Date

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Oganic
ALNES

lassthcaten
R-NHl R-NH-R
R-N-R R
Stuctue
H
lore pair bendpar iua
Hekhane Ammenia

’ bond angle tàmsitylanina(CN-à i

eu than terakedal bond angde
hlmethylamre (to1sduat
lon par -bond paîc Yepulslord.ig'
anmena de to sterchideraelatypa
OPAC
alkananine
lg9N-alkAlalkananine
3- N,N-dalsylalkaranine /N-alkyN-ayalsandee
Smallalky
Ahamad by olpkabetcalkbrde
S Ethananine

Propan-I-anine
’Fng nethylbaan-amine

NHt
 But 2-en-l-anine

N-nathy<paunie

NH-cH,C
N-enylatan-2-anmina
12)
3-bromeouilne 12) 8-inobenzoic acid

13) cH, NH,

haxane -l,6-dlamlne lCoven- hextylanadtaman)

4) Is) Cis NH ÇH(CH)

Nmthylpiapan-2-amine
2-mathylanille L)
(Cananen -Toluidine) Aphenymethtnamlne
N-methylaniline
Tsomesisn
Chan , pesttien, yunctnal & hctaasikm
(«//3)
 Prepaiahon
Reduction
) Nito comgounde
) Arnide

tmanwlyug olkyhalide
3 NaneYeacti :) Cobiel phthabimigle sythuu
) fyrann bionamida dagiadation reaton
enea
NH
CH),
Cethand)
R-CH,NH N/PNPt R-CN
Hyo
R-CH,-NHz LALHa R-CEN
LEALHLRCH,
NHz Hy
nit)
taide Roductiana
NH, they
NH RtHe ND, Ntg
ettttt
ction to
enagl He
D
Smallat
D
tisn, theduing HCl eleose
hydraysetn get and
aeFells prfeaed HU tFe
with Reduction
Ha fecl,t HCl Fet
NN)) azo to NO, Yeduce it
enzee Yeduclng sutable
fot (nst
tHCL Sh
HCe Fet
ampaund ne
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Jhis Teaction gves mitue 1'2'e 3° kquatera,

seperate.
’nayanina tjsd obahed as amaji pacdct by tut
(excuy (base) Cacid)

iNaoH 4o nctalir acid HE

Amines ae baste u°ch cembne toth tX toem Salt

o freean l°aminn td obtained.by using baetc mrada
NaoH

(excen
PeacttyR-T > R-Bt> R-aRE
Nane Yeactian
)Gabstel phthalinide
ko
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kot RX
KX H

coa
It u Su~table only to prepatng aliphatte jOamtne
’Ayomatelamire cant he prepaad becaue pastal
doule hond chasacte betueon C-X due to yeioneNca Ln
halorenes
’ 2°,3° amines cannt be paapared because phthalimtde
Phdtallnnid cordaining Actdte H, acidity y Hdue to

Hofman Bromanide deghadatan reactin

’ Armide en teated wth Br, kot gives 'amind chickh
contains Cne cabn les than that esetin atda
The alkyl gaup tAated fun castyl asbonto anin

NH
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fhyicas pgpute
laie aiphutic anel are qasemus oith fishy cdw
Nae than i Cakon -liqid highis mambey-$tlkd
Anatic amiuA ae cclawless, but dueto atMA

dark coe

ADmatic yne ae iniclub dile to hacphitbic

S3in soluhility duc tome tydoga
’Aleohe aseMEL Suuble thas aynies because oygn
Ee ectrncgatke than N, hence osn
Shong H-bad.
Anine ave laigha hoing ptdet Shong Entemisada

R-oH R-NH
branch
Chtnitat prepetied
NH

3°
24uhs
hamical propetta anties
Raic chasactei
Anmiras de basic due fo tedoncy to donate lon par
’

’TLay ae bate, tance react kot!, acid to fom sall

R-NH, t HX R-NHyx
CHz NHye Methylammonim chletda

Antlerium eheatde

’ Amne Salt are Soluble in wate

NaH Yegaratea pauntanie

Asine satt teated wlth base (ike Nhct,

This eacton used joa sepaAston antras yAm non -basie luen
Grganle Conpeunde Brolbletn tate
R-NH tOt
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Bastc stegth o Ki
lower pk Mee batic

fely paecipltaked bn yom hydated yertc cxide. (Bsasnp

Baatc,
pesence oy Hyo.patda OH Pon.which cenet fa;to
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Nkg
aminas are me basic than Nt becaie
ae e donattrg Gp by Tyoect, hance donutty alkylg
Raic strergth tagas phase,
ymenttenad (rotestoedh,agr pheu)
3° ° Nbaic by tT ectalEn

nofmentiaved ingy
3>2°>
Solucton/solkbilhy /hydaaton )2)8(
maH
Sletc acter
Fer methyl duiratvea 2°>3
(P g° due to less stelo hndean

Cmaty)

|3 >dueto stong +Teypet)

Aomatc amtne/Antln a leu baste than Mte andalkardnthe

due to ) RNH(ayl gspau Eo by Ieyd
+Ieject
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NH
+Ht
Aniliniutn

An&ine has 5 r-s whueas Aniih§n îon hau 2 Y-s.

