Lakshya JEE AIR D1(2025)

JEE
Advanced
Weekly Test - 32

DURATION ::180
DURATION Minutes
90 Minutes DATE : 11/01/2025 M.MARKS : 180

Topics Covered
Physics: Full Syllabus (11th+12th)
Chemistry: Full Syllabus (11th+12th)
Mathematics: Full Syllabus (11th+12th)

General Instructions:
1. Immediately fill in the particulars on this page of the test booklet.
2. The test is of 3 hours duration.
3. The test booklet consists of 51 questions. The maximum marks are 180.
SECTION-1 (Maximum Marks: 12)
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
SECTION-2 (Maximum Marks: 12)
• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option (i.e. the question is unanswered) will get 0 marks; and
choosing any other combination of options will get –2 marks.

[1]
 SECTION-3 (Maximum Marks: 24)
This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen
• virtual numeric keypad in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.

SECTION-4 (Maximum Marks: 12)

This section contains TWO (02) paragraphs.
• Based on each paragraph, there are TWO (02) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric
keypad in the place designated to enter the answer.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered in the designated place;
Zero Marks : 0 In all other cases.
OMR Instructions:
1. Use blue/black dark ballpoint pens.
2. Darken the bubbles completely. Don't put a tick mark or a cross mark where it is specified that you fill the bubbles
completely. Half-filled or over-filled bubbles will not be read by the software.
3. Never use pencils to mark your answers.
4. Never use whiteners to rectify filling errors as they may disrupt the scanning and evaluation process.
5. Writing on the OMR Sheet is permitted on the specified area only and even small marks other than the specified area may
create problems during the evaluation.
6. Multiple markings will be treated as invalid responses.
7. Do not fold or make any stray mark on the Answer Sheet (OMR).

Name of the Student (In CAPITALS) : _______________________________________________________________

Roll Number : _____________________________________________________________________________________________

OMR Bar Code Number : ________________________________________________________________________________

Candidate’s Signature : _______________________________ Invigilator’s Signature _____________________

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 IMPORTANT CONSTANTS

Speed of light in free space, : 3.00 × 108 ms–1

Permeability of free space, : 4 × 10–7 Hm–1
Permittivity of free space, : 8.85 × 10–12 Fm–1
The Planck constant, : 6.63 × 10–34 Js
Rest mass of electron, : 9.1 × 10–31 kg
Rest mass of proton, : 1.67 × 10–27 kg
Molar gas constant, : 8.31 JK–1 mol–1
The Avogadro constant, : 6.02 × 1023 mol–1
The Boltzmann constant, : 1.38 × 10–23 JK–1
Gravitational constant, : 6.67 × 10–11 N m2kg–2
Acceleration of free fall : 9.8 ms–2
Rydberg Constant : 1.097 × 107 m–1
Atomic mass unit : 1.67 × 10–27 kg
Charge on proton : 1.6 × 10–19 C

IMPORTANT VALUES

2 = 1.414 ln 10 = 2.303
3 = 1.732 log102 = 0.3010
5 = 2.236 log103= 0.4770
 = 3.142 log107 = 0.845
e (Euler’s constant) = 2.718

* Use above values unless otherwise specified in a question.

❑❑❑

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 PART-I (PHYSICS)
SECTION-1 4. A spherical insulator of radius R is charged uniformly
Single Correct Type Questions with a charge Q uniformly distributed throughout its
1. An ideal gas has molar heat capacity Cv at Q
volume and contains a point charge located at its
constant volume. The gas undergo the process T = 16
T0 (1 − V) where , T0 is constant and V is centre. Which of the following graphs best represent
qualitatively, the variation of electric field intensity E
volume. Then molar heat capacity of the gas is : with distance r from the centre.
R
(A) CV + (1 − V )
V
R (A)
(B) CV − (1 − V )
V
R
(C) CV − (1 + V )
2 V
R
(D) CV + (1 + V ) (B)
2 V

