M.Sc. Prospectus No.

2015125
Sem-I to IV(Chemistry)
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PROSPECTUS
OF
MASTER OF SCIENCE EXAMINATION
IN
CHEMISTRY
Semester -I & III, Winter 2014,
Semester -II & IV, Summer 2015,

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 INDEX XII Special Paper-II
Physical Chemistry
41

M.Sc.Part-I & Part-II (Semester I to IV) Examinations in Chemistry XI Special Paper-I 43

(Prospectus No.2015125) Industrial Chemistry (Heat Transfer, Unit
Operations and Material Balances)
Sr.No. Paper Page Nos. XII Special Paper-II 45
Industrial Chemistry (Processes Economics
1. Special Note 1 And Industrial Management)
2. Ordinance No.4 of 2008 3 XI Special Paper-I 46
3. Direction No.14 of 2009 12 Analytical Chemistry (Adv.Seperation Tech.)
4. Direction No.26 of 2010 14 XII Special Paper-II
5. Direction No.27 of 2010 37 Analytical Chemistry (Recent Advances in 49
6. Direction No.39 of 2011 40 Analytical Chemistry)
7. Direction No.25 of 2012 42 13. Semester IV
8. Direction No. 7 of 2014 46 XIII Spectroscopy-II 54
9. Direction No. 8 of 2014 47 XIV General Analytical Chemistry 57
XV Special Paper-III 59
Inorganic Chemistry (Photoinorganic &
10. Semester I
Organometallic Chemistry)
I Inorganic Chemistry 1 XVI Special Paper-IV 61
II Organic Chemistry 3 Inorganic Chemistry (Materials Chemistry)
III Physical Chemistry-I 6 XV Special Paper-III 63
IV Modern Methods of Separation 8 Organic Chemistry (Organic Synthesis: II)
11. Semester II XVI Organic Chemistry (Natural Product-II) 64
V Co-ordination Chemistry 14 XV Special Paper-III 67
VI Organic Chemistry-II 16 Physical Chemistry
VII Physical Chemistry-II 19 XVI Special Paper-IV 68
VIII Optical Methods and Environmental Chemistry 20 Physical Chemistry
12. Semester III XV Special Paper-III 69
IX Spectroscopy-I 26 (Unit Processes) Industrial Chemistry
X Analytical Chemistry-I 29 XVI Special Paper-IV 72
XI Special Paper-I 31 (Chemical Processes Industries)
Inorganic Chemistry (Bio-inorganic Chemistry) Industrial Chemistry
XII Special Paper-II 33 XV Special Paper-III 75
Inorganic Chemistry (Solid State Chemistry) Analytical Chemistry
XI Special Paper-I 36 (Analysis of Commercial Products)
Organic Chemistry (Organic Synthesis-I) XVI Special Paper-IV 78
XII Special Paper-II 38 Analytical Chemistry
Organic Chemistry (Natural Product-I) (Applied Analytical Chemistry)
XI Special Paper-I 40
Physical Chemistry
 1 2
Syllabus Prescribed for M.Sc.Part-I, Semester-I (Chemistry) Unit-III Metalic Cluster: 12L
Paper-I Boron hydrides: Classification, nomenclature, structure,
Inorganic Chemistry bonding and topology of boranes, 4-digit coding (s, t, y, x)
60hrs (4hrs/week). 12hrs/unit 50 Marks numbers for B2H6,B4H10,B5H9,B5H11 and B6H10 and their
Unit-I A) Stereochemistry and Bonding in Main Group Compound. utilities. Chemistry of diboranes. Acquaintance with
6L metalloboranes, Carboranes and Metallocarboranes.Metal
VSEPER-Shape of simple inorganic molecules and ions clusters: Occurrence of metal-metal bonds, binuclear,
containing lone pairs, Various stereochemical rules and trinuclear, tetranuclear, and octahedral clusters. Synthesis,
resultant geometry of the compounds of non-transitional properties and bonding, of carbides, sulphur-nitrogen
elements, Short coming of VSEPR model. Bent rule and compounds, peroxo compound of boron, carbon and
energetic of hybridization, some simple reaction of sulphur, oxy acids of nitrogen, Isopoly and Heteropoly
covalently bonded molecules, d-orbital participation by non- acids.
metal. Unit-IV A) Non-aqueous solvent behavior 6L
B) Molecular Orbital Theory: 6L Inorganic solutes in organic solvents. Solvent system
Molecular orbital representation of polyatomic molecules concept. The role of solvents in chemical reactions, effect
with special reference to C2H4.C2H6 and CO and delocalised of physical and chemical properties. Inorganic reactions in
molecular orbital of ozone, Carbon dioxide, Nitrite, Nitrate the following non-aqueous solvents: Dinitrogen tetroxide,
and Benzene. anhydrous sulphuric acid, bromine trifluride and reaction
in molten salts.
Unit-II 6L
B) Metal-Ligand equilibria in solution: 6L
A) Metal ligand Bonding: Splitting of d-orbital in low symmetry
environments, Structural effects of orbital splitting. Jahn- Stability of complex ions in solution. Basic principles,
Teller effects, tetragonally distorted octahedral complexes. Mathematical function and their interrelationship, trends
Jahn-Teller distortion in chelate complexes. Thermodynamic in stepwise constant, factors affecting the stability of metal
effects, crystal field stabilization energies (CFSE's) for complexes with reference to the nature of metal ion and
octahedral and tetrahedral complexes, correlation of crystal ligand, statistical, electrostatics, chelate effect and its
field stabilization energy with the related thermodynamic Thermodynamic origin (DG,DS,DH). Uses of stability
properties such as lattice energies, enthalpies of hydration, constants in analytical chemistry, resoluting of
formation constants, stabilization of unusual oxidation enantiomorphs. Determination of stability constants by
states and ionization energies, structure of mineral spinels. spectrophotometric methods (Job’s and Mole ratio),
Limitations of crystal field theory. Bjerrum’s pH metric method, polarographic method and
B) Magnetochemistry 6L Conductometric method.
Concept of magnetic susceptibility, types of magnetic Unit -V Symmetry and Group theory 12L
bodies, Magnetic properties of free ions and transition metal Symmetry elements and symmetry operations, symmetry
complexes of different geometries, factors affecting the groups or point groups. Schoenflies symbols, point group
magnetic properties, orbital splitting and magnetic classification, matrix representation of symmetry operations,
properties, quenching of orbital angular momentum, and identification of point groups (Cn/Cnv/Cnh/Dnh/Td, Oh etc),
effect of ligand field on spin-orbit coupling. Temperature necessary conditions for any set of elements to form a group,
dependence of paramagnetism, High spin-low spin subgroups, classes in a group, and representation of
crossover, spin crossover in coordination compounds, spin groups. The great orthogonality theorem (without proof)
equilibria, magnetic interactions, ferromagnetism and and its importance. Derivation of character tables for C2v,
antiferromagnetism. Anomalous magnetic moments and C 3 v points groups (construction not required),
magnetic exchange coupling. Magnetic properties of representation reducible and irreducible, and analysis of
polynuclear complexes. reducible representation.
 3 4
List of Books Aromaticity in benzenoid and non-benzenoid compounds,
1) S. F. A. Kettle, J. N. Murral & S. T. Teddler: Valency Theory alternant and non-alternat hydrocarbons Huckel’s rule,
2) C. A. Coulson: Valency energy level of pi-molecules orbitals, annulenes, anti-
3) J. E. Huheey :Inorganic Chemistry aromaticity, homo-aromoaticity. Aromatic character and
4) F .A. Cotton& G. Wilkinson: Advanced Inorganic Chemistry 3rd, 5th chemistry of cyclopentadiene anion, tropyllium cation,
& 6th Editions. tropene and tropelene.
5) A. F. Willims: Theoretical Approach in inorganic chemistry. Unit-II : Streochemistry 12L
6) A. Mannas Chanda: Atomic Structure and chemical Bonding Conformational analysis of cycloalkanes ( 5 – 8 membered
rings), decalines, effect of conformation on reactivity, steric
7) L. E. Orgel: An Introduction To transition metal chemistry, Ligand
strain due to unavoidable crowding.
field theory, 2nd Edition.
Elements of symmetry, chirality, molecules with more than
8) J. J. Logowski: Modern Inorganic Chemistry
one chiral center, threo and erythro isomers, method of
9) B.Durrant and P.J.Durrant: Advanced Inorganic Chemistry
resolution, optical purity, enantiotopic and distereotopic
10) J. C. Bailar: Chemistry of co-ordination compounds. atoms, groups and faces, stereospecific and steroselective
11) W. L. Jolly: Modern Inorganic Chemistry synthesis.
12) R. S. Drago: Physical methods in inorganic chemistry. Asymmetrical synthesis, optical activity in absence of chiral
13) Waddington: Nonaqueous solvents. carbon ( biphenyl, allenes and spiranes). Stereochemistry
14) Sisler: Chemistry of nonaqueous solvents. of the compounds containing N, P and Sulphur.
15) A. K. Barnard: Therotical Inorganic Chemistry Unit-III : Reaction mechanism: Structure and Reactivity 12L
16) Emeleus and Sharpe: Modern Aspect of Inorganic Chemistry. Types of mechanism, Types of reaction, thermodynamics
17) F. A. Cotton: Chemical Applications of Group theory. and kinetics requirements, kinetic and thermodynamic
18) Jones: Elementary Co-ordination chemistry. control, Hammond’s postulate, Curtin-Hammeett principle.
19) B. N. Figgis: Introduction to Ligand field. Potential energy diagrams, transition states and
20) S. F. A. Kettle: Co-ordination chemistry. intermediates, methods of determining mechanisms, isotope
21) M.C.Day and J.Selbin: Theoretical Inorganic Chemistry. effects.
22) J. Lewin and Wilkins: Modern Co-ordination chemistry. Effect of Structure on reactivity:-
23) Gowarikar, Vishwanathan and Sheedar: Polymer science. Resonance and field effects, Steric effect, quantitative
treatment. The Hammett equation and linear free energy
24) H. H. Jattey and M. Orchin: Symmetry in chemistry.
relationship, substituent and reaction constants. Taft
25) D. Schonaland: Molecular Symmetry in chemistry.
equation.
26) L. H. Hall: Group theory and Symmetry in chemistry
Unit-IV : A) reactive Intermediates: 12L
27) H. H. Jattey and M. Orchin: Symmetry in chemistry
Classical and non-classical carbocations, Carbanions,
28) R.L.Dutta and A.Symal: Elements of magneto chemistry radical anions and radical cations, Carbenes, nitrenes and
29) Inorganic Chemistry 4th Edition, P.Atkins, Oxford University Press. arynes. General methods of generation , detection and
30) Essential Trends in Inorganic Chemistry, D.M.P.Mingos, Oxford reactivity of these intermediates. Singlet oxygen, it’s
University Press generation and reactions with organic substrates.
Semester –I B) Aliphatic nucleophilic substitution:
Paper-II The SN1, SN2, mixed SN1, SN2 and SET and SNi mechanisms.
Organic Chemistry Nucleophilicty, effect of leaving group, ambient
60hrs (4hrs/week). 12hrs/unit 50 Marks nucleophiles and ambient substrates regiospeciticity. The
neighbouring group. Participation mechanisum,
Unit-I: Nature and Bonding in Organic Molecule 12L
substitution at allylic and vinylic carbon atoms.
Delocalized chemical bonding, conjugation, cross-
conjugation, resonance, hyper-conjugation, bonding in
fullerenes.
 5 6
Dehydration using DCC, Meyllers synthesis of aldehydes, 19. Modern organic chemistry- J.D. Roberts and M. C. Caserio.
ketones and acids. 20. The search for organic reaction pathways (Longmann), Peter Skyes.
Unit-V : A) Aromatic Nucleophilic Substitution 12L 21. Organic chemistry 5th Edition (McGraw Hill), Pine.
A general introduction to different mechanisms of aromatic 22. Organic chemistry (Willard Grant Press Botcon), John Mcmurry.
nucleophilic substitution SNAr, SN1, Benzyne and SRN1 23. A Textbook of organic chemistry- R.K. Bansal.
mechanisms. 24. New trends in green chemistry –V.K. Ahluwalia & M. kidwai,
Reactivity effect of substrate structure leaving group and Anamaya publishers New Delhi.
attacking nucleophile. The Von Richter, Sommlet-Hauser 25. Oranic Chemistry, J.Clayden, Oxford University Press.
and Smiles rearrangements. 26. Organic Chemistry, 4th Edition, G Marc Loudon, Oxford University
B) Elimination Reactions: Press.
The E1, E2 and E1CB mechanisms orientation of the double
bond. Saytzeff and Hoffman’s rule. Effect of substrate Semester I
structure, attacking base, leaving group and medium. Paper- III
Pyrolytic elimination mechanism and orientation. Cleavage Physical Chemistry-I
of quaternary ammonium salts. Conversion of vicinal
dihalides and nitro compounds to alkenes. 60 Hours (4-Hours/week) 50 Marks 12 hours/Unit
BOOK SUGGESTED- Unit-I Quantum Chemistry:
1. Advanced organic chemistry –Reaction mechanism and structure. A) Discussion of solutions of Schrodinger equation to some
Jerry March, John Wiley. model systems viz., Particle in a three dimensional box,
Harmonic oscillator, Rigid rotor. The variation theorem, linear
2. Advanced organic chemistry- F.A. Carey and R.J. Sunberg, Plenum.
variation principle. Perturbation theory (first order & non
3. A Guidebook to mechanism in organic chemistry-Peterskyes,
degenerate). Application of variation method & perturbation
Longman.
theory to the Helium atom. 6L.
4. Structure and mechanism in organic chemistry-C.K. Gold, Cornell
B) Ordinary angular momentum, generalized angular
University Press.
momentum, eigen functions for angular momentum, eigen
5. Organic chemistry, R.T. Morrison Boyd. Prentice Hall value of angular momentum. Pauli exclusion principle.
6. Modern organic chemistry-H.O. House, Benjamin. Russell-Saunders terms and coupling schemes, Slater-
7. Principal of organic chemistry-R.O.C. Norman and J.M. Coxon, Condon parameters, spin-orbit coupling and Zeeman
Blackie Academic and Professional. splitting. Numericals. 6L.
8. Reaction mechanism in organic chemistry-S.M. Mukharji and S.P. Unit-II Surface Chemistry :
Singh, Macmilan. A) Adsorption: Freundlich adsorption isotherm, Langmuir
9. Stereochemistry of organic compounds- D. Nasipuri, New age adsorption isotherm, Gibbs adsorption isotherm, estimation
international. of surface area (BET equation), surface films on liquids,
10. Stereochemistry of organic compounds- P.s.kalsi, New age and catalytic activity at surfaces. 6L
international. B) Micelles: micellization, hydrophobic interaction, critical
11. Frontier orbitals and organic chemical reactions-I. Fleming. micellar concentration (CMC), factors affecting the CMC
12. Orbital Symmetry – R.E.Lehr & A.P. Marchand. of surfactants, counter ion binding to micelles,
13. Reactive intermediate in organic chemistry-N. S. Isaacs. thermodynamics of micellization-phase separation & mass
14. Stereochemistry of carbon compounds- E.L.Eliel. models, solubilization, micro emulsion, reverse micelles.
15. Physical organic chemistry-J. Hine. Numericals. 6L.
16. Name reaction in organic chemistry –Surrey. Unit-III Thermodynamics
17. Advanced organic chemistry – L.F.Fieser and M. Fieser. A) Classical Thermodynamics: Partial molar properties. Partial
18. Vol.I & II organic chemistry - I. L. Finar. molar free energy, Chemical Potential, Partial molar volume
 7 8
and Partial molar heat content and their significances. 5) Statistical thermodynamics, by T.L.Hill, Addison Wesley, 1060
Determination of these quantities. Concept of fugacity and 6) Chemical thermodynamics, by F.T.Wall, W.H.Freeman & Co. 1965
determination of fugacity. 7) Irreversible thermodynamics, Theory and applications, by
Non-ideal systems: Activity, Activity coefficients, Debye- K.S.Forland, T. Forland, S.K.Ratje, Jonny Wiley, 1988.
Huckel theory for Activity coefficient of electrolytic 8) Chemical Kinetics,by K.J.Laidler, 3rd Edition, Harper and row, 1987.
solutions; Determination of Activity & Activity coefficients; 9) Chemical Kinetics-A study of reaction rate in solution, K.Conors,
ionic strength.. 6L. V.C.H.Publication 1990.
B) Non equilibrium Thermodynamics: Thermodynamic criteria 10) Chemical Kinetics and Dynamics, By J.I.Streinfeld, J.S. Francisco
for non-equilibrium states, entropy production and entropy & W.I.Hase, Pritice Hall, 1989.
flow for different irreversible processes (e.g. heat flow, 11) Kinetics and Mechanism of Chemical transformation, J.Rajraman,
chemical reaction, coupled reactions and electrochemical J. Kucriacose, Mc-Million
reactions.) Transformations of the generalized fluxes and
12) Molecular reaction Dynamics and chemical reactivity, R.D.Levine
forces, phenomenological equations. Microscopic
and R.B. Benstin, Oxford University press. 1987.
reversibility and Onsager’s reciprocity relation. Numericals.
13) Physical Chemistry by Alberty and Silby, Jolly Wiley
6L.
14) Essential of Quantum Chemistry by Anant Raman.
Unit-IV Nuclear chemistry:
15) Introduction to Relativistic Quantum Chemistry, K.G.Dyall, Oxford
A) Properties of Nucleons & Nuclei: Nuclear size and shape,
University Press.
mechanical effects due to orbiting and spinning of Nucleons,
magnetic quantum numbers, Principal and radial quantum 16) Molecular Quantum Mechanics, 4th Edition, P.W.Atkins, Oxford
numbers, Total angular momentum of the nucleus, Magnetic University Press
properties of the nucleus. Net magnetic moments of the Semester I
nuclei. Numericals. 6L. PAPER-IV
B) Nuclear models: Liquid drop model, shell model, Fermi gas Modern Methods of Separation
model, collective model and optical model. 6L.
60hrs(4hrs/week), 12hrs/Unit 50 Marks
Unit-V Chemical Dynamics:
Unit-I 12L
A) Theories of reaction rates: Collision theory, collision rates Role of Analytical Chemistry: Classification of analytical
in gases, energy requirement and steric requirement. methods-classical & instrumental. Types of instrumental
Dynamics of molecular collisions. Transition state theory: analysis. Selecting an analytical method. Laboratory
assumptions, Statistical Mechanics and chemical
Operations and practices. Analytical balances (Semi micro
equilibrium, derivations of Eyring equation, Application of
and Micro balances) and their use in analytical chemistry.
transition state theory to reaction between atoms and
Techniques of weighing and errors. Volumetric glassware
molecules (e.g. The reaction H + HBr ®H2+Br ) 6L.
cleaning and calibration of glassware. Principal and
B) Unimolecular reactions: Lindemann-Christiansen
Methods of sampling, theory of sampling, pit falls and
hypothesis and Hinshelwood treatment, Marcus’s extension
problems associated with sampling. Techniques of sampling
of the RRK treatment. 3L.
of gases, liquids, solids and particulates. Stoichiometric
C) Reactions in solution: Solvent effect on reaction rate, calculations based on gravimetry and titrimetry analysis of
Factors determining reaction rate. Numericals. 3L. commercial samples. Transmission and storage of samples.
List of Books : Effect of sampling uncertainties samplers’ responsibility,
1) Physical chemistry by P.W.Atkins & dePaula 7Th Edition sampling hazards.
2) Introduction to Quantum chemistry by A.K.Chandra, Tata Mc
3) Quantum chemistry by Ira N. Levine.
4) Molecular quantum mechanics, Vol. I & II, P.W. Atkins, Oxford
university presss, 1970.
 9 10
Unit-II 12L Extraction equilibria. Quantitative treatment of solvent
Statistical Analysis: (Emphasis should be placed on extraction. Synergetic effects, ion-pair extraction, salting
numerical problems) Collection, Treatment and presentation out effect and stripping. Techniques in extraction,
of analytical data. True, standard and observed value. application of diketone, hydroxyquinoline, oximes,
Defination of terms in mean and median. Errors in chemical dithiocarbamets, xanthets, thiols, high molecular weight
analysis, classification of errors, nature and origin of errors. amines i.e. crown ethers, cryptands and calixarenes.
Accuracy and precision. Average deviation and standard Advantages, applications of synergistic extraction.
deviation and its physical significance. Normal distribution Separation of nonmetals and metals.
curve and its properties. Coefficient of variation. Confidence
List of Books.
limit and probability. Probability theorem, probability
curves, comparison of analytical results. Tests for rejection 1. Analytical chemistry- Problems and Solution- S. M. Khopkar, New
of data. T-test, F-test and Q-test. Significant figures and Age International Publication.
computation rules. Least squares method for deriving 2. Day & Underwood: Quantitative Analysis.
calibration graph. Curve fitting, Correlation co-efficient. Limit 3. Findley: Practical Physical Chemistry:
of detection. Regression analysis and Statistical analysis 4. A. I. Vogel A Text book of Quantitative Inorganic Chemistry, ELBS,
of Chemical analysis. London.
Unit-III Modern method of separation: 12L 5. Strouts Galfillal: Analytical chemistry
Chromatography: General principles and Classification of 6. Y. Lyalikov: Physocochemical Analysis
various techniques. Study of following chromatographic 7. S. Wilson & P. Jones: Chemical Analysis Vol I
techniques: Partition Chromatography, Liquid-Liquid 8. Meites and Thomas: Advance Analytical Chemistry. (Mc Graw
Chromatography, Reverse Phase chromatography. Hill)
Adsorption chromatography. Principles, Techniques and 9. H.H.Willard ,L.L.Merritt and J.A.Dean: Instrumental Methods of
applications of paper, Thin-layer, column, HPLC, Gas Analysis (Van Nostrand).
Chromatography, size exclusion chromatography and 10. B. L. Krayer, H. H. Willard. L. Merrit, J. A. Dean & F. A. Settle:
Electro chromatography. Instrumental Methods of Analysis (CBS Publishers, Delhi, 1986)
Unit-IV Ion exchange 12L 11. R. D. Brown Instrumental Methods of Chemical Analysis (Mc Graw
Ion-Exchange Separation: Fundamental properties of ion Hill)
exchangers. Theory of ion exchange, exchange capacity, 12. L. R. Shyder & C. H. Harvath: An Introduction to Separation Science
screening effect, penetration of electrolytes into ion (Wiley Interscience)
exchange resins, sorption of complex ions Cation and Anion 13. F. J. Wicher Robert: Standard Methods Chemical Analysis.
exchangers, Action of ion exchange resins. Ion-exchange
14. G. L. Davis Krupadanam, D. Vijaya Prasad, K. Varaprasad Rao,
equilibria and ion exchange capacity. Strongly and weakly
KLN Reddy, C. Sudhakar, Analytical Chemistry.
acidic cation exchangers. Strongly and weakly basic anion
15. S. M. Khopkar Analytical Chemistry of Macrocyclic and
exchangers. Liquid ion exchangers, chelation ion
supramolecular and compounds, Narosa publication.
exchangers, techniques of ion exchange, use of non
aqueous solvents in one exchange separation, application 16. R. D. Budhiraja Separation Chemistry, New Age.
of ion exchange separation in determination of total salt 17. Kaushik & Kaushik Perspectives in Environmental Studies, New
concentration, removal of interfering ions, separation of Age
anions and metals and application in analytical chemistry. 18. R.L.Peesok and L.D.Shield: Modern Methods of Chemical Analysis.
