=
⇒ θ = 45º r2
4
2. (1) M = πr 3ρ
3
There are 6 significant figures in the number 4 
108.023 as all the figures define a particular G  πr 3ρ 
g=  2 
3
measurement. In the number 0.19 there are only two ⇒
r
significant figures as the zeroes on the left of
3g
decimal point and the zeroes on the right of non- ⇒ ρ=
4πGr
zero numbers after the decimal point are not
significant.
8. (3)
A= 4πr 2
3. (1)
∆A ∆r
V = d a Eb Fractional error =2
A r
Writing dimensions on two sides of the equation (Error will not be involved in constant 4π )
[ LT −1 ] = [ ML−1T −2 ]b [ ML−3 ]a ∆A
⇒ × 100 =×2 0.3% = 0.6%
⇒ LT −1 = M a +b L−3a −bT −2b A
Comparing the dimensions on two sides, we get ∆A ∆r
SO, =4 is false
a + b= 0 A r
–3a – b = 1
–2b = –1 9. (3)
Solving for a and b, we get Given p + q = 2
1 1 And p 4 + q 4 =
272
b = and a = −
2 2 Now, ( p 2 + q 2 ) 2 − 2 p 2 q 2 =
272
2
4. (2) ⇒ ( p + q ) 2 − 2 pq  − 2 p 2 q 2 =
272
E = σT 4 Let pq =t ⇒ (4 − 2t ) 2 − 2t 2 =272
⇒ [ E ] = [σ][T 4 ] 2t 2 − 16t − 256 =
0
ML2T −2 ⇒ t 2 − 8t − 128 =0
⇒ 2
= [σ]K 4
LT ⇒ (t − 16)(t + 8) =0
−3 −4
⇒ [σ] =MT K ⇒ = = 16
t pq
Hence, the required equation is x 2 − 2 x + 16 =
0
[2]
10. (1) =y 3sin 2 x cos x − 6sec x sec x tan x
Let r is common ratio 2
a3 a1r 2  3 1
= = r 2 ⇒ r 2 = 25 ⇒=y 3   × − 6 × 2 × 2 × 3
a1 a1  2  2
a9 a1r 8 9 9 − 192 3
Now = = r=
4
(25)=
2
54 ⇒ y= − 24 3 =
a5 a1r 4 8 8

11. (2) 15. (1)

dt 1
∫ (6t=
b = ar log(6t − 1) + C
c = ar2 − 1) 6
3a, 7b and 15c are in A.P.
⇒ 14b = 3a + 15c 16. (3)
⇒ 14(ar) = 3a + 15ar2
⇒ 14r = 3 + 15r2 17. (3)
⇒ 15r2 – 14r + 3 = 0 =y sin x + x 4
1 3
⇒ (3r − 1)(5r − 3) = 0, r =
, ⇒
dy
= cos x + 4 x3
3 5 dx
1
Only acceptable value is r = , because d2y
3 ⇒ 2
=
− sin x + 12 x 2
dx
 1
r ∈  0, 
 2
18. (3)
Let common difference of A.P. is d
Use dimensional analysis’s
7 2
∴ d= 7b − 3a =7 ar − 3a =a − 3a = − a
3 3 19. (3)
2 15 2
∴ 4th term = 15c − a = a− a= a Use dimensional analysis’s
3 9 3
20. (1)
12. (3)
Let sin 36º = α
(A) ∫ sec x tan =
xdx sec x + C

5 −1 −cosec kx
Take cos 72º = (B) ∫ cosec kx =
cot kx dx
k
+C
4
cot kx
⇒
5 −1
1 − 2sin 2 36º =
(C) ∫ cosec 2 kx dx = −
k
+C
4
sin kx
⇒ 4 − 8α 2= 5 −1 (D) ∫ =
cos kx dx
k
+C
⇒ 5 − 8α = 5 2

Take square of both sides 21. (7)

⇒ (5 − 8α ) = 5 ⇒ 25 + 64α − 80α = 5
2 2 4 2
dy
= 4 x − 1= 0
⇒ 64α 4 − 80α 2 + 20 =0 dx
1
⇒ 16α 4 − 20α 2 + 5 =0 ⇒x=
4
Now,
13. (1)
d2y
dy d 2e 2 x e 2 x = 4>0
=×
e 2x ( 2x ) = = dx 2
dx dx 2 2x 2x
 1 1 7
∴ y=
min 2  − = +1
14. (1)  16  4 8

[3]
22. (0) ⇒ x 2 − 7 x + 10 = 0
⇒ ( x − 2)( x − 5) =
1
1
 x3 4 x 2  0
∫
0
(3 x 2 − 4 x + 1)dx=  3 −
 3 2
+ x
0 ⇒ x = 2 or 5
But x > 3
4
=1− +1 = 0 So, x = 5
2 Only one solution

