Om

AmtuD NH,) 1
TMine
Orit-13 Aines Nitnle N

1 Lntrodtion
Dhe H-atom oAnmonia
A replaced b or Ayl
Hhenit i
Alky
naonas Aipahi D
Aomaie mEE:

R A-N1-/hY AY/R R/AY

AY

Stuetwe o Ane g
NH2 sr3 Hybidipation
Pyumida) Sae
H-NH Bond onngla lo

sp3 Hybndigation
N Pysramida Shabe -CH
lo8
C-N-C Bone cae >
Pwaida
$abe
 PAGE N
CHy > -H
Methyen DATE
Mea

( Nomencatue-
3 4
Sec
A Common Name , Is0 Neo,
et prefitef 0e
4 ged
RNH
R-IH
R-NH-R
ALkyl amaine

piaNy amine
AlAlKy adne

R-N RN-R RN-R

R

Tiaky Awne Dialky)awmne

AlRy AtKl AlKg

Exownple
CHNH, Methylamnne

n-poylarmine

Tpbutylauduns
 Orcle b Munubeouu E L multple Enebhb
=
CHNH-

wne

tt CHN
w

CHs
NN-ien)butyl amhue

OTEE Tso, Nep Cyclo prelike

re Considestada Kbatic odeu
pi,t secatetha X
CH=CHCHNH Allylammne
(AyicAmye

Hexcmethylenodiamine

Tabe13
 PAGE NO

DATE

B IUPAC Nane
O
KNH2 Alkanam^ne CHCMAM2
Emanamine

RNH-R N-AlkyAlkamamin
R-NHR -e more

Ex CH NHM N-mehyl metmarnine

CHNH-eH Nmetmylemanainc

R-N-A
R N,N-dialkal alkasnanaine
R-N-P

Ayl Alsalkawiamine
R

Ex
Pimethymemamamaine

CH3 N,N-di emnaius

 OATE
OTE I Numbe9tnq C-Chau Ctauts
Yom 3-Cosbon atn
2 3
Ch

Hl-N-Mehwd pripa-[-aine

13:
CIV) 2

eer
13-2
moleoulutoImwda CH
- NH2
Duly-1 i
Ch

ChCHWH-
 SM+H m PAGE NO

utt, DATE

TeX 13 13-

Mehhdpoprebaration-

Reouchion itso CounpoumdA

Nito alkane ame Yeduueed to a

Corresbondiiq allkaamine In
PcesimLe úf4/pL OY meta H
(Sn
N

NH
2 3h Hhame
21

Sn+ He N
OT FetHt

I i s realuon
Fe seap ancl HCL
efured
FeCLSo mel gets
yelvaussed to elae HCL Jutn
reeltun So Only cSmal
amont o HCL u raweel o
Lnkule
 DAT

Ammoyalytia o akyl Halideg

AnAlKyl OYbeunzy aliche mdesgoes
NSR Yn0 On reaon uith O Ekamalic
saldion a N H 3 uAich he X-atom
1s elalaceo am

proces
BoncdBond by NH male cuke 1f
k n aA AmmonauAiA

nCnod

HK
Sealeo tabe
a373k
Hx+R
FR-X N-
RuNX
letoalkylaomonumbalioe

haxdenoy pat
re&es u
eaien NHe as
Excecshan 1 A i n e 1f ormes pRet

procu wheseaj R RX
Maiun Duaxtenuomy B a u 1 E r e
ww Cxecs
A Ma
 PAGE NO.

DATE

The CumuN, Co be
Note
ob-taunat k a Cmma

SLt

R-NHH +Ny
CLmmonalyaA
T
andl 3
ammonuum_ a l l s obauu
Ihsis dusalenkage
eockto
Ordar o eactuunby R-Y.ue

R-T R-Re RT

Ex13
O C2HTC+HNH
C2HE NHa

CaNhc)
HC

CCait
en2 ynnnryancide
CHEOHt Na
PAGE O

HE +2H

NN-di.etny/ pumymemawmaine

educion o AUkuneniile -

axeYeduces to
AlKane utikg tne pcegenie
10 Aoe
o iAIH 0T Catalytic Hydhopeuation.
Ni
R-CEN +RHOY Nalt GHoH RHNHz
2h 21 Amne

Alkame Amiotes i
Yeduct1a o
Yeduces #o5TA
re
AKane
Amie
Amickes I n H a mefrlk
 PAGE NO.

