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80 views12 pagesAmines and Diazonium Salts
Uploaded by
atharvthapar3Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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/ 12
Lesson +PAmines
Ant : Gis Diggenium Sala
Lmines = They are
“ ¢ abkyl or age derivatives of Ammon'a
Cnisdficalion of Amines - > Aliphatic amines
\ Aromatic amines
Pisphatee amines
Amines sine which nile
alegt Howbt rey may be I,
aie
i
or three
(7
uns,
'
2) Adabheyl eenine’ ©
Gide Chats of Or
Ee NAD
‘oO
SY
!
nomenclature r
Arnine
CH NA
Gite NH
ann nnn
CH GO ces
He
vor 3
GUSNHGHS
tw
(ons Hel NH
(paprotic)
n- Peabyl amine
Qsopeehet amine
pimenyf ovine
eimy_megt eine
Framernyflaenin®
egyerin™
cz din ted & une, 8 or three
Gus"
i
guc7 NaN
3
3 ‘AS
Amines Ln which wi keogen
o or three atemalic A -
(Gusta); V-
s.
un attached te
Methanamine®
Efhanamine
feopon-i- amin
Propo 2amnin® Paomalic fines
a NH CH3 enon
a GI
Bengenamine N-mettelan' line 1, nebime thy fami ine
oe (meng lphenglamine] (Dmehigl phony amir)
eo ove
u-phenglanilin®
(Dipherglaenin) N, ne diphenplanilecie
y (tespheryptanine)
Sroposatnn of, Pines. ~
co from nile Gmpourds J
eagle meobiom
a . Kesluckon '— :
al illo Gmpoundt Upon Aecuclion wv 0
In Acids medium
ver amines
eco - Gnevo + 6c) Snel Gig nt 2He
Niloe tone Ethyl amine
(pos. . q
fe/ac! Ho
Gir tg EL! ay 2
ila bergene Anifine _
a clio esther
> Sn neal. mectum - Nilke upon Seca users
Pd-c Ethanol or wang Liatty pet amine.
Bromples Gg Noy + 3H fae Ge NH + 2H
nilQethane Ethane! Einytamine
NO
fa- © Dd
eo] +34 ——— oJ p 2K?
Wilkabengen® mnifine ‘
Mi i (ree a zoben ere
‘Note — Reoluchon nilkabenjere vsng Lialty Ff A
mot ami:
ene LAl .
“ si Alt » Bint
haa
o LialHy ue
oO —_—— olkn=
. 20) Bone ne
C1) Fond Bilegl haducle?
Lieateol with allege halidle nom ateshelic. tdilen op Amniénic. AY
ot AB? Sealed tube ot 298k aver min tar
Da fiver Tek cated telnet an fa
4 aenmaalpsts methwek
Li mt & method
Reason ~~ 9F give ™
Ap
2°83 ami
me, Which ax oleh Gout I Example i-
cbr, + Nt BRK Ct tH
WA By saints Stet @
an (cig din + MBP
me
ch, & ve
net a, “
Talal Fbe ot
neks br 7 {oun 373k 2° amine
tafboeile 2 373K, (cry), + HB
ti 373k, : ro .
oi uy Baa
ia 7
- C By rat ammonium ae
TUL Fram witedet 4 pao rbeher 2 v
‘lca open | Bone ainy Pre, " gynines
nities apn Aecuchon nn eaney Ni
ofrale pond let gre 2? Amines
fr egen -2MeL RAPE, Cres
Acchagectisle Linimy eanterine
Bhaneritcle cot tae
e
“
EN
éy ate Niy
8) ts ,
Bevagh orn
Bexgorctibe pitile
But toe roe pe
Hn Zc +24, } [mis nH CHg
ae pinatleine
ety me AlHy
aoojanide
i, PE Her
pines
pee 2th 2
wuiainy powerline
Lialty re amides
toneesp ed
~ ©)
LZ & del i Aaduclon
“pam _Pmbee Prides “bor rm
einung one murien Hy Cet chiar
tw CHRCONHE pints [Eb ory Ma Ke
le. 40H) é: amine
a geil. chy Ne
o © pinta] eho + te
Bengamide word beyyeor™®
L Gabe! teenie Me 7 kot mre n- Al
Paaacium Phe yal mi de cape “weaknene wil, ot of 7 5 ef
phitabini de, wes fo + Aydesigee* & ate, °
se dy iy c-on
oxo te Glo? Tez ad OL on
Bi ° OL
Phase prinaben Ae pyoeingt petal le phadee
gut
Efrylamine t
a fon ase degen em cess marm Byomamicle Seo
Significomee *~ Je Used fev degradation Ci a eaEE e (orm chan 3 @
a ko & Bre Rew
cleatend the Series
ealined wifr aligngue Sdualmon
then amides
> Amides upen
° frmines Paving 4 cugen alan eH
ex Cg Conr, 48a, & abe Ke — Chai, BEB ane + 46°38
Aceramede P amine
or Meg gn ele KO oy + DEgr f2M0% HOB
Begamide jhe
o Being bois nL PROPERT! es 0F AMINES
are = e
ba Boilang font ¢ amines Ore hghet thant hydric
Reagan :- Due & CuchermMecuber bayalze ox Loncleng Gy amines thoy bane
boiling, Pant st : .
