Scribd
Upload
25 views2 pages

DPP 3 Chemical Bonding

Uploaded by

uddeshranaprsnl766s
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
25 views2 pages

DPP 3 Chemical Bonding

Uploaded by

uddeshranaprsnl766s
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

Date of Discussion: 18-March 2021

Marks: 88 Time: 20 min DPP No:3


Batch: Spark & Legend Chemical Bonding Topic: Hybridization

1. In TeCl4 , the central atom tellurium involves


a) 𝑠𝑝3 hybridisation b) 𝑠𝑝 3 𝑑 hybridization c) 𝑠𝑝3 𝑑2 hybridisation d) 𝑑𝑠𝑝2 hybridisation
−
2. +
Some of the properties of the two species, NO3 and H3 O are described below. Which one of them is
correct?
a) Dissimilar in hybridization for the central atom with different structure
b) Isostructural with same hybridization for the central atom
c) Isostructural with different hybridization for the central atom
d) Similar is hybridization for the central atom with different structure

3. The bond length between C – C bond in 𝑠𝑝2 hybridised molecule is


a) 1.2 Å b) 1.39 Å c) 1.33 Å d) 1.54 Å
4. In which of the following compound 𝑠𝑝2 hybridisation is absent?
a) CH2 = CH − CH = CH2 b) CH ≡ C − CH2 − CH3
c) CH2 − CH = CH2 d) CH2 = CH − CH2 − CH3
5. 3
In which molecule Sulphur atom is not 𝑠𝑝 -hybridized?
a) SO2−
4 b) SF4 c) SF2 d) None of these

6. In which one of the following species, the central atom has the type of hybridization which is not the same
as that present in other three?
a) SF4 b) I3− c) SbCl2−
5 d) PCl5

7. The d – orbital involved in 𝑠𝑝3 d – hybridisation is


a) 𝑑𝑥 2−𝑦2 b) 𝑑𝑥𝑦 c) 𝑑𝑧 2 d) 𝑑𝑧𝑥

8. PCl5 exists but NCl5 does not because:


a) Nitrogen has no vacant 2𝑑-orbitals
b) NCl5 is unstable
c) Nitrogen atom is much smaller than phosphorus
d) Nitrogen is highly mert

9. In which of the following pairs the two species are not isostructural?
a) PCl+
4 and SiCl4 b) PF5 and BrF5 c) AlF63− and SF6 d) CO2− −
3 and NO3

10. A covalent molecule 𝐴𝐵3 has pyramidal structure. The number of lone pair and bond pair of electrons in
the molecule are respectively.
a) 2 and 2 b) 0 and 4 c) 3 and 1 d) 1 and 3

11. Be in BeCl2 undergoes


a) Diagonal hybridisation b) Trigonalhybridisation
c) Tetrahedral hybridisation d) No hybridisation

12. Which statement is wrong?


a) Hybridisation is the mixing of atomic orbitals prior to their combining into molecular orbitals
b) 𝑠𝑝2 -hybrid orbitals are formed from two 𝑝-atomic orbitals and one 𝑠-atomic orbitals
c) 𝑑𝑠𝑝 2-hybrid orbitals are all at 90 to one another
d) 𝑑2 𝑠𝑝2 -hybrid orbitals are directed towards the corners of a regular tetrahedron

Chemistry for IIT JEE Main & Advance MAHaqueSir @ Telegram


13. In the anion HCOO− the two carbon-oxygen bonds are found to be of equal length. What is the reason for
it?
a) Electronic orbits of carbon atom are hybridised
b) The C=O bond is weaker than the C − O bond
c) The anion HCOO− has two resonating structures
d) The anion is obtained by removal of a proton from the acid molecule

14. Which of the following molecules has three fold axis of symmetry?
a) NH3 b) C2 H4 c) CO2 d) SO2

15. As a result of resonance:


a) Bond length decreases
b) Energy of the molecules decreases
c) Stability of the molecule increases
d) All are correct

16. The molecule which has T – shaped structure is


a) PCl3 b) ClF3 c) NH3 d) BCl3

17. Which of the following molecules has pentagonal bipyramidal shape?


a) PF5 b) SF6 I c) XeF6 d) [Fe(CN)6 ]3−

18. If a molecule 𝑀𝑋3 has zero dipole moment the sigma bonding orbitals used by 𝑀 (at. No. < 21) is:
a) Pure𝑝 b) 𝑠𝑝-hybrid c) 𝑠𝑝2 -hybrid d) 𝑠𝑝3 -hybrid

19. The shape of XeF4 molecule and hybridisation of xenon in it are


a) Tetrahedral and 𝑠𝑝3 b) Square planar and 𝑑𝑠𝑝2
c) Square planar and 𝑠𝑝3 𝑑2 d) Octahedral and 𝑠𝑝3 𝑑2

20. How many bonds are there in?

a) 14 σ, 8π b) 18 σ, 8π c) 19 σ, 4π d) 14 σ, 2π

21. Among the following statement, the correct statement about PH3 and NH3 is:
NH3 is a better electron donor because the lone pair of electron occupies spherical 𝑠-orbital and is less
a)
directional
PH is a better electron donor because the lone pair of electron occupies 𝑠𝑝3 -orbital and is more
b) 3
directional
NH3 is a better electron donor because the lone pair of electron occupies 𝑠𝑝3 -orbital and more
c)
directional
PH is a better electron donor because the lone pair of electron occupies spherical 𝑠-orbital and is less
d) 3
directional

22. Identify the wrong statement in the following:


a) Atomic radius of the elements increases as one moves down the first group of the periodic table
b) Atomic radius of the elements decreases as one moves across from left to right in the 2nd period of the
periodic table
c) Amongst isoelectronic species, smaller the positive charge on the cation, smaller is the ionic radius
d) Amongst isoelectronic species, greater the negative charge on the anion, larger is the ionic radius

Chemistry for IIT JEE Main & Advance MAHaqueSir @ Telegram . 2

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy