Pre-Medical : Chemistry

ALLEN
EXERCISE-I (Conceptual Questions) Build Up Your Understanding
OCTET RULE : 11. Which compound of xenon is not possible
1. Among the following element group number is not (1) XeF2 (2) XeF4 (3) XeF5 (4) XeF6
equals to valence electrons -
(1) Na (2) N 12. Similarity of fluorine and oxygen may not be at-
(3) Ne (4) None tributed to-
(1) Their atomic and ionic radii are closely similar
2. Which of the following does not act as lewis acid ? (2) The atom of both elements attain an octet of
(1) BF3 (2) SnCl4 electrons in their valence shell
(3) CCl4 (4) SF4 (3) Both of them are highly electronegative ele-
COVALENT BOND ments
(4) Both form stable pp – pp multiple bonds with
3. The strength of bonds by 2s - 2s, 2p - 2p and themselves
2p -2s overlapping has the order :-
(1) s – s > p – p > s – p 13. Higher is the bond order, greater is -
(2) s – s > p – s > p – p (1) Bond dissociation energy
(3) p – p > s – p > s – s (2) Covalent character
(4) p – p > s – s > p – s (3) Bond length

N
(4) Paramagnetism
4. In which of the excitation state of chlorine ClF3 is
formed:- HYBRIDISATION
(1) In ground state

20
(2) In third excitation state 14. In the protonation of H2O, change occurs in
(3) In first excitation state (1) Hybridisation state of oxygen
(4) In second excitation state
E (2) Shape of molecule

-
(3) Hybridisation and shape both

19
5. A sigma bond is formed by the overlapping of :– (4) None
(1) s-s orbital alone
(2) s and p orbitals alone 15. In the compound
(3) s–s, s–p or p–p orbitals along internuclear axis
(4) p–p orbital along the sides
1 2 203 4 5
CH2 CH—CH2—CH2—C CH ,the C 2 —C 3
6
LL
bond is formed by the overlapping of :-
6. Which overlapping is involved in HCl molecule :– (1) sp – sp2 (2) sp3 – sp3
n
(1) s–s overlap (2) p–p overlap (3) sp – sp3 (4) sp2 – sp3
(3) s–d overlap (4) s–p overlap
io

16. Among the following species identify the

7. Which is not characteristic of p-bond:- isostructural pairs:-
ss

(1) p - bond is formed when a sigma bond already

+
formed NF3, NO3– ,BF3, H3O , HN3
(2) p - bond are formed from hybrid orbitals
Se

+
(3) p - bond may be formed by the overlapping of (1) [NF3, NO3– ] and [BF3, H3O ]
A

p-orbitals
(2) [NF3, HN3] and [ NO3– , BF3]
(4) p-bond results from lateral overlap of atomic
orbitals
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(3) [NF3, H3O+] and [ NO3– , BF3]

8. p bond is formed :- (4) [NF3, H3O+] and [HN3, BF3]
(1) By overlapping of hybridised orbitals
(2) Overlapping of s - s orbitals 17. Which of the set of species have same hybridisation
(3) Head on overlapping of p -p orbitals state but different shapes:-
(4) By p - p collateral overlapping
(1) NO2+ , NO2 , NO2–
9. Which of the following overlapping is strongest ?
(1) 1s – 1s (2) 2p – 2p (2) ClO4– , SF4, XeF4
(3) 2s – 2p (4) 1s – 2p
(3) NH+4 , H3O+, OF2
10. p–p overlapping will be observed in the molecules of:
(1) Hydrogen (2) Hydrogen bromide (4) SO4–2 , PO4–3 , ClO4–
(3) Hydrogen chloride (4) Chlorine

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18. Which of the following elements can not exhibit 27. Amongst CO32–, AsO33–, XeO3 , ClO3— , BO33– and
sp3d hybridisation state:- SO32– the non-planar species are :-
(a) C (b) P (c) Cl (d) B (1) XeO3 , ClO3– , SO32–,AsO33–
Correct answer is:- (2) AsO33– , XeO3 , CO3–2
(1) a, c (2) a, d (3) b, c (4) b, d (3) BO33– , CO32– , SO32–
(4) AsO33– , BO33– , CO32–
19. Which of the following species are expected to be
planar:- 28. The type of hybrid orbitals used by chlorine atom
in ClO–, ClO2 , ClO3 and ClO4 is/are :-
– – –
2+
(a) NH3 (b) NH3 (c) CH3+ (d) PCl3 (1) sp, sp2, sp3 and sp3d (2) sp and sp3
The correct answer is:- (3) Only sp3 (4) only sp
(1) b and c (2) c and d
29. On the basis of hybridization of one s & one p
(3) b and d (4) a and d
orbitals they are arrange at :-
20. In which following set of compound/ion has linear (1) Two orbitals mutually at 90° angle
shape (2) two orbitals mutually at 180° angle
(3) Two orbitals mutually at 120° angle
(1) CH4, NH+4 , BH4– (2) CO3–2 , NO3– , BF3 (4) Two orbitals mutually at 150° angle

N
(3) NO2+ , CO2, XeF2 (4) BeCl2, BCl3, CH4 30. Which of the following having a square planar struc-
ture is
21. Which order of decreasing bond angle is correct:-
(1) NH+4 (2) BF4– (3) XeF4 (4) CCl4

20
+
(1) CCl4 > BF3 > NO 2

(2) NH3 > NCl3 > NBr3 31. When p-character of hybridised orbital (formed by
(3) Br2O > Cl2O > OF2 s and p orbitals) increases. Then the bond angle
E
-
(1) Decreases (2) Increases
(4) PCl3 > PBr3 > PI3

19
(3) Becomes twice (4) Remains unaltered
22. Which of the following set is not correct:–
32. Which orbitals overlap to form bond in OF2
(1) SO3, O3, NH4+ all have coordinate bonds
(2) H2O, NO2, ClO2– , all are 'V' shape molecules (1) sp3 – 2p 20 (2) sp2–2p
LL
–
(3) sp – 2p (4) p – p
(3) I3 , ICl2– , NO2+ ; all are linear molecules
33. In compounds X, all the bond angles are exactly
n
(4) SF4, SiF4, XeF4 are tetrahedral in shape
109°28'. X is :
io

23. Shape of a molecule having 4 bond pairs and two (1) Chloromethane
lone pairs of electrons, will be :- (2) Carbon tetrachloride
(3) Iodoform
ss

(1) Square planar (2) Tetra hedral

(3) Linear (4) Octa hedral (4) Chloroform

34. Among the following orbitals/bonds, the angle is

Se

24. The shape of IF4+ will be :- minimum between :

A

(1) Square planar (1) sp3 bonds

(2) Tetrahedral (2) px and py orbitals
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(3) Pentagonal bipyramidal (3) H—O—H bond in water

(4) Distorted tetrahedral (4) sp bonds

25. Which of the following has pyramidal shape ? 35. The structure and hybridization of Si(CH3)4 is :
(1) BF3 (2) H3O+ (1) bent, sp
(3) NO3 —
(4) CO32— (2) trigonal, sp2
(3) octahedral, sp3d
26. A s bonded molecule MX3 is T–shaped. The (4) tetrahedral, sp3
number of non–bonding pairs of electrons is
(1) 0 36. The AsF5 molecule is trigonal bipyramidal. The hybrid
(2) 2 orbitals used by the As atoms for bonding are:
(3) 1
(1) d x2 - y2 ,d z2 ,s,p x ,p y (2) d xy ,s,p x ,p y ,p z
(4) Can be predicted if atomic number of M is
known.
(3) s,p x ,p y ,p z ,d z2 (4) d x2 - y2 , s,p x ,p y
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37. When the hybridization state of carbon atom DIPOLE MOMENT
changes from sp3, sp2 and sp, the angle between
the hybridized orbitals. 44. Which statement is correct:-
(1) decrease considerably (1) All the compounds having polar bonds, have
(2) increase progressively dipole moment
(3) decrease gradually (2) SO2 is non-polar
(4) all of these (3) H2O molecule is non polar, having polar bonds
(4) PH3 is polar molecule having non polar bonds
38. The hybridization states of the central atoms of the
45. BeF2 has zero dipole moment where as H 2O has a
ions I3- , ICl 4- and ICl2- are respectively : dipole moment because :-
(1) sp2, dsp2, sp3 (1) Water is linear
(2) sp3d, sp3d2 and sp3d (2) H2O is bent
(3) sp3d, sp3d, dsp2 (3) F is more electronegative than O
(4) sp, sp, dsp2 (4) Hydrogen bonding is present in H2O

39. Molecular shapes of SF4, CF4 and XeF4 are :- 46. Which of the following species are symmetrical :-
(1) The same, with 2, 0 and 1 lone pairs of electrons (a) XeF4 (b) XeF6

N
respectively +2
(2) The same, with 1,1 and 1 lone pairs of electrons (c) SO2 (d) NH3
respectively Correct answer is:-
(1) a and b (2) b and c

