QUIZ (CHEMISTRY)

GASE OUS STATE

NAME: M.MARKS: M.Time: minutes
SUB:CHEMISTRY
Single Correct Option Questions

1 Aclosed vesscl contains helium and oz0ne at a pressure of P atm. The ratio of He and oxygen
atoms is 1:1.1fhelium is removed from the vesscl, thc pressure of the system will reduce to0?
(A) 0.5 P atm (B) 0.75 P atm
(C) 0.25 Patm (D)0.33 P atm
2. The reciprocalof compressibility factor of a real gas in the critical state is
(A) 3/8 (B) 3/4
(C) 8/3 (D) 1/3
3 Consider the reaction: 2X(g)+3Y(g) Z(g) where gases X and Y are insoluble and inert to
water and Z fornms a basic solution. In an experiment, 3 mol cach of Xand Yare allowed to react in
15 L flask at 500 K. When the reaction is complete, 5L of water is added to the flask and the
temperature is reduced to 300 K. The pressure in the flask is (neglect aqucous tension)
(A) 1.64 atm (B) 2.46 atm
(C) 4.92 atm (D) 3.28 atm

4 There are 100 persons sitting at equal distances in a row XY. N,O gas (laughing gas) is released
from the side X and tear gas (molecular mass = 176) from side Y at the same moment and at the
same pressure. The person who will have a tendency to laugh and weep simultaneously is
(A) 34th from side X (B) 67h from side X
(C) 76th from side X (D) 67th from side Y
5 In the figure shown the pressure of the confined gas will be

P. = 76 cm of Hg P =?

p=1gm /cm 13.6 cm

p = 3.4 gm/cm 20 cm

30 cm
p= 6.8 gm/cm

15 cm

Hg

(A) 30 cm of Hg (B) 40 cm of Hg
(C) 36 cm of Hg (D) 46 cm of Hg
6 A 5.00 Levacuated cylinder is charged with 25.5 g of NH3 and 36.5 g of HCI. Calculate the final
pressure at 85.0°C after the two compounds have reacted completely:
NH, (g) +HCI(g) ’NH,CI(s)
(A) 2.94 atm (B) 5.88 atm
(C) 8.82 atm (D) 14.7 atm
7 Ax:1 molar mixture of He and CH4 is contained in a vessel at 20 bar pressure.Due to ahole in
the vessel, the gas mixture leaks out. If the composition of the mixture effusing out initially is 8:1,
then calculate the value of x?
(A) 1 (B) 4
(C) 8 (D) 9
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 QUIZ (CHEMISTRY)
Which of the following statement is incorrect?
3. IA) At critical point minimum pressure required for liquefaction is called critical pressure
IB) At temperature higher than critical temperature due to very high kinetic energy of gas
molecules liquefaction cannot be possible at any pressure
8
(C) Tc and TB related as T = 27 T, for a real gas
more than critical temperature, then
(D) If gaseous state ofa substance is present at temperature
the substance is known as vapour.
Another sample of O, at 27°C has a
9 The kinetic energy of N molecules of O) is x joule at -123°C. molecules of O,
kinetic energy of 2x. The latter sample contains
(A) N (B) N/2
(C) 2N (D) 3N
gas is increased by a factor of 1.5, by what
ratio does the
10. If the absolute temperature of a sample ofincrease?
average molecular speed of its molecules
(B) 1.5
(A) 1.2
(C) 2.2 (D) 3.0
atmn and 200 K.
pressure is compressed to a pressure of 600
11. One litre gas at 400 K and 300 atm respectively. Calculate the final volume of the
to 1.6
Thecompressibility factor is changed form 1.2
gas (B) 2/3 litre
(A) 2 litre
(C) 1/3 litre (D) 4/3 litre
volume of helium,
vessel of volume V litre, at T K. If V; is free
12. n moles of helium gas are placed in a
then diameter of He atom is
¬1/3 3(V-V)"3
3 V, (B)
(A) 27tN,n
2zN,n
¬1/3 q1/3
6(V -v,)] (D)
(C) aN,n
zN,n
Critical constants for a real gas are given as
13.
Tc = 180 K; Ve = 0.123 1L/mole; Pc = 45 atm;
The correct statement for the real gas is
0.123x 10-3
(A) The actual volume of single gas
molecule is
6.023 x 1023
cc

(B) b = 3x 0.1231 L moll

(C) The Boyle's temperature is less than 180 K
(D) Gas cannot be liquefied at 200 K
correct?
14. At critical temperature which of the following graph is
(A) (B)

PV
PV

P ’
P

(C) (D)