4
echo
Q
Biblhay botdung orntr ef acne, are ber tos athe?
fre 5 Sine OPH alestwls poe locke ve thoy Nile Aan
& tus fom hone et lang tan hanes
to a wir, amines “gone oa wing 1”
fort pends be ertea ee) mys Ne °
Prnimed Pe 2 al icra , Of Davie Crrtawwnr I, while 3
Pmineg Powe ne ty Tinted ke niltogen © yr anines howe
. Aughacl wlrile 3° et awe co ie yese iebng $n cide.
ci
') SdiabebSag -— Aenines frome, Hgdeoye bends wify wale, Asa. result lower
hate amines ore Mluble te wale .
reases, Atubilely decreases.
Coat mdjeculas. mars 4
a jen Aaya canbe pants Sopres hydrogen bende tai fy wae
Monealic Omines are idluble tn baler. Tris
ae Prin A eae due & g lage
0 oa PROPERTIES OF AMINES --
cle, of Amines :- Due &
ike, eat 4 ee a ea eee
Gn ues bons
Crcepliial 9) -b Miphalie S
amines au. Akarger base tay ammonia
ota sca proctecdy eb lec,
ae ae el pl sdame fair m wilgen
7 RO NH —
an an |
fo aaee Peeler. M Se ¢
2 (CHy),N, (%), iy 4 ein 9, bats shes . ?
7 .
| eae cae Of pe
S1,N “(Gus wn, Peo Ni, (In Aqucors tata
caus phage - Basic Character depenols upon +2 ehheck of
et peeps f Fur more are elechen Loni qeups me boss
diy by "ae om, siecle Nits 4 CHgNH, | WHS (CIN. [Ri Fp Ro git
Va a Stale ants Geet Sr eh a Cri PE
wm he Gs Nydorgen 1 boo Gi) pee velmueal Sen FE EE
pen. th adler 4 dasicily Should Se
B>2or
Bude Hyde © Amine tx be mest basic, ad
fete tlt mp a mege ene aestelly 4 ammonium
SO order of ban i
4 elf Dhol bee ot > 3,
— Mew % abet
Aincsance ate tyluepen 44 Mel then these ia moh te nic.
So order ue parding se Hyaleogen bencling acl fhecle minal
(CHs) NH > CHa i > (emi N > 5 b
> yA Frente 4 SEE BIC robrance ©,
eet BEEPS eljecr Padorninates 2 cele wily
aoe bond ha
“ (are, Num (GHS),N 7 Gis Nia 7 nia)
vet G Hes Arilace SS Lew bose thaws fenmonie?
ii more than fmmonia? -
ple Value of %niline 44 ea de ee
‘yo ‘apitine 2 Mona, phe
élections be
ey Onn,
- SS no rs
wv. in ammonia. - Aesonaliog Alia, clases ont present:
nts oN BASICITY oF
ARemaTic AMINES
NH, Ucreeses Lagi eek
olecseases basicity
Erpect of sugsrirvé
a Election donaling poups such
ou ecclion withchawing gow
8 aagage ofa en a nd
oH
ay CH, OCHs,
ch ot Nox, ov X +
e% oA in oreler se AO Rta =
Cig NH, GMS NM Ge
Pus ¢
eT GH NH Che CH, 6 Ch NHL
ane Bengyt an amine Mi amine
(due k oman engl
Mine fit Eesti Satine “OME pt le att gock
are tr auaileble — oP yiljagen ue
frrtmaledny nat Smee we auretlable or
ae ,
dn Aehenaurces |
9 CHEMICAL REACTIONS OF Animes -
Ly LATION = Je is fhoceds dy ine ducing am Atty! qmub in tiany médecule
A Phimang amine Gon be Gnveuled +5 Setondony 1 Gad tae 4 finaly &
q aanmovium calla, by with match of
chyennn, + HOB — Cone, in + Har
r
(CHy On).un + CH ky —? (mens: 3 + HBr
1 ChgcH), ut Ch er 2 (cy, Hy N gx ae .
Het Ee CuDsA
=
THE
sith Aaemalit’ aenines >
Gees? ,
nt Proce 1 Catled Ephauttive Tight, a be
e used a methyl Zocusle Seackon 14 Calle! “
mths
i
the process tp lance} acye youd CF Ey gmp de &
F melecute- nel
7 - CHEE NH cat
Ber cae doe bonnes wegen ide
sivibely o : en “tr + He
os boat + CH) NY oa
at amine NN, 5 metgtadtor ide
ene ob weit bengeyt Chicnide
Bauumesin 268cln
Aeklyt ehimide
malic axnine © 5
Maat
pono + He! >
Ben ene Haze nua
rede
priline wile
A called sazvia in seacion cn
piphalie prmerg amine. react with cota wi
wite patie amine | a
ive aleshds aga os +NLt De
+ ae ce Ni
yomolic) gee
on
o*
enh Saisecien
ceatkin £ we used a ha i Pmine. © 0) Bo Amines : a “cou
) dArmines Mipralie 2 Arie qrices wattr SAuble salt while
Demstic 3 fr pias, ann Cowsed orprrd @ |
(eosign + monene) eergerd, 81) No
Salt”
Hew “cable
LS
ag «> fnowe aye ernne #19
3 ?
‘a Bo Bb Fiffosonn,nraimeltplan line
oxidalon.- Cre)
nail oxrealion op. Aniline spit Bycean + Mason vet pb
pan, SI 0 wee
avitine p- bengoguinane
keum- 9t 4 became of HG election lenailg om Pre Aung
5 pec reopHiis SoBsI TUTOR REACTIONS. 2D AROMATIC AMINES =
Julie Umclecgrs élechaphbe Gubetitlion Aeachors ak 4p poten
cy Halogenobion _ with Bomine welt Andice re yigutanrated [podicl
“ yh.
Gy Hes. naker Sroroysr + guer
Frridhine aye eileen he .
Buk %G Monohalogenatial ‘devivalore £4 Acquired they amino goup Ls Hae
ateljlatia 2 then Roles ding. 44 casnied or
NH, CHC
> nyHcochy neHcoty NHC
Oo co x, | CHC a
pilaoe =e, 0007 o} ols oye + = 4+ Hex
Acetanlde Ls
Nh nite ari
oS + or rit [hae
er
oap- Boamoarilir®
Contiolied Gnoliton, ritialon priline 7
penilianilre 4 me Nilcoauiluine , wa Wh "hatn-
ce H,£04 Di a oy*
gn ner G+ Sag alee
Nos. .
asi nau vrvitjoowabaie oh
P wibjoawilne Cie cz
a Nitkin =
under ines, misclare ot
Be =) Conceptinal questins:- ( i)
GrPay Divect i Bakin of aniluie is mot cauied out ?
oe : of 7
Seba: Degg, wilahon o Praline, © seamen 1 6leune along eit BOS
fos ig Ey presence I Along 8 miata NM Converae
in valine,
4 On, um in
4 Ph od
Sie - GS 8 Gnvev j ni
Gnver™ Aniluie ti 04 para nulloanitine
@
fm
G+ cc. fyicocn, me woe,
So Ts ——> re ~ HANNO, 0c
cigeo 7° Th80y we * tar oe. shice ts
Aceh n wenycoon Melanie One Hoy - B
anhydride Ls
1»
0400
230004 [Ht | Ho
NH it
Sutphnation = Gnt a+ Oe
ee Cc with Sulphuce acd No, 2 Karin
7 om (miner)
p-nilfoaniline
Amilane upon Ticatmen
ot" gives pramino bengeme Sutbhon ie (mage
Baw,
at Yss-47SK,
acid algo Called Sudphaniie acid
Dymgtsoy ne H
Hy,
S + HyS0y ——> Co) yss-y 9s k —_—
Ho” ~ Yor
05
« S03 ot
ulphani lic 244! curbharrili — aud
F c
Gnceptiat question’ Ie gut ZeoiHee, fon! Comment ‘fet cen)
ead exist as ites, Lon. Gmme Zwi
By ‘guppharidic & both Sagi + NL qoup Se
Sogh yo
staan‘ clenabid ae ais
bie aud
Sutphen torn cat, Intl Sa tans
1 Such tyre % ap
on ities Lome 2
Sal Cag Aeackor. “tdy ombne *
2» 3
° = i
4 RNH,
ot . SHE! ° z
Geren tBu He ageresupner
° 12 Amin’
Gengene sulphory!
‘phbridle o, Ko ring dlenble
© - BN -g
Silt BMH pe? ay
° a Amine yw Dred bergen’
‘culphmazrace expert ge Me heat
The soacton mi @
Chloride +n ane a Wai theatnnent voit, bengenesel sai
he Aemauning Ks hited winere. 3 ATUNG Ws
Sduid Arvclt aes Shs filled #6 re iferalé. +
= ibe a pide Pee tach Conlle-oe, geile fee °
ane tyoesiysed spect & Pe BI? amines
Shed OE hai
yg 2° amines,
; caneyeamine Test 7 Tencganice SE
Note i- ‘Tas tele Coun be used te i St ate saints wen
Aromalit ) can
Amines because ? Amines (
jus tes
? 0 A ab (Auphalie 1 open beaker 4 cue, & i. Kon
ques Conger ite 3 a Aries O°
CH, NHL t CHCl; + 3kOH 2 CH, veer gKet 3H!
