X, Pyq, Chemistry
X, Pyq, Chemistry
Q2: Write the chemical equation for the reaction taking place when
steam is passed over hot aluminium. (CBSE 2015)
Ans: 2Al(s) + 3H2O (g) → Al2O3(s) + 3H2(g)
Q3: (a) Write the electron dot structure for chlorine (At No. 17) and
calcium (At No. 20). Show the formation of calcium chloride by the
transfer of electrons.
(b) Identify the nature of the above compound and explain the three
physical properties of such compounds. (CBSE 2015)
(iii) Metals conduct electricity because they have a large number of free
or delocalized electrons. These electrons are not bound to any particular
atom and can move freely throughout the metal lattice. When a
potential difference is applied across a metal, these free electrons can
easily move and carry an electric current.
Ans: The reverse of the given chemical reaction is not possible because it
violates the principle of conservation of mass. In the forward reaction,
zinc (Zn) displaces copper (Cu) from copper sulfate (CuSO4) to form zinc
sulfate (ZnSO4) and copper. However, in the reverse reaction, copper
cannot displace zinc from zinc sulfate, as copper is less reactive than
zinc. Hence, the reverse of this reaction is not feasible.
Q9: Describe an activity to find out the conditions under which iron
rusts.
Ans: To find out the conditions under which iron rusts, you can perform
the following activity:
• Take three test tubes and label them as A, B, and C.
Fill test tube A with water, test tube B with water and oil, and test tube C
with water and salt.
Place a small piece of iron nail in each test tube and allow them to stand
undisturbed for a few days.
• Observe the test tubes regularly and note any changes in the
appearance of the iron nails.
• After a few days, check for the presence of rust on the iron nails in
each test tube.
Analyze the results and determine the conditions under which iron rusts.
Q10: A metal 'X' combines with a non-metal 'Y' by the transfer of
electrons to form a compound Z.
(1) State the type of bond in compound Z.
(ii) What can you say about the melting point and boiling point of
compound Z?
(iii) Will this compound dissolve in kerosene or petrol?
(iv) Will this compound be a good conductor of electricity? (2017)
Ans: (i) The type of bond in compound Z is an ionic bond.
(II) lonic compounds generally have high melting and boiling points due
to the strong electrostatic forces of attraction between the positive and
negative ions.
(iii) lonic compounds like compound Z do not dissolve in non-polar
solvents like kerosene or petrol. They are only soluble in polar solvents.
(iv) No, compound Z will not be a good conductor of electricity in a solid
state because the ions are held in a fixed position and cannot move.
However, it may conduct electricity when dissolved in water or molten
state as the ions become free to move and carry electric charge.
Q11: Why do some metal surfaces acquire a dull appearance when they
are exposed to moist air?
Write the colour acquired by the surfaces of copper and silver in such a
situation and also write the chemical names of the substances due to
which it happens.
Ans: When metal surfaces are exposed to moist air, they can undergo
oxidation. This oxidation leads to the formation of metal oxides on the
surface of the metal. In the case of copper, the surface acquires a
greenish coating called copper(II) oxide (CuO). Copper(II) oxide gives the
surface a dull appearance. In the case of silver, the surface acquires a
blackish coating called silver sulfide (Ag2S). Silver sulfide also gives the
surface a dull appearance.
Q12: (a) What is reactivity series? How does the reactivity series help in
predicting the relative activity of various metals?
(b) Suggest different chemical processes used for obtaining a metal from
its oxides of metals in the middle and top of the reactivity series.
Support your answer with one example. (CBSE Sample Paper 2018)
Ans: (a) The series of metals in decreasing order of reactivity is called the
reactivity series of metals. The metals at the top are most reactive and
metals at the bottom are least reactive.
(b) The metals in the middle of the reactivity series are obtained from
their ores by chemical reduction with a suitable reducing agent, e.g.