Seperation using solvent mixture. 19. Data Analysis for Chemistry, D.B.Hibbert, Oxford University Press.
Unit-V Solvent Extraction 12L 20. Analytical Chemistry, S.P.J. Higson, , Oxford University Press
Solvent Extraction: Basic principles, Classification,
Mechanism of extraction. Multiple extration.significance of
various terms factors favouring solvent extraction,
 11 12
Semester I (3) Record -10 Marks
Organic Chemistry Practical-I (4) Viva-Voce -10 Marks
Total Hours: 90 hrs. (9 Hours per week) Marks: 100
Semester I
Unit-I Organic Synthesis
Practical II
Student is expected to carry out minimum of 8-10 organic
preparation (involving two steps) from the following lists. Physical Chemistry
1. Preparation of Benzanilide from Benzophenone.
2. Preparation of p- nitroaniline from Acetanilide. Total Hours: 90 hrs. 9 Hours per week
Time: 6 – 8 hrs. Marks: 50
3. Preparation of p-Bromoaniline from Acetanilide.
Use of Computer Programs 5 terms of practicals :
4. Preparation of m-nitroaniline from Nitrobenzene.
5. Preparation of p-Chlorotoulene from p-Toluidine. Treatment of experimental data, X-Y plots, programs with data
preferably from physical chemistry practicals. Students will operate two
6. Preparation of p- nitrobenzoic acid from p-Nitrotoulene.
packages I) MS-Word and II) MS-Excel.
7. Cannizzaro’s reaction with 4-Cholobenzaldehyde as a
Part –A
substrate.
1) To study the surface tension-concentration relationship for
8. Preparation of 2-Phenylindole (Fischer-Indole synthesis).
solution and determination of surface excess concentration by
9. Claisen – Schmidt: Dibenzal acetone from benzaldyde. using Gibbs’ adsorption equation.
10. Preparation of Anthranilic acid. (Hoffman’s bromamide 2) To find out the molecular surface energy and the association factor
reaction). of ethyl alcohol.
11. Diels –Alder reaction: Anthracene + Maleic anhydride. 4) To compare the cleansing power of two samples of detergent by
12. Methyl –orange from Sulphanilic acid. surface tension method.
13. Hydroquinone to 2,5-Dihydroxyacetophenone. 5) To study the effect of concentration of an electrolyte (KCl, NaCl)
14. Chlorobenzene to 2,4- Dinitrophenylhydrazine. on solubility of an organic acid.
15. Nitrobenzene to p- Aminophenol. 6) To study the kinetics of iodine clock reaction.
UNIT-II Quantitative Analysis 7) To study the reaction between acetone & iodine in presence of
Student is expected to carry out following estimations (minimum acids.
6 estimations.) 8) To study the decomposition of hydrogen peroxide catalyzed by
1. Estimation of Vitamin “C” Iodometry. iodine ion.
2. Estimation of Phenol by KbrO3-KBr. Part- B
3. Estimation of Amine by Bromate/ Bromide solution. 1) To measure refractometrically average polarisablity of some
4. Estimation of Formaldyde by Iodometry. common solvents.
5. Estimation of Glucose by Benedict’s solution. 2) To find out the order of reaction and velocity constant of inversion
6. Estimation of given carbonyl compound by hydrazone of cane sugar by acid polarimetrically.
formation. 3) Polarimetric determination of the specific rotation of camphor in
7. Estimation of Aldehyde by Oxidation method. benzene and carbon tetrachloride.
8. Determination of percentage of number of hydroxyl group 4) Determine the rate constant, order of reaction and energy of
in an organic compound by acetylation method. activation of saponification of ethyl acetate by sodium hydroxide
conductometrically.
Practical-I
5) To find out degree of dissociation constant of acetic acid and
Organic Chemistry monochloroacetic acid by conductometrically.
Time : 6-8 Hrs. (One day Examination) Marks : 100 6) Determination of strength of strong and weak acid in given mixture
(1) Exercise-1 (Organic Synthesis) - 40 Marks conductometrically.
(2) Exercise-2 (Qualitative Analysis) - 40 Marks
 13 14
7) To determine equivalence conductance of strong electrolytes at Syllabus for Semester II
several concentrations and verification of Debye-Huckel Onsagar Paper V
principle conductometrically. Co-ordination Chemistry
8) Determination of solubility and solubility product of sparingly 60hrs (4hrs/week). 12hrs/unit 50 Marks
s o l u b l e , BaSO4) conductometrically.
s a l t s
4
( P b S O
Unit-I 12L
9) To find out composition of ferric ion thiocynate/Nickel and o- Ligand field theory (LFT), Failure of ionic model of CFT.
phenanthrolein complex by Job’s method by colorimetrically Experimental evidences in support of metal ligand orbital
10) To study the complex formation between ferric and salicylic acid overlaps, Adjusted crystal field theory (ACFT), Molecular
and find the formula and stability constant of the complex Orbital Theory: Ligand symmetry orbitals, Sigma and pi-
colorimetrically. molecular orbitals, Qualitative treatment of MOT of
11) To determine the dissociation constant of phenolphthalein Octahedral complexes with sigma bonding and also with
colorimetrically sigma and pi bonding. Qualitative MO diagrams and their
12) To determine the dissociation constant of Cu (II) and Fe (III) interpretation of octahedral, tetrahedral and square planer
solution photometrically bt titrating it with EDTA complexes with example. Explanations of charge transfer
spectra. Comparison of theories of bonding-VBT, CFT, LFT
Practical-II and MOT.
Physical Chemistry
Time : 6-8 Hrs. (One day Examination) Marks : 100 Unit-II Electronic spectra: 12L
(1) Exercise-1 (Instrumental) - 40 Marks
Spin-orbit (L-S) coupling scheme, calculation of spectral
(2) Exercise-2 (Non-Instrumental) - 40 Marks term symbols for ground state and excited states, selection
(3) Record - 10 Marks rules, vibronic coupling, electronic spectra of transition
(4) Viva-Voce - 10 Marks metal complexes, charge transfer spectra, band intensities,
band energies, band width & shapes, construction and
List of Books:-
application of Orgel diagrams, Tanabe-Sugano diagrams,
1. Findley's Practical Physical Chemistry, B.P. Levitt Longman.
spectra of octahedral, tetrahedral and square planar
2. Practical Physical Chemistry, A.M. James and F.F. Prichanrd
complexes with examples, Jahn-Teller effect, calculation of
Longman.
crystal field parameters (10Dq,B, and B) for octahedral Ni
3. Experimental Physical Chemistry, R.C. Das and B.Behra, Tata (II) and Co(II) complexes from electronic
McGraw Hill. spectra.Spectrochemical series,Nephelauxetic effect and
4. Advanced Physical Chemistry Experimentals Gurtu-Gurtu Pragati Nephelauxetic series of ligands. Magnetic moment,
Prakashan electronic spectra and structure of complexes.
5. Experimental Physical Chemistry, V.D. Athanale and Parul Mathur Unit-III Reaction Mechanism of Transition Metal complexes -I
New age International 12L
6. Advance Practical Physical Chemistry J.B. Yadao Goel Pubs. House. Reactivity of metal complexes, ligand replacement reaction:
7. Experimentals in Physical Chemistry by Dr. D.V.Jahagirdhar. classification of mechanism and energy profile of reaction.
8. Experiments in Physical Chemistry by D.P.Shoemaker. Inert and labile complexes, interpretation of liability and
9. Systematic experimental Physical Chemistry by Dr. T.K. Chandhekar inertness of transition metal complexes on the basis of VBT
& S.W. Rajbhoj. and CFT. Factors affecting the liability of a complex,
transition state or activated complex, substrate, attacking
reagents electrophilic and nucleophilic, Nature of central
atom. Kinetic application of CFT.Kinetics of octahedral
substitution, acid hydrolysis, factors affecting acid
hydrolysis, base hydrolysis, conjugate base mechanism,
 15 16
direct & indirect evidences in favour of conjugate 7. B.Durrant and P.J.Durrant: Advanced Inorganic Chemistry
mechanism, anation reaction, reaction without metal ligand 8. J C. Bailar: Chemistry of co-ordination compounds.
bond cleavage, reactions of coordinated ligands. Molecular 9. W. L. Jolly: Modern Inorganic ChemistryJones: Elementry Co-
rearrangement complexes. Geometrical, linkage and optical ordination chemistry.
isomerization reactions. Ligand stereospecificity. 10. B. N. Figgis: Introduction to Ligand field.
Unit-IV Reaction Mechanism of Transition Metal complexes -I I 11. M.C.Day and J.Selbin: Therotical Inorganic Chemistry.
12L 12. J. Lewin and Wilkins: Modern Co-ordination chemistry.
Substitution reaction in square planer complexes: the trans 13. Purcell and Kotz: Inorganic Chemistry.
effect, cis effect, steric effect, solvent effect, effect of leaving
14. D. Banerjea: Co-ordination chemistry, Tata Mc. Graw. Pub.
group, effect of charge, effect of nucleophile, effect of
15. A.F. Wells: Structural inorganic chemistry, 5th Edition, Oxford.
temperature. Trans effect theories, uses of trans-effect,
mechanism of substitution reactions in Pt(II) complexes. 16. S. G. Davies: Organotransition metal chemistry applications to
Electron transfer reactions. Types of electron transfer organic synthesis.
reactions, conditions of electron transfer, and mechanism 17. R. C. Mehrotra: Organometallic chemistry Tata McGraw Hill. Pub.
of one-electron transfer reactions, outer sphere and inner 18. G. S. Manku: Thereotical priciples of inorganic chemistry
sphere mechanisms, two electron transfer reactions- 19. A. B. P. Lever: Inorganic electronic spectroscopy.
complimentary and non-complimentary reactions. 20. R.C.Maurya:Synthesis and charecterisation of novel nitrosyls
Tunneling effect, cross-reaction, Marcus-Hush theory, compounds, Pioneer Pub. Jabalpur 2000.
bridged activated mechanism. Synthesis of coordination 21. R.H.Crabtree:The Organometalic chemistry of Transition metals,
compounds using electron transfer reactions. John Wiley.
Photochemical reaction of Chromium and Ruthenium 22. D.N.Styanaryan:Electronic Absorption Spectroscopy and related
complexes. techniques, University Press.
Unit-V Metal pi-Complexes: 12L 23. R. S. Drago: Physical methods in inorganic chemistry
Metal carbonyls: Structure and bonding, vibrational spectra 24. F.Basolo &G.Pearson: Inorganic Reaction Mechanism
of metal carbonyls for bonding and structure elucidation, 25. Organometallics II & I complexes with transition metal- carbon
important reaction of metal carbonyls, Metal nitrosyls: bonds: Manfred Bochmann- Oxford Press.
Nitrosylating agents for synthesis of metal nitrosyls, 26. Advanced Inorganic Chemistry Vol I & II – Satyaprakash, Tuli,
vibrational spectra and X-ray diffraction studies of Bassu and Madan- S Chand.
transition metal nitrosyls for bonding and structure
27. M.Tsusui,M.Nlevy,M.Ichikwa and K.Mori:Introduction to metal
elucidation, important reactions of transition metal nitrosyls,
pi-complexe chemistry,Plenum press,NY
structure and bonding. Dinitrogen and dioxygen complexes;
28. A.E.Martel;Coordination Chemistry-VolI&II,VNR.
Wilkinson’s catalyst and Vaska’s compound. Fluxional
Organometallic compounds (h2-olefin, h3-allyl and dienyl PAPER VI
complexes) ORGANIC CHEMISTRY-II
List of Books 60hrs (4hrs/week). 12hrs/unit 50 Marks
1. J.E.Huheey :Inorganic Chemistry Unit-I : AROMATIC ELECTROPHILLIC SUBSTITUTION 12L
2. F.A.Cotton& G. Wilkinson: Advanced Inorganic Chemistry 3rd, The arenium ion mechanism,orientation and
5th & 6th Editions. reactivity,energy profile diagrams.The o/p ratio, ipso
3. A.F. Willims: Theoretical Approach in inorganic chemistry. attack,orientation in benzene ring with more than one
4. Mannas Chanda: Atomic Structure and chemical Bonding substituents, orientation in other ring system. Diazonium
5. L. E. Orgel: An Introduction To transition metal chemistry, Ligand coupling, Gatterman-koch reaction, Pechman
field theory, 2nd Edition. reaction,Houben –hoesch reaction.
6. J. J. Logowski: Modern Inorganic Chemistry
 17 18
Unit-II: A) ADDITION TO CARBON –CARBON MULTIPLE BOND minimization of hazardous products.Designing of safer
12L chemical.Synthesis involving basic principles of green
Mechanistic and stereochemical aspects of addition reaction chemistry,some examples.Synthesis of styrene,Synthesis
involving electrophiles, nucleophiles and free radicals, regio of urethane,Free radical bromination ,Synthesis of
and chemoselectivity, Orientation and stereochemistry, paracetamol, Synthesis of Ibuprofen.
Addition to cyclopropanes,Hydrogenation of double bond
BOOK SUGGESTED-
and triple bonds.Hydrogenation of aromatic rings,
hydroboration, Michael reaction. 1. Advanced organic chemistry –Reaction mechanism and structure.
Jerry March, John Wiley.
B) Addition to Carbon-Heteroatom multiple bonds.
2. Advanced organic chemistry- F.A. Carey and R.J. Sunberg, Plenum.
Mannich reaction, Lithium-Aluminium Hydride, reduction
of carbonyl compounds.nitriles.Reformatsky reaction,Aldol 3. A Guidebook to mechanism in organic chemistry-Peterskyes,
Condensation, Knovengel reaction, Perkin Witting, Stobbe Longman.
reaction, Hydrolysis of esters and amide, ammonolysis of 4. Structure and mechanism in organic chemistry-C.K. Gold, Cornell
esters. University Press.
Unit-III : FREE RADICAL REACTION 12L 5. Organic chemistry, R.T. Morrison Boyd. Prentice Hall
Type of free radical reactions, free radical substitution 6. Modern organic chemistry-H.O. House, Benjamin.
mechanism at an aromatic substrate, aliphatic substrate, 7. Principal of organic chemistry-R.O.C. Norman and J.M. Coxon,
reactivity at a bridgehead position.Neighbouring group Blackie Academic and Professional.
assistance,reactivity for aliphatic and aromatic 8. Reaction mechanism in organic chemistry-S.M. Mukharji and S.P.
substrates,reactivity in attacking radicals, effect of solvent Singh, Macmilan.
on reactivity. 9. Stereochemistry of organic compounds- D. Nasipuri, New age
Halogenation at an alkyl carbon, allylic carbon, international.
hydroxylation at an aromatic carbon by means of Fenton’s 10. Stereochemistry of organic compounds- P.s.kalsi, New age
reagent. Oxidation of aldehydes to carboxylic international.
acids.chlorosulphoration(Reed Reaction)Coupling of 11. Frontier orbitals and organic chemical reactions-I. Fleming.
alkynes and arylation of aromatic compounds by Diazonium 12. Orbital Symmetry – R.E.Lehr & A.P. Marchand.
salts. Sand Meyer reaction.Free radical rearrangement, 13. Reactive intermediate in organic chemistry-N. S. Isaacs.
Hunsdiecker reaction. 14. Stereochemistry of carbon compounds- E.L.Eliel.
Unit-IV : MECHANISM OF MOLECULAR REARRANGEMENT 15. Physical organic chemistry-J. Hine.
12L 16. Name reaction in organic chemistry –Surrey.
Classification and General mechanistic treatment of 17. Advanced organic chemistry – L.F.Fieser and M. Fieser.
electrophilic,nucleophilic and free radical molecule 18. Vol.I & II organic chemistry - I. L. Finar.
rearrangement. Mechanism of the following rearrangement
19. Modern organic chemistry- J.D. Roberts and M. C. Caserio.
–Wagner-Meerwin,Pinacol-Pinacolone, Tiffenev –Demjnov
ring expansion, Favorski, Wolff, Fristsch-Butenberg-wichel, 20. The search for organic reaction pathways (Longmann), Peter Skyes.
th
Curtius Lossen,Beckman,Hoffman, Schmidt rearrangement. 21. O r g a n i c Edition (McGraw Hill), Pine.
c h e m i s t r y 5

Unit-V : GREENCHEMISTRY 12L 22. Organic chemistry (Willard Grant Press Botcon), John Mcmurry.
Designing a green synthesis: Choice of starting material, 23. A Textbook of organic chemistry- R.K. Bansal.
choice of solvents. Basic principle of green chemistry: 24. New trends in green chemistry –V.K. Ahluwalia & M. kidwai,
Prevention of waste by products, Maximum incorporation Anamaya publishers New Delhi.
of the reactants (starting material and reagents) into the 25. Heterocyclic Chemistry, John Joule, Oxford University Press.
final products. Rearrangements reaction, Addition reaction,
substitution, elimination reaction. Prevention or
 19 20
Paper- VII B) The rate of charge transfer, the Butler-Volmer equation, the
Physical Chemistry-II low overpotential limit, the high overpotential limit, Tafel
60 Hours (4-Hours/week) 50 Marks 12 hours/Unit plot. Voltammetry, concentration polarization, experimental
techniques. Corrosion, types of corrosion, corrosion
Unit-I Chemical Dynamics: inhibitors, corrosion monitoring and prevention methods.
A) Kinetics of Complex reactions: Chain reaction (H2+Br2 ® 2 Numericals. 6L
HBr thermal and photo chemical reaction), Homogeneous Unit-V Statistical Thermodynamics
catalysis (acid-base and enzymes), oscillating reactions A) Concept of distribution, Thermodynamic probability and
(Belousov-Zhabotinsky reaction, Lotka-Volterra mechanism, most probable distribution. Ensemble averaging, postulates
the brusselator and the oregonator). 6L. of ensemble averaging. Canonical, grand canonical and
B) Fast reactions: General features of fast reactions, Stopped micro-canonical ensembles, corresponding distribution laws
flow method, relaxation method, nuclear magnetic resonance (using Lagrange’s method of undetermined multipliers).
method, flash photolysis. Numericals. 6L. 6L.
Unit-II Quantum Chemistry: B) Partition function- Translational, rotational, vibrational and
A) Molecular orbital theory: Basic ideas, criteria for forming electronic partition functions, calculations of
M.O. from A.O., Construction of M.O.’s by LCAO for H2+ thermodynamic properties in terms of partition functions.
ion. Calculation of energy levels from wave functions, Applications of partition functions. Numericals. 6L.
physical picture of bonding & anti-bonding wave functions,
List of Books:
concept of orbitals and their characteristics. 6L.
2 3
1) Physical chemistry by P.W.Atkins & dePaula 7Th Edition
B) Hybrid orbitals- sp, sp , sp . Calculations of coefficient of 2) Molecular reaction Dynamics and chemical reactivity, R.D.Levine
A.O.’s used in hybrid orbitals. Huckel theory of conjugated and R.B. Benstin, Oxford University press. 1987.
systems, bond order & charge density calculations. 3) Physical Chemistry by Alberty and Silby, Jolly Wiley
Applications to ethylene, butadiene, cyclopropenyl radical, 4) Adsorption and Catalysis by solids, by D.K.Chakraburti, Wiley
cyclo- butadiene. Numericals. 6L. Eastern, 1990
Unit-III Macromolecules: 5) The Theory of Adsoption and catalysis, by A. Clark, Academic
A) Definition of macromolecule (Polymer), types of polymers, press, 1970
Random coils, configuration and conformation of 6) Micells Theoretical and applied aspects, by V.Moroy. Plenum
macromolecules, electrically conducting molecular wires, 7) Modern Electrochemistry by A.K.N.Raddy
fire resistant, liquid crystal polymers, kinetics of 8) Theoretical electrochemistry by D.I.Antropov, Mir Publisher 1972
polymerization, mechanism of polymerization. The stability 9) Electrochemistry by J. Dvorak, J. Koryta, V. Bohackova.
of biological polymers. 6L 10) Introduction to radiation chemistry by J.W.T. Spinks and
B) Number average & mass average molecular mass, molecular R.J.Woods
mass determination by Osmometery, Viscometry,
Ultracentrifugation, Electrophoresis, Size-exclusion Paper VIII
chromatography and Light scattering methods. Numericals. Optical Methods and Environmental Chemistry
6L 60hrs(4hrs/week), 12hrs/Unit 50Marks
Unit-IV Electrochemistry: Unit-I Optical Method 12L
A) Electrochemistry of solutions: Debye-Huckel-Onsager Spectrophotometry and Colorimetry: Interaction of
treatment and its extension, ion solvent interactions. Theory radiations with matters, Fundamental laws of
of electron transfer processes, electron tunneling. The Spectrophotometry. Beer –Lambert’s law and its limitation.
electrode-solution interface, structure of electrified Varifification of Beer’s law and deviation from Beer’s law.
interface, electric potential at the interface. 6L Ringbom’s plot. Photometric titrations. pK value of
indicator. Outline of construction and working of the UV-
Visible spectrophotometers. (Single and double beam).
 21 22
Applications of quantitative and qualitative analysis, Pesticides and pollution, Sources of pesticide residue in
problems. the environment, classification of pesticides, pesticide
Theory, instrumentation and applications of fluorimetry, degradation by natural forces, effect of pesticide residue
Nephelometry, turbidimetry, Polarimetry & Refractometry. on life. Analytical techniques for pesticide residue analysis.
Unit-II Flame Emission and atomic spectrometry: 12L DDT problem.
Flame photometry: Elementary theory of flame photometry. Radiation pollution-Classification and effects of radiation.
Instrumentation and experimental techniques. Interferences, Effects of ionizing radiation on Man. Effect of nonionizing
analytical techniques and applications. Atomic absorption radiation on life, Radioactivity and nuclear fall out,
spectrometry (AAS): introduction, principles, Advantages protection and control from radiation.
of AAS over FES, Instrumentation, Flame atomization. List of Books
Hallow cathod lamps, interferences and applications.
1. Analytical chemistry- Problems and Solution- S. M. Khopkar, New
Comparison of atomic absorption with atomic emission
Age International Publication.
methods.