20
(3) Different, with 0,1 and 2 lone pairs of electrons
respectively (3) c and d (4) a and d
(4) Different, with 1,0 and 2 lone pairs of electrons
E 47. Which of the following molecule have zero dipole

-
respectively
moment:-

19
40. Which of the following two are isostructural :- (1) BF3 (2) CH2Cl2
- (3) NF3 (4) SO2
(1) XeF2, I F2 (2) NH3,BF3

(3) CO23- , SO23- (4) PCl5, ICl5

48. 20
The dipole moment of NH3 is:-
LL
(1) Less than dipole moment of NCl3
41. Select the correct matching : (2) Higher than dipole moment of NCl3
n
List I List II (3) Equal to the diple moment of NCl3
A : XeF4 1. Pyramidal (4) None of these
io

B : XeF6 2. T-shape
49. Which of the following order of polarities of
C : XeO3 3. Distorted octahedral
ss

molecules is correct:-
D : XeOF2 4. Square planar
A B C D (1) HF > NH3 > PH3
(2) CH4 > NH3 > H2O
Se

(1) 4 3 1 2
(2) 1 2 3 4 (3) CH3Cl < CH2Cl2 < CHCl3
A

(3) 2 1 3 4 (4) BF3 > BeF2 > F2

(4) 4 1 3 2
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50. Which set of molecules is polar :-

42. Which one of the following pair is a correct with (1) XeF4, IF7, SO3 (2) PCl5, C6H6, SF6
respect to molecular formula of xenon compound (3) SnCl2, SO2, NO2 (4) CO2, CS2, C2H6
and hybridization state of xenon in it :
(1) XeF4 ,sp3 (2) XeF2 ,sp 51. Which of the following has symmetrical structure :
(3) XeF2 ,sp3d (4) XeF4 ,sp2 (1) PCl3 (2) CH2Cl2
(3) CHCl3 (4) CCl4
43. The xenon compound(s) that are iso-structural with
IBr2- and BrO3- respectively are : 52. Species having zero dipole moment :-
(1) XeF4
(1) Linear XeF2 and pyramidal XeO3
(2) 1,2,4 trichloro benzene
(2) Bent XeF2 and pyramidal XeO3
(3) SF4
(3) Bent XeF2 and planar XeO3
(4) CH2Cl2
(4) Linear XeF2 and tetrahedral XeO3
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53. What conclusion can be drawn from the fact that 64. The no. of antibonding electron pair in O2– is
BF3 has no dipole moment but PF3 does (1) 4 (2) 3
(1) BF3 is not symmetrical but PF3 is (3) 8 (4) 10
(2) BF3 molecule must be linear
(3) Atomic radius of P is larger than that of B 65. Which of the following species will have the
(4) BF3 molecule must be planar triangular minimum bond energy
54. PCl5 is non polar because :- (1) N2 (2) N2–
(1) P – Cl bond is non-polar (3) N2+
(4) N2–2
(2) Its dipole moment is zero
(3) P – Cl bond is polar 66. Which of the following ion has not bond order of
(4) P & Cl have equal electronegativity 2.5 ?
(1) O2– (2) O2+
55. Dipole moment of CO2 is zero which implies that : (3) N2+
(4) N2–
(1) Carbon and oxygen have equal electronegativities
(2) Carbon has no polar bond 67. In a homonuclear molecule which of the following
(3) CO2 is a linear molecule set of orbitals are degenerate ?
(4) Carbon has bond moments of zero value (1) s2s and s1s (2) p2p and p2p
x y
56. The correct order of dipole moment is : (3) p2p and s2p (4) s2p and p*2p

N
x z z x
(1) CH4 < NF3 < NH3 < H2O
(2) NF3 < CH4 < NH3 < H2O COORDINATE BOND
(3) NH3 < NF3 < CH4 < H2O

20
(4) H2O < NH3 < NF3 < CH4 68. In Co-ordinate bond, the acceptor atoms must
essentially contain in its valency shell an orbital:-
57. Which of the following molecule does not possess (1) With paired electron
a permanent dipole moment :
E
-
(2) With single electron
(1) H2S (2) SO2 (3) SO32– (4) CS2

19
(3) With no electron
58. Which of the following has the highest value of (4) With three electron
dipole moment :
(1) HCl (2) HF (3) HI (4) HBr 69. 20
The bonds present in N2O5 are :–
(1) Only ionic
LL
MOLECULAR ORBITAL THEORY (2) Covalent & coordinate
(3) Only covalent
n
59. The ion that is isoelectronic with CO and having
same bond order is :- (4) Covalent & ionic
io

(1) CN– (2) O2+ (3) O2– (4) N2+

70. Dative bond is present in
ss

60. Which of the following is paramagnetic:- (1) SO3 (2) NH3

(1) O2– (2) CN– (3) CO (4) NO+ (3) K2CO3 (4) BF3
61. In the following which of the two are paramagnetic
Se

71. Which of the following has no coordinate bond ?

(a) N2 (b) CO (c) B2 (d) NO2 (1) PH3 (2) P2H6+2
A

Correct answer is :-
(3) P2H5Å (4) PH4+
(1) a and c (2) b and c
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(3) c and d (4) b and d 72. The compound containing co-ordinate bond is :
(1) H2SO4 (2) O3
62. The bond order of CO molecule on the basis of
(3) SO3 (4) All of these
molecular orbital theory is
(1) Zero (2) 2 (3) 3 (4) 1 WEAK FORCES

63. The energy of s2s ortbital is greater, than s1s* 73. In dry ice the bond present between two molecules
orbital because is
(1) s2s orbital is bigger than s1s* orbital (1) Ionic bond (2) Covalent bond
(2) s2s orbital is a bonding orbital where as s1s* is (3) Hydrogen bond (4) Vander Waal
an antibonding orbital
74. Intermolecular hydrogen bonds are not present in:-
(3) s2s orbital has a greater value of n than s1s*
(1) CH3CH2OH (2) CH3COOH
orbital (3) C2H5NH2 (4) CH3OCH3
(4) None
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75. In which of the following molecule, the shown 81. Strongest hydrogen bond is shown by :
hydrogen bond is not possible:- (1) Water (2) Ammonia
(3) Hydrogen fluoride (4) Hydrogen sulphide
H H
(1) N H N H 82. Density of ice is less than that of water because of
(1) presence hydrogen bonding
H H (2) crystal modification of ice
(3) open porous structure of ice due to hydrogen
OH bonding
O (4) different physical states of these
C H
83. NH3 has abnormally high boiling point because it
(2)
has :
(1) Alkaline nature
(2) Distorted shape
O H
(3) sp3 - Hybridisation
(4) Hydrogen bonding
(3)
84. Which of the following is soluble in water ?

N
O ¬N O (1) CS2 (2) C2H5OH
(3) CCl4 (4) CHCl3
Cl H

20
85. KF combines with HF to form KHF2. The com-
O
pound contains the species :
(4) Cl C C H
(1) K+, F— and H+ (2) K+, F— and HF
E O

-
(3) K and [HF2]
+ —
(4) [KHF]+ and F2

19
Cl H
86. Which of the following compounds show intramo-
lecular hydrogen bonding :
76. Correct order of volatility is:-
(1) HF > HCl > HBr > HI
20
(A) o - nitrophenol
(B) p - nitrophenol
LL
(2) HCl > HBr > HI > HF (C) phenol
(3) HI > HBr > HCl > HF (D) salicylaldehyde
n
(4) HBr < HCl < HI < HF (1) A & B (2) A & C
(3) A & D (4) B & C
io

77. The correct order of volatility is:-

(1) NH3 < H2O 87. The pair of molecules forming strongest hydrogen
ss

bonds are :
(2) p– nitro phenol < o– nitro phenol
(1) SiH4 and SiF4
(3) CH3OH > CH3 – O– CH3
Se

(4) HF > HCl (2) CH3—C—CH3 and CHCl3

A

O
78. The incorrect order of decreasing boiling points
is (3) H—C—OH and CH3—C—OH
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(1) NH3 > AsH3 > PH3 (2) H2O > H2Se > H2S O O
(3) Br2 > Cl2 > F2 (4) CH4 > GeH4 > SiH4 (4) H2O and H2

79. Acetic acid exists as dimer in benzene due to:- IONIC BOND
(1) Condensation reaction
88. Which one is the correct statement with reference
(2) Hydrogen bonding
to solubility of MgSO4 in water:
(3) Presence of carboxyl group
(1) Hydration energy of MgSO 4 is higher in
(4) None of the above
comparison to its lattice energy
80. Maximum no. of hydrogen bonds formed by a wa- (2) Ionic potential of Mg2+ is very low
ter molecule in ice is (3) SO42– ion mainly contributes towards hydration
(1) 4 (2) 3 energy
(3) 2 (4) 1 (4) Size of Mg2+ and SO42– are similar