ZnO+C ---->Zn + CO
The metals at the top of the series are obtained by electrolytic reduction
of their molten ore:
Q13: (a) Write the steps involved in the extraction of pure metals in the
middle of the activity series from their carbonate ores.
(b) How is copper extracted from its sulphide ore? Explain the various
steps supported by chemical equations. Draw a labelled diagram for the
electrolytic refining of copper. (2018)
Ans: (a) Extraction of metals of medium reactivity: The metals in the
middle of the reactivity series are
zinc, iron, lead, etc. The carbonate ores first need to get converted to
oxides as it is easier to get metal from their oxides.
(b) Copper glance (Cu2S) when heated in air gets partially oxidised to
copper oxide which further react with the remaining copper glance
to give copper metal.
Q14: What would a student report nearly after 30 minutes of placing
duly cleaned strips of aluminium, copper, iron and zinc in freshly
prepared iron sulphate solution taken in four beakers? (2019)
Ans: (a) The colour of the ferrous sulphate solution in test tube (1) will
match the colour of the solution in test tube II when a piece of copper is
dropped in it. This is because copper is less reactive than iron and will
not displace iron from ferrous sulphate solution, resulting in no change
in the colour of the solution.
(b) The colour of the ferrous sulphate solution will fade and a black mass
will be deposited on the surface of the metal when a piece of aluminium
or zinc is dropped in test tube III or IV. This is because aluminium and
zinc are more reactive than iron and will displace iron from the ferrous
sulphate solution, forming iron oxide (black mass) on their surfaces.
Q16: An ore on treatment with dilute hydrochloric acid produces brisk
effervescence. Name the type of ore with one example. What steps will
be required to obtain metal from the enriched ore? Also, write the
chemical equations for the reactions involved in the process. (AI 2019)
Ans: The ore that produces brisk effervescence when treated with dilute
hydrochloric acid is a carbonate ore. One example of a carbonate ore is
limestone (CaCO3).
Steps to obtain metal from the enriched ore:
Calcination: The ore is heated strongly in the absence of air to convert it
into metal oxide. CaCO3(s) → CaO(s) + CO2(g)
Reduction: The metal oxide is then reduced using a suitable reducing
agent, such as carbon or hydrogen, to obtain the metal. CaO(s) + C(s) →
Ca(s) + CO(g)
Q17: Silver articles become black when kept in the open for some time,
whereas copper vessels lose their shiny brown surfaces and gain a green
coat when kept in the open. Name the substances present in the air with
which these metals react and write the name of the products formed.
(2019)
Ans: The substances present in the air with which silver reacts are
hydrogen sulphide (H2S) and sulphur compounds. Silver reacts with
these substances to form a black layer of silver sulphide (Ag2S) on its
surface. The substances present in the air with which copper reacts are
moisture, carbon dioxide (CO2). and oxygen (O2). Copper reacts with
these substances to form a green layer of copper carbonate (CuCO3) or
copper hydroxide (Cu(OH)2) on its surface.
Q18: (a) List in tabular form three chemical properties based on which
we can differentiate between a metal and a non-metal.
(b) Give reasons for the following:
(i) Most metals conduct electricity well.
(ii) The reaction of iron (III) oxide (Fe2O3) with heated aluminium is used
to join cracked machine
parts. (Delhi 2019)
b) (i) Metals conduct electricity due to the flow of free electrons present
in them.
(ii) The reaction of iron (III) oxide, Fe2O3 with aluminium is highly
exothermic and the iron produced melts. This molten iron is used to join
cracked iron parts of machines and railway tracks.
Q22: (a) Complete and balance the following chemical equations: (2020)
(i) Al2O3 + HCI--->
(ii) K2O + H2O---->
(iii) Fe + H2O---->
(b) An element 'X' displaces iron from the aqueous solution of iron
sulphate. List your observations if the element 'X' is treated with the
aqueous solutions of copper sulphate, zinc sulphate and silver nitrate.