2. Day & Underwood: Quantitative Analysis.
Unit-III WATER POLLUTION 12L
3. Findley: Practical Physical Chemistry:
Origin of wastewater, types, water pollutants and their
effects. Sources of water pollution, domestic, industrial, 4. Vogel : A Text book of Quantitative inorganic Chemistry, ELBS,
agricultural soil and radioactive wastes as sources of London.
pollution. Objective of analysis, parameter for analysis 5. Strouts Galfillal: Analytical Y. Lyalikov: Physocochemical Analysis
colour, turbidity, total solid, conductivity, acidity, alkalinity, 6. S. M.Khopkar:Basic concept in Analytical Chemistry
hardness, chloride, sulphate, fluoride, silica, phosphates 7. Meites and Thomas: Advance Analytical Chemistry. (Mc Graw
and different forms of nitrogen. Heavy metal pollution, Hill)
public health significance of Cadmium, Chromium, Copper, 8. H.H.Willard ,L.L.Merritt and J.A.Dean: Instrumental Methods of
Zinc Lead, Manganese, Mercury and Arsenic. General Analysis (Van Nostrand).
survey of instrumental techniques for the analysis of heavy 9. B. L. Krayer, H. H. Willard. L. Merrit, J. A. Dean & F. A. Settle:
metals in aqueous systems. Oxygen content of water and Instrumental Methods of Analysis (CBS Publishers, Delhi, 1986)
aquatic life. Measurments of DO, BOD, COD and their 10. R. D. Brown, Instrumental Methods of Chemical Analysis ,McGraw
significance as pollution indicators. Pesticides as water Hill
pollutants and analysis. A brief idea of coagulation and 11. L. R. Shyder & C. H. Harvath: An Introduction to Separation Science
flocculation. (Wiley Interscience).
Unit-IV AIR POLLUTION 12L 12. Environmental Chemistry, S. E. Manahan, Lewis Publishers.
Sources and sinks of gases pollutants, classification of air 13. Environmental Chemistry, Sharma & Kaur, Krishna publishers.
pollutants, effect of air pollutants on living and non-living 14. Environmental Chemistry, A. K. De, Wiley Eastern.
things. Sources of air pollution, air quality standards and 15. Environmental Pollution Analysis, S. M. Khopkar, Wiley Eastern.
sampling. Analysis of air pollutants (CO, CO2, NOx, SOx,
16. Environmental Toxicology, Ed. J. Rose, Gordon and Breach Science
H2S ,NH3 and Hydrocarbons and particulates). Green house
Publication.
effect, acid rain, ozone depletion and their consequences
on environment. Effects of air pollution, photochemical 17. Elemental Analysis of Airborne Particles, Ed. S. Landberger and
smog and monitoring of air pollution. M. Creatchman, Gordon and breach Science Publication.
Unit-V Soil Pollution and Pesticide Analysis 12L 18. Atmospheric pollution, W. Buch, McGraw Hill, New York.
Chemistry of soil, soil irrigation by effluents. Agricultural 19. Fundamentals of Air Pollution, S. J. Williason, Addison – Wesley
pollution, role of micronutrients in soil, trace element Publishers.
analysis in soil 20. Analytical Aspect of Environmental Chemistry, D. F. S. Natush
and P. K. Hopke. John Wiley & sons. New York.
 23 24
21. Analytical chemistry- Problems and Solution- S. M. Khopkar, New 7) To determine the heat of reaction, equilibrium constant and othere
Age. thermodynamic functions for the reaction Zn + Cu2+ = Zn2+ + Cu
22. Environmental Chemistry, J.W.Vanloon, Oxford University Press. potentiometrically.
8) To titrate ferrous ammonium sulphate solution with potassium
Semester II dichromate solution potentiometrically using bimetallic electrode
Practical III pair.
Physical Chemistry 9) To determine the dipole moment of given liquid.
Practical Work load (9Hours/week) Duration: 6Hours Marks : 100 10) To obtain the phase diagram of ethanol-water-benzene system at
Use of Computer Programs 5 terms of practicals. room temperature.
Treatment of experimental data, X-Y plots, programs with 11) To obtain solubility curve for liquid say water-acetic acid-
data preferably from physical chemistry practical. Students chloroform system.
will operate two packages I) MS-Word and II) MS-Excel. 12) Determination of strength of commercial phosphoric acid/Vinegar
Part A by conductometic analysis.
1) To find out molecular weight of given liquid by steam distillation Physical Chemistry Practical
method.
Books Suggested :
2) To find out the molecular weight of sulphur, alpha-naphthol and
biphenyl by freezing point method using naphthalene as a solvent. 1) Experimental physical chemistry,
3) To find out degree of association of benzoic acid in benzene by R.C. Das and B. Behera, Tata McGraw-Hill
cryoscopy method. 2) Advanced physical chemistry
4) To study the effect of temperature on adsorption. J.B. yadao, Goel Pub House
5) To determine the viscosity of different mixture benzene, 3) Experiments in physical Chemistry,
nitrobenzene and also test the validity of Kendall’s method. D.P. Shormaker, C.W. Garland and J.W. Nibler, Tata McGraw Hill Comp.
6) Identify and separate given mixture of amino acid by paper 4) Post graduate physical chemistry,
chromatography. Patel, Turakhia, Kelkar, Himalaya Pub House
7) Separation of metal cations (Co, Ni, Zn, Mn) and the Rf value by 5) Experiments, in physical chemistry,
paper chromatography. D.v. Jahagirdar, Himalaya Pub House
8) Separate and identify sugar present in honey by paper 6) Practical Physical Chemistry,
chromatography. A. Findlay Revised by J.A. Kitehner, Longmans , Green
10) To check up by TLC techqunic whether the following ink consist 7) Experiments in Physical Chemistry,
of single or multiple mixtures of dyes. F. Daniels and J. Williams, Mc Graw Hill.
Part-B: 8) Systematic Experimental Physical Chemistry,
1) Determination of pK value of acid-base indicator (methyl red, T.K. Chondekar & S.W. Rajbhoj, Anjali Pub. Aurangabad.
methelene blue & bromo cresol) by spectrophotometrically. 9) Advanced Physical Chemistry Experiments,
2) Determination of standard electrode potential of Zinc and Copper. J.N. Gurtu & A. Gurtu, Pragati Prakashan
3) To find the strength of HCl and Acetic acid in given mixture 10) Practical Physical Chemistry,
potentiometrically. A.M. James & P.E. Prichard, Longam Group Ltd.
4) To find the strength of mixture of halides by titrating it against 11) Experiments in physical Chemistry,
AgNO3 solution potentiometrically.
J.M.Wilson, K.J.Newcombe, A.R. Denko, and
5) To determine the hydrolysis constant of aniline chloride by emf R.M.W.Richett, Pergamon Press,
method.
12) Senior Practical Physical Chemistry,
6) To determine the solubility and solubility product of a sparingly
B.D.Khosle and V.S. Garg S.Chand & Comp.
soluble salt potentiometrically.
 25 26
Practical-III Cations: Mercury (I, II), Pb, Ag, Bi (III), Cu (II), Cd (II), As (IV, V),
Physical Chemistry Sb (IV, V), Sn (II, IV), Fe (III), Al (III), Cr (III), Ni (II), Co (II), Mn (II),
Time : 6-8 Hrs. (One day Examination) Marks : 100 Zn (II), Barium, Strontium, Calcium and Magnesium.
(1) Exercise-1 (Based on Part-A) - 40 Marks Interfering radicals: Phosphate, Oxalate, Fluoride and Borate.
(2) Exercise-2 (Based on Part-B) - 40 Marks Rare Earth: Tl, Mo, W, Se, Ti, Zr, Th, V, U, Ce.
(3) Record - 10 Marks The Practical examination will be based on the Inorganic Chemistry.
(4) Viva-Voce - 10 Marks Time: 6-8 hours (one day examination) Marks: 100
I) Exercise -1 (Synthesis/Radicals) - 40 Marks
Semester II II) Exercise-2 (Estimation) - 40 Marks
Practical IV III) Record - 10 Marks
Inorganic Chemistry Practicals
IV) Viva- Voce - 10 Marks

Practical Work load 9 Hrs. /Week Marks 50 Total - 100 Marks

I] Preparation of inorganic compounds and their characterization by List of Books-
elemental analysis, MW determination, decomposition 1. Synthesis and Characterization of Inorganic Compounds, W. L.
temperatures and molar conductance studies. (Minimum 6) Jolly, Prentice Hall.
1. [VO (acac) 2] 2. Inorganic Experiments, J. Derck Woollins, VCH.
2. Cis K [Cr (C2O4) 2(H2O) 2] 3. Practical Inorganic Chemistry, G. Marrand, B. W. Rockett, Van
3. Na [Cr (NH3) 2(SCN) 4] Nostrand.
4. Mn (acac) 3 4. A Text Book of Quantitative Inorganic Analysis, A. I. Vogel
5. K3 [Fe (C2O4) 3] 5. EDTA Titrations. F. Laschka
6. Hg [Co (SCN) 4] 6. Instrumental Methods of Analysis, Willard, Merit and Dean (CBS,
7. [Co (Py) 2 Cl2] Delhi).
8. TiO (C9H8NO) 2(H2O) 2 7. Inorganic Synthesis, Jolly
9. Cis [Co (trine)(NO2) 2] Cl H2O 8. Instrumental Methods of Chemical Analysis, Yelri Lalikov
10. [Cu2 (CH3COO) 4(H2O) 2] 9. Fundamental of Analytical Chemistry, Skoog D.A. &West D.M
11. K3 [Al (C2O4) 3](H2O) 3 Holt Rinehart &Winston Inc.
12. Ni (dmg) 2 10. Experimental Inorganic Chemistry, W.G.Palmer, Cambridge.
II] A) Quantitative Analysis of mixture of two cations:
Syllabus for Semester III
Quantitative analysis of binary mixture of cations involving their
Paper IX
chemical separation and separate analysis of one cation by
gravimetry and another by volumetric or colorimetric. Certain model Spectroscopy I
examples are given below: 60 Hours (Four hours/week) 12 Hrs. / Unit. Max.Marks.50.
i) Copper (II) and Nickel (II) Unit-I
ii) Copper (II) and Zinc (II) A) Unifying principle:Electromagnetic radiation,interaction of
iii) Nickel (II)—Zinc (II) electromagnetic radiation with matter-absorbance emission,
transmission, reflection, refraction, dispersion ,polarization
iv) Copper (II)—Iron (III)
and scattering.Uncertainty relation and natural line width
B) Analysis of Limestone, Dolomite and Bauxite.
and line broadening,transition probabilities,results of the
III] Qualitative analysis of radicals
dependent pertubation theory,transion moment,selection
Qualitative analysis of inorganic mixture for a total of five radicals rule,intensity of spectral lines.Born-oppenheimer
including interfering radicals (not more than one such radical in a approximate, rotational,vibrational and electronic energy
mixture), rare earth (not more than two rare earths in a mixture) and level. 6L
combination of cations (minimum 8 mixtures).
 27 28
B) Microwave spectroscopy:Classification of molecules,rigid Unit-IV Nuclear Magnetic Resonance Spectroscopy:General
rotor model,effet of isotopic substitution on the trasition introduction and defination of nuclear spin,nuclear
frequencies,intensities,non rigid rotor,stark effect,nuclear resonance shielding of magnetic nuclei,chemical
and electron spin interaction and effect of external shift,factors influencing chemical shift,deshielding,chemical
field,applications. 6L shift values and correlation for protons bonded to carbons
Unit-II A) Ultraviolet and visible spectroscopy : Various electronic (aliphatic,olefinic,aldehydic,aromatic) and other
transition (185-800nm), Beer-Lambert law, effect of solvent n ul ei .(a lcoh ol s,ph enol s, enol s,a cids, am i des, an d
on electronic trasition, UV band for cabonyl compounds, mercaptans),chemicsal exchange,effect of duteration,spin
unsaturated carbonyl compound,diene,conjugated spin coupling(n+1) rule,copmplex spin spin interaction
polyenes. Fisher-Woodward rules for conjugated dienes between two,three,four,and five nulei(first order spectra)
and carbony compounds,UV spectra of aromatic and factors effecting coupling constant “J” classification of spin
heterocyclic compounds.Sterric effects in biphenyls.4L system like AX,AX2,ABX,AMX,ABC,A2B2 etc.Spin
B) Infrared spectroscopy : Review of linear harmonic oscillator, decoupling, basic idea about instrument,mechanics of
vibrational energies of diatomic molecules, zero point measurment,Stereochemistry,hindered rotation. 12L
energy, force constant and bond strength,unhormonicity, Unit-V A) Karlplus curve-variation of “J” with dihydral
Morse potential energy diagram,vibration of polyatomic angle.siumplification of complex spectra,nuclear magnetic
molecules,selection rules, normal modes of vibration, group double resonance,contact shift reagent,solvent
frequencies, overtone band, factors effecting the band effects,fourier trasform technique,nuclear over hauser effect
position and intensities, far IR region, metal ligand (NOE).resonance of other nucleilike P,F.some application
vibrations, Instrumentation and sample handling including biochemical system,an overview of NMR of metal
characteristics. Vibrational frequencies of alkanes,alkenes, nucleides with emphasis on 195Pt and 119Sn NMR. 6L
alkynes, aromatic compounds, alcohols,amines. Detail study B) Carbon : 13NMR spectroscopy :General consideration,
of vibrational frequencies of carbonyl compounds, chemical shift (aliphatic, olefinic, alkyne, aromatic,
(ketones, aldehydes,esters, amides, acids,acid chlorides heteroaromatic and carbonyl),coupling constants,general
and anhydrides, lactones.lactums and conjugated carbonyl idea about two dimentional NMR spectroscopy –
copmpounds).Effect of hydrogen bonding and solvent on COSY,NOESY- DEPT techniques,solid state NMR. 6L
vibrational frequencies,overtones, combinations bands and Books suggested
Fermi resonance. FT-IR, IR of gaseous solids and 1) Spectroscopic identification of organic compound-RM
polyatomic materials. Modes of bonding of ambidentate Silverstein,GC Bassler and TC Morril,John Wally
ligands etc. 8L 2) Introduction to NMR spectroscopy-RJ Abrahm,J Fisher and P loftus
Unit-III : Mass spectrometry: Introduction, theory, measurment Wiely
techniques (EI,CI,FD,FAB) recording of mass spectrum. 3) Application of spectroscopy to organic compound-JR Dyer,Printice
types of ions, isotopic contribution, fragmentation process, Hall
factors affecting fragmentation,ion analysis, ion abundance.
4) Organic spectroscopy-William kemp,ELB with McMillan
Mass spectral fragmentation of organic compounds of
5) Spectroscopy of organic molecule-PS Kalsi,Wiley,Esterna,New
various types,common functional groups, molecular ion,
Delhi
metastable ipons, Mcllaferty rearrangement. Retro-Diels
Alder fragmentation, nitrogen rule. High resolution mass 6) Organic spectroscopy-RT Morrison,and RN Boyd
spectrometry. Examples of mass spectral fragmentation of 7) Practical NMR spectroscopy-ML Martin,JJ Delpench, and DJ
organic compounds with respect to their structural Martyin
determination. 12L 8) Spectroscopic methods in organic chemistry-DH Willson, I Fleming
9) Fundamentals of molecular spectroscopy-CN Banwell
10) Spectroscopy in organic chemistry-CNR Rao and JR Ferraro
11) Photoelectron spectroscopy-Baber and Betteridge
 29 30
12) Electron spin resonance spectroscopy-J Wertz and JR Bolten Unit-III : Electoanalytical Techniques 12L
13) NMR –Basic principle and application-H Guntur Potentiometry & pH Metry: Potentiometry, Indicator
14) Interpritation of NMR spectra-Roy H Bible electrodes: hydrogen electrode, quinhydrone electrode,
15) Interpritation of IR spectra-NB Coulthop antimony electrode and glass electrode, Reference
16) Electron spin resonance theory and applications-W gordy electrodes, Bimetallic electrode, Theory of potentiometric
17) - Mass spectrometry organic chemical applications ,JH Banyon titrations, Problems, Nernst equation, standard electrode
potential, Determination of cell potential, n, Kf and Ksp. pH
Semester III titrations. Ion Selective Electrodes: Terminology, types and
Paper X construction of ion selective electrodes. Electrical
Analytical Chemistry-I properties of membrane, Glass membrane electrodes, solid-
Thermal & Electroanalytical Methods state sensors, gas sensing and enzyme electrodes. Glass
Total Lectures: 60Hours, 4Hours per week, 12Hours/unit Total Marks: 50 electrode with special reference to H+ ,Na + ,K+ ions,
Unit-I : Thermal methods of Analysis: 12L interference, ion activity evaluation methods, operations
of solid membrane electrode, operation of liquid membrane
Introduction of different thermal methods,
electrode, coated type ion electrode. Applications of ion
Thermogravimetry TG and DTG, Static thermogravimetry,
selective electrode in determination of some toxic metals
quasistatic Thermogravimetry and dynamic
and some anions (F,Cl-, Br-, I- and NO3). Advantages of
thermogravimetry, Instrumentation, Factors affecting
ISEs.
thermograms, Applications of thermogravimetry,
Differential thermal analysis (DTA), DTA curves, Factors Unit-IV : Electoanalytical Techniques: 12L
affecting DTA curves, instrumentation, applications of Polarography : Basics of polarography, reference and
DTA. Simple numerical problems. working electrodes, operational amplifiers concepts,
Differential Scanning Colorimetry(DSC): Introduction, components of the limiting current, adsorption, kinetic,
Instrumentation, DSC-curves, factors affecting DSC curves catalytic and diffusion currents and to distinguish them.
and applications. Thermometric Titrations; Introduction, Dropping mercury electrode, Ilkovic equation-diffusion
apparatus, theory and applications. current constant and capillary characteristics determination.
Half wave potential, Polarographic maxima. Role of
Unit-II : Electroanalytical Methods 12L
temperature on diffusion current. Reversible, quasi
Conductometry: Principal of analysis, measurement of reversible and irreversible electrode reactions and evaluation
conductance, analytical applications of conductometry, of parameters using various reactions. Organic
conductometric titrations. High frequency titrations. Types polarographic analysis. Limitations of polarography,
of cells used, instrumentation and applications. Problems. advancements-pulse and differential pulse polarography.
Electrogravimery: Theory of electrolysis, electrode Unit-V : Electoanalytical Techniques 12L
reactions, over voltage, characteristics of deposits and
Voltammetry & amperometric: Linear and Cyclic sweep
completion of deposition, separation of metals.
voltametry. Randle’s Sevcik equation. Adsorption
Coulometry: Principal, coulometry at constant potential, complications in voltammetry. Tests for electrode reactions
coulometry at constant current, coulometric method of coupled with chemical reactions, EC and ECE reactions.
analysis, instrumentation, coulometric titrations.
Application of voltametry in the study of unstable reaction
Advantages of coulometric titrations. Applications of
intermediates. Enzyme catalyzed reactions and applications
coulometric titrations
of voltammetry in monitoring such reactions.
Stripping Technique: Anodic and cathodic stripping
voltammetry and their applications in the trace determination
of metal ions and biologically importants compounds.
Principal, methodology and applications amperometric
titrations. Chronopotentiometry.
 31 32
List of Books- Unit-III : 12L
1. Day and Underwood: Quantitative Analysis A) Bio-energetics and ATP cycle: DNA polymerization, metal
2. A. I. Vogel: A text book of quantitative analysis. complexes in transmission of energy, chlorophylls,
3. Flaschka: EDTA Titration photosystem I and photosystem II in cleavage of water,
4. Meites and Thomas: Advanced Analytical Chemistry. Model systems.
5. G. W. Ewing: Instrumental Methods of Chemical Analysis. B) Electron transfer in Biology: Structure and functions of
6. R. S. Draga: Physical Methods in Inorganic Chemistry metalloproteins in electron transfer proteins, cytochromes
& Fe-S proteins, Non-heme iron proteins; Rubredoxins,
7. G. D. Christian: Analytical Chemistry
Synthetic models. Biological Nitrogen fixation (in vitro and
8. S. M. Khopkar: Basic Concept of Analytical Chemistry.
in vivo)
9. Kolltath and Ligane: Polarography
Unit IV 12L
10. Braun: Instrumental Methods of Chemical Analysis
Transport & Storage of Dioxygen: Heme proteins & oxygen
11. Willard, Merritt and Dean: Instrumental Methods of Analysis uptake, structure and functions of haemoglobin, myoglobin,
12. Strouts, Crifillan and Wison: Analytical Chemistry. hemocyanins & hemerythrin. Perutz mechanism showing
13. J. W. T. Spinks and R. J. Woods: Introduction to Radiation Chemistry. structural changes in porphyrin ring system. Oxygenation
14. S. A. Skoog and D. W. West: Fundamental 0f Analytical Chemistry and deoxygenation. Model compounds. Cyanide poisoning
15. R. V. Dilts: Analytical Chemistry and treatment. Vanadium storage and transport.
Unit-V 12L
Semester III
Metallo enzymes: Apoenzymes, Haloenzyme & Coenzyme. The
Paper XI
principle involved and role of various metals in-
Special Paper-I
i) Zn-enzyme:- Carboxyl peptidase & Carbonic anhydrase.
Inorganic Chemistry (Bio-inorganic Chemistry)
ii) Fe-enzyme:-Catalase Peroxidase & Cytochrome P-450
Total Lectures: 60Hrs, 4 Hrs per week, 12 Hrs/unit Total Marks-50
iii) Cu-enzyme:-Super Oxide dismutase
Unit-I 12L
iv) Molybdenum:-Oxatransferase enzymes, Xanthine
A) Essential and trace metals in biological systems: Biological oxidase,Co-enzyme
functions of inorganic elements, biological ligands for metal
Vit.B12, Structure of vitamin B12 Co-C bond cleavage, Mutase
ions. Coordination by proteins, Tetrapyrrole ligands and
activity of co- Enzyme B-12, Alkylation reactions of Methyl
other macrocycle. Influence of excess and difficiency of V,
Cobalamin. Synthetc model of enzyme action, stability and
Cr, Mn, Fe, Co, Cu,& Zn. Genetic defects in the absorption
ageing of enzyme.
of trace elements. Regulation and storage of trace elements.
Role of minerals. Toxic effects of metals. Books:
1. Akhmetov, N.: General and Inorganic Chemistry.
B) Metal storage, transport and biomineralization with respect
to Ferritin, Transferrin and Siderophores, Na+ /K+ pump. 2. Aylett, B. and Smith, B.: Problems in Inorganic Chemistry, (English
Role of Ca in transport and regulation in living cells University Press)
Unit-II 12L 3. Bertini, et al: Bioinorganic Chemistry (Viva)
Medicinal use of metal complexes as antibacterial, 4. Charlot, G and Bezier, D.: Quantitative Inorganic Analysis (john
anticancer, use of cis-platin as antitumor drug, antibiotics Wiley).