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89. Conditions for ionic bond formation is/are : 99. The electronic configuration of metal M is 1s2 2s2
(a) Small cation, large anion 2p6 3s1. The formula of its oxide will be :
(b) Low IP of cation, high electron affinity of anion (1) MO (2) M2O
(c) Large cation, small anion and less charge (3) M2O3 (4) MO2
(d) Less lattice enrgy
Correct answer is: 100. Which of the following pairs will form the most
(1) a, d (2) b, c and d stable ionic bond ?
(3) b and c (4) a, b (1) Na and Cl (2) Mg and F
(3) Li and F (4) Na and F
90. Capacity of solvent to neutralise charge on ionic
compound is called:- 101. For two ionic solids, CaO and KI. Identify the wrong
(1) Solvation energy (2) Dielectric constant statement among the following :
(3) Dipole moment (4) Solubility (1) Lattice energy of CaO is much larger than that
of KI
91. The force responsible for dissolution of ionic
(2) KI is soluble in benzene
compound in water is –
(1) Dipole – dipole forces (3) CaO has higher melting point
(2) Ion – dipole force (4) KI has lower melting point
(3) Ion – ion force

N
102. Which of the following does not show electrical
(4) Hydrogen bond
conduction ?
92. Born Haber cycle is mainly used to determine (1) diamond
(2) graphite

20
(1) Lattice energy (2) Electron affinity
(3) Ionisation energy (4) Electronegativity (3) sodium chloride (fused)
(4) potassium
93. An ionic compound A+ B– is most likely to be
E
-
formed when – 103. The most covalent halide is:-

19
(1) Ionization energy of A is low (1) AlF3 (2) AlCl3
(2) Electron affinity of B is high (3) AlBr3 (4) AlI3
(3) Electron affinity of B is low
(4) Both (1) and (2)
20
104. Ionic potential (f) of electropositive element will be
LL
highest in which of the following compound:-
94. The pair of elements which on combination are (1) CsCl (2) MgCl2
most likely to form an ionic compound is (3) AlF3 (4) SF6
n
(1) Na and Ca (2) K and O
io

(3) O and Cl (4) Al and I 105. LiCl is soluble in organic solvent while NaCl is not
because :-
95. Choose the compound of each of the following
ss

(1) Lattice energy of NaCl is less than that of LiCl

pairs that has the more solubility in water :-
(2) Ionisation potential of Li is more than that of Na
(a) BeSO4, BaSO4 (b) NaCl, MgCl2
(3) Li+ has more hydration energy than Na+ ion
(c) AgCl, AgI
Se

(4) LiCl is more covalent compound than that NaCl

(1) BeSO4, MgCl2, AgI (2) BeSO4,NaCl, AgCl
A

(3) BaSO4, NaCl, AgCl (4) BaSO4, MgCl2, AgI 106. The most stable carbonate is
96. Highest melting point would be of (1) Li2CO3 (2) BeCO3
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(1) AlCl3 (2) LiCl (3) CaCO3 (4) BaCO3

(3) NaCl (4) BeCl2
107. Correct order of covalent character of alkaline earth
97. Which of the following substance will have metal chloride in
highest b.p.t. ? (1) BeCl2 < MgCl2 < CaCl2 < SrCl2
(1) He (2) CsF (2) BeCl2 < CaCl2 < SrCl2 < MgCl2
(3) NH3 (4) CHCl3 (3) BeCl2 > MgCl2 > CaCl2 > SrCl2
98. As compared to covalent compounds electrovalent (4) SrCl2 > BeCl2 > CaCl2 > Mg Cl2
compounds generally possess
108. Which of the compound is least soluble in water
(1) High m.p. and high b.p.
(2) Low m.p. and low b.p. (1) AgF (2) AgCl
(3) Low m.p. and high b.p. (3) AgBr (4) AgI
(4) high m.p. and low b.p.

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109. CCl4 is more covalent than LiCl because : 114. Which of the following does not give an oxide on
(1) There is more polarization of Cl in CCl4 heating –
(2) There is more polarization of Cl in LiCl
(1) MgCO3 (2) Li2CO3
(3) CCl4 has more weight
(3) ZnCO3 (4) K2CO3
(4) None of above

110. The M.P. of SnCl4 is less than that of SnCl2, the 115. Which decomposes on heating –
suitable reason for the observed fact is (1) NaOH (2) KOH
(1) There is more charge on Sn+4 (3) LiOH (4) RbOH
(2) The size of Sn+4 is small
(3) Ionic potential of Sn+4 is high 116. Which of the following forms metal oxide on heating
(4) The shape of SnCl4 is tetrahedral (1) Na2CO3 (2) Li2CO3
(3) K2SO4 (4) NaHCO3
111. The correct order of decreasing polarisable ions is:
(1) Cl—, Br—, I—, F— 117. Increasing order of stability of –
(2) F—, I—, Br—, Cl—
I. K2CO3 II.MgCO3 III Na2CO3
(3) F—, Cl—, Br—, I—
(1) I < II < III (2) II < III < I
(4) I—, Br—, Cl—, F—
(3) II < I < III (4) I < III < II

N
112. Ionic conductances of hydrated M+ ions are in the
order – 118. Which of the following carbonate will not
(1) Li+ (aq) > Na+ (aq) > K+ (aq) > Rb+ (aq) > Cs+ (aq) decompose on heating :-

20
(2) Li+ (aq) > Na+ (aq) < K+ (aq) < Rb+ (aq) < Cs+ (aq) (1) BaCO3 (2) ZnCO3
(3) Li+ (aq) > Na+ (aq) > K+ (aq) > Rb+ (aq) < Cs+ (aq) (3) Na2CO3 (4) Li2CO3
(4) Li+ (aq) < Na+ (aq) < K+ (aq) < Rb+ (aq) < Cs+ (aq)
E
-
119. The decomposition temperature is maximum for:-

19
113. Which of the following halides has the highest melt-
(1) BeCO3 (2) CaCO3
ing point –
(3) K2CO3 (4) Li2CO3
(1) NaCl (2) KCl
(3) NaBr (4) NaF
20
LL
n
io
ss

EXERCISE-I (Conceptual Questions) ANSWER KEY

Se
A

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 3 3 3 3 4 2 4 1 4 3 4 1 2 4
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Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 3 3 2 1 3 3 4 1 4 2 2 1 3 2 3
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 1 1 2 2 4 3 2 2 4 1 1 3 1 4 2
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 1 2 1 3 4 1 4 2 3 1 4 2 1 1
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. 3 3 3 2 4 1 2 3 2 1 1 4 4 4 3
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. 2 2 4 2 1 3 3 4 2 3 3 3 1 3 2
Que. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. 2 1 4 2 2 3 2 1 2 2 2 1 4 4 4
Que. 106 107 108 109 110 111 112 113 114 115 116 117 118 119
Ans. 4 3 4 1 3 4 4 4 4 3 2 2 3 3
E 99
Pre-Medical : Chemistry
ALLEN
EXERCISE-II (Previous Year Questions) AIPMT/NEET & AIIMS (2006-2018)

AIPMT-2006 8. The correct order of C–O bond length among CO,

1. The number of unpaired electron s in a CO-32 , CO2 is
paramagnetic diatomic molecule of an element with
(1) CO < CO-32 < CO2 (2) CO-32 < CO2 < CO
atomic number 16 is
(1) 1 (2) 2 (3) 3 (4) 4 (3) CO < CO2 < CO-32 (4) CO2 < CO < CO-32
2. Which of the following species has a linear shape:
9. In which of the following hydration energy is higher
(1) O3 (2) NO2-
than lattice energy
(3) SO2 (4) NO2+ (1) MgSO4 (2) CaSO4
(3) BaSO4 (4) SrSO4
3. Which of the following is not isostructural with SiCl4? 10. Which one of the following orders correctly
(1) NH +
(2) SCl4 represents the increasing acid strengths of the given
4
acids :
(3) SO24- (4) PO34- (1) HOClO3 < HOClO2 < HOClO < HOCl

N
(2) HOCl < HOClO < HOClO2 < HOClO3
4. The electronegativity difference between N and F (3) HOClO < HOCl < HOClO3 < HOClO2
is greater than that between N and H yet the dipole (4) HOClO2 < HOClO3 < HOClO < HOCl
mement of NH3 (1.5 D) is larger than that of NF3

20
AIPMT-2008
(0.2 D). This is because
(1) in NH3 the atomic dipole and bond dipole are 11. Four diatomic species are listed below in different
E sequences. Which of these presents the correct

-
in the opposite directions whereas in NF3 these
order of their increasing bond order :

19
are in the same direction
(2) in NH3 as well as in NF3 the atomic dipole and (1) C22- < He2+ < NO < O2-
bond dipole are in the same direction
(3) in NH3 the atomic dipole and bond dipole are
in the same direction whereas in NF3 these are
20
(2) He2+ < O2- < NO < C22-
LL
in opposite directions (3) O2- < NO < C22- < He2+
(4) in NH3 as well as NF3 the atomic dipole and
n
bond dipole are in opposite directions (4) NO < C22- < O2- < He2+
io