Based on the observations arrange X, Zn, Cu and Ag in increasing order
of their reactivities.
Q24: (a) (i) Write two properties of gold that make it the most suitable
metal for ornaments.
(ii) Name two metals which are the best conductors of heat.
(iii) Name two metals that melt when you keep them on your palm.
(b) Explain the formation of the ionic compound CaO with an electron-
dot structure. Atomic numbers
of calcium and oxygen are 20 and 8 respectively. (2020)
Ans: (a) (i) The malleability and ductility properties of gold make it
suitable for ornaments. (ii) Silver and gold.
(iii) Gallium and caesium have so low melting points that they melt even
on keeping them in the palm.
In this structure, the calcium atom loses its two valence electrons to
oxygen, resulting in a Ca2+c cation and an 02 anion. The electrostatic
attraction between these oppositely charged ions forms the ionic bond
in calcium oxide (CaO).
Q25: Carbon cannot reduce the oxides of sodium, magnesium and
aluminium to their respective metals. Why? Where are these metals
placed in the reactivity series? How are these metals obtained from their
ores? Take an example to explain the process of extraction along with
chemical equations.
(2020)
Ans: (a) Gold and silver are highly malleable metals so, they are used for
making jewellery.
(b) Certain metals, such as stainless steel, copper, and aluminium, are
used for making cooking utensils due to their specific properties.
Stainless steel is chosen for its durability, corrosion resistance, and ease
of cleaning. Copper is an excellent conductor of heat, allowing for even
distribution of heat during cooking. Aluminium is lightweight and has
good thermal conductivity, making it suitable for cookware. These
metals provide the necessary characteristics required for efficient and
safe cooking.
Q30: A clear solution of slaked lime is made by dissolving Ca(OH)2 in an
excess of water. This solution is left exposed to air. The solution slowly
goes milky as a faint white precipitate form. Explain why a faint white
precipitate forms, and support your response with the help of a chemical
equation.
OR
Keerti added dilute Hydrochloric acid to four metals and recorded her
observations as shown in the table given below:
These compounds are termed ionic because they are formed by the
transfer of electrons from a metal to a non-metal. The electron transfer
in such compounds is controlled by the electronic configuration of the
elements involved. Every element tends to attain a completely filled
valence shell of its nearest noble gas or a stable octet.
(i) Show the electron transfer in the formation of magnesium chloride.
(ii) List two properties of ionic compounds other than their high melting
and boiling points.
(iii)
(A) While forming an ionic compound say sodium chloride how does
sodium atom attain its stable configuration?
(B) Give reasons:
OR
(i) Why do ionic compounds in the solid state not conduct electricity?
(ii) What happens at the cathode when electricity is passed through an
aqueous solution of sodium chloride? (2023)
(iii) (A) Sodium atom has one electron in its outermost shell. If it loses
the electron from its M shell then its L shell now becomes the outermost
shell and that has a stable octet. The nucleus of this atom still has 11
protons but the number of electrons has become 10, so there is a net
positive charge giving us a sodium cation Nat. On the other hand
chlorine has seven electrons in its outermost shell and it requires one
more electron to complete its octet. If sodium and chlorine were to
react, the electron lost by sodium could be taken up by chlorine. After
gaining an electron, the chlorine atom gets a unit negative charge,
because its nucleus has 17 protons and there are 18 electrons in its K, L
and M shells. This gives us a chloride anion CI.
(B) (i) The conduction of electricity through a solution involves the
movement of charged particles. A solution of an ionic compound in
water contains ions, which move to the opposite electrodes when
electricity is passed through the solution. Ionic compounds in the solid
state do not conduct electricity because the movement of ions in the
solid is not possible due to their rigid structure. But ionic compounds
conduct electricity in the molten state. This is possible in the molten
state since the electrostatic forces of attraction between the oppositely
charged ions are overcome due to the heat. Thus, the ions move freely
and conduct electricity.