DATE

LiA HY
R- H+4H
2
1 Amine

E) qabiel Phthalimide smtepis

Gamul Syatiag L3
hehaatuem ijhahu
Halimuele reclswbh elhonu
CkoH)Lo Jom altassum salt
salt o
Ahalmielo which_ hoalug
wth R-X eleuued A LAn
hclmedygis LAonchs
LmnS

NH
k
phthalimide N-Potesjum

ph#halkte-k +RX
O
o4
RNH +NaOH649 NR
1 Aiie
N-Akyiphtnalimide
 PAGE NO.

DATE

connttE artmalu Cumn3 eye

ol qeliL AhAalumicde

Ar-x wnelarpo NSR

uNth.
Jenmiel hhlhonmslo du
to _Unstall hrnyl sokoin
CutmoliL Cont e
epred mehere

EHoftmann bromamide degradahion A

eu t u i t D in
AlRne amiotes
aueaus hanalic Aolutim o NaH

Amane i OTmeo
This is Dsed i degrodahim o
A n e SesiesA

R-NH, +2Nak

NagH
Noo

MAp)
 PAGE NO

DATE

4PhyACa propesties =

phyaita tae
Lcuer alufhal amuas ae guss
wnlt ahy oreloruu 0ne d e g e e omunse
AkO 3 MLe Ccutn alenn
aLe luaucl ant k u g h a Mmbe
a iel

Ayl dminr& LAr NH a e LasLal,

colornilrss Juut
o2CLelskon

Sdnliyi
Laer althkal Cmnl_CL Sotuullu
wakedu lo eumalkon e
wth wata Malaulu
Soluluty denss
mala MasS
thhycloo
heduic ulo chana

gh wmunss_cu essLnttalynshula
 PAGE NO

DATE

andLut
QQut o utan -L0
whiwh ll b Mere aluu w
waber ancl y

Ans Th elkebronLgatuniby o
Cumin ane O oAlhhal
as 3:0 and 3. essrstuUey
Qu bo Eis ALLhahl
moe alar a n amnsad on
kongrete imalisuls Honily
Han aminrs,
Thus Rutans- o l wiu ebe.
Bulans -oi

Bou Paint
and2 muns_aLL EnqagA
ntumolutulas asstruabtin soo
H one

This iwurnaleLulas ass0-tLabten

mene u
un
amunnl hau n CM
aloms

3
amins do hot Kae
a4spcLttom JL lo tnlerma halluud

e H- (ponel alssnca H0
mabunn
 PAGE NO.
DATE

DrelOrel d BP 14meri.

2 2 2 3 Amine

R-N-H---- N H-- N H-

Inumesul ASsocuattin n
Cm u,

R
R

R - H - - - - -N H N-H-
1

L onolatule As&KLALwr un 2 min

l o u e _K m Alchodel
amnus w

sAlshohalsem trng H-enclng

Sc BP o
So aminns r las
 PAGE NO
DATE

5 Chumisal rvAukius
t AmnsU_aN rnackuA
eusaS;-

DuL o eE:N lent

N abtrmnXH-aloma

Duu lo esenle wnshce LlAtr

H-asens_uttahrello N-abtna.
So 1 2 ansl 3
mny
No TE Am Nhone ag anuchophib
Lns he _Au
- atem

(A) Basie Chaaute o

*Aineg zeat ait aidsHo Orm
korm
Salh
R ,tHx RNHX
GH +H
Aline
 PAGE NO

DATE

AnneAals ea it a bose
eene>zate u peo1w Ammne

RNH,X O H 2KNH, +4o t Nax

Baicchaassey o Omneg Com be

Exlaimes m erm hiL K
am Pkb- vales asoll6uf

Batiity

Pk Basiit

Basih

Ph

F lakb
No+e RNH NH2

NHs
 DATE

Bose
Amineg are Shmyen
Alfphatic du to-T matu o
h m NH3 uOLieLAeed zto h
Akyl 9ups N-atom
he
densiy_On
eo ane keake9 bates
AroaHc omneg ne
due Xo
h N Hhe
draulingnatuen ee d e i n o
ohic ecrease ka.

e N-atom

_Basiuity o Aimef depeols On

Fact
(A rdutive
Aawation 2ffectE
Steic HiveleaMLe

nducie zfect

Léz Taps nave

Lend deuaik Ove N-aom

due to asidty ncreales
o

RH2 RNH
R
 PAGE NO.