Mi ami aA anide
ee aed
a ime
wae
geet n,?
pcnels + BHO —
a
Pen pmtyaride
7a i
ndle ‘tg fest Com be
ab nile 2 met am dy Arilunt 4
Erne © 4 Hono FHC! we ess ae
Frldne 2 pil NaH 9
S\ ase foynen ms) + HCI
Gris ner $35 pHarle
prnpite! I" peter) "raph tel
aber .
Hinsberg s Teal aos bal be us " SE _
mire with esulphery! thloide, 9” Suach 1 Prine
ves, de nich * Aduble Icon.
a “urphonaenile ncuble Kou
oe
oo renin, TS nat Beat
z
oF pemine A
ont oy bee! a je 4 He
a i
Amine 6 L_KoH
cduble
ann + orien ois on
eee % Aenea Snseluble
an + Grfro > Ne ° seacton
mine _Congesesuspreny t Cher 7 p ena) Beenie
ene ere =
sad gooered ferrets Ea Ar ge
Bramgle ‘- _
Syiienc!
Alenide
ua zeniun
wach ore Paghly unstable
berger
is hatic oun diazoriuen £01
eng cf wonimes for azenium
A Compe
penenx —> RteN +KG vipske
> brim amines Bo pa Zorve” “endl writ saaie for 8 OE
tne de cdutin ak 273- 72K ae papers! peut
Pesson Tre dian op Onn son sabe ih OM
Zhaage on jengen® ® -
ei ae quai yen ° nen:
@ <> (eI ~ ra
—
. pemdteneny & Eleinal
flo, snstabilily of Pian Perce “eau we He ther 4
Stable Mo padtecute, & form corbe S
ReNENx~— ate it x7
eile x et net %
Phong! este _ awry ppocelians se
bri ree nilke ger"
woe a ce ha ©
akon S
> DypzoTISATIO® - De pros Me crvessin # pomarg
3 ae . Ott
suis azoriven gale 44 caused azo aon goaded ~ 4
2 3n the wepod & Cetd s futon 4 soci 4097 8K askion
fa guemalic amine 1 OA of ee
Me ane! rH oO pe Nacht 2°
© + Nano + egueanponin
Prilone 5 Clete
SALTS
eres OF py azonie ———
peo heel det ih gis vane” SO
L re e ertang A rt he amine oy dean
he fe \ ei
Nhe iy apacenene 4g 10% ate cr
tyeNx” +
> ee Hx tN;
BD) + Hy fo t 42 or 13 P23 le
Alonediage _ RR
+yeny” we
oc} + cone Als eo) aN pxt &
Ein! oleae Aheee nd . a
(0 dondme yess 8 cackon er cucper 1 -
“ect Sou [J @
cp vb
seprceenent 4
ot oN _ feagegecinze cuBsiner BF
op 5 chlevide Or
; cucnsken gal
Gi) Gattermann Atackon Newer @ ae
. Guttermann Aeaccer “ew fg) i
© epic vd Qo
cn Bengene Qt
cu] tar a
| cn 4 diazonium ¥
yt chloe Leu Kend on an
oO TN
(iii) Replatement by sodane
ri z
aut With poreasie”
Gcatinent @ Beugene ouazeniun
Ur dodo beng ene
+ Enel”
Oo] + kL
| Bengene
chiencle
|
ww Replacement by ydasngh fio |
bia zeniven cate Shuskon % faye volume of beheg
dodide, We
°
ph + KO!
iazonnum Poolobeuazen®
Upon low
ih 14804, Phenot 44 ob tauned -
4+ Encl oH
293K I
see ns Semen
Phenol
ww keplacement be Fluorine 7
> C gaiz- sebieman” Aeacton )
gi Cane SH Fen en
a + Be a © 4, ant 88
Dagenion robradi, Ary! duende
i Cou . peachons + Abene lia: salis Aras wilh aghty Reachve
pond ot ad phenols £ amines fom azo Compounds .
Hg
+ ed ie on wenn + HEL
Bengene er ® Phenol g70-278K by rong agenengene
a rey)
i ia Hs
ytenct + 4 ni fa (aynew Ere
“ roe p-aminoage bug ewe
ndte couplers usually octet at p- poslion a Ea on or Nh, po?
pul %f Pr Poeclon Gi ocaupied couple eeure oe 070 perrton
oon on leren
+ é,
sy Nene!
+Hel
+
lf NENC! + ote
pHa-lo
weNn