23. (19) 27. (3)

∆x
× 100
x 28. (3)
∆M  ∆L   ∆T  Let square is made with piece of length x meter &
= × 100 + 3  × 100  + 2  × 100  hexagon with piece of length y metre x + y = 20..(i)
M  L   T 

24. (36)
=n1 100,=M 1 1= g , L1 1cm, T1 = 1 sec and M2 = 1
kg
L2 =1 metre, T2 =1 minute
By substituting these values in the following x
Side of square (a ) = & side of a hexagon
conversion formula 4
a b c
 M   L  T  y
n2 = n1  1   1   1  (b) =
 M 2   L2   T2  6
Now, let combined area A = area of square + area of
Where a = 1, b = 1, c = –2
1 1 −2
hexagon
 1g   1 cm   1s  x2 3 y2
n2 = 100       A= + 6× ×
 1kg   1 meter   1minute  16 4 36
−2
1
 1g   1cm   1s 
1 x2 3 y 2 x2 3
= =+ =+ (20 − x) 2 from (i)
n2 100  3   2    3.6 16 24 16 24
 10 g   10 cm   60 s 
For minimum area
dA 2x 2 3
25. (50) =0 ⇒ − (20 − x) =0
[Density] = ML–3 dx 16 24
a
M  L   T 
b b
⇒ 6 x − 4 3(20 − x) = 0
Since n2 = n1  1   1   1 
 M 2   L2   T 2  ⇒ 6 x + 4 3x =
80 3
Where a = 1, b = –3, c = 0 and n1 = 8, n2 = ? 80 3 80 3 40
−3
=
⇒ x = =
 1g   1cm  6 + 4 3 2 3( 3 + 2) 2 + 3
⇒ n2 = 8   
 20 g   5cm  ⇒= x 40(2 − 3)
1 Hence, side of hexagon
⇒ n2 = 8 × × 5 × 5 × 5
⇒ n2 = 50
20
= =
(
y 20 3 2 − 3
=
)20 3
6 6 6(2 + 3)
26. (1) 10 3 10
log 4 ( x −=1) log 2 ( x − 3) = =
3(2 + 3) 2 3 + 3
x > 1 & x > 3 ⇒ x > 3 (according to definition of
log) 29. (2)
⇒ log 4 ( x −= 1) log 2 ( x − 3) x = 0.72 + 0.8 + 3.87 – 1.089 = 0.7 + 0.8 + 3.9 –1.1
1 = 4.3
log 2 ( x −=1) log 2 ( x − 3) Thus, the number of significant digit is 2
2
log 2 ( x −=
1) log 2 ( x − 3) 2 30. (2)
⇒ ( x − 1) = ( x − 3) 2 The volume of wire
= 1.4418 cm3 = 1.4 cm3
⇒ x2 + 9 − 6x = x − 1 Thus, number of significant digits in 1.4 cm3 is 2
[4]
 SECTION-II (CHEMISTRY)
31. (1) 41. (1)
8
C 3 × 10 m/s 1 1  1 1 
λ= = = × 10−6 m = RZ2  2 − 2  , where n1 = n, n 2= n + 1
v 6 × 1014 / s 2 λ  n1 n 2 
5 × 10−7 m =
= 500 nm
1  1 1 
=
∴ RZ2  2 − 
λ n (n + 1) 2 
32. (2)
H+ is not a single e– species 1  2n + 1  2
⇒ =   RZ
λ  n 2 (n + 1) 2 
33. (2)
Since, n >> 1;
For first line of Balmar series.
n2 = 3 to n1 = 2 Therefore, 2n + 1 ≈ 2n
For He+, Z = 2 And (n + 1) 2 ≈ n 2
1  1 1  9 − 4  20R 1  2n 
= R.(Z2 )  2 − 2  = R × 4 = ∴ =
RZ2  2 2 
λ 2 3   36  36 λ  n ⋅n 
v 2RZ2 2cRZ2
34. (1) =
⇒ = or v
c n3 n3
n2
⇒ rn =
r0
Z
42. (3)
35. (2) Work function of Li2+ = 9E.
1 1
Isotone has no. of neutrons in its nucleus Ep =
W + mv 2 ; E p = 9E + mv 2
2 2
8 X  → 17
x
9 Y
Number of neutrons in y = 17 – 9 = 8 2(E p − 9E)
v=
∴ no. of neutrons in X = x – 8 m
∴ x = 8 + 8 = 16
43. (3)
36. (3) Radial node occurs where probability of finding e–
1 2 1  n2h2  is zero.
KE = mv = m  2 2 2 
2 2  4π m r  ∴=
ψ 2 0 or=
ψ 0
1 m ⋅ (2) 2 ⋅ h 2 h2 ∴ 6 − 6σ + σ 2 = 0; σ = 3 ± 3
= × =
2 4 ⋅ π2 ⋅ m 2 (4a 0 ) 2 32π2 ma 02 3 (3 + 3)a 0
For max. distance r =
2 Z
37. (1)
hc 1 1  44. (2)
=2.178 × 10−18  −  Energy of 3s orbital is less than for the 3p and 3d
λ 1 4 
orbitals.
⇒
= λ 1.214 × 10−7 m