& related compounds. Metal used for dignosis and 5. Douglas, B. E. McDanirl, D. H. et al: Concept and Models of
chemotherapy with particular reference to anti cancer drugs. Inorganic Chemistry (4th edt.) J. Wiley
Chelate therapy, chemotherapy with compounds of some 6. Dutt P. K.: General and Inorganic Chemistry.(Sarat Books House)
non essential elements; platinum complexes in cancer 7. Fenton, David E.: Biocoordination chemistry, Oxford
therapy. Antiviral activity of metal complexes. Gold 8. Jolly, W. L. : Inorganic Chemistry (4th edn.) Addison-Wesley.
containing drugs used in the therapy of Rheumatic-Arthritis, 9. Katakis, D. and Gordon, G.: Mechanism of Inorganic Reactions.(J.
Gold complexes as anticancer drug. Lithium in psycho Wiley).
pharmacological drugs. Antimicrobial agents.
 33 34
10. Leigh, G. J.: IUPAC Nomenclature of Inorganic Chemistry vi) AB2O4 type- Spinel, Normal & inverse,2-3 and 4-2 spinel
(1990;Jain-Interscience) ,packing of oxygen in tetrahedral & octahedral sites, sites
11. Massey, A. G.: Main Group Chemistry. occupancy number of site surrounding each oxygen,
12. Porterfield, W. W.: Inorganic Chemistry-A unified approach (Holt application of charge neutrality principles, site preferences
Saunders) in spinel, distorted spinel.Hausmannite( Jahn-Teller
13. Banerjee,D.:Coordination Chemistry,TMH distortions),Factors causing distortion in spinel.
14. Lee J.D.:Concise Inorganic Chemistry,ELBS Unit-II: 12L
15. Lippard S.J and Berg,J.M.: Principal of Bioinorganic Lattice Defects: Perfect &Imperfect crystals, point defects,
Chemistry,University Sci.Book.,Mill Valley Interstitial, Schottky defect, Frenkel defect, line defect &
16. Hay R.W.:Bioinorganic Chemistry, Ellis Horwood, Chichester and other entities, thermodynamics of Schottky & Frankel
NY defects. Dissociation, theory of dislocation, plane defects-
Lineage boundary, grain boundary, stacking fault, 3D
17. Das A.K.: Text Book of Medicinal Aspects of Bioinorganic
defects, Defects & their concentrations, ionic conductivity
Chemistry,CBS
in solids, Non stoichiometric compounds. Electronic
18. Sigel H.:Metal ions in Biological systems,Marcell Dekker,NY(Vol.1-
properties of Non-stoichiometric oxides, solid electrolytes,
31)
pyknometric & electrical conductivity methods of study of
19. Reddy K.H.,Bioinorganic Chemistry,New Age Int.Pub. defects, radiation effects on solid nature and properties,
20. Kaim W.and Schwederski B.:Bioinorganic Chemistry:Inorganic photography, colour centers, order-disorder changes,
elements in the Chemistry of Life,JohnWiley & Sons. defects, imperfection equilibrium, atom movements, and
21. Medicinal Inorganic Chemistry, Edited by Jonathan L.Sessler, defect interactions.
Oxford University Press. Unit-III : 12L
Semester III Electronic Properties of materials: Metals, Insulators &
Paper XII semiconductors, electronic structure of solid: band theory,
Special Paper-II band structure of metals, insulators & semiconductors.
Intrinsic & extrinsic semiconductors, doping
Inorganic Chemistry (Solid State Chemistry)
semiconductors. Seebeck effect and Hall effect. Organic
Total Lectures:60 Hours,4Hours/week, 12Hours/unit Total Marks-50
semiconductors, properties & their applications. Types of
Unit-I : 12L ionic conductors, mechanism of ionic conduction, diffusion,
Crystal Structure of Some Simple Compounds: superionic conductors, phase-transitions & mechanism of
i) Ionic Crystals &Their structures, radius ratio rule, effect of conduction in super ionic conductors, applications of ionic
polarization on crystals. conductors.
ii) Covalent structure type-Diamond, Sphalerite & Wurtzite. Unit-IV : 12L
iii) Geometry of simple crystal AB type: NaCl, CsCl & NiAs Dielectric polarization: Piezo-electricity, pyroelectricity,
&Wurtzite, reasons for preference for a particular structure ferrielectricity, antiferroelectricity, ferroelectricity & their
in above AB type of compounds. applications.
iv) AB2 type: Fluorite, antifluorites, Rutile structures. Li2O, Superconductivity: Introduction, discovery magnetic
Na2O, etc. CdCl2, CdI2 structures, difference between them. properties of super conductor, theory of super conductivity,
AB2 type: ReO3, BiI3, CrCl3, A2B3 type:Fe2O3 ,Corundum Meissner effect, type I&II superconductors, Josephson
Al2O3,Mn2O3. effects, Hc- temperature superconductor, crystal structure
v) Ternary Compounds ABO3 type: Perovskite, Barium titanate, of high temperature semiconductors, & its uses.
lead titanate, CaTiO3 Tolerance factor, charge neutrality Lasers and Masers actions, laser production and
&deviation structures. FeTiO3. applications
 35 36
Unit-V : 12L 23. Masterton W.L.and Hurley C.N. chemistry,Principals and
Magnetic Properties of Materials: Introduction, Reactions,Harcourt
Magnetization, Electronic Spin and Magnetic
SEMESTER III
Moment,Classification of materials, magnetic susceptibility,
paramagnetism in metal complexes, diamagnetism, Paper XI
ferromagnetic metals, ferromagnetic compounds (CrO2), Special Paper-I
Antiferromagnetism- transition metal monoxides, Organic Chemistry (Organic Synthesis-I)
ferrimagnetisms(ferrites), magnetic anisotropy, magneto Total Lectures: 60Hrs, 4 Hrs per week, 12 Hrs/unit Total Marks-50
striction, cooperative phenomena- magnetic domains,
Unit-I : Photochemistry.
Domain Theory, hysteresis loops (hard & soft magnets)
Interaction of radiation with matter, types of excitation, rate
magnetic storage & applications of magnetic materials.
of excited molecules, quenching, Quantum efficiency,
Spin glasses.
quantum yield, transfer of excitation energy, actinometry,
Books: singlet and triplet states, experimental methods in
1. Azaroff L.V.,Introduction to Solids,TMH photochemistry of carbonyl compounds, and transition,
2. West A.R.,Solid State Chemistry and its Applications,Plenum Norrish type I and Norrish type II reactions Paterno –Buchi
3. Rao C.N.R,Solid State chemistry,Dekkar reaction, Photoreduction, Photochemistry of enones,
Hydrogen abstraction rearrangement of unsaturated
4. Hagenmuller,Preprative methods in solid state chemistry
ketones and cyclohexadienones ,Photochemistry of
5. Keer H.V.,Principal of the Solid state,Wiley Eastern. parabenzoquinones, photochemistry of Aromatic
6. Hannay N.B,.Solid State Chemistry compounds with reference to isomerisation additon and
7. Chakrabarty D.K.,Solid State Chemistry,New Age Int. substitution Photochemical isomerization of cis and trans
8. West A.R.,Solid state Chemistry,John Wiley alkenes, Photochemical cyclization of reaction, Photo-Fries
9. Pillai S.O.,Solid state Physics,Academic press rearrangement, Photo theory reaction of anilides 12L
10. ReyT.J.,The Defects Solid state,Interscience Unit-II : Pericyclic Reactions
11. Azoroof L.V.Brophy J.J., Electronic Process in Materials, McGraw Molecular orbital symmetry,Frontier orbitals of ethylene, 1,
Hills 3-butadiene, 1, 3, 5-hexatriene, allyl system, classification
12. Anderson and Leaver, Materials Science of pericyclic reaction . FMO approach,woodward-Hoffman
13. Kirkendale ,Analytical Methods of Materials Investigations correlation diagram method and Peturbation of molecular
14. Greenwood N.N.Ionic Crystals, Lattice Defects and orbital (PMO) approach of pericyclic reaction under
Nonstoichiometry, Butter worth photochemical conditions. Electrocyclic
15. Kroger Chemistry of imperfect crystals, Holland reactions,conrotatary and disrotatary motion 4n and (4n+2)
16. Callister W.D.Jr., Material Science and Engineering An systems, with more emphasis on (2+2) and (4n+2)
Introduction, Wiley India
17. Van Bueren H.G.,Imperfection in Crystals,Wiley-Interscience
18. Brandon D and Kaplan W.D.Microstructural Characterization of Cycloaddition of ketones Secondary effects in (4+2)
Materials,Wiley NY. cycloaddition. Stereochemical effects and effect of
19. Hummel R.E.Electronic Properties of Materials,Springer-Verlag substituents on rate of cycloaddition reaction,1,3-dipolar-
cycloaddition and chelotropic reaction. Sigmotropic
20. Solymar L.andWalsh D.,Electrial properties of Materials,Oxford
rearrangement ,suprafacial,and antarafacial shift involving
UniversityPress
carbon moieties ,retension and inversion of configuration,
21. Jiles D.,Introduction to Magnetism and Magnetic Materials,Nelson (3,3) and(3,5) sigmotropic rearrangements,Claisen and Cope
Thornes,Cheltenham rearrangements. 12L
22. Kotz J.C.,and Treichel,P.Jr.Chemistry AND chemical Unit-III: A) Oxidation-Reduction and Electron trasfer reactions
Reactivity,Saunders
 37 38
I) Oxidation: Principle,aromatisation,dehydration yielding 12) Organic synthesis via Boranes-HC.Brown
C=C ,oxidation aldehyde,ketone,cleavage of C-C single 13) Organo borane chemistry-TP onak
bond in glycols, ozonolysis,epoxidation,oppenauer 14) Organic chemistry of boron-W. gerrard
oxidation,sommelet reduction. 15) Fundamentals of photochemistry-KK Rohatgi & Mukharji
II) Reduction: Selectivity in reduction, reduction of nitro and 16) Photochemistry-Cundau & Gilbert
nitroso compounds,metal hydride reduction,dissolving 17) Aspects of organic phoptochemistry-WM horspoot
metal reduction,reduction of aldehydes,ketones to
18) Phptochemistry-JD calvert
alcohols,reduction of carbonyl group to methylene.
19) Photochemistry-RP Wayne
III) Electron transfer reaction: Selective oxidation of alkyl side
chain in aromatic compounds,alcohols and acid using
Semester-III
Co(III), Reduction with LiAlH4 ,NaBH4.
12L Paper XII
Unit-IV: A) Formation of C-C bond Special Paper-II
Principle,disconnection,synthons,electrophilic and Organic Chemistry (Natural Product-I)
nucleophilic carbon species,use of following reaction in Unit-I : Carbohydrates
carbon carbon bond formation,base catalysed Types of naturally occurring sugars,deoxy sugars,amino
condensation ,Aldol,Claisen,Perkin,Stobbes,Knoevengel sugars, branched chain sugars, methyl ethers and acid
use of malonic and acetoacetic esters.Michael derivatives of sugars,general methods of struture and ring
addition.wittig reaction,use of acetylides,acid catalysed size determination with reference to maltose, lactose,
condensation of olefins,FC reaction,Fries reaction and diels sucrose, starch and cellulose. 12L
alder reaction. 12L Unit-II : A)Amino acids ,protein and peptides.
Unit-V : A) Umpolung concept :Dipole inversion,generation of acyl Amino acids,structural characterstics,acid baseproperty,
anion ,use of 1,3-dithiane, methylthiomethylsulphoxide stereochemistry of amino acids,optical resolution,stecker
bisPhenylthiomethane. metallated enol ethers,alkylidene synthesis,peptide and proteins.structure of peptide and
dithiane.ketone thjioacetals,2-propenethiobismethyl thio- protein, primary, secondary, tertiary and quaternary
allyl anion. structure. Reaction of polypeptide ,structure determination
B) Phosphours and sulphar ylide;Preperation and their of polypeptide, end group analysis,purines and nucleic
synthetic application aiong with stereochemistry. Enamines acids, chemistry,structure and functional relation to gene
:Chemistry of enamines and their synthetic applications. of DNA and RNA. 8L
12L B) Prostaglandins:Occurrence,nomenclature,classification and
Books suggested. physiological effects,synthesis of PGE2 and PGE2a
1) Principle of organic synthesis. ROC Norman & JM coxon 4L
2) Modern synthetic reaction. H.O.House W.A.Benjamin Unit-III : Classification, Isolation, General Methods of structure
3) Organic synthesis,The disconnection approach-S.Warren determination of the following 12L
4) Designing organic synthesis-S.Warren A) Alkaloids: Papavarine, Morphine, Reserpine,Nicotine.
5) Some modern methods of organic synthesis-W.carruthers, B) Terpenoids: Camphor,Gereniol,Abietic acid, squalene
6) Advance organic reaction.Mechanism & structure-Jerry march Unit-IV: A) Steroids and Homones 12L
7) Advance organic chemistry Part-B-F.A.caray & RJ Cholesterol,Teststerone,Progesterone and Cortisone
sundberg,plenum P. B) Biosynthesis of Natural Products.
8) Organic reaction and their mechanism-PS kalsi Biosynthesis of terpenes, alkaloids, and amino acids
9) Protective group in organic synthesis-TW Greene,& PGM (Lysine and phenylalanine)
10) The chemistry of organo phpsphorous-AJ kirbi,&SG Warren Unit-V: DYES
11) Organo silicon compound-C.Eabon A) Dyes: General Introduction, classification on the basis of
 39 40
structure and methos of application dying mechanism, Semester III
methods of dying, such as direct dying, vat dying, dispersive Paper- XI
dying, formation of dye in fibre, dying with reactive dyes, (Special Paper-I)
study of quinoline yellow, cyamine dye, ethyl red, Physical Chemistry
methylene blue, Alizarin, cyamine-green,fluorescein, cosin, 60 Hours (4-Hours/week) 50 Marks 12 hours/Unit
erythrosine, Rhodomines and Indigo.
Unit-I Solid-state chemistry:
Books suggested : A) Solid state reactions: General principles, experimental
1) Chemistry of alkloids-SW Pelletier. procedures, co- precipitation as a precursor to solid state
2) Chemistry of steroids-LF fisher & M fisher. reactions, other precursor methods, kinetics of solid state
3) The molecules of nature-JB hendricsion. reactions. 6L.
4) Biogenesis of natural compound-benfield B) Crystal Defects & Non-Stoichiometry: Intrinsic and extrinsic
5) Natural product chemistry & biological significance,J.Mann,RS defects- point defects, line and plane defects, vacancies-
devison,JB hobbs,DV Banthripde & JB horborne. Schotcky defects and Frenkel defects. Thermodynamics of
Schotcky and Frenkel defect formation, color centers. Non-
6) Introduction to flavonoids-BA Bohm, Harwood
Stoichiometry and defects. Numericals. 6L.
7) Chemistry of naturally occurring quinines-RH Thomson
Unit-II Electronic properties and Band Theory:
8) The systematic identification of flavonoids-marby, markham, &
A) Metals, insulators and semiconductors, electronic structure
thomos
of solids- band theory, band structure of metals, insulators
9) Text book of organic medicinal chemistry-wilson,geswold and semiconductors. Intrinsic and extrinsic
10) Medicinal chemistry Vil I &II-Burger semiconductors, doping semiconductors, semiconductor
11) Synthetic organic chemistry-Gurudeep chatwal. p-n junctions. Color in inorganic solids, 6L.
12) Organic chemistry of natural products Vol I &II-OP agrawal B) Magnetic properties- Behavior of substances in magnetic
13) Organic chemistry of natural products-Gurudeep chatwal field. Effect of temperature: Curie and Curie-Weiss Laws.
14) A textbook of pharmaceitical chemistry-Jayshree Ghosh Calculation of magnetic moments, magnetic materials, their
15) Synthetic dyes series-venkatraman structures and properties. Applications: structure / property
16) Chemistry process industries-shreve & brink relations. Numericals. 6L.
17) Principal of modern heterocyclic chemistry-LA paquelte Unit-III Glass, Ceramics and Multiphase materials:
18) Heterocyclic chemistry-J Joule &G smith A) Factors influencing glass formation, kinetics and
19) Heterocyclic chemistry-morton thermodynamics of glass formation, electrical (ionic )
20) An introduction to chemistry of heterocyclic compound-JB Conductivity of glasses, metallic glasses. Composition,
acheson properties and applications of glass-ceramics. 6L.
21) Introduction to medicinal chemistry-A gringuadge B) Properties and applications of ferrous and non-ferrous
22) Wilson &Gisvold text book of organic medicinal & pharmaceitical alloys. Phase diagram of iron-carbon system. Stainless steel,
chemistry-Ed.Robert F dorge brass. 6L.
23) An introduction to drug design-SS pandey,& JR demmock Unit-IV Ceramics and Composites:
24) Goodman and Gilmans pharmacological basis of therapeutics- A) Structure and properties of ceramic: Crystal structure,
25) Stragies for organic drug sythesis & design-D lednicer silicate ceramics, carbon, and imperfection in ceramic,
diffusion in ionic materials, ceramic phase diagram. Type
26) Polymer science-v govarikar
and application of ceramics, Glasses and glass ceramics
27) Principle of polymer chemistry-PJ flory
clay product refractories, abrasive, cement and advance
28) An outline of polymer chemistry-james q.allen ceramics, fabrication and processing of ceramics,
29) Organic polymer chemistry-KJ Saunders. fabrication and processing of glass and clay product,
powder processing and tape casting. 6L
 41 42
B) Particle reinforced Composites: Large particle and B) Polymer processing: Plastic, elastomer and fibers.
dispersion-strengthened Composites, Fiber reinforced Compounding, processing technique: Calendaring, die
Composites: Influence of fiber length, fiber orientation and casting, rotational casting, film casting, injection molding,
concentration. Metal- Matrix Composites, Ceramics- Matrix glow molding, extrusion molding, thermoforming, foaming,
Composites, Carbon-Carbon and hybrid Composites. reinforcing and fibers spinning. 6L
6L. Unit-II Polymer characterization:
Unit-V Superconductivity: A) Polydispersion, average molecular weight concept. Number,
A) High Tc Materials: Superconductivity in cuprates, weight and viscosity average molecular weight.
preparation and characterization of 1-2-3 and 2-1-4 materials. Polydispersity and molecular weight distribution. The
Normal and Superconducting state of cuprates. The BCS practical significance of molecular weight. Measurement of
theory. Applications of Low-temperature and High- molecular weight. End group, viscosity, light scattering,
temperature Superconductors. 6L. osmotic and ultra centrifugation method. 6L
B) Thin Films: Preparation techniques: evaporation/sputtering, B) Analysis and testing of polymers: chemical analysis of
chemical processes, MOCVD, sol-gel etc. Growth polymer, X-ray diffraction study, microscopy. Thermal
techniques, properties and applications of thin films.6L. analysis and physical testing-tencile strength. Fatigue
impact. Tear resistance. Hardness and abrasion resistance.
List of Books: 6L
1) Physical chemistry by P.W.Atkins & dePaula 7Th Edition
Unit-III Structure and properties of Polymers:
2) Industrial Chemistry by. B.K.Sharma, Goel Publication House. A) Morphology and order in crystalline polymers, configuration
3) Physical Chemistry of Surface, by A.W. Admson, John Wiley and of polymers chains. Crystal structure of polymers.
Sons 1990. Morphology of crystalline polymers, strain induced
4) Electronic structure and Chemistry of Solids by P.A.Cox , Oxford morphology, crystallization and melting. 6L.
University Press. 1991. B) Properties and structure: Physical properties, crystalline
5) Solid State Chemistry by D.K.Chakraburti, New Edge Internation melting point, Tm-melting point of homogeneous serious,
Publication 1996. effect of chain flexibility and other steric factors. Entropy
6) Principles of Solid State by. H.V.Kirr, Wiley Estern Publication. and heat of fusion, the glass transition temperature, the
7) Material Science & Engineering an Introduction, by W.D. Callister relation between Tg and Tm. Effect of molecular weight,
8) Material Science by J.C. Anderson, K.K.Leaver, J.M. Alexander & diluents, chemical structures, chain topology, branching
R.D. Rawlings. ELBS. and crossing linking. Property requirements and polymer
utilization. Numericals. 6L
Semester III
Unit-IV A) Polymer composites: Polymer matrix material, reinforcement,
Paper- XII properties of composite and compost system. Fabrication
Special Paper-II of polymer composite, processing science and quality
Physical Chemistry assurance of composites, environmental effect on
60 Hours (4-Hours/week) 50 Marks 12 hours/Unit composites, Smart composites. 6L
Unit-I Polymers: B) Polyethylene, polyvinyl chloride, polyamide, polyester,
A) Basic concepts: Monomers, repeat unit, degree of phenolic resin, epoxy resin and silicon polymer, Functional
polymerization, linear branch, and network polymers, polymer: electrically conducting polymer. 6L
classification polymers, Polymerization: condensation, Unit-V A) Polymer degradation: Definition, Types: thermal,
addition, radical chain ionic and coordination and mechanical, degradation by ultrasonic waves, photo
copolymerisation.polymerization condition and polymer degradation, degradation by high-energy radiations,
reaction, polymerization in homogeneous and oxidative and hydrolytic degradation. 6L
heterogeneous system. 6L
 43 44
B) Polymer reactions: Hydrolysis, acetolysis, aminolysis, B) Gas Absorption : Introduction, equipments, packed
hydrogenation, addition and substitution reaction, reaction columns, spray column mechanically agitated contactors.
o0f various specific groups, cyclation reaction and cross C) Evaporation : Introduction, short tube evaporator, forced
linked reactions, reaction leading to graft and block circulation evaporator, falling film, climbing film, agitated
copolymers, miscellaneous reactions. 6L evaporators.
List of Books: D) Filtration : Introduction, Filter media, filter aids, equipments
sparkler filter, sand filters, bag filters, rotary drum filter
1) A Text Book of Polymer Science by Billmeyer, Jr. Wiley
etc.centrifuge.
2) Polymer Science by V.R.Gowarikar, N. V. Vishwanathan & J.
E) Crystallisation : Introduction, silubility, supersaturation,
Sreedhar, Wiley Estern.
nucleation, crystal growth, equipments tank crystallizer,
3) Physical Chemistry Polymers by D.D. Deshapande, Tata McGraw Swenson-Walker crystallizer, Oslo cystallizer.
Hill
F) Drying: Introduction, free moisture, bound moisture, drying
4) Principles of Physical Chemistry by P.J.Flory, Cornal University
curve, equipments: tray dryer, fluid bed dryer, drum dryer
Press
Unit-III : Material Balances 12L
5) Introduction to Polymer Chemistry by R.B. Seymour, McGraw Hill.