5. In which of the following molecules are all the bonds 12. The angular shape of ozone molecule (O3) consists of
not equal :-
ss

(1) 1 sigma and 1 pi bonds

(1) NF3 (2) ClF3 (2) 2 sigma and 1 pi bonds
(3) BF3 (4) AlF3 (3) 1 sigma and 2 pi bonds
Se

AIPMT-2007 (4) 2 sigma and 2 pi bonds

A

6. The correct order of increasing thermal stability of 13. The correct order of increasing bond angles in the
following triatomic species is:-
K2CO3 , MgCO3 CaCO3 and BeCO3 is
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(1) BeCO3 < MgCO3 < CaCO3 < K2CO3 (1) NO2+ < NO2 < NO2- (2) NO2+ < NO2- < NO2
(2) MgCO3 < BeCO3 <CaCO3 < K2CO3
(3) K2CO3 < MgCO3 < CaCO3 < BeCO3 (3) NO2- < NO2+ < NO2 (4) NO2- < NO2 < NO2+
(4) BeCO3 < MgCO3 < K2CO3 < CaCO3
7. In which of the following pairs the two species are AIPMT-2009
iso-structural
14. In which of the following molecules/ions BF 3,
(1) SO and NO NO2–, NH 2– and H 2O, the central atom is sp2
-2 -
3 3

(2) BF3 and NF3 hybridized :

(1) BF3 and NO2– (2) NO2– and NH2–
(3) BrO3- and XeO3 –
(3) NH2 and H2O (4) NO2– and H2O
(4) SF4 and XeF4

100 E
 Pre-Medical : Chemistry
ALLEN
15. According to MO theory which of the following lists 24. Property of the alkaline earth metals that increases
ranks the nitrogen species in terms of increasing with their atomic number :-
bond order : (1) Electronegativity
(1) N2– < N22– < N2 (2) N2– < N2 < N22– (2) Solubility of their hydroxides in water
2– –
(3) N2 < N2 < N2 (4) N2 < N22– < N2– (3) Solubility of their sulphates in water
(4) Ionization energy
16. In the case of alkali metals, the covalent character
AIPMT Pre-2011
decreases in the order :
(1) MI > MBr > MCl > MF 25. Considering the state of hybridization of carbon
(2) MCl > MI > MBr > MF atoms, find out the molecule among the following
(3) MF > MCl > MBr > MI which is linear :
(4) MF > MCl > MI > MBr (1) CH3–CH=CH–CH3
(2) CH3–CºC–CH3
17. What is the dominant intermolecular force or bond (3) CH2=CH–CH2–CºCH
that must be overcome in converting liquid CH3OH (4) CH3–CH2–CH2–CH3
to a gas :
(1) London or dispersion force 26. Which of the following has the minimum bond
(2) Hydrogen bonding length :
(3) Dipole-dipole interaction (1) O2+ (2) O2– (3) O2–
2
(4) O2

N
(4) Covalent bonds
AIPMT-2010 27. Which of the two ions from the list given below
th at have the geometry that is explained
18. Some of the properties of the two species, by the same hybridization o f orbitals,

20
NO3– and H3 O+ are described below. Which one NO2– , NO3– , NH2– , NH4+ , SCN – :
of them is correct :-
(1) Isostructural with same hybridization for the
E (1) NO2– and NO3– (2) NH+4 and NO3–

-
central atom. –

19
(3) SCN and NH2– (4) NO2– and NH2–
(2) Isostructural with different hybridization for the
central atom. 28. Which of the following compounds has the lowest
(3) Similar in hybridization for the central atom with melting point :
different structures. (1) CaCl2 20 (2) CaBr2
LL
(4) Dissimilar in hybridization for the central atom (3) CaI2 (4) CaF2
with different structures. 29. Which of the following structures is the most
n
19. In which of the following molecules the central atom preferred and hence of lowest energy for SO3 :
does not have sp3 hybridization :-
io

–
O O
(1) SF4 (2) BF4
(3) NH4
+
(4) CH4 (1) S (2) S
ss

O O O O
20. Which one of the following species does not exist
under normal conditions : O
..
Se

+
(1) Li2 (2) Be2 S S
(3) Be2 (4) B2 (3) O (4)
A

O O O
21. In which of the following pairs of molecules/ions, O
the central atoms have sp2 hybridization : AIIMS-2011
Z:\NODE02\B0AI-B0\TARGET\CHEM\ENG\MODULE-2\2-CHEMICAL BONDING\02-EXERCISE.P65

– –
(1) BF3 and NH2 (2) NO2 and NH3 30. In solid ice, oxygen atom is surrounded:
– –
(3) BF3 and NO2 (4) NH2 and H2O (1) Tetrahedrally by 4 hydrogen atoms
22. Which of the following alkaline earth metal (2) Octahedrally by 2 oxygen and 4 hydrogens
sulphates has hydration enthalpy higher than the atoms
lattice enthalpy : (3) Tetrahedrally 2 hydrogen and 2 oxygens atoms
(1) SrSO4 (2) CaSO4 (4) Octahedrally by 6 hydrogens atoms
(3) BeSO4 (4) BaSO4
31. Decreasing order of bond angle is :
23. In which one of the following species the central (1) BeCl2 > NO2 > SO2
atom has the type of hybridisation which is not the
(2) BeCl2 > SO2 > NO2
same as that present in the other three :
(1) PCl5 (2) SF4 (3) SO2 > BeCl2 > NO2
(3) I3– (4) SbCl52– (4) SO2 > NO2 > BeCl2

E 101
Pre-Medical : Chemistry
ALLEN
AIPMT Pre-2012 AIIMS-2013
32. Which one of the following pairs is isostructural (i.e. 44. Total no of Antibonding electrons present in O2 will
having the same shape and hybridization) : be :-
(1) [NF3 and BF3] (2) éë BF4- and NH4+ ùû (1) 6 (2) 8 (3) 4 (4) 2
AIPMT-2014
(3) [BCl3 and BrCl3] (4) [NH3 and NO-3 ]
45. Which of the following molecules has the maximum
33. Which of the following species contains three bond dipole moment :
pairs and one lone pair around the central atom: (1) CO2 (2) CH4 (3) NH3 (4) NF3
(1) NH2– (2) PCl3 (3) H2O (4) BF3
46. Which one of the following species has plane
34. The pair of species with the same bond order is: triangular shape :
(1) NO, CO (2) N2, O2 –
(3) O22–, B2 (4) O2+, NO+ (1) N3 (2) NO-3 (3) NO-2 (4) CO2

35. Bond order of 1.5 is show by: AIIMS-2014

(1) O22– (2) O2 (3) O2+ (4) O2–
47. Heat of sublimation of Na = x J

N
AIPMT Mains-2012
Ionization energy of Na= y J
–
36. During change of O2 to O2 ion, the electron adds Bond dissociation energy of Cl2 = a J
on which one of the following orbitals : e– gain enthalpy of Cl = – b J

20
(1) s* orbital (2) s orbital Enthalpy of formation of NaCl = – c J
(3) p* orbital (4) p orbital Then what will be lattice energy of NaCl(s)
E
-
37. Four diatomic species are listed below. Identify the æ aö

19
correct order in which the bond order is increasing (1) b + çè x + y + c – ÷ø
2
in them :
2– +
(1) C2 < He2 < O2 < NO
+ –
(2) He2 < O2 < NO < C2
–

2–
æ 20
(2) b – çè x + y + c – ÷ø
2
aö
LL
– 2– +
(3) NO < O2 < C2 < He2
– 2–
(4) O2 < NO < C2 < He2
+ æa ö
n
(3) b – çè + x + y + c÷ø
NEET-UG-2013 2
io

38. Which one of the following molecules contains no a

(4) c – x+ y+c
ss

p bond : 2
(1) NO2 (2) CO2 (3) H2O (4) SO2
AIPMT-2015
Se

39. XeF2 is isostructural with :-

48. The correct bond order in the following species is:-
A

(1) BaCl2 (2) TeF2 (3) ICl2– (4) SbCl3

(1) O2+ - +
2 < O2 < O2
(2) O+2 < O2- < O2+
2
40. Dipole induced dipole interactions are present in
Z:\NODE02\B0AI-B0\TARGET\CHEM\ENG\MODULE-2\2-CHEMICAL BONDING\02-EXERCISE.P65

which of the following pairs :- (3) O2- < O+2 < O2+
2
(4) O2+ + -
2 < O2 < O2
(1) SiF4 and He atoms (2) H2O and alcohol
49. Which of the following pairs of ions are isoelectronic
(3) Cl2 and CCl4 (4) HCl and He atoms
and isostructural :
41. Which of the following is a polar molecule : -
(1) ClO3– ,CO2–
3
(2) SO2-
3 , NO3
(1) XeF4 (2) BF3 (3) SF4 (4) SiF4
(3) ClO 3– ,SO2–
3
(4) CO23 - ,SO32 -
42. Which of the following is paramagnetic :
(1) NO+ (2) CO (3) O2– (4) CN– 50. Which of the following options represents the
correct bond order :
43. Identify the correct order of solubility in aqueous
medium : (1) O -2 < O2 < O +2 (2) O -2 > O2 < O2+
(1) Na2S > ZnS > CuS (2) CuS > ZnS > Na2S
(3) O -2 < O2 > O+2 (4) O -2 > O2 > O 2+
(3) ZnS > Na2S > CuS (4) Na2S < CuS > ZnS

