Phenolic Functional Group
Phenolic Functional Group
Materials required –
Test tubes, test tube stand, dropper, blue litmus solution, neutral
ferric chloride solution, crystals of sodium nitrite, concentrated
sulphuric acid solution, sodium hydroxide solution, beaker, etc.
Observation table –
S.No. Experiment Observation Inference
1 Litmus test –
Added a few drops of blue Red Phenolic
litmus solution to given colouration is group may
organic compound in a test observed. be present.
tube.
2 Neutral FeCl3 test –
To 1 ml of the given organic Violet Phenolic
sample in a test tube colouration is group is
added 1 ml of neutral observed. present.
FeCl3.
3 Liebermann’s test –
(i) Place 2-3 crystals of A deep blue or
sodium nitrite in a clean deep green
dry test-tube and add colouration
about 1 g of organic develops.
sample. Heat very gently
for half a minute and allow
it to cool. Then add about
1 ml of concentrated
sulphuric acid and shake
the tube to mix the
contents.
Result –
The given organic compound contains phenolic (Ar-OH) functional
group.
Precautions –
1. Use chemicals very carefully.
2. Use clean apparatus only.