Material balance without chemical reactions, flow diagram,
6) A Practical Course in Polymer Chemistry by S.J. Pnnea, Program without recycle or by-pass for above processes.
press.
Material balances involving chemical reactions, Concept
7) Polymer Composite by M.C. Gupta & A.P. Gupta. New Age of limiting reactant, conversion, purge operation and energy
International Publication. balance.
Unit-IV : Catalysis 12L
SemesterIII Introduction, types, homogeneous & heterogeneous, Basic
Paper XI Principles,mechanism, factors affecting the performance,
Special Paper-I Introduction to phase transfer catalysis.
Industrial Chemistry (Heat Transfer, Unit Operations and Industrial catalysts : Raney nickel, other forms of nickel,
Material Balances) palldium and Supported palladium, copper chromate,
vanadium & Platinum basecatalyst.
60hrs (4hrs/week). 12hrs/unit 50 Marks Aluminium alkoxides, titanium tetrachloride & titanates
Unit-I : 12L Titanium dioxide & Zeigler Natta catalyst and zeolite
A) Fundamentals of Heat transfer: Catalysts.
Methods of heat transfer, Fourier’s law, Newton’s law, heat Unit-V : Materials of construction for chemical plant. 12L
transfer by conductance, by convection and by radiation. A) Metals and Alloys : Copper, Aluminium, Nickel, titanium
Heat exchanger, types of heat exchanger, overall heat and their alloys. Mechanical & chemical properties and
their applications.
transfer co-efficient, double pipe heat exchanger, Shell & B) Corrosion : Types of corrosion relevant to chemical
tube type etc. industries, mechanism & prevention methods.
B) Fluid flow : C) Polymeric Materials: Industrial polymer and composite
Fluid flow phenomenon, introduction, Laminar flow, materials, their constitution, chemical and physical
Turbulant flow, Reynolds number, Bernoulls equation, fans, properties, industrial applications.
blowers, compressors, pumps etc.
List of Books-
Unit-II : Unit Operations: 12L
1) Heat transfer By Arora and Damkondwar, Pune
A) Distillation: Flash distillation, differential distillation,
2) Heat and Mass transfer by A, G. Gavane, Nirali Prakashan. Pune
rectification, plate columns, packed columns.
VOL I & II
 45 46
3) McCabe and Smith, Unit operations of Chemical Engineering, Mathods of determining depreciation.
McGraw Hill. Competitive & monopoly markets, some aspects of
4) Budger and Banchero, Introduction to Chemical Engineering marketing profitability criterion.
McGraw Hill. McGraw Hill. Economics of selecting alternatives.
5) Text Book of Industrial Chemistry Pragti Agencies Pune 2 Break even point, production scheduling
6) Engineering Chemistry By Dr. S. S. Dara. Unit-V : A) Industrial Management 12L
7) Catalysis in theory and practices, Ridder E. K. and Taylor H. S. Concept of scientific management in industry.
8) Phase transfer catalysis, Principles and techniques, Starles C. Fuctions of management : Decision making, planning,
9) Surface Chemistry by J. J. Bikermann, Academic Press. organizing, Material management, Inventory control,
10) Physical Chemistry of Surfaces, A. W. Aclamson. Information system & decision making.
11) Material science, O. P. Khanna, Khanna Publishers, Delhi B) Safety :
General occupational safety, flammble materials, Handling,
SemesterIII
fuel fighting equipments, control measures for Toxic
Paper XII chemicals. Safety with chemical engineering operations,
Sp.Paper-II hazardous chemicals process. Safety in Labortories and
Industrial Chemistry (Processes Economics And pilot plant. Safety in transportation & storage of chemicals,
Industrial Management) management of safety & loss prevention.
60hrs (4hrs/week). 12hrs/unit 50 Marks List of Books-
Unit-I : Manufacture of Heavy Chemicals 12L 1. Charles E. Dryden, Outline of Chemical Technology Edited by M.
Chemical processes for the manufacture of Heavy chemicals Gopal Rao and Marshall Siting, East West Press 2nd Edition 1973.
like- soda ash, bicarbonates, chlorine, caustic soda, 2. Manual of Chemical Technology VOL I & II by Venketesharul
bleaching power, calcium carbides and acids like H2SO4, Educational Development Center. IIT Madras,1977.
HCl, HNO3 H3PO4. 3. Chemical Process Industries by R. N. Shreves and M. J. A. Brink.
Unit-II : 12L McGraw Hill Ltd. 4th Edition 12977.
A) Industrial Gases: Heavy chemicals and production of gases. 4. Economics of chemical industry, Hempel E. M.
Chemistry, manufacture, storage, hazards & uses.- 5. Industrial organization and management, Bethal L. L.
Hydrogen, Oxygen, nitrogen, carbon dioxide, chlorine,
flurine, SO2 , phosgene, acetylene, argon, neon & helium. Semester III
B) Fertilizers: Fertilizer industries in India, Manufacture of Paper XI
Ammonium salts, Urea, nitrates, Ammonia, Nitrogeneous Analytical Chemistry
fertilizers, phophatic fertilizers, superphospates, complex (Advance Separation Techniques)
fertilizers, nitrogen fixation.
Unit-III: 12L Total Lectures: 60Hrs, 4Hrsper week, 12Hrs/unit Total Marks-80
A) Cement: Types of cement, manufacture- processes, and
setting of cements. Unit-I : 12L
B) Glass: Types, their composition & properties, manufacture Separation Methods: – Filtration, precipration, distillation,
of glass fitness, optical glass, coloured glasses, lead glass molecular seive, dialysis, Reverse osmosis, Ring oven
and neutron absorbing glass. methods, relative merit & demerit. Purification Techniques
C) Ceramics: Introduction, types, manufacturing process, (Solid organic compounds, liquids etc.) Criteria of purity.
applications & refractrories. Theory of chromatography, Classification, principles of
Unit-IV : Chemical Process Economics 12L chromatography, Van Deemeters Equation, Plate
Factors involved in project cost, estimation methods theory,significance of E,D V,D w. Techni ques of
employed for the estimation of capital investment.
 47 48
chromatographic separation gradient,isocranic, selective Ultrafiltration- working of techniques, membranes, non-
specifc separation,types of chromatographic methods gelatinous membranes and Applications. Dialysis compared
with other membrane-separation methods.
Unit-II : 12L Other Separation Methods:-Ultracentrifugation-Principle,
Gas Chromatography:- sedimentation constant, sedimentation equilibrium,
Introduction to different types of gas chromatography, How sedimentation velocity, methodology and applications.
does it differ from liquid chromatography .Principles of gas Zone refining- Principle, zone leveling and applications
chromatography, plate theory of gas chromatography,
Instrumentation for gas chromatography, working gas Unit-V : 12L
chromatography, application of gas chromatography, Kinetic Methods of analysis-
programmed temperature chromatography, flow programming Theoretical basis of kinetic methods of analysis, Rates of
chromatography, gas-solid chromatography, Columns for chemical reactions, rate laws, first order,second order
Gas Chromatography, choice of columns, polarity indices, kinetics,psudo first order and second order reactions,, factors
Gas chromatography and Chirality. affecting rate of reaction, , methods of determining amount
Ion chromatography –Principal, structure and characteristics of the substance (tangent method) fix time and concentration
of resins, eluent, suppressor columns and detectors used in method, addition method, oxidation reactions of H2O2
ion chromatography, analytical applications, environmental (thiosulphate, iodide, unimol), enzyme catalyzed reaction,
speciation by ion chromatography and applications inhibition and activation. Types of kinetic methods,
.Hyphenated techniques in Chromatography. differantial and integral, applications.

Unit-III : 12L Books Suggested :

Gel Filtration:- 1. Basic Concept in Analytical chemistry, by S.M. Khopkar.
Introduction, types of gels, techniques used in equilibrium 2. Day & Underwood: Quantitative Analysis.
studies, estimating size parameters, molecular 3. A. I. Vogel A Text book of Quantitative inorganic Chemistry,
wt.determinations separating plant aspects. ELBS, London.
Electrophoresis-Theory and classification, factors affecting 4. Analyticl Chemistry,D.C.Das,PHI Learning Pvt.Ltd,New Delhi
mobility, macromolecularsize and charge interactions with 5. Chromatography. By E Heftman, 5th edition, part-A and part-B,
supporting electrolyte, pH and concentrationdiscontinuities, Elsewhere Science Publisher, 1992
Factors affecting electrophoresis phenomena-electrolysis, 6. S. Wilson & P. Jones: Chemical Analysis Vol I
electrosomosis,temperature and supporting media. 7. Chromatography Today. By C F Poole and S K Poole, Elsewhere
Instrumentation, methodology, Preparation of gelstainingand Science Publisher, 1991.
destaining, preparative zone electrophoresis, continuous 8. H.H.Willard, L.L.Merritt and J.A.Dean: Instrumental Methods of
electrophoresis andApplications. Analysis (Van Nostrand).
Capillary Electrophoresis-Principle, theory, instrumentation, 9. B. L. Krayer, H. H. Willard. L. Merrit, J. A. Dean & F. A. Settle:
sample preparation andapplications, Capillary Instrumental Methods of Analysis (CBS Publishers, Delhi, 1986)
electrochromatography and Miscellar electrokinetic 10. Analytical Chemistry. By G D Christian 4th edition, John Wiley and
capillarychromatography Sons, 198611. L. R. Shyder & C. H. Harvath: An Introduction to
Separation Science (Wiley Interscience)
Unit-IV : 12L 12. F. J. Wicher Robert: Standard Methods Chemical Analysis.
Membrane-Based Methods:-Dialysis-working of techniques, 13. G. L. Davis Krupadanam, D. Vijaya Prasad, K. Varaprasad Rao,
membranes, general consideration of diffusion, Donnan KLN Reddy, C. Sudhakar, Analytical chemistry.
Membrane equilibrium and Applications. 14. R. D. Budhiraja Separation Chemistry, New Age.
Electrodialysis- working of techniques, membranes, 15. R.L.Peesok and L.D.Shield: Modern Methods of Chemical
Electrodialysis cells and Applications. Analysis.
 49 50
16 Electrophoresis- Analytical Chemistry. Open Learning by M Unit-IV : 12L
Melvin John Wiley and Sons.1987 Partical size determination- Introduction, low angle light
17 Analytical Chemistry, S.P.J. Higson, , Oxford University Press scattering, instrumentation, theoretical models and
18. Chemical Separations and Measurement; Theory and Practice, application.Dynamic light scattering-principles,
D.G.Peters, J.M.Hayes and G.M.Hieftje, Saunders Golden Sunburst instrumentation ans applications.Photosedimentation-
Series. settling velocity and partical size, instrumentation and
Semester III applications.
Paper XII Surface charactenzation by spectroscopy & microscopy:-
Analytical Chemistry (Special Paper-II) Introduction to the study of surfaces, types of surface
Recent Advances in analytical chemistry measurements,spectroscopic surface methods, general
Total Lectures: 60Hrs, 4Hrsper week, 12Hrs/unit Total Marks-80 techniques in surface spectroscopy,sampling of
surfaces,surface contamination. Scanning electron
Unit-I : 12L microscopy (SEM) and scanning probe microscopy.
High Performance liquid Chromatography:-
Principles, Instrumentation, Pumping systems, sample Unit-V : 12L
injection system, Columns and columns packings,Stationary Sensors:-
support in HPLC, applications, Validation of HPLC method . Glass membrane electrodes-solid state sensors-liquid
Preparative HPLC, Fast HPLC, Trouble shooting in HPLC, membrane electrodes-gas sensing and enzyme electrodes-
Flash chromatography, Capillary HPLC interferences-ion activity evaluation method-measurement
Super critical fluid chromatography, of pH-glass electrode for pH measurements-electrometric
Introduction,properties of super critical fluids, characteristics measurement of pH. Bio-sensors-principles, types and
of super critical fluid, Instrumentation and applications of applications
SFC, Comparison of HPLC with SFC..
Super critical fluid extraction-Introduction,advantages of Book Suggested:
SFE,instrumenation ,supercritical fluid choice,offline and on- 1. Analytical chemistry- Problems and Solution- S. M. Khopkar,
line extraction and application. New Age International Publication.
2. Day & Underwood: Quantitative Analysis.
Unit-II : 12L 3. Findley: Practical Physical Chemistry:
Functional group analysis- terminal methylene group, nitro 4. Vogel A Text book of Quantitative inorganic Chemistry, ELBS,
and Grignard reagent by titrimetry.Analytical organic London.
reagents, specificity, selectivity, sensitivity, stability, 5. Strouts Galfillal: Analytical Y. Lyalikov: Physocochemical
masking, demasking, types of organic reagents and priciples Analysis
opf underlying the uses of 2-pyridylazo-nathtol (PAN), 6. S. M.Khopkar:Basic concep in Analytical Chemistry
dithizone, 8- hydroxyquinoline, magneson I & II phenyl 7. Meites and Thomas: Advance Analytical Chemistry. (Mc Graw
arsonic acid, rubeanic acid and ethylene-diamine tetraacetic Hill)
acid EDTA. 8. H.H.Willard ,L.L.Merritt and J.A.Dean: Instrumental Methods of
Analysis (Van Nostrand).
Unit-III : Recent advances in Analytical chemistry:- 12L 9. B. L. Krayer, H. H. Willard. L. Merrit, J. A. Dean & F. A. Settle:
Ultra purity, ultra trace analysis, laboratory designing, Instrumental Methods of Analysis (CBS Publishers, Delhi, 1986)
purifications of reagents, pre-concentration techniques, 10. R. D. Brown Instrumental Methods of Chemical Analysis ,McGraw
methods of trace analysis such as NAA, XRF, EDX,AAS, Hill
and ICP. High purity materials for electronics industry, 11. L. R. Shyder & C. H. Harvath: An Introduction to Separation
contamination, control during analytical operations. Science (Wiley Interscience).
Importance of speciation analysis
 51 52
12. Elemental Analysis of Airborne Particles, Ed. S. Landberger and 15) Separation and estimation of-
M. Creatchman, Gordon and breach Science Publication. i) Cobalt and nickel
13. Atmospheric pollution, W. Buch, McGraw Hill, New York. ii) Calcium and Zinc and
14. Fundamentals of Air Pollution, S. J. Williason, Addison – Wesley iii) Zinc and Magnesium by anion exchange.
Publishers. 16) Separation and estimation of Fe3+ and Mg2+ by solvent extraction
15. Analytical Aspect of Environmental chemistry, D. F. S. Natush
17) Solvent extraction by binary mixtures i. e. Al/Mg, Mg/UO2, Cu/Ni,
and P. K. Hopke. John Wiley & sons. New York.
Cu/Co etc. and quantitative determination by spectrophotometry.
16. Analytical chemistry- Problems and Solution- S. M. Khopkar,
18) Nickel / Molybdenum / tungston/vanadium / Uranium etc by
New Age.
extractive spectrometric method.
17. Environmental Chemistry, J.W.Vanloon, Oxford University Press.
19) Separation, identification and quantitative determination of metal
ions by paper chromatography.
Semester III
20) Separation and identification of sugars/ honey/halides by paper
Practical V
chromatography and determination of Rf values
Inorganic Chemistry Practical
21) Thin layer chromatographic separation, identification and
Practical Workload 9 Hrs./week 100 Marks determination of Rf values –
Quantitative Inorganic Analysis: a. Metal ions (Mn, Co, Ni, Cu, Zn, Cd, Pb, alkali metals etc)
1) Detection and determination of Ascorbic acid from biological b. Amino acids/ Organic compounds
sample. c. Sulpha drugs in tablets and ointments.
2) Determination of Phosphates from plant samples by 22) Estimation of zinc/metals by fluorimetrically.
spectrophotometry. 23) Nephelometric determinations of sulphate, phosphate, silver.
3) Determination of iron from pharmaceutical samples and 24) Potentiometric determination of the percentage of sodium
coordination compounds. carbonate in commercial washing soda.
4) Determination of Calcium from given drug sample by 25) Water analysis:
complexometry. 1. Determination of hardness, alkalinity, salinity, Halides,
5) Determination of Iron, Calcium and Phosphorus from milk powder. Fluoride, Nitrite, Nitrate, phosphate and Sulphate.
6) Simultaneous Spectrophotometric determination of- 2. Determination of DO, COD and BOD.
i) Chromium and Manganese 3. Determination of toxic metals viz As, Cd, Pb, Hg, and Ni in
ii) Titanium and Vanadium. water and wastewater by suitable method.
iii) Cobalt and Chromium
The Practical examination will be based on the Inorganic Chemistry.
7) Analysis of stainless steel (Cr/Ni)
Time: 6-8 hours (one day examination) Marks: 100
8) To determine the stability constant and stoichiometry of Ferric-
thiocyanate complex by spectrophotometrically. I) Exercise -1 (Based on Instrumental) - 40 Marks
9) To study the stoichiometry and stability of Fe+3 salicylate complex II) Exercise-2 (Based on Separation Method) - 40 Marks
by job’s and mole ratio method spectrophotometrically. III) Record - 10 Marks
10) Estimate the amount of copper (II) with EDTA photometric titration IV) Viva- Voce - 10 Marks
11) Determination of capacity of anion and cation exchange resin by
Total - 100 Marks
column method.
12) To estimate the amount of magnesium and zinc in the given sample List of Books-
solution by ion exchange chromatography method. 1. Day and Underwood: Quantitative Analysis
13) Separation and estimation of Fe2+, Co2+ and Ni 2+ by anion 2. Vogel A.I: A textbook of quantitative Inorganic analysis, Longman.
exchanger.
3. Flaschka: EDTA Titration
14) Separation and estimation of Halide by anion exchanger.
 53 54
4. Meites and Thomas: Advanced Analytical Chemistry. Unit-III : SPECTRALINTERPRETATION
5. Ewing,G.W.: Instrumental Methods of Chemical Analysis,McGraw- Structure Elucidation of organic compounds on the basis
Hill of spectral data(UV, IR, 13CNMR and Mass) (Minimum 12
6. Drago,R.S: Physical Methods in Inorganic Chemistry compounds are to be analysed during regular Practical).
7. Christian G.D.: Analytical Chemistry
8. Khopkar S.M.: Basic Concept of Analytical Chemistry. Distribution of marks:
9. Kolltath and Ligane: Polarography Unit I ....... 40
10. Braun: Instrumental methods of chemical Analysis Unit II …… 20
11. Willard, Merritt and Dean: Instrumental methods of Chemical Unit III 20
Analysis,Van Nostrand Record 10
12. Strouts, Crifillan and Wison: Analytical Chemistry. Viva voce 10
13. Skoog S.A.and West D.W.: Fundamental of Analytical Chemistry —————————————————
14. Dilts R.V.: Analytical Chemistry TOTAL 100
15. Jahagirdar D.V.- Experiments in Chemistry —————————————————
16. Chondhekar T.K.- Systematic Experiments in Physical Book Suggested :
Chemistry,Rajbog S.W.,Anjali Pubn. 1. Modern Experimental Organic Chemistry-Royston M. Robert, John
17. Wlehov G.J.- Standard methods of Chemical analysis, 6th Ed. C. Gilbert, Lyu B. Rodewald, S. Wingrove.
18. Ramesh R&Anbu M,Chemical Methods for Environmental 2. Experimental Organic Chemistry- L. M. Harwood, C. I. Moody’
Analyss:Water & Sedient, Macmillion India. 3. Semi-microqualitative Organic analysis-N. D. Cheronis, J. B.
Entrikin, E.M. Wodnett.
4. The Systematic identification of Organic compounds-R.L. Shrine,
SEMESTER III
D.Y. Curtin.
ORGANIC
5. Quantitative Chemical analysis –A.I. Vogel.
PRACTICAL VI
6. Vogel’s textbook of quantative analysis (Revised)-J. Bassett, R.C.
9 Hours per week Total Hours: 90 hrs. Marks: 100 Denney, G.H. Jeffery and J. Mendham.
7. Experiment and technique in Oraganic chemistry-D. Pasto, C.
Unit-I : QUALITATIVEANALYSIS. Johnson and M. Miller.
Separation and identification of the components of a mixture 8. Hand book of organic analysis – qualitative and quantitative-H.
of two organic compounds (two solids, one solids and one Clark, Adward Arnold.
liquid, and all two liquids) using chemical methods or
Semester IV
physical techniques. Purification of the compounds by
Paper-XIII
crystallization, chromatographic techniques (Minimum of
12 mixtures to be done) SPECTROSCOPY-II
Unit-II : EXTRACTION 60 Hours (Four hours/week) 12 Hrs. / unit Max.Marks 50
1. Isolation of caffine from tea leaves.
2. Isolation of casein from milk. Unit-I : A) Emission spectroscopy based upon plasma: Arc and spark
atomization, spectra from higher energy sources, emission
3. Isolation of lactose from milk.
spectroscopy based upon plasma sources, atomic
4. Isolation of nicotine from tobacco. fluorescence method based upon plasma atomization.
5. Isolation of piperine from black paper. Emission spectroscopy based upon arc and spark sources.
6. Isolation of lycopene from tomatoes. X-ray fluorescence and its principle, instrumentation and
7. Isolation of â-carotene from carrots. application in analytical chemistry. 6L
 55 56
B) Photoelectron spectroscopy: Basic principle, photoelectric Unit-IV : Mossbaur spectroscopy: Basic principle,spectral
effect, ionization process, Koopemanss theorem PES and parameters and spectrum display.Doppler shift.recoilless
X-PES, PES spectra of simple molecule, ESCA, chemical emission of radition.isomer shift,quadrupole
information from ESCA. Auger electron spectroscopy-basic splitting,magnetic hyperfying splitting.application of the
idea. surface characterization by spectroscopy and techniques to the studies of 1. Bonding and structure of
microscoipy, (SEM). 6L Fe+2,and Fe+3 compounds including those of intermediate
spin (2) Sn+2 and Sn+4 compounds - Nature of M-L bond,
Unit-II : A) X-ray diffraction :Interaction of x-ray with matter, scattering coordination number, Structure and (3) Detection of
and diffraction. Brags method Debye-Sherrer method of X- oxidation state and in equivalent MB atoms. Mossbaur
ray structural analysis of crystals, index reflection, spectroscopy of Biological Systems. 12L
identification of unit cell from systematic absence in Unit-V : Structural Problem : Problems based on IR, Mass, UV, PMR,
diffraction pattern structure of simple lattice and x-ray 13C NMR data and structure determination of organic
intensities structure factor , its relation to intensity of molecules / inorganic compounds. 12L
electron density procedure for x-ray structure analysis. 4L
Books suggested
B) Electron diffraction : Scattering intensity Vs scattering angle,
1) Spectroscopic identification of organic compound-RM
wierl equation, measurment techniques, elucidation of
Silverstein,GC Bassler and TC Morril,John Wally
structure of simple gas phase molecules.Low energy
electron diffraction and stucture of surface. 4L 2) Introduction to NMR spectroscopy-RJ Abrahm,J Fisher and P loftus
Wiely
C) Nutron diffraction: Scattering of neutrons by solids and
3) Application of spectroscopy to organic compound-JR Dyer,Printice
liquids magnetic scattering, measurement techniques.