102 E
 Pre-Medical : Chemistry
ALLEN
51. Solubility of the alkaline earth's metal sulphates in 59. In solid phase of XeF6, it consists of
water decreases in the sequence :- (1) XeF5+ + F– (2) XeF4 + F2
(1) Ca > Sr > Ba > Mg (2) Sr > Ca > Mg > Ba
(3) XeF5 + XeF2
+ –
(4) XeF2 + 2F2
(3) Ba > Mg > Sr > Ca (4) Mg > Ca > Sr > Ba
60. Correct order of bond length
52. Maximum bond angle at nitrogen is present in
which of the following : (1) CO » CO2–
3 > CO2

(1) NO -2 (2) NO +2 (2) CO2 » CO32– > CO

(3) NO3- (4) NO 2 (3) CO < CO2 < CO32–
RE-AIPMT-2015 (4) CO2–
3 < CO2 < CO
53. On heating which of the following releases CO2
most easily : 61. Correct order of bond energy
(1) MgCO3 (2) CaCO3 (1) I–Cl < I2
(3) K2CO3 (4) Na2CO3 (2) Br – F < F–F
54. Decreasing order of stability of O2, O2–, O2+ and (3) Br – F < I – I
O22– is :- (4) F–F < Cl–Cl

N
(1) O2 > O2+ > O22– > O2– NEET-I 2016
(2) O2– > O22– > O2+ > O2 62. Consider the molecules CH4, NH3 and H2O. Which
O2+ > O2 > O2– > O22– of the given statements is false ?

20
(3)
(4) O22– > O2– > O2 > O2+ (1) The H –C–H bond angle in CH4, the H–N–H
bond angle in NH3, and the H–O–H bond angle
55. In which of the following pairs, both the species
E
-
are not isostructural : in H2O are all greater than 90°

19
(1) NH3, PH3 (2) The H–O–H bond angle in H2O is larger than
(2) XeF4, XeO+4 the H–C–H bond angle in CH4.
(3) SiCl4, PCl4
(4) Diamond, silicon carbide
20
(3) The H–O–H bond angle in H2O is smaller than
LL
the H–N–H bond angle in NH3.
56. The variation of the boiling points of the hydrogen
halides is in the order HF > HI > HBr > HCl. (4) The H–C–H bond angle in CH4 is larger than
n
What explains the higher boiling point of hydrogen the H–N–H bond angle in NH3.
io

fluoride ?
(1) The bond energy of HF molecules is greater than 63. Which one of the following orders is correct for
in other hydrogen halides the bond dissociation enthalpy of halogen
ss

(2) The effect of nuclear shielding is much reduced molecules?

in fluorine which polarises the HF molecule
(1) I2 > Br2 > Cl2 > F2
Se

(3) The electronegativity of fluorine is much higher

than for other elements in the group. (2) Cl2 > Br2 > F2 > I2
A

(4) There is strong hydrogen bonding between HF (3) Br2 > I2 > F2 > Cl2
molecules
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(4) F2 > Cl2 > Br2 > I2

AIIMS-2015
57. SF4 & XeF2 shape respectively are 64. Predict the correct order among the following :-
(1) Linear and distorted tetrahedral (1) lone pair- lone pair > lone pair - bond pair
(2) See-saw and linear > bond pair - bond pair

(3) T-shape and trigonal bipyramidal (2) lone pair - lone pair > bond pair - bond pair
> lone pair - bond pair
(4) Tetrahedral and linear
(3) bond pair - bond pair > lone pair - bond pair
58. In ClF3 lone pair are present at approx > lone pair - lone pair
(1) 180° (2) 120° (4) lone pair - bond pair > bond pair - bond pair
(3) 90° (4) 60° > lone pair - lone pair

E 103
Pre-Medical : Chemistry
ALLEN
65. Match the compounds given in column I with the AIIMS 2016
hybridisation and shape given in column II and mark
71. Minimum lone pair on central atom will be present
the correct option.
in :-
Column-I Column-II (1) XeO3 (2) XeF4

(a) XeF6 (i) Distorted (3) ClF3 (4) HOCl

octahedral 72. Which of the following has paramagnetic character
(b) XeO3 (ii) Square planar in gaseous state :-
(1) S–2 (2) S2
(c) XeOF4 (iii) pyramidal
(3) S8 (4) S6
(d) XeF4 (iv) Square
pyramidal 73. In which of the following molecule dipole moment
is more than zero but less than one ?
Code :-
(1) NH3 (2) NF3
(a) (b) (c) (d)
(1) (i) (iii) (iv) (ii) (3) BeF2 (4) BF3

N
(2) (i) (ii) (iv) (iii) 74. Select the incorrect statement :-
(3) (iv) (iii) (i) (ii) (1) hybrid orbitals are maximum repelled to each

20
(4) (iv) (i) (ii) (iii) other
NEET-II 2016
(2) only half filled atomic orbital are participate in
66. The correct geometry and hybridization for XeF4
E hybridisation.

-
19
are: (3) Bond energy of hybrid orbitals are more than
(1) Planar triangle, sp3d3 unhybrid atomic orbital.
(2) square planar, sp3d2
(3) octahedral, sp3d2
20
(4) Without hybridisation, geometry of molecule is
uncertain.
LL
(4) trigonal bipyramidal, sp3d
75. Which of the following has tetrahedral structure :-
n
67. Among the following which one is a wrong (1) XeF4 (2) H3PO4
statement? (3) SF4 (4) ClF3
io

(1) SeF4 and CH4 have same shape

76. Which of the following molecule has more than one
ss

(2) I3+ has bent geometry

lone pair on central atom :-
(3) PH5 and BiCl5 do not exist
(1) SO2 (2) XeF2
(4) pp-dp bonds are present in SO2
Se

(3) PCl5 (4) IF7

A

68. The hybridizations of atomic orbitals of nitrogen

77. In ice crystal nearest and second nearest atoms to
in NO2+ , NO3- and NH+4 respectively are water molecule respectively are :-
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(1) sp, sp2 and sp3 (2) sp2, sp and sp3 (1) 4 & 4 (2) 4 & 6
(3) sp, sp3 and sp2 (4) sp2, sp3 and sp (3) 6 & 6 (4) 6 & 4
69. Which of the following fluoro-compounds is most 78. Which of the following statement is true regarding
likely to behave as a Lewis base ? H-bond :-
(1) CF4 (2) SiF4 (3) BF3 (4) PF3
(1) it is a directional bond
70. Which of the following pairs of ions is isoelectronic (2) bond strength is similar to O–H bond
and isostructural ?
(3) it is attract ion between hydrogen and
(1) SO , NO2-
3
-
3
(2) ClO , SO
-
3
2-
3 electronegative atom like as F, O, N
(4) it does not require minimum one lone pair of
(3) CO23- , NO3- (4) ClO3- , CO32-
electron at electronegative atom
104 E
 Pre-Medical : Chemistry
ALLEN
NEET(UG) 2017 86. Which of the following is diamagnetic ?
79. Ionic mobility of which of the following alkali metal (1) NO (2) Cl2+
ions is lowest when aqueous solution of their salts (3) S22–
(4) ClO
are put under an electric field ? 87. Number of lone pair in SO 2 on S & O are
(1) K (2) Rb (3) Li (4) Na respectively
80. Match the interhalogen compounds of column-I (1) 0, 6 (2) 2, 4
with the geometry in column II and assign the (3) 2, 5 (4) 1, 5
correct. code.
NEET(UG) 2018
Column-I Column-II 88. Among CaH2, BeH2, BaH2, the order of ionic
character is
(a) XX' (i) T-shape
(1) BeH2 < CaH2 < BaH2
(b) XX'3 (ii) Pentagonal (2) CaH2 < BeH2 < BaH2
bipyramidal (3) BeH2 < BaH2 < CaH2
(4) BaH2 < BeH2 < CaH2
(c) XX'5 (iii) Linear

N
89. Magnesium reacts with an element (X) to form an
(d) XX'7 (iv) Square-pyramidal ionic compound. If the ground state electronic
configuration of (X) is 1s2 2s2 2p3, the simplest
(v) Tetrahedral

20
formula for this compound is
Code : (1) Mg2X3 (2) MgX2 (3) Mg2X (4) Mg3X2
(a) (b) (c) (d) 90. Consider the following species:
E
-
(1) (iii) (i) (iv) (ii) CN+, CN–, NO and CN

19
(2) (v) (iv) (iii) (ii) Which one of these will have the highest bond
(3) (iv) (iii) (ii) (i) order?