2. A uniform rod rotating in gravity free region with

certain constant angular velocity. The variation of
(C)
tensile stress with distance x from axis of rotation
is best represented by which of the following
graphs:

(D)
(A) (B)

SECTION-2
One or More Than One Correct Type Questions
5. In the figure shown, there is a conical shaft
(C) (D)
rotating on a bearing of very small clearance t.
The space between the conical shaft and the
bearing, is filled with a viscous fluid having
coefficient of viscosity . The shaft is having
3. The trajectory of light ray in a non-homogeneous radius R and height h. If the external torque
 y applied by the motor is  and the power delivered
medium is representing by x = A sin   where A by the motor is P working in 100% efficiency to
B
rotate the shaft with constant . Then
and B are positive constants. Assuming that
refractive index varies only with x-coordinate and
has the value n0 at x = 0; compute the refractive
index as function of x in the space between the
planes x = –A and x = +A.
1/2
 x2 
(A) n( x) = n0 1 − 2 2
 A + B 
1/2
 x2 
(B) n( x) = n0 1 − 2  2 R 3 R 2 + h 2
 A  (A) P =
  2t
1/2
 x2  R3 R 2 + h 2
(C) n( x) = n0 1 − 2  (B)  =
 B  2t
 
2 2 R 3 R 2 + h 2
(D) n( x) =
n0 (C) P =
1/2 4t
 x2 
1 − 2  (D) τ =
πωηR 3 R 2 + h 2
 B  4t
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6. Some oscillating systems, instead of having one SECTION-3
natural frequency, have two natural frequencies. Non-Negative Integer Type Questions
Let the lower angular frequency be denoted by L 8. A rectangular rigid fixed block has a long
and the other one by H. Consider one such horizontal edge. A solid homogeneous cylinder of
radius R is placed horizontal ly at rest with its
system: Two physical pendulums, each
length parallel to the edge such that the axis of the
comprising of a uniform rod of mass M and cylinder and the edge of the block are in the same
length L with small ball of mass M attached at vertical plane as shown in Figure. There is
one end, connected by a spring of spring constant sufficient friction present at the edge so that a very
k. The spring connects the mid-points of the rods small displacement causes the cylinder to roll off
and both the rods are hinged at their top points the edge without slipping. The angle θc through
such that the whole arrangement is free to rotate which the cylinder rotates before it leaves contact
in the vertical plane: with the edge is cos θc = 4/x. Find the value of x.

9. Two antinodes are observed on either side of rod

C. If the frequency of the mode in which the rod
One of the natural frequencies results when both
is vibrating is f (Hz), find f /1000 (Y = 2 × 1011
the rods are disturbed (together) by equal
N/m2, density of rod = 8 × 103 kg/m3, length of
amounts in the same direction while the other
the rod = 1.25 m)
natural frequency results when both the rods are
disturbed (together) by equal amounts in opposite
directions.
Now, consider the following statements and
choose the correct option(s). 10. Two infinitely long straight wires are placed
(A) Changing the stiffness of spring changes H perpendicularly at a separation of d. Each wire
 carries linear charge density . The magnitude of
(B) The ratio H increases on increasing the
L 3 2
repulsive force on each wire is . Find the
dimension (L) of the system n0
9 g value of n.
(C) L = .
8 L

(D) H =
3  2k 3 g 
+
11. The radio isotope 64 29 Cu can decay through
8  M L  positron emission and electron capture. In both
process neutrino is emitted. The difference in
7. Consider a hypothetical situation in which the maximum possible kinetic energies of neutrino is
potential energy between electron and proton at a k MeV. (given that rest mass energy of an electron
is 0.51 MeV). Then the value of 100 k is?
−ke 2
3
distance r is given by 3r where k is constant, e 12. A circuit shown consists of two inductors of
is charge of proton and r is radius of orbit. inductances L1 and L2, a capacitor of capacitance
Application of Bohr’s theory to hydrogen atom in C, a battery of electromotive force E and internal
this case shows that resistance r and a switch. Initially the switch was
(A) energy of electron in nth orbit is proportional in position 1 for a long time. Find the maximum
to n6. current (in A) in the inductor L2 after the switch is
(B) energy of electron in nth orbit is proportional thrown to position 2?
to m–3 (m = mass of electron). (Given: E = 5V, L1 = 4 mH, L2 = 1 mH, r = 2)
(C) energy of electron in nth orbit is proportional
to n–2.
(D) energy of electron in nth orbit is proportional
to m3 (m = mass of electron).