Hall
Elucidation of structure of magnetically ordered unit cell.
4L 4) Organic spectroscopy-William kemp,ELB with McMillan
5) Spectroscopy of organic molecule-PS Kalsi,Wiley,Esterna,New
Unit-III A) Raman spectroscopy: Classical and quantum theories of Delhi
raman effects,Pure rotational and vibrational and 6) Organic spectroscopy-RT Morrison,and RN Boyd
vibrationalrotational raman spectra,selection rules,mutual 7) Practical NMR spectroscopy-ML Martin,JJ Delpench, and DJ
exclusion Raman spectroscopy,coherent antistokes Raman Martyin
spectroscopy (CARS).Applications for the study of active 8) Spectroscopic methods in organic chemistry-DH Willson,I Fleming
sites of metalloproteins. 6L 9) Fundamentals of molecular spectroscopy-CN Banwell
B) Electron Spin Resonance Spectroscopy : Introductiuon 10) Spectroscopy in organic chemistry-CNR Rao and JR Ferraro
,basic principle.zero field splitting and kramers degeneracy, 11) Photoelectron spectroscopy-Baber and Betteridge
factors effecting the “g” values,hyperfying splitting, 12) Electron spin resonance spectroscopy-J Wertz and JR Bolten
determination of “g” values.Instumentation,working of 13) NMR –Basic principle and application-H Guntur
instruments,sensitivity,concentration,choice of solvent. 14) Interpritation of NMR spectra-Roy H Bible
presentation of ESR spectra,application of ESR to study 15) Interpritation of IR spectra-NB Coulthop
the free radicals,structure determination,reaction
16) Electron spin resonance theory and applications-W gordy
velocities,application to inorganic compounds including
biological system and to inorganic free radicals such as 17) Mass spectrometry organic chemical applications ,JH Banyon
PH4-,F 2 -,[BH3] -,determination of oxidation state of
metals,Eldor and Eldor techniques. 6L
 57 58
Semester IV Unit-IV: Analysis of Food, Body fluids and Drugs: 12L
Paper XIV A) The chemical and nutritional composition of food: analysis
General Analytical Chemistry of trace elements such as Pb, As, Cd in food, Analysis of
Tea, Milk, Spices.Chemical preservation of food, Analysis
Total Lectures: 60Hours, 4Hours per week, 12Hours/unit Total Marks: 50 of sodium benzoate and sodium metabisulphite, Analysis
Unit-I : 12L of adulterants in food, Analysis of artificial sweeteners in
Radiochemical Methods: Elementary working, principles food and colouring agents.
of Geiger Muller, Ionisation, proportional and l-ray counters. B) Clinical Chemistry and Drug Analysis: Composition of
Radiotracer techniques, application of radiotracers in blood, collection and preservation of samples, clinical
analytical chemistry. Neutron activation analysis (NAA): analysis, serum electrolytes, blood glucose, blood urea
Principle, technique and applications in preparation of some nitrogen, uric acid, albumin, globulin, barbiturates, acid and
commonly used radioactive isotopes. Isotopic Dilution alkaline phosphatases. Immunoassay :principles of radio
Analysis (IDA), substoichiometric IDA, experimental immunoassy(RIA) and applications. The blood gas analysis
technique and applications of IDA, advantages and trace elements in the body. Narcotics and dangerous drugs,
limitations of IDA and comparison of IDA with NAA. classification of drugs, screening by gas and thin layer
Principle of Radiometric titrations, types, Experimental chromatography and specrtophotometric measurements
techniques and its applications. Carbon dating. Numericals. Unit-V : Fuel analysis: 12L
Unit-II : Online Analyzers 12L Solid, Liquid and gaseous fuels. Characteristics of ideal
Automation in Chemical Analysis: Introduction, fuels. Ultimate and proximate analysis of coal, heating
Classification of automated methods, principles and values, grading of coal, liquid fuels-flash point, aniline point,
techniques of auto-analyzers employed for microanalysis knocking, antiknock compounds, octane number, cetane
with emphasis on the basis sequences in operational modes number and carbon residue. Gaseous fuels, producer gas
in segmented and non-segmented flow and applications. and water gas, determination of calorific value. Analysis of
Selection of online analyzers. fuel Gas. Numerical problems.
Flow Injection Analysis: Introduction, principal, theoretical List of Books-
aspects of FIA, techniques, pretreatment of sample in 1. Day and Underwood: Quantitative Analysis
packed reactiors, components of FIA apparatus, Factors 2. A. I. Vogel: A text book of quantitative Inorganic analysis.
affecting FIA and applications for the determination F-, Cl-
3. Flaschka: EDTA Titration
PO4-, SiO32- NO2-+NO3-,SO42-,BO33-,Ca2+,Mg2+, Al3+, Mn2+,
Cr6+, Fe3+ in water. 4. Meites and Thomas: Advanced Analytical Chemistry.
Unit-III : Optical Methods Of Analysis: 12L 5. G. W. Ewing: Instrumental Methods of Chemical Analysis.
A) Molecular Luminescence Spectroscopy: Introduction, 6. R. S. Drago: Physical Methods in Inorganic Chemistry
Molecular fluorescence, phosphorescence and 7. G. D. Christian: Analytical Chemistry
Chemiluminescence’s, theory, factors affecting fluorescence 8. S. M. Khopkar: Basic Concept of Analytical Chemistry.
and phosphorescence, instrumentation and analytical 9. Kolltath and Ligane: Polarography
applications. Applications of fluorimetry. Fluorescence 10. R.D.Braun: Instrumental methods of chemical Analysis
quenching. Photoacoustic spectroscopy: Theory, 11. Willard, Merritt and Dean: Instrumental methods of Analysis
Instrumentation, PAS-gases and condensed systems, 12. Strouts, Crifillan and Wison: Analytical Chemistry.
chemical and surface applications. Qualitative and 13. J. W. T. Spinks and R. J. Woods: Introduction to Radiation
quantitative analysis. Chemistry.
B) Inductively Coupled Plasma Atomic Emission Spectroscopy 14. S. A. Skoog and D. W. West: Fundamental 0f Analytical Chemistry
(ICPAES): 15. R. V. Dilts: Analytical Chemistry
Principles, atomization and excitation, ICP-source,
Instrumentation and applications.
 59 60
Semester IV Unit-IV : 12L
Paper-XV Organotransition Metal Chemistry:
Special Paper-III Alkyls and Aryls of Transition Metals:
Inorganic Chemistry (Photoinorganic & Organometallic Chemistry) Types, routes of synthesis, stability & decomposition
pathways of alkyls & aryls of transition metals.
Total Lectures: 60Hrs, 4 Hrs per week, 12 Hrs/unit Total Marks-50 Organocopper in Organic synthesis.
Unit-I : 12L Compounds of Transition Metal –Carbon Multiple bonds:
A) Basics of Photochemistry: Absorption, excitation, Alkylidenes, alkylidynes, low valent carbenes & carbynes–
photochemical laws, quantum yield, electronically excited synthesis, nature of bond, structural characteristics,
states-life times-measurements of the times. Flash nucleophilic & electrophilic reactions on ligands, role in
photolysis, stopped flow techniques, Energy dissipation organic synthesis.
by radiative and no-radiative processes, absorption spectra, Unit-V : 12L
Frank-Condon principles; photochemical stages-primary & Transition Metal Pi Complexes-Carbon multiple bonds.
secondary processes. Nature of bonding, structural characteristics & synthesis,
B) Properties of excited states: Photochemical kinetics, properties of transition metal pi- Complexes with unsaturated
Calculation of rates of radiative processes. organic molecules, alkenes alkynes, allyl, diene, dienyl,
Unit-II 12L arene & trienyl complexes. Application of transition metal,
A) Excited States of Metal Complexes: Electronically excited organometallic intermediates in oraganic synthesis relating
states of metal complexes, charge transfer spectra, charge to nucleophilic & electrophilic attack on ligands, role in
transfer excitations, metods for obtaining charge transfer organic synthesis.
spectra.
Books:
B) Ligand field Photochemistry: photosubstitution, photo
1. Elschenbroich Ch.and Salzer A.: Organometallics, VCH,Weinheim,
oxidation & photoreduction.
NY.
Liability and selectivity, zero vibrational levels of ground 2. Balzani Vand Cavassiti V.:Photochemistry of Coordination
state and excited state, energy content of excited state, compounds,AP,London
zero-zero spectroscopic energy, development of the
3. Purcell K.F.and KotzJ.C., An Introduction to Inorganic
equations for redox potentials of the excited states.
Chemistry,Holt Sounder,Japan.
Unit-III 12L
4. Rohtagi K.K.and Mukharjee,Fundamentals of
A) Redox reactions by Excited Metal Complexes: Energy Photochemistry,Wiley eastern
transfer under conditions of weak interaction & strong
5. Calverts J.G.and Pits.J.N.,Photochemicals of Photochemistry,John
interaction – exciplex formation, conditions of excited states
Wiley
to be useful as redox reactants, excited electron transfer,
6. Wells,Introduction of Photochemistry
metal complexes as attractive candidates (2,2-bipyridine &
7. Paulson,Organometallic Chemistry,Arnold
1,10-Phenanthroline complexes.), illustration of reducing and
oxidizing character of ruthenium (II); role of spin-orbit 8. Rochow,Organometallic Chemistry,Reinhold
coupling, lie time of these processes. Application of redox 9. Zeiss,Organometallic Chemistry,Reinhold
processes of electronically excited states for catalytic 10. Gilbert A.and Baggott,J,Essential of Molecular
purposes, transformation of low energy reactants in to high- Photochemistry,Blackwell Sci.Pub.
energy products, chemical energy in to light. 11. Turro N.J.and Benjamin W.A.,Molecular Photochemistry
B) Metal Complex Sensitizers: Metal Complex Sensitizers, 12. CoxAand Camp,T.P.Introductory Photochemistry,McGraw-Hill
electron relay, metal colloid systems, and semiconductor 13. KundallR.P.and GilbertA,Photochemistry, Thomson Nelson Coxon
supported metal or oxide systems, water photolysis, J and Halton B.,Organic Photochemistry,CambridgeUniversity
nitrogen fixation & carbon dioxide reduction. Press.
 61 62
B) Coordination Polymers:
Semester IV
Natural polymers and reactions yielding coordination
Paper-XVI
polymers. Synthesis of coordination polymers. Use of
Special paper-IV polymeric ligands in synthesis of coordination polymers.
Inorganic Chemistry (Materials Chemistry) Metal coordination polymers. Silicon polymers.
Total Lectures: 60Hrs, 4 Hrs per week, 12 Hrs/unit Total Marks-50 Organosilicon polymers. Synthesis and their uses.
Unit-I : Glasses, Ceramics & Composites: 12L Unit-V : 12L
Glass: A general idea of Glassy state, types, their Catalysis: Basic principals, thermodynamic and kinetic
composition & properties, glass formers & modifiers, optical aspects, industrial requirements, classification, theories of
glass, coloured glasses, lead glass, neutron absorbing glass. catalysis, homogeneous and heterogeneous catalysis.
Ceramics: General introduction, types, manufacturing Introduction, types & characteristics of substrate-catalyst
process, structure, mechanical properties. interactions, kinetics and energetic aspects of catalysis,
selectivity, stereochemistry, orbital symmetry and reactivity.
Unit-II 12L
Catalytic reactions of coordination and Organometallic
A) Liquid Crystals: Mesomorphic behaviour, thermotropic compounds including polymerization activation of small
liquid crystals, positional order, bond orientational order, molecules, addition to multiple bonds, hydrogenation,
nematics & smectic mesophases; smectic-Nematic transition Zeigler-Natta polymerization of olefins, hydroformylations,
clearing temperature-homeotrpic, planer & schlieren textures oxidations, carbonylations and epoxidation.
twisted nematics, chiral nematics, molecular arrngement in
smectic A & smectic C phases, optical properties of liquid Books Suggested:
crystals. Dielectric susceptibility & dielectric constants. 1. Barsoum ,M.W.,Fundamentals of Ceramics,McGraw Hill ,New Delhi
Lyotropic phases & their description of ordering in liquid 2. Ashcroft ,N.W. and Mermin,N.D.,Solid Stae Physics,Saunders
crystals. College
B) Bio-materials: Biomineralisation, controlled formation of 3. Callister W.D.,Material Science and Engineering,An
biological composits, bone & other mineralised tissues, Introduction,Wiley
materials of construction, applications (General aspect 4. Keer,H.H,Principals of Solid State,Wiley Eastern
only). 5. Anderson J.C.,Lever K.D.,Alexander J.M and Rawlings,R.D.,ELBS
Unit-III : 12L 6. Gray G.W.Ed.Thermotropic Liquid Crystals,John Wiley
Nanoparticals & Nanostructural materials :Introduction, 7. Kelkar and Hatz Handbook of Liquid Crystals,Chemie Verlag.
methods of preparation, physical properties, and chemical 8. Kalbunde K.I.,Nanoscale Materials in Chemistry,John Wiley,NY.
properties. Molecular Precursor routes to inorganic solids:-
9. Shull R.D.,McMichael R.D. and Swartzendrub L.J.,Studies of
Introduction, sol-gel chemistry of metal alkoxide, hybrid
Magnetic Properties of Fine particals and their relevance to
organic-inorganic compounds
Mataerials Science, Elsevier Pub.Amsterdam
Nanoporous Materials: Introduction, Zeolites & molecular
10. Breck D.W.,Zeolite Molecular Sieves:Structure Chemistry and
sieves, determination of surface acidity, porous lamellar
Use,WileyChichester,Eng.
solids, composition-structure, preparation & applications.
11. Mor r ish A. H. , Ha n eda K. , Zh ouX. Z. In Na n op h a se
B) Solid State Reaction: General principles, reaction rates,
Materials:synthesis,properties,applications,Kulwer,London.
reaction mechanism, reaction of solids, factors influencing
reactivity, photographic process.
Unit-IV 12L
A) Fertilizers: Classification of fertilizers, nitrogen fertilizers,
phosphate fertilizers, N, P, K fertilizers, H3PO4 production
without using H2SO4.
 63 64
Semester IV Unit-V: A) Polynuclear Hydrocarbons: 12L
Paper XV Introduction, Comparative study of the aromatic character
Special Paper-III of linear and nonlinear Ortho fused Polynuclear
Organic Chemistry (Organic Synthesis: II) Hydrocarbon. General methods of preparation of fluorine,
anthracene and phenanthrene.
Total Lectures: 60Hrs, 4 Hrs per week, 12 Hrs/unit Total Marks-50 B) Heterocyclic Compounds:
Unit-I : A) Chemo and Regio Selectivity. 6L Nomenclature and familiarity with the heterocyclic ring (3-
Selectivity in organic synthesis, chemo and regio 7 members containing up to 3 heteroatoms. Detailed
selectivity,stereoselective and stereospecific reactions, chemistry of Pyrozole, imidazole, oxazole, thiazole, thiazine,
Kinetic and Thermodynamic control in reaction. pyrimidines, pyrazines and zepines
B) Application of organometallics in organic synthesis. Books suggested.
Use of Organometallic compounds of Mg, Li, Zn, B,Sn and 1) Principle of organic synthesis. ROC Norman & JM coxon
organocopper compounds in organic synthesis 2) Modern synthetic reaction. H.O.House W.A.Benjamin
.Organotrasition metal reagents of C R,Fe,Co,Rh,Ni and Pd. 3) Organic synthesis,The disconnection approach-S.Warren
6L
4) Designing organic synthesis-S.Warren
Unit-II : Designing the synthesis based on retrosynthetic analysis
5) Some modern methods of organic synthesis-W.carruthers,
12L
6) Advance organic reaction.Mechanism & structure-Jerry march
A disconnection approach to the synthesis of organic
compound. Different consideration in designing target 7) Advance organic chemistry Part-B-F.A.caray & RJ
molecule,concept of synthonss, FGI, Chemoselectivity, sundberg,plenum P.
regioselectivity, specificity, stereoselectivity, general 8) Organic reaction and their mechanism-PS kalsi
strategy choosing a disconnection.Types of bond 9) Protective group in organic synthesis-TW Greene,& PGM
disconnection, some of the applications of these concepts 10) The chemistry of organo phpsphorous-AJ kirbi,&SG Warren
in designing the synthesis of common impotant class of 11) Organo silicon compound-C.Eabon
the compounds. 12) Organic synthesis via Boranes-HC.Brown
Unit-III : A) Protection and Deprotection of functional groups 13) Organo borane chemistry-TP onak
12L 14) Organic chemistry of boron-W. gerrard
Protection and deprotection of functional groups 15) Fundamentals of photochemistry-KK Rohatgi & Mukharji
like,hydroxyl,amino,carbonyl and carboxylic acids groups, 16) Photochemistry-Cundau & Gilbert
techniques employed for these. 17) Aspects of organic phoptochemistry-WM horspoot
B) Phase Transfer Catalysis and Crown ethers. Their methods 18) Phptochemistry-JD calvert
of preparation and application in Organic Synthesis,
19) Photochemistry-RP Wayne
Mechanism of Phase transfer reaction.
Unit-IV A) Selective Oraganic Name Reaction 12L SEMESTER –IV
Stark-Enamine reaction,Michel addition ,Favorski reaction, Paper XVI
Mannich reaction, Sharpless asymmetric epoxidation ,Ene ORGANIC CHEMISTRY (Natural Product-II)
reaction, Baeyer –Villeger reaction.
Unit-I : Synthesis Polymers and Rubbers - 12L
B) Reagents in Organic Synthesis: Use of following reagents
in Synthesis and functional group transformations such as A) Synthesis Polymers- Introduction, types of polymerization,
complex metal hydrides, Gillmen reagents, Lithium dialkyl Mechanism of condensation Polymerization, Addition
cuprate LDA, DCC, Trimethyl silyl Iodide, Tributyl Tin polymerization free radical cationic, anionic and co-
hydride, Woodward and Prevost Hydroxylation, DDQ, polymerization, chain transfer agents, stereoregulated
Peterson Synthesis, Wilkinson’s Catalyst, Becker Yeast. polymers. Atactic, Isotactic and syndiotactic polymers.
 65 66
B) Study of synthetic Rubbers: Buna S SBR, cold rubber, Buna B) Antimalerial : Chemotherapy of maleria, Aminoquinolines,
N,NBR,Butyl Rubber, polyisoprene, ployurethanes, pamaquine,chloroquineand sulphones.
vulcanization mechanism,foaming agents, plasticizers, C) Antipyretic and Analgesic: Aspirin, salol, phenacetin,
statrilizers, silicones. antipyrin.
Unit-II : General aspects of drug: 12L Unit-V: Vitamin and Natural Pigments 12L
Historical, Definations used in drug chemistry-pharmacy, A) Vitamins: Structure determination and chemistry of Thiamine
pharmacology, pharmacodynamics, pharmacodynamic (Vitamin D) Ascorbic acid (Vitamin C) Vitamin E and A.
agents,metabolite and antimetabolites,gram positive and B) Natural Pigments: Chemistry of Carotenes, anthocyarins,
gram negative Bacteria, Virus, Actinomucetes, Mutation, General study of porphyrins, structure and synthesis of
Chemotherapy, Nomenclature of medicinal compounds. Hemoglobin and chlorophyll.
Classification of drugs on basis of their
Therapeutic actions. Books suggested :
1. Chemotherapeutic agents 1) Chemistry of alkloids-SW Pelletier.
2. Pharmacodynamic agents 2) Chemistry of steroids-LF fisher & M fisher.
Mechanism of Chemotherapeutic action: 3) The molecules of nature-JB hendricsion.
1. Biological defences 4) Biogenesis of natural compound-benfield
2. Chemical defences 5) Natural product chemistry & biological significance,J.Mann,RS
a) Surface active agents devison,JB hobbs,DV Banthripde & JB horborne.
b) Metabolic Antagonism 6) Introduction to flavonoids-BA Bohm, Harwood
Assay of Drugs: 7) Chemistry of naturally occurring quinines-RH Thomson
1. Chemical assay 8) The systematic identification of flavonoids-marby, markham,
&thomos
2. Biological assay
9) Text book of organic medicinal chemistry-wilson,geswold
3. Immunological assay
10) Medicinal chemistry Vil I &II-Burger
Unit-III DRUGS DESIGN: 12L
11) Synthetic organic chemistry-Gurudeep chatwal.
Development of new drugs, procedures followed in drug
12) Organic chemistry of natural products Vol I &II-OP agrawal
design. Concept Of lead compound and modification
concept of Prodrugs and Softdrugs structure activity 13) Organic chemistry of natural products-Gurudeep chatwal
relationship (SAR) Factors affecting bioactivity resonance, 14) A textbook of pharmaceitical chemistry-Jayshree Ghosh
inductive effect, isosterism, Biosterism, Spatial 15) Synthetic dyes series-venkatraman
consideration, theories of drug activity occupancy theory, 16) Chemistry process industries-shreve & brink
Rate theory induced tit theory, Quantitative structure 17) Principal of modern heterocyclic chemistry-LA paquelte
activity relationship. 18) Heterocyclic chemistry-J Joule &G smith
History and development of QASAR, Concept of drug 19) Heterocyclic chemistry-morton
receptor interaction,Physico-Chemical parameter. 20) An introduction to chemistry of heterocyclic compound-JB
Lipophilicity, Partition coefficient Electronic ionization acheson
constants,Steric Shelton and surface activity parameters 21) Introduction to medicinal chemistry-A gringuadge
and redox potential. Free Wilson analysis, Hansch analysis
22) Wilson &Gisvold text book of organic medicinal & pharmaceitical
LD-50,ED-50(Mathematical derivatives of equations
chemistry-Ed.Robert F dorge
included)
23) An introduction to drug design-SS pandey,& JR demmock
Unit-IV : MEDICINAL CHEMISTRY 12L
24) Goodman and Gilmans pharmacological basis of therapeutics-
A) Antibiotics: Introduction, Penicillin V And G, Streptomycin,
25) Stragies for organic drug sythesis & design-D lednicer
Chloram phenicol, Tetracyclins.
26) Polymer science-v govarikar
 67 68
27) Principle of polymer chemistry-PJ flory Unit-V Reaction Dynamics:
28) An outline of polymer chemistry-james q.allen A) Molecular dynamical calculations for H + H2, Br + H2, and
29) Organic polymer chemistry-KJ Saunders. more complex reactions. Chemi-luminescence: highly dilute
flames, diffusion flames. 6L
Semester IV B) Molecular beams: Stripping and rebound mechanism, state
Paper- XV to state kinetics, influence of reactant vibrational energy
Special Paper-III and rotational energy, spectroscopy of transition species.