PV PV

P P

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 (CHEMISTRY)
gases,A and B with molecular masses MA and MB, it is observed that a certain
For twomean
Tthe velocity of Ais equal to the root mean square velocity of EB. Thus the mean temperature
velocity of A
5 mean velocity of B. if
the
oan be made equal to
temperature T, and B at T', T > T'
A) Ais at temperature T2 < T while B is at
T
D Ais lowered to a temperature
raised to a higher
iC both Aand B are
placed at lower temperature
iD) both A and B are
Options Questions
saltiple Correct could be
g of a gas occupies 224 mL at STP. The gas
16
0.28 (B) CO
(A) N2 (D) N,O4
(C) CoH4 absolute
energy of an ideal gas (X) is directly proportional to
Knowing that average kinetic statement (s) describe (s) the other curves?
17.
temperature,
molecules
of which
if T; = 273 K,

velocit

given
Fraction
a
at P

Velocity
temperature
(A) Curve A is for heavier gas but at same
same gas but at 373 K
(B) Curve B is for the
gas but at 373 K
(C) Curve A is for the same
(D) Curve B is for lighter gas but at same temperature
gas?
prediction regardinga van der Waal's
18 Which of the following are wrongcritical temperature
high
(A) A gas with large 'a' hasmore compressible
(B) A gas with large b' is critical pressure
(C) A gas with large b' has highliquefiable
(D) A gas with large 'a' is easily
is/are
19 The incorrect statement/s)
On increasing pressure, rms increases
(A)
average kinetic energy decreases
(B) On decreasing temperature, inversion temperature, cooling effect is observed
(C) On expan sion of a gas above
correct order of molecular speeds for a gas is
(D) The
Ums > Uavg > Umps
following:
20. Select the correct statements of the very low temperature and applying a
very high
can be liquefied by cooling it to a
(A) Ideal gas
pressure
characteristic temperature and compressing
(B) Helium can be liquefied by cooling it to a through an orifice
(C) Atordinary temperatures compressed helium gas get heated up when passed
conditions
into vacuum under adiabatic
compressible than an ideal gas
(D) At ordinary temperatures hydrogen is less
21. According to kinetic theory of gases:
(A) collisions are always elastic
momentum to the wall of the container
(B) heavier molecules transfer more
high velocity
(C) only a small number of molecules have very straight lines with constant velocities
(D) between collisions, the molecules move in

22. Select the correct option (s) for an ideal gas. temperature
(A) Most probable speed increases with increase in
(B) Fraction of particles moving with most probable speed increases with increase in temperature
(C) Fraction of particles moving with most probable speed are more for Clb than HT under similar
conditions of T, Pand V
(D) Most probable speed is more for Cl, than H2 at same
temperature

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 QUIZ (CHEMISTRY)
tube of negligible volume, container (|) has Na(g) gas at a
containers are connected by a
Two (I) has 1 litre H,O(0) at temperature (T)
23. temperature T (K) and container
pressure 4 atm and removed. (aqucous tension 190 torr)
option (s) after stopcock is
initially. Find correct
(0) ()

H,O(g)
N, (9)
1litre H,0()
4 litre
3 litre
(B) Total pressure 2.25 atn
atm 0.25 atm
(A) Pressure of N) = 2.0 (D) Pressure of H,O(g) is
195 atm
(C) Total pressure =
constant 'a' is given by
24. The van der Waal's gas
(B) 3P, V
(A
27 R°T
1RT, (D)
(C) 64 P.
8P. kinetic
which of the following will have same translational
and pressure,
25. At the same temperature
N,0?
energy per mole as (B) H)S
(A) He (D) NO,
(C) CO:

Digital Integer Type Questions

atm, then critical
conditions molar volume of gas is 8.21 L at 3
26. For a real gas, if at critical
temperature (in K) will be.
Hg. If
to 100 K and 760 mm of
flask containing air at 107°Cand 722 mm of Hg is cooled
27. A flexible 1.0 g/cc the final density is.
density in the initial condition was
increases by X%. X is.
heated to 109 K, the pressure
28. If an ideal gas at 100 K is
vapour effuses
substance at 1.0 atm and 500 K is 0.36 kg/m3, The What is
29. The density of a vapour of a 1.33 times faster than oxygen under similar conditions.
through a small hole at a rate of
vapour.
the compression factor (Z) of the
pressure correction factor for two
moles of gas
equation of state, calculate the
30. Using van der Waal's pressure of 11 atm at 300 K. (b = 0.05
L mol )
confined in a four litre flask that exerts a

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QUIZ (CHEMISTRY)
ANSWERS
GASEOUS STATE
1 C 2 C 3 B 4. A

5 B 6. A 7 B 8 D

9. A 10. A 11. 12. B

13. D 14. 15. B 16. A, B, C

17. A, B, D 18. B, C 19. A, C 20. B, C, D

21. A, C, D 22. A, C 23. A, B, D 24. B, D

25. A, B, C, D 26. 800.00 27. 4.0 28. 9.00

29. 01.22 30. 1.61

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