81.
(4) (iii) (iv) (i) (ii)
Which of the following pairs of compounds is
(1) NO
(3) CN+
20 (2) CN–
LL
(4) CN
isoelectronic and isostructural ? 91. Which one of the following elements is unable to
n
(1) TeI2,XeF2 (2) IBr2–,XeF2 form MF63– ion ?
(1) Ga (2) AI
io

(3) IF3, XeF2 (4) BeCl2,XeF2

(3) B (4) In
82. The species, having bond angles of 120° is :-
ss

92. In the structure of ClF3, the number of lone pairs

(1) CIF3 (2) NCl3 (3) BCl3 (4) PH3 of electrons on central atom 'Cl' is
(1) one (2) two
Se

83. Which of the following pairs of species have the

same bond order ? (3) four (4) three
A

(1) O2, NO+ (2) CN–, CO AIIMS 2018

93. Which statement is correct regarding N2O5 :-
Z:\NODE02\B0AI-B0\TARGET\CHEM\ENG\MODULE-2\2-CHEMICAL BONDING\02-EXERCISE.P65

(3) N2 , O2- (4) CO, NO (1) It is anhydride of nitrous acid

(2) It is brown color gas
AIIMS 2017
(3) It is paramagnetic
84. Which of the following has longest bond length (4) It exist as NO2+ & NO3– in solid state
94. In s-p overlapping wrong statement is :-
(1) C = O (2) N = O
(1) Nodal plane formed in ABMO
(3) C = C (4) C º N
(2) Some orbital may have higher energy than
85. Which of the following has hydrogen bonded water combining orbitals
(1) BaCl2.2H2O (2) CrCl3.5H2O (3) Combining orbitals should have same symmetry
(3) CuSO4.5H2O (4) CaCl2.6H2O (4) Nodal plane is found in BMO

E 105
Pre-Medical : Chemistry
ALLEN
95. Which pair not shows same shape :- 100. Wrong statement for N3 is :- –

(1) I , BeCl2
3
–1
(2) BF3, ClO 3
–1
(1) Isoelectronic with CO2
(3) SO2, H2O (4) XeF4, BrF4– (2) Structure is linear
96. In which at least one s–bond of np (snp) orbital is (3) Both N–N bond lengths are unequal in hydrogen
present :- azide
(1) B2 (2) O2 (4) Oxidation state for Nitrogen is same as in
(3) C2 (4) Li2 NH2OH

97. Which is correct for dipole moment :- 101. Bond order of which of following pair is different:-

(1) NH3 < NF3 (2) SO2 < SO3 (1) F2– & O2–2 (2) N2– & O2+

(3) NF3 > BF3 (4) SO2 > H2O (3) C2 & B2–2 (4) N2 & O22+
98. Which of the following is a molecular solid :- 102. Correct order for Bond angle is
(1) solid SO2 (2) SiC (1) SO2 > NH3 (2) NH3 < H2O
(3) C. (graphite) (4) ZnS (3) SO2 < H2O (4) H2S > NH3

N
99. The geometry and No. of lone pair on ClF2 and –
103. Which of the following two species have same
ClF4– are respectively :- shape but different hybridisation

20
(1) Square planar, 2 & Linear, 3 (1) XeF2 and ICl2– (2) NO2+ and SO2
(2) Square Planar, 3 & Linear, 2 (3) BeCl2 and NO2+ (4) SO2 and NH2–
E
(3) Linear, 3 & Square planar, 2 104. Which of the following has maximum %s character

-
19
(4) Tetrahedral, 2 & linear, 3 in N–H bond ?
(1) N2H2 (2) NH4+ (3) NH3 (4) N2H4

20
LL
n
io
ss
Se

EXERCISE-II (Previous Year Questions) ANSWER KEY

A

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
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Ans. 2 4 2 3 2 1 3 3 1 2 2 2 4 1 3
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 1 2 4 1 3 3 3 4 2 2 1 1 3 1 1
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 1 2 2 3 4 3 2 3 3 4 3 3 1 1 3
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 2 3 3 3 1 4 2 1 3 2 4 2 2 1 3
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. 4 2 2 1 1 2 1 1 4 2,3 1 2 2 2 2
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. 2 2 3 3 1 2 3 2 3 3 3 4 1 4 2
Que. 91 92 93 94 95 96 97 98 99 100 101 102 103 104
Ans. 3 2 4 4 2 2 3 1 3 4 1 1 4 1

106 E
 Pre-Medical : Chemistry
ALLEN
EXERCISE-III (Analytical Questions) Check Your Understanding
1. The thermal stability of alkaline earth metal 8. In silicon dioxide –
carbonates MgCO3, CaCO3, BaCO3 and SrCO3 (1) each silicon atom is surrounded by four oxygen
decreases as : atoms and each oxygen atom is bonded to two
(1) CaCO3 > SrCO3 > MgCO3 > BrCO3 silicon atoms
(2) BaCO3 > SrCO3 > MgCO3 > CaCO3 (2) each silicon atom is surrounded by two oxygen
(3) BaCO3 > SrCO3 > CaCO3 > MgCO3 atoms and each oxygen atom is bonded to two
(4) MgCO3 > CaCO3 > SrCO3 > BaCO3 silicon atoms
2. Which of the following are iosoelectronic and (3) silicon atom is bonded to two oxygen atoms
isostructural NO3–, CO3–2, ClO3–, SO3 (4) there are double bond between silicon and
(1) NO3–, CO3–2 (2) SO3, NO3– oxygen atoms
(3) ClO3 , CO3
– –2
(4) CO3–2, SO3 9. The number and type of bond between two carbon
3. According to molecular orbital theory which of the atom in calcium carbide are :
following statement about the magnetic character (1) One sigma, one pi
and bond order is correct regarding O2+ ? (2) One sigma, two pi
(1) paramagnetic and bond order < O2 (3) Two sigma, one pi

N
(2) paramagnetic and bond order > O2 (4) Two sigma, two pi
(3) diamagnetic and bond order < O2
(4) diamagntic and bond order > O2 10. What is the hybridization of oxygen atom in an
alcohol molecule?

20
4. The bond order in NO is 2.5 while that in NO+ (1) sp3 (2) sp (3) sp2 (4) sp3d
is 3. Which of the following statements is true for
these two species ? 11. The decreasing values of bond angles from NH3
E (106°) to SbH3 (91°) down group-15 of the periodic

-
(1) Bond length in NO+ is equal to that in NO

19
(2) Bond length in NO is greater than in NO+ table is due to
(3) Bond length in NO+ is greater than in NO (1) decreasing lp – bp repulsion
(4) Bond length is unpredictable (2) increasing electronegativity
(3) increasing bp – bp repulsion
5. Number of s and p bond in SO4-2 are %&
20
(4) increasing p-orbital character in sp3
LL
(1) 4, 2 (2) 4, 3 12. In which of the following ionisation processes, the
(3) 4, 4 (4) 2, 3 bond order has increased and the magnetic
n
behaviour has changed
io

6. The paramagnetic property of the oxygen molecule

(1) NO ® NO+ (2) O2 ® O2+
is due to the presence of unpaired electrons present
in :-
ss

(3) N2® N2+ (4) C2 ® C2+

(1) (s2px)1 and (s*2px)1
13. Which of the following hydrogen bonds is the
(2) (s2px)1 and (p2py)1
Se

strongest
(3) (p*2py)1 and (p*2px)1 (1) F–H.....F (2) O–H.....O
A

(4) (p*2py)1 and (p2py)1 (3) O–H.....F (4) O–H.....N

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14. Which of the following species exhibits the

7. The boiling point of methanol is greater than that of diamagnetic behaviour
methylthiol because :-
(1) There is intramolecular hydrogen bonding in (1) O2+ (2) O2 (3) NO (4) O22 -
methanol and intermolecular hydrogen bonding
in methyl thiol 15. The charge/size ratio of a cation determines its
(2) There is intermolecular hydrogen bonding in polarizing power. Which one of the following
methanol and no hydrogen bonding in sequences represents the increasing order of the
methylthiol polarizing power of the cationic species, K+, Ca+2,
(3) There is no hydrogen bonding in methanol and Mg+2, Be+2
intermolecular hydrogen bonding in methylthiol (1) Be+2 < K+ < Ca+2 < Mg+2
(4) There is intramolecular hydrogen bonding in (2) K+ <Ca+2 < Mg+2 < Be+2
methanol and no hydrogen bonding in (3) Ca+2 < Mg+2 < Be+2 < K+
methylthiol (4) Mg+2 < Be+2 <K+ <Ca+2

