Untitled Document 2024 05 23T141837.430
Untitled Document 2024 05 23T141837.430
to talk about atoms. Atoms are like tiny building blocks that make up everything around us. We'll
learn about how scientists discovered what atoms are made of and how they're put together.
From the earliest ideas about atoms to the modern understanding, we'll cover it all.
By the end of this chapter, you'll have a better understanding of how everything in the world is
made up of these tiny, invisible particles called atoms.
With detailed explanations and illustrative examples, these notes are an invaluable resource to
aid students in mastering the complexities of atomic theory.
Atom
Atoms are the basic units of matter, forming the foundation of all substances in the universe.
Comprising three subatomic particles—protons, neutrons, and electrons—atoms exhibit unique
properties based on their composition. Protons, with a positive charge, and neutrons, which are
neutral, reside in the atom's nucleus, while electrons, negatively charged, orbit around the
nucleus in specific energy levels or shells. This intricate structure enables atoms to interact with
one another, forming the diverse array of elements and compounds observed in nature.
Thomson observed that regardless of the type of gas in the tube or the material of the
electrodes, the particles always moved in the same manner, indicating they were fundamental
constituents of atoms. These particles were later identified as electrons, revealing that atoms
were not indivisible, but composed of smaller subatomic particles. This experiment
revolutionized our understanding of atomic structure and laid the foundation for modern physics.
Electrons
Electrons are fundamental subatomic particles that carry a negative electric charge within an
atom. They are characterized by their negligible mass, denoted as -1 charge, and represented
by the symbol "e⁻". Electrons are exceptionally tiny in size and are located outside the nucleus
of an atom, where they move within specific energy levels or orbitals. These negatively charged
particles play a crucial role in determining the chemical behavior and properties of atoms, as
they participate in various chemical reactions and interactions with other atoms.
Thomson’s Model of an Atom
Thomson's model of an atom, proposed by physicist J.J. Thomson in 1904, is often referred to
as the "plum pudding" model. According to this model, the atom is envisioned as a uniform,
positively charged sphere with negatively charged electrons embedded within it, akin to plums in
a pudding. In this representation, the positive charge is spread out evenly throughout the atom,
while the electrons are scattered throughout the positively charged sphere.
This model implies that the atom has no overall charge and seeks to explain the stability of the
atom despite the presence of negatively charged electrons. However, later discoveries and
experiments led to the refinement of this model, ultimately paving the way for the development
of more accurate atomic models, such as Rutherford's nuclear model and Bohr's planetary
model.
Radioactivity
Radioactivity is a natural process where the unstable nucleus of an atom emits energy in the
form of particles or electromagnetic waves. This phenomenon occurs spontaneously in certain
types of atoms, particularly those with an imbalance of protons and neutrons in their nuclei.
During radioactivity, particles such as alpha particles (consisting of two protons and two
neutrons) or beta particles (electrons or positrons) are emitted from the nucleus. These
emissions help the unstable atom achieve a more stable configuration. Since radioactivity is an
intrinsic property of certain atomic nuclei, it occurs independently of external influences.
Rutherford Model
The Rutherford model, proposed by physicist Ernest Rutherford in 1911, revolutionized the
understanding of atomic structure. In this model, Rutherford suggested that atoms have a dense
central nucleus surrounded by orbiting electrons. The nucleus, which contains positively
charged protons and neutral neutrons, occupies a very small volume compared to the overall
size of the atom.
The electrons, which are negatively charged, orbit the nucleus in fixed paths or orbits, much like
planets orbiting the sun. Rutherford's model also introduced the concept of the atomic number,
representing the number of protons in the nucleus, which determines the identity of the element.
Although the Rutherford model was groundbreaking, it was later refined with the development of
quantum mechanics to explain the behavior of electrons in greater detail.
(iii) The nucleus is remarkably tiny in comparison to the overall size of the atom.
Protons:
Neutrons:
1. Charge: Neutral (no charge).
2. Mass: Approximately equal to that of protons.
3. Location: Also located in the nucleus along with protons.
4. Role: Helps stabilize the nucleus and contributes to the atomic mass.
Bohr’s Model of an Atom: Niels Bohr proposed a model of the atom that addressed some of the
limitations of Rutherford's model. According to Bohr's model:
Bohr's model provided a framework for understanding atomic spectra and the quantized nature
of electron energies, laying the foundation for modern quantum mechanics.
Orbits
Orbits, also known as energy shells or energy levels, are regions around the nucleus of an atom
where electrons are found. These orbits are arranged at different distances from the nucleus
and are designated by letters such as K, L, M, and so on. Each orbit can hold a specific
maximum number of electrons, determined by the formula 2n^2, where 'n' represents the orbit
number.
Electrons fill these orbits in a step-wise manner, starting from the lowest energy level (K shell)
and proceeding to higher energy levels. Orbits play a important role in understanding the
electronic structure of atoms and their chemical behavior.
Electron Distribution in Different Orbits
According to Bohr and Bury, the maximum number of electrons in an orbit is given by the
formula 2n^2, where 'n' represents the orbit number. The shells are filled stepwise, from lower to
higher energy levels, and electrons are not filled in the next shell until previous shells are filled.
Valency
The valency of an atom is determined by the number of electrons in its outermost shell. Atoms
with a completely filled outermost shell exhibit little chemical activity and have a valency of zero.
For example, hydrogen has a valency of 1, while magnesium has a valency of 2.
Atomic Number: The atomic number of an atom is the number of protons present in its nucleus,
denoted by 'Z'. It determines the identity of the element and is unique to each element.
Isotopes:
● Isotopes are atoms of the same element that have the same number of protons (atomic
number) but different numbers of neutrons (and therefore different mass numbers).
● Since isotopes of the same element have the same number of protons, they exhibit
similar chemical properties but may have different physical properties due to variations in
mass.
● For example, carbon-12, carbon-13, and carbon-14 are isotopes of carbon, with the
same number of protons (6) but different numbers of neutrons and different mass
numbers (12, 13, and 14 respectively).
Isobars:
● Isobars are atoms of different elements that have the same mass number (total number
of protons and neutrons) but different atomic numbers (number of protons).
● Isobars have different chemical properties since they belong to different elements with
different numbers of protons and electrons.
● For example, calcium-40 and argon-40 are isobars, both having a mass number of 40
but different atomic numbers (20 for calcium and 18 for argon).
Determine the isotopes present and their respective percentages or relative abundances. For
example, consider an element like carbon, which has two common isotopes: carbon-12 (with a
natural abundance of about 98.9%) and carbon-13 (with a natural abundance of about 1.1%).
Convert the percentages to decimals by dividing by 100. For example, 98.9% becomes 0.989
and 1.1% becomes 0.011.
Multiply each isotope's relative abundance by its mass number. For carbon-12, the calculation
would be 12 * 0.989 = 11.868, and for carbon-13, it would be 13 * 0.011 = 0.143.
Add the results of these calculations together to find the average mass number. For carbon, the
calculation would be 11.868 + 0.143 = 12.011.
So, the calculated mass number for carbon, considering its isotopes carbon-12 and carbon-13,
would be approximately 12.011 atomic mass units (u).