Anilne nuene stabletan anilàniun ion,cuetotis
bale
pAotn aceptabilthy & antltne ulesaat au cweak

NO, (Eç)
Ortao Sub ahilnes are alsys lesA batc dua to

Nh Ntz

basieihy oude
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8) Ohennical Reactons

)Atkalaten
2) Acylata
4 Tensth nitouw aci (diazotsaton)

a)bamtnatton Coteled
Uncotrolled
Salphonaton
Netraton Cotalled
d) Gfedel Crak eontoled
n dbenotoaw
HKulaton

Aculaden ond

Nnethytebangnida
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HC-NH
sm casted cut tn storg baic meolau lkke pykidin

seplacad byay
but not aacylaten becae duatng.acylatan, antdi at be
emsd tnwhtch the ane gir ey Nstitisad by castonyl

CH) NH t CHzCo@’(cH, N-co-ci+HQ

N,N-dnatiylekananida

NHCOCH
t CtzCooH

Nphanylakanamtde (e) acelaniltda

losylande
nd alcohde koHto yom Eso yontdawrbylanine Whidh
ave youl sinall.
&donttcation P aine.
’R-C t3KLt3,0
foul Smdl)
Ctych, NH, CHa, 3kOH> thCH,NC + 3kee43tyo
Comten
 cASSMte
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Pace

Rxnth nibawadd
’altlatc anina
dia ZengnSalt which ae tale &cndegoe
hydaya to form alcehe LN ga.
Quantate analysi e N gad wedto estimat

NaNGtHa
R-NH TR-N,eRH +N,Seta
Paomattc an&n
Yeack with nathroud actd to fon salt (alotontun) hich
Qre petAe Stased by Yeyonan

,3' anny gues dyleract producb itla nibus aa.

Hindieg seagnt
awnine react otfa benzena ulphanyl caideto ,fom

’Solub n alklle dueto aádlo tH gaN

Naehaylkezeeaplonga
actdky atH due to stnng Eq natue g Sukpbanylg
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Paa-chleto Paatoulene salahanylchlorde also ued as

Hawbeq reagent

NHg gioufp la EDG & tngease e doraity atolp

poston, calledas achvatg qp Bokpdrecting g4
Bontaation
Ohcontolled NH
BY
Br, (ag)
2,4,6-tibromoakflie
Bx
lhtto pp)

NHCOCH
Ht

’only p nto- ue to sterte hindoance

pain N eonana toth
abonyl caben, hance loRs, pai
Ntes aaibble to donate toseae
g Yeactvity dereale)
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A53-4BKy
Arillnim
hydhogensutphate
Alphantlteactd

thaton
Uncontroted
N
Nh

(51)

madum, anilineptatote to foUm antltni on itek

A m
drectny

KD)
NO
does not o
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Nacquire tve chage, honca, tf-act au deactretrg gp

Dazonum sall

niline eat sth NaNGt te (nitous ackd) to yorm diazori

Selt

NaNo t Ha
L3-29R

Reßonance
N N=N;
ONEN:

Aromatic diazoniun galts ae Stable di to Yesonante

Phystoal popcute,
) Colauless cyitaline sdl
) Solubie bn t;o but seact wthhot oater,itfetms phensl
A) Benzena diazoium plupnide ae stale at ôm fenperata.
and tnseusle nttzo

Chenicalprgpoxtes

CEN
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t N,tur

Sandry prysaslHhan Qatenan kecauu

mee teld.

HBF

H6F, NaNO

Roducedt beazena

Ho

CH, CHo t HXt Ng

 Small Youl
smell fout ha tott
CHa3 CHC
abyemie
teatNC I32)
bl(tihaas
iay kdane’
p t whte antltne botth
teat GoateBoMRe W)
joanilinay) test dye )Azo
Chanical
test
nzer
NN
Ht
dye) yallons
enzene p-
H
/coupling dye Azo
1
classmate
 classmAt
Date

K-CHNHcg
|soa
ConueisionROH
chat ectNH
RNH Rce RcN
NaNo
kOH
patiad
R-coNH,

NH. topo
tomplet
poeeed
talt
to dlazo
pt
to
malket
LIHa
’R-CHO
KMno,OHT mate
Nan,tH
to

Hce
WoNo

NoNOHe
antln
Amene

o
.Tnea

RcH
Notet
Fe