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13. There exist a uniform inward magnetic field 14. If the particle mass loses the contact at point A
B = 1T in cylindrical region of radius r = 2 m . and follows trajectory ABC then the value of
Outside the cylindrical region the magnetic field R x
height h will be equal to . Value of x is equal
is outward but of same magnitude 1 T . A point 2
charge (q = 1C and m = 1 kg) is projected from to _____. (Answer to nearest integer)
a point A on circumference with velocity
15. The value of ω (in terms of acceleration due to
2 m / s towards center as shown in figure. After
time t = N sec particle again passes through g y
gravity g and R) is equal to . Value of y is
initial point A . Find the minimum possible value 4R
of N. equal to _____. (Answer to nearest integer)

Paragraph for question nos. (16-17)

In a Young's double slit experiment, a point source is
placed on a solid slab of refractive index 8/5 at a
distance of 2 mm from the plane of two slits spaced 3
mm apart as shown and at equal distance from both the
slits. The screen is at a distance of 1 m from the slits.
SECTION-4 Wavelength of light used is 500 nm in air.
Paragraph Type Questions
Paragraph for question nos. (14-15)
There is a hollow cylinder of radius R and it is rotating
with constant angular speed ω about a horizontal axis
passing through its center. There is a particle mass on
circumference which rotates along with the cylinder and
gets carried upward. Friction is sufficient enough such
that the particle mass does not slip with respect to the
cylinder as long as the normal force becomes zero. If the
path of the particle after it lost contact with the cylinder
is as shown along the curve ABC in the figure then, 1
16. Position of central maxima will be m below
x
O then the value of x is.

17. Order of fringe formed at O is 100y. Then the

Value of y is _______.

PART-II (CHEMISTRY)
SECTION-1
Single Correct Type Questions
18. Select the correct option for following aqueous
solutions: (D)

(A)
2+ +
19. H3C − C  C − Ph ⎯⎯⎯⎯⎯⎯
Hg /H /H 2O
→ P, P is :
(A) H3C − C − CH 2 − Ph
||
O
(B)
(B) H3C − CH 2 − C − Ph
||
O
(C) H3C − C − C– Ph
|| ||
(C) O O
(D) H3C − CH − CH 2 − Ph
|
OH
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20. Among the following, which reaction will not SECTION-3
give N-ethylcyclopentylamine as major product? Non-Negative Integer Type Questions
25. Identify correct number of statements :
(A) Statement-1: Entropy of system increases in
dissociation of ammonia gas into N2 and H2
(B) gases.
Statement-2: Entropy of system increases in
polymerization process of ethene to form
(C) polythene.
Statement-3: Entropy of system increases in
adiabatic irreversible compression of an ideal
(D) gas.
Statement-4: Entropy of system increases in
21. Potential energy of electron present in 2nd orbit of condensation of H2O (vapour).
Li2+ is : (a0 = Radius of 1st Bohr's orbit) : Statement-5: Entropy of system increases in
isothermal free expansion of ideal gas.
e2 3e 2
(A) − (B) − Statement-6: Entropy of system always
40 a 0 40 a 0 increases in a spontaneous process.
3e 2 9e 2 Statement-7:Adiabatic process whether
(C) − (D) − reversible or irreversible will not cause any
160 a 0 160 a 0
change in entropy of the surroundings.
Statement-8: At absolute zero, entropy of any
SECTION-2 substance becomes zero.
One or More Than One Correct Type Questions
22. Consider two liquids A and B having pure 26. 1.2 gram of carbon is burnt completely with 2.56
vapour pressures PA & PB forming an ideal gram of oxygen to produce CO(g) and CO2(g).
None of the reactant remaining after reaction.
1 1
solution. The plot of y − axis v/s x-axis Produced mixture of gases is treated with solid
XA YA I2O5 (to know the amount of CO(g) produced).
(where XA and YA are the mole fraction of liquid The liberated iodine required x mL of 0.1 M
A in liquid and vapour phase respectively) is hypo solution for complete titration. The value of
linear with slope and Y intercepts respectively: x is
PA − PB
(A) Intercept = 27. Consider all possible isomeric ketones including
PB stereoisomers of MW = 86 g/mol, All these
PB − PA isomers are independently reacted with NaBH4
(B) Intercept = (NOTE: stereoisomers are also reacted
PB separately). The total number of ketones that give
PA a racemic product(s) is/are.
(C) Slope =
PB
28. At 300 K temperature and 8 atm pressure the
P compressibility factor for a real gas is 0.8. The
(D) Slope = B
PA volume (in litre) of 10 mole of the gas at same
temperature and pressure is? (Round off to the
23. The complex(es) which are paramagnetic in nearest integer)
[Given : R = 0.0821 L-atm mol–1 K–1]
nature is/are:
(A) [Cu(H2O)6]2+ 29. How many of the following will give N2(g) on
(B) [FeF6]3– heating.
(C) [MnF6]3– (NH4)2SO4, NH4NO3, (NH4)2Cr2O7, NH4Cl,
(D) [Fe(CN)6]4– NH4NO2, NH4MnO4.