45. (3)
38. (3)
Number of electrons = 2n2 = 9 × 2 = 18 3d x 2 − y2 orbital has zero radial node.

39. (1) 46. (1)

Rubidium = [Kr]5s1
Uncertainity principle is not applicable to
40. (1)
φ= hv − KE stationary electrons.
0.5 eV = 5 eV – hv0
hv0 = 4.5 eV 47. (4)
All statements are correct.
[5]
48. (2) 55. (102)
A-S, B-P, C-Q, D-R 1  1 1 
= RH  2 − 2 
49. (4) λ  n1 n 2 
S-I ; n = 4 1 1 1 8
2h ⇒ = R H  2 − 2  = 1.1 × 107 ×
Angular momentum = λ 1 3  9
π
900
=λ × 10−9 = 102 nm
50. (2) 8 × 1.1
Both statements are correct
56. (10)
51. (10) ∆n = 6 – 2 = 4
n = 3,  = 2 ⇒ 3d orbital 4(4 + 1)
So maximum no. of e– no. of lines = = 10
2
= 2(2 + 1) = 2(2 × 2 + 1) = 10e −
57. (2)
52. (4) h 6.62 × 10−27
For mmax = 3 ∆x ⋅ ∆=
P ⇒ ∆=
x
 max = 3
4π 4π × 2.5 × 10−16
0.662
∴ n = 4 because  varies from 0 to (n – 1) = × 10−11
∴ number of waves made by e– = n = 4 π

53. (6) 58. (6)

Cr = [Ar] 4s13d5
∆n(∆n + 1) 3 × 4
=
Number of radiation = = = 6
2 2 59. (202)
T ⋅ E = n ⋅ EP
54. (602)
6.6 × 10−34 × 3 × 108
I.E. =
hc 1= n ×
λ 4000 × 10−10
6.6 × 10−34 × 3 × 108 4000 × 10−10
= n=
198 × 10−9 6.6 × 3 × 10−26
198 = 202 × 1016
= × 10−18 J/atom
198
60. (7)
For 1 mole
∆n(∆n + 1) 4 × 5
10−18 × 6.02 × 1023 Total number of lines = = = 10
I.E. = kJ/mol 2 2
1000 No. of lines in Balmer series = 5 – 2 = 3
= 602 kJ/mol

SECTION-III (MATHEMATICS)
61. (1) 63. (4)
f (π) + f (2 ⋅ 1)
=2
f (3)
λ=2
17λ
⇒ = 8.5
4

62. (1)
n(A – B) ∪ n(B – A)
The number of students who have taken exactly one
= n(A) + n(B) – 2n(A ∩ B)
subject is 98