E 107
Pre-Medical : Chemistry
ALLEN
16. Which one of the following constitutes a group of 23. The boiling point of ICl is nearly 40°C higher than
the isoelectronic species ? that of Br2 although the two substances have the
same relative molecular mass. This is bacasue :-
(1) C22 - ,O2- ,CO,NO
(1) ICl is ionic compound
(2) NO+ ,C22 - ,CN - ,N2 (2) I-Cl bond is stronger than Br - Br bond
(3) ICl is polar covalent molecule while Br2 is non
(3) CN - ,N2 ,O22 - ,C22 - polar
(4) IP of Iodine is less than that of Br.
(4) N2 ,O2- ,NO+ ,CO
24. Nitrogen does not form NF5 because
17. Which of the following pairs of species have the (1) Nitrogen is member of V group
same bond order ? (2) It contains no empty d-orbital
(1) CN- and NO + (2) CN- and CN+ (3) The bond energy of N N is very high
(4) Inert pair effect exists in the molecule
(3) O2- and CN- (4) NO + and CN+
25. CO2 is a gas, while SiO2 is a solid but both are-
18. Among the following, the molecule with highest (1) Covalent containing p–bond
dipole moment is :- (2) Molecules having pp – dp bonding

N
(1) CH3Cl (2) CH2Cl2 (3) Acidic
(3) CHCl3 (4) CCl4 (4) Discrete molecules

20
19. For a diatomic molecule the dipole moment is 1.2D 26. Which trihalide ion is unknown due to absence of
and bond length is 1.0 Å then charge fraction on vacant d-orbital?
each atom is :-
E (1) F3– (2) Br3– (3) I3– (4) Cl3–

-
(1) 12% (2) 18%

19
27. Dipole moment is shown by
(3) 25% (4) 29% (1) 1, 4 - dichlorobenzene
20. Which one of the following molecules is expected (2) Cis 1, 2-dichloro ethene
to exhibit diamagnetic behaviour ?
(4) benzene
20
(3) Trans-1, 2– dichloro ethene
LL
–
(1) C2 (2) N2
(3) O2 (4) S2 28. Experiment shows that H2O has a dipole moment
n
21. For which of the following molecule significant where as CO2 has not. Point out the structures
which best illustrate these facts –
io

µ ¹ 0
(1) O C O, H—O—H
ss

Cl CN (2) C , H—O— H
O O
Se

(a) (b) (3) O C O, O

H
A

Cl CN H
O H
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OH SH (4) C O , H
O

29. In which of the species, bond order increases on

(c) (d)
removing one electron:-
–
OH SH (a) NO (b) CN (c) O2 (d) CO
Correct answer is -
(1) Only (c) (2) (c) and (d)
(1) b and d (2) a and c
(3) Only (a) (4) (a) and (b)
(3) b, d and c (4) b and c
22. Which one of the following order is correct for the
30. Increasing order of bond length in NO, NO + and
bond energies of halogen molecules :
NO– is :-
(1) I2 > Cl2 > Br2 (2) Br2 > Cl2 > I2
(1) NO > NO– > NO+ (2) NO+ < NO < NO–
(3) I2 > Br2 > Cl2 (4) Cl2 > Br2 > I2
(3) NO < NO < NO
+ –
(4) NO < NO+ = NO–
108 E
 Pre-Medical : Chemistry
ALLEN
31. N2 and O2 are converted into monoanions, N2– and 40. Which is most ionic :
O2– respectively. Which of the following statements (1) P2O5 (2) MnO
is wrong ? (3) CrO3 (4) Mn2O7
(1) In N2-– , N-N bond weakens
(2) In O2–-, O-O bond order increases 41. Lithium chloride is highly soluble in –
(3) In O2–, O-O bond order decreases (1) C6H6 (2) H2O
(4) N2– becomes pagamegnetic (3) D2O (4) All
32. N2 and O2 are converted into monocations, N2+ 42. Which of the following linear combinations of
and O2+ respectively. Which of the following is atomic orbitals is incorrectly depicted ?
wrong ?
(1) ®
(1) In N2+, N-N bond weakens
(2) In O2+, the O-O bond order increases (2) ®
(3) In O2+, paramagnetism decreases
(4) N2+ becomes diamagnetic (3) ®

33. The pair of compounds which can form a

co–ordinate bond is :-

N
(1) (C2H5)3B and (CH3)3N
(4) ¾¾
®
(2) HCl and HBr
(3) BF3 and NH3

20
(4) (1) & (3) both

34. In the neutralization process of NH3 and AlCl3 the

E
-
compound formed will have the bonding 43. Which of the following molecule contains net p-

19
bond only
(1) Ionic (2) Covalent
(3) Coordinate (4) Hydrogen (1) B2 (2) C2
(3) C2–2 (4) Both 1 & 2
35. Glycerol is more viscous than glycol the reason is :- 20
LL
(1) Higher molecular wt. 44. Pick out the incorrect statement :-
(2) More covalent
(1) sp3d hybridisation involves d x 2 - y 2 orbital
n
(3) More extent of hydrogen bonding
(4) Complex structure
io

(2) Hybridised orbital form s-bond when overlaps

36. Incorrect order of viscosity :- with other orbitals.
ss

(1) H2SO4 > HNO3 (3) SF2 molecule is more polar than CS2
(2) H2O > CH3OH
(4) o-nitrophenol is more volatile than p-
(3) o-nitro phenol > p-nitro phenol
Se

(4) Glycol > ether nitrophenol.

A

37. Which of the following can form H-Bond with water 45. The group of substances in which at melting point
covalent bond becomes weak :-
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(1) HCN (2) NH4F

(3) NaHCO3 (4) All (1) NaCl, KCl, CaCl2
(2) I2(S), CH4(S), dry ice
38. Which of the following does not form a hydrogen
bond with water (3) B4C, dimond, SiC
(1) (CH3)2CO (2) CH3CN (4) All of the above
(3) CH3OH (4) C2H6
46. The incorrect statement is :-
39. A metal M readily forms its sulphate MSO 4, which (1) p* p have two nodal planes
is water soluble. It forms an insoluble hydroxide (2) Bond order of HeH+ is 0.5
M(OH)2 which is soluble in NaOH solution, then
(3) In NCO– , C is sp hybridised
M is :-
(4) O3 is polar while O2 is non polar
(1) Mg (2) Ca (3) Be (4) Ba

E 109
Pre-Medical : Chemistry
ALLEN
47. Solid CH4 is 52. Match the column :-
(1) Molecular solid
(A) NO3– + HCl (p) Kessome attraction
(2) Ionic solid
(3) Covalent solid (B) Xe + H2O (q) Debye attraction
(4) None of these
(C) CH3–C–CH3+CH3–CºN (r) London force
48. Which compound has the weakest bond O
(1) Diamond (D) CO2 + CS2 (s) Ion-dipole attraction
(2) Neon(solid)
(1) A-s, B-q, C-p, D-r (2) A-q, B-s, C-p, D-r
(3) KCl
(4) water (ice) (3) A-s, B-p, C-q, D-r (4) A-s, B-q, C-r, D-p
49. Which of the following order is incorrect ? 53. Correct order is :-
(1) Na2O < K2O < Rb2O (basic nature) (1) MgO < NiO < K2O < Cs2O (basic strength)
(2) CH4 > SiH4 > GeH4 > SnH4 (Stability of hydride) (2) Cs+ < K+ < Mg2+ < Be2+ (ionic mobility in aqueous
(3) NH3 < PH3 < AsH3 (basic nature) solution)
(4) N2O5 > P2O5 > As2O5 (acidic nature)

N
(3) Li2CO3 < Na2CO3 < K2CO3 (solubility order)
50. Which order are correct ? (4) NH3 < PH3 < AsH3 (thermal stability)
(a) Thermal stability : BeSO4 < MgSO4 < CaSO4 54. Which of the following statement is not correct ?