24. First ionization energy order is CORRECT in: 30. Find the total stereoisomers for:
(A) Sc3+ > Sc2+ > Sc+ (a) [Cr(C2O4)3]3– = x
(B) Sc3+ > Ti4+ > V5+ (b) [PtCl2(en)2]2+ = y
(C) Sc > Y > La (c) [Cr(NH3)2Cl2 (en)]+ = z
(D) Sc > Ca > K Hence write the value of (x + y + z).

[7]
 SECTION-4 32. Overall activation energy of reaction,
Paragraph Type Questions CHCl3 (g) + Cl 2 (g) ⎯⎯→ CCl 4 (g) + HCl(g),
hv
is
Paragraph for question nos. (31-32) ___ kJ/mol.
For the reaction, CHCl3(g) + Cl2(g) ⎯⎯
hv
→ CCl4(g) +
HCl(g) mechanism is given below Paragraph for question nos. (33-34)
k1
Cl2 (g) 2Cl(g)
k −1

CHCl3 (g) + Cl(g) ⎯⎯→

k2
CCl3 (g) + HCl(g)
(i)BH − THF
CCl3 (g) + Cl(g) ⎯⎯
3 → CCl (g)
k ⎯⎯⎯⎯⎯→ 3
(ii)CH COOH
(B) ⎯⎯⎯
Cl2
hv
→ (C) products(s)
4 3 (Monochloro derivative)
Given: 33. Total number of fractions obtained on fractional
k1 = 4.8  103 sec −1 , k −1 = 1.2  103 M −1 sec −1 , distillation of all monochloro derivatives product(s)
k 2 = 1.3 10−2 M −1 sec −1 , k 3 = 2.1  102 M −1 sec −1 (C) is _____?
E a1 = 10 kJ / mol, E a −1 = 15 kJ / mol,
34. The mass of Cl2 required to react with 9.8 gm of
E a 2 = 45kJ / mol, E a3 = 12 kJ / mol
compound (B) to form monochloro product is ___
31. Overall rate constant of reaction, grams. Assuming % yield = 100%
CHCl3 (g) + Cl 2 (g) ⎯⎯
hv
→ CCl 4 (g) + HCl(g), is (Molar mass of Cl = 35.5 g/mol)
____×10–2 M–1/2 sec–1.