[6]
64. (1) 70. (4)
(a + b + c)2 = a2 + b2 + c2 + 2ab + 2bc + 2ca
∴ 21 − 4 5 − 8 3 − 4 15
(
log 5 + log x 2 + 1 ) =2
log( x − 2)
=−
( 5) 2 + (2 3)2 + (2)2 + 2(− 5)2 + 2(2)2 3
⇒ log 5 + log (x2 + 1) = log (x – 2)2
+2(2 3)(− 5) ⇒ log (x2 + 1) – log (x – 2)2 = –log 5
=(− 5 + 2 3 + 2)2 x2 + 1 1
⇒ = ⇒ x2 + 4 – 4x = 5x2 + 5
( x − 2) 2 5
⇒ 21 − 4 5 + 8 3 − 4 15 = (− 5 + 2 3 + 2) 2
⇒ 4x2 + 4x + 1 = 0 ⇒ (2x + 1)2 = 0
=
− 5+2 3+2=
− 5+2 3+2
⇒ x = –1/2
{ }
x 2 =| x |
71. (4)
 x 4
65. (2) 2 − 
 3
>0
( )(
2 − 1 2x − 2
x
)
72. (3)
2
3 x −5 x +3
<0
66. (4) x2 − 2 x + 2
(x2 + 3x + 1) (x2 + 3x – 3) ≥ 5 2 
⇒ x ∈  ,1
Let y = x2 + 3x 3 
(y + 1) (y – 3) ≥ 5
⇒ y2 – 3y + y – 3 ≥ 5 73. (1)
⇒ y2 – 2y – 8 ≥ 0 A = {1, 5, 7, 11, 13, 17, 19, 23, 25, 29, 31, 35}
⇒ (y + 2) (y – 4) ≥ 0 B = {1, 3, 7, 9, 11, 13, 17, 19, 21, 23, 27, 29, 31, 33,
⇒ (x2 + 3x + 2) (x2 + 3x – 4) ≥ 0 37, 39}
⇒ (x + 1) (x + 2) (x + 4) (x – 1) ≥ 0 (A) A ∩ B = {1, 7, 11, 13, 17, 19, 23, 29, 31, 37}
n(A ∩ B) = 9
(B) C = {3, 5, 7, 11, 13, 17, 19, 23, 29, 31, 37}
x ∈ (–∞, –4] ∪ [–2, –1] ∪ [1, ∞) n(C) = 11
(C) A – B = {5, 25, 35}
67. (4) B – A = {3, 9,21,27, 33, 37, 39}
Only (2, 1) is possible n(A∆B) = 10
(D) n(A – B) × n(B – A) = 3 × 7 = 21
68. (1)
a1 = a2 = ….. = an = 0 74. (1)
( 1 + x2 + 1 − x2 ) + ( 1 + x2 − 1 − x2 ) 3 +1
69. (3) =
( 1 + x2 + 1 − x2 ) − ( 1 + x2 − 1 − x2 ) 3 −1

2 1 + x2
4
⇒ =
2 1− x 2 2

1 + x2
4
⇒ =
1− x 1 2

3 3
⇒ x2 = ⇒ x =±
5 5

[7]
75. (3) 83. (21)
n(A ∩ B)′ = 40 ⇒ n (A ∩ B) = 60 – 40 = 20 (2m – n) 2n = 120
⇒ n(A – B) = 50 – 20 = 30 ⇒ n = 3, m = 7

76. (1) 84. (1)

−m
( x − 1) 2 ( x + 2)( x − 2)( x − 2)( x − 3)  1  x  1 
≥0  m−n m− p  × +
−m  n−m n− p 
x 2 ( x + 6) 1+ x +x  x 1+ x +x 

( x − 1) 2 ( x − 2) 2 ( x − 3)( x + 2) x−n  1  x
−p
≥0 × +  ×
x 2 ( x + 6) x−n  1 + x p −m + x p −n  x − p
CP: x = 1, 2, 3, –2, 0, –6 x−m x−n
= +
x−m + x−n + x− p x−n + x−m + x− p
x− p
x ∈ (–6, –2] ∪ [3, ∞) ∪ {1, 2} +
x− p + x−m + x−n
x−m + x−n + x− p
77. (3) = = 1
x−m + x−n + x− p
Option (3) is correct.

78. (1) 85. (9)

x ∈ {–1, 1, 2, 4, 5, 6, 7, 8, 9}
m=
−n ( log 2 5 − 2 )( log 2 5 + 1) > 0
86. (13)
79. (2)
x−6 + x+6 =
12
The number of elements in the range of n(A∆B) is
16 x ∈ [–6, 6]

80. (4) 87. (9)

A – (B ∪ C) 4a2 + 9b2 + c2 – 6ab – 3bc – 2ca = 0
⇒ (2a)2 + (3b)2 + c2 – (2a) (3b) – (3b) c – c (2a) = 0
81. (8) If A2 + B2 + C2 – AB – BC – CA = 0

x −3 ⇒A=B=C
<0 ⇒ 2a = 3b = c
x −5
c c
⇒ x ∈ (–5, –3) ∪ (3, 5) ⇒ a= , b=
2 3
c
82. (60) 4× + c
4a + c 2 3c
∴ = = ×3= 9
b c c
3
88. (4)
x 2 − 3 x − 28 =
0

⇒ ( x − 7 )( x + 4 ) =
0
Hence number of subset = 22 = 4

[8]
89. (4) 3
1  1  1
x3 + = x +  − 3 x +  = 8 − 6 = 2
3 
n(A × B) ∩ (B × A)) = (n(A ∩ B))2 = 4 x  x   x
 1  1  1 1
∴  x 2 + 2  x3 + 3  = x5 + + x + 5
90. (2)  x  x  x x
 1
2
 1 
x+  =
(2) 2 ⇒ 2 × 2=  x5 + 5  + 2
 x  x 
1
⇒ x2 +
1
=
2 ⇒ x5 + 5 = 2
x2 x

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