Physical Chemistry 6L
60 Hours (4-Hours/week) 50 Marks 12 hours/Unit List of Books:
Unit-I : Liquid Crystals: 1) Physical chemistry by P.W.Atkins & dePaula 7Th Edition
A) Mesomorphic behavior, thermotropic liquid crystals, 2) Chemical Kinetics by K.J. Laidler. IIIrd Edition. Pearson Education.
nematic and sematic meso phases, sematic and nematic 3) Liquid State by J.A. Pryde.
transitions, and clearing temperature, twisted nematics, 4) Theorotropic Liquid Crystals by G.W. Gray, Wiley
cheral nematics molecular arrangement in sematic A and 5) Hand Book of Liquid Crystals by Kelkar & Hatz, Chemie Verlag.
Sematic C phases, optical properties of liquid crystals 6) A Dynamic Liquid State, A. F.M. Barton, Longman.
6L 7) Chemical Kinetics & Dynamics by J.I. Steinfeld, J.S. Francisco &
B) General properties of liquids: liquid as dense gases, liquid W.L.Hase. Printice Hall. 1989.
as disorder solid, different types of intermolecular forces in 8) Kinetic & Mechanism of Chemical Transformation by J. Rajaram &
liquids, theory of liquids. 6L. J. Kuriacose, McMillion.
Unit-II Isotope Effect:
Semester IV
Equilibrium isotope effects, equilibria in solution, primary
kinetic isotope effect, semi classical treatment, quantum Paper- XVI
mechanical tunneling, reactions of Muonium, isotope Special Paper-IV
effects of heavy atoms, secondary kinetic isotope effect. Physical Chemistry
12L 60 Hours (4-Hours/week) 50 Marks 12 hours/Unit
Unit-III Reactions in solutions: Unit-I Nuclear Chemistry:
A) Reaction between ions: Influence of solvent, dielectric A) General characteristics of radioactive decay, decay kinetics
constant & ionic strength, pre-exponential factor, single parent daughter decay growth relationship. a- decay, a-
sphere activated complex. 6L. decay , nuclear de-excitation, Secular and transient
B) Ion dipole & dipole-dipole reaction, Diffusion controlled equilibrium, a- particle energy spectrum, Geiger-Nuttal’s Law,
reaction, influence of hydrostatic pressure, substitutent and Theory of a, band g decay process, 6L.
correlation effect. Hammett equation, compensation effect, B) Detection and measurement of activity: The electrometer,
diffusion controlled reaction: full microscopic and partial the ionization chamber, electro pulse counter, scintillation,
microscopic diffusion controlled and ionic reactions. semiconductor, thermo-luminescence and neutron detector.
6L. 6L.
Unit-IV Chemical kinetic methods: Unit-II Nuclear reactions:
A) Basic principle of chemical relaxation method, chemical Bathe’s notation, types of nuclear reactions, conservation
relaxation in two and multi-step systems, thermodynamic in nuclear reaction, reaction cross section, compound
aspect of chemical relaxation. 6L. nucleus theory, experimental evidence of Bohr’s theory:
B) Experimental methods for relaxation kinetics and Experiments of Ghoshal, of Alexander and Simonoff specific
applications: Temperature jump method, electrical field jump nuclear reactions, trans uraniens, photonuclear reactions,
method, ultrasonic relaxation method. 6L. thermonuclear reaction, fusion reactors, origin and
evolution of elements. 12L
 69 70
Unit-III Nuclear fission: B) Amination by reduction: Introduction, methods of
A) Process of nuclear fission, fission fragments and their mass reduction metal & acid, sulphide reduction, metal & alkali
and charge distribution. Fission energy, fission cross- reduction, manufacture of aniline, meta nitro aniline
section and threshold. Theory of nuclear fission, fission C) Halogenation: introduction, reagents of halogenation,
neutrons, other types of nuclear fissions. 6L. aromatic halogenation, manufacture of chlorobenzene,
B) Nuclear reactors: Nature’s nuclear reactor, Natural Uranium dichlorofluromethane
reactor, classification of reactors critical size of thermal Unit-II A) Sulphonation: introduction, sulphonating agents, factor
reactors, the breeder reactors. Reprocessing of spent fuel, affecting sulphonation, equipment, manufacture of benzene
nuclear waste management. 6L. sulphonic acid, sulphonation of anthraquinone
Unit-IV Radiation Chemistry: B) Oxidation: introduction, oxidizing agents, vapour & liquid
Interaction of radiation with matter, Radiation track spurs phase oxidation, manufacture of acetic acid, acetaldehyde,
and d-rays, linear energy transfer, Bathes equation for linear benzoic acid.
energy transfer, Bremsstrahlung effect. Passage of neutron C) Hydrogenation: introduction, catalyst used for
through matter, Interaction of g-radiation with matter: hydrogenation, hydrogenation of vegetable oil,
photoelectric effect and Compton effect, pair production manufacture of methanol,
phenomenon, units of measuring radiation absorption, Unit-III A) Esterification: Introduction, esterification by organic acids,
radiolysis of water, radiolysis of some aqueous solutions. esters by adding unsaturated systems, manufacture of ethyl
12L. acetate, cellulose acetate.
Unit-V A) Radiation dosimetry: Unit of radiation energy , chemical B) Hydrolysis: introduction, hydrolysis agents, acid
dosimeter, Fricke dosimeter and ceric sulphate dosimeter, hydrolysis alkali hydrolysis, enzymatic hydrolysis, factors
conversion of measured dose values, Distribution prp of affecting hydrolysis,.
water, free radicals in water, radiation induced color centers C) Alkylaion: Introduction, alkylting agents, factors affecting
in crystals. 6L. alkylation, manufacture of ethyl benzene, phenyl ethyl
B) Applications of radioactivity: Probing by isotopes, the alcohol
Szilard-Chalmers reaction, cow and milk system. Principle Unit-IV - Petroleum Refining and Petrochemical Technology :
and applications of radioisotopes as tracers, radioisotopes A) Petroleum refining practice
as source of electricity. 6L. - Petroleum Refining in India
List of Books: - Indian Standards for Motor gasoline, Kerosene and Diesel
1) Introduction to radiation chemistry by J.W.T. Spinks and - Atmospheric and vacuum distillation of crude
R.J.Woods.
- Petroleum coking and visbreking
2) Essentials of Nuclear chemistry by S.J.Arnikar.
- Fluidised catalytic cracking, catalytic reforming, catalytic
alkylation, catalytic isomerisation.
Semester IV - Hydrocracking & Hydotreating
Paper XV - Lube processing.
Special Paper-III B) Petrochemical Industry :
(Unit Processes) - Petrochemical Industry in India
Industrial Chemistry - Petrochemical Feed stocks.
60hrs (4hrs/week). 12hrs/unit 50 Marks - Naphtha cracking & separation and purification of olefins
Unit-I A) Nitration: Introduction, nitrating agents, equipment for to get ethylene, propylene, butylenes etc.
nitration, manufacture of nitrobenzene, Ortho and para - Manufacture of BTX aromatics
nitrochlorobenzene.
- Butadiene & Xylenes separation techniques.
- Important monomers like, Styrene, DMT & Caprolactum.
 71 72
Unit-V - Polymers 11. Polymer Science by V. Govarikar, N. Viswanathan and J. Sreedhar,
1) Nomenclature, classification of polymer : Natural and New Age International (P) Ltd. Publishers New Delhi
synthetic polymers, organic and inorganic polymers, 12. Physical chemistry of polymers by D. D. Deshpande, Tata McGraw
thermoplastic and thermosetting polymers, plastic Hill.
elastomers, fibres and liquid resin, block & graft copolymers. 13. Principles of polymer chemistry By P. J. Flory, Cornell Univ. Press.
2) Types of polymerization: Addition (chain) : 14. Introduction to polymer chemistry by R. B. Seymour McGraw Hill.
Polymerization- free radical, ionic, coordination and their 15. A Practical Course in polymer chemistry by S. J. Pnnea, Pergamon
mechanism, condensation (step) polymerization press.
polycondensation, polyaddition, ring opening, linear and 16. Labortary preparation of macro chemistry by E. M. M. Effery
cross-linked and their mechanism, copolymerisation. McGraw Hill.
3) Techniques of polymerization : Bulk, solution, suspension
and emulsion polymerization. Semester IV
4) Molecular weight and size : Number-average and weight- Paper XVI
average molecular weights viscosity-average molecular Special Paper-IV
weight, degree of polymerization, significance of polymer (Chemical Processes Industries)
molecular weight, size of polymer molecule; molecular Industrial Chemistry
weight determination: by Osmometry (membrane & vapour 60hrs (4hrs/week). 12hrs/unit 50 Marks
phase), end group analysis, viscometry and light scattering Unit-I : Dyes 12L
methods. i) Chemistry of dyes :- Introduction, classification of dyes on
5) Physical characteristics of polymers : Glass transition the basis of structure and the mode of application to the
temperature and crystallinity of polymer, Determination of fibre. Colour and chemical constitution of dyes. General
Glass transition temperature. methods of preparation of important azodyes, Cyanindyes
6) Manufacturing, properties and uses of following polymers: and anthraquinone vat dyes.
i) Natural and synthetic rubber ii) Chemistry of intermediates :- Introduction to the history of
ii) Synthetic fibers – polyesters, polyamides, rayons dyes. Natural to synthetic dyes.
iii) Synthetic plastics : Polyoliefins, polyurathanes 1) Manufacturing, properties and uses of following
iv) Silicones polymers:
i) Natural and synthetic rubber
List of Books-
ii) Synthetic fibers – polyesters, polyamides, rayons
1. Unit Process in Organic Synthesis, by P. H. Grogins
iii) Synthetic plastics : Polyoliefins, polyurathanes
2. Modern Petroleum Technology by G. D. Hobson and W. Pohl.
iv) Silicones
3. Petroleum refining and engineering by W. L. Nelson.
Mediates: - chloronitrobeneze Nitroanilines,
4. Petroleum refining technology and economics by J. H. Gary and G.
diaminobenzenes.
E. Hardwork.
Napthalene intermediates :- Napthyl sulphuric acids, Naphyl
5. The Petroleum chemical industry by Goldsteim andWaddams.
amine sulphuric acids.
6. Petroleum processing handbook by W. E. Bland and R. L. Davidson.
Mescallaneous
7. The Text book on Petrochemical by Dr. B. K. Bhaskar Rao, Khanna
i) Amino anthraquinones, methyl & methylamino
Publishers New Delhi.
anthraquinones, Disperse dye intermediates, disperse
8. Modern Petroleum refining Processes by Dr. B. K. Bhaskar Rao,
– reactive intermediates.
Oxford, IBH, 1984
9. Petroleum product handbook, V. B. Guthrie.
10. Textbook of polymer science by F. Bill Mayer, Wiley Inter Science.
 73 74
ii) Analysis & applications of dyes :- Different methods Unit-IV : Pharmaceuticals 12L
used in analysis, Nitrate value determination, Coupling Product profile study of the following drugs and
value, titanius chloride reduction, metal estimations – intermediates with particular stress on the manufacturing
Cu, Ni, Cr etc. process engineering problems involved, quality control,
Dying methods :- Dying methods for direct, acid, reactive equipment and economics ;
disperse, vat, cataionic, sulphur, indigo and azoics. i) Sulpha drugs :- Sulphaguanidine, sulphamethoxazole.
Unit-II : Sugar Industries 12L ii) Antimicrobial :- chloramphenicol, streptomycin,
Manufacturing of sugar from sugarcane : Introduction, Tetracyclines cifron.
agriculcture, harvesting, preparation of cane for mealing, iii) Anagesic :- anti inflammatory, Acetyl Salicyclic acid,
juice extraction, diffusion, juice purification, evaporation, Ibuprofen, paracetamol.
crystlisation (production of raw sugar), centrifugation, iv) Vitamin – Vit, A. Vit. B6 , Vit. C
sugar refining, decolouring, purification, filtration, v) Barbiturates :- Pentobarbital
crystlisation grade analysis. vi) Beta- blockers :- proranolol, atenolol, Beta-Nifedine, (
Analysis of bagasse and molasses, byproducts of sugar Antihyperpension )
industries. vii) Cardiovscular gent :- Methyldopa, enalaprilmaleate,
Unit-III : Pulp and paper industries 12 Benazeprill.
A) Chemistry of paper making, raw materials- viii) Antihistamines – Chloropheneramine maleate,
- physical properties of wood, classification of woods, plants ix) Antidepressants – Resperidone, sertraline
used in pulp & paper , grass. x) Anticancer drugs & antiaids.
- Chemical composition of wood , non-weedy fibers used in Unit-V : Agrochemicals 12L
pulping
Inorganic insecticides :- Arsenic insecticides, fluoro
- Lignin-lignification of wood, chemical aspects of lignin insecticides
formation .
Insecticides of plant origins: - Nicotine, nornicotine,
- Structure & properties of lignin pyrethroids, ratenoids, analagin, allethnin.
B) Pulping: Chlorinated hydrocarbon:- DDT, dilan sulphenex, DFDT,
Preparation of pulp, wood, cheeps endosulphan.
Manufacture of mechanical pulp, woods used , types , Organophosphorus Insecticides :-
grades& uses. Dithiophoshoric acid derivatives :- Melathion, dimethoate
Equipment for ground wood pulping process , dimecron.
Semichemical pulping, wood preparation, digesters Diphosphoric acid derivatives :- Parathion, methyl
Steam cooking parathion, thiophos, chlorthion, paraoxon.
Utilisation of secondary fibres. Pyrophosphoric acid derivatives.
Rag pulping Sulphotepp, sohhradan.
C) Bleaching Other organosphosphorus Insecticites.
- bleaching of wood pulp-bleaching practice Isopertox, trichlorofin.
- stock preparation-internal sizing of papers Carbamate insecticides.
- Filling paper manufacture - Additives Carlang, isolom, phyrolan, bygon.
- types of paper machine - sheet formation Fungicides:-
- press section - drying of papers Inorganic Fungicides:-
-cylinder mould type -calendaring Sulphur, limesulphur, copper sulphate, Bordeaux paste,
- Speciality papers-injection moulding Bordeaux paint, Burgundy, copper oxychlorite.
 75 76
Organomercuric compounds:- source of impurities in pharmaceutical raw materials such as
Ethyl mercuric chloride, cereasn Dithiocarbamates- Ziram, chemicals, reagents and solvents, atmospheric and microbial
thiram,Zinc, captan. contaminants, packing errors,chemical instability,container
Miscallaneous fungicides :- Polpet, Bavistin contamination,physical changes,temperature effects,
manufacturing and storage effects. General manufacturing
List of Books- processes, stability studies,shelf life fixation for formulated
1. Synthetic dyes by Venkatram (VOL I &II) products.Introduction to pharmaceutical formulations,
2. Fundamental processes of dye chemistry, by Fietz. Standardization, Evaluation analysis of common drugs,
3. Dyes and Intermediates by Adrahaedt Antibiotics-Chloramphenicol, Ampicilline, Terramycine.
4. Chemical Process Industries by R. N. Shreves and M. J. A. Brink. Vitamins- Vitamin B12, B6, Vitamin K
5. Pulp and paper chemistry and chemical Technology by James P. Sulpha drugs-Sulphaguandine, Sulphapyrazine,
Casey Sulphanilamide Analysis of common drugs (aspirin,
6. The chemistry of cellulose by Emit Ptauseg, John wiley and sons, paracetamol etc..)
New York.
7. Indian Pharmacopoeia, 1985 Unit-II : 12L
a) Analysis of petroleum and petroleum products-
8. British pharamacopoeia, 1990
Introduction,constituents and fractionation,Quality control
9. Textbook of Organic Medicinal and Pharmaceutical Chemistry by requirements of petrol and petroleum products, safety and
Willson, Jisvold, Dejja, Lippinett Toppan. hazarodous aspects .Analysis of petroleum products-specific
10 Essentials of Medicinal Chemistry by Korolkovas and Burkhatter- gravity,viscosity,doctor test,sulphuric acid absorption,aniline
Wiley-Interscience. point,vapour pressur and colour determination,cloud
11. Pharmaceutical Dosage forms point,pour point.Determination of water,neutralization
12. Pesticites-Color Publications,P. L. Bombay value,ash content estimation of sulphur and lead in petrol.
13. Elements of Plant Protection by L. L. Pyenson, John Wiley and b) Analysis of Explosive -General methods,heat of
sons. explosion,hygroscopicity,moisture by Karl Fischer
14. Chemistry of Pesticides by N. N. Melnikov Springer-Verlag, New titration,qualitative tests of explosives,qualitataive analysis
York of explosive mixtures,Dynamites .Blasting caps and electric
15. Fungicites in Plant Disease control by Y. L. Nines, Oxford and IBH detonators,primers,liquid propellants and solid propellants
Publishing company New Dehli.
16. Methods Pesticides Analysis by Sree Ramuly, U. I. Oxford and Unit-III : 12L
IBH Publishers. Analysis of Paints,soap and detregents
17. Charles E. Dryden, Outline of Chemical Technology Edited by M. Analysis of Paints and Pigments-Preliminary inspection of
Gopal Rao and Marshall Siting, East West Press 2nd Edition 1973. sample,Test on the total coating.Separation of
pigments,binder and thinner of latex paints,
determination of volatile and non volatile constituents, flash
Semester-IV
points, separation of pigments, estimation of binders and
Paper XV
thiners. Modification of binder. Identification and analysis
Analytical Chemistry
of thinner.
Analysis of commercial products
Analysis of soaps-
Total Lectures: 60Hrs, 4Hrsper week, 12Hrs/unit Total Marks-80
General idea of soaps and detergents, sampling,
separation,identification , determination of soap
Unit-I : 12L
composition-fatty acids,total anhydrous soap and combined
Pharmaceutical analysis:-
Requirement of a quality control laboratory for
pharmaceutical units, SOP of sophisticated instruments,
 77 78
alkali,potassium,water,determination of inorganic fillers and List of Books-
soap builders,determaination of other additives. 1. Pharmacoepia of India Volume I and II.
Analysis of Detergents- types,method of analysis, sampling, 2. Aids to the Analysis of Food and Drug by Nicholls
separation,identification of components ,deternmination of 3. Standard Methods of Chemical Analysis. 6th Ed. Vol I & II
surfactants, determination of surfactants-anionic, cationic, (D.Van.Nostard comp) by F.J.Welcher
non-ionic. Determination of Abrasives, Ammonia, 4. Forensic pharmacy by B.S Kuchekar, A.M Khadatare (Nirali
Carbonates, Cellulose, Glycerine, Silicates, Sulphates, Prakashan)
Phosphates, moisture content, saponification value. 5. Treatise on Analytical Chemistry Vol..I & II by L.M.Kolthoff.
Analytical techniques used for analysis of soaps and 6. Separation Chemistry in Chemistry and Biochemistry. By Roy
detergents Keller, M Decker Inc
7. G. D. Christian: Analytical Chemistry
Unit-IV : 12L 8. Handbook of Analysis and Quality, Control for Fruits and
Forensic Analysis- Vegetable Products 2nd Ed Mc.Graw hill) by S.Ranganna.
General introduction of forensic analysis, sampling,sample 9. Encyclopedia of Industrial chemical Analysis Vol I to 20 (John
storage,sample dissolution,classification of poisons,lethal Wiley) Riech
dose,significance of LD-50 and LC-50,general discussion of 10. Cosmetics by W D Poucher (Three volumes)
poisons with special reference to ode of action of 11. Willard, Merritt and Dean: Instrumental methods of Analysis
cyanide,organophosphate and snake venom. 12. Strouts, Crifillan and Wison: Analytical Chemistry.
Analytical toxicology: Isolation, Identification, Estimation 13 Texbook of Forenisc pharmacy- B. M. Mithal 9th Edn (1993)
of poisonous materials such as lead,mercury and arsenic in National Centre, Calcutta. V. Malik, Drug and Cometics Act.
biological samples.Quantification of drugs, insecticides, 14. Textbook of Forensic Pharmacy by B M Mithal 9th edition 1993,
alkaloids and other products of synthetic and natural origin, National Centre Kolcutta
ethyl alcohol, methyl alcohol, Zinc phosphides, effects of 15. Forensic Pharmacy by B.S Kuchekar, and A.M Khadatare Nirali
Kerosene and cooking gas. General discussion, Diagonosis Prakshan
and Management of poison, food poisoning, narcotic,
stimulants, paralytic, antihistamine. Semester-IV
Paper XVI
Unit-V : 12L Analytical Chemistry (Special Paper-IV)
Analysis of cosmetics, creams, lotions and hair dyes:- Applied analytical chemistry
a) Composition of creams and lotions: Determination of Total Lectures: 60Hrs, 4Hrsper week, 12Hrs/unit Total Marks-80
water, propylene glycol, non-volatile matter and ash Unit-I : 12L
content, analysis of borates, carbonates, sulphates, Agricultural analysis-I
phosphate, chloride, Titanium and Zinc oxide. Soil analysis- Classification and composition , Soil formation,
b) Analysis of face powder: Estimation of boric acid, Mg, weathering, (especially SRMs), composition soil sampling,
Ca, Zn, Fe, Al and Ba field description of soils, physical analysis,determination of
c) Analysis of deodorants and antiperspirants- major and minor constituents,exchange capacity,soil
composition,analysis of fats and fatty acids,boric reaction,chemical analysis as a measure of soil fertility.
acid,magnesium,calcium,zinc,iron,titanium,aluminium,phenol,hexachlorophenone,methanamine,sulphonates Analysis of constituents such as Nitrogen, Phosphorus,
and urea. Potassium and micronutrients.
d) Analysis of ingredients of hair dyes. Stock feeds analysis - feeding stuffs,qualitative analysis and
e) Analysis of Vanishing cream quantitative analysis.
f) Analysis of Lipsticks Plant analysis- Preparation of sample, moisture
determination- methods of ashing,methods of plant
 79 80
analysis- starch, sugars, determination of mineral Case studies-Bhopal gas, chronobyal, Three Mile Island
constituents (Fe, Mn,Mo, Si, Ca, Mg, P, S, C and N). minamata disasters.