20
< SrSO4 < BaSO4
(1) NO has one unpaired electron in ABMO.
(b) Basic Nature : ZnO > BeO > MgO > CaO
E (2) N–H bond length is higher in N2H4 as compared

-
(c) Solubility in water : LiOH > NaOH > KOH to N2H2

19
> RbOH > CsOH (3) Both PF5 and IF5 have identical shape
(d) Melting point : NaCl > KCl > RbCl > CsCl > LiCl
(4) Both SO2 and BrF3 are polar and planar
(1) a, b, d (2) b, c
55.
20
In which of the following process, hybridisation of
LL
(3) a, d (4) All correct central atom remains same ?
51. Which of the following order is not correct ?
n
(1) Solidification of PCl5
(1) SF2 > SF4 > SF6 (ionic character)
io

(2) Dimerisation of NO2

(2) AlF3 < Al2O3 < AIN (covalent character)
(3) Trimerisation of SO3
ss

(3) CaCl2 < SnCl2 < CdCl2 (covalent character)

(4) BF3 forms adduct with lewis base
(4) ZnCl2 < CdCl2 < HgCl2 (ionic character)
Se
A

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EXERCISE-III (Analytical Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 1 2 2 1 3 2 1 2 1 4 1 1 4 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 2 1 1 3 1 2 4 3 2 3 1 2 3 2 2
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 2 4 4 3 3 3 4 4 3 2 1 4 4 1 3
Que. 46 47 48 49 50 51 52 53 54 55
Ans. 2 1 2 3 3 4 1 3 3 2
110 E
 Pre-Medical : Chemistry
ALLEN
EXERCISE-IV (Assertion & Reason) Target AIIMS
Directions for Assertion & Reason questions
These questions consist of two statements each, printed as Assertion and Reason. While answering
these Questions you are required to choose any one of the following four responses.
(A) If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(B) If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
(C) If Assertion is True but the Reason is False.
(D) If both Assertion & Reason are false.
1. Assertion : Ionic bonds are formed between 10. Assertion : In MgO electrovalency of Mg is 2.
metal and nonmetals Reason : Mg shares two electrons with
Reason : In ionic bonds electrons are shared oxygen.
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D
2. Assertion : D2O is better solvent for ionic 11. Assertion : Ionic reactions are faster than

N
compounds, than H2O. molecular reactions.
Reason : dielectric constant of D2O is higher Reason : Ionic bonds are weaker than
than H2O. covalent bonds.
(1) A (2) B (3) C (4) D

20
(1) A (2) B (3) C (4) D
3. Assertion : Hydrated ionic radius of Li+ is 12. Assertion : LiI is more soluble in water than LiF.
maximum in IA group elements.
E Reason : LiI has more ionic character.

-
Reason : Lithium is a metal
(1) A (2) B (3) C (4) D

19
(1) A (2) B (3) C (4) D
13. Assertion : Bond energy of H–H bond is
4. Assertion : LiCl exhibits covalent character.
greater than Cl–Cl bond.
Reason : Lithium is lightest metal.
(1) A (2) B (3) C (4) D
Reason
(1) A
20
: H2 is more covalent than Cl2.
(2) B (3) C (4) D
LL
5. Assertion : K2CO3 do not gives CO2 gas on
heating. 14. Assertion : Ionic compounds tend to be non–
n
volalite.
Reason : Value of f for K+ is high. Reason : Inter ionic forces in these com-
io

(1) A (2) B (3) C (4) D pounds are strong.

(1) A (2) B (3) C (4) D
ss

6. Assertion : CO2 molecule is non–polar while

SO2 is polar. 15. Assertion : NCl3 has pyramidal shape
Reason : Carbon atom is smaller than Reason : In NCl3 central atom is sp3 hybrid-
Se

sulphur. ised.
A

(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D

7. Assertion : CH3OH is soluble in water 16. Assertion : BF3 is planar while NF3 is non–
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Reason : CH3OH is ionic in nature planar molecule.

(1) A (2) B (3) C (4) D Reason : B–F bond is more polar than
8. Assertion : Boiling point of H2O is greater than N–F bond.
C2H5OH. (1) A (2) B (3) C (4) D
Reason : Molecular wt. of H2O is higher than 17. Assertion : Density of ice is greater than water
C2H5OH. Reason : In ice H2O molecules are closely
(1) A (2) B (3) C (4) D packed.
9. Assertion : NO+ is more stable than NO–. (1) A (2) B (3) C (4) D
Reason : NO + do not have electron in 18. Assertion : Bond order of O2 and BN is same.
antibonding orbitals. Reason : O2 and BN are isoelectronic
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D

E 111
Pre-Medical : Chemistry
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19. Assertion : p–nitrophenol is more viscous than 30. Assertion : NaCl is soluble in non polar solvents.
o-nitrophenol. Reason : NaCl is a non-polar covalent
Reason : In p-nitrophenol, intermolecular compound.
H-bonding occurs. (1) A (2) B (3) C (4) D
(1) A (2) B (3) C (4) D
31. Assertion : Sigma bonds are stronger than
20. Assertion : H2O2 is not used as solvent for ionic
p bonds.
compounds
Reason : Sigma bonds are covalent bonds.
Reason : Dielectric constant of H2O2 is low
(1) A (2) B (3) C (4) D
(1) A (2) B (3) C (4) D
32. Assertion : CO2 is non polar while SO2 is polar
21. Assertion : Ionic compounds exhibits electrical
conductivity in solution state. molecule.
Reason : In solution state electrons of ionic Reason : S-O bonds are polar while C-O non
compounds are free. polar.
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D

22. Assertion : p–nitrophenol is more volatile than 33. Assertion : Both H 2O and SnCl 2 are bent

N
o–nitrophenol. molecules.
Reason : Molecular wt. of p–nitrophenol is Reason : Both H 2O and SnCl 2 are sp 2
higher than o–nitrophenol. hybridised.

20
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D
+ – 34. Assertion : NO is paramagnetic in nature.
23. Assertion : N2 is more stable than N2
E
-
Reason : N2
+
has less elect rons in Reason : Bond order of NO is 2.5.

19
antibonding orbitals. (1) A (2) B (3) C (4) D
(1) A (2) B (3) C (4) D 35. Assertion : Nitrogen is unreactive at room
24. Assertion : SO4–2 is square planar in shape
Reason : SO4–2 has sp3d hybridisation
20
temperature but becomes reactive at elevated
temperature (on heating or in the presence of
LL
(1) A (2) B (3) C (4) D catalysts).
Reason : In nitrogen molecule, there is
n
25. Assertion : NF3 molecule is more polar than
extensive delocalization of electrons.
NH3 molecule.
io

(1) A (2) B (3) C (4) D

Reason : NF 3 is pyramidal while NH 3 is
trigonal planar. 36. Assertion : NO3– is planar.
ss

(1) A (2) B (3) C (4) D Reason : N in NO3– is sp2 and no lone pair
26. Assertion : OF4 does not exists. at central atom.
Se

Reason : Empty d–orbitals are absent in (1) A (2) B (3) C (4) D

A

valence shell of oxygen. 37. Assertion : The electronic structure of O 3

(1) A (2) B (3) C (4) D
Z:\NODE02\B0AI-B0\TARGET\CHEM\ENG\MODULE-2\2-CHEMICAL BONDING\02-EXERCISE.P65

+
O
27. Asertion : BeCl2 shows covalent character.
is O O–
Reason : More polarization of Cl– by Be+2.
..
(1) A (2) B (3) C (4) D O
Reason : O O Structure is not allowed
28. Assertion : MgO and NaF are isomorphous
Reason : Crystal structure of MgO and NaF because octet around 'O' can not be expanded.
is identical. (1) A (2) B (3) C (4) D
(1) A (2) B (3) C (4) D 38. Assertion : LiCl is predominantly a covalent
compound.
29. Assertion : NF3 molecule is polar.
Reason : Electonegativity difference between
Reason : N–F bonds are polar. 'Li' and 'Cl' is too small.
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D

112 E
 Pre-Medical : Chemistry
ALLEN
39. Assertion :– Ozone is a powerful oxidizing agent 44. Assertion :- ClF3 has T-shape structure.
in comparison to O2. Reason :- It has two lone pair arrange at 180°
Reason :– Ozone is diamagnetic but O 2 is (Angle).
paramagnetic. (1) A (2) B (3) C (4) D
(1) A (2) B (3) C (4) D
45. Assertion :- Bond Dissociation energy is
40. Assertion :– B2 molecule is diamagnetic. F2 > Cl2.
Reason :– The highest occupied molecular orbital Reason :- Cl2 have more electronic repulsion
is of s type. than F 2.
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D

41.
–
Assertion :– BH4 is known while BH 6-3 is not. 46. Assertion :- H 2 O molecule can form four
hydrogen bonds.
Reason :– B has very small atomic size.
(1) A (2) B (3) C (4) D Reason :- Two lone pairs and two hydrogens are
directly attached with oxygen atoms.
42. Assertion :– Some molecules are polar.
Reason :– The centre of negative charge and (1) A (2) B (3) C (4) D
positive charge do not coincide each other in some

N
molecule.
47. Assertion :- Bond angle in O is more than
(1) A (2) B (3) C (4) D R R
43. Assertion :- R3P = O exists but R3N = O does expected.

20
not exists Reason :- It is due to lp-lp repulsion.
Reason :- P is more electronegative than N
(1) A (2) B (3) C (4) D
(1) A (2) B (3) C (4) D
E
-
19
20
LL
n
io
ss
Se
A
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EXERCISE-IV (Assertion & Reason) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 4 2 2 3 2 3 3 3 3 3 3 3 1 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 2 4 3 1 3 3 4 1 4 4 1 1 1 2 4
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 2 3 3 2 3 1 1 3 2 4 2 1 3 3 4
Que. 46 47
Ans. 1 3
E 113
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Pre-Medical : Chemistry

A
Se
LL
IMPORTANT NOTES

ss
Eio
n
20 N
19
-
ALLEN

20
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