DATE

Ordeo Bagiitu
3 2 inesGaseus
ate

alvation SfectE

L e t us Conciol he xea tim o L,

2
3 Aines i apratan to
ConpaL heisu Dasiciy_

R
R H
R H

Subsitudeo Amonium Cation

Th Substuted Awmeniuwa Cafiong et

Stahiiseo bye9 relcasiiy efect F
Aawatian
Akyl ganb CE) Vas weu a
LHA_H,o molecules.

Stabiy oubtituted pasiiky

Anise
Awwwyitiun Cation
 PAGE NO

DATE

Orcde o Stahilty

R-N-H---HO R
N - N-

31
o Onche o Baiáy a Ane
3

St Hindsrance

more s ho of A
moTe e oub 0T
mOTe u be
All pYu
to H-bondim Leic udermeee
due to
eOeOde2 Baiüy oh Amines
 AGE NO

DATE

tus here A a
he imdeive Suhte
Efect,teapla
abin
Steic hindteramce o
he he
Shreno decicef
alky aÝnes e bac
in e Aquunus
Stade

2 3 NH,
R--H
2 3 N R CH
NOT E _e
he
eka
bauihy
rnues
Os
reusee
Asne
0CHT
utmdraun LSdeceae
he bal 0 ines.
e - NO2
S -CoOH X e t

CahN
Armatt
Aharicc Aia
AmimCE
 PAGE NOP.

DATE
Tott
13.3 U),ë,vi)
7
Ludeg

1 3 : 4
134

(8 Alkylaio
xAdAition AK trnp is k
As_ALRylafion.

RNH RX=HK> RNH-R

RNR. R-NP

0Y RNX uathesnay Salt

enaky amsanoumaalisl

Acylation t-
Alimaic Amatic Amines
reac ui Ai chloide Aid
Amhyetides £ l e r by NSRR
Ctom Amges
Ts_fx) n aA Acylahon
 PAGE NO
DATE

Cesre Outin e
presele C bele Stronge tha
he a n e pyidie).

Pyidime
GHNHt-th C
Shonoy
Culoi&e N EHy emannamite

Cphs ymoline
C
N, N-Aietnylthmamde

C
gHNn

N-ptrenyl-ethanawige
Acefamili4e)

CooH

rOTE Aminesreas mitu bevzoy

benzamiole
Chloite to torm
 PAGE NO.
DATE

Thi Kn i kn aA benzylation.

CHNHH
N-metmyl benzade

Corbylamnne Ceahon =
(TAoLcyamige. e s
Aliphatic 2 Arpmatic Aneg
Oxre healed itu CHUa- amg eHhauolie
KOH0rm A0Cyamiole 0r Cashylammime
uish ase u Smel SubstLeg,
Teauion
Caubylaäne YXY_or Tøcyanid
est

R-N CHcl+3KaH_ RNEc+3ktl-

OH ALky_booauigt 31
O
houl Anmeb
R w HNO
2 3 3° Ammne àre eat dLHeuky
i h HNO
 PAGE NO

DATE

Allptnatie 1L Amnes reac witw

Aiphaic duazonim LautHNO2
uich wtabe OMd iberate
N a One Acohls
HH
HN=0

RENR,+ HNO, Nae,H

cegyKN=N-C

2,0 wwatae)

HC N ROH
s7 e in estimahonok
Ammo aues 3 proteind

Avomatie 1 Amines eac i Ho

HNO
o o m Aromahc duzmumEaut whih
_takle d oYesonmee

Ntandt He
CENCEE sHN=U-
MNH, HN (Benza digen
Sfae_dne

uLe
Aromaicdiozorw gabs a
tor synthesis o
a Vasitehy
 PAGE NOp.

DATE

#2 wu HNO
C MnU,

(E) R i t amylsulphonul Code -

emzee Sulbhomyl chleDride ( C4HCo C
i Km a 0 Hinsbengls eazaut

t t iYeacted4 itu Aminep

tonm benzeme Sulpaonamidep

+HNHCH
(1'Arvne
N-2 lebenzeaSulpbarae
saube alkali)
he. H-ato atkashed to nihaen
Gphonamude I Stxonguy ioie
d u to a pmeseine o
itndaainliing Sulpuomy raip
So t Laukl in_alkali

N, N-ouemyl btnze
(denot Eaube fn alkau) Sulhouauid