Unit-II : Agricultural Analysis-II 12L Unit-V : Analysis of mineral materials:

Analysis of Fertilizers- Sampling, sample preparation. 12L
Analysis of nitrogen, phosphrousand potassium. Nitrogen: a) Cement-Loss on ignitation,insoluble residue,total
urea nitrogen, total Kjeldahl nitrogen method, s i l i c a , s e s q u i ox i od e s , l i m e , m a g n e s i a , fe r r i c
Ammonianitrogen, phosphrous: total phosphrous. available oxide,sulphuric anhydride,air and dust pollution from
and non-available, alkalimetricammonium cement plants,atmospheric dispersion of pollutants in
molybdophosphate method, potassium : potassium by cement industry.
sodium tetraphenylborate method. b) Glass and Glass-Ceramics-
Pesticides and insecticides analysis-Introduction, Introduction,composition,methods of analysis-
classification, Analysis of organochlorine, sampling and sapling preparation,composition analysis-
organophosphorus and carbonate pesticides, analysis of prelminary testing,decomposition.Chemical method for
DDT, gammexane, endosulphan, zinab, ziram, malathion, the individual constituents-Si,B,Pb,Zn,Al,Cl,Mg,Ti.
thiram, thiometon, simazine and chloridane . Green List of Books-
technologies in agriculture industries and water resource 1. Agricultural Analysis. By Kanwar
managements 2. A. I. Vogel: A text book of quantitative Inorganic analysis.
3. Soil Analysis. By Jackson.
Unit-III 12L 4. Encyclopedia of Industrial Methods of Chemical Analysis. By F D
Analysis of minerals, ores and alloys Snell ( All senus).
a) Minerals and ores-Hematite, pyrolusite, ypsum, dolomite 5. G. W. Ewing: Instrumental Methods of Chemical Analysis.
chromate, bauxite, limestone, illmenite and uranium ores. 6. Standard Methods of Chemical Analysis. By F J Welchar
b) Metal and alloys analysis- iron, different kinds of 7. G. D. Christian: Analytical Chemistry
iron,steel,Cu-Ni alloy,solder,bronze,aluminium 8. S. M. Khopkar: Basic Concept of Analytical Chemistry.
alloy,ferroallys of 9. Handbook of Air Pollution. By Stern, APHA , 1980.
silicon,molybdenum,chromium,titanium and vanadium. 10. Fundamentals of Analytical Chemistry 6th edition by D.A.Skoog,
D.M.West and F.S.Holler
Unit-IV : 12L 11. Industrial Chemistry by B.K.Sharma.
Industrial pollution- Sugar industry, paper and pulp industry, 12. Strouts, Crifillan and Wison: Analytical Chemistry.
nuclear power plant, polymer drugs, radionuclide analysis, 13. Principle and practice of Analytical chemistry by F.U.Fifield and
disposal of wastes and their management.Principles of D.Keuley 3rd edition,Blackie and sons Ltd..
decomposition Biodegradability, classification of hazardous 14. S. A. Skoog and D. W. West: Fundamental 0f Analytical Chemistry.
substances andwater, chemical classes of hazardous wastes, 15. Pollution Control in Process Industries by S.P.Mahajan.
hazardous substances to health betterindustrial process.
Industrial Operation and Green Methodology . Introduction Semester IV
and evolution of green chemistry, green reagents, solvents Practical-VII
and catalysts Inorganic Chemistry Special
Hazardous substance analysis- nature, source, treatment and Pracitcal Workload 9 Hrs./week Time: 9-12 hours Marks: 100
disposal of hazardouswaste, classification of hazardous
Unit-I 1) Extraction and absorption spectral study of chlorophylls
substants and wastes, origin, toxic substances,
from green leaves.
chemical,classification hazardous wastes, physical and
chemical methods of wastes treatment andpreparation of 2) Determination of Phosphates from cold drink samples by
waste and ultimate disposal of hazardous waste. spectrophotometry.
 81 82
3) Analysis of talcum and nyclin powders (Mg-complexometry, Book Suggested:
ZnO/H3BO3) 1. Synthesis and Characterization of Inorganic Compounds, W. L.
4) Determination of iron in soap bar. Jolly, Prentice Hall.
5) Analysis of N, P, K from fertilizer 2. Inorganic Experiments, J. Derck Woollins, VCH.
6) Analysis of cement/paint/soil. 3. Practical Inorganic Chemistry, G. Marrand, B. W. Rockett, Van
Unit-II : Study of complex formation: Nostrand.
1) To determine the formula and formation of a complex by 4. A Text Book of Quantitative Inorganic Analysis, A. I.
spectrophotometry (Job’s/ mole/Slope ratio methods) Vogel,Longoman.
2) To determine stepwise proton-ligand and metal-ligand 5. EDTA Titrations. F. Laschka
stability constant of complex by Irving-Rossotti method. 6. Instrumental Methods of Analysis, Willard, Merit and Dean (CBS,
3) To determine the instability constant of complex by Delhi).
potentiometry (AgNH3, Ag-thiosulphate) 7. Inorganic Synthesis, Jolly
4) To determine the composition and formation constant of a 8. Instrumental Methods of Chemical Analysis, Yelri Lalikov
Fe-SSA complex by conductometry. 9. Fundamental of Analytical Chemistry, Skoog D.A. &West D.M
5) Determination of composition and stability constant of Holt Rinehart &Winston Inc.
complex by polarography. 10. Experimental Inorganic Chemistry, W.G.Palmer, Cambridge.
Unit-III : Inorganic reaction mechanism: 11. Solid state Chemistry, N.B.Hanney
Kinetics and mechanism of following reactions: 12. Introduction to Thermal Analysis, Techniques&Applications,
1) Substitution reactions in octahedral complexes (Acid/Base M.E.Brown, Springer
hydrolysis) 13. Preparation and Properties of solid state Materials, Wilcox, Vol.
2) Redox reactions in octahedral complexes. I&II, Dekker
3) Isomerization reaction of octahedral complexes. 14. The Structure and Properties of Materials Vol.IV, JohnWulff, Wiley
4) Enzyme kinetics in presence of metal ions. Eastern.
5) To determine the corrosion rate of metal strip.
The Practical examination will be based on the Inorganic Chemistry.
6) To study the 1,10 phenanthroline as corrosion inhibitor for
mild steel in sulphuric acid. Time: 6-8 hours (Two days examination) Marks: 100
7) To study the adsorption and desorption of gases on I) Exercise -1 (Synthesis &Analysis) - 40 Marks
heterogeneous catalyst. II) Exercise-2 (Kinetics/complex) - 40 Marks
Unit-IV: Solid State: III) Record - 10 Marks
1) Preparation of oxides and mixed oxides (Mn2O3, NiO, Cu2O, IV) Viva- Voce - 10 Marks
Fe3O4, ZnFe2O4, ZnMn2O4, CuMn2O4 and NiFe2O4) Total -100 Marks
2) Preparation of Silica and Alumina by sol-Gel technique.
3) To study the electrical conductivity of ferrites, Magnetites,
doped oxides and pure samples and determine band gap. SEMESTER IV
Unit-V : Two/Three steps synthesis and characterization: Practical VII
Synthesis of metal complexes/Polymers/Lanthanide
Organic Chemistry Special
complexes and their structural characterizations by possible
physical methods such as: elemental analysis (N, S, M % Pracitcal Workload 9 Hrs./week Time: 9-12 hours Marks: 100
etc.), m.p. Solubility, MW, molar conductance, magnetic
moment, thermogravemetric analysis, IR and electronic
spectral data, determination of crystal field parameters
(minimum five)
 83 84
Unit-I : QUALITATIVE ANALYSIS. 6. Small scale organic preparation-P.J. Hill
Separation of the components of a mixture of three organic 7. Practical organic chemistry-H. Dupont Durst & George W.Gokal.
compounds (three solids, two solids and one liquid, two 8. Experimental organic chemistry Part I & II, P. R. Singh, D. S.Gupta
liquids and one solid, all three liquids and identification of & K.S. Bajpai.
any two components using chemical methods or physical 9. Vogel’s textbook of practical organic chemistry-A.R. Tatchell
techniques. Purification of the compounds by crystallization,
chromatographic techniques (Minimum of 12 mixtures to Semester IV
be done) Practical-VII
UNIT-II : ORGANIC ESTIMATION Physical Chemistry Special
Organic Estimation.
1. Estimation of nitrogen. Pracitcal Workload 9 Hrs./week Time: 9-12 hours Marks: 100
2. Estimation of halogen. Use of Computer Programes 5 terms of practicals.
3. Estimation of sulphur. Treatment of experimental data, X-Y plots, programs with data preferably
Spectrophotometric/calorimetric Estimation. from physical chemistry practical. Students will operate two packages I)
4. Estimation of streptomycin sulphate. MS-Word and II) MS-Excel.
5. Estimation of B-12. Part-A
6. Estimation of amino acids. 1) To find out Energy of activation & Temperature coefficient of
7. Estimation of proteins. hydrolysis of methyl / ethyl acetate
8. Estimation of carbohydrates. 2) To find out Energy of activation of the reaction between potassium
9. Estimation of Ascorbic acid. persulphate & potassium iodide.
10. Estimation of Aspirin. 3) Determination of partial molar volume of solute and solvent in
11. Solvent extraction of oil from oil seeds and determination binary mixture.
of saponification value, iodine value of the same oil. 4) To study the variation of solubility of calcium sulphate with ionic
strength and hence determine thermodynamic solubility product.
Organic practical :
5) To study the adsorption of acetic acid on charcoal and prove the
Two Days Examination - 9-12 Hrs. 100 Marks
validity of Frendich and Langmuir adsorption isotherm.
6) To determine the critical micelle concentration of soap.
Distribution of marks:
7) To determine the molecular weight of high polymer by viscosity
Unit I …… 40 measurement.
Unit II ……… 40 8) To find out partition coefficient of Iodine/Benzoic/Salicylic acid
Record 10 between benzene and water.
Viva-voce 10 Part-B
TOTAL 100 1) Determination of half wave potential of metal ions by polarography.
2) Simultaneous determination of suitable of metal ion by
BOOKS SUGGESTED :- polarography
1. Textbook of practical organic chemistry qualitative and quantitative 3) Analysis of aspirin conductometrically and potentiometrically
analysis (Vol I &II)- A.I. Vogel. 4) Determination of sodium , potassium, lithium and calcium by Flame
2. Elementary practical organic chemistry small scale preparation photometric individually and mixture.
(Langman)- A.I. Vogel. 5) Elecronics measurement of resistance with multimeter and use of
3. A handbook of organic analysis.-H.T.Clark. Wistone Bridge for accurate measurement of resistance.
4. Systematic qualitative organic analysis –H. Middeton. 6) Determine the dipole moment of given liquid.
5. Advanced practical organic chemistry-N. K. Vishnoi.
 85 86
7) Plot the current voltage curve for copper sulphate and sulphuric 14) Qualitative analysis of commercial available drugs including
acid using bridge platinum electrode. chromatographic technique.
8) Determine the transport number of ions by moving boundary 15) Preparation of simple drugs involving two or three steps.
method. 16) Preparation of melamine – HCHO resin.
9) Determine the composition of binary mixture 17) Determination of number average molecular weight (Mn) by end
spectrophotometrically group analysis by conductmetric method.
18) Determination of average molecular weight of polymer by
Physical Chemistry Practical :
viscometric method.
Distribution of marks:
19) Determination of reducing sugar in cane juice.
Two Days Examination - 9-12 Hrs. 100 Marks
20) Determination of moisture content and ash content of wood sample.
Unit A …… 40
21) Experiments based on simple & fractional crystallization.
Unit B ……… 40
22) Analysis of nonfibrous materials used in pulp industries such as
Record 10
caustic soda as Na2O, Soda ash as Na2O, lime as CaO.
Viva-voce 10 23) Extraction of essential oils from medicinal plants (Tikhadi).
TOTAL 100 24) Separation of Chromium (VI) & Chromium (III) by TLC in wastewater
sample from electroplating industry.
Semester IV 25) Preparation of selected pesticide formulations in the form of dusts,
Pratical-VII emulsions, sprays.
Industrial Chemistry Special 26) Determination of calorific value of fuels.
Pracitcal Workload 9 Hrs./week Time: 9-12 hours Marks: 100 Distribution of marks:
Multi step organic Synthesis: The Practical examination will be based on the syllabus for Industrial
1) Nitrobenzene - m-dinitrobenzene – m-nitroaniline- m-nitrophenol. Chemistry (Elective Paper).
Anthranilic acid – phenylglycine orthocarboxylic acid – indigo Time: 9-12 hours (Two days examination) Marks: 100
2) Cyclohehanone – cyclohexanone oxime – caprolactum. I) Exercise -1 (Synthesis) - 40 Marks
3) Preparation of P- bromoanaline from analine. II) Exercise-2 (Analysis) - 40 Marks
4) Preparation of Synthetic Zeolites. III) Record - 10 Marks
5) Determination of ‘N’ and ‘P’ nitrogen and phosphous containing IV) Viva- Voce - 10 Marks
fertilizer respectively by suitable methods.
Total - 100 Marks
6) Determination of Iron and Calcium from Cement by suitable
methods. List Of Books-
7) Determination of Lead (Pb) from Opal Glass by suitable methods. 1. Practical Engineering by S. S. Dara.
8) Experiments based on distillation under reduced pressure, fractional 2. Labortary Preparation of Microchemistry by E. M. M. Effery,
and steam distillation. McGraw Hill.
9) Measurment of flash point, ignition point, kinematic viscosity by 3. Practical Course in Polymer Chemistry by S. J. Pnnea, Pargaman
U-tube method. Press
10) Estimation of Copper from – fungicides. 4. Practical Pharmacognosy by T. B. Willis.
11) Determination of pesticide contents in the soil. 5. Practical Pharmacognosy by T. N. Vasudevan.
12) Preparation of Methyl orange, Methyl red, orange II, Fluorescin, 6. Indian Pharmacopea-1985, British Pharmacopea-1990.
Quinoline, Anthraquinone. 7. Handbook of Drugs and Cosmetics by Mehrotra
13) Quantitative estimations of important commercially available drugs. 8. Methods of Pesticide Analysis by Sree Ramuly U. I. Oxford and
IBH Publishing Co.
 87 88
9. Methods of testing for petroleum and petroleum products. IS 1448- 20) Colorimetric determination of simple ions (phosphate, sulphate,
1960 Part I to Part IV. Published by ISI New Delhi 1967 nitrate/nitrite, toxic heavy metals).
10. IP Stands for Petroleum and products Published Applied Service 21) Analysis of soap and detergent.
Publisher Ltd. London, 33rd Edition 1974. 22) Determination of alcohol from beverages spectrophotometrically
11. American Stds. For testing Materials, New York 1967. using dichromate.
12. Textbook of Inorganic Chemistry by A. I. Vogel. 23) Determination of amount of Zinc from the given sample solution by
13. Instrumental Methods of Analysis by Willard, Merit and Dean Nephelometric/Turbidimetric titration using standard solution of
Ba (NO3)2 or
14. Industrial Chemicals, Faith et. al. Wiley Interscience New York
24) Pb (NO3)Analysis of Pharmaceutical mixtures
15. Textbook Of Practical Organic Chemistry by I. C. Voley.
25) Simultanious determination of Vitamic C andVitamin E
16. Industrial Organic Chemistry by J. K. Sttille 26) Analysis of some common pesticides insecticides, plastics and
17. Unit Operations by Kale detergents
18. Reagents for Organic Synthesis Fisher and Fisher. 27) To determine the amount of each para nitro-phenol and meta nitro-
19. Technique of Organic Chemistry Vol I, Part I- IV A. Weishberger. phenol from the given mixture by spectrophotometric titration using
standard solution of NaOH (max-280 nm)
28) Estimation of sodium benzoate/sodium metabisulphite. boric acid
Semester IV and salicylic acid in food
Analytical Chemistry Practicals (Special) 29 ) Analysis of chrome steel alloy for chromium and nickel content
Total Hours: 90 hrs. (9 Hours per week) Marks: 100 30) Agricultural analysis of soil sample, animal feeds, soil micronutrients,
milk powder for Ca, Fe and P content.
1) Solvent extraction of Al/Mg or Mg/UO2 using 8- hydroxy quinoline 31) Any other relevant expt. may be added
complex and determination by spectrophotometry.
2) Separation and estimation of copper and cobalt on cellulose Column. The Practical examination will be based on the syllabus of Analytical
3) Analysis of pyrolosite with respect to I) iron II) Manganese Chemistry (Special Papers).
4) Assay of sulpha drugs
5) Analysis of vit. C in juice and squashs Time: 6-8 hours (one day examination) Marks: 100
6) Determination of sap value and iodine value of oil.
7) Determination of p- nitrophenol by colorimetry. I) Exercise -1 - 40 Marks
8) Determination of iron in syndets by colorimetric method. II) Exercise-2 - 40 Marks
9) Determination of Phenol by Conductometry. III) Record - 10 Marks
10) Potentiometric determination of thiourea. IV) Viva- Voce - 10 Marks
11) Estimation of calcium/sodium in the sample of dairy whitener by —————————————————————————————
flame photometry. Total -100 Marks
12) Analysis of pigments with respect to Zn and Cr.
—————————————————————————————
13) To determine the amout of each copper and bismuth or copper and
iron (III) from the given mixture at 745 nm by spectrophotometric M.Sc. (Chemistry)
titration using solution of Semester-IV
14) EDTAIdentification of sulpha drug in tablets and ointments by TLC. Practical-VIII - Project Work
15) Fertilizer analysis for N, P, K
Time : 9 Hrs. Per Week Marks : 100
16) Analysis of iodized table salt for its iodine content.
The Students will develop utilities such as analytical spectra,
17) Estimation of the purity of given azo dye colorometrically.
simulation programmes that will suppliment laboratory exercises in their
18) Chemical analysis of chilly and turmeric powder.
subject of specialization. For this, variety of small research project designed
19) Simultaneous estimation of Cl and I by potentiometric method.
by the teacher based on the interest of the student and capabilities should
be worked out.
 89 90
The project will be evaluated by external and internal examiners. 30. Refrigerator 01 no./lab
Study Tour: Educational / Industrial tour is compulsory for M.Sc. 31. Magnetic stirrer 2 ml, 5 ml. 02 nos./batch
Chemistry. 32. Dimmer state 01 no./lab
(i) Semesters I / II : Visit to local industry. 33. Abbe’s refractometer 01 no./batch
(ii) Semester III / IV : Education tour to visit the industry / 34. Sodium lamp for polarimeter 02 nos./batch
Research Laboratory. 35. T.L.C. Kit 01 no./lab
36. Calorimeter 01 no./lab
List of equipments/appratus required for the M.Sc. Chemistry Semester- 37. Bomb Calorimeter 02 nos./batch
I to IV Practicals. 38. BOD analyser 01 no./lab
1. Conductivity meter 03 nos./batch 39. Water analysis kit 01 no./lab
2. pH meter 03 nos./batch 40. Computer-386/486 01 no./lab
3. Potentiometer 03nos./batch 41. U.V.Lamp 02 no./lab
4. Polariometer 02 nos./batch 42. Ice making machine 01 no./lab
5. Centrifuge machine 02 nos./batch 43. LCR bridge 01 no./lab
6. Vaccum Pump 01 no./batch 44. HPLC 01 no./lab
7. Hot air oven 01 no./batch 45. Deioniser 01 no./lab
8. Blower hot & cold 03 nos./batch 46. Ion exchange column’s 04 no./lab
9. Stop watch 10 nos./batch 47. Turbidity meter 01 no./lab
10. Weight box con.100 gm. 10 nos./batch 48. Optical densitometer 01 no./lab
11. Analytical double pan balance 10 nos./batch 49. Orsat apparatus (gas analysis) 01 no./lab
12. One pan electrical balance 10 nos./batch 50. Interferometer (ultrasound) 01 no./batch
13. Tripple beam balance 02 nos./batch 51. Youy’s balance 01 no./lab
14. Melting point apparatus 02 nos./batch 52. Hydraulic press 01 no./lab
15. Spectro photometer 02 nos./batch 53. Shaking machine 01 no./lab
16. Water still 01 no./lab 54. G.M.Counter 01 no./lab
17. Colorimeter 02 nos./batch 55. Electrophorasis apparatus 01 no./lab
18. Thermostate 01 no./batch 56. Karl-Fisher Titration apparatus 01 no./lab
19. Electrodes platinum 03 nos./batch 57. Power supply (regulator) 01 no./batch
Silver 03 nos./batch 58. Regulated furnace 01 no./lab
Glass 03 nos./batch 59. Thermocouple 01 no./lab
Reference 03 nos./batch 60. Vaccum oven 01 no./lab
20. Heating mentle 02 nos./batch 61. Top pan balance 01 no./lab
21. Glass double distillation unit 01 no./lab etc.,
22. Flamed Photometer 01 no./batch
23. LCR meter 01 no./lab List of glasswares (main) for M.Sc. Chemistry Semester-I to IV
24. Polarpgraph with recorder 01 no./lab Practicals
25. U.V.visible spectrophotometer 1 no./lab 1. Soxhlet set 02 nos./batch
26. Standard cell 02 nos./batch 2. Kjeldahl’s apparatus set 02 nos./batch
27. Muffle furnace 01 no./lab (for Nitrogen element estimation)
28. D.C.Voltmeter 01 no./lab 3. Distillation unit 04 nos./batch
29. Infrared lamp 05 nos./lab 4. Separating funnel 10 no./batch
 91
5. Steam distillation unit 02 nos./batch
6. Vaccum desicator 01 no./batch
7. Paper chromatography chamber 03 nos./batch
8. Silica crucibles 20 nos./batch
9. Sintered glass crucibles g4/g5 20 nos./batch
10. Spot test plates 10 nos./batch
11. Wash bottles 10 nos./batch
12. Density bottles 10 nos./batch
13. Viscometer 10 nos./batch
14. Kipp’s apparatus 10 nos./batch
15. Beakers, capacity :50 ml, 100 ml, 250 ml, 400 ml, 500 ml, 1000ml,
16. Conical flask : 100 ml, 250 ml.
17. Burettes with stop cock, capacity : 2ml, 5 ml, 10ml, 25 ml.
18. Lambda pipette 02 nos./batch
19. Voumetric flasks, capacity : 10 ml, 25 ml, 50 ml, 100 ml, 250 ml, 500 ml,
1000ml.
20. Measuring cylinder, capacity : 10 ml, 25 ml, 50 ml, 100 ml, 500 ml,
1000 ml
21. Pipette, capacity : 1 ml, 2 ml, 5 ml, 10 ml, 25 ml.
22. Stalagnometer 10 nos./batch
23. Thermometer (b-24) 0 to 3600C (quick fit) 05 nos./batch
24. Water suction pump (glass) 05 nos./batch
25. Filtration flasks with buckner funnels 50 ml 10 nos./batch
100ml 10 nos./batch
250ml 10 nos./batch
500ml 10 nos./batch
26. Quick fit stand joints b-14, b-19, b24
27. China dishes 10 nos./batch
28. Dessicators 10 nos./batch
29. Thiel’s tube for melting point 05 nos./batch
30. Quick fit water condensors b-19, b-24 10 nos./batch
31. Quick fit flasks, Capacity 50 ml, 100 ml,
250 ml, 500 ml, 1000 ml. 10 nos./batch

*****