PART-III (MATHEMATICS)
SECTION-1
Single Correct Type Questions SECTION-2
35. The complex number z satisfies |2z + 10 + 10i| One or More Than One Correct Type Questions
dy
 5 3 − 5 , then the least principal argument of z 39. Let + y = f ( x) where y is a continuous
dx
is
function of x with y(0) = 1 and
−5 −11
(A) (B) e− x if 0  x  2
6 12 f ( x) =  . Which of the
−2
−3 −2  e if x2
(C) (D)
4 3 following hold(s) good?
(A) y(1) = 2e–1 (B) y’(1) = –e–1
–3
 2 1  (C) y(3) = –2e (D) y’(3) = –2e–3
 x sin  x  − x 
36. The value of lim     is equal to 40. Which of the following is (are) true?
x →  | x|  1 2
 
   sin( x + 2 x + 1)dx −  sin( x ) dx = 0
2 2
(A)
(A) 0 (B) 1 0 1
1 2
(C) 2 (D) 3
e dx − 2 esin(2 x −1) dx = 0
sin x
(B)
0 1
37. Radius of the circle that passes through origin −4 −1
and touches the parabola y2 = 4ax at the point (a,
 sin ( x − 3)dx +  sin( x + 12 x + 33) dx = 0
2 2
(C)
2a) is −5 −2
5 4 1
(A) a (B) 2 2 a
 cos( x )dx − 8 cos(16(2 x − 1) 2 ) dx = 0
2
(D)
2
−4 0
5 3
(C) a (D) a
2 2 41. Given a function 'g' which has a derivative g'(x)
for every real x and satisfied g'(0) = 2 and g (x +
38. If A and B are squares matrices such that A2006 = y) = eyg (x) + exg (y) for all x and y then
0 and AB = A + B, then det(B) = g ( x)
(A) lim =2
(A) 0 x →0 x
(B) 1 (B) g (x) is increasing function xR
(C) 2 (C) g (x) is one-one function x−1,)
(D) 3

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(D) Range of g(x) is  − ,  
2 SECTION-3
 e  Non-Negative Integer Type Questions
42. If the equation x2 + px + q = 0 (p, q ∈ R) and x3 +
3x2 + 5x + 3 = 0 have two roots common, then
the value of (p + q) is

43. If area between the curves y = xex and y = xe–x

and the line x = 1 is λ sq unit, then the value of
128 eλ must be

44. A given quantity of metal is to be casted into

solid half cylinder i.e., with a rectangular base
and semicircular ends in order that the total
surface area is minimum. The ratio of the height
of the cylinder to the diameter of the semi-
circular ends is 𝜋: 𝜋 + 𝑘. Find 𝑘.

45. The distance of point of intersection of

x − 4 y + 3 z +1 x − 1 y + 1 z + 10
= = and = =
1 −4 7 2 −3 8
from (1, –4, 7) is λ. Then [λ] is equal to
(where [] represents g.i.f)

   
46. If the equation 4sin  x +  cos  x − 
 3  6
= a 2 + 3 sin 2 x − cos 2 x has solution then
number of the integral value(s) of a is


 16(2n + 1) 
47. If  =  tan −1   and
 (2n + 1) − 4(2n + 1) + 16 
4 2
n =1
a
sin  = where a, b  N, then find the least
b
value of a2 + b2.

SECTION-4
Paragraph Type Questions
Paragraph for question nos. (48- 49)
(8 5 + 6 2)
100
Let N =
48. The number of irrational terms in the expansion
of N is:

49. Sum of all possible values of r, such that Tr +1

[(r + 1)th term] in the expansion of N is rational,
is:

Paragraph for question nos. (50-51)

Eight players P1, P2, …. P8 play a one on one knock out
tournament, whenever player Pi plays with player Pj,
player Pi will win if i < j. Assuming pairing of players
is random in each round, then
50. The number of ways in which round 1 of the
tournament can be planned is

[9]
 p minimum value of (p + q) is (where p, q ∈ Z)
51. The probability that P4 reach the final is then
q

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